CN105307630A - Shampoo composition - Google Patents
Shampoo composition Download PDFInfo
- Publication number
- CN105307630A CN105307630A CN201480034963.1A CN201480034963A CN105307630A CN 105307630 A CN105307630 A CN 105307630A CN 201480034963 A CN201480034963 A CN 201480034963A CN 105307630 A CN105307630 A CN 105307630A
- Authority
- CN
- China
- Prior art keywords
- component
- quality
- aforementioned
- shampoo compositions
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002453 shampoo Substances 0.000 title claims abstract description 116
- 239000000203 mixture Substances 0.000 title claims abstract description 114
- -1 fatty acid glycol ester Chemical class 0.000 claims abstract description 112
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 55
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 55
- 239000006185 dispersion Substances 0.000 claims abstract description 55
- 239000000194 fatty acid Substances 0.000 claims abstract description 55
- 229930195729 fatty acid Natural products 0.000 claims abstract description 55
- 239000007788 liquid Substances 0.000 claims abstract description 44
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 16
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 14
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000001408 amides Chemical class 0.000 claims abstract description 12
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 76
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical group OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 13
- 238000001035 drying Methods 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002932 luster Substances 0.000 description 53
- 238000003860 storage Methods 0.000 description 33
- 238000000465 moulding Methods 0.000 description 30
- 238000000034 method Methods 0.000 description 25
- 229920001296 polysiloxane Polymers 0.000 description 24
- 238000011010 flushing procedure Methods 0.000 description 21
- 244000293323 Cosmos caudatus Species 0.000 description 18
- 235000005956 Cosmos caudatus Nutrition 0.000 description 18
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 18
- 238000000926 separation method Methods 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 16
- 238000005406 washing Methods 0.000 description 16
- 239000012530 fluid Substances 0.000 description 14
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 12
- 239000004205 dimethyl polysiloxane Substances 0.000 description 12
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 12
- 229940100608 glycol distearate Drugs 0.000 description 12
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 12
- 239000003240 coconut oil Substances 0.000 description 11
- 235000019864 coconut oil Nutrition 0.000 description 11
- 238000011156 evaluation Methods 0.000 description 11
- 239000013078 crystal Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 7
- 230000006866 deterioration Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000008213 purified water Substances 0.000 description 7
- 210000004761 scalp Anatomy 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 6
- 238000005187 foaming Methods 0.000 description 6
- 238000004321 preservation Methods 0.000 description 6
- 229940057950 sodium laureth sulfate Drugs 0.000 description 6
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 5
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 5
- 239000004299 sodium benzoate Substances 0.000 description 5
- 235000010234 sodium benzoate Nutrition 0.000 description 5
- 235000013599 spices Nutrition 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- 239000004475 Arginine Substances 0.000 description 3
- 208000001840 Dandruff Diseases 0.000 description 3
- BIVBRWYINDPWKA-VLQRKCJKSA-L Glycyrrhizinate dipotassium Chemical compound [K+].[K+].O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@H]1CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@](C)(CC[C@@]5(CC[C@@]4(C)[C@]3(C)CC[C@H]2C1(C)C)C)C(O)=O)C([O-])=O)[C@@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O BIVBRWYINDPWKA-VLQRKCJKSA-L 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 150000008051 alkyl sulfates Chemical class 0.000 description 3
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000003002 pH adjusting agent Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 230000002889 sympathetic effect Effects 0.000 description 3
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- PSYGHMBJXWRQFD-UHFFFAOYSA-N 2-(2-sulfanylacetyl)oxyethyl 2-sulfanylacetate Chemical compound SCC(=O)OCCOC(=O)CS PSYGHMBJXWRQFD-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 244000274847 Betula papyrifera Species 0.000 description 2
- 235000009113 Betula papyrifera Nutrition 0.000 description 2
- 235000009109 Betula pendula Nutrition 0.000 description 2
- 235000010928 Betula populifolia Nutrition 0.000 description 2
- 235000002992 Betula pubescens Nutrition 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- LBBUFSLOOTXUJP-UHFFFAOYSA-N N(=O)OC(C)CCCCCC.C(C=CC1=CC=CC=C1)(=O)O Chemical compound N(=O)OC(C)CCCCCC.C(C=CC1=CC=CC=C1)(=O)O LBBUFSLOOTXUJP-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 229920006322 acrylamide copolymer Polymers 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 150000001340 alkali metals Chemical group 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 2
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
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- 235000013922 glutamic acid Nutrition 0.000 description 2
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- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
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- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- 229940043810 zinc pyrithione Drugs 0.000 description 2
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- OIQPTROHQCGFEF-QIKYXUGXSA-L Sunset Yellow FCF Chemical compound [Na+].[Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=CC2=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 OIQPTROHQCGFEF-QIKYXUGXSA-L 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 description 1
- KFOLLPUZRCFERL-UHFFFAOYSA-N [O-2].[Mg+2].O=[Si]=O Chemical compound [O-2].[Mg+2].O=[Si]=O KFOLLPUZRCFERL-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000008168 almond oil Substances 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000001654 beetroot red Substances 0.000 description 1
- 235000012677 beetroot red Nutrition 0.000 description 1
- 235000002185 betanin Nutrition 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 229960003720 enoxolone Drugs 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 125000005908 glyceryl ester group Chemical group 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 230000003741 hair volume Effects 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229940071826 hydroxyethyl cellulose Drugs 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- NFIDBGJMFKNGGQ-UHFFFAOYSA-N isopropylmethylphenol Natural products CC(C)CC1=CC=CC=C1O NFIDBGJMFKNGGQ-UHFFFAOYSA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000013507 mapping Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LAQFLZHBVPULPL-UHFFFAOYSA-N methyl(phenyl)silicon Chemical compound C[Si]C1=CC=CC=C1 LAQFLZHBVPULPL-UHFFFAOYSA-N 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- WNIFXKPDILJURQ-UHFFFAOYSA-N stearyl glycyrrhizinate Natural products C1CC(O)C(C)(C)C2CCC3(C)C4(C)CCC5(C)CCC(C(=O)OCCCCCCCCCCCCCCCCCC)(C)CC5C4=CC(=O)C3C21C WNIFXKPDILJURQ-UHFFFAOYSA-N 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000004173 sunset yellow FCF Substances 0.000 description 1
- 235000012751 sunset yellow FCF Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000002560 therapeutic procedure Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/45—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
Abstract
[Problem] To provide a shampoo composition which produces good shine, has a stable pearl appearance and maintains uniformity of dispersion even when stored in high-temperature conditions, and has good feel during rinsing and good ease of styling during hair drying after shampooing. [Solution] A shampoo composition containing: (A) a pearlizer liquid dispersion comprising (A1) a fatty acid glycol ester, (A2) a polyoxyethylene fatty acid monoalkanol amide in which the average number of added moles of an ethylene oxide (EO) is 1-5, (A3) a polyhydric alcohol, (A4) a polyoxyethylene alkyl ether sulfate, and (A5) water, the mass ratio A1/A2 of the component (A1) and the component (A2) being 0.5-4, and the mass ratio (A1 + A2)/A3 of the component (A1), the component (A2), and the component (A3) being 20-100; and (B) a sulfate-type anionic surfactant having a sulfate residue including the component (A4).
Description
Technical field
The present invention relates to shampoo Compositions.
Background technology
Giving the pearly lusters such as shampoo to improve the technology of its commodity value with regard to carrying out widely in the past, and there will be a known the manufacture method (see such as patent documentation 1 and 2) for giving the nacreous dispersion liquids such as shampoo, there is the technology of nacreous shampoo Compositions and manufacture method (see such as patent documentation 3 ~ 5) thereof.
The nacreous shampoo Compositions that has like this has such problem: preserve for a long time or in high temperature environments, can lose the dispersion homogeneity of this nacreous stability and/or pearling agent particle.In order to solve foregoing problems, someone suggested such as following method: in the aqueous system of the anion surfactant of thickening, add isoprenediol, with the method making aforesaid pearling agent stably disperse (see patent documentation 6); Compositions is made to contain the method (see patent documentation 7) of xanthan gum and cation based polymer; Make it the method (see patent documentation 8) containing containing 3-alkyl (C10 ~ 20) oxygen base-2-hydroxypropyl arginine and/or its salt while pearling agent, at suspendible in the waterborne liquid of pearling agent, cool after adding the pearling agent of melting, make the method that pearling agent is separated out, the height (see patent documentation 9) in the aforesaid pearling agent of ratio of the fatty acid of the formation ester that the carbon number in pearling agent described later is large; Add specific water-soluble polymer, make the shampoo Compositions (see patent documentation 10) etc. of pearling agent crystallization with specific manufacture method.
On the other hand, if mix a large amount of pearling agents in shampoo Compositions, so just there is the situation of foaming and/or the foaming properties reduction making shampoo.For this problem, someone proposes such as: the long-chain fatty acid diol ester dispersion liquid as pearling agent adding preparation in addition in cation property copolymer aqueous solution, after having prepared premix material, in other detergent component, mix the method (patent documentation 11 reference) of aforementioned premix material.
In addition, also the pearling agent known in shampoo Compositions not only has impact to foaming, also have impact to the sense of touch of hair after hair washing, the composition of detergent disclosing the pearly-lustre particle containing specified particle diameter obtained by the pearlescent composition of specific composition improves the smoothness (see patent documentation 12) of hair while not reducing hair volume.
But, present situation does not provide a kind of shampoo Compositions, pearling agent is scattered in shampoo Compositions and shows excellent reflecting feel, even if preserve in hot conditions and also can obtain stable pearly luster, while pearling agent dispersion homogeneity continues, the moulding easiness after sense of touch when rinsing shampoo and hair washing in trichoxerosis process is good.
Prior art document
Patent documentation
[patent documentation 1] Japanese Patent Laid-Open No. Sho 60-25906 publication
[patent documentation 2] Japanese Patent Laid-Open 2003-155214 publication
[patent documentation 3] Japan Patent examined patent publication 44-671 publication
[patent documentation 4] Japanese Patent Laid-Open 4-244009 publication
[patent documentation 5] Japanese Patent Laid-Open 4-26614 publication
[patent documentation 6] Japanese Patent Laid-Open 7-188693 publication
[patent documentation 7] Japanese Patent Laid-Open 11-228383 publication
[patent documentation 8] Japanese Patent Laid-Open 2002-121131 publication
[patent documentation 9] Japanese Patent Laid-Open 2004-67641 publication
[patent documentation 10] Japanese Patent Laid-Open 2006-316035 publication
[patent documentation 11] Japanese Patent Laid-Open 2004-83480 publication
[patent documentation 12] Japanese Patent Laid-Open 2010-53037 publication
Summary of the invention
The problem that invention will solve
The present invention solving above-mentioned all problems, reach following object for problem.The object of the present invention is to provide a kind of shampoo Compositions, it shows excellent reflecting feel, also can obtain stable pearlescent appearance even if preserve under the high temperature conditions, while dispersion homogeneity continues, the moulding easiness after sense of touch during flushing and hair washing in trichoxerosis process is good.
Solve the means of problem
Shampoo Compositions of the present invention as the method solving aforementioned problems contains:
(A) pearling agent dispersion liquid, polyoxyethylene fatty acid monoalkylol amide, (A3) polyhydric alcohol, (A4) polyoxyethylene alkyl ether sulfate salt and (A5) water that described pearling agent dispersion liquid is 1 ~ 5 by the average addition molal quantity of (A1) fatty acid diol ester, (A2) oxirane are formed, the mass ratio A1/A2 of aforementioned (A1) component and aforementioned (A2) component is 0.5 ~ 4, mass ratio (the A1+A2)/A3 of aforementioned (A1) component and aforementioned (A2) component and aforementioned (A3) component is 20 ~ 100, and
(B) the sulfate type anionic surfactant with sulphuric acid residue of aforementioned (A4) component is comprised.
The effect of invention
If according to the present invention, then solve aforesaid all problems in the past, aforementioned object can be completed, shampoo Compositions can be provided, it shows excellent reflecting feel, also can obtain stable pearlescent appearance even if preserve in hot conditions, while dispersion homogeneity continues, the moulding easiness after sense of touch during flushing and hair washing in trichoxerosis process is good.
Accompanying drawing explanation
[Fig. 1] Fig. 1 is the phase contrast microscope photo of the pearling agent crystal (pearly luster particle) in the shampoo Compositions that obtains of embodiment 1.
[Fig. 2] Fig. 2 is the phase contrast microscope photo of the pearling agent crystal (pearly luster particle) in the shampoo Compositions that obtains of comparative example 4.
[Fig. 3] Fig. 3 is the phase contrast microscope photo of the pearling agent crystal (pearly luster particle) in the shampoo Compositions that obtains of comparative example 6.
Detailed description of the invention
(shampoo Compositions)
Shampoo Compositions of the present invention contains the pearling agent dispersion liquid that polyoxyethylene fatty acid monoalkylol amide, (A3) polyhydric alcohol, (A4) polyoxyethylene alkyl ether sulfate salt and (A5) water that (A) is 1 ~ 5 by the average addition molal quantity of (A1) fatty acid diol ester, (A2) oxirane are formed, (B) the sulfate type anionic surfactant with sulphuric acid residue of aforementioned (A4) component is comprised, further as required containing other component.
The fatty acid diol ester of aforementioned (A1) of the present invention component is generally by being scattered in shampoo Compositions as crystal thus can giving shampoo Compositions reflecting feel.Melt the fatty acid diol ester of aforementioned (A1) component, it is made to disperse to be mixed in the aqueous surfactant solution of more than the fatty acid diol ester fusing point remaining on aforementioned (A1) component, by cooling the dispersed mixture obtained, thus the pearling agent dispersion liquid of the fatty acid diol ester crystal of aforementioned (A1) component can be prepared.The pearling agent dispersion liquid of (A) component obtained is added into and contains as in the various component mixed solutions of the sulfate type anionic surfactant of aforementioned (B) component, the fatty acid diol ester concentration making (A1) component in shampoo is normal concentration, thus can prepare the shampoo Compositions imparting Margarita outward appearance.
< (A) pearling agent dispersion liquid >
Polyoxyethylene fatty acid monoalkylol amide, (A3) polyhydric alcohol, (A4) polyoxyethylene alkyl ether sulfate salt and (A5) water that the pearling agent dispersion liquid of aforementioned (A) component is 1 ~ 5 by the average addition molal quantity of (A1) fatty acid diol ester, (A2) oxirane are formed.
-(A1) fatty acid diol ester-
Consider from the angle of pearly luster sense and storage stability, the preferred chain length of fatty acid alkyl of the fatty acid diol ester of aforementioned (A1) component is the straight chain of 14 ~ 22, more preferably 18 ~ 22.The concrete ethylene glycol bisthioglycolate enumerated myristin, ethylene glycol bisthioglycolate cetylate, glycol distearate, ethylene glycol monostearate, ethylene glycol bisthioglycolate behenate etc.They can a kind be used alone, also can two or more also use.Wherein, consider from pearly luster sense this point, preferred glycol distearate.
Consider from pearly luster sense this point, the fusing point of the fatty acid diol ester of aforementioned (A1) component preferably 59 DEG C ~ 70 DEG C, more preferably 61 DEG C ~ 63 DEG C.If aforementioned fusing point is more than 70 DEG C, pearly luster is sympathetic can not be manifested fully, the stability degradation of pearling agent dispersion liquid in addition.On the other hand, if aforementioned fusing point is less than 59 DEG C, the storage stability of Margarita outward appearance reduces.
With reference to the method recorded in " medicine part outer article raw material standard 2006 (Yao Shi newspaper office) " (medicine part outer article raw material Regulations lattice 2006 (Yao Shi Reported society)) ordinary test method 70. melting point determination the 1st method, the fusing point of the fatty acid diol ester of aforementioned (A1) component can be measured.
Glycol distearate as the fatty acid diol ester of aforementioned (A1) component can use commercially available product.The commercially available product of aforementioned glycol distearate such as can be illustrated GenapolPMS (fusing point: 63 DEG C, Clariant company (Network ラ リ ア Application ト society) system), CutinaAGS-T (fusing point: 63 DEG C, BASF AG's system), TeginG1100 (fusing point: 61.4 DEG C, Evonik Inc.), TeginEGS (fusing point: 69.2 DEG C, Evonik Inc.) etc.Wherein, consider from reflecting feel this point, preferred TeginG1100 (fusing point: 61.4 DEG C, Evonik Inc.), GenapolPMS (fusing point: 63 DEG C, Clariant Inc.), CutinaAGS-T (fusing point: 63 DEG C, BASF AG's system).
Consider from the angle of the moulding easiness after pearly luster sense and hair washing, the content of the fatty acid diol ester of aforementioned (A1) component is relative to aforementioned shampoo Compositions total amount preferably 0.5 quality % ~ 5 quality %, more preferably 0.75 quality % ~ 3 quality %.If just can not give aforementioned shampoo Compositions sufficient pearly luster aforementioned containing quantity not sufficient 0.5 quality %, if more than 5 quality %, then the dispersion stabilization in shampoo Compositions worsens, and uses the moulding easiness deterioration after shampoo.
-(A2) polyoxyethylene fatty acid monoalkylol amide-
The polyoxyethylene fatty acid monoalkylol amide of aforementioned (A2) component is the component played a role as the dispersant of the fatty acid diol ester of aforementioned (A1) component.
Consider from the angle of smoothness during flushing when pearly luster sense, dispersion stabilization, hair washing and moulding easiness, saturated or the unsaturated alkyl of the carbon number 9 ~ 17 of the polyoxyethylene fatty acid monoalkylol amide preferred fatty acid of aforementioned (A2) component, the average addition molal quantity of optimization ethylene oxide (EO) is 1 ~ 5.Consider from the angle of pearly luster sense, storage stability, more preferably the carbon number of fatty acid is 11 ~ 13, the average addition molal quantity of oxirane (EO) is 1 ~ 2.
If the carbon number of aforementioned fatty acids is less than 9, the sympathetic possible deviation of pearly luster, if more than 17, the stability of pearling agent dispersion liquid just may reduce.In addition, if the average addition molal quantity of aforementioned epoxy ethane (EO) is less than 1, while pearly luster sense is deteriorated, smoothness when using the flushing after shampoo Compositions, the deterioration of moulding easiness, if more than 5, then do not manifest pearly luster sense, the storage stability in shampoo Compositions worsens.
Concrete, polyoxyethylene (1) coconut oil fatty acid monoethanolamide, polyoxyethylene (2) lauric monoethanolamide, polyoxyethylene (2) coconut oil fatty acid monoethanolamide, polyoxyethylene (4) coconut oil fatty acid monoethanolamide, polyoxyethylene (5) coconut oil fatty acid monoethanolamide etc. can be enumerated.They can a kind be used alone, also can two or more also use.Wherein, consider from storage stability this point, preferred polyoxyethylene (2) lauric monoethanolamide, polyoxyethylene (2) coconut oil fatty acid monoethanolamide, polyoxyethylene (1) coconut oil fatty acid monoethanolamide, consider from pearly luster sense this point, preferred polyoxyethylene (2) lauric monoethanolamide.
The polyoxyethylene fatty acid monoalkylol amide of aforementioned (A2) component can use commercially available product.Aforementioned commercially available product include, for example trade name " Amizetto " (the ア ミ ゼ ッ ト) series etc. that Chuan Yan fine chemistry industry Co., Ltd. (Off ァ イ Application ケ ミ カ Le Co., Ltd. is ground in river) makes, polyoxyethylene (2) lauric monoethanolamide (Amizetto2L-Y) can be enumerated, polyoxyethylene (2) coconut oil fatty acid monoethanolamide (Amizetto2C), polyoxyethylene (5) coconut oil fatty acid monoethanolamide (Amizetto5C), polyoxyethylene (1) coconut oil fatty acid monoethanolamide (NorfoxDGCA, Norman, Fox & Co Inc.), polyoxyethylene (4) coconut oil fatty acid monoethanolamide (EmpilanMAA, Albright & WilsonUKLimited system) etc.
Consider from the angle of the use sense of pearly luster sense and shampoo Compositions, the content of the polyoxyethylene fatty acid monoalkylol amide of aforementioned (A2) component is relative to aforementioned shampoo Compositions total amount preferably 0.5 quality % ~ 5 quality %, more preferably 0.75 quality % ~ 3 quality %.If aforementioned, containing quantity not sufficient 0.5 quality %, then the fatty acid diol ester of aforementioned (A1) component can not disperse fully, and pearly luster sense is deteriorated.On the other hand, if aforementioned content is more than 5 quality %, then smoothness when rinsing is destroyed, and the moulding easiness after shampoo is poor.
-mass ratio A1/A2-
Consider from the angle of smoothness when rinsing when pearly luster sense and shampoo, moulding smoothness, the mass ratio A1/A2 of the content of aforementioned (A1) component and the content of aforementioned (A2) component is 0.5 ~ 4, preferably 0.75 ~ 2.If aforementioned mass ratio A1/A2 less than 0.5, then can not obtain pearly luster sense, if aforementioned mass ratio A1/A2 is more than 4, then pearly luster is sympathetic insufficient, rinse shampoo Compositions time smoothness and shampoo after moulding easiness be deteriorated.
Consider from the angle of pearly luster sense and use sense, the total amount of aforementioned (A1) component and aforementioned (A2) component is relative to aforementioned shampoo Compositions total amount preferably 1.4 quality % ~ 8 quality %, more preferably 1.5 quality % ~ 4.5 quality %.Within the scope of this, the pearly luster sense of shampoo Compositions and dispersion stabilization good.In addition, the moulding easiness be coated in by shampoo Compositions after smoothness when hair bubbling afterflush, hair washing is good.If aforementioned total amount is less than 1.4 quality %, then has and can not obtain sufficient nacreous situation, if more than 8 quality %, then have smoothness during flushing to be destroyed, use the situation of the moulding easiness difference after shampoo.
-(A3) polyhydric alcohol-
The polyhydric alcohol of aforementioned (A3) component can enumerate such as Polyethylene Glycol, propylene glycol, dipropylene glycol, hexanediol, Sorbitol, 1,3 butylene glycol, isoprenediol, glycerol etc.They can a kind be used alone, also can two or more also use.
Consider from the angle of the use sense of storage stability and shampoo Compositions, in foregoing polyols, preferred IOB value is 1.8 ~ 4, more preferably 1.8 ~ 3.3.3.3), dipropylene glycol (IOB value: 1.8), hexanediol (IOB value: 1.8), 1,3 butylene glycol (IOB value: 2.5), isoprenediol (IOB value: 2.0), PEG400 (IOB value: 2.3) concrete preferred propylene glycol (IOB value:.If aforementioned IOB value is less than 1.8, then have that pearly luster sense is unexcellent, the storage stability of pearling agent situation unsatisfactory, if more than 4, then have the shampoo being mixed with aforementioned pearling agent dispersion liquid storage stability deterioration, rinse time smoothness and moulding easiness situation unsatisfactory.
Herein, aforementioned IOB value refers to the ratio of the inorganic value (IV) in organic conceptional diagram for organic value (OV), that is, " inorganic value (IV)/organic value (OV) ".Aforementioned organic conceptional diagram refers to what Tentianmu was advised, and details is at " pharmacy publication " (PharmaceuticalBulletin) 1954, vol.2,2, p.163-173, " chemical field " ization Collar territory), 1957, vol.11,10, p.719-725, " the cosmetic literature magazine of Japan " (Off レ グ ラ Application ス ジ ャ ー Na Le), 1981, vol.50, has explanation in p.79 ~ 82 grades.That is, methane (CH
4) as the root of whole organic compound, other compounds all can regard the derivant of methane as, its carbon number, substituent group, crushed element, ring etc. are set as certain numerical value respectively, its score is added, try to achieve organic value, inorganic value, using this value at organic value as X-axis, inorganic value is obtained as mapping in the figure of Y-axis.During this organic conceptional diagram is also shown in " organic conceptional diagram-basis and application-" (have Machine concept map-Ji Foundation と ying with-) (first Tian Shansheng work, three publish altogether, 1984) etc.
From the viewpoint of the storage stability of Margarita outward appearance and shampoo Compositions and smoothness when rinsing, the content of the polyhydric alcohol of aforementioned (A3) component is relative to aforementioned shampoo Compositions total amount preferably 0.02 quality % ~ 0.5 quality %, more preferably 0.03 quality % ~ 0.2 quality %.If aforementioned containing quantity not sufficient 0.02 quality %, then the situation having the homogeneous dispersibility of the fatty acid diol ester of aforementioned (A1) component to worsen, the situation that smoothness when having the storage stability of shampoo Compositions and rinse is deteriorated.On the other hand, if aforementioned content is more than 0.5 quality %, then there is the insufficient situation about manifesting of Margarita sense.
-mass ratio (A1+A2)/A3-
Mass ratio (the A1+A2)/A3 of aforementioned (A1) component and aforementioned (A2) component and aforementioned (A3) component is 20 ~ 100, preferably 30 ~ 75.If within the scope of this, then the pearly luster sense of shampoo Compositions and storage stability good, the smoothness during foaming afterflush of shampoo Compositions, the moulding easiness after shampoo hair washing are good.
If aforementioned mass ratio (A1+A2)/A3 is less than 20, then can not get good pearly luster sense, if more than 100, then have the deterioration of the storage stability of pearling agent, shampoo Compositions flushing time smoothness, the unexcellent situation of moulding easiness after hair washing.
-(A4) polyoxyethylene alkyl ether sulfate salt-
The polyoxyethylene alkyl ether sulfate salt of aforementioned (A4) component can improve the dispersibility of aforementioned (A1) fatty acid diol ester etc. further.The compound identical with the polyoxyethylene alkyl ether sulfate salt in (B) described later component can be used.The content of the polyoxyethylene alkyl ether sulfate salt of aforementioned (A4) component is relative to the total amount preferably 0.5 quality % ~ 5 quality % of pearling agent dispersion liquid, more preferably 1 quality % ~ 3 quality %.
In addition, content in the shampoo Compositions of aforementioned (A4) component is, the aggregate value of the content of aforementioned (A4) component comprised with the sulfate type anionic surfactant with sulphuric acid residue of aftermentioned (B) component.
-(A5) water-
The water of aforementioned (A5) component can use pure water or the ultra-pure water of such as ion exchange water, purified water, ultrafiltration water, reverse osmosis water, distilled water etc.Consider from the angle of preservation (separation) stability of pearly luster sense and Margarita dispersant, the content of aforementioned (A5) component water in (A) component, relative to pearling agent dispersion liquid total amount, preferably 30 quality % ~ 90 quality %, more preferably 45 quality % ~ 85 quality %.If aforementioned content is more than 90 quality %, then there is the situation that pearly luster sense is insufficient, if less than 30 quality %, then have the situation of the smoothness deterioration when preservation of pearling agent (separation) stability is unsatisfactory, shampoo rinses,
In the present invention, the content of the pearling agent dispersion liquid of aforementioned (A) component is relative to aforementioned shampoo Compositions total amount preferably 3 quality % ~ 25 quality %, more preferably 5 quality % ~ 20 quality %.If aforementioned containing quantity not sufficient 3 quality %, then there is the situation of the bad stability of pearly luster sense and pearling agent, if more than 25 quality %, then have the situation that the moulding easiness after hair washing is deteriorated.
< (B) has the sulfate type anionic surfactant > of sulphuric acid residue
Aforementioned (B) component comprises the sulfate type anionic surfactant with sulphuric acid residue of described (A4) component, is the component forming the foam of appropriateness and the washing base of the spot of adhering in removal hair.
The sulfate type anion surfactant with sulphuric acid residue comprising aforementioned (A4) component of aforementioned (B) component, include, for example alkyl sulfate, alkenyl sulfate, polyoxyalkylene ether sulfate, polyoxyalkylene alkenyl ether sulfates, polyoxyalkylene alkylamine phenyl ether sulfate, sulphate of glyceryl ester, amide ether sulfate etc.They can a kind be used alone, but also two or more is also used.The wherein polyoxyalkylene alkyl ether sulfate, the polyoxyalkylene alkenyl ether sulfates that represent of preferred following general formula (B1), alkyl sulfate, alkenyl sulfate that preferred following general formula (B2) represents, the polyoxyethylene alkyl ether sulfate salt that preferred following general formula (B1) represents.
R
1o (CH
2cH
2o) mSO
3m general formula (B1)
But (, in aforementioned formula (B1), R
1represent the alkyl or alkenyl of carbon number 10 ~ 18, M represents alkali metal, ammonium or alkanolamine, and m represents the number of average addition molal quantity 1 ~ 5.〕
R
2oSO
3m general formula (B2)
But (, in aforementioned formula (B2), R
2represent the alkyl of carbon number 10 ~ 18, M represents alkali metal, ammonium or alkanolamine.〕
In front note general formula (B1) and (B2), R
1, R
2the concrete lauryl enumerated, myristyl, palmityl, stearyl etc.
M can enumerate the alkali metal salts such as lithium, sodium, potassium, the alkanolamine etc. of monoethanolamine, diethanolamine, triethanolamine etc.
In addition, deposit, the R in preferred aforementioned formula (B1) from the viewpoint of the smoothness when steady dissolution in aforementioned shampoo Compositions and good flushing
1, and aforementioned formula (B2) in R
2for the alkyl of carbon number 12 ~ 16.Concrete preferred lauryl, myristyl, palmityl, more preferably lauryl.
In addition, consider from smoothness this point when rinsing, m preferably 2 ~ 3 in aforementioned formula (B1).
Consider from smoothness this point during flushing after hair washing, the preferred sodium of M or ammonium in aforementioned formula (B1) and (B2).
The sulfate type anionic surfactants with sulphuric acid residue of aforementioned (B) component such as polyoxyethylene alkyl ether sulfate salt can enumerate " TexaponN28L " (BASF AG's system) as polyoxyethylene (2) sodium laureth sulfate, " CinnolineSPE-1250 " (シ ノ リ Application SPE-1250) (New Japan Chem Co., Ltd's system), " Pepmacol2SLES70 " (PEPMACO Inc.), as " TexaponALES70 " etc. of polyoxyethylene (3) Zetesol AP.The example of alkyl sulfate can enumerate " TexaponALS70 " (BASF AG's system) as ammonium lauryl sulfate, " TexaponK12 " (BASF AG's system) etc. as sodium lauryl sulfate.Wherein, consider from smoothness this point when rinsing, preferred polyoxyethylene (2) sodium laureth sulfate, polyoxyethylene (3) sodium laureth sulfate.In addition, the average addition molal quantity of () interior representative ring oxidative ethane.
Consider from the angle of fluidity when bubbling, use and washing performance, the content with the sulfate type anionic surfactant of sulphuric acid residue of aforementioned (B) component, relative to aforementioned shampoo Compositions total amount preferably 5 quality % ~ 30 quality %, more preferably 10 quality % ~ 25 quality %, further preferred 12 quality % ~ 20 quality %.If aforementioned containing quantity not sufficient 5 quality %, then there is the situation that the smoothness of flushing is deteriorated, if more than 30 quality %, then high, smoothness deterioration when rinsing of toughness, the situation of desired performance can not be shown.
In addition, the content with the sulfate type anionic surfactant of sulphuric acid residue of aforementioned (B) component is the aggregate value of the content of the polyoxyethylene alkyl ether sulfate salt comprising (A4) component in pearling agent dispersion liquid.
Other compositions of < >
Other components aforesaid only otherwise damaging effect of the present invention just has no particular limits, suitably can be selected according to object, to include, for example in general shampoo Compositions widely used various addO-on therapy etc.
The concrete example of other components aforementioned can enumerate the hydrocarbon such as liquid paraffin, squalane; The esters such as isopropyl myristate; Camellia oil, almond oil, Jojoba wet goods vegetable oil; The silicone compounds such as methyl polysiloxane; The plant extracts such as white birch extract; The cationic surface active agents such as mountain Yu base trimethyl ammonium chloride; The non-ionic surface active agents such as polyoxyethylene alkyl ether, fatty acid glyceride, sucrose fatty acid ester, polyglyceryl fatty acid ester, polyoxyethylene hydrogenated Oleum Ricini; The amphoteric surfactantes such as lauric amide CAB, lauric amide hydroxysultaine, lauryl dimethyl amine oxide; Gallic acid-derivate; The aminoacid such as glycine, serine, arginine; The antiinflammatory such as 2-pyrrolidone-5-carboxylic acid or salt, crude drug, vitamin, glycyrrhizic acid dipotassium, enoxolone; The antidandruff agent such as piroctone olamine salt (ピ ロ Network ト Application オ ラ ミ Application), Zinc Pyrithione; The antibacterial such as isopropyl methyl phenol, triclosan; Coal tar oil colours element; The UV absorbent such as OXYBENZONE, methoxyl group cinnamic acid 2-Octyl Nitrite; The antioxidants such as dibenzylatiooluene; The wetting agents such as glycerol, trimethylamino acetic acid; Water, ethanol equal solvent; The anionic polymers such as acrylic acid series polymeric compounds, acrylate/stereth-20 methacrylate copolymer; The nonionic polymeric such as vinyl pyrrolidone type polymer; The amphiphilic polymers such as diallyldimethylammonium chloride/acrylic acid; The cation property copolymers such as Poise C-80M; The inorganic particles such as anhydride silica, magnesium oxide silicon dioxide; The organic powder such as nylon, polyethylene; Spice; The pH adjusting agents such as citric acid, sodium citrate, two alkyd; The amines such as acyl glutamic acid triethanolamine; The antiseptic such as sodium benzoate; Hydroxyethane diphosphonic acid, dibenzylatiooluene, disodium edetate etc. are stable.They can a kind be used alone, also can two or more also use.
Aforementioned silicone compound is not particularly limited, suitably can select from the material being generally used for shampoo Compositions, include, for example dimethyl polysiloxane and (comprise high polymerization dimethyl polysiloxane, silicone rubber), methyl phenyl silicone, polyether modified silicone, poly-amino modified silicone, betanin modified silicone, ethanol modifier silicone, fluorine richness silicone, epoxy-modified silicone, sulfhydryl modified silicone, carboxy-modified silicone, fatty acid modified silicone, silicone graft polymer, cyclic silicone, alkyl-modified silicone, trimethylsilyl terminal dimethyl polysiloxane, silanol group terminal dimethyl group polysiloxanes etc.They can a kind be used alone, also can two or more also use.Wherein, preferred dimethyl polysiloxane, polyether modified silicone, poly-amino modified silicone.
Aforesaid cations polymer include, for example dimethyl diallyl ammonium chloride-acrylamide copolymer, trimethyl methyl acrylic amido propyl ammonium chloride-acrylic acid-acrylic acid methyl ester terpolymer, trimethyl methyl acrylamide propyl ammonium chloride-acrylic acid-acrylamide terpolymer, methacryloylethyl trimethyl ammonium chloride-N-(2-ethoxy) acrylamide copolymer, O-[2-hydroxyl-3-(trimethyl ammonium) propyl group] hydroxyethyl-cellulose, JR-125 etc.
Mean diameter (the average major diameter of the number) > of < pearly-lustre particle
Consider from the angle of smoothness when Margarita outward appearance, pearlescence, flushing, the mean diameter (the average major diameter of number) preferably 6 μm ~ 11 μm of aforementioned pearling agent particle (crystal), more preferably 7 μm ~ 10 μm.
If aforementioned mean diameter is less than 6 μm, then there is insufficient situation of preservation (separation) poor stability manifesting pearly luster sense, pearling agent.On the other hand, if more than 11 μm, then there is preservation (separation) poor stability of pearling agent, smoothness and a situation of moulding easiness deterioration when rinsing.
Aforementioned mean diameter is obtained by following method: be added drop-wise to by shampoo Compositions in sliding glass, with phase contrast microscope, (Olympus Co., Ltd (オ リ Application パ ス society) makes, AX70), observe under 400 times, the major diameter of the pearling agent particle that random mensuration 50 is identified as crystallization, the meansigma methods obtained is as the mean diameter (the average major diameter of number) of crystallization.
＜pH＞
The pH of aforementioned shampoo Compositions, is not particularly limited, and can carry out suitable selection according to object, is preferably 5.0 ~ 6.0 at 25 DEG C.
Aforementioned pH such as can use pH meter (HM-30G, (East Ami デ ィ ー ケ ー ケ ー Co., Ltd. of East Asia DKK-TOA Co., Ltd.) to make) at 25 DEG C, measure aforementioned shampoo Compositions.
Desired pH adjusting agent can be used to regulate the pH of aforementioned shampoo Compositions.Aforementioned pH adjusting agent is not particularly limited, and suitably can select according to object, include, for example citric acid, succinic acid, sulphuric acid, 2-amino-2-methyl-1-propanol, monoethanolamine, their salt etc.
< viscosity >
The viscosity of aforementioned shampoo Compositions, is not particularly limited, and can carry out suitable selection according to object, is preferably 1Pas ~ 30Pas at 25 DEG C.
Aforementioned viscosity such as can use viscometer (BM type viscometer, TOKIMEC Inc.), adopts No.4 rotor, 30rpm, after 20 seconds, measures under the condition of 25 DEG C.
< purposes >
Aforementioned shampoo Compositions demonstrates pearly luster outward appearance, storage stability is good, hair smoothness during flushing can be given, the moulding easiness after hair washing can be brought, therefore, may be used in various uses, include, for example the Clean-shampoo of scalp, damage nursing shampoo, hair care and hair cleaning agent, containing hair conditioner shampoo, gentle shampoo, scalp care shampoo, anti-dandruff shampoo etc.
[embodiment]
Below, display embodiment and comparative example, specifically describe the present invention, but the present invention is not restricted to following embodiment.In addition, without when writing exactly especially, except pearling agent dispersion liquid, in following embodiment, the quality % of this component in shampoo Compositions represents purity scaled value.Such as, purity scaled value when dimethyl polysiloxane emulsion 3.1 quality % of silicone composition 65 quality % is used to be recited as 2.0 quality %.
(embodiment 1 ~ 29 and comparative example 1 ~ 13)
The manufacture method > of < pearling agent dispersion liquid
(A1) component glycol distearate shown in table 1 ~ table 9, (A2) component polyoxyethylene fatty acid monoalkylol amide and (A3) component polyhydric alcohol are mixed dispersion with ormal weight at 80 DEG C.Then, add (A4) component sodium laureth sulfate and (A5) component purified water wherein, after mixing dispersion, add in 40 DEG C of purified water commensurability with mixture at leisure while stirring, homogeneous dispersion mixing.Herein, stir and use three-in-one motor (ス リ ー ワ ン モ ー タ) (HEIDEN Inc., FBL1200) and propeller blade, thus mixing dispersion.
Then, under the rate of cooling of about 0.5 DEG C/min, while using paddle stirrer to stir the dispersed mixture obtained, be cooled to 25 DEG C in dispersion mixing channel, obtain the pearling agent dispersion liquid of glycol distearate.
Then, after 10 hours, for the preparation of following shampoo Compositions.
The preparation > of < cleansing composition
(B) component recorded by following table 1 ~ table 9 and other components are uniformly mixed 30 minutes in advance at 25 DEG C.Pearling agent (glycol distearate) dispersion liquid that interpolation is prepared above, the pearling agent (glycol distearate) making (A1) component in whole composition is ormal weight.Such as, when the pearling agent concentration in shampoo Compositions is 1.25 quality %, add 13 quality % pearling agent dispersion liquid 9.6 quality % of embodiment 1.About (A1), (A2) and (A3) component, above a line describe its content in pearling agent dispersion liquid, below a line describe its content in shampoo Compositions total amount.Can be calculated containing (A4) component polyoxyethylene lauryl ether sulfate 0.2 quality % (converting according to whole shampoo composition) in aforementioned pearling agent dispersion liquid, but the content of (B) component in embodiment is the total amount comprising the addition come from pearling agent dispersion liquid.But arithmetic point the 3rd rounds up.
After adding pearling agent dispersion liquid, fully stir, use Fructus Citri Limoniae acid for adjusting pH to 5.8 afterwards, manufacture the shampoo Compositions of embodiment 1 ~ 29 and comparative example 1 ~ 13.
In addition, the phase contrast microscope photo of the pearling agent crystal of the shampoo Compositions that embodiment 1 obtains is shown in Fig. 1, the phase contrast microscope photo of the pearling agent crystal of the shampoo Compositions that comparative example 4 obtains is shown in Fig. 2, and the phase contrast microscope photo of the pearling agent crystal of the shampoo Compositions that comparative example 6 obtains is shown in Fig. 3
Below, for each shampoo Compositions obtained, by following evaluation methodology evaluation " pearly luster sense ", " storage stability (Margarita outward appearance) ", " storage stability (fluid separation applications) ", " hair smoothness during flushing " and " moulding easiness ".Result is as shown in table 1 ~ table 9.
< pearly luster sense >
10 special women panel member, from in the 50mL vial of each shampoo Compositions being filled with about 40mL, get about 3mL in hands, evaluate " pearly luster sense " by following visual judgement, try to achieve the meansigma methods of 10, evaluated by following metewand.
(scoring)
3 points: have pearly luster sense
2 points: slightly pearly luster sense
1 point: without pearly luster sense
(metewand)
◎: the average mark of pearly luster sense is more than 2.5 points
Zero: the average mark of pearly luster sense be more than 2.0 points less than 2.5 points
△: the average mark of pearly luster sense be more than 1.5 points less than 2.0 points
×: the average mark of pearly luster sense is less than 1.5 points
Storage stability (Margarita outward appearance) >
In 50mL Clear glass bottles and jars, fill each shampoo Compositions of about 40mL, at 50 DEG C, preserve the Margarita outward appearance after 1 preservation with following metewand evaluation.
(metewand)
◎: have pearly luster sense, manifests Margarita outward appearance fully
Zero: the disappearance confirming extremely few pearly luster sense, but show Margarita outward appearance
△: pearly luster sense disappears quite a lot of, only shows Margarita outward appearance a little
×: pearly luster sense disappears, and does not show Margarita outward appearance
Storage stability (fluid separation applications) >
In 50mL Clear glass bottles and jars, fill each shampoo Compositions of about 40mL, at 50 DEG C, preserve the fluid separation applications after 1 preservation with following benchmark evaluation.
(metewand)
◎: liquid is not separated is stable
Zero: visible extremely few fluid separation applications, but also have commodity value
△: visible fluid separation applications
×: visible significant fluid separation applications
Hair smoothness > when < rinses
After hair with water moistening 20 women's expertise group members fully, hair to expertise group member applies each shampoo Compositions with the use amount of about 6g/ time, makes abundant foaming to enable the foam degree covered on overall hair press...with one's finger to rub scalp.
Then, evaluate the shower with flow 250mL/3 second, temperature 40 DEG C tap water time " hair smoothness ", according to being judged as good number, by following benchmark evaluation " hair smoothness during flushing ".
(metewand)
In ◎: 20, more than 16
In zero: 20, more than 11 less than 15
In △: 20, more than 6 less than 10
×: in 20, less than 5
< moulding easiness >
After hair with water moistening 20 women's expertise group members fully, hair to expertise group member applies each shampoo Compositions with the use amount of about 6g/ time, makes abundant foaming to enable the foam degree covered on overall hair press...with one's finger to rub scalp.
Then, with the shower of flow 250mL/3 second, the tap water of temperature 40 DEG C.
Then, wipe the steam in hair fully with towel, moulding easiness when evaluation hair-dryer dries up, according to being judged as good number, by following benchmark evaluation " moulding easiness ".
(metewand)
In ◎: 20, more than 16
In zero: 20, more than 11 less than 15
In △: 20, more than 6 less than 10
×: in 20, less than 5
[table 1]
[table 2]
[table 3]
[table 4]
[table 5]
[table 6]
[table 7]
[table 8]
[table 9]
Then, the details of each component used in embodiment 1 ~ 29 and comparative example 1 ~ 13 is as shown in following expression 10.
[table 10]
* 1: kinematic viscosity 600,000 mm of the dimethyl polysiloxane emulsion in table 10
2/ s, silicone component 65 quality %, mean diameter 35 μm.
(embodiment 30)
The gentle shampoo > of <
Except following composition and content change, all manufacture shampoo Compositions by the method same with embodiment 1 ~ 29 and comparative example 1 ~ 13.Pearling agent dispersion liquid uses and the material of embodiment 1 same composition, adds each component and makes ethylene glycol content be 1.25 quality % in shampoo Compositions.
For embodiment 30 shampoo Compositions obtained, evaluate " pearly luster sense ", " storage stability (Margarita outward appearance) ", " storage stability (fluid separation applications) ", " hair smoothness during flushing " and " moulding easiness " in the same manner as embodiment 1 ~ 29 and comparative example 1 ~ 13.Result is as follows.
(composition and content)
The pearling agent dispersion liquid (A) of embodiment 1: 9.6 quality %
The content of each component in pearling agent dispersion liquid
(A1) glycol distearate (fusing point 63 DEG C): 1.25 quality %
(A2) polyoxyethylene (2) lauric monoethanolamide: 1.25 quality %
(A3) propylene glycol (IOB value: 3.3): 0.05 quality %
POE (2) sodium laureth sulfate (B): 11.0 quality %
Lauric amide CAB: 1.0 quality %
Lauryl dimethyl amine oxide: 0.2 quality %
JR-125 A:0.3 quality %
Poise C-80M A:0.1 quality %
Dimethyl polysiloxane C:2.0 quality %
POE (20) castor oil hydrogenated: 1.0 quality %
Sodium benzoate: 0.3 quality %
Hydroxyethane diphosphonic acid: 0.2 quality %
Spice: 0.5 quality %
Citric acid: appropriate to make pH for 5.8
Purified water: surplus (adds up to: 100 quality %)
Mass ratio A1/A2:1
Mass ratio (A1+A2)/A3:50
[evaluation result]
Pearly luster sense: ◎
Storage stability (Margarita outward appearance): ◎
Storage stability (fluid separation applications): ◎
Smoothness during flushing: ◎
Moulding easiness: ◎
(embodiment 31)
< hair care and hair cleaning agent >
Except changing following composition and content, all manufacture shampoo Compositions by the method same with embodiment 1 ~ 29 and comparative example 1 ~ 13.Pearling agent dispersion liquid uses and the material of embodiment 14 same composition, adds each component and makes ethylene glycol content be 2.0 quality % in shampoo Compositions.
For embodiment 31 shampoo Compositions obtained, in the same manner as embodiment 1 ~ 29 and comparative example 1 ~ 13, evaluate " pearly luster sense ", " storage stability (Margarita outward appearance) ", " storage stability (fluid separation applications) ", " hair smoothness during flushing " and " moulding easiness ".Result is as follows.
(composition and content)
The pearling agent dispersion liquid (A) of embodiment 14: 15.38 quality %
The content of each component in pearling agent dispersion liquid
(A1) glycol distearate (fusing point 63 DEG C): 2.00 quality %
(A2) polyoxyethylene (2) coconut oil fatty acid monoethanolamide: 2.00 quality %
(A3) propylene glycol (IOB value: 3.3): 0.08 quality %
POE (3) Zetesol AP (B): 9.0 quality %
Ammonium lauryl sulfate (B): 6.0 quality %
Acyl glutamic acid triethanolamine: 1.5 quality %
Lauryl dimethyl amine oxide: 0.3 quality %
Lauric amide hydroxysultaine: 0.5 quality %
JR-125 B:0.2 quality %
Poise C-80M A:0.05 quality %
Dimethyl polysiloxane A:2.0 quality %
Amino modified silicone B:0.3 quality %
Pantothenylol: 0.12 quality %
Ethyl panthenol: 0.1 quality %
Glycine: 0.05 quality %
Sodium benzoate: 0.9 quality %
Arginine: 0.1 quality %
White birch extract: 0.1 quality %
Yellow No. 203: 0.001 Quality measures %
Sunset Yellow FCF: 0.002 Quality measures %
Spice: 0.5 Quality measures %
Citric acid: appropriate to make pH for 5.8
Purified water: surplus (adds up to: 100 quality %)
Mass ratio A1/A2:1
Mass ratio (A1+A2)/A3:50
[evaluation result]
Pearly luster sense: ◎
Storage stability (outward appearance): ◎
Storage stability (fluid separation applications): ◎
Hair smoothness during flushing: ◎
Moulding easiness: ◎
(embodiment 32)
< anti-dandruff shampoo >
Except changing following composition and content, all manufacture shampoo Compositions by the method same with embodiment 1 ~ 29 and comparative example 1 ~ 13.Pearling agent dispersion liquid uses and the material of embodiment 11 same composition, adds each component and makes ethylene glycol content be 1.5 quality % in shampoo Compositions.
For the shampoo Compositions of the embodiment 32 obtained, in the same manner as embodiment 1 ~ 29 and comparative example 1 ~ 13, evaluate " pearly luster sense ", " storage stability (Margarita outward appearance) ", " storage stability (fluid separation applications) ", " hair smoothness during flushing " and " moulding easiness ".Result is as follows.
(composition and content)
The pearling agent dispersion liquid (A) of embodiment 11: 11.53 quality %
The content of each component in pearling agent dispersion liquid
(A1) glycol distearate (fusing point 63 DEG C): 1.50 quality %
(A2) polyoxyethylene (2) lauric monoethanolamide: 1.50 quality %
(A3) propylene glycol (IOB value: 3.3): 0.096 quality %
POE (2) sodium laureth sulfate (B): 11.0 quality %
Sodium lauryl sulfate (B): 3.0 quality %
Lauric amide CAB: 0.4 quality %
JR-125 A:0.3 quality %
Poise C-80M B:0.1 quality %
Dimethyl polysiloxane A:1.0 quality %
Dimethyl polysiloxane B:1.0 quality %
Piroctone olamine salt: 0.5 Quality measures %
Zinc Pyrithione: 0.5 quality %
Glycyrrhizic acid dipotassium: 0.1 quality %
Acrylate/stereth-20 methacrylate copolymer: 0.3 quality %
Sodium benzoate: 0.5 quality %
Trimethyl glycine: 0.1 quality %
Dibenzylatiooluene: 0.01 quality %
Oxybenzone: 0.1 quality %
Spice: 0.5 Quality measures %
Citric acid: appropriate to make pH for 5.8
Purified water: surplus (adds up to: 100 quality %)
Mass ratio A1/A2:1
Mass ratio (A1+A2)/A3:31
[evaluation result]
Pearly luster sense: ◎
Storage stability (outward appearance): ◎
Storage stability (fluid separation applications): ◎
The smoothness of hair: ◎ during flushing
Moulding easiness after hair washing: ◎
(embodiment 33)
< scalp care shampoo >
Except changing following composition and content, all manufacture shampoo Compositions by the method same with embodiment 1 ~ 29 and comparative example 1 ~ 13.Pearling agent dispersion liquid uses and the material of embodiment 18 same composition, adds each component and makes ethylene glycol content be 0.75 quality % in shampoo Compositions.
For the shampoo Compositions of the embodiment 33 obtained, in the same manner as embodiment 1 ~ 29 and comparative example 1 ~ 13, evaluate " pearly luster sense ", " storage stability (Margarita outward appearance) ", " storage stability (fluid separation applications) ", " hair smoothness during flushing " and " moulding easiness ".Result is as follows.
(composition and content)
The pearling agent dispersion liquid (A) of embodiment 18: 5.77 quality %
The content of each component in pearling agent dispersion liquid
(A1) glycol distearate (fusing point 61.4 DEG C): 0.75 quality %
(A2) polyoxyethylene (2) lauric monoethanolamide: 0.75 quality %
(A3) propylene glycol (IOB value: 3.3): 0.03 quality %
POE (2) Zetesol AP (B): 13.0 quality %
Lauric amide CAB: 1.0 quality %
Lauryl dimethyl amine oxide: 0.3 quality %
Poise C-80M A:0.3 quality %
Dimethyl polysiloxane A:2.0 quality %
Mountain Yu base trimethyl ammonium chloride: 0.1 quality %
Disodium edetate: 0.1 quality %
Sodium benzoate: 0.3 quality %
Radix sophorae (Network ラ ラ root) extract: 0.1 quality %
Glycyrrhizic acid dipotassium: 0.1 quality %
Methoxyl group cinnamic acid 2-Octyl Nitrite: 0.3 quality %
Dibenzylatiooluene: 0.01 quality %
Two alkyd: 0.1 quality %
Spice: 0.5 Quality measures %
Citric acid: appropriate to make pH for 5.8
Purified water: surplus (adds up to: 100 quality %)
Mass ratio A1/A2:1
Mass ratio (A1+A2)/A3:50
[evaluation result]
Pearly luster sense: ◎
Storage stability (outward appearance): ◎
Storage stability (fluid separation applications): ◎
Hair smoothness during flushing: ◎
Moulding easiness after hair washing: ◎
Then, the details of each component used in embodiment 30 ~ 33 is as shown in following expression 11.
[table 11]
* 1: the dimethyl polysiloxane B (emulsion) in table 11 is prepare by following method.
ReofuroDMS-60 (レ オ フ ロ ー DMS-60) (Ipposha Oil Ind Co., Ltd.'s system) (kinematic viscosity 10,000,000mm
2the high polymeric MAO polysiloxanes of/s: kinematic viscosity 4,000,000mm
2the high polymeric MAO polysiloxanes of/s: kinematic viscosity 1,000mm
2methyl polysiloxane=the 15:15:70 (mass ratio) of/s) middle POE (15) cetyl ether (trade name: NPO-97 of adding as emulsifying agent, lion chemicals Co., Ltd. system (ラ イ オ Application ケ ミ カ Le Co., Ltd.)), emulsion dispersion in water.
As mode of the present invention, can be listed below.
< 1 > pearling agent compositions, it is characterized in that, containing (A) pearling agent dispersion liquid, described pearling agent dispersion liquid is by (A1) fatty acid diol ester, (A2) the average addition molal quantity of oxirane is the polyoxyethylene fatty acid monoalkylol amide of 1 ~ 5, (A3) polyhydric alcohol, (A4) polyoxyethylene alkyl ether sulfate salt, and (A5) water is formed, the mass ratio A1/A2 of aforementioned (A1) component and aforementioned (A2) component is 0.5 ~ 4, mass ratio (the A1+A2)/A3 of aforementioned (A1) component and aforementioned (A2) component and aforementioned (A3) component is 20 ~ 100, with
(B) the sulfate type anionic surfactant with sulphuric acid residue of aforementioned (A4) component is comprised.
< 2 > is as the shampoo Compositions recorded in < 1 >, and the fusing point of (A1) component fatty acids diol ester is 61 DEG C ~ 63 DEG C.
The shampoo Compositions that < 3 > records any one of aforementioned < 1 > ~ < 2 >, the IOB value of the polyhydric alcohol of (A2) component is 1.8 ~ 3.3
The shampoo Compositions that < 4 > records any one of < 1 > ~ < 3 >, wherein, (A1) content of component is 0.75 quality % ~ 3 quality %, (A2) content of component is 0.75 quality % ~ 3 quality %, and the content of (A3) component is 0.03 quality % ~ 0.2 quality %.
Utilizability in industry
Shampoo Compositions of the present invention be suitable for the Clean-shampoo of such as scalp, damage nursing shampoo, hair care and hair cleaning agent, containing hair conditioner shampoo, gentle shampoo, scalp care shampoo, anti-dandruff shampoo etc.
Claims (4)
1. a shampoo Compositions, it is characterized in that, comprise (A) pearling agent dispersion liquid, described pearling agent dispersion liquid is by (A1) fatty acid diol ester, (A2) the average addition molal quantity of oxirane is the polyoxyethylene fatty acid monoalkylol amide of 1 ~ 5, (A3) polyhydric alcohol, (A4) polyoxyethylene alkyl ether sulfate salt and (A5) water are formed, the mass ratio A1/A2 of described (A1) component and described (A2) component is 0.5 ~ 4, mass ratio (the A1+A2)/A3 of described (A1) component and described (A2) component and described (A3) component is 20 ~ 100, with
(B) the sulfate type anionic surfactant with sulphuric acid residue of described (A4) component is comprised.
2., as the shampoo Compositions that claim 1 is recorded, the fusing point of (A1) component fatty acids diol ester is 61 DEG C ~ 63 DEG C.
3. the shampoo Compositions recorded any one of claim 1 ~ 2, wherein, the IOB value of the polyhydric alcohol of (A2) component is 1.8 ~ 3.3.
4. the shampoo Compositions recorded any one of claims 1 to 3, wherein,
(A1) content of component is 0.75 quality % ~ 3 quality %,
(A2) content of component is 0.75 quality % ~ 3 quality %,
(A3) content of component is 0.03 quality % ~ 0.2 quality %.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013-134883 | 2013-06-27 | ||
| JP2013134883 | 2013-06-27 | ||
| PCT/JP2014/058938 WO2014208162A1 (en) | 2013-06-27 | 2014-03-27 | Shampoo composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105307630A true CN105307630A (en) | 2016-02-03 |
| CN105307630B CN105307630B (en) | 2018-01-05 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201480034963.1A Expired - Fee Related CN105307630B (en) | 2013-06-27 | 2014-03-27 | Shampoo compositions |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP6154012B2 (en) |
| KR (1) | KR102159536B1 (en) |
| CN (1) | CN105307630B (en) |
| MY (1) | MY173814A (en) |
| PH (1) | PH12015502759A1 (en) |
| WO (1) | WO2014208162A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109952088A (en) * | 2017-05-12 | 2019-06-28 | 宝洁公司 | Comprising having the composition for the scalp health agent for increasing deposition |
| CN110960433A (en) * | 2019-11-12 | 2020-04-07 | 澳宝化妆品（惠州）有限公司 | Composition containing strip crystals and application thereof |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107004898B (en) | 2015-02-10 | 2020-03-06 | 株式会社钟化 | Electricity storage device |
| EP3793510A1 (en) | 2018-05-15 | 2021-03-24 | The Procter & Gamble Company | Synergistic antioxidant compositions |
| CN113194909A (en) | 2018-12-20 | 2021-07-30 | 宝洁公司 | Scalp care compositions with improved stability |
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| JP2006316035A (en) * | 2005-05-16 | 2006-11-24 | Lion Corp | Shampoo composition and production method for the same |
| KR100854787B1 (en) * | 2001-09-10 | 2008-08-27 | 라이온 가부시키가이샤 | Pearl gloss agent dispersions and method for producing the same |
| CN101631531A (en) * | 2007-03-12 | 2010-01-20 | 花王株式会社 | Pearlescent composition |
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| DE4103551A1 (en) * | 1991-02-06 | 1992-08-13 | Henkel Kgaa | FLOWABLE PEARL CONCENTRATE |
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| JPH11228383A (en) | 1998-02-05 | 1999-08-24 | Pola Chem Ind Inc | Cosmetic for cleansing |
| JP2002121131A (en) | 2000-10-16 | 2002-04-23 | Pola Chem Ind Inc | Detergent having stable pearly feeling |
| JP3625458B2 (en) | 2002-08-09 | 2005-03-02 | 花王株式会社 | Washing soap |
| JP3766651B2 (en) | 2002-08-27 | 2006-04-12 | 花王株式会社 | Cleaning composition |
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| JP2007084482A (en) * | 2005-09-22 | 2007-04-05 | Lion Corp | Hair detergent composition |
| JP5294754B2 (en) | 2008-08-26 | 2013-09-18 | 花王株式会社 | Cleaning composition |
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- 2014-03-27 KR KR1020157024541A patent/KR102159536B1/en active IP Right Grant
- 2014-03-27 MY MYPI2015704527A patent/MY173814A/en unknown
- 2014-03-27 CN CN201480034963.1A patent/CN105307630B/en not_active Expired - Fee Related
- 2014-03-27 WO PCT/JP2014/058938 patent/WO2014208162A1/en active Application Filing
- 2014-03-27 JP JP2015523895A patent/JP6154012B2/en active Active
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2015
- 2015-12-10 PH PH12015502759A patent/PH12015502759A1/en unknown
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100854787B1 (en) * | 2001-09-10 | 2008-08-27 | 라이온 가부시키가이샤 | Pearl gloss agent dispersions and method for producing the same |
| JP2006316035A (en) * | 2005-05-16 | 2006-11-24 | Lion Corp | Shampoo composition and production method for the same |
| CN101631531A (en) * | 2007-03-12 | 2010-01-20 | 花王株式会社 | Pearlescent composition |
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| CN109952088A (en) * | 2017-05-12 | 2019-06-28 | 宝洁公司 | Comprising having the composition for the scalp health agent for increasing deposition |
| CN109952088B (en) * | 2017-05-12 | 2022-05-13 | 宝洁公司 | Compositions comprising scalp health agents with increased deposition |
| CN114632026A (en) * | 2017-05-12 | 2022-06-17 | 宝洁公司 | Compositions comprising scalp health agents with increased deposition |
| CN110960433A (en) * | 2019-11-12 | 2020-04-07 | 澳宝化妆品（惠州）有限公司 | Composition containing strip crystals and application thereof |
| CN110960433B (en) * | 2019-11-12 | 2023-03-03 | 澳宝化妆品（惠州）有限公司 | Composition containing strip crystals and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| PH12015502759A1 (en) | 2016-03-21 |
| MY173814A (en) | 2020-02-24 |
| KR20160023635A (en) | 2016-03-03 |
| CN105307630B (en) | 2018-01-05 |
| WO2014208162A1 (en) | 2014-12-31 |
| JPWO2014208162A1 (en) | 2017-02-23 |
| KR102159536B1 (en) | 2020-09-24 |
| JP6154012B2 (en) | 2017-06-28 |
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