CN105050578A - Shampoo composition - Google Patents

Shampoo composition Download PDF

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Publication number
CN105050578A
CN105050578A CN201480017249.1A CN201480017249A CN105050578A CN 105050578 A CN105050578 A CN 105050578A CN 201480017249 A CN201480017249 A CN 201480017249A CN 105050578 A CN105050578 A CN 105050578A
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composition
quality
hair
people
flatness
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CN105050578B (en
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谷口香织
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Lion Corp
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Lion Corp
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/602—Glycosides, e.g. rutin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Cosmetics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Detergent Compositions (AREA)

Abstract

A shampoo composition containing: (A) an anionic surfactant having a sulfuric acid residue; (B) a gallic acid glycoside; (C) a gloss imparting agent; (D) a cationic polymer; and (E) a specific amount of a silicone compound; the mass ratio (B + C)/(A + D) between components (B) and (C) and components (A) and (D) being 0.05 to 0.6, component (D) comprising cationized guar gum (D1) and cationized cellulose (D2), component (D1) and component (D2) being present at a specific mass ratio, component (E) comprising dimethyl polysiloxane (E1) and amino-modified silicone (E2), and component (E1) and component (E2) being present at a specific mass ratio.

Description

Shampoo Compositions
Technical field
The present invention relates to shampoo Compositions.
Background technology
In recent years, in the Southeast Asia being feature with the high-temperature high-humidity weather of average temperature of the whole year more than 25 DEG C, average relative humidity about 70%, the customs such as using air-condition are defined.Therefore, be strongly required to provide a kind of shampoo Compositions with following character: under the temperature of indoor and outdoor and the widely different environment of humidity, no matter in which environment, can prevent the dry sensation of hair and have flatness and flexibility concurrently, light ease sense is good simultaneously.
In the past, complete sense in order to improve after hair washing, after use shampoo, usually also use hair conditioner and nursing agent.
In addition, propose the technology much relating to the shampoo Compositions with following effect, namely only improved the effect of the sensation of dried hair with shampoo, and it can be used as hair care and hair cleaning agent list marketing.Such as, the scheme (for example, referring to patent documentation 1-4) mixed in shampoo Compositions as the cationization polymer of sense of touch imparting agent, various silicone, oil component, cationic surface active agent etc. is proposed.
In addition, in order to improve the friction of damage hair and hair, the scheme (for example, referring to patent documentation 5 and 6) mixing gallic acid glycosides in shampoo Compositions is proposed.
But these technology proposed, under the condition of high-temperature high-humidity, use hair care and hair cleaning agent, hair can be made to have between viscosity, hair be close to, be difficult to carry out moulding, the light ease of damage hair and smoothness and flexibility.
Therefore, desirable to provide a kind of following shampoo Compositions with following character: even if the fierce region of the environmental change under the low humidity obtained with operation of air conditioner under high-temperature high-humidity, hair is not fluffy, be easy to moulding, be not close between hair, hold concurrently with sense, flatness and the flexibility of gently escaping, and usability is excellent.
Prior art document
Patent documentation
Patent documentation 1: Japan Patent spy table 2010-512406 publication
Patent documentation 2: Japanese Patent Laid-Open 2007-45726 publication
Patent documentation 3: Japanese Patent Laid-Open 2006-219449 publication
Patent documentation 4: Japan Patent spy table 2005-506989 publication
Patent documentation 5: Japanese Patent Laid-Open 2000-319116 publication
Patent documentation 6: Japanese Patent Laid-Open 2004-059560 publication
Summary of the invention
The problem that invention will solve
In order to solve existing above-mentioned each problem, problem of the present invention is to reach following object.That is, the object of the present invention is to provide a kind of shampoo Compositions with following character: even if the fierce region of the environmental change under the low humidity obtained at high-temperature high-humidity and operation of air conditioner, hair is not fluffy, be easy to moulding, be not close between hair, hold concurrently with sense, flatness and the flexibility of gently escaping, and usability is excellent.
The means of dealing with problems
As the shampoo Compositions of the present invention for solving the problem, it contains:
(A) there is the anionic surfactant of sulphuric acid residue;
(B) gallic acid glycosides;
(C) gloss imparting agent;
(D) cation property copolymer; And
(E) silicone compounds 0.15 quality % ~ 5.0 quality %;
Wherein, mass ratio (B+C)/(A+D) of described (B) composition and described (C) composition and described (A) and described (D) composition is 0.05 ~ 0.6;
Described (A) composition contains polyoxyethylene alkyl ether sulfate salt (A1) and alkyl sulfate (A2);
Described (D) composition contains JR-125 (D1) and Poise C-80M (D2), and the mass ratio D1/D2 of described (D1) composition and described (D2) composition is 2 ~ 20;
Described (E) composition contains dimethyl polysiloxane (E1) and amino modified silicone (E2), and the mass ratio E1/E2 of described (E1) composition and described (E2) composition is 2 ~ 30.
Invention effect
According to the present invention, can above-mentioned each problem in the past be solved and can achieve the above object, simultaneously, a kind of shampoo Compositions with following character can be provided: even if the fierce region of the environmental change under the low humidity obtained at high-temperature high-humidity and operation of air conditioner, hair is not fluffy yet, is easy to moulding, is not close between hair, hold concurrently with sense, flatness and the flexibility of gently escaping, and usability is excellent.
Detailed description of the invention
(shampoo Compositions)
Shampoo Compositions of the present invention contains: the anionic surfactant with sulphuric acid residue is (following, there is the situation being called " (A) composition "), gallic acid glycosides is (following, there is the situation being called " (B) composition "), gloss imparting agent is (following, there is the situation being called " (C) composition "), cation property copolymer is (following, there is the situation being called " (D) composition ") and silicone compounds is (below, there is the situation being called " (E) composition "), and as required, also other composition can be contained.
< (A) composition: the anionic surfactant > with sulphuric acid residue
As the anionic surfactant of described (A) composition, be form form appropriate foam and remove the composition being attached to the detergent base of the dirt of hair.
As described (A) composition, as long as it has sulphuric acid residue, just be not particularly limited, suitably can select according to object, such as, alkyl sulfate, alkenyl sulfate, polyoxyalkylene alkyl ether sulfate, polyoxy alkylidene alkenyl ether sulfates, polyoxyalkylene alkyl phenylate sulfate and amide ether sulfate etc. can be enumerated.
As above-mentioned salt, be not particularly limited, suitably can select according to object, such as, the alkali metal such as sodium and potassium can be enumerated; Ammonium; Alkanolamine etc.
In these, as composition (A), preferred polyoxyalkylene alkyl ether sulfate, polyoxy alkylidene alkenyl ether sulfates and alkyl sulfate, more preferably the anionic surfactant shown in following general formula (A1) is (following, there is the situation being called " (A1) composition ") and the anionic surfactant (following, to there is the situation being called " (A2) composition ") shown in following general formula (A2).
R 1o (CH 2cH 2o) msO 3m 1general formula (A1)
[but in described general formula (A1), R 1represent the alkyl or alkenyl of carbon number 10 ~ 18, M 1represent any one in alkali metal, ammonium and alkanolamine, m represents that average addition molal quantity is the numerical value of 1 ~ 5.]
R 2oSO 3m 2general formula (A2)
[but in described general formula (A2), R 2represent the alkyl of carbon number 10 ~ 18, M 2represent any one in alkali metal, ammonium and alkanolamine.]
From the viewpoint of the finger smoothness of hair when the steady dissolution taken into account described shampoo Compositions and hair washing, the R in described general formula (A1) 1and/or the R in described general formula (A2) 2the alkyl of preferred carbon number 12 ~ 16.In addition, in the hair flatness when giving washing, the m in described general formula (A1) is preferably 2 ~ 3.Further, when washing, the flatness of hair, the rapid draing of the rear hair of washing and hair are easy in moulding, the M in described general formula (A1) 1or the M in described general formula (A2) 2be particularly preferably ammonium.
As (A) composition, the product of commercially available prod or suitably synthesis can be used.As the object lesson of described commercially available prod, commodity can be enumerated and be called TexaponALES70 (POE (3) Zetesol AP, BASF AG manufactures) and (A1) composition such as CHINOLINESPE-1250 (シ ノ リ Application SPE-1250) (POE (2) sodium laureth sulfate, New Japan Chem Co., Ltd manufacture); (A2) compositions etc. such as TexaponALS70 (ammonium lauryl sulfate, BASF AG manufactures) and TexaponK12 (sodium lauryl sulfate, BASF AG manufactures).
In these, from the viewpoint of the flatness of hair during washing, as described (A1) composition, preferred TexaponALES70 (POE (3) Zetesol AP); As described (A2) composition, preferred TexaponALS70 (ammonium lauryl sulfate, BASF AG manufactures).
As described (A) composition, particularly preferably described (A1) composition and described (A2) composition are used.When described (A) composition is only described (A1) composition, there is following situation: under high humility, the formative nature that is easy to of hair declines with the flatness of hair during washing, and can not obtain sufficient foaming characteristic.In addition, when described (A) composition is only described (A2) composition, there is following situation: under high humility, the formative nature that is easy to of hair declines with the flatness of hair during washing, and during washing, the flatness of hair becomes insufficient.
The content of described (A1) composition is not particularly limited, suitably can select according to object, but relative to the total amount of described shampoo Compositions, the content of described (A1) composition is preferably 3 quality % ~ 24 quality %, more preferably 5 quality % ~ 22 quality %, particularly preferably 7 quality % ~ 15 quality %.When the content of described (A1) composition is less than 3 quality %, the situation that the flatness that there is hair during washing declines, when more than 24 quality %, there is following situation: during washing, defoaming is deteriorated, and viscosity uprises, usability is deteriorated.
The content of described (A2) composition is not particularly limited, suitably can select according to object, but relative to the total amount of described shampoo Compositions, the content of described (A2) composition is preferably 1 quality % ~ 15 quality %, more preferably 2 quality % ~ 12 quality %, particularly preferably 3 quality % ~ 10 quality %.When the content of described (A2) composition is less than 1 quality %, there is the situation that when washing, defoaming is deteriorated, when more than 15 quality %, there is the flatness decline situation of hair during washing.
The content (the total content of described (A1) composition and described (A2) composition) of described (A) composition is not particularly limited, suitably can select according to object, but the flatness of hair during defoaming good and washing during, washing good from the viewpoint of foaming characteristic, relative to the total amount of described shampoo Compositions, the content of described (A) composition is preferably 5 quality % ~ 30 quality %, more preferably 10 quality % ~ 25 quality %, particularly preferably 12 quality % ~ 20 quality %.When the content of described (A) composition is less than 5 quality %, there is following situation: foaming characteristic is deteriorated, and when washing, the flatness of hair declines; When more than 30 quality %, there is following situation: viscosity is high and usability is poor, during washing, defoaming is deteriorated, and hair flatness when washing declines.
The mass ratio A1/A2 of described (A1) composition and described (A2) composition is not particularly limited, suitably can select according to object, but from the flatness of hair when bubble performance and washing and preventing high-temperature high-humidity (temperature 27 DEG C, humidity 70%RH) dry after the viscosity aspect of hair, mass ratio A1/A2 is preferably 1 ~ 7, and more preferably 1.3 ~ 4.When described mass ratio A1/A2 is less than 1, there is the flatness decline situation of hair during washing; When more than 7, there is following situation: under generation high-temperature high-humidity, the dry back of (temperature 27 DEG C, humidity 70%RH) is tackiness, is difficult to moulding, and hair gently escapes, after sense and drying, the flatness of hair declines.
< (B) composition: gallic acid glycosides >
As the gallic acid glycosides of described (B) composition, it is the composition giving following functions: the flexibility that can obtain dried hair, even and if under the low humidity (temperature 25 DEG C, humidity 40%RH), hair also can not be fluffy, be easy to moulding, and be difficult between hair be close to, hair becomes does not have viscosity, hair gently escapes sense.
Be not particularly limited as described gallic acid glycosides, suitably can select according to object, such as, gallicin-3-glucoside can be enumerated, gallicin ester-4-glucoside, propyl gallate-3-glucoside, gallicin-3-maltoside, gallic acid-3-glucoside, gallic acid-3-maltoside, gallic acid octyl group-3-maltoside, gallic acid-3-glucuronide, gallic acid galacturonic acid glycosides, gallicin-3, 5-diglucoside, gallic acid-3, 4-diglucoside and gallic acid-3, 5-diglucoside etc.These one or by two or more and use of can be used alone.In these, from the viewpoint of dried hair soft, particularly preferably gallic acid 3,4-diglucoside and gallic acid-3,5-diglucoside.
As the gallic acid glycosides of described (B) composition, the product of commercially available prod or suitably synthesis can be used.As described commercially available prod, such as, gallic acid-3,4-diglucoside (DGA, Mitsui Chemicals, Inc manufactures) and gallic acid-3,5-diglucoside (DGA, Mitsui Chemicals, Inc manufactures) etc. can be enumerated.
The content of described (B) composition gallic acid glycosides is not particularly limited, suitably can select according to object, but relative to the total amount of described shampoo Compositions, the content of gallic acid glycosides is preferably 0.01 quality % ~ 7.5 quality %, more preferably 0.05 quality % ~ 3 quality %, further preferred 0.1 quality % ~ 1 quality %.When described content is less than 0.01 quality %, there is following situation: the flexibility that can not obtain hair, under high-temperature high-humidity, (temperature 27 DEG C, humidity 70%RH) hair is too fluffy, becomes and is difficult to carry out moulding.When described content is more than 7.5 quality %, there is following situation: the adsorbance of hair is become superfluous, and under high-temperature high-humidity under (temperature 27 DEG C, humidity 70%RH) and low temperature and low humidity degree (temperature 25 DEG C, humidity 40%RH), be close between hair, be difficult to carry out forming hair, and make because of viscosity the light ease of hair decline.
< (C) composition: gloss imparting agent >
As the gloss imparting agent (also exist and be called the situation such as " polishing material ", " pearling agent " and " pearly-lustre imparting agent ") of described (C) composition, described shampoo Compositions pearl-like gloss can be given.Therefore, be favourable improving in commodity value.
In addition, described (C) composition can not only give shampoo Compositions pearl-like gloss, and under high-temperature high-humidity (temperature 27 DEG C, humidity 70%RH), make hair not fluffy, be difficult between hair be close to, therefore, be easy to the moulding carrying out hair, and hair do not have viscosity and has sense of gently escaping.
As described (C) composition, be not particularly limited, suitably can select according to object, such as, the stearate of preferred ethylene glycol, diethylene glycol or triethylene glycol, specifically, hydroxy stearic acid ester, polyethylene glycol mono stearate, polyglycol distearate, ethylene glycol monostearate, glycol distearate, stearic acid monoethanolamide and stearic acid monoethanol stearate etc. can be enumerated.These one or by two or more and use of can be used alone.In these, from (temperature 27 DEG C, humidity 70%RH) high-temperature high-humidity, hair is not fluffy, hair is easy to carry out moulding, obtain sense of gently escaping, the stability aspect of dried hair flatness and pearl-like gloss, particularly preferably glycol distearate.
Described (C) composition, is scattered in shampoo Compositions usually used as crystal, therefore, can give shampoo Compositions pearl-like gloss.As the dispersion liquid method of the described crystal of preparation, be not particularly limited, suitably can select according to object, such as, following method etc. can be enumerated: described (C) composition of fusing, and in aqueous surfactant solution more than the fusing point maintaining this (C) composition, dispersion mixing should (C) composition, cooling.
By adding the crystal dispersion liquid of described (C) composition in described shampoo Compositions, making described (C) composition reach predetermined concentration, the pearl-like gloss that described shampoo Compositions is suitable can be given.
As the median particle diameter of the crystal dispersion liquid of described (C) composition, be not particularly limited, suitably can select according to object, preferably 0.5 μm ~ 6 μm, more preferably 1 μm ~ 3 μm.When described median particle diameter is less than 0.5 μm, there is following situation: hair flatness during washing declines, and cannot give pearl-like gloss further and lose feeling of high class.When described median particle diameter is more than 6 μm, there is following situation: the light ease of dried hair and the drying of making a start clearly feel decline, and gratifying washing sense of reality declines.
In addition, the dispersion shape of the crystal of described (C) composition is preferably acicular crystal.By forming acicular crystal, hair flatness during washing can be increased.
Described median particle diameter, is typically expressed as D50, its refer to according to certain particle diameter described dispersion liquid is divided into 2 parts and particle diameter larger side and smaller side are equivalent time particle diameter.Specifically, by using laser diffraction formula sedimentograph (LA-920, Horiba Ltd manufactures), and using the relative index of refraction relative to water as 1.08, be determined in described shampoo Compositions the particle size distribution of the crystal dispersion liquid of described (C) composition adding preparation in advance, thus calculate described median particle diameter.
The content of the gloss imparting agent of described (C) composition is not particularly limited, suitably can select according to object, but from the viewpoint of imparting pearly luster, relative to the total amount of described shampoo Compositions, the content of gloss imparting agent is preferably 1 quality % ~ 5 quality %, more preferably 1.2 quality % ~ 4.5 quality %.When described content is less than 1 quality %, there is following situation: precious light outward appearance dies down, be easy to be close between (temperature 27 DEG C, humidity 70%RH) hair under high-temperature high-humidity, be difficult to the moulding carrying out hair, and the flatness of the light ease sense of hair and hair declines; When content is more than 5 quality %, there is following situation: dried hair flatness declines, and usability (the taking-up easiness from bottle) is poor.
< (D) composition: cation property copolymer >
The cation property copolymer of described (D) composition, (following by JR-125, there is the situation of " (D1) composition " of being called) and Poise C-80M (following, existence is called the situation of " (D2) composition ") formed.
<< (D1) composition: JR-125 >>
As the JR-125 of described (D1) composition, be also referred to as guar hydroxypropyltrimonium ammonium chloride and chlorination O-[2-hydroxyl-3-(trimethyl ammonium) propyl group] guar gum etc.
Nitrogen content in described (D1) composition is not particularly limited, suitably can select according to object, but from the viewpoint of the flatness of the hair can given when washing, this nitrogen content is preferably 1 quality % ~ 1.8 quality %, more preferably 1.1 quality % ~ 1.45 quality %.
Described nitrogen content according to Kjeldahl's method, can obtain ammonium sulfate with (D1) composition described in sulfuric acid decomposition, and by quantitatively measuring its ammonia.Specifically, by measuring with reference to the method described in " medicine part outer article raw material specification 2006 (society of medicine thing Japan) " ordinary test method 44. azotometry.
As described (D1) composition, the product of commercially available prod or suitably synthesis can be used.As the preferred object lesson of described commercially available prod, commodity can be enumerated and be called the JAGUAR series (manufacture of Rhodia company) such as JAGUARC14S (nitrogen content: 1.3 quality % ~ 1.7 quality %), JAGUARExcel (nitrogen content: 1.0 quality % ~ 3.0 quality %) and JAGUARC-500 (nitrogen content: 1.15 quality % ~ 1.45 quality %); The N-Hance series such as N-HanceCG14 (nitrogen content: 1.25 quality % ~ 1.55 quality %), N-Hance3299 (nitrogen content: 1.15 quality % ~ 1.45 quality %) and N-HanceCCG45 (nitrogen content: 1.15 quality % ~ 1.45 quality %) (Ashland company manufactures, Aqualon department); CatinalCG-100S (カ チ ナ ー Le CG-100S) (nitrogen content: 1.0 quality % ~ 1.7 quality %) (Toho Chemical Industry Co., Ltd. (JP) Tokyo-To, Japan); And GuarsafeJK140 (nitrogen content: 1.3 quality % ~ 1.7 quality %) (JINGKINCHEMISTRYCOMPANY manufacture) etc.In these, when washing after the flatness of hair and drying hair flatness in, particularly preferably N-Hance3299, N-HanceCCG45 and JAGUARC-500.
The content of described (D1) composition is not particularly limited, suitably can select according to object, but from the viewpoint of the flatness of hair when froth breaking formedness during washing, washing and the flatness of dry rear hair, the total amount of relatively described shampoo Compositions, (D1) content of composition is preferably 0.075 quality % ~ 4.5 quality %, more preferably 0.1 quality % ~ 1.1 quality %, further preferred 0.2 quality % ~ 0.6 quality %.When the content of described (D1) composition is less than 0.075 quality %, there is the flatness decline situation of hair during washing; When more than 4.5 quality %, there is following situation: after dry hair flexibility, washing time defoaming and usability be deteriorated.
<< (D2) composition: Poise C-80M >>
The described Poise C-80M as (D2) composition, it is the epoxide reaction replaced with the trimethyl ammonium that also can be called as Polyquaternium-10 and chlorination O-[2-hydroxyl-3-(trimethyl ammonium) propyl group] hydroxyethyl-cellulose etc. and the hydroxyethyl-cellulose salt obtained.
Nitrogen content as described (D2) composition is not particularly limited, suitably can select according to object, but good from the viewpoint of defoaming during washing and when can give washing hair flatness, this nitrogen content is preferably 1.5 quality % ~ 2.2 quality %, more preferably 1.6 quality % ~ 2.0 quality %.
Described nitrogen content according to Kjeldahl's method, can obtain ammonium sulfate with (D2) composition described in sulfuric acid decomposition, and measures by carrying out its ammonia quantitatively.Specifically, by measuring with reference to the method described in " medicine part outer article raw material specification 2006 (society of medicine thing Japan) " ordinary test method 44. azotometry.
As described (D2) composition, the product of commercially available prod or suitably synthesis can be used.As the preferred object lesson of described commercially available prod, commodity can be enumerated and be called the UCAREPolymerJR series (Dow Chemical (ダ ウ ケ ミ カ Le society) manufacture) such as UCAREPolymerJR400 (nitrogen content: 1.5 quality % ~ 2.2 quality %) and UCAREPolymerJR-30M (nitrogen content: 1.5 quality % ~ 2.2 quality %); The CatinalHC series such as CatinalHC100 and CatinalHC200 (Toho Chemical Industry Co., Ltd.'s manufacture); The Reogado series (Lion Corporation's manufacture) of Reogado (レ オ ガ ー De) GP, ReogadoKGP and ReogadoMGP etc. (nitrogen content: 1.6 quality % ~ 2.0 quality %); And MICONIUM (registered trade mark) PQ10-J-400 (nitrogen content: 1.5 quality % ~ 2.2 quality %) (manufacture of MIWON company) etc.In these, hair flatness when also can give washing from the viewpoint of froth breaking formedness during washing, particularly preferably MICONIUM (registered trade mark) PQ10-J-400, ReogadoGP and ReogadoKGP.
The content of described (D2) composition is not particularly limited, suitably can select according to object, but from the viewpoint of hair flatness when froth breaking formedness during washing, washing, relative to the total amount of described shampoo Compositions, the content being somebody's turn to do (D2) composition is preferably 0.01 quality % ~ 1 quality %, more preferably 0.03 quality % ~ 0.7 quality %, further preferred 0.09 quality % ~ 0.5 quality %.When the content of described (D2) composition is less than 0.01 quality %, there is hair flatness decline situation during washing; When more than 1 quality %, there is following situation: defoaming when dried hair soft and washing is deteriorated.
The total content of described (D1) composition and described (D2) composition is (following, exist and be called " content of (D) composition " situation) be not particularly limited, suitably can select according to object, but relative to the total amount of described shampoo Compositions, this total content is preferably 0.1 quality % ~ 5 quality %, more preferably 0.2 quality % ~ 1.5 quality %, further preferred 0.3 quality % ~ 0.8 quality %.When the content of described (D) composition is less than 0.1 quality %, existence cannot obtain dried hair flatness situation; When more than 5 quality %, there is following situation: dried hair soft declines, described shampoo Compositions gelation and viscosity is uprised, usability is deteriorated.
From the viewpoint of hair flatness during washing and dried hair flatness, the mass ratio D1/D2 of described (D1) composition and described (D2) composition is 2 ~ 20, preferably 3 ~ 15, more preferably 3 ~ 9.When described mass ratio D1/D2 is less than 2, there is hair flatness decline situation during washing; When mass ratio D1/D2 is more than 20, there is dried hair flatness decline situation.
< (E) composition: silicone compounds >
As the silicone compounds of described (E) composition, it is (following by dimethyl polysiloxane, there is the situation of " (E1) composition " of being called) and amino modified silicone (following, existence is called the situation of " (E2) composition ") formed.
< (E1) composition: dimethyl polysiloxane >
Described (E1) composition, as long as its dimethyl polysiloxane, is just not particularly limited, suitably can select according to object, such as, trimethylsilyl terminal dimethyl polysiloxane and silanol group terminal dimethyl group polysiloxanes etc. can be enumerated.In these, hair after the drying gently escapes, dried hair flatness and giving is made a start dry salubrious sense aspect, preferred trimethylsilyl terminal dimethyl polysiloxane.
As the kinematic viscosity at 25 DEG C of dimethyl polysiloxane, to make a start dry salubrious sense from the viewpoint of the light fugacity of dried hair, dried hair flatness and giving, preferably 10,000mm 2/ s ~ 30,000,000mm 2/ s, more preferably 100,000mm 2/ s ~ 10,000,000mm 2/ s, particularly preferably 100,000mm 2/ s ~ 1,000,000mm 2/ s.
Kinematic viscosity at 25 DEG C of described dimethyl polysiloxane, such as, measures by method shown below.
The toluene solution of the dimethyl polysiloxane of preparation 1g/100mL concentration, and according to following formula (1), obtain specific viscosity η sp (25 DEG C).Then, substitute into the relational expression of the Huggins shown in following formula (2), obtain intrinsic viscosity [η].For Huggins constant, adopt field, Zhongmou County, daily use chemicals, 77,588, the value described in 1956.Then, by [η] in the A.Kolorlov formula as shown in following formula (3), molecular weight is obtained.Finally, M is substituted in the A.J.Barry formula shown in following formula (4), obtain the kinematic viscosity η of dimethyl polysiloxane.
η sp=(η/η 0)-1 formula (1)
η sp=[η]+K'[η] 2formula (2)
[η]=0.215 × 10 -4m 0.65formula (3)
Log η=1.00+0.0123M 0.5formula (4)
In described formula (1), " η 0" represent the viscosity of toluene, " η " represents the viscosity of solution.
Described η 0the value measured according to cosmetic material benchmark ordinary test method viscosimetry the 1st method with described η.
From the viewpoint of manufacture efficiency and the dispersion stabilization of shampoo Compositions, described (E1) composition preferably carries out pre-emulsification with emulsifying agent.As the emulsifying agent described in emulsifying during (E1) composition or emulsification method, be not particularly limited, suitably can select according to object.
As the number average bead diameter of (E1) composition described in above-mentioned emulsion, be not particularly limited, suitably can select according to object, but good from the viewpoint of hair finger smoothness during hair washing and after having one's hair wash hair rapid draing, this number average bead diameter is preferably 0.5 μm ~ 60 μm, more preferably 10 μm ~ 50 μm, particularly preferably 15 μm ~ 40 μm.When described number average bead diameter is less than 0.5 μm, there is following situation: be easy to be close between (temperature 27 DEG C, humidity 70%RH) hair under high-temperature high-humidity, be difficult to moulding, and make owing to producing viscosity the light ease sense of hair decline; When number average bead diameter is more than 60 μm, there is hair flatness decline situation during washing.
Described number average bead diameter is the particle image obtained by importing any 100 place's observation by light microscope in computer, carries out image procossing (such as, two dimensional image analysis software WinROOF etc.) obtain with same multiplying power.
As described (E1) composition, the product of commercially available prod or suitably synthesis can be used.As the object lesson of (E1) composition described in sold in the form of an emulsion, commodity can be enumerated and be called BY22-029 [kinematic viscosity: 100,000mm 2/ s, number average bead diameter: 0.5 μm] (Dong Li DOW CORNING Co., Ltd. (East レ ダ ウ コ ー ニ Application グ Co., Ltd.) manufacture) and DC-7137 [kinematic viscosity: 600,000mm 2/ s, number average bead diameter: 35 μm] (Dow Corning Corporation (ダ ウ コ ー ニ Application グ society) manufacture); KM-902 [kinematic viscosity: 500,000mm 2/ s, number average bead diameter: 0.5 μm] (more than, Shin-Etsu Chemial Co., Ltd manufactures); Reofuro (レ オ フ ロ ー) DMS-55 [kinematic viscosity: 100,000mm 2/ s, number average bead diameter: 0.5 μm] and ReofuroDMS-60 [kinematic viscosity: 10,000,000mm 2/ s:4,000,000mm 2/ s:1,000mm 2/ s=15:15:70 (mass ratio), number average bead diameter: 0.9 μm] (more than, Ipposha Oil Ind Co., Ltd. manufactures); And EMU120 [kinematic viscosity: 900,000mm 2/ s, number average bead diameter: 20 μm] (Mai Tu company (モ メ ンティブ society) manufacture) etc.In these, gently escape from the hair of (temperature 27 DEG C, humidity 70%RH) dried hair flatness, high-temperature high-humidity and feel and be easy to moulding aspect, preferred DC-7137 and EMU120.
From the viewpoint of obtaining dried hair flatness, relative to the total amount of described shampoo Compositions, the content of described (E1) composition is preferably 0.1 quality % ~ 4.8 quality %, more preferably 0.5 quality % ~ 3 quality %.When the content of described (E1) composition is less than 0.1 quality %, there is following situation: hair flatness when washing and dried hair flatness cannot be obtained; When the content of described (E1) composition is more than 4.8 quality %, there is following situation: be easy to be close between (temperature 27 DEG C, humidity 70%RH) hair under high-temperature high-humidity, the formative nature that is easy to of hair declines, and hair produces viscosity, and the light ease of hair declines.
< (E2) composition: amino modified silicone >
As the amino modified silicone of described (E2) composition, be not particularly limited, suitably can select according to object, such as, aminoethylaminopropyl siloxane-dimethylsiloxane copolymer can be enumerated (following, there is the situation being called " ammonia end polydimethylsiloxane "), aminoethylaminopropyl methylsiloxane-dimethylsiloxane copolymer is (following, there is the situation being called " aminoethylaminopropyl first polysiloxanes-dimethyl silicone copolymer "), the copolymer with the block chain of amino modified organopolysiloxane chain and polyoxy alkylidene chain is (following, there is the situation being called " the amino-polyether modified silicone of straight chain ") and aminopropyl dimethicone etc.These one or by two or more and use of can be used alone.In these, from the viewpoint of hair flatness, preferred amino dimethicone and the amino-polyether modified silicone of straight chain that can give when washing.
As described (E2) composition, the product of commercially available prod or suitably synthesis can be used.
As the object lesson of the commercially available prod of described (E2) composition, commodity can be enumerated and be called SM8904CE, BY22-079 and FZ-4671 (amino dimethicone emulsion, Dong Li DOW CORNING Co., Ltd. manufactures) and the amino dimethicone such as DC2-8194 (Dow Corning Corporation's manufactures), KF-8004, KF-867S and KF-880 (more than, Shin-Etsu Chemial Co., Ltd manufacture); The aminoethylaminopropyl first polysiloxanes-dimethyl silicone copolymers such as KF-8005 (Shin-Etsu Chemial Co., Ltd's manufacture); The amino-polyether modified silicone of straight chain such as SILSTYLE104 (two isobutyl group PEG-14/ amino dimethicone) copolymer, SILSTYLE201 (two isobutyl group PEG-14/ ammonia end polydimethylsiloxane) copolymer and SILSTYLE401 (two butoxy ammonia end polydimethylsiloxane/PEG-60) copolymer (more than, Dong Li DOW CORNING Co., Ltd. manufactures); And the aminopropyl dimethyl polysiloxane etc. such as KF-8015, KF-865, KF-8017, KF-8018 and KF-8020 (Shin-Etsu Chemial Co., Ltd's manufacture).In these, preferred SILSTYLE401.
The content of described (E2) composition is not particularly limited, suitably can select according to object, but relative to the total amount of shampoo Compositions, the content being somebody's turn to do (E2) composition is preferably 0.01 quality % ~ 1.5 quality %, more preferably 0.1 quality % ~ 1 quality %.When the content of described (E2) composition is less than 0.01 quality %, there is the situation that cannot obtain dry rear hair flatness; (E2) when the content of composition is more than 1.5 quality %, there is following situation: be easy to be close between (temperature 27 DEG C, humidity 70%RH) hair under high-temperature high-humidity, be easy to formative nature and decline, hair produces viscosity, and the light ease of hair declines.
From the expansion aspect being easy to formative nature of (temperature 27 DEG C, humidity 70%RH) hair preventing high-temperature high-humidity, relative to the total amount of described shampoo Compositions, the total content of described (E1) composition and described (E2) composition is (following, there is the situation being called " content of (E) composition ") be 0.15 quality % ~ 5.0 quality %, preferably 0.8 quality % ~ 3.8 quality %.When the content of described (E) composition is less than 0.15 quality %, there is hair flatness when cannot obtain washing and dried hair flatness situation; (E) when the content of composition is more than 5.0 quality %, there is following situation: be easy to be close between (temperature 27 DEG C, humidity 70%RH) hair under high-temperature high-humidity, be easy to formative nature and decline, hair produces viscosity, and the light ease of hair and usability decline; And when described (E) composition is emulsion, have that emulsion particle is coalescent, the situation of bad stability.
The mass ratio E1/E2 of described (E1) composition and described (E2) composition is 2 ~ 30, preferably 5 ~ 27.When described mass ratio E1/E2 is less than 2, there is following situation: under high-temperature high-humidity (temperature 27 DEG C, humidity 70%RH) drying after, become between hair and be easy to be close to, be easy to formative nature decline, hair produces viscosity, the light ease of hair declines, and can become the shampoo Compositions cleaned sense and lack.When described mass ratio E1/E2 is more than 30, there is the situation of dried hair flatness and usability decline.
< mass ratio (B+C)/(A+D) >
Formative nature and hair gently ease aspect is easy to from fluffy, the hair of (temperature 27 DEG C, humidity 70%RH) hair preventing high-temperature high-humidity, mass ratio (B+C)/(A+D) of described (B) composition and described (C) composition and described (A) and described (D) composition is 0.05 ~ 0.6, preferably 0.06 ~ 0.5, more preferably 0.08 ~ 0.4.When described mass ratio (B+C)/(A+D) is less than 0.05, there is following situation: become between (temperature 27 DEG C, humidity 70%RH) hair under high-temperature high-humidity and be easy to be close to, the formative nature that is easy to of hair declines, and hair produces viscosity, and the light ease of hair declines; When mass ratio (B+C)/(A+D) is more than 0.6, there is following situation: become between (temperature 27 DEG C, humidity 70%RH) hair under high-temperature high-humidity and be easy to be close to, the formative nature that is easy to of hair declines, hair produces viscosity, the light ease of hair declines, and dried hair flatness is deteriorated.
When described mass ratio (B+C)/(A+D) is for above-mentioned numerical range, favourable in the following areas: even if in any one situation under the low humidity that (temperature 27 DEG C, humidity 70%RH) and operation of air conditioner obtain under high-temperature high-humidity, hair is not fluffy and make hair be easy to moulding, be difficult between hair be close to, the bad generation viscosity of hair, hair is light.
Other composition of < >
As other composition above-mentioned, only otherwise damage effect of the present invention, just be not particularly limited, suitably can select according to object, such as, following composition can suitably be mixed as required: oil content, alcohols, wetting agent, thickening agent, antiseptic, antioxidant, chelating agen, pH adjusting agent, ultra-violet absorption and scattering diluent, vitamins, amino acids, spice, pigment and water etc.These one or by two or more and use of can be used alone.
As described oil content, such as, Oleum Ricini, olive oil, cupu oil, hydrogenated palm oil, Camellia oil, Oleum Cocois, haze tallow, Jojoba oil, Oleum Vitis viniferae and American Avocado Tree wet goods Vegetable oil lipoprotein class or their ester compounds can be enumerated; Ermine oil and egg yolk wet goods animal oil class; The wax classes such as Cera Flava, spermaceti, lanoline, hydrogenated lanolin, Brazil wax and candelilla wax; The hydro carbons such as liquid paraffin, squalane, microwax, ceresine, paraffin and vaseline; The natural fatty acid with synthesizing such as lauric acid, myristic acid, stearic acid, oleic acid, isostearic acid He behenic acid etc.; Esters and the dimethyl polysiloxanes etc. such as glycerol three-2-ethylhexanoate, stearic acid 2-Octyl Nitrite, butyl stearate, isopropyl myristate, isopropyl palmitate, myristic acid octyldodecyl, octyldodecyl oleate and cholesterol acid ester.
As described alcohols, such as, the natural higher alcohols etc. with synthesizing such as spermol, oleyl alcohol, stearyl alcohol, hexyldecanol, octyldodecanol and lauryl alcohol can be enumerated.
As described wetting agent, such as, can 1 be enumerated, 3-butanediol, isoprene, 1, (mean molecule quantity is 200,300,400,600,1 for 2-pentanediol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, diethylene glycol monoalky lether, Polyethylene Glycol, 000 or 1,500), polypropylene glycol, polyethylene glycol-propylene glycol, castor oil hydrogenated (30E.O.), glycerol, two glycerol, triglycerin, polyglycereol and Sorbitol etc.
As described thickening agent, such as, the natural polymers such as sodium alginate, xanthan gum, aluminium silicate, Fructus cydoniae oblongae seed extract, Tragacanth and starch can be enumerated; The semi-synthetic macromolecules such as methylcellulose, hydroxyethyl-cellulose, hydroxypropyl cellulose, carboxymethyl cellulose and soluble starch; The synthetic macromolecular compounds etc. such as CVP Carbopol ETD2050, polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid, Methacryloyl ethyl betaine-methacrylate copolymer.
As described antiseptic, such as, benzoate, sorbate, dehydroacetate salts, p-Hydroxybenzoate, 2 can be enumerated, 4, the chloro-2'-dihydroxy diphenyl ether of 4'-tri-, 3,4,4'-trichlorocarbanilides (3,4,4 '-ト リ Network ロ ロ カ Le バ ニ リ De), benzalkonium chloride, chamenol, resorcinol, methylchloroisothiazandnone-Methylisothiazolinone liquid (trade name KathonCG (ケ ー ソ Application CG); ROHM AND HAAS Japanese firm (ロ ー system ア Application ド ハ ー ス ジ ャ パ Application society) manufacture), salicylic acid, pentanediol, phenoxyethanol and ethanol etc.
As described antioxidant, such as, dibenzylatiooluene, butylated hydroxyanisole (BHA), ascorbic acid etc. can be enumerated.
As described chelating agen, such as, disodiumedetate, edetate, hexametaphosphate and gluconic acid etc. can be enumerated.
As described pH adjusting agent, such as, sodium hydroxide, potassium hydroxide, citric acid, succinic acid, triethanolamine, ammonia, triisopropanolamine, phosphoric acid, glycolic etc. can be enumerated.
As described ultra-violet absorption, scattering diluent, such as, ESCALOL 567, octyldimethyl p-aminobenzoate, Parsol MCX, titanium dioxide, Kaolin and Talcum etc. can be enumerated.
As described vitamin, such as, vitamin A, vitamin B complex, vitamin C, vitamin D, vitamin E, vitaminF, vitamin K, Citrin, vitamin U, carnitine, ferulic acid, gamma oryzanol, alpha-lipoic acid, orotic acid or derivatives thereof etc. can be enumerated.
As described amino acids, such as, glycine, alanine, valine, leucine, isoleucine, phenylalanine, tryptophan, cystine, cysteine, methionine, proline, hydroxyproline, aspartic acid, glutamic acid, arginine, histidine, lysine or derivatives thereof etc. can be enumerated.
As described spice, the fragrance component described in paragraph [0021] ~ [0035] of Japanese Patent Laid-Open 2003-300811 publication, the spice solvent etc. described in paragraph [0050] can be enumerated.
<pH>
As the pH value of described shampoo Compositions, be not particularly limited, suitably can select according to object, but preferably at 25 DEG C pH value be 5.0 ~ 6.0.
Described pH, such as, by using pH meter (HM-30G, (East Ami デ ィ ー ケ ー ケ ー Co., Ltd. of DKK Toa Corp.) manufacture) at 25 DEG C, measure described shampoo Compositions and obtain.
The pH of described shampoo Compositions, can use desired pH adjusting agent to regulate.As described pH adjusting agent, be not particularly limited, suitably can select according to object, such as, citric acid, succinic acid, sulphuric acid, 2-amino-2-methyl-1-propanol, monoethanolamine or their salt etc. can be enumerated.
< viscosity >
Viscosity as described shampoo Compositions is not particularly limited, and suitably can select according to object, but the viscosity preferably at 25 DEG C is 1Pas ~ 30Pas.
Described viscosity, such as, by using viscometer (BM type viscometer, TOKIMEC company manufacture) at No. 4 rotors, 30rpm, after 20 seconds, recording under the condition of 25 DEG C.
< container >
As the container of described shampoo Compositions, be not particularly limited, suitably can select according to object, such as, the pipe such as aluminium lamination pressure pipe, EVAL pipe, aluminum pipe, glass evaporation plastic tube, in addition also the liquor separator container of with good grounds mechanical differential pressure or squeeze-type container, laminated film container, dropper container, excellent container and bottle container etc. can be filled in.
Described laminated film has the multilamellar of more than 2 layers usually, and its material is made up of the synthetic resin such as polyvinyl resin, polyethylene terephthalate resin, mylar, Biaxially oriented polypropylene resin, un-stretched polypropylene resin, polyacrylonitrile resin, ethylene-vinyl acetate copolymer resin, paper, aluminium-vapour deposition plastics etc.In these, when considering intensity, flexibility and weatherability, the laminated film of general preferred employing 2 layers ~ 5 layers.
As the material of described bottle, be not particularly limited, suitably can select according to object, such as, resin or the glass etc. such as polyvinyl resin, acrylic resin, polyethylene terephthalate resin, polystyrene resin, Corvic, ethylene-vinyl alcohol copolymer resin, acrylonitrile-styrene copolymerized resin, ABS resin, polyamide can be combinationally used with Shangdi in monolayer ~ 2 layer.
< application >
For described shampoo Compositions, even if the fierce region of the environmental change under the low humidity that (temperature 27 DEG C, humidity 70%RH) and operation of air conditioner obtain under high-temperature high-humidity, hair is not fluffy yet, be easy to moulding, be not close between hair, there is sense of gently escaping, hold concurrently with flatness and flexibility, and usability is excellent, therefore, such as, the Clean-shampoo of scalp, injury repairing shampoo, gentle shampoo and two-in-one shampoo (リ Application ス イ Application シ ャ ン プ ー) etc. are applicable to.In addition, except for except the hair of people, also can be used for the hair of the animals such as house pet.
Embodiment
Below, by enumerating the embodiment of the present invention, the present invention is specifically described, but the present invention is not limited to these embodiments.In addition, in embodiment shown below and comparative example, as being not particularly illustrated, then " % " expression " quality % ", the combined amount of each composition represents purity scaled value.
(embodiment 1 ~ 50 and comparative example 1 ~ 18)
Add (A) composition described in the embodiment shown in following table 1 ~ table 12 and comparative example, (B) composition, (C) composition, (D) composition, (E) composition and any composition, stir 30 minutes at 25 DEG C.For the gloss imparting agent (glycol distearate) of (C) composition, in advance according to following preparation method, be prepared into 4.5 quality % gloss imparting agent dispersion liquids, add in shampoo Compositions, make gloss imparting agent reach ormal weight.Such as, when being mixed with (C) composition gloss imparting agent of 1.5 quality %, add the 4.5 quality % gloss imparting agent dispersion liquids of 33.3 quality %.In gloss imparting agent dispersion liquid, containing during as the polyoxyethylene laural base sulfate of (A) composition and lauryl sulfate, the combined amount described in embodiment is recorded as with the total amount from the addition in gloss imparting agent dispersion liquid.After adding gloss imparting agent dispersion liquid, and after fully stirring, with citric acid, pH is adjusted to 5.8, obtains shampoo Compositions.
(preparation example 1)
-preparation of glycol distearate crystal dispersion liquid-
Glycol distearate crystal dispersion liquid as the gloss imparting agent of (C) composition is prepared in accordance with the following methods.
Polyoxyethylene (3) Zetesol AP (TexaponALES70 is dissolved in water, BASF AG manufactures) and ammonium lauryl sulfate (TexaponALS70, BASF AG manufactures), its final concentration is made to be 10 quality %, 5 quality % respectively, keep aqueous solution at 80 DEG C, and stir in 2L beaker.While this aqueous solution of stirring, glycol distearate (the TeginEGS melted at 80 DEG C is slowly added in this aqueous solution, Evonik company manufactures), its final concentration is made to be 4.5 quality %, and at 80 DEG C, use multi-function motor (ス リ ー ワ ン モ ー タ) (FBL1200, HEIDEN company manufactures), four inclination oars are with 100rpm Homogeneous phase mixing after 30 minutes, use homogeneous mixer (PRIMIX Co., Ltd. (プ ラ イ ミ Network ス Co., Ltd.) manufacture), disperse mixing 10 minutes with 4500rpm.
Then, the dispersed mixture of gained is flooded in water bath, and while use four inclination oars stir with 100rpm, being cooled in dispersion mixing channel 35 DEG C (rate of cooling is 1 DEG C/min), thus preparation 4.5 quality % glycol distearate crystal dispersion liquids.
In addition, in embodiment 21, use polyoxyethylene (2) sodium laureth sulfate/sodium lauryl sulfate, and according to operation similar to the above, prepare 4.5 quality % glycol distearate crystal dispersion liquids.
Use laser diffraction type sedimentograph (LA-920, Horiba Ltd manufactures), and using the relative index of refraction relative to water 1 as 1.08, measure the median particle diameter of described 4.5 quality % glycol distearate crystal dispersion liquids.Median particle diameter is 2.0 μm.In addition, the dispersion shape of this crystal is needle-like.
For each shampoo Compositions of gained, women professional group member 20 is with the about use amount of 6mL/ time, use 7 days, and according to following evaluation methodology and benchmark, evaluate following aspect: " 27 DEG C, dried hair under 70%RH gently escapes ", " 25 DEG C, dried hair under 40%RH gently escapes ", " 27 DEG C, dried hair under 70%RH is easy to formative nature ", " 25 DEG C, dried hair under 40%RH is easy to formative nature ", " hair flatness during washing ", " dried hair flatness ", " dried hair soft " and " usability (the taking-up easiness from bottle) ".Result is closed and is remembered in table 1 ~ table 12.
< evaluation methodology >
In such a way, repeat seven times (being cycled to repeat 7 times below): on fully moistening hair, be coated with each shampoo Compositions 6mL, after abundant foaming washing, rinse with the shower of tap water temperature 40 DEG C, flow 250mL/3 second, towel off after doing lightly, in the room of temperature 27 DEG C, humidity 70%RH, undisturbedly stay 12 hours, more undisturbedly stay 12 hours in the room of temperature 25 DEG C, humidity 40%RH.
[several 1]
When the 7th time clean, evaluate " hair flatness during washing ", after towel, in the room of temperature 27 DEG C, humidity 70%RH, undisturbedly stay 12 hours, evaluate " 27 DEG C, dried hair under 70%RH gently escape ", " 27 DEG C, dried hair under 70%RH be easy to formative nature ", " dried hair flatness " and " dried hair soft ".
In addition, then, in the room of temperature 25 DEG C, humidity 40%RH, undisturbedly stay 12 hours, evaluate " 25 DEG C, dried hair under 40%RH gently escape " and " 25 DEG C, dried hair under 40%RH be easy to formative nature ".
(1) 27 DEG C, dried hair under 70%RH gently escapes
According to following judgment standard, evaluate " 27 DEG C, dried hair under 70%RH gently escape ".According to answering as good number, represent in order to following judgment standard.Herein, " hair gently escapes " represents that hair is light, hair separates by root, drying is salubrious.
[judgment standard]
It is good for more than ◎: 16 people answering
◎ ~ zero: it is good for answering more than 13 people, below 15 people
It is good for answering more than zero: 11 people, below 12 people
It is good for answering more than △: 6 people, below 10 people
×: it is good for answering below 5 people
(2) 25 DEG C, dried hair under 40%RH gently escapes
According to following judgment standard, evaluate " 25 DEG C, dried hair under 40%RH gently escape ".According to answering as good number, represent in order to following judgment standard.Herein, " hair gently escapes " represents that hair is light, hair separates by root, drying is salubrious.
[judgment standard]
It is good for more than ◎: 16 people answering
◎ ~ zero: it is good for answering more than 13 people, below 15 people
It is good for answering more than zero: 11 people, below 12 people
It is good for answering more than △: 6 people, below 10 people
×: it is good for answering below 5 people
(3) 27 DEG C, dried hair under 70%RH is easy to formative nature
According to following judgment standard, evaluate " 27 DEG C, dried hair under 70%RH be easy to formative nature ".According to answering as good number, represent in order to following judgment standard.Herein, " hair is easy to formative nature " represents that the comb general character of hair is good, is easy to unified.
[judgment standard]
It is good for more than ◎: 16 people answering
◎ ~ zero: it is good for answering more than 13 people, below 15 people
It is good for answering more than zero: 11 people, below 12 people
It is good for answering more than △: 6 people, below 10 people
×: it is good for answering below 5 people
(4) 25 DEG C, dried hair under 40%RH gently escapes
According to following judgment standard, evaluate " 25 DEG C, dried hair under 40%RH be easy to formative nature ".According to answering as good number, represent in order to following judgment standard.Herein, " hair is easy to formative nature " represents that the comb general character of hair is good, is easy to unified.
[judgment standard]
It is good for more than ◎: 16 people answering
◎ ~ zero: it is good for answering more than 13 people, below 15 people
It is good for answering more than zero: 11 people, below 12 people
It is good for answering more than △: 6 people, below 10 people
×: it is good for answering below 5 people
(5) hair flatness during washing
According to following judgment standard, evaluate " hair flatness during washing ".According to answering as good number, represent in order to following judgment standard.Herein, " hair flatness during washing " when touching hair, can carry out finger sliding during representing flushing shampoo without resistance.
[judgment standard]
It is good for more than ◎: 16 people answering
◎ ~ zero: it is good for answering more than 13 people, below 15 people
It is good for answering more than zero: 11 people, below 12 people
It is good for answering more than △: 6 people, below 10 people
×: it is good for answering below 5 people
(6) dried hair flatness
According to following judgment standard, evaluate " dried hair flatness ".According to answering as good number, represent in order to following judgment standard.Herein, when " dried hair flatness " expression touches dried hair, finger sliding can be carried out without resistance.
[judgment standard]
It is good for more than ◎: 16 people answering
◎ ~ zero: it is good for answering more than 13 people, below 15 people
It is good for answering more than zero: 11 people, below 12 people
It is good for answering more than △: 6 people, below 10 people
×: it is good for answering below 5 people
(7) dried hair soft
According to following judgment standard, evaluate " dried hair soft ".According to answering as good number, represent in order to following judgment standard.Herein, when " dried hair soft " expression touches dried hair, there is flexibility.
[judgment standard]
It is good for more than ◎: 16 people answering
◎ ~ zero: it is good for answering more than 13 people, below 15 people
It is good for answering more than zero: 11 people, below 12 people
It is good for answering more than △: 6 people, below 10 people
×: it is good for answering below 5 people
(8) usability
According to following judgment standard, evaluate " usability " of shampoo Compositions.According to answering as good number, represent in order to following judgment standard.Herein, " usability " represents the taking-up easiness of shampoo Compositions from bottle.
[judgment standard]
It is good for more than ◎: 16 people answering
◎ ~ zero: it is good for answering more than 13 people, below 15 people
It is good for answering more than zero: 11 people, below 12 people
It is good for answering more than △: 6 people, below 10 people
×: it is good for answering below 5 people
[table 1]
[table 2]
[table 3]
[table 4]
[table 5]
[table 6]
[table 7]
[table 8]
[table 9]
[table 10]
[table 11]
[table 12]
The details of each composition used in the embodiment of table 1 ~ table 12 and comparative example is as shown in following table 13.
[table 13]
* 1: the dimethyl polysiloxane B (emulsion) in table 13 is prepared in accordance with the following methods.
At ReofuroDMS-60 (Ipposha Oil Ind Co., Ltd.'s manufacture) [kinematic viscosity 10,000,000mm 2the high polymeric MAO polysiloxanes of/s: kinematic viscosity 4,000,000mm 2the high polymeric MAO polysiloxanes of/s: kinematic viscosity 1,000mm 2methyl polysiloxane=the 15:15:70 (mass ratio) of/s] in, add emulsifying agent POE (15) cetyl ether (trade name: NPO-97, Shi Wang Chemical Co., Ltd (ラ イ オ Application ケ ミ カ Le Co., Ltd.) manufactures), and emulsion dispersion is in water.
As form of the present invention, such as, following form etc. can be enumerated.
<1> shampoo Compositions, is characterized in that, contain:
(A) there is the anionic surfactant of sulphuric acid residue;
(B) gallic acid glycosides;
(C) gloss imparting agent;
(D) cation property copolymer; And
(E) silicone compounds 0.15 quality % ~ 5.0 quality %;
Wherein, mass ratio (B+C)/(A+D) of described (B) composition and described (C) composition and described (A) and described (D) composition is 0.05 ~ 0.6;
Described (A) composition contains polyoxyethylene alkyl ether sulfate salt (A1) and alkyl sulfate (A2);
Described (D) composition is made up of JR-125 (D1) and Poise C-80M (D2), and the mass ratio D1/D2 of described (D1) composition and described (D2) composition is 2 ~ 20;
Described (E) composition is made up of dimethyl polysiloxane (E1) and amino modified silicone (E2), and the mass ratio E1/E2 of described (E1) composition and described (E2) composition is 2 ~ 30.
<2> as described in the shampoo Compositions recorded of <1>, it contains:
(A) there is the anionic surfactant 10 quality % ~ 25 quality % of sulphuric acid residue;
(B) gallic acid glycosides 0.05 quality % ~ 3 quality %;
(C) gloss imparting agent 1.2 quality % ~ 4.5 quality %; And
(D) cation property copolymer 0.2 quality % ~ 1.5 quality %.
<3> as described in the shampoo Compositions recorded of any one in <1> ~ <2>, wherein, (D1) nitrogen content of composition is 1 quality % ~ 1.8 quality %, and the nitrogen content of (D2) composition is 1.5 quality % ~ 2.2 quality %.
<4> as described in the shampoo Compositions recorded of any one in <1> ~ <3>, wherein, the mass ratio A1/A2 of (A1) composition and (A2) composition is 1 ~ 7.
Industry utilizes probability
Even if due to the fierce region of the environmental change under the low humidity that shampoo Compositions of the present invention obtains with operation of air conditioner under high-temperature high-humidity, hair is not fluffy, be easy to moulding, be not close between hair, hold concurrently with sense, flatness and the flexibility of gently escaping, and usability is excellent, therefore, such as, the Clean-shampoo of scalp, injury repairing shampoo, gentle shampoo and two-in-one shampoo etc. are applicable to.

Claims (4)

1. a shampoo Compositions, is characterized in that, contains:
(A) there is the anionic surfactant of sulphuric acid residue;
(B) gallic acid glycosides;
(C) gloss imparting agent;
(D) cation property copolymer; And
(E) silicone compounds 0.15 quality % ~ 5.0 quality %;
Wherein, mass ratio (B+C)/(A+D) of described (B) composition and described (C) composition and described (A) and described (D) composition is 0.05 ~ 0.6;
Described (A) composition contains polyoxyethylene alkyl ether sulfate salt (A1) and alkyl sulfate (A2);
Described (D) composition contains JR-125 (D1) and Poise C-80M (D2), and the mass ratio D1/D2 of described (D1) composition and described (D2) composition is 2 ~ 20;
Described (E) composition contains dimethyl polysiloxane (E1) and amino modified silicone (E2), and the mass ratio E1/E2 of described (E1) composition and described (E2) composition is 2 ~ 30.
2., as the shampoo Compositions that claim 1 is recorded, it contains:
(A) there is the anionic surfactant 10 quality % ~ 25 quality % of sulphuric acid residue;
(B) gallic acid glycosides 0.05 quality % ~ 3 quality %;
(C) gloss imparting agent 1.2 quality % ~ 4.5 quality %; And
(D) cation property copolymer 0.2 quality % ~ 1.5 quality %.
3., as the shampoo Compositions that any one in claim 1 ~ 2 is recorded, wherein, the nitrogen content of (D1) composition is 1 quality % ~ 1.8 quality %, and the nitrogen content of (D2) composition is 1.5 quality % ~ 2.2 quality %.
4. as the shampoo Compositions that any one in claims 1 to 3 is recorded, wherein, (A1) composition is 1 ~ 7 with the mass ratio A1/A2 of (A2) composition.
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