CN110894400A - Glass ceramic coating and preparation method thereof - Google Patents

Glass ceramic coating and preparation method thereof Download PDF

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Publication number
CN110894400A
CN110894400A CN201811059740.7A CN201811059740A CN110894400A CN 110894400 A CN110894400 A CN 110894400A CN 201811059740 A CN201811059740 A CN 201811059740A CN 110894400 A CN110894400 A CN 110894400A
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China
Prior art keywords
parts
powder
agent
water
weight
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CN201811059740.7A
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Chinese (zh)
Inventor
王占庭
王辉
徐祖猛
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Anhui Kangrui High-Tech New Material Technology Engineering Co Ltd
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Anhui Kangrui High-Tech New Material Technology Engineering Co Ltd
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Priority to CN201811059740.7A priority Critical patent/CN110894400A/en
Publication of CN110894400A publication Critical patent/CN110894400A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • C09D183/08Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2251Oxides; Hydroxides of metals of chromium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2268Ferrous oxide (FeO)

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention belongs to the technical field of paint preparation, and particularly discloses a glass-ceramic paint and a preparation method thereof, wherein the glass-ceramic paint comprises the following components in parts by weight: silicone resin: 40-60 parts of chromium iron black: 35-50 parts, talc powder: 10-20 parts of glass powder: 10-15 parts of xylene: 10-15 parts of deionized water: 15-30 parts of defoaming agent: 0.1-1 part of wetting and leveling agent: 0.5-3 parts of pH neutralizer: 5-10 parts of cosolvent: 3-8 parts of a thickening agent: 0.5-3 parts of an adhesion promoter: 0.5-2 parts of alkali washing mica powder: 5-10 parts. The glass ceramic coating prepared by the invention has good wear resistance and heat resistance, the heat resistance temperature is as high as 800 ℃, and the requirements of modern production and living application can be well met.

Description

Glass ceramic coating and preparation method thereof
Technical Field
The invention relates to the technical field of paint preparation, in particular to a glass-ceramic paint and a preparation method thereof.
Background
The glass ceramic coating is widely applied to daily life of people, and is applied to daily ceramics such as tableware, tea sets, jars and plates; artistic ceramics, such as vases, sculptures, furnishings; the application of industrial ceramics is very frequent, particularly the industrial ceramics, relating to building sanitary ceramics, chemical ceramics and electric ceramics, have high requirements on the wear resistance and the heat resistance of coatings, such as tiles, drain pipes, acid-resistant containers, wireless insulators and the like; good wear resistance and heat resistance are also required in glass products in daily life to keep the beauty of the glass products, ensure the safety of people in daily life and prevent fire problems caused by the burning of the coating.
Based on the background, it is necessary to develop a glass-ceramic coating with good wear resistance and high heat resistance to meet the requirements of people in daily life.
Disclosure of Invention
The invention aims to provide a water-based glass-ceramic paint with good wear resistance, stable paint film and good humidity resistance and heat performance and a preparation method thereof, so as to meet the requirements of modern production and application.
In order to achieve the purpose, the invention provides the following technical scheme:
the glass ceramic coating comprises the following components in parts by weight:
silicone resin: 40-60 parts of (A) a water-soluble polymer,
chrome iron black: 35 to 50 parts of (a) a water-soluble polymer,
talc powder: 10-20 parts of (A) a water-soluble polymer,
glass powder: 10-15 parts of (a) a water-soluble polymer,
xylene: 10-15 parts of (a) a water-soluble polymer,
deionized water: 15-30 parts of (A) a water-soluble polymer,
defoaming agent: 0.1 to 1 part by weight of a surfactant,
wetting and leveling agent: 0.5 to 3 parts by weight of a stabilizer,
pH neutralizer: 5 to 10 parts by weight of a surfactant,
cosolvent: 3 to 8 parts of (A) a water-soluble polymer,
thickening agent: 0.5 to 3 parts by weight of a stabilizer,
an adhesion promoter: 0.5 to 2 parts by weight of a stabilizer,
washing mica powder with alkali: 5-10 parts.
Preferably, the glass ceramic coating comprises the following components in parts by weight: silicone resin: 50 parts of ferrochrome black: 40 parts, talcum powder: 15 parts of glass powder: 12 parts, xylene: 12 parts of deionized water: 16 parts, defoaming agent: 0.6 part, wetting and leveling agent: 2 parts, pH neutralizer: 8 parts of cosolvent: 6 parts of a thickening agent: 2 parts, adhesion promoter: 1.5 parts of alkali washing mica powder: 8 parts.
Preferably, the organic silicon resin is a mixture of phenylchlorosilane, methylchlorosilane and fluorine organic silicon compound monomers mixed in any proportion.
Preferably, the wetting leveling agent is one of a BYK-333 leveling agent or a BYK-349 leveling agent.
Preferably, the defoaming agent is one of BYK-080, BYK-022, EKKA-4050 and Tego 825.
Preferably, the preparation method of the alkali washing mica powder comprises the following steps:
(1) pulverizing mica, and sieving with 80-200 mesh sieve to obtain mica powder;
(2) mixing mica powder with alkali liquor at 100-120 deg.C, stirring for 18-24 hr, centrifuging for 10-20min, filtering, washing with water, and drying to obtain alkali washing mica.
Preferably, the preparation method of the glass ceramic coating comprises the following steps:
1) weighing the materials of the components in parts by weight;
2) sequentially adding organic silicon resin, deionized water, ferrochrome black, talcum powder, glass powder, xylene, a defoaming agent, a wetting and leveling agent, a cosolvent, a thickening agent, an adhesion promoter and alkali washing mica powder into a stirring kettle at a stirring speed of 800-1000 r/min, stirring for 20 minutes, adding a pH neutralizing agent to adjust the pH value to 7-8, and uniformly stirring;
3) and adjusting the viscosity to 70 KU.
Compared with the prior art, the invention has the beneficial effects that:
1. the pure organic silicon resin has the advantage of good heat resistance, and the glass ceramic coating has the advantages of good high temperature resistance and temperature change resistance.
2. Mica is one of the components of granite and has great hardness and mechanical strength. Mica powder is added into the glass ceramic coating as a filler, so that the wear resistance of the coating can be effectively improved.
3. The ferrochrome black is used as black pigment and can resist the high temperature of 800 ℃.
Detailed Description
Example 1:
the glass ceramic coating comprises the following components in parts by weight:
silicone resin: 50 parts of ferrochrome black: 40 parts, talcum powder: 15 parts of glass powder: 12 parts, xylene: 12 parts of deionized water: 16 parts, defoaming agent: 0.6 part, wetting and leveling agent: 2 parts, pH neutralizer: 8 parts of cosolvent: 6 parts of a thickening agent: 2 parts, adhesion promoter: 1.5 parts of alkali washing mica powder: 8 parts.
According to the technical scheme, the organic silicon resin is a mixture formed by mixing 15 parts of phenyl chlorosilane, 15 parts of methyl chlorosilane and 20 parts of fluorine organic silicon compound monomers; the wetting leveling agent is a BYK-333 leveling agent; the antifoaming agent is BYK-080.
In the technical scheme, the preparation method of the alkali washing mica powder comprises the following steps:
(1) pulverizing mica, and sieving with 80-200 mesh sieve to obtain mica powder;
(2) mixing mica powder with alkali liquor at 100-120 deg.C, stirring for 18-24 hr, centrifuging for 10-20min, filtering, washing with water, and drying to obtain alkali washing mica.
According to the formula of the technical scheme, the preparation steps of the glass ceramic coating are as follows:
1) weighing the materials of the components in parts by weight;
2) sequentially adding organic silicon resin, deionized water, ferrochrome black, talcum powder, glass powder, xylene, a defoaming agent, a wetting and leveling agent, a cosolvent, a thickening agent, an adhesion promoter and alkali washing mica powder into a stirring kettle at a stirring speed of 800-1000 r/min, stirring for 20 minutes, adding a pH neutralizing agent to adjust the pH value to 7-8, and uniformly stirring;
3) and adjusting the viscosity to 70 KU.
Example 2:
the glass ceramic coating comprises the following components in parts by weight: silicone resin: 40 parts of ferrochrome black: 35 parts, talc powder: 15 parts of glass powder: 12 parts, xylene: 12 parts of deionized water: 16 parts, defoaming agent: 0.6 part, wetting and leveling agent: 2 parts, pH neutralizer: 8 parts of cosolvent: 6 parts of a thickening agent: 2 parts, adhesion promoter: 1.5 parts of alkali washing mica powder: 8 parts.
According to the technical scheme, the organic silicon resin is a mixture formed by mixing 10 parts of phenyl chlorosilane, 10 parts of methyl chlorosilane and 20 parts of fluorine organic silicon compound monomers; the wetting leveling agent is a BYK-349 leveling agent; the defoaming agent is BYK-022.
In the technical scheme, the preparation method of the alkali washing mica powder comprises the following steps:
(1) pulverizing mica, and sieving with 80-200 mesh sieve to obtain mica powder;
(2) mixing mica powder with alkali liquor at 100-120 deg.C, stirring for 18-24 hr, centrifuging for 10-20min, filtering, washing with water, and drying to obtain alkali washing mica.
According to the formula of the technical scheme, the preparation steps of the glass ceramic coating are as follows:
1) weighing the materials of the components in parts by weight;
2) sequentially adding organic silicon resin, deionized water, ferrochrome black, talcum powder, glass powder, xylene, a defoaming agent, a wetting and leveling agent, a cosolvent, a thickening agent, an adhesion promoter and alkali washing mica powder into a stirring kettle at a stirring speed of 800-1000 r/min, stirring for 20 minutes, adding a pH neutralizing agent to adjust the pH value to 7-8, and uniformly stirring;
3) and adjusting the viscosity to 70 KU.
Example 3:
the glass ceramic coating comprises the following components in parts by weight: silicone resin: 50 parts of ferrochrome black: 40 parts, talcum powder: 15 parts of glass powder: 12 parts, xylene: 12 parts of deionized water: 16 parts, defoaming agent: 0.6 part, wetting and leveling agent: 2 parts, pH neutralizer: 8 parts of cosolvent: 6 parts of a thickening agent: 2 parts, adhesion promoter: 1.5 parts of alkali washing mica powder: 8 parts.
According to the technical scheme, the organic silicon resin is a mixture formed by mixing 20 parts of phenyl chlorosilane, 20 parts of methyl chlorosilane and 10 parts of fluorine organic silicon compound monomers; the wetting leveling agent is a BYK-333 leveling agent; the antifoaming agent is EKKA-4050.
In the technical scheme, the preparation method of the alkali washing mica powder comprises the following steps:
(1) pulverizing mica, and sieving with 80-200 mesh sieve to obtain mica powder;
(2) mixing mica powder with alkali liquor at 100-120 deg.C, stirring for 18-24 hr, centrifuging for 10-20min, filtering, washing with water, and drying to obtain alkali washing mica.
According to the formula of the technical scheme, the preparation steps of the glass ceramic coating are as follows:
1) weighing the materials of the components in parts by weight;
2) sequentially adding organic silicon resin, deionized water, ferrochrome black, talcum powder, glass powder, xylene, a defoaming agent, a wetting and leveling agent, a cosolvent, a thickening agent, an adhesion promoter and alkali washing mica powder into a stirring kettle at a stirring speed of 800-1000 r/min, stirring for 20 minutes, adding a pH neutralizing agent to adjust the pH value to 7-8, and uniformly stirring;
3) and adjusting the viscosity to 70 KU.
Example 4:
the glass ceramic coating comprises the following components in parts by weight: silicone resin: 50 parts of ferrochrome black: 40 parts, talcum powder: 15 parts of glass powder: 12 parts, xylene: 12 parts of deionized water: 16 parts, defoaming agent: 0.6 part, wetting and leveling agent: 2 parts, pH neutralizer: 8 parts of cosolvent: 6 parts of a thickening agent: 2 parts, adhesion promoter: 1.5 parts of alkali washing mica powder: 8 parts.
According to the technical scheme, the organic silicon resin is a mixture formed by mixing 10 parts of phenyl chlorosilane, 10 parts of methyl chlorosilane and 30 parts of fluorine organic silicon compound monomers; the wetting leveling agent is a BYK-349 leveling agent; the antifoaming agent was Tego 825.
In the technical scheme, the preparation method of the alkali washing mica powder comprises the following steps:
(1) pulverizing mica, and sieving with 80-200 mesh sieve to obtain mica powder;
(2) mixing mica powder with alkali liquor at 100-120 deg.C, stirring for 18-24 hr, centrifuging for 10-20min, filtering, washing with water, and drying to obtain alkali washing mica.
According to the formula of the technical scheme, the preparation steps of the glass ceramic coating are as follows:
1) weighing the materials of the components in parts by weight;
2) sequentially adding organic silicon resin, deionized water, ferrochrome black, talcum powder, glass powder, xylene, a defoaming agent, a wetting and leveling agent, a cosolvent, a thickening agent, an adhesion promoter and alkali washing mica powder into a stirring kettle at a stirring speed of 800-1000 r/min, stirring for 20 minutes, adding a pH neutralizing agent to adjust the pH value to 7-8, and uniformly stirring;
3) and adjusting the viscosity to 70 KU.
The raw materials listed in the invention, the upper and lower limits and interval values of the raw materials of the invention, and the upper and lower limits and interval values of the process parameters (such as temperature, time and the like) can all realize the invention, and the examples are not listed.
While the foregoing is directed to the preferred embodiment of the present invention, other and further embodiments of the invention may be devised without departing from the basic scope thereof, and the scope thereof is determined by the claims that follow.

Claims (7)

1. The glass ceramic coating is characterized by comprising the following components in parts by weight:
silicone resin: 40-60 parts of (A) a water-soluble polymer,
chrome iron black: 35 to 50 parts of (a) a water-soluble polymer,
talc powder: 10-20 parts of (A) a water-soluble polymer,
glass powder: 10-15 parts of (a) a water-soluble polymer,
xylene: 10-15 parts of (a) a water-soluble polymer,
deionized water: 15-30 parts of (A) a water-soluble polymer,
defoaming agent: 0.1 to 1 part by weight of a surfactant,
wetting and leveling agent: 0.5 to 3 parts by weight of a stabilizer,
pH neutralizer: 5 to 10 parts by weight of a surfactant,
cosolvent: 3 to 8 parts of (A) a water-soluble polymer,
thickening agent: 0.5 to 3 parts by weight of a stabilizer,
an adhesion promoter: 0.5 to 2 parts by weight of a stabilizer,
washing mica powder with alkali: 5-10 parts.
2. The vitreous porcelain coating of claim 1, which is composed of the following components in parts by weight: silicone resin: 50 parts of ferrochrome black: 40 parts, talcum powder: 15 parts of glass powder: 12 parts, xylene: 12 parts of deionized water: 16 parts, defoaming agent: 0.6 part, wetting and leveling agent: 2 parts, pH neutralizer: 8 parts of cosolvent: 6 parts of a thickening agent: 2 parts, adhesion promoter: 1.5 parts of alkali washing mica powder: 8 parts.
3. The vitreous porcelain coating of claim 1, wherein the silicone resin is a mixture of phenylchlorosilane, methylchlorosilane, and fluorosilicone monomers mixed in any proportion.
4. The vitreous porcelain coating of claim 1, wherein the wetting and leveling agent is one of a BYK-333 leveling agent or a BYK-349 leveling agent.
5. The glass-ceramic coating of claim 1, wherein the defoaming agent is one of BYK-080, BYK-022, EKKA-4050, Tego 825.
6. The vitreous enamel coating according to any of claims 1 to 3, wherein the alkali washing mica powder is prepared by the following method:
(1) pulverizing mica, and sieving with 80-200 mesh sieve to obtain mica powder;
(2) mixing mica powder with alkali liquor at 100-120 deg.C, stirring for 18-24 hr, centrifuging for 10-20min, filtering, washing with water, and drying to obtain alkali washing mica.
7. The preparation method of the vitreous porcelain coating of any one of claims 1 to 6, characterized by comprising the following steps:
1) weighing the materials of the components in parts by weight;
2) sequentially adding organic silicon resin, deionized water, ferrochrome black, talcum powder, glass powder, xylene, a defoaming agent, a wetting and leveling agent, a cosolvent, a thickening agent, an adhesion promoter and alkali washing mica powder into a stirring kettle at a stirring speed of 800-1000 r/min, stirring for 20 minutes, adding a pH neutralizing agent to adjust the pH value to 7-8, and uniformly stirring;
3) and adjusting the viscosity to 70 KU.
CN201811059740.7A 2018-09-12 2018-09-12 Glass ceramic coating and preparation method thereof Pending CN110894400A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201811059740.7A CN110894400A (en) 2018-09-12 2018-09-12 Glass ceramic coating and preparation method thereof

Publications (1)

Publication Number Publication Date
CN110894400A true CN110894400A (en) 2020-03-20

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1560156A (en) * 2004-02-19 2005-01-05 常州市鑫发涂料有限公司 Paint of organic silicon capable of resisting high temp
CN1948403A (en) * 2006-11-09 2007-04-18 上海大学 Preparation method of pearl light pigment for high grade paint
CN1995250A (en) * 2006-01-04 2007-07-11 北京国邦技术发展中心 Thermostable heat-isolating coating and its preparation method
CN101130663A (en) * 2007-10-10 2008-02-27 大庆油田有限责任公司 Fire resistant anticorrosive paint of organosilicon
CN101550315A (en) * 2009-05-15 2009-10-07 泰州市四联化工有限公司 Black organic silicon heat-resistant paint and preparation method thereof
CN103484014A (en) * 2013-06-26 2014-01-01 南京市荣达树脂有限公司 Preparation method of organic silicon high-temperature resistant resin coating
CN103965775A (en) * 2014-05-20 2014-08-06 重庆海联水性涂料有限公司 Water-based organosilicone high temperature resistant anticorrosive coating and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1560156A (en) * 2004-02-19 2005-01-05 常州市鑫发涂料有限公司 Paint of organic silicon capable of resisting high temp
CN1995250A (en) * 2006-01-04 2007-07-11 北京国邦技术发展中心 Thermostable heat-isolating coating and its preparation method
CN1948403A (en) * 2006-11-09 2007-04-18 上海大学 Preparation method of pearl light pigment for high grade paint
CN101130663A (en) * 2007-10-10 2008-02-27 大庆油田有限责任公司 Fire resistant anticorrosive paint of organosilicon
CN101550315A (en) * 2009-05-15 2009-10-07 泰州市四联化工有限公司 Black organic silicon heat-resistant paint and preparation method thereof
CN103484014A (en) * 2013-06-26 2014-01-01 南京市荣达树脂有限公司 Preparation method of organic silicon high-temperature resistant resin coating
CN103965775A (en) * 2014-05-20 2014-08-06 重庆海联水性涂料有限公司 Water-based organosilicone high temperature resistant anticorrosive coating and preparation method thereof

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