CN110862880A - Neutral sodium peroxydisulfate aerobic powder and its prepn and application - Google Patents

Neutral sodium peroxydisulfate aerobic powder and its prepn and application Download PDF

Info

Publication number
CN110862880A
CN110862880A CN201911174031.8A CN201911174031A CN110862880A CN 110862880 A CN110862880 A CN 110862880A CN 201911174031 A CN201911174031 A CN 201911174031A CN 110862880 A CN110862880 A CN 110862880A
Authority
CN
China
Prior art keywords
sodium
powder
aerobic
parts
neutral
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911174031.8A
Other languages
Chinese (zh)
Inventor
郭保来
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanxi Baoqing Chemical Co Ltd
Original Assignee
Shanxi Baoqing Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanxi Baoqing Chemical Co Ltd filed Critical Shanxi Baoqing Chemical Co Ltd
Priority to CN201911174031.8A priority Critical patent/CN110862880A/en
Publication of CN110862880A publication Critical patent/CN110862880A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/02—Sulfur; Selenium; Tellurium; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00—Soil-conditioning materials or soil-stabilising materials
    • C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C11D3/323—Amides; Substituted amides urea or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38609—Protease or amylase in solid compositions only
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Molecular Biology (AREA)
  • Toxicology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Materials Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention provides sodium peroxide sulfate neutral aerobic powder and a preparation method and application thereof, wherein the aerobic powder comprises the following raw materials: sodium peroxide sulfate, surfactant and assistant. The neutral aerobic powder prepared by the method has good stability and is not easy to expand; meanwhile, the problems that the prior oxygen powder is difficult to dissolve and can only take effect in hot water when in use are solved, the oxygen powder can be dissolved immediately when meeting water, oxygen can be quickly, fully and completely released within an effective use period, and the efficiency is fully exerted. The neutral aerobic powder prepared by the technology is safe, efficient and wide in application range, is suitable for various industries and fields, and people are used at natural water body temperature, and the application range is wider.

Description

Neutral sodium peroxydisulfate aerobic powder and its prepn and application
Technical Field
The invention relates to sodium peroxydisulfate neutral aerobic powder and a preparation method and application thereof.
Background
The existing aerobic powder is called as aerobic powder because a sodium carbonate peroxide component is added, and the cleaning principle of the aerobic powder is that the aerobic powder releases oxygen in water and reacts with bacteria, toxin, peculiar smell, colored stains and the like to achieve the effects of decontamination, bleaching, sterilization, brightening, odor removal, mildew prevention and deep cleaning.
However, sodium carbonate peroxide has the following drawbacks: (1) the pH is alkaline, and the skin, organisms and the affected cleaning objects are damaged to different degrees by adding excessive or long-term use, so that the pH state of the original water body is influenced; (2) the non-wrapped sodium carbonate peroxide has unstable property, is easily affected by surrounding media and environment to release oxygen in storage and transportation in an independent and compound state, and causes bag expansion and content reduction; the relatively stable coated sodium carbonate peroxide can not completely and fully dissolve the coating material within the effective time period in the normal-temperature water body, so that the oxygen release is delayed, the energy is discharged after being released in time, the efficiency is not obvious, and the resource waste is caused; (3) the water body temperature is required, the optimal water temperature is 50-60 ℃, the efficiency can not be fully exerted in the normal-temperature water body, the application environment of various industry fields is the natural water body temperature state, and a good product can adapt to the environment instead of changing the conditions to adapt to the environment.
The defects are determined by the properties of the sodium carbonate peroxide, the sodium carbonate peroxide is prepared from sodium carbonate and hydrogen peroxide, is naturally alkaline, has a molecular structure which belongs to a hydrogen bond structure, is sensitive to the surrounding environment and media, is unstable in property, is not dissolved easily in water at normal temperature and is not sufficiently released in spite of relatively stable coated carbon peroxide, and is discharged when the efficiency is not fully exerted in an effective use period, so that the resource waste is formed. The defects are not suitable for the use habit of people in various industry fields in the natural environment state, which is determined by the intrinsic property of the defects and cannot be changed. Therefore, it is desired to develop a novel room temperature neutral oxygen-containing powder to compensate and solve these problems.
Disclosure of Invention
One purpose of the invention is to provide sodium peroxydisulfate neutral aerobic powder.
The sodium peroxydisulfate neutral aerobic powder comprises the following raw materials in parts by weight: 5 to 95 parts of sodium peroxide sulfate, 3 to 35 parts of surfactant and 5 to 60 parts of assistant.
The sodium peroxide sulfate neutral aerobic powder provided by the invention solves the alkaline problem of the existing aerobic powder, and the aerobic powder prepared by the technology belongs to neutral aerobic powder, has a pH value of about 7.0, is harmless to skin, organisms and action objects, and is environment-friendly; the problem that the prior aerobic powder is unstable before use is also solved, and the neutral aerobic powder prepared by the method has good stability and is not easy to expand; meanwhile, the problem that the existing oxygen powder is difficult to dissolve and needs heating when in use is solved, the oxygen powder can be dissolved immediately when meeting water and is not limited by the temperature condition of the water body, oxygen can be quickly, fully and completely released in an effective use period, and the efficiency is fully exerted. The neutral aerobic powder prepared by the technology is safe, efficient and wide in application range, is suitable for the habit that people use at the temperature of natural water in various industry fields, and has better applicability and wider application range. The method particularly solves the problem of granularity of the existing aerobic powder, the dissolution degree of the granular powder is influenced by water temperature when the granular powder is used, the preparation process of the granular powder is complex, the production cost is high, the neutral aerobic powder prepared by the method is in a concentrated powder state, is very fine and smooth, is quickly dissolved, is not influenced by the temperature of the water body, and the production process is safe and simple, can save a plurality of costs, and has no environmental influence.
In a word, the neutral aerobic powder prepared by the invention can cause the revolution and trend of related industries and fields, can adapt to and meet the continuously improved requirements of people on good life, and can generate epoch-making historical significance with milestones.
In addition, the sodium peroxydisulfate neutral aerobic powder according to the invention can also have the following additional technical characteristics:
as a preferred embodiment of the invention, the sodium peroxydisulfate neutral aerobic powder comprises the following raw materials in parts by weight: 5 parts of sodium peroxide sulfate, 35 parts of surfactant and 5 parts of assistant.
As a preferred embodiment of the invention, the sodium peroxydisulfate neutral aerobic powder comprises the following raw materials in parts by weight: 95 parts of sodium peroxide sulfate, 3 parts of surfactant and 60 parts of assistant.
As a preferred embodiment of the invention, the sodium peroxydisulfate neutral aerobic powder comprises the following raw materials in parts by weight: 50 parts of sodium peroxide sulfate, 19 parts of surfactant and 28 parts of assistant.
Further, the surfactant is at least one of fatty alcohol-polyoxyethylene ether, fatty acid methyl ester ethoxylate, alkyl glycoside, fatty acid methyl ester sulfonate, linear alkyl benzene sulfonate, sodium fatty acid, sodium fatty alcohol sulfate, secondary alkyl sodium sulfonate, α -alkenyl sodium sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid methyl ester sodium sulfonate and fatty alcohol-polyoxyethylene ether carboxylic acid sodium salt.
Further, the auxiliary agent is at least one of anhydrous sodium metasilicate, powdered sodium silicate, layered crystalline sodium silicate, sodium carbonate, sodium tripolyphosphate and sodium bicarbonate; the auxiliary agent also comprises anhydrous citric acid, an anti-fouling redeposition agent, an enzyme preparation, an activating agent, an aromatic preparation and an anti-caking preparation.
Further, the anti-soil redeposition agent is at least one of sodium carboxymethyl cellulose, hydroxyethyl cellulose, carboxymethyl ammonium, sodium polyacrylate, a copolymer of maleic anhydride and acrylic acid, polyvinylpyrrolidone, polyethylene glycol and polyvinyl alcohol; the enzyme preparation is at least one of protease, amylase, cellulase, lipase and mannanase; the activating agent is at least one of tetraacetylethylenediamine, nonanoyloxybenzenesulfonic acid sodium salt, tetraacetylglycoluril and pentaacetylglucose; the aromatic preparation is essence or spice without water.
Further, the water content of the neutral sodium peroxysulfate aerobic powder is lower than 0.1%, and the pH value is 6.5-7.5.
The invention also aims to provide a preparation method of the neutral sodium peroxydisulfate aerobic powder.
The preparation method of the neutral sodium peroxydisulfate aerobic powder comprises the following steps: firstly, adding the sodium peroxide sulfate into a stainless steel stirring container, then adding the surfactant, sequentially adding the auxiliary agents, finally spraying the nonionic surfactant into the mixture, and stirring for 15-25 min to obtain the neutral aerobic powder of the sodium peroxide sulfate.
The invention also aims to provide application of the sodium peroxysulphate neutral aerobic powder in the fields of washing, breeding, medical treatment and sanitation, sewage treatment, printing and dyeing, papermaking, soil improvement agent and disinfection.
Additional aspects and advantages of the invention will be set forth in part in the description which follows and, in part, will be obvious from the description, or may be learned by practice of the invention.
Detailed Description
The following detailed description of embodiments of the invention is intended to be illustrative, and not to be construed as limiting the invention.
Example 1
Neutral aerobic powder component
Composition (I) In percentage by weight%
Sodium peroxydisulfate 30
Fatty alcohol polyoxyethylene ether 5
Powdery sodium dodecylbenzenesulfonate 20
Anhydrous sodium metasilicate 22
Protease enzyme 2
Sodium carboxymethylcellulose 1
Ethylene diamine tetra (amide) 1
Anti-caking preparation 1
Anhydrous citric acid 17
Perfume 1
Remarking: 1. the water content in the above components and the whole components is less than 0.1%;
2. the pH value of the whole components is controlled between 6.5-7.5, the components are neutral, and the components are blended by increasing and decreasing the proportion of anhydrous citric acid and anhydrous sodium metasilicate
The preparation method comprises the following steps: under the constant temperature of 15 ℃, the air humidity is 3%, the components are sequentially added into an inner porcelain stainless steel container, finally, the fatty alcohol-polyoxyethylene ether is sprayed, the mixture is stirred for 25min, the mixture of the product is obtained, and the product is packaged according to a certain gram number.
Example 2
Neutral aerobic powder component
Composition (I) In percentage by weight%
Sodium peroxydisulfate 50
Powdered sodium fatty acid methyl ester sulfonate 15
Fatty acid methyl ester ethoxylates 5
Sodium carbonate 15
Lipase enzyme 2
Carboxyethyl cellulose 1
Nonoyloxybenzene sulfonic acid sodium salt 1
Anti-caking preparation 2
Anhydrous citric acid 8
Perfume 1
Remarking: 1. the water content in the above components and the whole components is less than 0.1%;
2. the pH value of the whole components is controlled between 6.5 and 7.5, the components are neutral, and the components are blended by increasing and decreasing the proportion of anhydrous citric acid and sodium carbonate.
The preparation method comprises the following steps: sequentially adding the components into an inner porcelain stainless steel container at a constant temperature of 20 ℃ and with air humidity of 1%, finally spraying fatty acid methyl ester ethoxylate, stirring for 20min to obtain a mixture of the product, and packaging the mixture according to a certain gram number.
Example 3
Neutral aerobic powder component
Figure BDA0002289497160000051
Figure BDA0002289497160000061
Remarking: 1. the water content in the above components and the whole components is less than 0.1%;
2. the pH value of the whole components is controlled between 6.5 and 7.5, the components are neutral, and the components are blended by increasing and decreasing the proportion of anhydrous citric acid and sodium tripolyphosphate.
The preparation method comprises the following steps: sequentially adding the above components into an inward porcelain stainless steel container at a constant temperature of 25 deg.C and an air humidity of 2%, spraying alkyl glycoside, stirring for 15min to obtain a mixture, and packaging according to a certain gram.
Comparison of various effects
Figure BDA0002289497160000062
Figure BDA0002289497160000071
Remarking: SPS neutral aerobic powder is the product of the invention which mainly takes sodium peroxydisulfate as the main material;
SPC aerobic powder is the current aerobic powder on the market, which mainly comprises sodium carbonate peroxide.
The invention is based on a novel peroxide, namely sodium peroxysulphate, the molecular formula of which is 4Na2SO4·2H2O2NaCl, which is formed by adding hydrogen peroxide, sodium sulfate, sodium chloride and crystallization aids through a certain process, and naturally has the multiple characteristics of integrating anhydrous sodium sulphate, hydrogen peroxide and industrial salt into a whole: 1. the self-stability and the compatibility are stable, and the coating can be compounded with various chemical preparations without water and metal ions, does not react, release oxygen and lose efficacy, is determined by the internal cage-shaped molecular structure and does not need to be wrapped; 2. the water can be quickly dissolved at the temperature of natural water, all active oxygen is fully released, the efficiency is fully exerted, and the water is not limited by the temperature of the water; 3. the pH is about 7.0, is neutral, cannot damage the acidity and alkalinity of the original water body when being used in large quantity, cannot cause damage to skin, organisms and affected objects, and is non-toxic, tasteless, non-irritant, free of side effects, pollution-free and environment-friendly. The advantages of the sodium peroxide exactly solve the problems and the defects of the prior aerobic powder represented by the sodium peroxide, are suitable for the current use situation under the natural environment state of various industries and fields, can be used safely and widely, and are a novel peroxide which is safe, effective, economic and environment-friendly.
The invention is based on the advantages of the sodium peroxide sulfate, takes the sodium peroxide sulfate as a leading idea, is the core of a scheme, and is a novel neutral aerobic powder invented and created for the technical foundation.
The invention has the following effects and advantages:
1. the invention solves the alkaline problem that the traditional aerobic powder takes sodium percarbonate as a main element for a long time, and leads the aerobic powder to move to a neutral era, thereby bringing the safe experience of not stimulating skin, fabrics, organisms and affected objects;
2. compared with the existing aerobic powder, the oxygen-releasing and bag-expanding phenomenon can not be caused; the storage and transportation are safer, and particularly, the storage and transportation are more safe, the packaging and granulation are not needed, the powder is finer and finer, the concentration is higher, the solubility is better, the oxygen can be quickly released in various natural water body temperatures, all the effects of decontamination, deodorization, oxygenation, disinfection, sterilization, bleaching, brightening, mildew prevention and water purification can be fully exerted in an effective use period, the multiple effects of water body temperature change are not needed, and the use habit of most people in a natural environment state is met;
3. the quality is safe and stable, the formula is wide, and the application is wide; more importantly, the production process is simple, the cost advantage is obvious, the environment is not polluted, the method is a novel product which is safe, green, efficient, environment-friendly and wide in market prospect, and a powder revolution can be caused.
The sodium peroxide sulfate neutral aerobic powder provided by the invention solves the alkaline problem of the existing aerobic powder, and the aerobic powder prepared by the technology belongs to neutral aerobic powder, has a pH value of about 7.0, is harmless to skin, organisms and action objects, and is environment-friendly; the problem that the prior aerobic powder is unstable before use is also solved, and the neutral aerobic powder prepared by the method has good stability and is not easy to expand; meanwhile, the problem that the existing oxygen powder is difficult to dissolve and needs heating when in use is solved, the oxygen powder can be dissolved immediately when meeting water and is not limited by the temperature condition of the water body, oxygen can be quickly, fully and completely released in an effective use period, and the efficiency is fully exerted. The neutral aerobic powder prepared by the technology is safe, efficient and wide in application range, is suitable for the habit that people use at the temperature of natural water in various industry fields, and has better applicability and wider application range. The method particularly solves the problem of granularity of the existing aerobic powder, the dissolution degree of the granular powder is influenced by water temperature when the granular powder is used, the preparation process of the granular powder is complex, the production cost is high, the neutral aerobic powder prepared by the method is in a concentrated powder state, is very fine and smooth, is quickly dissolved, is not influenced by the temperature of the water body, and the production process is safe and simple, can save a plurality of costs, and has no environmental influence.
In a word, the neutral aerobic powder prepared by the invention can cause the revolution and trend of related industries and fields, can adapt to and meet the continuously improved requirements of people on good life, and can generate epoch-making historical significance with milestones.
In the description herein, references to the description of the term "one embodiment," "some embodiments," "an example," "a specific example," or "some examples," etc., mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above are not necessarily intended to refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, various embodiments or examples and features of different embodiments or examples described in this specification can be combined and combined by one skilled in the art without contradiction.
Although embodiments of the present invention have been shown and described above, it is understood that the above embodiments are exemplary and should not be construed as limiting the present invention, and that variations, modifications, substitutions and alterations can be made to the above embodiments by those of ordinary skill in the art within the scope of the present invention.

Claims (10)

1. The sodium peroxide sulfate neutral aerobic powder is characterized by comprising the following raw materials in parts by weight: 5 to 95 parts of sodium peroxide sulfate, 3 to 35 parts of surfactant and 5 to 60 parts of assistant.
2. The sodium peroxydisulfate neutral aerobic powder of claim 1, which is characterized by comprising the following raw materials in parts by weight: 5 parts of sodium peroxide sulfate, 35 parts of surfactant and 5 parts of assistant.
3. The sodium peroxydisulfate neutral aerobic powder of claim 1, which is characterized by comprising the following raw materials in parts by weight: 95 parts of sodium peroxide sulfate, 3 parts of surfactant and 60 parts of assistant.
4. The sodium peroxydisulfate neutral aerobic powder of claim 1, which is characterized by comprising the following raw materials in parts by weight: 50 parts of sodium peroxide sulfate, 19 parts of surfactant and 28 parts of assistant.
5. The sodium peroxide sulfate neutral aerobic powder of any of the claims 1 to 4 wherein the surfactant is at least one of fatty alcohol-polyoxyethylene ether, fatty acid methyl ester ethoxylate, alkyl glycoside, fatty acid methyl ester sulfonate, sodium linear alkyl benzene sulfonate, sodium fatty acid, sodium fatty alcohol sulfate, secondary alkyl sodium sulfonate, α -sodium alkenyl sulfonate, sodium fatty alcohol-polyoxyethylene ether sulfate, sodium fatty acid methyl ester sulfonate and sodium fatty alcohol-polyoxyethylene ether carboxylate.
6. The neutral sodium peroxydisulfate aerobic powder of any one of claims 1-4 wherein the auxiliary agent is at least one of anhydrous sodium metasilicate, powdered sodium silicate, layered crystalline sodium silicate, sodium carbonate, sodium tripolyphosphate, and sodium bicarbonate; the auxiliary agent also comprises anhydrous citric acid, an anti-fouling redeposition agent, an enzyme preparation, an activating agent, an aromatic preparation and an anti-caking preparation.
7. The neutral sodium peroxydisulfate aerobic powder of claim 6 wherein the anti-redeposition agent is at least one of sodium carboxymethylcellulose, hydroxyethylcellulose, carboxymethyl ammonium, sodium polyacrylate, a copolymer of maleic anhydride and acrylic acid, polyvinylpyrrolidone, polyethylene glycol, polyvinyl alcohol; the enzyme preparation is at least one of protease, amylase, cellulase, lipase and mannanase; the activating agent is at least one of tetraacetylethylenediamine, nonanoyloxybenzenesulfonic acid sodium salt, tetraacetylglycoluril and pentaacetylglucose; the aromatic preparation is essence or spice without water.
8. The neutral sodium sulfate peroxide-oxidized powder according to any one of claims 1 to 4, wherein the neutral sodium sulfate peroxide-oxidized powder has a moisture content of less than 0.1% and a pH value of 6.5 to 7.5.
9. The method for preparing neutral aerobic powder of sodium peroxysulfate as claimed in claim 8, which comprises the steps of: firstly, adding the sodium peroxide sulfate into a stainless steel stirring container, then adding the surfactant, sequentially adding the auxiliary agents, finally spraying the nonionic surfactant into the mixture, and stirring for 15-25 min to obtain the neutral aerobic powder of the sodium peroxide sulfate.
10. Use of the sodium peroxysulphate neutral aerobic powder according to any of the claims 1 to 4 in the fields of washing, farming, medical hygiene, sewage treatment, printing, paper, soil improvement and disinfection.
CN201911174031.8A 2019-11-26 2019-11-26 Neutral sodium peroxydisulfate aerobic powder and its prepn and application Pending CN110862880A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911174031.8A CN110862880A (en) 2019-11-26 2019-11-26 Neutral sodium peroxydisulfate aerobic powder and its prepn and application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911174031.8A CN110862880A (en) 2019-11-26 2019-11-26 Neutral sodium peroxydisulfate aerobic powder and its prepn and application

Publications (1)

Publication Number Publication Date
CN110862880A true CN110862880A (en) 2020-03-06

Family

ID=69656187

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911174031.8A Pending CN110862880A (en) 2019-11-26 2019-11-26 Neutral sodium peroxydisulfate aerobic powder and its prepn and application

Country Status (1)

Country Link
CN (1) CN110862880A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111848481A (en) * 2020-04-08 2020-10-30 郭保来 Solid generating agent for preparing solid peroxyacetic acid and preparation method and application thereof
CN113652309A (en) * 2021-09-15 2021-11-16 广州立白企业集团有限公司 Instant active oxygen washing particle composition and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1780787A (en) * 2003-05-07 2006-05-31 德古萨股份公司 Coated sodium percarbonate granules with improved storage stability
CN104263553A (en) * 2014-10-13 2015-01-07 濮阳宏业汇龙化工有限公司 Cleanser with active oxygen sterilization effect
CN108576049A (en) * 2018-05-29 2018-09-28 山西宝清化工有限公司 Sodium peroxydisulfate sterilizes degerming cleansing tablet and preparation method thereof
CN109439448A (en) * 2018-11-16 2019-03-08 上海污师环保科技有限公司 A kind of self-cleaning washing particle of the ozone of rapid osmotic
CN109439455A (en) * 2018-11-19 2019-03-08 山东丽波日化股份有限公司 A kind of use in dishwasher detergent block and preparation method thereof
CN110184129A (en) * 2019-06-24 2019-08-30 东莞市水卫仕日化有限公司 Detergent composition and its preparation method and application
CN110408483A (en) * 2019-08-30 2019-11-05 郭家乐 Solid-state powder ball shaped detergent and its preparation method and application

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1780787A (en) * 2003-05-07 2006-05-31 德古萨股份公司 Coated sodium percarbonate granules with improved storage stability
CN104263553A (en) * 2014-10-13 2015-01-07 濮阳宏业汇龙化工有限公司 Cleanser with active oxygen sterilization effect
CN108576049A (en) * 2018-05-29 2018-09-28 山西宝清化工有限公司 Sodium peroxydisulfate sterilizes degerming cleansing tablet and preparation method thereof
CN109439448A (en) * 2018-11-16 2019-03-08 上海污师环保科技有限公司 A kind of self-cleaning washing particle of the ozone of rapid osmotic
CN109439455A (en) * 2018-11-19 2019-03-08 山东丽波日化股份有限公司 A kind of use in dishwasher detergent block and preparation method thereof
CN110184129A (en) * 2019-06-24 2019-08-30 东莞市水卫仕日化有限公司 Detergent composition and its preparation method and application
CN110408483A (en) * 2019-08-30 2019-11-05 郭家乐 Solid-state powder ball shaped detergent and its preparation method and application

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111848481A (en) * 2020-04-08 2020-10-30 郭保来 Solid generating agent for preparing solid peroxyacetic acid and preparation method and application thereof
CN113652309A (en) * 2021-09-15 2021-11-16 广州立白企业集团有限公司 Instant active oxygen washing particle composition and preparation method thereof

Similar Documents

Publication Publication Date Title
US6726936B1 (en) Antimicrobial agents
US8211842B2 (en) Preventive and/or curative agent for cleaning materials that are brought into contact with water
CN110862880A (en) Neutral sodium peroxydisulfate aerobic powder and its prepn and application
CN106879593A (en) A kind of alkalescent low corrosion Peracetic acid effervescent tablet disinfectant
CN101514305B (en) Fabric softener with bactericidal function and preparation method thereof
CN102559421A (en) Enzyme-containing fabric detergent with synergistic anticorrosion effect
CN104877765A (en) Cleaning agent for washing machine slot
JP2004231671A (en) Detergent composition and method for evaluating bacteria-removing power and deterging power
CN108576049A (en) Sodium peroxydisulfate sterilizes degerming cleansing tablet and preparation method thereof
CN114250120A (en) Clothes sterilizing detergent, clothes sterilizing and cleaning mousse and preparation method thereof
CN105886172A (en) Soap powder composition containing oxygen ion bacterial removing ingredients and preparation method of soap powder composition
EP3224336B1 (en) Cleaning composition
CN1270531A (en) Method for sanitization of substrates with deteragent compositions
JP2012131836A (en) Granular detergent composition
KR20220007054A (en) Composition for removing biofilm for water system
CN102100237A (en) Composite disinfectant and preparation method
CN102234598A (en) Common jasminorange leaf and twig flower-jasmine flower phosphorous-free perfumed washing powder
KR102212915B1 (en) Method of preparing eco-friendly tablet type peroxide-based disinfectant
US5932531A (en) Method for forming solid detergent activator for use with oxygen bleaches
CN104194960A (en) Environment-friendly deodorant
CN103897812A (en) Deodorizing toilet cleaner
CN108743450A (en) A kind of preparation method of skin care decontamination hand sanitizer
CN102876513A (en) Flavour-removing sterilizing toilet cleaner
CN101565656A (en) Laundry material, preparation method thereof and laundry ball
CN114480032A (en) Formula and production of antibacterial and acarus killing concentrated washing powder

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination