CN110835853A - 一种亚麻纤维的抗菌消臭工艺 - Google Patents

一种亚麻纤维的抗菌消臭工艺 Download PDF

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CN110835853A
CN110835853A CN201911149632.3A CN201911149632A CN110835853A CN 110835853 A CN110835853 A CN 110835853A CN 201911149632 A CN201911149632 A CN 201911149632A CN 110835853 A CN110835853 A CN 110835853A
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antibacterial
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刘江
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CHANGSHU CHANGHONG TEXTILE Co Ltd
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    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
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    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

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  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
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  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明公开了一种亚麻纤维的抗菌消臭工艺，所述亚麻纤维的抗菌消臭工艺包括：在去离子水中投入有机氮抗菌剂、无甲醛树脂、非离子渗透剂混合，搅拌均匀，制得整理剂，将亚麻纤维在含有整理剂的浸渍液中，浸轧一定时间，然后一定的温度下预烘，最后再经过160°焙烘一定时间，制成纤维。通过上述方式，本发明制备工艺简便，使用方法简单，抗菌纺织制品具有环保性，抑制细菌效果好。

Description

一种亚麻纤维的抗菌消臭工艺
技术领域
本发明涉及织物的染色工艺领域，特别是涉及一种亚麻纤维的抗菌消臭工艺。
背景技术
目前，对纺织材料抗菌加工的研究报道很多，所用的抗菌大多为有机类抗菌剂如季铵盐类、胍类、脂肪酸类和金属化合物等，其中多数有毒，不环保；有些抗菌剂只适用于某种特定的纤维；有的抗菌剂成本高，加工工艺复杂；有的抗菌效果欠佳，耐久性、耐洗性差。抗菌纺织制品具有生态、环保特点，同时具有高效、耐洗特点；其制备方法具有工艺简单，加工成本低等特点。
发明内容
本发明主要解决的技术问题是：针对现有技术的不足，提供一种亚麻纤维的抗菌消臭工艺，制备工艺简便，使用方法简单，抗菌纺织制品具有环保性，抑制细菌效果好。
为解决上述技术问题，本发明采用的一个技术方案是：提供一种亚麻纤维的抗菌消臭工艺，所述亚麻纤维的抗菌消臭工艺包括：将亚麻纤维放入阻燃整理剂中控制一定温度浸泡15-20min，然后置于浸轧双氧水、汽蒸的缸内氧化预处理，接着排水后入水，再置于浸轧生物酶、汽蒸的缸内生物酶处理，再排水后入水，完成亚麻纤维的前处理，然后温度直线上升到170℃，保温一定时间后，接着降到80℃后加入皂洗剂，最后排水后入水两次烘干。
在本发明一个较佳实施例中，所述浸扎的轧液率为50-100％。
在本发明一个较佳实施例中，所述阻燃整理剂包括无机磷与氮化合物的阻燃剂、三聚氰胺树脂、尿素、催化剂。
在本发明一个较佳实施例中，所述控制一定温度为10-15℃。
在本发明一个较佳实施例中，所述烘干的温度180℃。
在本发明一个较佳实施例中，所述保温一定时间为3min。
本发明的有益效果是：制备工艺简便，使用方法简单，抗菌纺织制品具有环保性，抑制细菌效果好。
具体实施方式
下面结合对本发明的较佳实施例进行详细阐述，以使本发明的优点和特征能更易于被本领域技术人员理解，从而对本发明的保护范围做出更为清楚明确的界定。
本发明实施例包括：
一种亚麻纤维的抗菌消臭工艺，所述亚麻纤维的抗菌消臭工艺包括：将亚麻纤维放入阻燃整理剂中控制一定温度浸泡15-20min，然后置于浸轧双氧水、汽蒸的缸内氧化预处理，接着排水后入水，再置于浸轧生物酶、汽蒸的缸内生物酶处理，再排水后入水，完成亚麻纤维的前处理，然后温度直线上升到170℃，保温一定时间后，接着降到80℃后加入皂洗剂，最后排水后入水两次烘干。
所述浸扎的轧液率为50-100％，所述阻燃整理剂包括无机磷与氮化合物的阻燃剂、三聚氰胺树脂、尿素、催化剂，所述控制一定温度为10-15℃，所述烘干的温度180℃，所述保温一定时间为3min。
在一实施例中，在纤维浸轧过程中，选用的柔软剂是能改善纤维手感；二是不影响染色牢度；三是能和染液中的各种助剂相配伍。浸轧采用二浴法，在浸轧焙烘后，再浸轧阳离子氨基硅油柔软剂，染色牢度略提高。
有机氮抗菌剂适用于纤维素及其混纺织物的耐久抗菌整理，它对真菌、革兰氏阳性菌、革兰氏阴性菌等具有优异的抗菌活性，对人体安全性高，无毒副作用，已广泛用于袜子、内衣、毛巾、运动服、床上用品和地毯等。亚麻织物具有卫生性能好、吸湿散热快、透气滑爽、体感舒服、凉爽吸汗不粘身、消除静电、抑菌除臭等保健功能。亚麻不但舒适透气，还具有的天然抑菌除臭功能。油画用亚麻布作底布能防虫、防蛀、防潮，作品可保存几百年。亚麻织物吸汗强、易挥发、不粘身，不发臭。亚麻纺织品是举世公认的珍贵装饰品，用亚麻纺织品作室内墙贴、窗帘、桌布和其它家具的罩垫、可以调节空气湿度和温度。用亚麻床单、枕巾，睡觉舒适。亚麻可以织制各种粗细的帆布，还可与棉、毛、丝、人造纤维混纺。亚麻纤维强人、柔细，其强度是绢丝的1.6倍，可纺支数高，织物平滑整洁，适合制作高级衣料。亚麻纤维还具有吸湿性强、散热快、耐摩擦。耐高温、不易燃、抑菌等独特优点，广泛应用于制作汽车用品。织物抗菌除臭整理剂是一种有机抗菌剂，主成份选用最为安全的胍类，是一种非溶出型抗菌剂，对于危害人体的各类细菌、真菌的生长繁殖有极强的快速杀菌作用，杀菌率大于99.9%，其抗菌原理是它破坏细菌的细胞壁，由于胞内渗透压是胞外渗透压的20-30倍，因此细胞膜破裂，胞浆物外泄。这样也就终止了微生物的代谢过程，使微生物无法生长和繁殖。适用于各种纺织物，可以赋予织物高效的抗菌除臭及耐水洗性，可达50次以上。用于纯棉、混纺、化纤、无纺布、皮革等各类织物。织物抗菌整理剂处理织物的方法可以采用浸轧、浸渍、喷涂等，一般用量为2-4%（浴比1：8，1：10），具体用量和用法根据被处理物的用途、种类、组成，及加工设备而确定。通常抗菌整理与染色采用同浴吸尽法进行加工。
本发明揭示了一种亚麻纤维的抗菌消臭工艺，制备工艺简便，使用方法简单，抗菌纺织制品具有环保性，抑制细菌效果好。
在本发明的描述中，需要说明的是，术语“上”、“下”、“左”、“右”、“内”、“外”等指示的方位或位置关系为基于所示的方位或位置关系，或者是该发明产品使用时惯常摆放的方位或位置关系，仅是为了便于描述本发明和简化描述，而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作，因此不能理解为对本发明的限制。以上所述仅为本发明的优选实施例而已，并不用于限制本发明，对于本领域的技术人员来说，本发明可以有各种更改和变化。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
以上所述仅为本发明的实施例，并非因此限制本发明的专利范围，凡是利用本发明说明书内容所作的等效结构或等效流程变换，或直接或间接运用在其他相关的技术领域，均同理包括在本发明的专利保护范围内。

Claims (6)

1.一种亚麻纤维的抗菌消臭工艺，其特征在于，所述亚麻纤维的抗菌消臭工艺包括：在去离子水中投入有机氮抗菌剂、无甲醛树脂、非离子渗透剂混合，搅拌均匀，制得整理剂，将亚麻纤维在含有整理剂的浸渍液中，浸轧一定时间，然后一定的温度下预烘，最后再经过160°焙烘一定时间，制成纤维。
2.根据权利要求1所述的亚麻纤维的抗菌消臭工艺，其特征在于，所述浸轧的轧液率为60-70％。
3.根据权利要求1所述的亚麻纤维的抗菌消臭工艺，其特征在于，所述有机氮抗菌剂的重量为3-5g、无甲醛树脂的重量为30-40g、非离子渗透剂的重量为0.5g。
4.根据权利要求1所述的亚麻纤维的抗菌消臭工艺，其特征在于，所述浸轧一定时间为20-30min。
5.根据权利要求1所述的亚麻纤维的抗菌消臭工艺，其特征在于，所述烘干的温度110℃。
6.根据权利要求1所述的亚麻纤维的抗菌消臭工艺，其特征在于，所述焙烘一定时间为1.5min。
CN201911149632.3A 2019-11-21 2019-11-21 一种亚麻纤维的抗菌消臭工艺 Withdrawn CN110835853A (zh)

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Application publication date: 20200225

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