CN110799699A

CN110799699A - Steel cord for reinforcing rubber article

Info

Publication number: CN110799699A
Application number: CN201880042677.8A
Authority: CN
Inventors: 尾花直彦
Original assignee: Bridgestone Corp
Current assignee: Bridgestone Corp
Priority date: 2017-06-30
Filing date: 2018-06-28
Publication date: 2020-02-14
Anticipated expiration: 2038-06-28
Also published as: AU2018291351B2; US11352744B2; EP3647487A4; EP3647487A1; WO2019004393A1; JP6936059B2; US20200131699A1; CN110799699B; JP2019011536A; AU2018291351A1

Abstract

Provided is a steel cord for reinforcing rubber articles, which has improved corrosion resistance without increasing the weight thereof. The steel cord 1 for reinforcing rubber goods comprises a plurality of sheath strands 3 twisted around at least one core strand 2 having a plurality of steel filaments twisted therein, said sheath strands 3 comprising a plurality of steel filaments twisted therein. The core strand 2 and the sheath strand 3 include at least one core filament 2c, 3c, and a plurality of sheath filaments 2s, 3s wound therein. Satisfying the relationship expressed by the formula (1), dcc > dcs > dsc > dss, wherein the core filament 2c of the core strand 2 has a wire diameter dcc, the sheath filament 2s has a wire diameter dcs, the core filament 3c of the sheath strand 3 has a wire diameter dsc, and the sheath filament 3s has a wire diameter dss.

Description

Steel cord for reinforcing rubber article

Technical Field

The present invention relates to a steel cord for reinforcing a rubber article (hereinafter, also simply referred to as "steel cord"), more particularly a steel cord for reinforcing a rubber article in which corrosion resistance is improved without increasing weight.

Background

In rubber articles such as conveyor belts and tires, a steel cord obtained by twisting a plurality of steel wires (hereinafter, also simply referred to as "wires") together is generally used as a reinforcing material. Many solutions have been proposed with respect to such steel cords.

For example, patent document 1 proposes a steel cord having a double-twisted structure in which two core filaments are used in a core strand and the diameter of the outermost sheath filament of each sheath strand is controlled to be larger than the diameter of the filament inside the outermost sheath of the sheath strand, thereby improving cut resistance while avoiding an increase in the diameter and weight of the steel cord. In addition, patent document 2 proposes a steel cord having a double twist structure in which a ratio (dc/ds) between a diameter (dc) of a sheath filament of a core strand and a diameter (ds) of a sheath filament of an outermost layer of the sheath strand is controlled to be greater than 1.25 and 1.50 or less, thereby improving cut resistance while maintaining an amount of steel. Further, patent document 3 proposes a steel cord having a double-twisted structure in which a plurality of strands each having a layer-twisted structure composed of a core composed of two or three core filaments and at least one sheath layer are twisted together, wherein gaps between sheath filaments constituting the outermost layer of the strands are controlled to be 0.5 to 4.0% of the diameter of the outermost layer sheath filament 13, thereby suppressing the occurrence of premature breakage of the outermost layer filament.

Still further, patent document 4 proposes a steel cord composed of a single core strand having a layer twist structure and a plurality of sheath strands each having a layer twist structure, in which the rust resistance, cord strength and shear resistance are improved by controlling the average size of gaps between outermost sheath filaments of the core strand to 0.073 to 0.130mm and setting the number of outermost sheath filaments to 7 to 10. Further, patent document 5 proposes a steel cord having a (2+ M + N) structure in which filaments having a prescribed wire diameter are used for each layer and twisted together at a prescribed twist pitch, and the amount of the filler rubber is controlled to a prescribed level, thereby improving productivity and fatigue corrosion resistance. In addition, patent document 6 proposes a steel cord obtained by twisting together a plurality of strands each having an outermost filament and an inner filament, in which adhesiveness to rubber is improved by performing a brass plating treatment on the outermost filament of each outermost strand constituting the outer circumferential portion and performing a zinc plating treatment on at least one filament located further inside the outermost strand.

Documents of the prior art

Patent document

[ patent document 1] JP 2016-

[ patent document 2] JP 2016 30863A

[ patent document 3] JP 2009-108460A

[ patent document 4] WO 2016/017654

[ patent document 5] WO 2011/000950

[ patent document 6] JP 2011-202291A

Disclosure of Invention

Problems to be solved by the invention

Steel cords for conveyor belts are typically coated with zinc. The reason for this is that even when rainwater or the like reaches the wire through cutting or the like caused by the conveyed matter on the conveyor belt, corrosion of the wire can be delayed by allowing plated zinc to corrode in preference to the wire. However, even without such zinc plating, as long as rubber intrudes into the inside of the steel cord (this characteristic is hereinafter also simply referred to as "rubber penetration"), water does not reach the filaments first, which is preferable in terms of corrosion resistance.

However, the ease of intrusion of rubber into the interior of the steel cord means that the steel cord has a large gap therein, and in this case, the occupancy of the filaments with respect to the cord circumscribed circle is reduced, resulting in a corresponding reduction in strength. Therefore, to ensure strength, the wire diameter is increased; however, this results in deterioration of rubber permeability and an increase in the weight of the cord. In general, these problems have not been sufficiently studied for a steel cord having a double-twisted structure, and there is still room for further improvement.

In view of the above, an object of the present invention is to provide a steel wire for reinforcing a rubber article, in which corrosion resistance is improved without increasing weight.

Means for solving the problems

The present inventors have intensively studied to solve the above-described problems, and as a result, have found that the above-described problems can be solved by controlling the diameters of filaments constituting a steel cord having a double twist structure to satisfy a prescribed relationship, thereby completing the present invention.

That is, the steel cord for reinforcing a rubber article according to the present invention is a steel cord for reinforcing a rubber article in which a plurality of sheath strands each formed by twisting a plurality of steel wires together are twisted together around at least one core strand formed by twisting a plurality of steel wires together,

the rubber article-reinforcing cord is characterized in that

The core strand and the sheath strand are each formed by twisting together one or two core filaments and a plurality of sheath filaments, and

when the wire diameter of the core filament of the core strand, the wire diameter of the sheath filament of the core strand, the wire diameter of the core filament of the sheath strand, and the wire diameter of the sheath filament of the sheath strand are defined as dcc, dcs, dsc, and dss, respectively, a relationship represented by the following equation (1) is satisfied:

dcc>dcs≥dsc>dss (1)。

in the steel cord of the present invention, it is preferable that when the tensile strength of the core filament of the core strand, the tensile strength of the sheath filament of the core strand, the tensile strength of the core filament of the sheath strand, and the tensile strength of the sheath filament of the sheath strand are defined as Tcc, Tcs, Tsc, and Tss, respectively, a relationship represented by the following formula (2) is satisfied:

Tss>Tsc≥Tcs>Tcc (2)。

in the steel cord of the present invention, it is also preferable that the tensile strength t (mpa) of the steel wire satisfies a relationship represented by the following formula:

(-2,000×d+3,825)≤T<(-2,000×d+4,525)。

further, in the steel cord of the present invention, it is preferable that the diameter (d) of the steel wire is 0.3 to 0.8 mm. Still further, in the steel cord of the present invention, it is preferable that an average gap between adjacent sheath filaments in the same sheath filament layer of the core strand is 35 to 76 μm, and an average gap between adjacent sheath filaments in the same sheath filament layer of the sheath strand is 20 to 76 μm.

Still further, in the steel cord of the present invention, it is preferable that the core filaments of the core strand and the core filaments of the sheath strand are not twisted, and a minor axis/major axis ratio of the core strand and the sheath strand in a cross-sectional view taken along a direction perpendicular to a longitudinal direction of the strand is 0.7 to 0.85. Still further, in the steel cord of the present invention, the core strand and the sheath strand have a (2+ m) structure or a (2+ m + n) structure, and these strands may be suitably applied to a steel cord, where m is 8 to 9 and n is 14 to 15. Still further, in the steel cord of the present invention, it is preferable that when the core strand includes two or more sheath filament layers, the diameter (dcs) of the sheath filament is smaller in the sheath filament layer on the outside in the strand radial direction, and when the sheath strands each include two or more sheath filament layers, the diameter (dss) of the sheath filament is smaller in the sheath filament layer on the outside in the strand radial direction.

Still further, in the steel cord of the present invention, it is preferable that when the core strand and the sheath strand each include two or more sheath filament layers, an average gap between adjacent sheath filaments of the sheath filament layer on the outer side in the strand radial direction is larger than an average gap between adjacent sheath filaments of the sheath filament layer on the inner side in the strand radial direction. Still further, in the steel cord of the present invention, it is preferable that a ratio between a major axis of the sheath strand and a major axis of the core strand (major axis of the sheath strand: major axis of the core strand) is 100:105 to 130. Still further, the steel cord of the present invention preferably has a minor axis/major axis ratio of 0.80 to 0.95 in a cross-sectional view taken along a direction perpendicular to a longitudinal direction of the steel cord.

Still further, in the steel cord of the present invention, it is preferable that brass plating and zinc plating are sequentially performed on the steel wire. Still further, in the steel cord of the present inventionPreferably, when the diameter of the steel wire is defined as d, the amount of brass plating (g/m) attached to the steel wire²) Is 6d to 10d, and the amount of the zinc plating (g/m) attached to the steel wire²) Is 25 d-95 d. The steel cord of the present invention can be suitably used for reinforcing a conveyor.

ADVANTAGEOUS EFFECTS OF INVENTION

According to the present invention, it is possible to provide a steel cord for reinforcing a rubber article in which corrosion resistance is improved without increasing weight.

Drawings

Fig. 1 is a sectional view showing a steel cord for reinforcing a rubber article according to a preferred embodiment of the present invention.

Fig. 2 is a sectional view showing a steel cord for reinforcing a rubber article according to another preferred embodiment of the present invention.

Fig. 3 is a sectional view showing a steel cord for reinforcing a rubber article according to still another preferred embodiment of the present invention.

Fig. 4 is a sectional view showing a steel cord for reinforcing a rubber article according to still another preferred embodiment of the present invention.

Fig. 5 is a sectional view showing a steel cord for reinforcing a rubber article according to still another preferred embodiment of the present invention.

Detailed Description

The steel cord for reinforcing rubber articles of the present invention will now be described in detail with reference to the accompanying drawings. Fig. 1 is a sectional view showing a steel cord for reinforcing a rubber article according to a preferred embodiment of the present invention. The steel cord 1 of the present invention has a double-twisted structure in which a plurality of sheath strands 3 each formed by twisting a plurality of steel wires together are twisted together around at least one core strand 2 formed by twisting a plurality of steel wires together. The core strand 2 and the sheath strand 3 are each formed by twisting together one or two core filaments and a plurality of sheath filaments. The illustrated steel cord 1 has a (2+8) +6 × (2+8) structure in which six sheath strands 3 are twisted together around a single core strand 2, and the core strand 2 and the sheath strands 3 are each composed of a core in which two

core filaments

2c or 3c are arranged in parallel without being twisted together, and eight

sheath filaments

2s or 3s twisted together around the core.

In the steel cord 1 of the present invention, the reason why the core of each of the core strand 2 and the sheath strand 3 is composed of one or two core filaments is that, when the core is composed of three or more core filaments, corrosion resistance cannot be obtained in some cases because gaps, into which rubber does not intrude, are formed in the core.

In the steel cord 1 of the present invention, when the wire diameter of the core filament 2c of the core strand 2, the wire diameter of the sheath filament 2s of the core strand 2, the wire diameter of the core filament 3c of the sheath strand 3, and the wire diameter of the sheath filament 3s of the sheath strand 3 are defined as dcc, dcs, dsc, and dss, respectively, a relationship represented by the following formula (1) is satisfied:

dcc>dcs≥dsc>dss (1)。

in other words, the rubber penetration is improved by reducing the diameter of the filaments constituting the steel cord 1 toward the outside in the cord radial direction.

In the steel cord of the present invention, when the core strand and the sheath strand each have two sheath filament layers, the relationship represented by the following formula (3) is satisfied (where the wire diameter of the first sheath filament of the core strand is dcs1, the wire diameter of the second sheath filament of the core strand is dcs2, the wire diameter of the first sheath filament of the sheath strand is dss1, and the wire diameter of the second sheath filament of the sheath strand is dss 2):

dcc>dcs1>dcs2≥dsc>dss1>dss2 (3)。

when the core strand or each sheath strand has two sheath filament layers, dcs2 or dss2 of strands having a single sheath filament layer may be excluded from formula (3) above.

In the steel cord 1 of the present invention, it is preferable that when the tensile strength of the core filaments 2c of the core strand 2, the tensile strength of the sheath filaments 2s of the core strand 2, the tensile strength of the core filaments 3c of the sheath strand 3, and the tensile strength of the sheath filaments 3s of the sheath strand 3 are defined as Tcc, Tcs, Tsc, and Tss, respectively, a relationship represented by the following formula (2) is satisfied:

Tss>Tsc≥Tcs>Tcc (2)。

in other words, the tensile strength T of the filaments constituting the steel cord 1 toward the cord radial direction outer side increases. When a bending input is applied to the steel cord 1, a larger input is added to the filaments located radially outside the cord. Therefore, in the steel cord 1 of the present invention, fatigue durability is improved by increasing the tensile strength T of the filaments constituting the steel cord 1 toward the cord radial direction outer side.

In the steel cord 1 of the present invention, it is preferable that the tensile strength t (mpa) of the steel wire satisfies a relationship represented by the following formula:

(-2,000×d+3,825)≤Ts<(-2,000×d+4,525)。

by controlling the tensile strength T to (-2,000 Xd +3,825) or more, a weight reduction effect can be obtained, and since this tensile strength T allows the use of a filament, the resistance to repeated bending fatigue is improved. On the other hand, a tensile strength T of (-2,000 Xd +4,525) or more may impair drawing processability and thus there is a problem in productivity of the wire. In the steel cord 1 of the present invention, the filaments preferably have a diameter (d) in the range of 0.3 to 0.8 mm. The reason for this is that when the diameter (d) of the filament is less than 0.3mm, the desired strength cannot be obtained in some cases, and when the diameter (d) is more than 0.8mm, the desired tensile strength cannot be obtained in some cases.

In the steel cord 1 of the present invention, it is preferable that the average gap Gc between the adjacent sheath filaments 2s in the same sheath filament layer of the core strand 2 is 35 to 76 μm, and the average gap Gs between the adjacent sheath filaments 3s in the same sheath filament layer of the sheath strand 3 is 20 to 76 μm. When the average gaps Gc and Gs between the sheath filaments 2s and between the sheath filaments 3s are each smaller than the above-described respective ranges, the rubber is difficult to intrude into the steel cord 1, which is not preferable. Meanwhile, when the average gaps Gc and Gs between the sheath filaments 2s and between the sheath filaments 3s are each larger than the above-described respective ranges, the proportion of steel in the circumscribed circle of the cord is reduced, whereby the cord strength is reduced. Therefore, in order to ensure the strength of the cord, it is necessary to increase the diameter of the filaments; however, this results in an increase in the cord diameter and an increase in the thickness of the coating rubber, which is disadvantageous in terms of lightness.

Further, in the steel cord 1 of the present invention, it is preferable that, as shown in fig. 1, the core filaments 2c of the core strand 2 and the core filaments 3c of the sheath strand 3 are not twisted, and the core strand 2 and the sheath strand 3 have a minor axis/major axis ratio of 0.7 to 0.85 in a cross-sectional view taken along a direction perpendicular to the longitudinal direction of the strands. In other words, the cross section of the strand in the direction perpendicular to the longitudinal direction is flattened. When the short axis/long axis ratio is less than 0.7, since the gaps Gc and Gs between the sheath filaments in the same sheath filament layer are reduced, the rubber permeability is deteriorated. Meanwhile, when the minor axis/major axis ratio is more than 0.85, since the cross section of the strands in the direction perpendicular to the length direction is close to a circle, the cord diameter increases, which is disadvantageous in terms of lightness.

Still further, in the steel cord 1 of the present invention, it is preferable that when the core strand 2 has two or more sheath filament layers, the diameter (dcs) of the sheath filament in the sheath filament layer on the radially outer side of the strand is small. By adopting this constitution, the rubber permeability is improved, and therefore, the effect of the present invention can be obtained well. Similarly, it is preferable that when the sheath strands 3 each have two or more sheath filament layers, the diameter (dss) of the sheath filaments 3s in the sheath filament layer radially outside the strand is smaller.

Still further, in the steel cord 1 of the present invention, it is preferable that when the core strand and the sheath strand each have two or more sheath filament layers, an average gap between adjacent sheath filaments of the sheath filament layer on the outer side in the strand radial direction is larger than an average gap between adjacent sheath filaments of the sheath filament layer on the inner side in the strand radial direction. Also, as described above, by adopting this constitution, the rubber permeability is improved, and therefore, the effect of the present invention can be obtained well.

In the steel cord 1 of the present invention, as shown in fig. 1, the ratio between the long axis of the sheath strand 3 and the long axis of the core strand 2 (long axis of the sheath strand 3: long axis of the core strand 2) is preferably 100:105 to 130. When the above ratio is less than 105, the core strand 2 and the sheath strand 3 have substantially the same diameter; therefore, the gaps between the sheath strands 3 in the same sheath strand layer are reduced, resulting in deterioration of rubber permeability. Meanwhile, when the above ratio is more than 130, the cord diameter must be increased in order to obtain the required strength, which results in an increase in the thickness of the coating rubber, which is disadvantageous in terms of lightness.

Further, as shown in fig. 1, the steel cord 1 of the present invention preferably has a minor axis/major axis ratio of 0.80 to 0.95 in a cross-sectional view taken along a direction perpendicular to the longitudinal direction of the steel cord. When the above ratio is less than 0.80, the steel cord 1 is too flat; the gaps between the sheath strands 3 in the same sheath strand layer are reduced, resulting in deterioration of rubber permeability. Meanwhile, when the above ratio is more than 0.95, since the steel cord 1 is close to a circular shape, the thickness of the coating rubber increases, which is disadvantageous in terms of lightness.

In the steel cord 1 of the present invention, it is preferable that brass plating and zinc plating are sequentially performed on the wire. This configuration allows zinc plating to corrode preferentially to the wire, and therefore, corrosion of the wire can be retarded. In addition, zinc plating does not inhibit adhesion to rubber. For the production of such a wire, it is preferable to subject a brass-plated steel wire rod to a drawing process and then zinc plating thereon. The reason for this is that, when wire drawing is performed on a galvanized steel wire rod, for example, the falling off of the galvanization and the abrasion of the die occur, and the productivity is thereby deteriorated. Therefore, by performing zinc plating after the drawing process, a decrease in the drawing speed of the steel wire rod is suppressed, so that problems such as peeling of the plating layer and abrasion of the die can be avoided. In particular, by introducing a zinc plating process for zinc plating before or after the strand twisting process, it is possible to simultaneously plate a plurality of filaments with zinc, which is preferable.

The zinc plating step is preferably performed by electroplating. In the molten zinc plating, which is general zinc plating, since the plating treatment is performed by dipping the wire in molten zinc at 450 ℃ or higher, the strength of the wire is significantly reduced when the strength of the wire is 2,500MPa or higher. Therefore, in the manufacturing method of the present invention, this problem can be avoided by performing the zinc plating process by electroplating.

In the steel cord 1 of the present invention, it is preferable that the amount of brass plating (g/m) attached to the steel wire when the diameter of the steel wire is defined as d²) 6d to 10d, and the amount of zinc plating (g/m) attached to the steel wire²) Is 25 d-95 d. When the amount of brass plating is less than 6d, wire drawingThe processability is deteriorated, which is not preferable. Meanwhile, when the amount is more than 10d, productivity is lowered, which is disadvantageous and thus not preferable from the viewpoint of economy. Further, when the adhesion amount of zinc plating is less than 25d, corrosion resistance may deteriorate, which is not preferable, and when the amount is more than 95d, which is not preferable from the viewpoint of economy due to reduction in productivity.

The method of performing brass plating on the steel wire rod is not particularly limited, and the brass plating layer may be formed by plating copper and zinc in sequence followed by a thermal diffusion treatment, or by plating copper and zinc simultaneously.

In the steel cord 1 of the present invention, other configurations are not particularly limited as long as the above-described configuration is satisfied. Fig. 2 to 5 each show a cross-sectional view of a steel cord for reinforcing a rubber article according to other preferred embodiments of the present invention.

The steel cord 11 shown in fig. 2 has a structure in which six sheath strands 13 are wound around a single core strand 12, and the core strand 12 and the sheath strands 13 are each formed by twisting together six sheath filaments 12s or 13s around a single core filament 12c or 13 c. The steel cord 21 shown in fig. 3 has a structure in which six sheath strands 23 are wound around a single core strand 22, and the core strand 22 and the sheath strands 23 are each formed by twisting eight

sheath filaments

22s or 23s together around a core in which two

core filaments

22c or 23c are twisted together. The steel cord 31 shown in fig. 4 has a structure in which six sheath strands 33 are wound on a single core strand 32, and the core strand 32 and the sheath strands 33 are each formed by twisting six

sheath filaments

32s or 33s together around a

single core filament

32c or 33c, and further twisting twelve

sheath filaments

32s or 33s together thereon. The steel cord 41 shown in fig. 5 has a structure in which six sheath strands 43 are wound on a single core strand 42, and the core strand 42 and the sheath strands 43 are each formed by twisting eight

sheath filaments

42s or 43s together around a core in which two

core filaments

42c or 43c are twisted together, and further twisting fourteen

sheath filaments

42s or 43s together thereon.

In the steel cord of the present invention, a (2+ m) structure or a (2+ m + n) structure is preferable, where m is 8 to 9 and n is 14 to 15, which can successfully produce the effects of the present invention. In the steel cord of the present invention, the twist pitch and twist direction of the core filaments and the sheath filaments constituting the respective strands may be appropriately selected according to a conventional method. Further, the twisting direction, the twisting pitch, and the like of the strands are also not particularly limited, and may be appropriately selected according to a conventional method.

As the filaments used in the steel cord 1 of the present invention, any conventionally used filaments may be selected; however, the wire is preferably made of a high carbon steel containing a carbon component of 0.80 mass% or more. By using a high-carbon steel containing 0.80 mass% or more of a carbon component with high hardness as a material of the wire, a reinforcing effect of a rubber article such as a tire or a conveyor belt can be sufficiently obtained. Meanwhile, a carbon component content higher than 1.5% is not preferable, since it reduces ductility and is deteriorated due to fatigue resistance.

The use of the steel cord 1 of the present invention is not particularly limited, and the steel cord 1 of the present invention can be widely used for various rubber products and parts, for example, automobile tires and industrial belts such as dynamic conveyor belts and conveyor belts, as well as rubber crawler belts, hoses, and vibration-isolating rubber supports. Among them, the steel cord 1 of the present invention can be particularly suitably used as a reinforcing material for a conveyor belt which is liable to suffer from cutting damage.

Examples

The invention will now be described in more detail by means of examples thereof.

< conventional examples, comparative examples 1 to 3 and examples 1 to 9>

Steel cords each having a structure shown in tables 1 to 4 were produced. As the steel wire rod, a steel wire rod having a wire diameter of 1.86 to 2.62mm, which is obtained by wire drawing and patenting a piano wire rod having a diameter of 5.5mm and a carbon content of 0.82 mass%, is used. The steel wire rod was subjected to wire drawing processing again to obtain wires having various wire diameters. Thereafter, the filaments thus obtained are twisted together to form strands, and the strands are plated with zinc by electroplating and further twisted together to obtain a steel cord. In example 4, a steel wire rod was patented and then plated with copper and zinc, followed by thermal diffusion and brass plating, after which the steel wire rod was wire-drawn again to obtain a wire having a prescribed wire diameter. The filaments thus obtained are subsequently twisted together to form strands, and these strands are plated with zinc by electroplating and further twisted together to obtain steel cords.

For each of the thus obtained steel cords, rubber penetration, corrosion resistance, cord weight, and repeated bending fatigue resistance were evaluated. Rubber penetration, corrosion resistance, cord weight, and repeated bending fatigue resistance were tested by the following methods.

< rubber Permeability >

Each of the steel cords was embedded in unvulcanized rubber and then vulcanized at 145 ℃ for 45 minutes to prepare an evaluation sample, and the state of rubber intrusion was evaluated by observing the section of the steel cord in the sample, when rubber intrudes into the center portion of the core strand, an evaluation of "○" was given, and when rubber does not intrude into the center portion of the core strand, an evaluation of "X" was given, the results of which are also shown in tables 1 to 4.

< Corrosion resistance test >

The steel cords were each arranged in parallel to each other at an interval of 2.0mm, and then coated with rubber sheets from upper and lower sides, and the resultant was vulcanized at 145 ℃ for 40 minutes to prepare evaluation samples. From the thus obtained sample, a steel cord cut in a length of 200mm was taken out and then immersed in a neutral aqueous solution containing a small amount of nitrate ions and sulfate ions. 300N/mm²Is repeatedly applied to the steel cord at a speed of 1,000 rpm, and the number of revolutions required for the steel cord to break is measured. The spin number was measured to be 1,000,000. The results thus obtained are expressed exponentially. The measured value of the steel cord of example 1 was taken as 100. The results are also shown in tables 1 to 4.

< cord weight >

The weight per 1m of each steel cord was measured and expressed as an index, and the value of the steel cord of example 1 was taken as 100. The results are also shown in tables 1 to 4.

< repeated flexural fatigue resistance >

The steel cords were arranged in parallel to each other at intervals of 2.0mm each, and then coated with rubber sheets from the upper and lower sides, and the resultant was vulcanized at 145 ℃ for 40 minutes. For a sample prepared by cutting out a bundle of three cords after vulcanization, a fatigue test was conducted in which the sample was passed through a pulley having a diameter of 50mm and vertically driven at a tension of 8.0% of the strength of the applied cord, and the number of repeated vertical movements required for the sample to break was measured and expressed by an index, and the measured value of the steel cord of example 1 was taken as 100. The results are also shown in tables 1 to 4.

[ Table 1]

^*1: average gap between adjacent sheath filaments

^*2: (average of core strand and sheath strand)

[ Table 2]

[ Table 3]

[ Table 4]

As seen from tables 1 to 4, in the steel cord according to the present invention, corrosion resistance is improved without increasing weight. Note here, however, in example 3, since the strands are not double-twisted cords but triple-twisted cords, the cord strength is higher, and the cord diameter and the cord weight are larger than those of example 1.

Description of the reference numerals

1. 11, 21, 31, 41: steel cord

2. 12, 22, 32, 42: core strand

2c, 12c, 22c, 32c, 42 c: core wire

2s, 12s, 22s, 32s, 42 s: sheath filament

3. 13, 23, 33, 43: sheath strand

3c, 13c, 23c, 33c, 43 c: core wire

3s, 13s, 23s33s, 43 s: sheath filament

Claims

1. A steel cord for reinforcing rubber articles, wherein a plurality of sheath strands each formed by twisting a plurality of steel wires together are twisted together around at least one core strand formed by twisting a plurality of steel wires together,

wherein

dcc>dcs≥dsc>dss (1)。

2. the steel cord for reinforcing rubber articles according to claim 1, wherein when the tensile strength of the core filament of the core strand, the tensile strength of the sheath filament of the core strand, the tensile strength of the core filament of the sheath strand, and the tensile strength of the sheath filament of the sheath strand are defined as Tcc, Tcs, Tsc, and Tss, respectively, a relationship represented by the following formula (2) is satisfied:

Tss>Tsc≥Tcs>Tcc (2)。

3. the steel cord for reinforcing rubber articles according to claim 1 or 2, wherein the tensile strength t (mpa) of the steel wire satisfies the relationship represented by the following formula:

(-2,000×d+3,825)≤T<(-2,000×d+4,525)。

4. the steel cord for reinforcing rubber articles according to any one of claims 1 to 3, wherein the diameter (d) of the steel wire is 0.3 to 0.8 mm.

5. The steel cord for reinforcing rubber articles according to any one of claims 1 to 4, wherein

The average gap between adjacent sheath filaments in the same sheath filament layer of the core strand is 35 to 76 [ mu ] m, and

the average gap between adjacent sheath filaments in the same sheath filament layer of the sheath strand is 20-76 [ mu ] m.

6. The steel cord for reinforcing rubber articles according to any one of claims 1 to 5, wherein

The core filaments of the core strand and the core filaments of the sheath strand are not twisted, and

the core strand and the sheath strand have a minor axis/major axis ratio of 0.7 to 0.85 in a cross-sectional view taken in a direction perpendicular to the longitudinal direction of the strands.

7. The steel cord for rubber article reinforcement according to any one of claims 1 to 6, wherein the core strand and the sheath strand have a (2+ m) structure or a (2+ m + n) structure, wherein m is 8 to 9 and n is 14 to 15.

8. The steel cord for reinforcing rubber article according to any one of claims 1 to 7, wherein

When the core strand comprises two or more sheath filament layers, the diameter (dcs) of the sheath filaments in the sheath filament layers radially outside the strand is smaller, and

when the sheath strands each include two or more sheath filament layers, the diameter (dss) of the sheath filaments in the sheath filament layers radially outside the strands is smaller.

9. The rubber article-reinforcing steel cord according to any one of claims 1 to 8, wherein when each of the core strand and the sheath strand includes two or more sheath filament layers, an average gap between adjacent sheath filaments of the sheath filament layer on a radially outer side of the strand is larger than an average gap between adjacent sheath filaments of the sheath filament layer on a radially inner side of the strand.

10. The steel cord for rubber article reinforcement according to any one of claims 1 to 9, wherein a ratio between a long axis of the sheath strand and a long axis of the core strand (long axis of the sheath strand: long axis of the core strand) is 100:105 to 130.

11. The steel cord for reinforcing rubber articles according to any one of claims 1 to 10, having a minor axis/major axis ratio of 0.80 to 0.95 in a cross-sectional view taken along a direction perpendicular to a longitudinal direction of the steel cord.

12. The steel cord for reinforcing rubber articles according to any one of claims 1 to 11, wherein brass plating and zinc plating are sequentially performed on the steel wire.

13. The steel cord for reinforcing rubber articles according to any one of claims 1 to 12, wherein the amount of brass plating (g/m) attached to the steel wire when the diameter of the steel wire is defined as d²) Is 6d to 10d, and the amount of the zinc plating (g/m) attached to the steel wire²) Is 25 d-95 d.

14. The steel cord for reinforcing rubber articles according to any one of claims 1 to 13, which is used for a conveyor.