CN110790583A - High-strength ultra-light fireproof green heat insulation board, preparation method thereof and wall system - Google Patents

High-strength ultra-light fireproof green heat insulation board, preparation method thereof and wall system Download PDF

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CN110790583A
CN110790583A CN201810869952.5A CN201810869952A CN110790583A CN 110790583 A CN110790583 A CN 110790583A CN 201810869952 A CN201810869952 A CN 201810869952A CN 110790583 A CN110790583 A CN 110790583A
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weight
insulation board
thermal insulation
water
palm
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刘钊锦
周颂刚
樊勇
沈文龙
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Palmeco Tech Ltd
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Palmeco Tech Ltd
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Priority to CN201810869952.5A priority Critical patent/CN110790583A/en
Priority to CN201980037141.1A priority patent/CN112292362A/en
Priority to PCT/CN2019/090983 priority patent/WO2020024704A1/en
Priority to PCT/CN2019/098572 priority patent/WO2020024975A1/en
Priority to CN201980037009.0A priority patent/CN112313185A/en
Publication of CN110790583A publication Critical patent/CN110790583A/en
Priority to PH12021550219A priority patent/PH12021550219A1/en
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Abstract

本申请公开了一种高强度重量超轻防火绿色隔热保温板,所述防火绿色隔热保温板由水和其他原料制备而成,其中基于除水以外的原料的重量,所述原料含有0.1‑10重量%的棕榈纤维,并且其中所述棕榈纤维的纤维长度范围为2mm至15mm。本申请还公开了一种使用本申请的防火绿色隔热保温板的墙身系统。本申请还公开了所述的高强度超轻防火绿色隔热保温板的环保制备方法。本发明的防火绿色隔热保温板能够兼顾多种优异性能:密度≤180kg/m3、导热系数≤0.055W/mK、压缩强度≥0.3MPa、燃烧性能符合A1标准,且吸水率≤10%。本申请墙身系统具有良好的隔音及防火性能。并且其生产方法成本低节能环保。The present application discloses a high-strength and light-weight fireproof green thermal insulation board prepared from water and other raw materials, wherein based on the weight of the raw materials other than water, the raw materials contain 0.1 -10 wt% palm fibers, and wherein the palm fibers have a fiber length ranging from 2mm to 15mm. The present application also discloses a wall body system using the fireproof green thermal insulation board of the present application. The present application also discloses an environment-friendly preparation method of the high-strength ultra-light fireproof green thermal insulation board. The fireproof green thermal insulation board of the present invention can take into account various excellent properties: density≤180kg/m 3 , thermal conductivity≤0.055W/mK, compressive strength≥0.3MPa, combustion performance conforming to A1 standard, and water absorption rate≤10%. The wall system of the present application has good sound insulation and fire performance. And the production method has low cost, energy saving and environmental protection.

Description

高强度超轻防火绿色隔热保温板及其制备方法、墙身系统High-strength ultra-light fireproof green thermal insulation board and its preparation method, wall system

技术领域technical field

本发明涉及一种防火隔热保温板、及其制备方法和包括其的墙身系统。更具体地,本发明涉及一种高强度重量超轻防火绿色隔热保温板,及其环保制备方法和包括其的墙身系统。The present invention relates to a fireproof thermal insulation board, a preparation method thereof, and a wall body system including the same. More specifically, the present invention relates to a high-strength, ultra-lightweight, fire-proof green thermal insulation board, an environmental protection preparation method thereof, and a wall system including the same.

背景技术Background technique

以往建筑上安装的保温材料一般都是由轻质低成本有机材料制成的,例如发泡聚苯乙烯(Expanded polystyrene,EPS)、挤塑聚苯乙烯泡沫(Extruded polystyrene foam,XPS)、聚氨酯(polyurethane,PU)等。这类材料很受欢迎,因为它易于获得且具有成本竞争力。然而,这类材料的使用具有破坏性的后果。由于它们对火和热的耐受性非常弱,因此在点燃时,其顺燃速度极快,会释放出有毒气体。事实上,这类材料的使用是中国主要城市和世界各地发生重大火灾事故的原因,导致严重的生命损失。Insulation materials installed on buildings in the past are generally made of lightweight and low-cost organic materials, such as expanded polystyrene (EPS), extruded polystyrene foam (XPS), polyurethane ( polyurethane, PU) and so on. This type of material is popular because it is readily available and cost-competitive. However, the use of such materials has devastating consequences. Since they are very resistant to fire and heat, when ignited, they burn down extremely quickly, releasing toxic gases. In fact, the use of such materials is the cause of major fire accidents in major Chinese cities and around the world, resulting in serious loss of life.

鉴于此,中国政府以及国际上包括阿联酋(迪拜)、沙特阿拉伯、澳大利亚等国家的监管当局,对建筑物中使用的隔热材料实行了严格规定,必须根据不同国家或地区的当地建筑法规进行不可燃性测试。以中国为例,中国有关部门规定建筑物保温材料的燃烧性能必须达到GB 8624-2012规定的A级水平。依照中国国家标准《建筑材料及制品燃烧性能分级》(GB8624-2012),建筑材料的燃烧性能分为:A级-不燃材料(制品);B1级-难燃材料(制品);B2级-可燃材料(制品);和B3级-易燃材料(制品)。并且其中对平板状建筑材料及制品的燃烧性能的A级又进一步划分为A1级和A2级。In view of this, the Chinese government and international regulatory authorities including the United Arab Emirates (Dubai), Saudi Arabia, Australia and other countries have implemented strict regulations on the thermal insulation materials used in buildings, which must be carried out according to the local building regulations of different countries or regions. Flammability test. Taking China as an example, the relevant Chinese authorities stipulate that the combustion performance of building insulation materials must reach the A-level level stipulated in GB 8624-2012. According to the Chinese national standard "Classification of Combustion Performance of Building Materials and Products" (GB8624-2012), the combustion performance of building materials is divided into: Class A - non-combustible materials (products); Class B1 - flame retardant materials (products); Class B2 - flammable Materials (Articles); and Class B3 - Flammable Materials (Articles). And the class A of the combustion performance of flat building materials and products is further divided into class A1 and class A2.

目前能够满足A级标准的隔热材料一般都是无机材料。质量好且性能更高的无机隔热材料的价格非常高,这就解释了为什么它们不那么流行的原因。At present, the thermal insulation materials that can meet the A-level standards are generally inorganic materials. The price of good quality and higher performance inorganic insulation materials is very high, which explains why they are not as popular.

然而,在物理性能方面,无机隔热保温材料具有强度低、质地脆、吸水率高、密度大的常见问题。通常使用这类材料很不方便,因为它们需要在施工现场混合或填充,在现场产生碎片,并因此产生填埋的负担。However, in terms of physical properties, inorganic thermal insulation materials have common problems of low strength, brittle texture, high water absorption and high density. The use of such materials is often inconvenient because they need to be mixed or filled at the construction site, creating debris on site and thus creating a landfill burden.

诸如水泥、陶瓷、泡沫玻璃和珍珠岩的无机材料自身生产过程不环保,并且能耗高,是碳排放的主要来源。例如水泥需要煅烧,珍珠岩需要焙烧,陶瓷需要烧制,泡沫玻璃也需要高耗能生产。Inorganic materials such as cement, ceramics, foam glass and perlite are not environmentally friendly in their own production processes, and are energy-intensive, which is a major source of carbon emissions. For example, cement needs to be calcined, perlite needs to be fired, ceramics need to be fired, and foam glass needs to be produced with high energy consumption.

综上所述,现有技术满足A级标准的保温材料制成的防火隔热保温板存在能耗高、污染大、成本高、强度低、质地脆、吸水率高、密度大施工不便的缺点,亟需一种种生产成本低、高强度、超轻且环保的防火隔热保温板。To sum up, the fireproof thermal insulation board made of the thermal insulation material that meets the A-level standard in the prior art has the disadvantages of high energy consumption, high pollution, high cost, low strength, brittle texture, high water absorption rate, and high density, which is inconvenient for construction. , there is an urgent need for a variety of fire-proof thermal insulation boards with low production cost, high strength, ultra-light and environmental protection.

发明内容SUMMARY OF THE INVENTION

本发明的一个目的是克服现有的防火隔热保温板不能实现强度高、密度小、生产过程环保、原料环保、隔音效果好并且同时满足燃烧性能A1标准的缺点,提供一种高强度、重量超轻的防火绿色隔热保温板。One object of the present invention is to overcome the shortcomings of the existing fire-proof, heat-insulating and thermal-insulation boards that cannot achieve high strength, low density, environmental protection in the production process, environmental protection of raw materials, good sound insulation effect, and at the same time meet the combustion performance A1 standard, and provide a high-strength, lightweight Ultralight fireproof green thermal insulation board.

本发明的第二个目的是提供所述高强度超轻防火绿色隔热保温板的制备方法。The second object of the present invention is to provide a preparation method of the high-strength ultra-light fireproof green thermal insulation board.

本发明的第三个目的是提供包括所述高强度超轻环保防火绿色隔热保温板的且隔音性能良好的墙身系统。The third object of the present invention is to provide a wall system including the high-strength, ultra-light, environmental-friendly, fire-proof, green thermal insulation board and having good sound insulation performance.

本发明提供了一种高强度重量超轻防火绿色隔热保温板,所述防火绿色隔热保温板由水和其他原料制备而成,其中基于除水以外的原料的重量,所述原料含有0.1-10重量%的棕榈纤维,并且其中所述棕榈纤维的纤维长度范围为2mm至15mm。The present invention provides a high-strength and light-weight fireproof green thermal insulation board, which is prepared from water and other raw materials, wherein based on the weight of the raw materials other than water, the raw materials contain 0.1 - 10 wt% palm fibers, and wherein the palm fibers have a fiber length ranging from 2 mm to 15 mm.

本发明还提供了一种墙身系统,所述墙身系统包括本发明所述的防火绿色隔热保温板。The present invention also provides a wall body system, the wall body system includes the fireproof green thermal insulation board of the present invention.

本发明还提供了所述高强度超轻防火绿色隔热保温板的环保制备方法,所述方法包括将棕榈纤维与其他原料混合的步骤;其中基于除水以外的原料的重量,所述原料含有0.1-10重量%的棕榈纤维,并且其中所述棕榈纤维的纤维长度范围为2mm至15mm。The present invention also provides an environment-friendly preparation method of the high-strength, ultra-light, fire-proof green thermal insulation board, the method comprising the step of mixing palm fiber with other raw materials; wherein based on the weight of the raw materials other than water, the raw materials contain 0.1-10% by weight of palm fibers, and wherein the palm fibers have a fiber length ranging from 2 mm to 15 mm.

与现有技术满足A级标准的保温材料制成的防火隔热保温板相比,本发明的防火隔热保温板不仅强度高、密度小、生产过程环保、原料环保,而且同时满足燃烧性能A1标准。本发明以环保及有利环境的方法利用了农业和工业生产产生的废弃物。它通过消耗工业废弃物副产品来提供环保(绿色)材料,同时提供超轻(等于或小于180kg/m3),不燃(A1级),良好的隔音和隔热效果。具体地,本发明的防火隔热环保板能够兼顾多种优异性能:密度≤180kg/m3、导热系数≤0.055W/mK、压缩强度≥0.3MPa、Compared with the fire-proof, heat-insulation and heat-insulation board made of the heat-insulating material meeting the A-level standard in the prior art, the fire-proof heat-insulation and heat-insulation board of the present invention not only has high strength, low density, environmental protection in the production process, and environmental protection of the raw materials, but also satisfies the combustion performance A1 at the same time. standard. The present invention utilizes wastes from agricultural and industrial production in an environmentally friendly and environmentally friendly way. It provides environmentally friendly (green) materials by consuming industrial waste by-products, while providing ultra-light (equal to or less than 180kg/m 3 ), non-combustible (A1 class), good sound and thermal insulation. Specifically, the fireproof, heat-insulation and environmental protection board of the present invention can take into account various excellent properties: density≤180kg/m 3 , thermal conductivity≤0.055W/mK, compressive strength≥0.3MPa,

燃烧性能符合A1标准,吸水率≤10%。并且包括本发明所述的防火绿色隔热保温板的墙身系统也具有上述优点并且还具有优异的隔音指标≥35dB。并且本发明所述高强度超轻环保防火隔热保温板的制备方法成本低,耗能低,对环境的污染小。The combustion performance meets the A1 standard, and the water absorption rate is less than or equal to 10%. And the wall system including the fireproof green thermal insulation board of the present invention also has the above advantages and also has an excellent sound insulation index ≥ 35dB. In addition, the preparation method of the high-strength, ultra-light and environment-friendly fire-proof heat-insulation-insulation board of the present invention has low cost, low energy consumption and little pollution to the environment.

此外,本发明的方法使用非常高百分比的再利用材料,并且其制造过程消耗非常低的能量水平并且不污染河流或溪流。本发明的产品重量超轻且不易碎,这样建筑工人在工地上更容易施工。本发明是不可燃的并且经测试符合欧洲标准的无毒类别。除了具有有机(低导热率和吸水性)和无机(耐火)材料的综合优势外,还具有好的成本效率。Furthermore, the method of the present invention uses a very high percentage of recycled materials, and its manufacturing process consumes very low energy levels and does not pollute rivers or streams. The product of the present invention is ultra-light and not brittle, so that it is easier for construction workers to construct on the construction site. The present invention is non-flammable and tested to the non-toxic category of European standards. In addition to the combined advantages of organic (low thermal conductivity and water absorption) and inorganic (refractory) materials, it also has good cost efficiency.

此外,本发明的环保概念对人类和地球都具有巨大的社会效益。下面的表1提供了本发明绿色建筑与普通建筑材料相比的竞争分析。In addition, the environmental protection concept of the present invention has enormous social benefits to both human beings and the earth. Table 1 below provides a competitive analysis of the green building of the present invention compared to common building materials.

表1Table 1

Figure BDA0001750600980000031
Figure BDA0001750600980000031

具体实施方式Detailed ways

本发明提供的高强度重量超轻防火绿色隔热保温板,所述防火绿色隔热保温板由水和其他原料制备而成,其中基于除水以外的原料的重量,所述原料含有0.1-10重量%的棕榈纤维,并且其中所述棕榈纤维的纤维长度范围为2mm至15mm。The high-strength and light-weight fireproof green thermal insulation board provided by the present invention is prepared from water and other raw materials, wherein based on the weight of the raw materials other than water, the raw materials contain 0.1-10 % by weight palm fibers, and wherein the palm fibers have a fiber length ranging from 2 mm to 15 mm.

优选地,所述除水以外的原料包括活性粉末、硬化剂、发泡剂、泡沫稳定剂和任选的功能性外加剂;并且其中所述活性粉末选自矿渣、煤灰、硅粉和偏高岭土中的三种或更多种;所述硬化剂选自硅酸钠、硅酸钾、氢氧化钾和氢氧化钠中的两种或更多种;所述发泡剂选自过氧化氢和铝粉中的一种或多种;所述泡沫稳定剂选自硬脂酸钙和硅酮酰胺中的一种或多种;以及所述任选的功能性外加剂选自减水剂、缓凝剂和颜料中的一种或多种。Preferably, the raw materials other than water include active powder, hardener, foaming agent, foam stabilizer and optional functional admixtures; and wherein the active powder is selected from slag, coal ash, silica fume and partial Three or more kinds of kaolin; the hardening agent is selected from two or more kinds of sodium silicate, potassium silicate, potassium hydroxide and sodium hydroxide; the foaming agent is selected from hydrogen peroxide and one or more of aluminum powder; the foam stabilizer is selected from one or more of calcium stearate and silicone amide; and the optional functional admixture is selected from water reducer, One or more of retarders and pigments.

更优选地,所述活性粉末选自0.6-29.4重量%的矿渣、1.8-51.7重量%的煤灰、0.6-5.9重量%的硅粉和0.6-11.8重量%的偏高岭土中的三种或更多种;所述硬化剂选自17.6-35.3重量%的硅酸钠、17.6-35.3重量%的硅酸钾、0.6-8.8重量%的氢氧化钾和0.6-8.8重量%的氢氧化钠中的两种或更多种;所述发泡剂选自1.8-5.9重量%的过氧化氢和1.8-5.9重量%的铝粉中的一种或多种;所述泡沫稳定剂选自0.1-5.9重量%的硬脂酸钙和0.1-5.9重量%的硅酮酰胺中的一种或多种;以及所述任选的功能性外加剂选自0-10重量%的减水剂、0-10重量%的缓凝剂和0-10重量%的颜料中的一种或多种;以上所有百分比都基于除水以外的原料的重量。More preferably, the active powder is selected from three or more of 0.6-29.4 wt% slag, 1.8-51.7 wt% coal ash, 0.6-5.9 wt% silica fume and 0.6-11.8 wt% metakaolin A variety of; the hardener is selected from 17.6-35.3% by weight of sodium silicate, 17.6-35.3% by weight of potassium silicate, 0.6-8.8% by weight of potassium hydroxide and 0.6-8.8% by weight of sodium hydroxide two or more; the foaming agent is selected from one or more of 1.8-5.9% by weight of hydrogen peroxide and 1.8-5.9% by weight of aluminum powder; the foam stabilizer is selected from 0.1-5.9 One or more of calcium stearate in wt % and silicone amide in 0.1-5.9 wt %; and the optional functional admixture is selected from 0-10 wt % water reducer, 0-10 One or more of wt % retarder and 0-10 wt % pigment; all percentages above are based on the weight of the raw materials excluding water.

进一步优选地,所述活性粉末选自5-20重量%的矿渣、5-40重量%的煤灰、1-4重量%的硅粉和5-11重量%的偏高岭土中的三种或更多种;所述硬化剂选自20-30重量%的硅酸钠、20-30重量%的硅酸钾、1-6重量%的氢氧化钾和1-6重量%的氢氧化钠中的两种或更多种;所述发泡剂选自2-5重量%的过氧化氢和2-5重量%的铝粉中的一种或多种;所述泡沫稳定剂选自0.1-4重量%的硬脂酸钙和0.1-4重量%的硅酮酰胺中的一种或多种;所述任选的功能性外加剂选自0-6重量%的减水剂、0-6重量%的缓凝剂和0-6重量%的颜料中的一种或多种;以及2-6重量%的棕榈纤维;以上所有百分比都基于除水以外的原料的重量。Further preferably, the active powder is selected from three or more of 5-20% by weight of slag, 5-40% by weight of coal ash, 1-4% by weight of silica fume and 5-11% by weight of metakaolin. Various; the hardener is selected from 20-30% by weight of sodium silicate, 20-30% by weight of potassium silicate, 1-6% by weight of potassium hydroxide and 1-6% by weight of sodium hydroxide two or more; the foaming agent is selected from one or more of 2-5 wt% hydrogen peroxide and 2-5 wt% aluminum powder; the foam stabilizer is selected from 0.1-4 One or more of calcium stearate in wt % and silicone amide in 0.1-4 wt %; the optional functional admixture is selected from 0-6 wt % water reducing agent, 0-6 wt % % retarder and 0-6 wt % of one or more of pigments; and 2-6 wt % palm fiber; all percentages above are based on the weight of the raw materials excluding water.

最优选地,所述活性粉末选自9-20重量%的矿渣、10-40重量%的煤灰、2-4重量%的硅粉和5-10重量%的偏高岭土中的三种或更多种;所述硬化剂选自20-28重量%的硅酸钠、20-28重量%的硅酸钾、1_5重量%的氢氧化钾和1-5重量%的氢氧化钠中的两种或更多种;所述发泡剂选自2-4.5重量%的过氧化氢和2-4.5重量%的铝粉中的一种或多种;所述泡沫稳定剂选自0.1-3.5重量%的硬脂酸钙和0.1-3.5重量%的硅酮酰胺中的一种或多种;所述任选的功能性外加剂选自0-5重量%的减水剂、0-5重量%的缓凝剂和0-5重量%的颜料中的一种或多种;以及2-5重量%的棕榈纤维;以上所有百分比都基于除水以外的原料的重量。Most preferably, the active powder is selected from three or more of 9-20% by weight of slag, 10-40% by weight of coal ash, 2-4% by weight of silica fume and 5-10% by weight of metakaolin. Multiple; the hardener is selected from two of 20-28% by weight of sodium silicate, 20-28% by weight of potassium silicate, 1-5% by weight of potassium hydroxide and 1-5% by weight of sodium hydroxide or more; the foaming agent is selected from one or more of 2-4.5% by weight of hydrogen peroxide and 2-4.5% by weight of aluminum powder; the foam stabilizer is selected from 0.1-3.5% by weight One or more of calcium stearate and 0.1-3.5% by weight of silicone amide; the optional functional admixture is selected from 0-5% by weight of water reducing agent, 0-5% by weight of One or more of a retarder and 0-5 wt% pigment; and 2-5 wt% palm fiber; all percentages above are based on the weight of the raw materials excluding water.

本发明所述棕榈纤维得自棕榈科植物,优选得自棕榈科棕榈属植物。优选地,所述棕榈纤维可以是从棕榈果中挤出油后产生的主要由纤维物质组成的物质,并且所述棕榈纤维具有少于20%的水含量和少于15%的油含量。优选所述棕榈纤维具有少于15%的水含量和少于8%的油含量。进一步优选所述棕榈纤维具有少于10%的水含量和少于5%的油含量。由于含有残余的油,在制备本发明的高强度超轻环保防火隔热保温板时,无需添加额外的表面活性剂。所述棕榈纤维还可以是棕榈科棕榈属植物的叶鞘纤维或椰壳纤维。The palm fibers of the present invention are obtained from plants of the palm family, preferably from the palm genus of the palm family. Preferably, the palm fiber may be a material consisting mainly of fibrous matter resulting from the extrusion of oil from palm fruit, and the palm fiber has a water content of less than 20% and an oil content of less than 15%. Preferably the palm fibers have a water content of less than 15% and an oil content of less than 8%. It is further preferred that the palm fibers have a water content of less than 10% and an oil content of less than 5%. Due to the residual oil, there is no need to add additional surfactants when preparing the high-strength, ultra-light, environment-friendly fire-proof thermal insulation board of the present invention. The palm fibers may also be sheath fibers or coir fibers of the palm family, the genus Palm.

优选地,基于除水以外的原料的重量,所述原料含有2-6重量%的棕榈纤维,并且其中所述棕榈纤维的纤维长度范围为3mm至9mm。更优选地,基于除水以外的原料的重量,所述原料含有3-6重量%的棕榈纤维,并且其中所述棕榈纤维的纤维长度范围为7mm至9mm。所述棕榈纤维的纤维长度可以为7.0、7.1、7.2、7.3、7.4、7.5、7.6、7.7、7.8、7.9、8.0、8.1、8.2、8.3、8.4、8.5、8.6、8.7、8.8、8.9、或9毫米。优选所述棕榈纤维的纤维长度范围为7.5-8.5毫米。特定长度的棕榈纤维可以通过剪切设备(例如混纺纤维剪切机等)加工而成。棕榈纤维的长度偏差为0.5-1毫米是可以接受的。此外,本发明所述的棕榈纤维也可以是具有不同长度的棕榈纤维的混合物。例如,所述棕榈纤维混合物中30-70%具有2-6mm的纤维长度、5-40%具有7-9mm的纤维长度、3-30%具有10-15mm的纤维长度。优选地,所述棕榈纤维混合物中40-60%具有2-6mm的纤维长度、15-35%具有7-9mm的纤维长度、5-25%具有10-15mm的纤维长度。优选本申请的所述棕榈纤维是不同长度棕榈纤维的混合物,该混合物可以进一步提高最终所得防火绿色隔热保温板的强度和韧性。Preferably, the raw material contains 2-6 wt% palm fibers based on the weight of the raw material excluding water, and wherein the palm fibers have a fiber length ranging from 3 mm to 9 mm. More preferably, the raw material contains 3-6 wt% palm fibers based on the weight of the raw material excluding water, and wherein the palm fibers have a fiber length ranging from 7 mm to 9 mm. The palm fiber may have a fiber length of 7.0, 7.1, 7.2, 7.3, 7.4, 7.5, 7.6, 7.7, 7.8, 7.9, 8.0, 8.1, 8.2, 8.3, 8.4, 8.5, 8.6, 8.7, 8.8, 8.9, or 9mm. Preferably, the palm fibers have a fiber length in the range of 7.5-8.5 mm. Palm fibers of a specific length can be processed by shearing equipment (eg blended fiber shears, etc.). Length deviation of palm fibers of 0.5-1 mm is acceptable. In addition, the palm fibers described in the present invention can also be a mixture of palm fibers with different lengths. For example, 30-70% of the palm fiber blend has a fiber length of 2-6 mm, 5-40% has a fiber length of 7-9 mm, and 3-30% has a fiber length of 10-15 mm. Preferably, 40-60% of the palm fiber mixture has a fiber length of 2-6 mm, 15-35% has a fiber length of 7-9 mm, and 5-25% has a fiber length of 10-15 mm. Preferably, the palm fiber of the present application is a mixture of palm fibers of different lengths, and the mixture can further improve the strength and toughness of the finally obtained fireproof green thermal insulation board.

另外,本发明的发明人发现,防火绿色隔热保温板除水以外的原料中的棕榈纤维含量可根据应用场所的不同气候进行调整以获得更好的性能。例如,当最终板安装在具有地中海气候的区域时,基于除水以外的原料的重量,所述原料含有4-10重量%的棕榈纤维。当最终板安装在亚热带季风气候区时,基于除水以外的原料的重量,所述原料含有0.5-5重量%的棕榈纤维。当最终板安装在具有温带季风气候的区域时,基于除水以外的原料的重量,所述原料含有3-7重量%的棕榈纤维。当最终板安装在亚热带气候区时,原材料包括基于除水以外的原料的重量,所述原料含有0.7-6重量%的棕榈纤维。当最终板安装在具有潮湿大陆性气候的区域时,原材料包括基于除水以外的原料的重量,所述原料含有4-9重量%的棕榈纤维。In addition, the inventors of the present invention found that the content of palm fiber in the raw materials of the fireproof green thermal insulation board other than water can be adjusted according to different climates of the application site to obtain better performance. For example, when the final panel is installed in an area with a Mediterranean climate, the raw material contains 4-10% by weight of palm fibers, based on the weight of the raw material excluding water. When the final panel is installed in a subtropical monsoon climate zone, the raw material contains 0.5-5 wt% palm fiber based on the weight of the raw material excluding water. When the final panel is installed in an area with a temperate monsoon climate, the raw material contains 3-7% by weight of palm fibers, based on the weight of the raw material excluding water. When the final panel is installed in a subtropical climate zone, the raw material includes 0.7-6 wt% palm fiber based on the weight of the raw material excluding water. When the final panel is installed in an area with a humid continental climate, the raw material includes 4-9% by weight of palm fibers, based on the weight of the raw material excluding water.

本发明所述的煤灰,即一种细灰,属于工业污染物中常见的一种固体废物。这是由工业或发电站使用煤作为生热剂,从中生产的副产品废物。主要是由煤燃烧后产生,主要成分为金属氧化物FeO、Fe2O3、CaO、MgO、Na2O、TiO2等和非金属氧化物SiO2。例如,电厂煤粉炉烟道气体中收集的粉末称为粉煤灰。优选所述煤灰包含SiO2、Al2O3、Fe2O3和CaO,并且其中所述CaO的含量不超过10wt%。更优选所述煤灰为中国国家标准GB/T1596-2005中规定的F类粉煤灰。The coal ash of the present invention, namely a kind of fine ash, belongs to a common solid waste in industrial pollutants. This is by-product waste produced by industry or power stations using coal as a heat generator. It is mainly produced by coal combustion, and its main components are metal oxides FeO, Fe 2 O 3 , CaO, MgO, Na 2 O, TiO 2 , etc. and non-metal oxides SiO 2 . For example, the powder collected in the flue gas of pulverized coal furnaces in power plants is called fly ash. Preferably, the coal ash contains SiO 2 , Al 2 O 3 , Fe 2 O 3 and CaO, and wherein the content of the CaO does not exceed 10 wt %. More preferably, the coal ash is Class F fly ash specified in the Chinese National Standard GB/T1596-2005.

本发明所述矿渣是在高炉炼铁过程中的副产品。其包含SiO2、Al2O3、MgO和CaO。优选地,炉渣是基于标准GB/T18046-2008的磨碎的粒状高炉矿渣。优选地,炉渣的粒度范围为5-40mm,优选5-20mm,最优选5-10mm。更优选地,所述矿渣优选为符合中国国家标准GB/T18046-2008中规定的S95级别的高炉矿渣。The slag described in the present invention is a by-product in the blast furnace ironmaking process. It contains SiO 2 , Al 2 O 3 , MgO and CaO. Preferably, the slag is ground granulated blast furnace slag based on standard GB/T18046-2008. Preferably, the particle size of the slag is in the range of 5-40mm, preferably 5-20mm, most preferably 5-10mm. More preferably, the slag is preferably a blast furnace slag of grade S95 specified in the Chinese national standard GB/T18046-2008.

硅粉(Silica Fume)也称为微硅粉(CAS号69012-64-2,EINECS号273-761-1)是二氧化硅的无定形(非结晶)多晶型物。它是作为硅和硅铁合金生产的副产物收集的超细粉末,由平均粒径为150nm左右的球形颗粒组成。Silica Fume, also known as microsilica (CAS No. 69012-64-2, EINECS No. 273-761-1), is an amorphous (non-crystalline) polymorph of silicon dioxide. It is an ultrafine powder collected as a by-product of the production of silicon and ferrosilicon alloys and consists of spherical particles with an average particle size of around 150nm.

本发明所述偏高岭土是高岭土脱水产生的。通过向高岭土提供超过700℃的加热,它将高岭土重构为偏高岭土。脱水后,它含有高百分比的SiO2和Al2O3,用于产生地质聚合物结构。偏高岭土的粒径范围为5-40mm,优选5-20mm,最优选5-10mm。The metakaolin of the present invention is produced by dehydration of kaolin. It restructures the kaolin into metakaolin by providing the kaolin with heating in excess of 700°C. After dehydration, it contains high percentages of SiO 2 and Al 2 O 3 , which are used to create geopolymer structures. The particle size range of metakaolin is 5-40mm, preferably 5-20mm, most preferably 5-10mm.

用于本发明的发泡剂在发泡时不释放任何有害气体。本发明所述发泡剂选自1.8-5.9重量%的过氧化氢和1.8-5.9重量%的铝粉中的一种或多种。优选地,发泡剂为25-60wt%的过氧化氢水溶液。更优选地,过氧化氢是25-40wt%的过氧化氢水溶液。The blowing agent used in the present invention does not release any harmful gas during foaming. The foaming agent of the present invention is selected from one or more of 1.8-5.9% by weight of hydrogen peroxide and 1.8-5.9% by weight of aluminum powder. Preferably, the blowing agent is a 25-60 wt% aqueous hydrogen peroxide solution. More preferably, the hydrogen peroxide is a 25-40 wt% aqueous hydrogen peroxide solution.

在本申请中使用的硬化剂包括水玻璃是具有10-40重量%固体含量的硅酸钠或硅酸钾水分散体。优选地,硬化剂是硅酸钠与氢氧化钠的混合物或硅酸钾与氢氧化钾的混合物。优选地,需要是含有氢氧化钠的硅酸钠。通过提供氢氧化钠,可以改变硅酸钠的模量比。然而,添加氢氧化钠的主要目的是提高强度并从活性粉末中溶解更多的Si4+和Al3+离子。优选水玻璃的模量比为3.1至3.4模量。优选所述硅酸钠水分散体为符合中国国家标准GB/T4209-2008中规定的“液-2”型号的液体硅酸钠。所述硅酸钠需要99%wt的钠,并且水玻璃的模量比变为1.2-1.6模量。本发明所述水玻璃的固体含量≤40%,更优选20-40%(重量),最优选30-40%(重量)。The hardener used in this application, including water glass, is an aqueous dispersion of sodium silicate or potassium silicate with a solids content of 10-40% by weight. Preferably, the hardener is a mixture of sodium silicate and sodium hydroxide or a mixture of potassium silicate and potassium hydroxide. Preferably, it is required to be sodium silicate with sodium hydroxide. By providing sodium hydroxide, the modulus ratio of sodium silicate can be changed. However, the main purpose of adding sodium hydroxide is to increase the strength and dissolve more Si 4+ and Al 3+ ions from the active powder. Preferably, the modulus ratio of the water glass is 3.1 to 3.4 modulus. Preferably, the aqueous sodium silicate dispersion is liquid sodium silicate of the "Liquid-2" type specified in the Chinese national standard GB/T4209-2008. The sodium silicate requires 99% wt sodium and the modulus ratio of water glass becomes 1.2-1.6 modulus. The solid content of the water glass of the present invention is less than or equal to 40%, more preferably 20-40% by weight, most preferably 30-40% by weight.

在本申请中使用的泡沫稳定剂包括硬脂酸钙或硬脂酸钙。优选地,需要工业级的硬脂酸钙。Foam stabilizers used in this application include calcium stearate or calcium stearate. Preferably, technical grade calcium stearate is required.

所述减水剂可以是本领域常用的减水剂,例如木质素磺酸盐、萘磺酸盐甲醛聚合物等。The water-reducing agent can be a water-reducing agent commonly used in the art, such as lignosulfonate, naphthalenesulfonate formaldehyde polymer, and the like.

所述缓凝剂可以是本领域常用的缓凝剂,例如糖钙、葡萄糖酸盐、柠檬酸、酒石酸及其盐、锌盐、磷酸盐等。The retarder may be a retarder commonly used in the art, such as calcium sugar, gluconate, citric acid, tartaric acid and its salts, zinc salts, phosphates and the like.

所述颜料可以是本领域常用的颜料,例如氧化铁、二氧化锰、氧化铬、钴蓝、炭黑等。The pigment can be a pigment commonly used in the art, such as iron oxide, manganese dioxide, chromium oxide, cobalt blue, carbon black, and the like.

最优选地,所述煤灰是从煤火电站产生的煤灰,所述矿渣是炼钢厂产生的炉渣,并且所述棕榈纤维来自提取棕榈油后得到的油棕榈果残渣。这样可以有效利用这些固体废弃物,变废为宝。它具有低能耗生产和无废物排放的优点。Most preferably, the coal ash is coal ash produced from coal-fired power plants, the slag is slag produced by a steel mill, and the palm fiber is derived from oil palm fruit residue obtained after palm oil extraction. In this way, these solid wastes can be effectively utilized and turned waste into treasure. It has the advantages of low energy consumption production and no waste discharge.

本发明还提供了包括本发明所述的防火绿色隔热保温板的墙身系统。所述防火绿色隔热保温板可以安装在墙身系统的中央或者其主体部分的单侧或双侧。所述墙身系统不仅满足防火隔热的要求,而且具备优异的隔音性能。The present invention also provides a wall body system comprising the fireproof green thermal insulation board of the present invention. The fireproof green thermal insulation board can be installed in the center of the wall system or on one or both sides of its main body. The wall body system not only meets the requirements of fire and heat insulation, but also has excellent sound insulation performance.

本发明还提供的所述高强度超轻防火绿色隔热保温板的环保制备方法,所述方法包括将棕榈纤维与其他原料混合的步骤;其中基于除水以外的原料的重量,所述原料含有0.1-10重量%的棕榈纤维,并且其中所述棕榈纤维的纤维长度范围为2mm至15mm。The present invention also provides an environment-friendly preparation method of the high-strength, ultra-light, fire-proof green thermal insulation board, the method comprising the step of mixing palm fiber with other raw materials; wherein, based on the weight of the raw materials other than water, the raw materials contain 0.1-10% by weight of palm fibers, and wherein the palm fibers have a fiber length ranging from 2 mm to 15 mm.

优选地,所述高强度超轻防火绿色隔热保温板的环保制备方法包括以下步骤:Preferably, the environmental protection preparation method of the high-strength ultra-light fireproof green thermal insulation board comprises the following steps:

a)在400-800rpm的转速下混合水、活性粉末、硬化剂、泡沫稳定剂、棕榈纤维和任选的功能性外加剂至均质,其中水与除水之外的原料的体积比为1∶50至1∶2;a) Mix water, active powder, hardener, foam stabilizer, palm fiber and optional functional admixtures to homogeneity at a rotational speed of 400-800 rpm, wherein the volume ratio of water to raw materials other than water is 1 : 50 to 1:2;

b)向a)的混合物中加入发泡剂在700-1000rpm的转速下保持3-15秒以产生孔结构;b) adding a blowing agent to the mixture of a) at 700-1000 rpm for 3-15 seconds to create a cell structure;

c)将b)的混合物倒入容器模具中并固化1-12小时;c) pour the mixture of b) into a container mould and cure for 1-12 hours;

d)将c)的固化后的板脱模并切割成所需尺寸,以及d) demoulding and cutting the cured panel of c) to the desired size, and

e)继续固化d)的切割后的板1-30天;所述除水以外的原料包括活性粉末、硬化剂、发泡剂、泡沫稳定剂和任选的功能性外加剂;并且其中e) continue to cure the cut board of d) for 1-30 days; the raw materials other than water include active powder, hardener, foaming agent, foam stabilizer and optional functional admixtures; and wherein

所述活性粉末选自矿渣、煤灰、硅粉和偏高岭土中的三种或更多种;The active powder is selected from three or more of slag, coal ash, silica fume and metakaolin;

所述硬化剂选自硅酸钠、硅酸钾、氢氧化钾和氢氧化钠中的两种或更多种;The hardener is selected from two or more of sodium silicate, potassium silicate, potassium hydroxide and sodium hydroxide;

所述发泡剂选自过氧化氢和铝粉中的一种或多种;The foaming agent is selected from one or more of hydrogen peroxide and aluminum powder;

所述泡沫稳定剂选自硬脂酸钙和硅酮酰胺中的一种或多种;以及The foam stabilizer is selected from one or more of calcium stearate and silicone amide; and

所述任选的功能性外加剂选自减水剂、缓凝剂和颜料中的一种或多种。The optional functional admixture is selected from one or more of water reducers, retarders and pigments.

进一步优选地,所述高强度超轻防火绿色隔热保温板的环保制备方法包括以下步骤:a)在600-800rpm的转速下混合水、活性粉末、硬化剂、泡沫稳定剂、棕榈纤维和任选的功能性外加剂至均质,其中水与除水之外的原料的体积比为1∶30至1∶4;b)向a)的混合物中加入发泡剂在860-960rpm的转速下保持5-15秒以产生孔结构;c)将b)的混合物倒入容器模具中并固化8-12小时;d)将c)的固化后的板脱模并切割成所需尺寸,以及e)继续固化d)的切割后的板7-28天。Further preferably, the environmental protection preparation method of the high-strength ultra-light fireproof green thermal insulation board comprises the following steps: a) mixing water, active powder, hardener, foam stabilizer, palm fiber and any Selected functional admixtures to homogeneity, wherein the volume ratio of water to raw materials other than water is 1:30 to 1:4; b) Add a blowing agent to the mixture of a) at a rotational speed of 860-960 rpm hold for 5-15 seconds to create the pore structure; c) pour the mixture of b) into a container mold and cure for 8-12 hours; d) demould and cut the cured plate of c) to the desired size, and e ) Continue to cure the cut panels of d) for 7-28 days.

更优选地,其中所述步骤b)在15-35℃的温度范围内进行;步骤c)在≤100℃的温度范围内进行;且步骤c)在≥50%湿度下固化;当取样步骤c)的混合物至190-270kg/m3密度范围内时,进行步骤d)。More preferably, wherein said step b) is carried out in a temperature range of 15-35°C; step c) is carried out in a temperature range of ≤100°C; and step c) is cured at ≥50% humidity; when sampling step c ) to within the density range of 190-270 kg/m 3 , proceed to step d).

本发明防火绿色隔热保温板/墙身系统的性能按以下标准进行测试:The performance of the fireproof green thermal insulation board/wall system of the present invention is tested according to the following standards:

1.密度测量基于JC/T 2200-2013;1. Density measurement is based on JC/T 2200-2013;

2.压缩强度试验方法基于JC/T2200-2013;2. The compressive strength test method is based on JC/T2200-2013;

3.燃烧性能方法基于BS EN 13501-1:2007+A1:2009或GB8624-2012;3. The combustion performance method is based on BS EN 13501-1:2007+A1:2009 or GB8624-2012;

4.吸水率基于JC/T2200-2013;和4. Water absorption is based on JC/T2200-2013; and

5.隔音性能基于BS EN ISO 140-3:1995。5. Sound insulation performance based on BS EN ISO 140-3:1995.

下面结合实施例对本发明做进一步的说明。The present invention will be further described below in conjunction with the embodiments.

实施例1Example 1

本实施例说明本发明的防火绿色隔热保温板及其制备方法,原料配比如以下表2所示:The present embodiment illustrates the fireproof green thermal insulation board of the present invention and its preparation method, and the ratio of raw materials is shown in Table 2 below:

表2Table 2

Figure BDA0001750600980000091
Figure BDA0001750600980000091

1.棕榈纤维的预处理1. Pretreatment of palm fiber

棕榈纤维来源于恒华资源集团棕榈油提取后得到的油棕残渣,棕榈纤维含水量为20%,含油量为8%。剪切设备用于制备具有上述限定长度的棕榈纤维。The palm fiber is derived from the oil palm residue obtained after the palm oil extraction of Henghua Resources Group. The palm fiber has a water content of 20% and an oil content of 8%. Shearing equipment is used to produce palm fibers having the above-defined lengths.

2.板的制备2. Plate Preparation

a)在600rpm的转速下混合水、活性粉末、硬化剂、泡沫稳定剂、棕榈纤维和颜料至均质;a) Mix water, active powder, hardener, foam stabilizer, palm fiber and pigment to homogeneity at 600 rpm;

b)在29℃下向a)的混合物中加入发泡剂在900rpm的转速下保持6秒以产生孔结构;b) adding a blowing agent to the mixture of a) at 29°C for 6 seconds at 900 rpm to generate a cell structure;

c)将b)的混合物倒入容器模具中并在30℃于70%湿度下固化12小时;c) Pour the mixture of b) into a container mould and cure at 30°C and 70% humidity for 12 hours;

d)取样步骤c)的混合物测密度至200kg/m3,将c)的固化后的板脱模并切割成15cmX15cm的测试尺寸,以及d) sampling the mixture of step c) to a density of 200 kg/m 3 , demoulding and cutting the cured plate of c) to a test size of 15 cm×15 cm, and

e)继续固化d)的切割后的板28天。e) Continue to cure the cut panels of d) for 28 days.

3.板的性能测试结果3. Board performance test results

表3所示的测试结果来自至少20个样品。并且通过在两侧安装面板的墙身系统获得空气隔声效果。The test results shown in Table 3 are from at least 20 samples. And the air sound insulation effect is obtained through the wall system with panels installed on both sides.

表3table 3

密度(kg/m<sup>3</sup>)Density (kg/m<sup>3</sup>) ≤180(JC/T-2200)≤180(JC/T-2200) 防火等级Fire-proof level A1级(GB8624-2012)Class A1 (GB8624-2012) 抗压强度(MPa)Compressive strength (MPa) >0.30(JC/T-2200)>0.30(JC/T-2200) 热导率Thermal conductivity 0.055w/m.k(JC/T-2200)0.055w/m.k(JC/T-2200) 吸水性water absorption <10%(JC/T-2200)<10% (JC/T-2200) 石棉纤维asbestos fiber 未检出(EPA-600)Not detected (EPA-600) 有害物质含量Hazardous substance content 达标(GL-008-009)Standard (GL-008-009) 墙身系统的空气声隔绝性能Airborne sound insulation performance of wall systems >35dB(BS EN ISO 140-3)>35dB(BS EN ISO 140-3) 墙身系统的防火性能Fire performance of wall system >2-Hr(BS EN 1364-1)>2-Hr (BS EN 1364-1)

其他的实施例other embodiments

发明人还选择了本发明“具体实施方式”的数值范围中的组合,按照实施例1的方法制备并测试防火绿色隔热保温板。结果所有实施例的防火绿色隔热保温板都能够实现兼顾多种优异性能:密度≤180kg/m3、导热系数≤0.055W/mK、压缩强度≥0.3MPa、燃烧性能符合A1标准,且吸水率≤10%。并且本申请装有以上防火绿色隔热保温板的墙身系统还具有良好的隔音性能。The inventor also selected a combination within the numerical range of the "specific embodiment" of the present invention, and prepared and tested the fireproof green thermal insulation board according to the method of Example 1. Results The fireproof green thermal insulation boards of all the examples can achieve a variety of excellent properties: density≤180kg/m 3 , thermal conductivity≤0.055W/mK, compressive strength≥0.3MPa, combustion performance conforming to A1 standard, and water absorption rate ≤10%. In addition, the wall body system equipped with the above fireproof green thermal insulation board of the present application also has good sound insulation performance.

该说明书中提到的所有出版物和专利申请都表明本发明涉及的本领域技术人员的水平。所有出版物和专利申请都通过引用并入本文中,其参考程度如同各单个出版物或专利申请各自具体地和个别地表明被并入的一样,以便参考。All publications and patent applications mentioned in this specification are indicative of the level of those skilled in the art to which this invention pertains. All publications and patent applications are incorporated herein by reference to the same extent as if each individual publication or patent application was specifically and individually indicated to be incorporated by reference.

尽管已描述了某些实施方式,但是它们仅是以示例性方式示出,而不意图限制本发明的范围。所附权利要求和该说明书中它们的等同方案被认为涵盖了在本发明的范围和精神内的这类形式或改进。While certain embodiments have been described, they have been shown by way of example only, and are not intended to limit the scope of the inventions. The appended claims and their equivalents in this specification are considered to cover such forms or modifications as are within the scope and spirit of the inventions.

Claims (17)

1.一种高强度重量超轻防火绿色隔热保温板,所述防火绿色隔热保温板由水和其他原料制备而成,其中基于除水以外的原料的重量,所述原料含有0.1-10重量%的棕榈纤维,并且其中所述棕榈纤维的纤维长度范围为2mm至15mm。1. A high-strength, weight, and ultra-light fireproof green thermal insulation board prepared from water and other raw materials, wherein based on the weight of the raw materials other than water, the raw materials contain 0.1-10 % by weight palm fibers, and wherein the palm fibers have a fiber length ranging from 2 mm to 15 mm. 2.如权利要求1所述的防火绿色隔热保温板,其中,所述除水以外的原料包括活性粉末、硬化剂、发泡剂、泡沫稳定剂和任选的功能性外加剂;并且其中2. The fireproof green thermal insulation board according to claim 1, wherein the raw materials other than water include active powder, hardener, foaming agent, foam stabilizer and optional functional admixtures; and wherein 所述活性粉末选自矿渣、煤灰、硅粉和偏高岭土中的三种或更多种;The active powder is selected from three or more of slag, coal ash, silica fume and metakaolin; 所述硬化剂选自硅酸钠、硅酸钾、氢氧化钾和氢氧化钠中的两种或更多种;The hardener is selected from two or more of sodium silicate, potassium silicate, potassium hydroxide and sodium hydroxide; 所述发泡剂选自过氧化氢和铝粉中的一种或多种;The foaming agent is selected from one or more of hydrogen peroxide and aluminum powder; 所述泡沫稳定剂选自硬脂酸钙和硅酮酰胺中的一种或多种;以及The foam stabilizer is selected from one or more of calcium stearate and silicone amide; and 所述任选的功能性外加剂选自减水剂、缓凝剂和颜料中的一种或多种。The optional functional admixture is selected from one or more of water reducers, retarders and pigments. 3.如权利要求2所述的防火绿色隔热保温板,其中,3. The fireproof green thermal insulation board as claimed in claim 2, wherein, 所述活性粉末选自0.6-29.4重量%的矿渣、1.8-51.7重量%的煤灰、0.6-5.9重量%的硅粉和0.6-11.8重量%的偏高岭土中的三种或更多种;The active powder is selected from three or more of 0.6-29.4% by weight of slag, 1.8-51.7% by weight of coal ash, 0.6-5.9% by weight of silica fume and 0.6-11.8% by weight of metakaolin; 所述硬化剂选自17.6-35.3重量%的硅酸钠、17.6-35.3重量%的硅酸钾、0.6-8.8重量%的氢氧化钾和0.6-8.8重量%的氢氧化钠中的两种或更多种;The hardener is selected from 17.6-35.3% by weight of sodium silicate, 17.6-35.3% by weight of potassium silicate, 0.6-8.8% by weight of potassium hydroxide and 0.6-8.8% by weight of sodium hydroxide or more; 所述发泡剂选自1.8-5.9重量%的过氧化氢和1.8-5.9重量%的铝粉中的一种或多种;The foaming agent is selected from one or more of 1.8-5.9 wt % hydrogen peroxide and 1.8-5.9 wt % aluminum powder; 所述泡沫稳定剂选自0.1-5.9重量%的硬脂酸钙和0.1-5.9重量%的硅酮酰胺中的一种或多种;以及The foam stabilizer is selected from one or more of 0.1-5.9% by weight of calcium stearate and 0.1-5.9% by weight of silicone amide; and 所述任选的功能性外加剂选自0-10重量%的减水剂、0-10重量%的缓凝剂和0-10重量%的颜料中的一种或多种;The optional functional admixture is selected from one or more of 0-10% by weight of water reducing agent, 0-10% by weight of retarder and 0-10% by weight of pigment; 以上所有百分比都基于除水以外的原料的重量。All percentages above are based on the weight of the feedstock excluding water. 4.如权利要求3所述的防火绿色隔热保温板,其中,4. The fireproof green thermal insulation board according to claim 3, wherein, 所述活性粉末选自5-20重量%的矿渣、5-40重量%的煤灰、1-4重量%的硅粉和5-11重量%的偏高岭土中的三种或更多种;The active powder is selected from three or more of 5-20% by weight of slag, 5-40% by weight of coal ash, 1-4% by weight of silica fume and 5-11% by weight of metakaolin; 所述硬化剂选自20-30重量%的硅酸钠、20-30重量%的硅酸钾、1-6重量%的氢氧化钾和1-6重量%的氢氧化钠中的两种或更多种;The hardener is selected from two or more of 20-30% by weight sodium silicate, 20-30% by weight potassium silicate, 1-6% by weight potassium hydroxide and 1-6% by weight sodium hydroxide more; 所述发泡剂选自2-5重量%的过氧化氢和2-5重量%的铝粉中的一种或多种;The foaming agent is selected from one or more of 2-5% by weight of hydrogen peroxide and 2-5% by weight of aluminum powder; 所述泡沫稳定剂选自0.1-4重量%的硬脂酸钙和0.1-4重量%的硅酮酰胺中的一种或多种;The foam stabilizer is selected from one or more of 0.1-4% by weight of calcium stearate and 0.1-4% by weight of silicone amide; 所述任选的功能性外加剂选自0-6重量%的减水剂、0-6重量%的缓凝剂和0-6重量%的颜料中的一种或多种;以及The optional functional admixture is selected from one or more of 0-6 wt % water reducing agent, 0-6 wt % setting retarder and 0-6 wt % pigment; and 2-6重量%的棕榈纤维;2-6% by weight of palm fibers; 以上所有百分比都基于除水以外的原料的重量。All percentages above are based on the weight of the feedstock excluding water. 5.如权利要求1所述的防火绿色隔热保温板,其中,基于除水以外的原料的重量,所述原料含有2-6重量%的棕榈纤维,并且其中所述棕榈纤维的纤维长度范围为3mm至9mm。5. The fireproof green thermal insulation board of claim 1, wherein, based on the weight of the raw material other than water, the raw material contains 2-6 wt% palm fiber, and wherein the fiber length range of the palm fiber 3mm to 9mm. 6.如权利要求1所述的防火绿色隔热保温板,其中,所述棕榈纤维中30-70%具有2-6mm的纤维长度、5-40%具有7-9mm的纤维长度、3-30%具有10-15mm的纤维长度。6. The fireproof green thermal insulation board of claim 1, wherein 30-70% of the palm fibers have a fiber length of 2-6mm, 5-40% have a fiber length of 7-9mm, 3-30 % have a fiber length of 10-15mm. 7.根据权利要求1-6中任意一项所述的防火绿色隔热保温板,其中所述棕榈纤维来自提取棕榈油后得到的油棕榈果残渣,并且所述棕榈纤维具有低于20%的水含量和低于15%的油含量。7. The fireproof green thermal insulation board according to any one of claims 1-6, wherein the palm fiber is derived from oil palm fruit residue obtained after palm oil extraction, and the palm fiber has less than 20% Water content and less than 15% oil content. 8.根据权利要求2-7中任意一项所述的防火绿色隔热保温板,其中,所述煤灰包含SiO2、Al2O3、Fe2O3和CaO,并且其中所述CaO的含量不超过10wt%。8. The fireproof green thermal insulation board according to any one of claims 2-7 , wherein the coal ash contains SiO2 , Al2O3 , Fe2O3 and CaO, and wherein the CaO has The content does not exceed 10wt%. 9.根据权利要求2-8中任意一项所述的防火绿色隔热保温板,其中,所述煤灰为中国国家标准GB/T1596-2005中规定的F类粉煤灰。9. The fireproof green thermal insulation board according to any one of claims 2-8, wherein the coal ash is Class F coal ash specified in the Chinese national standard GB/T1596-2005. 10.根据权利要求2-9中任意一项所述的防火绿色隔热保温板,其中所述矿渣为符合中国国家标准GB/T 18046-2008中规定的S95级别的高炉矿渣。10. The fireproof green thermal insulation board according to any one of claims 2-9, wherein the slag is blast furnace slag of the S95 level specified in the Chinese national standard GB/T 18046-2008. 11.根据权利要求2-10中任意一项所述的防火绿色隔热保温板,其中,所述过氧化氢为20-60wt%的过氧化氢水溶液;并且所述硅酸钠为20-40固含量的硅酸钠水分散体。11. The fireproof green thermal insulation board according to any one of claims 2-10, wherein the hydrogen peroxide is an aqueous hydrogen peroxide solution of 20-60 wt%; and the sodium silicate is 20-40 Aqueous dispersion of sodium silicate at solids content. 12.根据权利要求11中任意一项所述的防火绿色隔热保温板,其中,所述硅酸钠水分散体为符合中国国家标准GB/T4209-2008中规定的“液-2”型号的液体硅酸钠。12. The fireproof green thermal insulation board according to any one of claims 11, wherein the sodium silicate water dispersion is of the "Liquid-2" model specified in the Chinese national standard GB/T4209-2008. Liquid sodium silicate. 13.根据权利要求1-12中任意一项所述的防火绿色隔热保温板,其中所述煤灰是从煤火电站产生的煤灰,所述矿渣是炼钢厂产生的炉渣,并且所述棕榈纤维来自提取棕榈油后得到的油棕榈果残渣。13. The fireproof green thermal insulation board according to any one of claims 1-12, wherein the coal ash is coal ash produced from a coal-fired power station, the slag is slag produced by a steelmaking plant, and the The palm fiber is derived from the oil palm fruit residue obtained after palm oil extraction. 14.一种墙身系统,所述墙身系统包括权利要求1-13中任意一项所述的防火绿色隔热保温板。14. A wall body system comprising the fireproof green thermal insulation board according to any one of claims 1-13. 15.权利要求1-13中任意一项所述的高强度超轻防火绿色隔热保温板的环保制备方法,所述方法包括将棕榈纤维与其他原料混合的步骤;其中基于除水以外的原料的重量,所述原料含有0.1-10重量%的棕榈纤维,并且其中所述棕榈纤维的纤维长度范围为2mm至15mm。15. The environmental protection preparation method of the high-strength, ultra-light, fire-proof green thermal insulation board according to any one of claims 1-13, the method comprises the step of mixing palm fiber with other raw materials; wherein based on raw materials other than water The raw material contains 0.1-10% by weight of palm fibers, and wherein the palm fibers have a fiber length ranging from 2 mm to 15 mm. 16.权利要求15所述的方法,其中所述方法包括以下步骤:16. The method of claim 15, wherein the method comprises the steps of: a)在400-800rpm的转速下混合水、活性粉末、硬化剂、泡沫稳定剂、棕榈纤维和任选的功能性外加剂至均质,其中水与除水之外的原料的体积比为1∶50至1∶2;a) Mix water, active powder, hardener, foam stabilizer, palm fiber and optional functional admixtures to homogeneity at a rotational speed of 400-800 rpm, wherein the volume ratio of water to raw materials other than water is 1 : 50 to 1:2; b)向a)的混合物中加入发泡剂在700-1000rpm的转速下保持3-15秒以产生孔结构;b) adding a blowing agent to the mixture of a) at 700-1000 rpm for 3-15 seconds to create a cell structure; c)将b)的混合物倒入容器模具中并固化1-12小时;c) pour the mixture of b) into a container mould and cure for 1-12 hours; d)将c)的固化后的板脱模并切割成所需尺寸,以及d) demoulding and cutting the cured panel of c) to the desired size, and e)继续固化d)的切割后的板1-30天;所述除水以外的原料包括活性粉末、硬化剂、发泡剂、泡沫稳定剂和任选的功能性外加剂;并且其中e) continue to cure the cut board of d) for 1-30 days; the raw materials other than water include active powder, hardener, foaming agent, foam stabilizer and optional functional admixtures; and wherein 所述活性粉末选自矿渣、煤灰、硅粉和偏高岭土中的三种或更多种;The active powder is selected from three or more of slag, coal ash, silica fume and metakaolin; 所述硬化剂选自硅酸钠、硅酸钾、氢氧化钾和氢氧化钠中的两种或更多种;The hardener is selected from two or more of sodium silicate, potassium silicate, potassium hydroxide and sodium hydroxide; 所述发泡剂选自过氧化氢和铝粉中的一种或多种;The foaming agent is selected from one or more of hydrogen peroxide and aluminum powder; 所述泡沫稳定剂选自硬脂酸钙和硅酮酰胺中的一种或多种;以及The foam stabilizer is selected from one or more of calcium stearate and silicone amide; and 所述任选的功能性外加剂选自减水剂、缓凝剂和颜料中的一种或多种。The optional functional admixture is selected from one or more of water reducers, retarders and pigments. 17.权利要求16所述的方法,其中所述步骤b)在15-35℃的温度范围内进行;步骤c)在≤100℃的温度范围内进行;且步骤c)在≥50%湿度下固化;当取样步骤c)的混合物至190-270kg/m3密度范围内时,进行步骤d)。17. The method of claim 16, wherein step b) is performed in a temperature range of 15-35°C; step c) is performed in a temperature range of ≤ 100°C; and step c) is performed at ≥ 50% humidity Curing; Step d) is carried out when the mixture of step c) is sampled to a density range of 190-270 kg/ m3 .
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