CN110747072B - Environment-friendly automobile detergent - Google Patents
Environment-friendly automobile detergent Download PDFInfo
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- CN110747072B CN110747072B CN201911150591.XA CN201911150591A CN110747072B CN 110747072 B CN110747072 B CN 110747072B CN 201911150591 A CN201911150591 A CN 201911150591A CN 110747072 B CN110747072 B CN 110747072B
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
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Abstract
The invention discloses an environment-friendly automobile detergent, which comprises 0.5-2% of oil tea saponin, 0.5-1% of soapberry saponin, 1-3% of black tiger extract, 1-3% of acacia tannin extract, 0.2-0.8% of essence, deionized water and the like. The prepared automobile detergent is added with natural nonionic surfactants of the oil-tea saponin and the soapberry saponin, and the surface activity of a compound system is improved after the natural nonionic surfactants of the oil-tea saponin and the soapberry saponin are compounded with other surfactants, so that the cleaning effect is better, and the natural product is free from pollution to the environment after being washed. The black cutworm extract and the acacia queliana extract are added into the detergent, and the decontamination capability of the detergent is remarkably improved by the black cutworm extract and the acacia queliana extract. Compared with synthetic detergents, the invention has the advantages of better cleaning effect, better biodegradability, environment-friendly degradation product and the like.
Description
Technical Field
The invention belongs to the technical field of cleaning products, and particularly relates to an environment-friendly automobile detergent.
Background
The earliest detergents used by humans were soaps, and with the development of organic synthetic surfactants, synthetic detergents were widely used in the washing industry and gradually replaced soaps.
With the rapid increase of the automobile market and the continuous improvement of living conditions of people, the quantity of automobiles kept in China reaches 2.29 hundred million, and the automobiles will continuously increase in recent years, and each automobile needs to be cleaned for many times, so that the automobile cleaning market is huge. However, the main components of the automobile detergent used in the current market are branched alkyl benzene compounds, nitrides and phosphates, and although the cleaning effect of the compounds is good, the biodegradability of the compounds is poor, and the direct discharge of decomposition products can cause eutrophication of water bodies and environmental pollution. In the face of the condition that water resources are increasingly deficient, water is saved urgently, a large amount of clear water is needed for cleaning one vehicle, and the cleaned water needs to be treated, so that the financial resources and the material resources which are invested for cleaning the vehicle in China every year are more.
At present, natural cleaning products with proprietary intellectual property rights are developed by a plurality of foreign institutions, and the detergent is close to the standard of no toxicity and no public hazard. In China, there have been descriptions about washing hair with eggs, soaking clothes with Chinese honeylocust fruit, etc., which suggests that the development of detergents from natural resources is promising. In response to the gradual deterioration of the environment, the replacement of synthetic products with natural products is a trend of market development in the future. Some natural detergent products have also appeared on the market, but the use effect is not ideal, and the detergent is decomposed slowly after washing, which has adverse effect on the environment.
Disclosure of Invention
In order to solve the technical problems, the invention provides an environment-friendly automobile detergent, which is prepared by changing the formula of the traditional detergent and adding substances with natural environment-friendly performance and high and new cleaning effect, and achieves the purposes of high-efficiency decontamination, energy conservation and environmental protection, and can be washed clean by a small amount of water.
The purpose of the invention can be realized by the following technical scheme:
the environment-friendly automobile detergent comprises the following components in percentage by mass: 0.5-2% of oil tea saponin, 0.5-1% of soapberry saponin, 0.8-1.2% of sodium perborate, 0.6-1% of sodium carbonate, 4-6% of lauryl glucoside, 0.6-1.0% of fatty alcohol-polyoxyethylene ether sodium sulfate, 2-3% of fatty acid methyl ester sulfonate, 1-3% of coconut oil fatty acid diethanolamide, 0.4-0.8% of sorbitan monolaurate, 1-2% of sec-butyl alcohol, 1-3% of wood vinegar, 0.8-1.2% of enzyme, 1-3% of kadsura coccinea extract, 1-3% of Maria abrata extract, 0.4-0.8% of essence, 0.1-0.3% of preservative and the balance of deionized water.
Preferably, the environment-friendly automobile detergent comprises the following components in percentage by mass: 1% of oil tea saponin, 0.8% of soapberry saponin, 1% of sodium perborate, 0.8% of sodium carbonate, 4.8% of lauryl glucoside, 0.8% of fatty alcohol-polyoxyethylene ether sodium sulfate, 2.4% of fatty acid methyl ester sulfonate, 2% of coconut oil fatty acid diethanolamide, 0.5% of sorbitan monolaurate, 1.4% of sec-butyl alcohol, 2% of wood vinegar, 1% of enzyme, 2% of black tiger extract, 2% of Marina abrotanum tannin extract, 0.6% of essence, 0.2% of preservative and the balance of deionized water.
The oil tea saponin can be a directly purchased product or a product prepared by the following method: the oil tea saponin powder is prepared by drying an oil tea seed cake at 55-65 ℃ until the moisture content is less than 5%, crushing, sieving with a 40-50 mesh sieve, adding 40-60% of low-alcohol for extraction, heating in a water bath at 50-70 ℃ for 3-4h, concentrating and drying the obtained filtrate, and the oil tea saponin powder contains 15-20% of oil tea saponin by mass. The lower alcohol may be ethanol, propanol, isopropanol, etc.
The soapberry saponin can be a product which is directly purchased in the market and can also be a product prepared by the following method: the soapberry saponin powder is prepared by drying soapberry pericarp at 65-75 ℃ until the moisture content is less than 5%, crushing, sieving with a 50-60-mesh sieve, placing in a conical flask, adding 60-90% of low-alcohol, shaking uniformly, performing ultrasound for 30-50 min, concentrating the obtained filtrate, and drying to obtain the soapberry saponin powder, wherein the soapberry saponin powder contains 10-15% of soapberry saponin by mass. The lower alcohol may be ethanol, propanol, isopropanol, etc.
The black tiger extract can be a product which is directly purchased in the market and also can be a product prepared by the following method: the black cutworm extract is prepared by extracting black cutworm stems and leaves with 40-60% ethanol, concentrating under reduced pressure, passing through an AB-8 type macroporous resin column, eluting with 50-70% ethanol, and evaporating ethanol to obtain a second concentrated solution, wherein the second concentrated solution contains 5-7% by mass of terpineol.
Preferably, the environment-friendly automobile detergent is prepared by the following method:
1) adding the measured oil tea saponin, soapnut saponin and sodium perborate into a beaker filled with 35-45g of deionized water, heating to 55-65 ℃ by using a constant-temperature water bath kettle, uniformly stirring for 20-30 min at the temperature, adding sodium carbonate to adjust the pH value to 8.5-9.5, and using the mixture as solution A for later use;
1) adding the metered lauryl glucoside, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid methyl ester sulfonate, coconut oil fatty acid diethanolamide, sorbitan monolaurate and sec-butyl alcohol into a beaker filled with deionized water, stirring for 10-30 min, adding wood vinegar and enzyme, and stirring uniformly to obtain a mixture B;
1) and adding the mixture B into the solution A, uniformly mixing, adding the black tiger extract, the acacia mangosteen extract, the essence and the preservative, adding deionized water to 100g, and stirring for 2min-5min to obtain the environment-friendly automobile detergent.
Preferably, the essence is lavender essence.
Preferably, the preservative is a kaempferon preservative.
Compared with the prior art, the invention has the beneficial effects that:
the detergent prepared by the invention contains natural saponin, wherein the oil-tea saponin and the soapberry saponin have excellent washing performance and can be biodegraded in percent, so that phosphorus and nitrogen compounds in the synthetic detergent are replaced, and the detergent after washing is easy to degrade and reaches the standard of no toxicity and no public nuisance. The black cutworm extract and the acacia queliana extract are added into the detergent, and the decontamination capability of the detergent is remarkably improved by the black cutworm extract and the acacia queliana extract. The detergent prepared by the invention can be washed clean by a small amount of water after cleaning the vehicle body, thereby greatly saving the water consumption.
Detailed Description
The present invention is further illustrated by the following examples, which are intended to be purely exemplary of the invention and are not to be construed as limiting the invention in any way.
The reagents used in the present application are commercially available unless otherwise specified. Oil tea saponin, a Jincheng grease factory in Changshan county; sapindoside, sienna lilac ring biotechnology ltd; maran Acacia tannin extract, Changsheng chemical industry business in Jinshui district of Zhengzhou city.
Example 1
An environment-friendly automobile detergent comprises the following raw materials in parts by weight: 0.5% of oil tea saponin, 0.5% of soapberry saponin, 0.8% of sodium perborate, 0.6% of sodium carbonate, 4% of lauryl glucoside, 0.6% of fatty alcohol-polyoxyethylene ether sodium sulfate, 2% of fatty acid methyl ester sulfonate, 1% of coconut oil fatty acid diethanolamide, 0.4% of sorbitan monolaurate, 1% of sec-butyl alcohol, 1% of wood vinegar, 0.8% of ferment, 1% of black tiger extract, 1% of acacia tannin extract, 0.4% of essence, 0.1% of preservative and 84.3% of deionized water.
The environment-friendly automobile detergent is prepared by the following steps:
1) adding measured oil tea saponin, soapnut saponin and sodium perborate into a beaker filled with 40g of deionized water, heating to 60 ℃ by using a constant-temperature water bath kettle, stirring at constant speed for 20min at the temperature, and adding sodium carbonate to adjust the pH to about 9.0 to serve as liquid A for later use;
2) adding the metered lauryl glucoside, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid methyl ester sulfonate, coconut oil fatty acid diethanolamide, sorbitan monolaurate and sec-butyl alcohol into a beaker filled with deionized water, stirring for 10min, adding wood vinegar and enzyme, and stirring uniformly to prepare a mixture B;
3) and adding the mixture B into the solution A, uniformly mixing, adding the black tiger extract, the acacia mangosteen extract, the essence and the preservative, adding deionized water to 100g, and stirring for 2min to obtain the environment-friendly automobile detergent.
Example 2
An environment-friendly automobile detergent comprises the following raw materials in parts by weight: 2% of oil tea saponin, 1% of soapberry saponin, 1.2% of sodium perborate, 1% of sodium carbonate, 6% of lauryl glucoside, 1% of fatty alcohol-polyoxyethylene ether sodium sulfate, 3% of fatty acid methyl ester sulfonate, 3% of coconut oil fatty acid diethanolamide, 0.8% of sorbitan monolaurate, 2% of sec-butyl alcohol, 3% of wood vinegar, 1.2% of enzyme, 3% of black tiger extract, 3% of Ma-Yuan-Si tannin extract, 0.8% of essence, 0.3% of preservative and 67.7% of deionized water.
The environment-friendly automobile detergent is prepared by the following steps:
1) adding measured oil tea saponin, soapnut saponin and sodium perborate into a beaker filled with 40g of deionized water, heating to 60 ℃ by using a constant-temperature water bath kettle, stirring at constant speed for 20min at the temperature, and adding sodium carbonate to adjust the pH to about 9.0 to serve as liquid A for later use;
2) adding the metered lauryl glucoside, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid methyl ester sulfonate, coconut oil fatty acid diethanolamide, sorbitan monolaurate and sec-butyl alcohol into a beaker filled with deionized water, stirring for 10min, adding wood vinegar and enzyme, and stirring uniformly to prepare a mixture B;
3) and adding the mixture B into the solution A, uniformly mixing, adding the black tiger extract, the acacia mangosteen extract, the essence and the preservative, adding deionized water to 100g, and stirring for 2min to obtain the environment-friendly automobile detergent.
Example 3
An environment-friendly automobile detergent comprises the following raw materials in parts by weight: 1% of oil tea saponin, 0.8% of soapberry saponin, 1% of sodium perborate, 0.8% of sodium carbonate, 4.8% of lauryl glucoside, 0.8% of fatty alcohol-polyoxyethylene ether sodium sulfate, 2.4% of fatty acid methyl ester sulfonate, 2% of coconut oil fatty acid diethanolamide, 0.5% of sorbitan monolaurate, 1.4% of sec-butyl alcohol, 2% of wood vinegar, 1% of enzyme, 2% of black tiger extract, 2% of acacia tannin extract, 0.6% of essence, 0.2% of preservative and 76.7% of deionized water.
The oil tea saponin is prepared by the following method:
taking 100-120g of camellia seed cake, drying at 60 ℃ until the moisture content is less than 5%, crushing, sieving with a 40-mesh sieve, adding 40-60% of low-alcohol for extraction, heating in a water bath at 50-70 ℃ for 3.5h, concentrating the obtained filtrate by using a rotary evaporator, and drying to obtain the camellia saponin powder, wherein the camellia saponin powder contains 15-20% of the camellia saponin by mass.
The soapberry saponin is prepared by the following method:
drying 140-160g of soapberry peel at 70 ℃ until the moisture content is less than 5%, crushing, sieving with a 60-mesh sieve, placing into a conical flask, adding 60-90% of low-alcohol, shaking uniformly, placing into an ultrasonic cleaning machine, carrying out ultrasonic treatment for 30min, concentrating the obtained filtrate with a rotary evaporator, and drying to obtain the soapberry saponin powder, wherein the soapberry saponin powder contains 10-15% of soapberry saponin by mass.
The black tiger extract is prepared by the following method:
adding 8-9kg of black tiger stem and leaf and 40-60% ethanol by volume into an extraction tank, wherein the mass (kg)/volume ratio (L) of the black tiger stem and leaf and the ethanol with the 50% concentration by volume is 1:5-1:7, reflux heating (boiling) for 1-3 hours to obtain an extracting solution, carrying out reduced pressure concentration under-0.25-0.75 Mpa until the concentrated solution is 0.5-1 time of the black tiger stem and leaf mass, passing the concentrated solution through AB-8 type macroporous resin, washing a column with 8-10 times of the black tiger stem and leaf mass of distilled water, eluting with 50-70% ethanol by volume, detecting the terpineol content in the eluent on line, stopping elution after the mass content of the component in the eluent is lower than 0.6%, evaporating and concentrating the eluent to obtain a second concentrated solution (black tiger extracting solution), the second concentrated solution contains 5-7% by mass of terpineol.
The environment-friendly automobile detergent is prepared by the following steps:
1) adding measured oil tea saponin, soapnut saponin and sodium perborate into a beaker filled with 40g of deionized water, heating to 60 ℃ by using a constant-temperature water bath kettle, stirring at constant speed for 20min at the temperature, and adding sodium carbonate to adjust the pH to about 9.0 to serve as liquid A for later use;
2) adding the metered lauryl glucoside, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid methyl ester sulfonate, coconut oil fatty acid diethanolamide, sorbitan monolaurate and sec-butyl alcohol into a beaker filled with deionized water, stirring for 10min, adding wood vinegar and enzyme, and stirring uniformly to prepare a mixture B;
3) and adding the mixture B into the solution A, uniformly mixing, adding the black tiger extract, the acacia mangosteen extract, the essence and the preservative, adding deionized water to 100g, and stirring for 2min to obtain the environment-friendly automobile detergent.
Example 4
An environment-friendly automobile detergent comprises the following raw materials in parts by weight: 1.5% of oil tea saponin, 0.8% of soapberry saponin, 1% of sodium perborate, 0.8% of sodium carbonate, 5% of lauryl glucoside, 0.8% of fatty alcohol-polyoxyethylene ether sodium sulfate, 2.8% of fatty acid methyl ester sulfonate, 2% of coconut oil fatty acid diethanolamide, 0.6% of sorbitan monolaurate, 1.8% of sec-butyl alcohol, 2% of wood vinegar, 1% of ferment, 2% of black tiger extract, 2% of acacia tannin extract, 0.6% of essence, 0.2% of preservative and 75.1% of deionized water.
The environment-friendly automobile detergent is prepared by the following steps:
1) adding measured oil tea saponin, soapnut saponin and sodium perborate into a beaker filled with 40g of deionized water, heating to 60 ℃ by using a constant-temperature water bath kettle, stirring at constant speed for 20min at the temperature, and adding sodium carbonate to adjust the pH to about 9.0 to serve as liquid A for later use;
2) adding the metered lauryl glucoside, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid methyl ester sulfonate, coconut oil fatty acid diethanolamide, sorbitan monolaurate and sec-butyl alcohol into a beaker filled with deionized water, stirring for 10min, adding wood vinegar and enzyme, and stirring uniformly to prepare a mixture B;
3) and adding the mixture B into the solution A, uniformly mixing, adding the black tiger extract, the acacia mangosteen extract, the essence and the preservative, adding deionized water to 100g, and stirring for 2min to obtain the environment-friendly automobile detergent.
Example 5
An environment-friendly automobile detergent comprises the following raw materials in parts by weight: 1% of oil tea saponin, 0.8% of soapberry saponin, 1% of sodium perborate, 0.8% of sodium carbonate, 4.8% of lauryl glucoside, 0.8% of fatty alcohol-polyoxyethylene ether sodium sulfate, 2.4% of fatty acid methyl ester sulfonate, 2% of coconut oil fatty acid diethanolamide, 0.5% of sorbitan monolaurate, 1.4% of sec-butyl alcohol, 1% of wood vinegar, 1.2% of enzyme, 2% of black tiger extract, 2% of acacia tannin extract, 0.6% of essence, 0.2% of preservative and 76.7% of deionized water.
The environment-friendly automobile detergent is prepared by the following steps:
1) adding measured oil tea saponin, soapnut saponin and sodium perborate into a beaker filled with 40g of deionized water, heating to 60 ℃ by using a constant-temperature water bath kettle, stirring at constant speed for 20min at the temperature, and adding sodium carbonate to adjust the pH to about 9.0 to serve as liquid A for later use;
2) adding the metered lauryl glucoside, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid methyl ester sulfonate, coconut oil fatty acid diethanolamide, sorbitan monolaurate and sec-butyl alcohol into a beaker filled with deionized water, stirring for 10min, adding wood vinegar and enzyme, and stirring uniformly to prepare a mixture B;
3) and adding the mixture B into the solution A, uniformly mixing, adding the black tiger extract, the acacia mangosteen extract, the essence and the preservative, adding deionized water to 100g, and stirring for 2min to obtain the environment-friendly automobile detergent.
Example 6
An environment-friendly automobile detergent comprises the following raw materials in parts by weight: 1% of oil tea saponin, 0.8% of soapberry saponin, 1% of sodium perborate, 0.8% of sodium carbonate, 4.8% of lauryl glucoside, 0.8% of fatty alcohol-polyoxyethylene ether sodium sulfate, 2.4% of fatty acid methyl ester sulfonate, 2% of coconut oil fatty acid diethanolamide, 0.5% of sorbitan monolaurate, 1.4% of sec-butyl alcohol, 3% of wood vinegar, 0.8% of enzyme, 2% of black tiger extract, 2% of acacia tannin extract, 0.6% of essence, 0.2% of preservative and 75.9% of deionized water.
The environment-friendly automobile detergent is prepared by the following steps:
4) adding measured oil tea saponin, soapnut saponin and sodium perborate into a beaker filled with 40g of deionized water, heating to 60 ℃ by using a constant-temperature water bath kettle, stirring at constant speed for 20min at the temperature, and adding sodium carbonate to adjust the pH to about 9.0 to serve as liquid A for later use;
5) adding the metered lauryl glucoside, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid methyl ester sulfonate, coconut oil fatty acid diethanolamide, sorbitan monolaurate and sec-butyl alcohol into a beaker filled with deionized water, stirring for 10min, adding wood vinegar and enzyme, and stirring uniformly to prepare a mixture B;
6) and adding the mixture B into the solution A, uniformly mixing, adding the black tiger extract, the acacia mangosteen extract, the essence and the preservative, adding deionized water to 100g, and stirring for 2min to obtain the environment-friendly automobile detergent.
Example 7
An environment-friendly automobile detergent comprises the following raw materials in parts by weight: 1% of oil tea saponin, 0.8% of soapberry saponin, 1% of sodium perborate, 0.8% of sodium carbonate, 4.8% of lauryl glucoside, 0.8% of fatty alcohol-polyoxyethylene ether sodium sulfate, 2.4% of fatty acid methyl ester sulfonate, 2% of coconut oil fatty acid diethanol amide, 0.5% of sorbitan monolaurate, 1.4% of sec-butyl alcohol, 2% of wood vinegar, 1% of ferment, 2% of black tiger extract, 0.4% of essence, 0.2% of preservative and 78.9% of deionized water.
The environment-friendly automobile detergent is prepared by the following steps:
1) adding measured oil tea saponin, soapnut saponin and sodium perborate into a beaker filled with 40g of deionized water, heating to 60 ℃ by using a constant-temperature water bath kettle, stirring at constant speed for 20min at the temperature, and adding sodium carbonate to adjust the pH to about 9.0 to serve as liquid A for later use;
2) adding the metered lauryl glucoside, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid methyl ester sulfonate, coconut oil fatty acid diethanolamide, sorbitan monolaurate and sec-butyl alcohol into a beaker filled with deionized water, stirring for 10min, adding wood vinegar and enzyme, and stirring uniformly to prepare a mixture B;
3) and adding the mixture B into the solution A, uniformly mixing, adding the black tiger extract, the essence and the preservative, adding deionized water to 100g, and stirring for 2min to obtain the environment-friendly automobile detergent.
Example 8
An environment-friendly automobile detergent comprises the following raw materials in parts by weight: 1% of oil tea saponin, 0.8% of soapberry saponin, 1% of sodium perborate, 0.8% of sodium carbonate, 4.8% of lauryl glucoside, 0.8% of fatty alcohol-polyoxyethylene ether sodium sulfate, 2.4% of fatty acid methyl ester sulfonate, 2% of coconut oil fatty acid diethanolamide, 0.5% of sorbitan monolaurate, 1.4% of sec-butyl alcohol, 2% of wood vinegar, 1% of enzyme, 2% of acacia tannin, 0.4% of essence, 0.1% of preservative and 78.9% of deionized water.
The environment-friendly automobile detergent is prepared by the following steps:
1) adding measured oil tea saponin, soapnut saponin and sodium perborate into a beaker filled with 40g of deionized water, heating to 60 ℃ by using a constant-temperature water bath kettle, stirring at constant speed for 20min at the temperature, and adding sodium carbonate to adjust the pH to about 9.0 to serve as liquid A for later use;
2) adding the metered lauryl glucoside, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid methyl ester sulfonate, coconut oil fatty acid diethanolamide, sorbitan monolaurate and sec-butyl alcohol into a beaker filled with deionized water, stirring for 10min, adding wood vinegar and enzyme, and stirring uniformly to prepare a mixture B;
3) and adding the mixture B into the solution A, uniformly mixing, adding the Marsdenia abrata tannin extract, the essence and the preservative, adding deionized water to 100g, and stirring for 2min to obtain the environment-friendly automobile detergent.
Comparative example 1
The automobile detergent prepared according to the present comparative example was prepared without adding the black tiger extract and the acacia tannin extract in the preparation process, compared to example 3. The environment-friendly automobile detergent is prepared by the following steps:
4) adding measured oil tea saponin, soapnut saponin and sodium perborate into a beaker filled with 40g of deionized water, heating to 60 ℃ by using a constant-temperature water bath kettle, stirring at constant speed for 20min at the temperature, and adding sodium carbonate to adjust the pH to about 9.0 to serve as liquid A for later use;
5) adding the metered lauryl glucoside, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid methyl ester sulfonate, coconut oil fatty acid diethanolamide, sorbitan monolaurate and sec-butyl alcohol into a beaker filled with deionized water, stirring for 10min, adding wood vinegar and enzyme, and stirring uniformly to prepare a mixture B;
6) and adding the mixture B into the solution A, uniformly mixing, adding essence and preservative, adding deionized water to 100g, and stirring for 2min to obtain the environment-friendly automobile detergent.
Comparative example 2
This comparative example is a car detergent purchased in the market.
The foam performance and the stain removal performance of the automobile detergents prepared in examples 1 to 8 and comparative examples 1 to 2 were measured.
Measurement of foam Properties: according to the standard GB/T-7462-.
Determination of defoaming Properties: the observation records the time taken for the automobile detergents prepared in examples 1 to 7 and comparative examples 1 to 2 to naturally defoam after the end of foaming.
Measurement of cleaning efficiency: the detergency of examples 1 to 7 of the present invention and comparative examples 1 to 2 was measured in accordance with standard MHT 6007-1998.
1) Coating oil stains: the weighed test panel was laid flat on clean paper, and the artificial oil stain was taken in with a small spatula and uniformly coated on the center of the test panel (area 17.0 cm. times.5.0 cm). The coating amount of the oil stain is 150mg +/-50 mg. The coated test plate is dried for 60min at 105 +/-5 ℃, put into a dryer for cooling, and weighed to be-0.1 mg for later use.
2) The prepared automobile detergent and the reference solution are respectively prepared into 10 percent distilled water diluent. The oil-stained test panel was placed in a 40.0cm x 30.0cm dish, about 150ml of diluent was added to the dish to completely immerse the test panel in the solution for 30 seconds, and the test panel was scrubbed with a sponge-attached cleaning shampoo. Before scrubbing, the sponge is soaked by diluted solution, and the cleaning head is uniformly pulled by a force parallel to the test plate for 5 times. Finally, the test panels were rinsed with copious amounts of distilled water. Oven dry at 105 ℃ 5 for 10min, cool to room temperature, weigh-1 mg. And respectively calculating the cleaning efficiency according to a formula.
The results are shown in table 1 below:
TABLE 1
According to the results in table 1, as can be seen from the comparison between the cleaning effects of the formulations of examples 1 to 8 and the cleaning effects of the formulations of comparative examples 1 to 2, the automobile detergent added with the black tiger extract and the acacia tannin extract has foam performance, defoaming capability and cleaning efficiency which are obviously superior to those of the formulation only containing the saponin-surfactant compound system. It can be seen that the black tiger extract and the acacia tannin extract play a more critical role in cleaning efficiency. Particularly, as can be seen from the comparison between the cleaning efficiency of the formulations of examples 1 to 6 and the cleaning efficiency of the formulations of examples 7 to 8, when the black tiger extract and the acacia tannin extract coexist in the formulations, a synergistic effect is generated between the black tiger extract and the acacia tannin extract, and the cleaning efficiency of the formulations is improved. Further, from the results of examples, it is found that the effect is most preferable at a usage amount of 2% in the examples, as the black tiger extract and the acacia tannin extract are respectively 1% to 3% in the usage range of the black tiger extract and the acacia tannin extract, not as much as possible. While the present application has been described with reference to specific embodiments, those skilled in the art will appreciate that various changes can be made without departing from the true spirit and scope of the present application. In addition, many modifications may be made to adapt a particular situation, material, composition of matter, and method to the objective, spirit and scope of the present application. All such modifications are intended to be included within the scope of the claims of this application.
Claims (7)
1. The environment-friendly automobile detergent is characterized by comprising the following components in percentage by mass: 0.5-2% of oil tea saponin, 0.5-1% of soapberry saponin, 0.8-1.2% of sodium perborate, 0.6-1% of sodium carbonate, 4-6% of lauryl glucoside, 0.6-1.0% of fatty alcohol-polyoxyethylene ether sodium sulfate, 2-3% of fatty acid methyl ester sulfonate, 1-3% of coconut oil fatty acid diethanolamide, 0.4-0.8% of sorbitan monolaurate, 1-2% of sec-butyl alcohol, 1-3% of wood vinegar, 0.8-1.2% of enzyme, 1-3% of kadsura coccinea extract, 1-3% of acacia tannin extract, 0.4-0.8% of essence, 0.1-0.3% of preservative and the balance of deionized water; the preparation method comprises the following steps:
1) adding the measured oil tea saponin, soapnut saponin and sodium perborate into a beaker filled with 35-45g of deionized water, heating to 55-65 ℃ by using a constant-temperature water bath kettle, uniformly stirring for 20-30 min at the temperature, adding sodium carbonate to adjust the pH value to 8.5-9.5, and using the mixture as solution A for later use;
2) adding the metered lauryl glucoside, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty acid methyl ester sulfonate, coconut oil fatty acid diethanolamide, sorbitan monolaurate and sec-butyl alcohol into a beaker filled with deionized water, stirring for 10-30 min, adding wood vinegar and enzyme, and stirring uniformly to obtain a mixture B;
3) and adding the mixture B into the solution A, uniformly mixing, adding the black tiger extract, the acacia mangosteen extract, the essence and the preservative, adding deionized water to 100g, and stirring for 2min-5min to obtain the environment-friendly automobile detergent.
2. The environment-friendly automobile detergent as claimed in claim 1, which comprises the following components in percentage by mass: 1% of oil tea saponin, 0.8% of soapberry saponin, 1% of sodium perborate, 0.8% of sodium carbonate, 4.8% of lauryl glucoside, 0.8% of fatty alcohol-polyoxyethylene ether sodium sulfate, 2.4% of fatty acid methyl ester sulfonate, 2% of coconut oil fatty acid diethanolamide, 0.5% of sorbitan monolaurate, 1.4% of sec-butyl alcohol, 2% of wood vinegar, 1% of enzyme, 2% of black tiger extract, 2% of acacia tannin extract, 0.6% of essence, 0.2% of preservative and 76.7% of deionized water.
3. The environment-friendly automobile detergent as claimed in claim 1, wherein the essence is lavender essence.
4. The environment-friendly automobile detergent as claimed in claim 1, wherein the preservative is a kaempon preservative.
5. The environment-friendly automobile detergent as claimed in any one of claims 1-4, wherein the sasanqua saponin powder comprises sasanqua saponin 15-20% by mass by drying sasanqua seed cake at 55-65 ℃ until the water content is less than 5%, pulverizing, sieving with a 40-50 mesh sieve, extracting with 40-60% low-alcohol, heating in water bath at 50-70 ℃ for 3-4h, concentrating the filtrate, and drying.
6. The environment-friendly automobile detergent as claimed in any one of claims 1-4, wherein the sapindoside is prepared by drying sapindus mukorossi pericarp at 65-75 deg.C until the water content is less than 5%, pulverizing, sieving with 50-60 mesh sieve, placing in a conical flask, adding 60-90% low-alcohol, shaking, performing ultrasound for 30-50 min, concentrating the filtrate, and drying to obtain sapindoside powder containing 10-15% sapindoside by mass.
7. The environment-friendly automobile detergent as claimed in any one of claims 1-4, wherein the black tiger extract is prepared by extracting black tiger stems and leaves with 40-60% ethanol, concentrating under reduced pressure, passing through AB-8 type macroporous resin column, eluting with 50-70% ethanol, and evaporating ethanol to obtain a second concentrated solution, wherein the second concentrated solution contains 5-7% by mass of terpineol.
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