CN110746933A - 一种基于偶联反应实现缓慢释放的主动型融雪剂及其制备方法 - Google Patents
一种基于偶联反应实现缓慢释放的主动型融雪剂及其制备方法 Download PDFInfo
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- CN110746933A CN110746933A CN201911136538.4A CN201911136538A CN110746933A CN 110746933 A CN110746933 A CN 110746933A CN 201911136538 A CN201911136538 A CN 201911136538A CN 110746933 A CN110746933 A CN 110746933A
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- solution
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- snow
- slow release
- melting agent
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Links
- 238000002844 melting Methods 0.000 title claims abstract description 63
- 238000005859 coupling reaction Methods 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000002893 slag Substances 0.000 claims abstract description 53
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 47
- 230000007797 corrosion Effects 0.000 claims abstract description 40
- 238000005260 corrosion Methods 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 37
- 239000010959 steel Substances 0.000 claims abstract description 37
- 239000000463 material Substances 0.000 claims abstract description 32
- 239000012876 carrier material Substances 0.000 claims abstract description 29
- 239000003112 inhibitor Substances 0.000 claims abstract description 29
- 150000003839 salts Chemical class 0.000 claims abstract description 25
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 22
- 230000002940 repellent Effects 0.000 claims abstract description 21
- 239000005871 repellent Substances 0.000 claims abstract description 21
- 239000000853 adhesive Substances 0.000 claims abstract description 19
- 230000001070 adhesive effect Effects 0.000 claims abstract description 19
- 239000007822 coupling agent Substances 0.000 claims abstract description 19
- 238000002156 mixing Methods 0.000 claims abstract description 19
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 11
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 7
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000176 sodium gluconate Substances 0.000 claims abstract description 6
- 235000012207 sodium gluconate Nutrition 0.000 claims abstract description 6
- 229940005574 sodium gluconate Drugs 0.000 claims abstract description 6
- MFXMOUUKFMDYLM-UHFFFAOYSA-L zinc;dihydrogen phosphate Chemical compound [Zn+2].OP(O)([O-])=O.OP(O)([O-])=O MFXMOUUKFMDYLM-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000000243 solution Substances 0.000 claims description 49
- 239000000203 mixture Substances 0.000 claims description 40
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 18
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 17
- 229910000077 silane Inorganic materials 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 10
- 238000000227 grinding Methods 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 238000005266 casting Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 5
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 239000002244 precipitate Substances 0.000 claims description 3
- 239000012047 saturated solution Substances 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 229910001514 alkali metal chloride Inorganic materials 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- -1 alkaline earth metal bicarbonate Chemical class 0.000 claims description 2
- 229910001617 alkaline earth metal chloride Inorganic materials 0.000 claims description 2
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 2
- 239000011230 binding agent Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 6
- 239000002699 waste material Substances 0.000 abstract description 5
- 238000010276 construction Methods 0.000 abstract description 2
- 230000008018 melting Effects 0.000 description 15
- 239000010426 asphalt Substances 0.000 description 13
- 238000012360 testing method Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000047 product Substances 0.000 description 7
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- 238000007710 freezing Methods 0.000 description 6
- 230000008014 freezing Effects 0.000 description 6
- 230000002829 reductive effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 229910000975 Carbon steel Inorganic materials 0.000 description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- 239000010962 carbon steel Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical group [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 4
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 description 3
- 229940050410 gluconate Drugs 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical group [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 150000003841 chloride salts Chemical class 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000002440 industrial waste Substances 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 235000019359 magnesium stearate Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- XYRAEZLPSATLHH-UHFFFAOYSA-N trisodium methoxy(trioxido)silane Chemical compound [Na+].[Na+].[Na+].CO[Si]([O-])([O-])[O-] XYRAEZLPSATLHH-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910000954 Medium-carbon steel Inorganic materials 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 206010039203 Road traffic accident Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011549 displacement method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- KAEAMHPPLLJBKF-UHFFFAOYSA-N iron(3+) sulfide Chemical compound [S-2].[S-2].[S-2].[Fe+3].[Fe+3] KAEAMHPPLLJBKF-UHFFFAOYSA-N 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000005413 snowmelt Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
- C09K3/185—Thawing materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
Description
融雪剂种类 | 对金属碳钢腐蚀率(mm/a) |
对照例1 | 0.277 |
实施例1 | 0.073 |
对照例2 | 0.262 |
实施例2 | 0.034 |
对照例3 | 0.423 |
实施例3 | 0.062 |
Claims (10)
Priority Applications (1)
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CN201911136538.4A CN110746933B (zh) | 2019-11-19 | 2019-11-19 | 一种基于偶联反应实现缓慢释放的主动型融雪剂及其制备方法 |
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CN201911136538.4A CN110746933B (zh) | 2019-11-19 | 2019-11-19 | 一种基于偶联反应实现缓慢释放的主动型融雪剂及其制备方法 |
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CN110746933A true CN110746933A (zh) | 2020-02-04 |
CN110746933B CN110746933B (zh) | 2022-05-20 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111675506A (zh) * | 2020-05-29 | 2020-09-18 | 山东高速集团有限公司创新研究中心 | 一种抗凝冰剂及其制备方法 |
CN115260991A (zh) * | 2022-07-27 | 2022-11-01 | 胡勇 | 一种包覆型融雪剂及其制备方法与应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101735770A (zh) * | 2008-11-18 | 2010-06-16 | 熊长宏 | 高效复合防腐型融雪剂 |
US20140091251A1 (en) * | 2012-03-09 | 2014-04-03 | Hubei Expressway Business Development Co., Ltd | Slow release anti-icing material for bituminous pavement and preparation method thereof |
CN106893139A (zh) * | 2017-03-30 | 2017-06-27 | 安徽工业大学 | 一种用于橡胶填料的改性多孔钢渣及其制备方法 |
CN108623200A (zh) * | 2018-05-15 | 2018-10-09 | 长安大学 | 一种用于自融雪沥青路面的裹油型盐化物及其制备方法 |
CN109054415A (zh) * | 2018-09-11 | 2018-12-21 | 河南省济阳高速公路建设有限公司 | 一种主动式融雪除冰沥青混合料及其制备方法 |
-
2019
- 2019-11-19 CN CN201911136538.4A patent/CN110746933B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101735770A (zh) * | 2008-11-18 | 2010-06-16 | 熊长宏 | 高效复合防腐型融雪剂 |
US20140091251A1 (en) * | 2012-03-09 | 2014-04-03 | Hubei Expressway Business Development Co., Ltd | Slow release anti-icing material for bituminous pavement and preparation method thereof |
CN106893139A (zh) * | 2017-03-30 | 2017-06-27 | 安徽工业大学 | 一种用于橡胶填料的改性多孔钢渣及其制备方法 |
CN108623200A (zh) * | 2018-05-15 | 2018-10-09 | 长安大学 | 一种用于自融雪沥青路面的裹油型盐化物及其制备方法 |
CN109054415A (zh) * | 2018-09-11 | 2018-12-21 | 河南省济阳高速公路建设有限公司 | 一种主动式融雪除冰沥青混合料及其制备方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111675506A (zh) * | 2020-05-29 | 2020-09-18 | 山东高速集团有限公司创新研究中心 | 一种抗凝冰剂及其制备方法 |
CN115260991A (zh) * | 2022-07-27 | 2022-11-01 | 胡勇 | 一种包覆型融雪剂及其制备方法与应用 |
Also Published As
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CN110746933B (zh) | 2022-05-20 |
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Address after: 250357 No.5 Jiaoxiao Road, Tianqiao District, Jinan City, Shandong Province Patentee after: SHANDONG JIAOTONG University Patentee after: SHANDONG HI-SPEED TECHNOLOGY DEVELOPMENT GROUP Co.,Ltd. Address before: 250000 No. 12550 East Second Ring Road, Jinan City, Shandong Province Patentee before: SHANDONG HI-SPEED TECHNOLOGY DEVELOPMENT GROUP Co.,Ltd. Patentee before: SHANDONG JIAOTONG University |
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Effective date of registration: 20240329 Address after: 250357 No.5 Jiaoxiao Road, Tianqiao District, Jinan City, Shandong Province Patentee after: SHANDONG JIAOTONG University Country or region after: China Address before: 250357 No.5 Jiaoxiao Road, Tianqiao District, Jinan City, Shandong Province Patentee before: SHANDONG JIAOTONG University Country or region before: China Patentee before: SHANDONG HI-SPEED TECHNOLOGY DEVELOPMENT GROUP Co.,Ltd. |