CN110714162A - Method for manufacturing high-temperature bolt for steam turbine - Google Patents

Method for manufacturing high-temperature bolt for steam turbine Download PDF

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Publication number
CN110714162A
CN110714162A CN201911053740.0A CN201911053740A CN110714162A CN 110714162 A CN110714162 A CN 110714162A CN 201911053740 A CN201911053740 A CN 201911053740A CN 110714162 A CN110714162 A CN 110714162A
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China
Prior art keywords
percent
temperature
quenching
bolt
steam turbine
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Pending
Application number
CN201911053740.0A
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Chinese (zh)
Inventor
张军
赵中清
涂露寒
张兴勇
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Chengdu Advanced Metal Materials Industry Technology Research Institute Co Ltd
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Chengdu Advanced Metal Materials Industry Technology Research Institute Co Ltd
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Priority to CN201911053740.0A priority Critical patent/CN110714162A/en
Publication of CN110714162A publication Critical patent/CN110714162A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • C21D1/25Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0093Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for screws; for bolts
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/52Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16BDEVICES FOR FASTENING OR SECURING CONSTRUCTIONAL ELEMENTS OR MACHINE PARTS TOGETHER, e.g. NAILS, BOLTS, CIRCLIPS, CLAMPS, CLIPS OR WEDGES; JOINTS OR JOINTING
    • F16B35/00Screw-bolts; Stay-bolts; Screw-threaded studs; Screws; Set screws

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

The invention discloses a method for manufacturing a high-temperature bolt for a steam turbine, belongs to the technical field of heat treatment processes of metal materials, and provides a method for manufacturing a high-temperature bolt for a steam turbine, which can effectively control the internal quality and the mechanical property of the bolt. The high-temperature bolt for the steam turbine produced by the method ensures the heat treatment effect of the metal material aiming at the specific material components by adopting the specific heat treatment process, so that the obtained product has good surface and internal quality, basically no defect, proper hardenability and uniform tempered martensite in microstructure, has higher yield strength, high-temperature endurance strength, toughness and oxidation and corrosion resistance, and can meet the operation requirement of the high-temperature bolt for the steam turbine.

Description

Method for manufacturing high-temperature bolt for steam turbine
Technical Field
The invention relates to the technical field of heat treatment processes of metal materials, in particular to a manufacturing method of a high-temperature bolt for a steam turbine.
Background
The 10Cr11Co3W3NiMoVNbNB steel is a novel 9-12Cr martensite heat-resistant steel for an ultra-supercritical parameter unit, is mainly used for manufacturing high-temperature blades, bolts and other high-temperature end parts and the like, and has the upper limit of the use temperature of 630 ℃. The material has high yield strength, high-temperature endurance strength, toughness and oxidation and corrosion resistance.
The high-temperature bolts for the ultra-supercritical steam turbine unit in the thermal power plant are subjected to the combined action of high-temperature thermal stress and complex load in the operation, the failure and the fracture of a single bolt can enable the fastening force of the cylinder to be rearranged, the service life loss of other bolts around the cylinder is accelerated, and the leakage of high-temperature and high-pressure steam is caused. Therefore, the safety of the bolt connection of the cylinder of the turbine of the ultra-supercritical unit is an important component for ensuring the safe operation of the unit.
In the production and manufacturing process of the steam turbine fastener: in the processes of electric furnace smelting, electroslag remelting, forging, quenching and tempering heat treatment, machining and the like, if technological parameters are not controlled well, quality defects or improper high-temperature performance are caused, so that accidents such as failure of a stud of a fastener occur, and the safe operation of a generator set is seriously influenced. Therefore, the quenching and tempering heat treatment process of the high-temperature bolt is reasonably designed, the matrix structure and the precipitated phase of the material are regulated and controlled, the service performance of the bolt at high temperature is improved, and the safety and the reliability of the fastener bolt are ensured.
Disclosure of Invention
The invention aims to provide a method for manufacturing a high-temperature bolt for a steam turbine, which can effectively control the internal quality and the mechanical property of the bolt.
The technical scheme adopted by the invention for solving the technical problems is as follows: the manufacturing method of the high-temperature bolt for the steam turbine is applied to a fastener stud with the bolt specification of M36 multiplied by 3 mm-M160 multiplied by 4mm and the length of 430-520 mm, and the fastener stud comprises the following components in percentage by weight: 0.08 to 0.12 percent of carbon, less than or equal to 0.10 percent of silicon, 0.35 to 0.55 percent of manganese, 10.00 to 12.00 percent of chromium, 0.10 to 0.40 percent of molybdenum, 0.15 to 0.25 percent of vanadium, 0.40 to 0.70 percent of nickel, 2.7 to 3.2 percent of cobalt, 2.50 to 3.0 percent of tungsten, less than or equal to 0.04 percent of titanium, less than or equal to 0.01 percent of aluminum, 0.05 to 0.12 percent of niobium, 0.010 to 0.025 percent of nitrogen, 0.010 to 0.025 percent of boron, less than or equal to 0.015 percent of phosphorus, less than or equal to 0.010 percent of sulfur, and the balance of iron;
the manufacturing method comprises smelting, forging, quenching and tempering heat treatment and machining treatment in sequence;
the quenching and tempering heat treatment is a treatment process for performing the following steps on the round-rod-shaped fastener blank after smelting and forging:
A. quenching: the quenching temperature is 1085-1115 ℃, the quenching time is 60-120 min, and the oil cooling is carried out;
B. tempering: quenching at the temperature of not less than 700 ℃ for 45-75 min, and air cooling;
after quenching and tempering heat treatment, the mechanical property of the fastener blank is required to meet the following index requirements:
① tensile strength Rm (MPa) 900-1030;
② yield strength Rp0.02 is more than or equal to 690 MPa;
③ elongation A (%) > 15;
④ the section audience rating Z (%) is more than or equal to 45;
⑤ impact energy KV2(J) is more than or equal to 11;
⑥ hardness HB 290-330;
⑦ 660 deg.CStrength for a long time: stress (N/mm)2)245, the breaking time (h) is more than or equal to 100.
Further, the method comprises the following steps: according to different specifications of bolts, the setting of the quenching temperature and time parameters and the tempering temperature and time parameters in the quenching and tempering heat treatment process respectively correspond to the following table:
bolt specification (mm) Quenching temperature (. degree. C.) Quenching time (min) Tempering temperature (. degree.C.) Tempering time (min)
≤M52 1090 60 700 45
M56~M100 1100 90 710 60
≥M110 1110 120 720 75
Further, the method comprises the following steps: an electric furnace smelting and slag remelting process is adopted in the smelting process, and chemical components are controlled in the smelting process to meet the requirements on the components of the fastener stud.
Further, the method comprises the following steps: the minimum forging ratio during forging was 5: 1.
Further, the method comprises the following steps: in the machining process, checking of fastener blank, drilling through holes, machining of an outer circle and cleaning of burrs are performed.
The invention has the beneficial effects that: the high-temperature bolt for the steam turbine produced by the method ensures the heat treatment effect of the metal material aiming at the specific material components by improving the heat treatment process, so that the obtained product has good surface and internal quality, basically no defect, proper hardenability and uniform tempered martensite in microstructure, thereby having higher yield strength, high-temperature endurance strength, toughness and oxidation and corrosion resistance, and being capable of meeting the operation requirements of the high-temperature bolt for the steam turbine.
Detailed Description
According to the manufacturing method of the high-temperature bolt for the steam turbine, the processes of smelting, forging, machining and the like can be processed by adopting the existing process technology; the invention aims at the process improvement of the quenching and tempering heat treatment process so as to improve the product quality through the heat treatment process.
Example 1
Quenching a forged phi 44mm round bar by an electric furnace electroslag remelting smelting process at 1090 ℃ for 60min, carrying out oil quenching, tempering at 700 ℃, preserving heat for 45min, and cooling to room temperature; the mechanical property of the quenched and tempered product meets the requirement after quenching and tempering.
When the inner hole of the stud is machined, the rotating speed of a main shaft is set to 40 revolutions per minute and the feeding amount is 0.08 mm per revolution when the inner hole is drilled, and high-pressure cooling liquid of 11.0bar is started to punch the cuttings out of the hole. Machining an M42 multiplied by 3mm double-end cylindrical thread, reserving a machining allowance of 2.5mm on the radius, performing finish turning, reserving a machining allowance of a 1.8mm turning thread, and during the thread machining, adopting a hard alloy thread forming cutter-a thread 4-tooth chaser, performing feed twice, wherein the feed amount is 1.0mm and 0.8mm respectively, the turning speed is 100M/min, and the feed amount is 3 mm/r.
When the high-temperature fastener stud of the steam turbine with the specification is processed, each stud needs to consume about 8 working hours, and the qualification rate is 99.5%.
Example 2
Quenching a forged phi 80mm round bar by an electric furnace and electroslag remelting smelting process at 1100 ℃, preserving heat for 90min, performing oil quenching, tempering at 710 ℃, preserving heat for 60min, and cooling to room temperature; the mechanical property of the quenched and tempered product meets the requirement after quenching and tempering.
When the stud inner hole is machined, the rotating speed of a main shaft is set to 35 revolutions per minute when the inner hole is drilled, the feeding amount is 0.075 mm per revolution, high-pressure cooling liquid with high pressure of 10.5bar is started, and chips are punched out of the hole. The machining method comprises the steps of machining an M76 multiplied by 4mm double-end cylindrical thread, reserving a machining allowance of 2.8mm on the radius, performing finish turning machining, reserving a machining allowance of 2.0mm turning threads, and during machining of the threads, adopting a hard alloy thread forming cutter-a thread 4-tooth chaser, feeding twice, wherein the feed amount is 1.2mm and 0.8mm respectively, the turning speed is 90M/min, and the feed amount is 3 mm/r.
When the high-temperature fastener stud of the steam turbine with the specification is processed, each stud needs to consume about 10 working hours, and the qualification rate is 99.5%.
Example 3
Quenching a forged phi 170mm round bar by an electric furnace electroslag remelting smelting process at 1110 ℃ for 120min, carrying out oil quenching, tempering at 720 ℃, carrying out heat preservation for 75min, and cooling to room temperature; the mechanical property of the quenched and tempered product meets the requirement after quenching and tempering.
When the inner hole of the stud is machined, the rotating speed of a main shaft is set to 30 revolutions per minute and the feeding amount is 0.095 mm per revolution when the inner hole is drilled, and 8.5bar high-pressure cooling liquid is started to punch the cuttings out of the hole. The machining method comprises the steps of machining an M160 multiplied by 4mm double-end cylindrical thread, reserving a machining allowance of 4.8mm on the radius, performing finish turning machining, reserving a machining allowance of a 2.4mm turning thread, and during machining of the thread, adopting a hard alloy thread forming cutter-a thread 3-tooth chaser, performing feed for three times, wherein the feed amount is respectively 1.1mm, 0.9mm and 0.4mm, the turning speed is 80M/min, and the feed amount is 4 mm/r.
When the steam turbine fastener stud with the specification is processed, each piece needs about 16 working hours, and the qualification rate is 98%.

Claims (5)

1. The manufacturing method of the high-temperature bolt for the steam turbine is characterized by comprising the following steps: the bolt is applied to a fastener stud with the bolt specification of M36 multiplied by 3 mm-M160 multiplied by 4mm and the length of 430-520 mm, and the fastener stud comprises the following components in percentage by weight: 0.08 to 0.12 percent of carbon, less than or equal to 0.10 percent of silicon, 0.35 to 0.55 percent of manganese, 10.00 to 12.00 percent of chromium, 0.10 to 0.40 percent of molybdenum, 0.15 to 0.25 percent of vanadium, 0.40 to 0.70 percent of nickel, 2.7 to 3.2 percent of cobalt, 2.50 to 3.0 percent of tungsten, less than or equal to 0.04 percent of titanium, less than or equal to 0.01 percent of aluminum, 0.05 to 0.12 percent of niobium, 0.010 to 0.025 percent of nitrogen, 0.010 to 0.025 percent of boron, less than or equal to 0.015 percent of phosphorus, less than or equal to 0.010 percent of sulfur, and the balance of iron;
the manufacturing method comprises smelting, forging, quenching and tempering heat treatment and machining treatment in sequence;
the quenching and tempering heat treatment is a treatment process for performing the following steps on the round-rod-shaped fastener blank after smelting and forging:
A. quenching: the quenching temperature is 1085-1115 ℃, the quenching time is 60-120 min, and the oil cooling is carried out;
B. tempering: quenching at the temperature of not less than 700 ℃ for 45-75 min, and air cooling;
after quenching and tempering heat treatment, the mechanical property of the fastener blank is required to meet the following index requirements:
① tensile strength Rm (MPa) 900-1030;
② yield strength Rp0.02 is more than or equal to 690 MPa;
③ elongation A (%) > 15;
④ the section audience rating Z (%) is more than or equal to 45;
⑤ impact energy KV2(J) is more than or equal to 11;
⑥ hardness HB 290-330;
⑦ 660 ℃ permanent strength stress (N/mm)2)245, the breaking time (h) is more than or equal to 100.
2. A method for manufacturing a high-temperature bolt for a steam turbine according to claim 1, wherein: according to different specifications of bolts, the setting of the quenching temperature and time parameters and the tempering temperature and time parameters in the quenching and tempering heat treatment process respectively correspond to the following table:
bolt specification (mm) Quenching temperature (. degree. C.) Quenching time (min) Tempering temperature (. degree.C.) Tempering time (min) ≤M52 1090 60 700 45 M56~M100 1100 90 710 60 ≥M110 1110 120 720 75
3. A method for manufacturing a high-temperature bolt for a steam turbine according to claim 1, wherein: an electric furnace smelting and slag remelting process is adopted in the smelting process, and chemical components are controlled in the smelting process to meet the requirements on the components of the fastener stud.
4. A method for manufacturing a high-temperature bolt for a steam turbine according to claim 1, wherein: the minimum forging ratio during forging was 5: 1.
5. A method of manufacturing a high-temperature bolt for a steam turbine according to any one of claims 1 to 4, wherein: in the machining process, checking of fastener blank, drilling through holes, machining of an outer circle and cleaning of burrs are performed.
CN201911053740.0A 2019-10-31 2019-10-31 Method for manufacturing high-temperature bolt for steam turbine Pending CN110714162A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911053740.0A CN110714162A (en) 2019-10-31 2019-10-31 Method for manufacturing high-temperature bolt for steam turbine

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Application Number Priority Date Filing Date Title
CN201911053740.0A CN110714162A (en) 2019-10-31 2019-10-31 Method for manufacturing high-temperature bolt for steam turbine

Publications (1)

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CN110714162A true CN110714162A (en) 2020-01-21

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004100027A (en) * 2002-09-12 2004-04-02 Nippon Steel Corp Steel for liquid-phase diffusion bonding having excellent resistance to low-temperature transformation crack
CN101525727A (en) * 2009-04-22 2009-09-09 四川江油六合汽轮机材料有限公司 Heat-resisting steel material used as vane or bolt of ultra-supercritical steam turbine and preparation method thereof
CN103602919A (en) * 2010-12-28 2014-02-26 株式会社东芝 Forging heat resistant steel, manufacturing method thereof, forged parts and manufacturing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004100027A (en) * 2002-09-12 2004-04-02 Nippon Steel Corp Steel for liquid-phase diffusion bonding having excellent resistance to low-temperature transformation crack
CN101525727A (en) * 2009-04-22 2009-09-09 四川江油六合汽轮机材料有限公司 Heat-resisting steel material used as vane or bolt of ultra-supercritical steam turbine and preparation method thereof
CN103602919A (en) * 2010-12-28 2014-02-26 株式会社东芝 Forging heat resistant steel, manufacturing method thereof, forged parts and manufacturing method thereof

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Application publication date: 20200121