CN110698220B - Method for firing lightweight porcelain plate for exterior wall decoration by using roller kiln - Google Patents

Method for firing lightweight porcelain plate for exterior wall decoration by using roller kiln Download PDF

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Publication number
CN110698220B
CN110698220B CN201911102930.7A CN201911102930A CN110698220B CN 110698220 B CN110698220 B CN 110698220B CN 201911102930 A CN201911102930 A CN 201911102930A CN 110698220 B CN110698220 B CN 110698220B
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exterior wall
porcelain plate
wall decoration
firing
roller kiln
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CN110698220A (en
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李成峰
黄华
李永倩
张肖林
刘帅
吴越添
张伟
葛筱璐
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Shandong University of Technology
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/04—Clay; Kaolin
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/16—Lean materials, e.g. grog, quartz
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/86—Glazes; Cold glazes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3215—Barium oxides or oxide-forming salts thereof
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/448—Sulphates or sulphites
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602—Making the green bodies or pre-forms by moulding
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567—Treatment time

Abstract

A method for firing a lightweight porcelain plate for exterior wall decoration by using a roller kiln belongs to the technical field of architectural ceramic production. The method is characterized by comprising the following steps: adding water into kaolin, feldspar, quartz, dolomite, sillimanite, green coke, barium carbonate, magnesium oxide, pyrophyllite and barium sulfate, ball-milling, drying, manufacturing granules, pressing, molding, glazing, and firing in a roller kiln at 1170 ℃ for 50 minutes to obtain the light porcelain plate for exterior wall decoration. The density of the light porcelain plate for exterior wall decoration produced by the method is slightly lower than that of the traditional ceramics, the air holes are closed, the water absorption rate is low, the impact resistance is strong, and the basic requirements of climate examination, construction and decoration in the field of exterior wall space-isolation decoration can be met.

Description

Method for firing lightweight porcelain plate for exterior wall decoration by using roller kiln
Technical Field
A method for firing a lightweight porcelain plate for exterior wall decoration by using a roller kiln belongs to the technical field of architectural ceramic production.
Background
In recent years, with the high-speed healthy development of global economy, the level of urbanization is higher and higher, and the process of urbanization is faster and faster, and 60% of people live in cities in 2030 world is expected. The city square and the outer vertical surface of the main building are used as important components of the city outer space and are marks of civilization degrees of city economy, culture and consciousness forms. People have higher and higher requirements on decorative materials for outer walls of buildings, glass curtain wall materials are limited due to the problem of light pollution, and natural stone materials are scarce due to the gradual shortage of resources. In recent years, novel building boards, especially ceramic boards, are increasingly emphasized, on one hand, the materials can shield the heat radiation effect of sunlight on buildings, and on the other hand, the materials can play a decoration effect which cannot be realized by paint decoration.
In the practical application of the ceramic plate in the air-isolated dry hanging decoration, the following difficulties need to be overcome: (1) the proper amount of pores are needed in the board, so that the weight and the heat conductivity coefficient can be reduced, and the ceramic board has certain processability due to the proper amount of pores, namely, the back of the ceramic board can be processed and drilled without brittle fracture; (2) the connectivity of internal pores is avoided to ensure the weather resistance of the decorative plate, and the problems of increased water absorption, freeze-thaw cycle, weathering and the like are caused by the communicated pores, so that the service life of the plate is greatly reduced. So far, no research report exists on the rapid firing of ceramic plates with closed pores, low water absorption and strong impact resistance by a roller kiln.
Disclosure of Invention
The invention aims to provide a method for firing a light porcelain plate for exterior wall decoration by using a roller kiln, namely, a method for optimizing a formula is utilized, so that the generation of gas at high temperature and the wrapping process of a melt can be generated in a coordinated manner, and the mutual auxiliary effect can form closed air holes in a blank body, thereby producing the light porcelain plate for exterior wall decoration. The invention is characterized by comprising the following steps:
(1) preparing the following materials in percentage by mass: 46.082-46.512% of kaolin, 18.433-18.605% of feldspar, 27.650-27.907% of quartz, 2.765-2.791% of dolomite, 0.922-0.930% of sillimanite, 0.461-0.465% of green coke, 1.382-1.395% of barium carbonate, 0.461-0.465% of magnesium oxide, 0.922-0.930% of pyrophyllite and 0-0.922% of barium sulfate, and adding water to ensure that the mass ratio of the materials to the water is 100: 80, ball milling for 1 hour at the speed of 400 revolutions per minute in a planetary ball mill, drying the slurry at 110 ℃, and manually manufacturing material particles;
(2) putting the material particles prepared in the step (1) into a mould, forming under 200MPa to obtain a blank, and glazing the blank with decorative glaze through an ink-jet printer;
(3) and (3) placing the glazed green body prepared in the step (2) into a roller kiln, and firing at 1170 ℃ for 50 minutes to obtain the light porcelain plate for exterior wall decoration.
The density and impact resistance of the light porcelain plate for exterior wall decoration can be changed by changing the addition amount of barium sulfate in the step (1), the viscosity of the melt at high temperature can be regulated and controlled by the addition amount of magnesium oxide in the step (1), so that the generation of gas and the formation of bubbles are matched with the regulation and control process of the viscosity of the melt, the gas is wrapped in the melt, and the light porcelain plate for exterior wall decoration with closed pores and low water absorption is produced.
The invention has the beneficial effects that:
1. the raw materials selected by the method are mostly mineral materials, the cost is low, the technical process is consistent with the production of the traditional roller kiln, and the industrial production is easy to realize;
2. the blank produced by the method has good compatibility with the traditional decorative glaze, does not generate physical and chemical reactions, has consistent shrinkage at the joint of the blank and the glaze, has no air holes and has no deformation;
3. the light porcelain plate for exterior wall decoration produced by the method has the advantages of slightly lower density than that of the traditional ceramics, certain closed pores, low water absorption rate and strong impact resistance, and can meet the basic requirements of climate examination, construction and decoration in the field of exterior wall space-isolation decoration.
Detailed Description
Example 1-KB2
(1) Preparing the following materials in percentage by mass: 46.082% of kaolin, 18.433% of feldspar, 27.650% of quartz, 2.765% of dolomite, 0.922% of sillimanite, 0.461% of green coke, 1.382% of barium carbonate, 0.461% of magnesium oxide, 0.922% of pyrophyllite and 0.922% of barium sulfate, and adding water to ensure that the mass ratio of the materials to the water is 100: 80, ball milling for 1 hour at the speed of 400 revolutions per minute in a planetary ball mill, drying the slurry at 110 ℃, and manually manufacturing material particles;
(2) putting the material particles prepared in the step (1) into a mould, forming under 200MPa to obtain a blank, and glazing the blank with decorative glaze through an ink-jet printer;
(3) and (3) placing the glazed green body prepared in the step (2) into a roller kiln, and firing at 1170 ℃ for 50 minutes to obtain the light porcelain plate for exterior wall decoration.
According to the test of the boiling method mentioned in the national standard GB/T3810.1-2006 ceramic tile test method, the density of the light porcelain plate for exterior wall decoration is 1.96 g per cubic centimeter, and the water absorption rate is 0%. The porcelain plate was placed at a height of 1.4 m, allowed to fall freely to the floor where the tile was laid, and recorded as one time, and the test was repeated, one corner of the porcelain plate dropped when the 12 th drop, and the porcelain plate was broken into small pieces when the 18 th drop, and the water absorption of the broken block was 0.48%.
Example 2K 0
(1) Preparing the following materials in percentage by mass: 46.512% of kaolin, 18.605% of feldspar, 27.907% of quartz, 2.791% of dolomite, 0.930% of sillimanite, 0.465% of green coke, 1.395% of barium carbonate, 0.465% of magnesium oxide and 0.930% of pyrophyllite, and adding water to ensure that the mass ratio of the materials to the water is 100: 80, ball milling for 1 hour at the speed of 400 revolutions per minute in a planetary ball mill, drying the slurry at 110 ℃, and manually manufacturing material particles;
(2) putting the material particles prepared in the step (1) into a mould, forming under 200MPa to obtain a blank, and glazing the blank with decorative glaze through an ink-jet printer;
(3) and (3) placing the glazed green body prepared in the step (2) into a roller kiln, and firing at 1170 ℃ for 50 minutes to obtain the light porcelain plate for exterior wall decoration.
According to the test of the boiling method mentioned in the national standard GB/T3810.1-2006 ceramic tile test method, the density of the light porcelain plate for exterior wall decoration is 2.15 g per cubic centimeter, and the water absorption rate is 0%. And (3) placing the porcelain plate at a position with a height of 1.4 meters, enabling the porcelain plate to freely fall to the ground paved with the ceramic tiles, recording the height as one time, repeating the test, crushing the porcelain plate into small blocks when the porcelain plate falls for the 2 nd time, and enabling the water absorption of the crushed blocks to be 0%.
Comparative example
(1) Preparing the following materials in percentage by mass: 50% of kaolin, 20% of feldspar and 30% of quartz, and adding water to ensure that the mass ratio of the materials to the water is 100: 80, ball milling for 1 hour at the speed of 400 revolutions per minute in a planetary ball mill, drying the slurry at 110 ℃, and manually manufacturing material particles;
(2) putting the material particles prepared in the step (1) into a mould, forming under 200MPa to obtain a blank, and glazing the blank with decorative glaze through an ink-jet printer;
(3) and (3) placing the glazed green body prepared in the step (2) into a roller kiln, and firing at 1170 ℃ for 50 minutes to obtain the traditional ceramic plate.
The test was carried out according to the procedure of the boiling method mentioned in the national standard GB/T3810.1-2006 ceramic brick test method, the density of the conventional ceramic plate was 2.35 g per cubic centimeter and the water absorption rate was 0.10%. The porcelain plate was placed at a height of 1.4 m, allowed to fall freely to the floor where the tile was laid, and recorded as one time, and the test was repeated, with one corner of the porcelain plate falling at the 1 st fall, and the porcelain plate was broken into small pieces at the 3 rd fall, and the water absorption of the broken block was 0.73%.

Claims (1)

1. A method for firing a lightweight porcelain plate for exterior wall decoration by using a roller kiln is characterized by comprising the following steps:
step 1, preparing the following materials in percentage by mass: 46.082-46.512% of kaolin, 18.433-18.605% of feldspar, 27.650-27.907% of quartz, 2.765-2.791% of dolomite, 0.922-0.930% of sillimanite, 0.461-0.465% of green coke, 1.382-1.395% of barium carbonate, 0.461-0.465% of magnesium oxide, 0.922-0.930% of pyrophyllite and 0-0.922% of barium sulfate, and adding water to ensure that the mass ratio of the materials to the water is 100: 80, ball milling for 1 hour at the speed of 400 revolutions per minute in a planetary ball mill, drying the slurry at 110 ℃, and manually manufacturing material particles;
step 2, placing the material particles prepared in the step 1 into a mold, forming under 200MPa to produce a blank, and glazing the blank with decorative glaze through an ink-jet printer;
and 3, placing the glazed green body obtained in the step 2 into a roller kiln, and firing at 1170 ℃ for 50 minutes to obtain the light porcelain plate for exterior wall decoration.
CN201911102930.7A 2019-11-12 2019-11-12 Method for firing lightweight porcelain plate for exterior wall decoration by using roller kiln Active CN110698220B (en)

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CN101786844A (en) * 2010-01-25 2010-07-28 厦门三荣陶瓷开发有限公司 Light heat-preserving brick and fabrication method thereof
CN102718547A (en) * 2012-06-11 2012-10-10 中国钢研科技集团有限公司 Foamed ceramic material and preparation method thereof
CN108863331A (en) * 2018-08-21 2018-11-23 淄博新金亿陶瓷科技有限公司 A kind of high-performance building composite ceramic material and preparation method thereof

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CN105152675B (en) * 2015-09-05 2017-05-17 景德镇陶瓷大学 Preparation method of stain resistant easy-to-clean permeable ceramic brick
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Publication number Priority date Publication date Assignee Title
CN101638315A (en) * 2008-07-28 2010-02-03 咸阳陶瓷研究设计院 Ceramic plate composite and preparation method thereof
CN101786844A (en) * 2010-01-25 2010-07-28 厦门三荣陶瓷开发有限公司 Light heat-preserving brick and fabrication method thereof
CN102718547A (en) * 2012-06-11 2012-10-10 中国钢研科技集团有限公司 Foamed ceramic material and preparation method thereof
CN108863331A (en) * 2018-08-21 2018-11-23 淄博新金亿陶瓷科技有限公司 A kind of high-performance building composite ceramic material and preparation method thereof

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