CN110684603A - Leather cleaning agent and preparation method thereof - Google Patents
Leather cleaning agent and preparation method thereof Download PDFInfo
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- CN110684603A CN110684603A CN201910916441.9A CN201910916441A CN110684603A CN 110684603 A CN110684603 A CN 110684603A CN 201910916441 A CN201910916441 A CN 201910916441A CN 110684603 A CN110684603 A CN 110684603A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
The invention discloses a leather cleaning agent and a preparation method thereof, wherein the leather cleaning agent comprises the following components in percentage by mass: emulsifier: 10% -20%; polishing agent: 10% -20%; dust-proof agent: 0.01 to 0.5 percent; leather nourishing agent: 0.5 to 1.5 percent; degerming agent: 0.01 to 0.5 percent; antistatic agent: 3% -10%; defoaming agent: 0.1 to 0.5 percent; pH regulator: 0.1 to 1 percent; plant essence: 0.1 to 0.5 percent; water: and (4) the balance. The leather cleaning agent disclosed by the invention is very simple in preparation method, and all the components are uniformly mixed in batches. The leather cleaning agent disclosed by the invention not only has excellent decontamination, sterilization, polishing and anti-aging effects, but also can effectively prevent dust and static electricity, and can keep a leather product with lasting gloss.
Description
Technical Field
The invention relates to a leather cleaning agent and a preparation method thereof, and belongs to the technical field of leather care.
Background
The leather product has unique lines and luster on the surface, is wear-resistant, durable and soft in hand feeling, and becomes an essential daily article for people in daily life, such as leather shoes, leather clothing, sofas, leather bags, leather automobile cushions and the like. However, leather products tend to turn dark yellow or light after a period of use, are prone to moisture, mildew, and insects, and require periodic care to extend the useful life and increase the gloss of the leather product. In addition, leather products are easy to be charged with static electricity, so that the leather products are easy to be stained with dust in the air, and the use experience is seriously influenced.
Therefore, there is a need to develop a leather cleaning agent with good cleaning quality, high cleaning efficiency and multiple functions.
Disclosure of Invention
The invention aims to provide a leather cleaning agent and a preparation method thereof.
The technical scheme adopted by the invention is as follows:
a leather cleaning agent comprises the following components in percentage by mass:
emulsifier: 10% -20%;
polishing agent: 10% -20%;
dust-proof agent: 0.01 to 0.5 percent;
leather nourishing agent: 0.5 to 1.5 percent;
degerming agent: 0.01 to 0.5 percent;
antistatic agent: 3% -10%;
defoaming agent: 0.1 to 0.5 percent;
pH regulator: 0.1 to 1 percent;
plant essence: 0.1 to 0.5 percent;
water: and (4) the balance.
Preferably, the leather cleaning agent consists of the following components in percentage by mass:
emulsifier: 10% -20%;
polishing agent: 10% -20%;
dust-proof agent: 0.1 to 0.3 percent;
leather nourishing agent: 0.6 to 1.2 percent;
degerming agent: 0.05 percent to 0.2 percent;
antistatic agent: 3% -5%;
defoaming agent: 0.1 to 0.2 percent;
pH regulator: 0.1 to 0.3 percent;
plant essence: 0.1 to 0.3 percent;
water: and (4) the balance.
Preferably, the emulsifier is at least one of isomeric alcohol ethers, sorbitan fatty acid esters and fatty alcohol-polyoxyethylene ethers.
Preferably, the glazing agent is at least one of simethicone, amino silicone oil and glycerol.
Preferably, the dustproof agent is at least one of methyl fluorosilicone oil and hydrogen-containing fluorosilicone oil.
Preferably, the leather nourishing agent is at least one of lanolin and aloe extract.
Preferably, the degerming agent is at least one of cason, triclosan and 2, 4-imidazolidinedione.
Preferably, the antistatic agent is at least one of octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate, octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate and octadecyl dimethyl hydroxyethyl quaternary ammonium potassium nitrate.
Preferably, the defoamer is a silicone defoamer.
Preferably, the pH regulator is triethanolamine or ammonia water.
The preparation method of the leather cleaning agent comprises the following steps:
1) adding the emulsifier, the polishing agent, the dust-proof agent and water into a reaction kettle, and uniformly stirring;
2) adding the leather nourishing agent, the bacteria removing agent, the antistatic agent and the plant essence into a reaction kettle, and uniformly stirring;
3) and adding the defoaming agent and the pH regulator into the reaction kettle, and uniformly stirring to obtain the leather cleaning agent.
The invention has the beneficial effects that: the leather cleaning agent disclosed by the invention not only has excellent decontamination, sterilization, polishing and anti-aging effects, but also can effectively prevent dust and static electricity, and can keep a leather product with lasting gloss.
The leather cleaning agent can be directly used for decontamination, sterilization, polishing, anti-aging, dust prevention and static resistance of general leather products, and for leather products with good self maintenance, the leather cleaning agent can be diluted by 1-3 times with water for use and is used for endowing the leather products with dust prevention and static resistance effects.
Detailed Description
The invention will be further explained and illustrated with reference to specific examples.
Example 1:
a leather cleaner having the composition shown in the following table:
TABLE 1 composition table of leather detergent
| Raw materials | Mass percent (%) |
| Isomeric alcohol polyoxyethylene ethers | 11 |
| Sorbitan fatty acids | 3 |
| Dimethyl silicone oil | 12 |
| Amino silicone oil | 2 |
| Methyl fluorosilicone oil | 0.1 |
| Aloe extract | 1 |
| Triclosan | 0.2 |
| Octadecyl dimethyl hydroxyethyl Quaternary ammonium sodium nitrate | 3 |
| Organic silicon defoaming agent | 0.2 |
| Triethanolamine | 0.2 |
| Lemon essence | 0.2 |
| Water (W) | 67.1 |
The preparation method of the leather cleaning agent comprises the following steps:
1) adding the isomeric alcohol polyoxyethylene ether, the sorbitan fatty acid, the dimethyl silicone oil, the amino silicone oil, the methyl fluorosilicone oil and water into a reaction kettle, and uniformly stirring;
2) adding aloe extract, triclosan, sodium octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate and lemon essence into a reaction kettle, and uniformly stirring;
3) and adding the organic silicon defoaming agent and triethanolamine into a reaction kettle, and uniformly stirring to obtain the leather cleaning agent.
Example 2:
a leather cleaner having the composition shown in the following table:
TABLE 2 composition table of leather detergent
The preparation method of the leather cleaning agent comprises the following steps:
1) adding fatty alcohol-polyoxyethylene ether, sorbitan fatty acid, dimethyl silicone oil, glycerol, hydrogen-containing fluorosilicone oil and water into a reaction kettle, and uniformly stirring;
2) adding lanolin, 2, 4-imidazolidinedione, octadecyl dimethyl hydroxyethyl quaternary ammonium potassium nitrate and lemon essence into a reaction kettle, and uniformly stirring;
3) and adding the organic silicon defoaming agent and ammonia water into the reaction kettle, and uniformly stirring to obtain the leather cleaning agent.
Example 3:
a leather cleaner having the composition shown in the following table:
TABLE 3 composition table of leather detergent
The preparation method of the leather cleaning agent comprises the following steps:
1) adding the isomeric alcohol polyoxyethylene ether, the sorbitan fatty acid, the glycerol, the amino silicone oil, the methyl fluorosilicone oil and the water into a reaction kettle, and uniformly stirring;
2) adding aloe extract, triclosan, sodium octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate and mint essence into a reaction kettle, and uniformly stirring;
3) and adding the organic silicon defoaming agent and triethanolamine into a reaction kettle, and uniformly stirring to obtain the leather cleaning agent.
Example 4:
a leather cleaner having the composition shown in the following table:
TABLE 4 composition table of leather detergent
| Raw materials | Mass percent (%) |
| Isomeric alcohol polyoxyethylene ethers | 10 |
| Sorbitan fatty acids | 3 |
| Fatty alcohol polyoxyethylene ether | 2 |
| Amino silicone oil | 15 |
| Hydrogen-containing fluorosilicone oil | 0.25 |
| Lanolin | 0.6 |
| 2, 4-imidazolidinediones | 0.15 |
| Octadecyl dimethyl hydroxyethyl Quaternary ammonium sodium nitrate | 4.5 |
| Organic silicon defoaming agent | 0.15 |
| Aqueous ammonia | 0.1 |
| Mint essence | 0.3 |
| Water (W) | 63.95 |
The preparation method of the leather cleaning agent comprises the following steps:
1) adding isomeric alcohol polyoxyethylene ether, sorbitan fatty acid, fatty alcohol polyoxyethylene ether, amino silicone oil, hydrogen-containing fluorosilicone oil and water into a reaction kettle, and uniformly stirring;
2) adding lanolin, 2, 4-imidazolidinedione, sodium octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate and mint essence into a reaction kettle, and uniformly stirring;
3) and adding the organic silicon defoaming agent and ammonia water into the reaction kettle, and uniformly stirring to obtain the leather cleaning agent.
Example 5:
a leather cleaner having the composition shown in the following table:
TABLE 5 composition table of leather detergent
| Raw materials | Mass percent (%) |
| Isomeric alcohol polyoxyethylene ethers | 7 |
| Sorbitan fatty acids | 2 |
| Fatty alcohol polyoxyethylene ether | 2 |
| Dimethyl silicone oil | 13.5 |
| Methyl fluorosilicone oil | 0.2 |
| Aloe extract | 0.8 |
| Kathon | 0.05 |
| Octadecyl dimethyl hydroxyethyl Quaternary ammonium sodium nitrate | 5 |
| Organic silicon defoaming agent | 0.2 |
| Triethanolamine | 0.2 |
| Lemon essence | 0.15 |
| Water (W) | 68.9 |
The preparation method of the leather cleaning agent comprises the following steps:
1) adding isomeric alcohol polyoxyethylene ether, sorbitan fatty acid, fatty alcohol polyoxyethylene ether, dimethyl silicone oil, methyl fluorosilicone oil and water into a reaction kettle, and uniformly stirring;
2) adding aloe extract, carbazone, sodium octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate and lemon essence into a reaction kettle, and uniformly stirring;
3) and adding the organic silicon defoaming agent and triethanolamine into a reaction kettle, and uniformly stirring to obtain the leather cleaning agent.
Comparative example:
some leather cleaner is commercially available.
Test example:
1) the leather cleaning agents of examples 1-5 and comparative example were subjected to a cleaning agent performance test, and the test results are shown in the following table:
TABLE 6 detergent Performance test results of leather detergents of examples 1 to 5 and comparative example
2) The leather cleaning agents of examples 1 to 5 and comparative example were subjected to antistatic property test, and the test results are shown in the following table:
TABLE 7 antistatic Property test results of leather cleaners of examples 1 to 5 and comparative example
Note:
the surface resistance test method comprises the following steps: uniformly coating the leather cleaning agent on 20 leather blocks of 10cm multiplied by 10cm, randomly extracting 10 leather blocks, measuring the resistivity and the electrostatic charge attenuation half-life period of the sample material by adopting an ACL800 megameter, recording a table, and calculating an average value.
3) The leather cleaning agents of examples 1-5 and comparative example were subjected to dust removal performance tests, and the test results are shown in the following table:
TABLE 8 dust removal Performance test results of leather cleaners of examples 1 to 5 and comparative example
Note:
weight difference M test method: uniformly coating the leather cleaning agent on 20 pieces of leather with the thickness of 10cm multiplied by 10cm, weighing the weight M1Weighing after 10 days, and marking as M2The weight difference is M ═ M2-M1From this, 10 pieces of leather were randomly extracted, and another piece of blank uncoated leather was prepared, and at the same temperature and humidity, a table was recorded, and an average value was calculated.
As can be seen from tables 6 to 8: compared with a certain commercially available leather cleaning agent, the leather cleaning agent disclosed by the invention has a better brightening effect, can keep longer gloss time, and has better effects of static electricity prevention, dust prevention and the like.
The above embodiments are preferred embodiments of the present invention, but the present invention is not limited to the above embodiments, and any other changes, modifications, substitutions, combinations, and simplifications which do not depart from the spirit and principle of the present invention should be construed as equivalents thereof, and all such changes, modifications, substitutions, combinations, and simplifications are intended to be included in the scope of the present invention.
Claims (10)
1. A leather cleaning agent is characterized in that: the composite material comprises the following components in percentage by mass:
emulsifier: 10% -20%;
polishing agent: 10% -20%;
dust-proof agent: 0.01 to 0.5 percent;
leather nourishing agent: 0.5 to 1.5 percent;
degerming agent: 0.01 to 0.5 percent;
antistatic agent: 3% -10%;
defoaming agent: 0.1 to 0.5 percent;
pH regulator: 0.1 to 1 percent;
plant essence: 0.1 to 0.5 percent;
water: and (4) the balance.
2. The leather cleaning agent according to claim 1, wherein: the emulsifier is at least one of isomeric alcohol ether, sorbitan fatty acid ester and fatty alcohol-polyoxyethylene ether.
3. The leather cleaning agent according to claim 1, wherein: the polishing agent is at least one of dimethyl silicone oil, amino silicone oil and glycerol.
4. The leather cleaning agent according to any one of claims 1 to 3, wherein: the dustproof agent is at least one of methyl fluorosilicone oil and hydrogen-containing fluorosilicone oil.
5. The leather cleaning agent according to any one of claims 1 to 3, wherein: the leather nourishing agent is at least one of lanolin and aloe extract.
6. The leather cleaning agent according to any one of claims 1 to 3, wherein: the degerming agent is at least one of cason, triclosan and 2, 4-imidazoline diketone.
7. The leather cleaning agent according to any one of claims 1 to 3, wherein: the antistatic agent is at least one of octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate, octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate and octadecyl dimethyl hydroxyethyl quaternary ammonium potassium nitrate.
8. The leather cleaning agent according to any one of claims 1 to 3, wherein: the defoaming agent is an organic silicon defoaming agent.
9. The leather cleaning agent according to any one of claims 1 to 3, wherein: the pH regulator is triethanolamine or ammonia water.
10. The method for producing a leather cleaning agent according to any one of claims 1 to 9, characterized in that: the method comprises the following steps:
1) adding the emulsifier, the polishing agent, the dust-proof agent and water into a reaction kettle, and uniformly stirring;
2) adding the leather nourishing agent, the bacteria removing agent, the antistatic agent and the plant essence into a reaction kettle, and uniformly stirring;
3) and adding the defoaming agent and the pH regulator into the reaction kettle, and uniformly stirring to obtain the leather cleaning agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910916441.9A CN110684603A (en) | 2019-09-26 | 2019-09-26 | Leather cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910916441.9A CN110684603A (en) | 2019-09-26 | 2019-09-26 | Leather cleaning agent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN110684603A true CN110684603A (en) | 2020-01-14 |
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| CN201910916441.9A Pending CN110684603A (en) | 2019-09-26 | 2019-09-26 | Leather cleaning agent and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102863904A (en) * | 2012-09-18 | 2013-01-09 | 江苏雪豹日化有限公司 | Moldproof softening and brightening agent for cleaning leather and preparation method thereof |
| CN102876238A (en) * | 2012-09-18 | 2013-01-16 | 江苏雪豹日化有限公司 | High-performance nutritious waterproof shoe cream and preparation method thereof |
| CN102993983A (en) * | 2012-12-14 | 2013-03-27 | 吴江市利达上光制品有限公司 | Spray type sterilization leather polishing agent and preparation method thereof |
| CN105219539A (en) * | 2015-09-17 | 2016-01-06 | 广州佳伲思抗菌材料有限公司 | A kind of antimildew and antibacterial cleansing cream and preparation method thereof and application |
| CN108129990A (en) * | 2016-12-01 | 2018-06-08 | 青岛赛泽网络科技有限公司 | A kind of Leather mildew-proof liquid |
| CN108396083A (en) * | 2018-02-26 | 2018-08-14 | 合肥远科服装设计有限公司 | A kind of environmental-friendly leather care agent and preparation method thereof |
-
2019
- 2019-09-26 CN CN201910916441.9A patent/CN110684603A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102863904A (en) * | 2012-09-18 | 2013-01-09 | 江苏雪豹日化有限公司 | Moldproof softening and brightening agent for cleaning leather and preparation method thereof |
| CN102876238A (en) * | 2012-09-18 | 2013-01-16 | 江苏雪豹日化有限公司 | High-performance nutritious waterproof shoe cream and preparation method thereof |
| CN102993983A (en) * | 2012-12-14 | 2013-03-27 | 吴江市利达上光制品有限公司 | Spray type sterilization leather polishing agent and preparation method thereof |
| CN105219539A (en) * | 2015-09-17 | 2016-01-06 | 广州佳伲思抗菌材料有限公司 | A kind of antimildew and antibacterial cleansing cream and preparation method thereof and application |
| CN108129990A (en) * | 2016-12-01 | 2018-06-08 | 青岛赛泽网络科技有限公司 | A kind of Leather mildew-proof liquid |
| CN108396083A (en) * | 2018-02-26 | 2018-08-14 | 合肥远科服装设计有限公司 | A kind of environmental-friendly leather care agent and preparation method thereof |
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