CN110650552A - Production method of graphene electrothermal film - Google Patents

Production method of graphene electrothermal film Download PDF

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Publication number
CN110650552A
CN110650552A CN201910868466.6A CN201910868466A CN110650552A CN 110650552 A CN110650552 A CN 110650552A CN 201910868466 A CN201910868466 A CN 201910868466A CN 110650552 A CN110650552 A CN 110650552A
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China
Prior art keywords
film
conductive
carbon paste
paste
heating
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CN201910868466.6A
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Chinese (zh)
Inventor
刘鑫
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Taizhou Sicarbon Technology Co Ltd
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Taizhou Sicarbon Technology Co Ltd
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Priority to CN201910868466.6A priority Critical patent/CN110650552A/en
Publication of CN110650552A publication Critical patent/CN110650552A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/02Details
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/02Details
    • H05B3/04Waterproof or air-tight seals for heaters
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/10Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/12Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
    • H05B3/14Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
    • H05B3/145Carbon only, e.g. carbon black, graphite
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/20Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
    • H05B3/34Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater flexible, e.g. heating nets or webs

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  • Conductive Materials (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention relates to the technical field of electric heating, in particular to a production method of a graphene electrothermal film, which comprises the following steps: preparing raw materials for producing the electrothermal film, such as conductive carbon paste, heating carbon paste, conductive silver paste, a hot melt adhesive film, a sealing bag and the like, printing the conductive carbon paste, the heating carbon paste and the conductive silver paste on the electrothermal film by using printing equipment, compounding the hot melt adhesive film, the metal current carrying strip and the electrothermal film twice and then packaging the film. And has a leakage current recovery device and an electromagnetic radiation prevention device, so that the graphene electrothermal film can reach the level of national standard class II electric appliances on the level of preventing electric shock, the electromagnetic protection reaches the national standard class I standard, the waterproof level reaches more than IPX7 level, the moisture insulation resistance can reach more than 100M omega, simultaneously, the graphene electrothermal film has high modularization degree, does not need to work such as electrothermal film wiring, simplifies the installation link, and greatly improves the construction efficiency and the use safety requirement.

Description

Production method of graphene electrothermal film
Technical Field
The invention relates to the technical field of electric heating, in particular to a production method of a graphene electrothermal film.
Background
Graphene is a new material with a single-layer sheet structure formed by carbon atoms, and has excellent characteristics of high charge carrying capacity, low resistivity, high electrical conductivity, high thermal conductivity and the like. The graphene has extremely high conductivity, the concentration of a hole carrier and an electron carrier can reach 1013cm & lt-2 & gt, electrons directly migrate on the graphene layer without scattering, and the carrier mobility can reach 15000cm 2/(v.s). The graphene structure is also very stable, and the flexible outer surface can be subjected to bending deformation to adapt to external force, so that the lattice structure is kept stable, the thermal conductivity of the graphene structure is more excellent than that of any known material, and the thermal conductivity of the graphene structure is as high as 5300W/m.K. Because the graphene has light weight, extremely large specific surface area, remarkable electrochemical performance and excellent heat conduction performance, the graphene is used for compounding related compounds to obtain a new modified material, and the new material is used for participating in the preparation of the electrothermal membrane liquid, so that the prepared electrothermal membrane has excellent performance, and the stability of the conductivity and the thermal stability of the work are greatly improved.
Along with the use of graphite alkene electric heat membrane more and more frequently, all there is various problems about the preparation of graphite alkene electric heat membrane among the prior art, it is poor if the electromagnetic protection effect, the modularization degree is low, consequently, to above current situation, urgent need develop a production method of graphite alkene electric heat membrane to overcome not enough in the current practical application.
Disclosure of Invention
The invention aims to provide a production method of a graphene electrothermal film, which aims to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme:
a production method of a graphene electrothermal film comprises the following steps:
the method comprises the following steps: preparing raw materials for producing the electrothermal film, such as conductive carbon paste, heating carbon paste, conductive silver paste, a hot melt adhesive film, a sealing bag and the like;
step two: printing the conductive carbon paste according to a preset pattern by using printing equipment to manufacture a film with a shielding circuit;
step three: printing the heating carbon paste on the reverse side of the film with the shielding circuit according to a pre-designed conductive circuit diagram by using printing equipment, and simultaneously adjusting the resistance of the heating carbon paste to meet the power design requirement according to the requirement;
step four: printing conductive silver paste on the heating carbon paste according to a pre-designed pattern by using printing equipment;
step five: carrying out hot-pressing compounding on a metal current carrying strip, a film printed with a silver paste circuit and a heating carbon paste circuit, and a hot-melt adhesive film by using a compounding machine, wherein the metal current carrying strip is positioned between the heating carbon paste film and a pre-coated film, and the current conveying part of the metal current carrying strip is contacted with the silver paste but not contacted with the heating carbon paste;
step six: compounding the hot-melt adhesive film, the metal current-carrying strip and the electric heating film prepared in the fifth step by using a hot-pressing compounding machine, wherein the metal current-carrying strip is positioned between the hot-melt adhesive film and the printed electromagnetic shielding layer to prepare an electric heating film with a leakage current absorption layer;
step seven: connecting the power lines of the prepared electrothermal films in the six steps by using cold pressing terminals or a welding process according to requirements, wherein the metal current carrying strip printed with the electromagnetic shielding layer is communicated with a zero line of the power supply, and the current carrying strip of the heating carbon paste is respectively connected with the zero line and the live line of the power supply;
step eight: the electric heating film which is connected with the power supply and is provided with the insulation device is placed into a bag which is manufactured in advance and sealed at two sides, wherein a special outgoing line crimping mold is manufactured at an outgoing line outlet of the power supply so as to ensure that the outgoing line outlet can be closed with the sealing bag without damaging a power supply connection line, two ends of the bag are sealed by a high-frequency sealing machine, and air in the bag is pumped out by a vacuum air pump.
As a further scheme of the invention: the preparation steps of the conductive carbon paste and the heating carbon paste are that one or more of carbon black, graphite, carbon nano tubes and graphene is added with an adhesive, a diluent, a dispersing agent, a leveling agent, a plasticizer and a defoaming agent to prepare the conductive ink with conductive and resistance characteristics.
As a further scheme of the invention: the conductive silver paste is prepared by adding one or more of silver powder, copper powder, silver-plated copper powder, aluminum powder and nickel powder into an adhesive, a diluent, a dispersant, a leveling agent, a defoaming agent and a plasticizer to prepare the conductive paste with the conductive characteristic.
As a further scheme of the invention: and stirring, dispersing and other operations are carried out by using a stirrer, a three-roller dispersing machine and a sand mill in the preparation process of the conductive carbon paste and the conductive silver paste.
As a further scheme of the invention: the hot melt adhesive film is prepared by uniformly spraying one or more of EVA, PE, TPU and PES on a polyester film or other films with insulating property in a film spraying or coating manner by using a film spraying machine or a coating machine, so that the pre-coated adhesive film with the property of compounding by heating and pressurizing is prepared.
As a further scheme of the invention: the sealing bag is made of PVC material with good flame retardant property.
As a further scheme of the invention: the metal current carrying strip is a degreased copper strip.
As a further scheme of the invention: the printing equipment is a gravure printing machine, a screen printing machine, a coating machine and an offset printing machine.
Compared with the prior art, the invention has the beneficial effects that:
1. by adopting double insulation and double waterproof design, and the graphene electrothermal film is provided with a leakage current recovery device and an electromagnetic radiation prevention device, the electric shock prevention level of the graphene electrothermal film reaches the level of a national standard second-class electric appliance, the electromagnetic protection level reaches the national standard first-class standard, the electric floor heating paved by the electrothermal film does not influence the health of a human body under the condition of long-term use, the waterproof level reaches more than IPX7 level, and the moisture insulation resistance can reach more than 100M omega;
2. this graphite alkene electric heat membrane has the modularization degree height, need not do work such as electric heat membrane wiring, has not only simplified the installation link, has improved the efficiency of construction simultaneously greatly and has improved the safe in utilization requirement.
Detailed Description
The technical solution of the present patent will be described in further detail with reference to the following embodiments.
Example 1
A production method of a graphene electrothermal film comprises the following steps:
the method comprises the following steps: preparing raw materials for producing the electrothermal film, such as conductive carbon paste, heating carbon paste, conductive silver paste, a hot melt adhesive film, a sealing bag and the like;
step two: printing the conductive carbon paste according to a preset pattern by using printing equipment to manufacture a film with a shielding circuit;
step three: printing the heating carbon paste on the reverse side of the film with the shielding circuit according to a pre-designed conductive circuit diagram by using printing equipment, and simultaneously adjusting the resistance of the heating carbon paste to meet the power design requirement according to the requirement;
step four: printing the conductive silver paste on the heating carbon paste according to a pre-designed pattern by using printing equipment, so that the conductive silver paste can play a role in supplying power to the heating carbon paste;
step five: carrying out hot-pressing compounding on a metal current carrying strip, a film printed with a silver paste circuit and a heating carbon paste circuit, and a hot-melt adhesive film by using a compounding machine, wherein the metal current carrying strip is positioned between the heating carbon paste film and a pre-coated film, and the current conveying part of the metal current carrying strip is contacted with the silver paste but not contacted with the heating carbon paste;
step six: compounding the hot-melt adhesive film, the metal current-carrying strip and the electric heating film prepared in the fifth step by using a hot-pressing compounding machine, wherein the metal current-carrying strip is positioned between the hot-melt adhesive film and the printed electromagnetic shielding layer to prepare an electric heating film with a leakage current absorption layer;
step seven: connecting the power lines of the prepared electrothermal films in the six steps by using cold pressing terminals or a welding process according to requirements, wherein the metal current carrying strip printed with the electromagnetic shielding layer is communicated with a zero line of the power supply, and the current carrying strip of the heating carbon paste is respectively connected with the zero line and the live line of the power supply;
step eight: the electric heating film which is connected with the power supply and is provided with the insulation device is placed into a bag which is manufactured in advance and sealed at two sides, wherein a special outgoing line crimping mold is manufactured at an outgoing line outlet of the power supply so as to ensure that the outgoing line outlet can be closed with the sealing bag without damaging a power supply connection line, two ends of the bag are sealed by a high-frequency sealing machine, and air in the bag is pumped out by a vacuum air pump.
Example 2
In this embodiment, the conductive carbon paste and the heating carbon paste are prepared by adding one or more of carbon black, graphite, carbon nanotubes and graphene into an adhesive, a diluent, a dispersant, a leveling agent, a plasticizer and a defoaming agent, and then the conductive ink having conductive and resistive characteristics and capable of being used for screen printing, gravure printing and offset printing is prepared.
In this embodiment, the conductive carbon paste has different resistance characteristics according to the difference of the use requirements and the difference of the production power, and the conductive carbon paste can absorb the leakage current generated when the electric heating film works, so that the problem of electric leakage caused by distributed capacitance is solved, and meanwhile, a certain shielding effect can be achieved on the electromagnetic field generated when the electric heating film works.
In this embodiment, the conductive silver paste is prepared by adding one or more of silver powder, copper powder, silver-plated copper powder, aluminum powder, and nickel powder to an adhesive, a diluent, a dispersant, a leveling agent, an antifoaming agent, and a plasticizer, to prepare a conductive paste having a conductive property.
In this embodiment, operation such as stirring, dispersion are all carried out to all using mixer, three-roller dispenser and sand mill in the preparation process of electrically conductive carbon thick liquid and electrically conductive silver thick liquid.
In this embodiment, the hot melt adhesive film is formed by uniformly spraying one or more of EVA, PE, TPU, and PEs on a polyester film or other films having insulating properties by using a film coating machine or a coater, and is a pre-coated adhesive film that can be heat-laminated and pressure-laminated.
In this embodiment, the sealing bag is made of a PVC material having good flame retardant properties, and the specific steps are as follows:
two pieces of PVC materials are made into a cylindrical material with two sealed sides according to the width of the electric heating film by using a high-frequency bag making sealing machine or a hot melting sealing machine.
In this embodiment, the metal carrier strip is a degreased copper strip. A
In this embodiment, the printing apparatus is an intaglio printing press, a screen printing press, a coater, or an offset printing press.
This production method of graphite alkene electric heat membrane, through adopting dual insulation, dual waterproof design, and possess leakage current recovery unit and anti-electromagnetic radiation device, make graphite alkene electric heat membrane reach the second type electrical apparatus level of national standard on preventing the electric shock level, electromagnetic protection reaches the first order standard of national standard, the electricity that uses this kind of electric heat membrane to lay warms up and does not exert an influence to human health under the condition of long-term use, its waterproof level reaches more than IPX7 level, the moisture state insulation resistance can reach more than 100M omega, this graphite alkene electric heat membrane has the modularization degree height simultaneously, need not do work such as electric heat membrane wiring, the installation link has not only been simplified, simultaneously the efficiency of construction is greatly improved and the safe in utilization requirement has been improved.
The above is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, it is possible to make several variations and modifications without departing from the concept of the present invention, and these should be considered as the protection scope of the present invention, which will not affect the effect of the implementation of the present invention and the utility of the patent.

Claims (8)

1. A production method of a graphene electrothermal film is characterized by comprising the following steps:
the method comprises the following steps: preparing raw materials for producing an electrothermal film by using conductive carbon paste, heating carbon paste, conductive silver paste, a hot-melt adhesive film and a sealing bag;
step two: printing the conductive carbon paste according to a preset pattern by using printing equipment to manufacture a film with a shielding circuit;
step three: printing the heating carbon paste on the reverse side of the film with the shielding circuit according to a pre-designed conductive circuit diagram by using printing equipment, and simultaneously adjusting the resistance of the heating carbon paste to meet the power design requirement according to the requirement;
step four: printing conductive silver paste on the heating carbon paste according to a pre-designed pattern by using printing equipment;
step five: carrying out hot-pressing compounding on a metal current carrying strip, a film printed with a silver paste circuit and a heating carbon paste circuit, and a hot-melt adhesive film by using a compounding machine, wherein the metal current carrying strip is positioned between the heating carbon paste film and a pre-coated film, and the current conveying part of the metal current carrying strip is contacted with the silver paste but not contacted with the heating carbon paste;
step six: compounding the hot-melt adhesive film, the metal current-carrying strip and the electric heating film prepared in the fifth step by using a hot-pressing compounding machine, wherein the metal current-carrying strip is positioned between the hot-melt adhesive film and the printed electromagnetic shielding layer to prepare an electric heating film with a leakage current absorption layer;
step seven: connecting the power lines of the prepared electrothermal films in the six steps by using cold pressing terminals or a welding process according to requirements, wherein the metal current carrying strip printed with the electromagnetic shielding layer is communicated with a zero line of the power supply, and the current carrying strip of the heating carbon paste is respectively connected with the zero line and the live line of the power supply;
step eight: the electric heating film which is connected with the power supply and is provided with the insulation device is placed into a bag which is manufactured in advance and sealed at two sides, wherein a special outgoing line crimping mold is manufactured at an outgoing line outlet of the power supply so as to ensure that the outgoing line outlet can be closed with the sealing bag without damaging a power supply connection line, two ends of the bag are sealed by a high-frequency sealing machine, and air in the bag is pumped out by a vacuum air pump.
2. The production method of the graphene electrothermal film according to claim 1, wherein the conductive carbon paste and the heating carbon paste are prepared by adding one or more of carbon black, graphite, carbon nanotubes and graphene into a binder, a diluent, a dispersant, a leveling agent, a plasticizer and a defoaming agent to prepare conductive ink with conductive and resistive characteristics.
3. The production method of the graphene electrothermal film according to claim 1, wherein the conductive silver paste is prepared by adding one or more of silver powder, copper powder, silver-plated copper powder, aluminum powder and nickel powder into an adhesive, a diluent, a dispersant, a leveling agent, a defoaming agent and a plasticizer to prepare the conductive paste with the conductive property.
4. The production method of the graphene electrothermal film according to claim 1, wherein stirring, dispersing and other operations are performed by using a stirrer, a three-roll disperser and a sand mill in the preparation process of the conductive carbon paste and the conductive silver paste.
5. The production method of the graphene electrothermal film according to claim 4, wherein the hot melt adhesive film is prepared by uniformly spraying one or more of EVA, PE, TPU and PES on a polyester film or other films with insulating properties by using a film coating machine or a coater in a film coating or coating manner, so as to form a pre-coated film which can be compounded by heating and pressurizing.
6. The production method of the graphene electrothermal film according to claim 1, wherein the sealing bag is made of a PVC material with good flame retardant property.
7. The production method of the graphene electrothermal film according to claim 1, wherein the metal current carrying strip is a degreased copper strip.
8. The method for producing a graphene electrothermal film according to claim 7, wherein the printing apparatus is a gravure printing machine, a screen printing machine, a coating machine, and an offset printing machine.
CN201910868466.6A 2019-09-16 2019-09-16 Production method of graphene electrothermal film Pending CN110650552A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111669846A (en) * 2020-06-11 2020-09-15 安徽宇航派蒙健康科技股份有限公司 Preparation method of graphene electrothermal film for floor heating
CN111712001A (en) * 2020-06-11 2020-09-25 安徽宇航派蒙健康科技股份有限公司 Graphite alkene electric heat membrane for warm up
CN112361891A (en) * 2020-11-02 2021-02-12 孙立峰 Method for manufacturing conductive target plate
CN112469151A (en) * 2020-12-04 2021-03-09 湖北暖季地暖科技股份有限公司 Production process of 24V safe graphene electrothermal film
CN113492562A (en) * 2020-03-19 2021-10-12 上海康天新能源科技有限公司 Processing technology for preparing water-based graphene electrothermal film by die cutting and laminating method
CN113766682A (en) * 2021-08-30 2021-12-07 兰州大学 Wearable heater and preparation method thereof
CN113873699A (en) * 2021-10-11 2021-12-31 中暖新能源(青岛)有限公司 Electric heating film material capable of generating heat uniformly and manufacturing method thereof
CN114205930A (en) * 2021-11-23 2022-03-18 浙江波仕科技有限公司 Production process of printed electrothermal film

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Publication number Priority date Publication date Assignee Title
CN104159340A (en) * 2014-08-18 2014-11-19 上海暖康新材料技术有限公司 Composite facial heating material and preparation method thereof
CN208479967U (en) * 2018-06-14 2019-02-05 苏州汉纳材料科技有限公司 Safety electric film and electric hot plate
CN109714841A (en) * 2019-03-12 2019-05-03 云南荣光石墨烯新技术开发有限公司 A kind of graphene far infrared cloud floor heating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104159340A (en) * 2014-08-18 2014-11-19 上海暖康新材料技术有限公司 Composite facial heating material and preparation method thereof
CN208479967U (en) * 2018-06-14 2019-02-05 苏州汉纳材料科技有限公司 Safety electric film and electric hot plate
CN109714841A (en) * 2019-03-12 2019-05-03 云南荣光石墨烯新技术开发有限公司 A kind of graphene far infrared cloud floor heating

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113492562A (en) * 2020-03-19 2021-10-12 上海康天新能源科技有限公司 Processing technology for preparing water-based graphene electrothermal film by die cutting and laminating method
CN113492562B (en) * 2020-03-19 2022-10-14 上海康天新能源科技有限公司 Processing technology for preparing water-based graphene electrothermal film by die cutting and laminating method
CN111669846A (en) * 2020-06-11 2020-09-15 安徽宇航派蒙健康科技股份有限公司 Preparation method of graphene electrothermal film for floor heating
CN111712001A (en) * 2020-06-11 2020-09-25 安徽宇航派蒙健康科技股份有限公司 Graphite alkene electric heat membrane for warm up
CN112361891A (en) * 2020-11-02 2021-02-12 孙立峰 Method for manufacturing conductive target plate
CN112469151A (en) * 2020-12-04 2021-03-09 湖北暖季地暖科技股份有限公司 Production process of 24V safe graphene electrothermal film
CN113766682A (en) * 2021-08-30 2021-12-07 兰州大学 Wearable heater and preparation method thereof
CN113873699A (en) * 2021-10-11 2021-12-31 中暖新能源(青岛)有限公司 Electric heating film material capable of generating heat uniformly and manufacturing method thereof
CN114205930A (en) * 2021-11-23 2022-03-18 浙江波仕科技有限公司 Production process of printed electrothermal film

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