CN110592636A - Electrolytic bath solution for coloring aluminum alloy - Google Patents
Electrolytic bath solution for coloring aluminum alloy Download PDFInfo
- Publication number
- CN110592636A CN110592636A CN201911002032.4A CN201911002032A CN110592636A CN 110592636 A CN110592636 A CN 110592636A CN 201911002032 A CN201911002032 A CN 201911002032A CN 110592636 A CN110592636 A CN 110592636A
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- CN
- China
- Prior art keywords
- aluminum alloy
- electrolytic bath
- bath solution
- coloring
- selenate
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Classifications
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/06—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
- C25D11/08—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used containing inorganic acids
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/14—Producing integrally coloured layers
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Printing Plates And Materials Therefor (AREA)
Abstract
The invention relates to an electrolytic bath solution for coloring aluminum alloy, which comprises an additive and a carrier, wherein the raw materials in the formula comprise the following components in percentage by weight: 0.5-6% of selenate, 10-35% of sulfuric acid, 1-10% of a conductive medium, 0-3% of a silane coupling agent, 0-2.5% of an explosion-proof agent, 5-20% of a hydrogen inhibitor, 10-20% of amino acid and 30-60% of a catalyst.
Description
Technical Field
The invention discloses an electrolytic bath solution for coloring aluminum alloy.
Background
In the prior art, most of aluminum alloy coloring methods are carried out by utilizing section bar anodic oxidation, the main process flow is degreasing, alkaline etching, neutralization, anodic oxidation, coloring, hole sealing, air drying and warehousing, the defect is single color tone, and in the prior art of the electrolytic coloring of the golden yellow aluminum alloy selenium salt with Chinese patent application No. 96119433.3, a hole expanding treatment process is added in the anodic oxidation and electrolytic coloring process.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides the electrolytic bath solution for coloring the aluminum alloy, the electrolytic bath solution has the effect of quickly and deeply coloring the aluminum alloy section, the coloring color can be from light to deep according to different temperatures, the obtained aluminum alloy section is magnificent titanium yellow, the color is pure, other variegated colors are not contained, and the stability is good.
In order to achieve the purpose, the invention is realized by the following technical scheme: an electrolytic bath solution for coloring aluminum alloy comprises the following raw materials in percentage by weight: 0.5-6% of selenate, 10-35% of sulfuric acid, 1-10% of conductive medium, 0-3% of silane coupling agent, 0-2.5% of explosion-proof agent, 5-20% of hydrogen inhibitor, 10-20% of amino acid and 30-60% of catalyst.
Has the advantages that: the product prepared by the method has the effect that the aluminum alloy section is quickly and deeply colored by the electrolytic bath solution, the colored color can be from light to dark according to different temperatures, the obtained aluminum alloy section is magnificent titanium yellow, the color is pure, other variegated colors are not contained, and the stability is good.
Detailed Description
Example 1
An electrolytic bath solution for coloring aluminum alloy comprises the following raw materials in percentage by weight: 0.5% selenate, 10% sulfuric acid, 1% conductive medium, 1% silane coupling agent, 1% explosion-proof agent, 5% hydrogen inhibitor, 10% amino acid and 30% catalyst, wherein the color is not pure enough and the stability is not enough.
Example 2
An electrolytic bath solution for coloring aluminum alloy comprises the following raw materials in percentage by weight: 6% selenate, 35% sulfuric acid, 10% conductive medium, 3% silane coupling agent, 2.5% explosion-proof agent, 20% hydrogen inhibitor, 20% amino acid and 60% catalyst, and at the moment, the production cost is high and the cost performance is not high.
Example 3
An electrolytic bath solution for coloring aluminum alloy comprises the following raw materials in percentage by weight: 4% selenate, 23% sulfuric acid, 5% conductive medium, 1.5% silane coupling agent, 1.25% explosion-proof agent, 13% hydrogen inhibitor, 15% amino acid and 45% catalyst, and the electrolytic bath solution can color the aluminum alloy section quickly and deeply, so that the colored color can be obtained from light to dark according to different temperatures, and the obtained aluminum alloy section is flourishing titanium yellow, pure in color, free of other variegated colors and good in stability.
Claims (4)
1. The electrolytic bath solution for coloring the aluminum alloy comprises an additive and a carrier, and is characterized in that the raw materials in the formula comprise the following components in percentage by weight: 0.5-6% of selenate, 10-35% of sulfuric acid, 1-10% of conductive medium, 0-3% of silane coupling agent, 0-2.5% of explosion-proof agent, 5-20% of hydrogen inhibitor, 10-20% of amino acid and 30-60% of catalyst.
2. The electrolytic bath solution for aluminum alloy coloring according to claim 1, wherein the raw materials in the formulation comprise, in weight percent: 0.5% selenate, 10% sulfuric acid, 1% conductive medium, 1% silane coupling agent, 1% explosion-proof agent, 5% hydrogen inhibitor, 10% amino acid and 30% catalyst.
3. The electrolytic bath solution for aluminum alloy coloring according to claim 1, wherein the raw materials in the formulation comprise, in weight percent: 6% selenate, 35% sulfuric acid, 10% conductive medium, 3% silane coupling agent, 2.5% explosion-proof agent, 20% hydrogen inhibitor, 20% amino acid and 60% catalyst.
4. The electrolytic bath solution for aluminum alloy coloring according to claim 1, wherein the raw materials in the formulation comprise, in weight percent: 4% selenate, 23% sulfuric acid, 5% conductive medium, 1.5% silane coupling agent, 1.25% explosion-proof agent, 13% hydrogen inhibitor, 15% amino acid and 45% catalyst.
Priority Applications (1)
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CN201911002032.4A CN110592636A (en) | 2019-10-21 | 2019-10-21 | Electrolytic bath solution for coloring aluminum alloy |
Applications Claiming Priority (1)
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CN201911002032.4A CN110592636A (en) | 2019-10-21 | 2019-10-21 | Electrolytic bath solution for coloring aluminum alloy |
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CN110592636A true CN110592636A (en) | 2019-12-20 |
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CN201911002032.4A Pending CN110592636A (en) | 2019-10-21 | 2019-10-21 | Electrolytic bath solution for coloring aluminum alloy |
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1232888A (en) * | 1998-04-17 | 1999-10-27 | 南海市宏基铝材厂 | Oxidizing and coloring process of golden yellow aluminium alloy shapes |
CN1251396A (en) * | 1999-10-29 | 2000-04-26 | 南海市绍祥铜铝合金型材厂 | Electrophoretic titanium-golden yellow alluminium alloy section material processing method |
CN1251395A (en) * | 1999-10-26 | 2000-04-26 | 南海市绍祥铜铝合金型材厂 | Titanium-golden yellow alumium alloy colouring processing method |
CN102080247A (en) * | 2009-11-26 | 2011-06-01 | 苗恩利 | Coloring processing method for tobacco-yellow titanium alloy |
CN104152969A (en) * | 2014-08-04 | 2014-11-19 | 石狮市星火铝制品有限公司 | Coloring method adopting aluminium alloy alternate current electrolysis for precipitating silver and copper |
CN104651905A (en) * | 2015-01-28 | 2015-05-27 | 永保纳米科技(深圳)有限公司 | Anodic aluminum level dyeing retarding aid and operating liquid thereof as well as anodic aluminum level dyeing retarding treatment process |
CN109537020A (en) * | 2019-01-18 | 2019-03-29 | 佛山泰铝新材料有限公司 | A kind of organic coloring process of aluminum alloy coiled materials medium temperature and aluminum alloy sheet |
-
2019
- 2019-10-21 CN CN201911002032.4A patent/CN110592636A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1232888A (en) * | 1998-04-17 | 1999-10-27 | 南海市宏基铝材厂 | Oxidizing and coloring process of golden yellow aluminium alloy shapes |
CN1251395A (en) * | 1999-10-26 | 2000-04-26 | 南海市绍祥铜铝合金型材厂 | Titanium-golden yellow alumium alloy colouring processing method |
CN1251396A (en) * | 1999-10-29 | 2000-04-26 | 南海市绍祥铜铝合金型材厂 | Electrophoretic titanium-golden yellow alluminium alloy section material processing method |
CN102080247A (en) * | 2009-11-26 | 2011-06-01 | 苗恩利 | Coloring processing method for tobacco-yellow titanium alloy |
CN104152969A (en) * | 2014-08-04 | 2014-11-19 | 石狮市星火铝制品有限公司 | Coloring method adopting aluminium alloy alternate current electrolysis for precipitating silver and copper |
CN104651905A (en) * | 2015-01-28 | 2015-05-27 | 永保纳米科技(深圳)有限公司 | Anodic aluminum level dyeing retarding aid and operating liquid thereof as well as anodic aluminum level dyeing retarding treatment process |
CN109537020A (en) * | 2019-01-18 | 2019-03-29 | 佛山泰铝新材料有限公司 | A kind of organic coloring process of aluminum alloy coiled materials medium temperature and aluminum alloy sheet |
Non-Patent Citations (2)
Title |
---|
《电镀工艺手册》编委会: "《电镀工艺手册》", 31 August 1989, 上海科学技术出版社 * |
郑水林: "《粉体表面改性(第二版)》", 31 August 2003, 中国建材工业出版社 * |
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