CN110592636A - Electrolytic bath solution for coloring aluminum alloy - Google Patents

Electrolytic bath solution for coloring aluminum alloy Download PDF

Info

Publication number
CN110592636A
CN110592636A CN201911002032.4A CN201911002032A CN110592636A CN 110592636 A CN110592636 A CN 110592636A CN 201911002032 A CN201911002032 A CN 201911002032A CN 110592636 A CN110592636 A CN 110592636A
Authority
CN
China
Prior art keywords
aluminum alloy
electrolytic bath
bath solution
coloring
selenate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911002032.4A
Other languages
Chinese (zh)
Inventor
程峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xuzhou Guoyi Aluminum Alloy Packing Box Co Ltd
Original Assignee
Xuzhou Guoyi Aluminum Alloy Packing Box Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xuzhou Guoyi Aluminum Alloy Packing Box Co Ltd filed Critical Xuzhou Guoyi Aluminum Alloy Packing Box Co Ltd
Priority to CN201911002032.4A priority Critical patent/CN110592636A/en
Publication of CN110592636A publication Critical patent/CN110592636A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/06Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
    • C25D11/08Anodisation of aluminium or alloys based thereon characterised by the electrolytes used containing inorganic acids
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/14Producing integrally coloured layers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Printing Plates And Materials Therefor (AREA)

Abstract

The invention relates to an electrolytic bath solution for coloring aluminum alloy, which comprises an additive and a carrier, wherein the raw materials in the formula comprise the following components in percentage by weight: 0.5-6% of selenate, 10-35% of sulfuric acid, 1-10% of a conductive medium, 0-3% of a silane coupling agent, 0-2.5% of an explosion-proof agent, 5-20% of a hydrogen inhibitor, 10-20% of amino acid and 30-60% of a catalyst.

Description

Electrolytic bath solution for coloring aluminum alloy
Technical Field
The invention discloses an electrolytic bath solution for coloring aluminum alloy.
Background
In the prior art, most of aluminum alloy coloring methods are carried out by utilizing section bar anodic oxidation, the main process flow is degreasing, alkaline etching, neutralization, anodic oxidation, coloring, hole sealing, air drying and warehousing, the defect is single color tone, and in the prior art of the electrolytic coloring of the golden yellow aluminum alloy selenium salt with Chinese patent application No. 96119433.3, a hole expanding treatment process is added in the anodic oxidation and electrolytic coloring process.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides the electrolytic bath solution for coloring the aluminum alloy, the electrolytic bath solution has the effect of quickly and deeply coloring the aluminum alloy section, the coloring color can be from light to deep according to different temperatures, the obtained aluminum alloy section is magnificent titanium yellow, the color is pure, other variegated colors are not contained, and the stability is good.
In order to achieve the purpose, the invention is realized by the following technical scheme: an electrolytic bath solution for coloring aluminum alloy comprises the following raw materials in percentage by weight: 0.5-6% of selenate, 10-35% of sulfuric acid, 1-10% of conductive medium, 0-3% of silane coupling agent, 0-2.5% of explosion-proof agent, 5-20% of hydrogen inhibitor, 10-20% of amino acid and 30-60% of catalyst.
Has the advantages that: the product prepared by the method has the effect that the aluminum alloy section is quickly and deeply colored by the electrolytic bath solution, the colored color can be from light to dark according to different temperatures, the obtained aluminum alloy section is magnificent titanium yellow, the color is pure, other variegated colors are not contained, and the stability is good.
Detailed Description
Example 1
An electrolytic bath solution for coloring aluminum alloy comprises the following raw materials in percentage by weight: 0.5% selenate, 10% sulfuric acid, 1% conductive medium, 1% silane coupling agent, 1% explosion-proof agent, 5% hydrogen inhibitor, 10% amino acid and 30% catalyst, wherein the color is not pure enough and the stability is not enough.
Example 2
An electrolytic bath solution for coloring aluminum alloy comprises the following raw materials in percentage by weight: 6% selenate, 35% sulfuric acid, 10% conductive medium, 3% silane coupling agent, 2.5% explosion-proof agent, 20% hydrogen inhibitor, 20% amino acid and 60% catalyst, and at the moment, the production cost is high and the cost performance is not high.
Example 3
An electrolytic bath solution for coloring aluminum alloy comprises the following raw materials in percentage by weight: 4% selenate, 23% sulfuric acid, 5% conductive medium, 1.5% silane coupling agent, 1.25% explosion-proof agent, 13% hydrogen inhibitor, 15% amino acid and 45% catalyst, and the electrolytic bath solution can color the aluminum alloy section quickly and deeply, so that the colored color can be obtained from light to dark according to different temperatures, and the obtained aluminum alloy section is flourishing titanium yellow, pure in color, free of other variegated colors and good in stability.

Claims (4)

1. The electrolytic bath solution for coloring the aluminum alloy comprises an additive and a carrier, and is characterized in that the raw materials in the formula comprise the following components in percentage by weight: 0.5-6% of selenate, 10-35% of sulfuric acid, 1-10% of conductive medium, 0-3% of silane coupling agent, 0-2.5% of explosion-proof agent, 5-20% of hydrogen inhibitor, 10-20% of amino acid and 30-60% of catalyst.
2. The electrolytic bath solution for aluminum alloy coloring according to claim 1, wherein the raw materials in the formulation comprise, in weight percent: 0.5% selenate, 10% sulfuric acid, 1% conductive medium, 1% silane coupling agent, 1% explosion-proof agent, 5% hydrogen inhibitor, 10% amino acid and 30% catalyst.
3. The electrolytic bath solution for aluminum alloy coloring according to claim 1, wherein the raw materials in the formulation comprise, in weight percent: 6% selenate, 35% sulfuric acid, 10% conductive medium, 3% silane coupling agent, 2.5% explosion-proof agent, 20% hydrogen inhibitor, 20% amino acid and 60% catalyst.
4. The electrolytic bath solution for aluminum alloy coloring according to claim 1, wherein the raw materials in the formulation comprise, in weight percent: 4% selenate, 23% sulfuric acid, 5% conductive medium, 1.5% silane coupling agent, 1.25% explosion-proof agent, 13% hydrogen inhibitor, 15% amino acid and 45% catalyst.
CN201911002032.4A 2019-10-21 2019-10-21 Electrolytic bath solution for coloring aluminum alloy Pending CN110592636A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911002032.4A CN110592636A (en) 2019-10-21 2019-10-21 Electrolytic bath solution for coloring aluminum alloy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911002032.4A CN110592636A (en) 2019-10-21 2019-10-21 Electrolytic bath solution for coloring aluminum alloy

Publications (1)

Publication Number Publication Date
CN110592636A true CN110592636A (en) 2019-12-20

Family

ID=68851448

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911002032.4A Pending CN110592636A (en) 2019-10-21 2019-10-21 Electrolytic bath solution for coloring aluminum alloy

Country Status (1)

Country Link
CN (1) CN110592636A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1232888A (en) * 1998-04-17 1999-10-27 南海市宏基铝材厂 Oxidizing and coloring process of golden yellow aluminium alloy shapes
CN1251396A (en) * 1999-10-29 2000-04-26 南海市绍祥铜铝合金型材厂 Electrophoretic titanium-golden yellow alluminium alloy section material processing method
CN1251395A (en) * 1999-10-26 2000-04-26 南海市绍祥铜铝合金型材厂 Titanium-golden yellow alumium alloy colouring processing method
CN102080247A (en) * 2009-11-26 2011-06-01 苗恩利 Coloring processing method for tobacco-yellow titanium alloy
CN104152969A (en) * 2014-08-04 2014-11-19 石狮市星火铝制品有限公司 Coloring method adopting aluminium alloy alternate current electrolysis for precipitating silver and copper
CN104651905A (en) * 2015-01-28 2015-05-27 永保纳米科技(深圳)有限公司 Anodic aluminum level dyeing retarding aid and operating liquid thereof as well as anodic aluminum level dyeing retarding treatment process
CN109537020A (en) * 2019-01-18 2019-03-29 佛山泰铝新材料有限公司 A kind of organic coloring process of aluminum alloy coiled materials medium temperature and aluminum alloy sheet

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1232888A (en) * 1998-04-17 1999-10-27 南海市宏基铝材厂 Oxidizing and coloring process of golden yellow aluminium alloy shapes
CN1251395A (en) * 1999-10-26 2000-04-26 南海市绍祥铜铝合金型材厂 Titanium-golden yellow alumium alloy colouring processing method
CN1251396A (en) * 1999-10-29 2000-04-26 南海市绍祥铜铝合金型材厂 Electrophoretic titanium-golden yellow alluminium alloy section material processing method
CN102080247A (en) * 2009-11-26 2011-06-01 苗恩利 Coloring processing method for tobacco-yellow titanium alloy
CN104152969A (en) * 2014-08-04 2014-11-19 石狮市星火铝制品有限公司 Coloring method adopting aluminium alloy alternate current electrolysis for precipitating silver and copper
CN104651905A (en) * 2015-01-28 2015-05-27 永保纳米科技(深圳)有限公司 Anodic aluminum level dyeing retarding aid and operating liquid thereof as well as anodic aluminum level dyeing retarding treatment process
CN109537020A (en) * 2019-01-18 2019-03-29 佛山泰铝新材料有限公司 A kind of organic coloring process of aluminum alloy coiled materials medium temperature and aluminum alloy sheet

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
《电镀工艺手册》编委会: "《电镀工艺手册》", 31 August 1989, 上海科学技术出版社 *
郑水林: "《粉体表面改性(第二版)》", 31 August 2003, 中国建材工业出版社 *

Similar Documents

Publication Publication Date Title
CN107189620A (en) A kind of preparation method of black matt electrophoretic aluminium section
DE60309076D1 (en) Process for the preparation of a lutein fatty acid concentrate
CN102031509A (en) Chemical coloring method for copper and alloys of copper
CN110592636A (en) Electrolytic bath solution for coloring aluminum alloy
US4526671A (en) Surface treatment of aluminum or aluminum alloys
ATE397593T1 (en) METHOD FOR PRODUCING A PRECURSOR OF VITAMIN B1
CN110777418A (en) Coloring electrolytic bath solution for energy equipment
CN110158136B (en) Aluminum electrolytic coloring titanium golden surface treatment method
US2154455A (en) Cadmium bright dip
CN1251395A (en) Titanium-golden yellow alumium alloy colouring processing method
CN102080247A (en) Coloring processing method for tobacco-yellow titanium alloy
CN110819212A (en) Environment-friendly coating suitable for mechanical equipment
US2860089A (en) Method of electro depositing zinc
JP2003518559A (en) Tanks for electroplating high gloss white rhodium coatings and whitening agents for electroplating tanks
KR102476892B1 (en) A Aluminium Surface Treating Method Having High Light Stability Using Anodizing
RU2390588C1 (en) Procedure for hard anodising items out of aluminium alloys
CN110885474A (en) Preparation method and application of phosphite antioxidant
AU609320B2 (en) Colour anodizing of aluminium surfaces with p-toluenesulfonic acid
US3257295A (en) Method of chemically treating metals
CN104988562B (en) A kind of cast member electrophoretic process method
CN107119083A (en) A kind of method that biological enzyme prepares sodium polydithio-dipropyl sulfonate
RU2262522C2 (en) Protective varnish composition and method for production of protective coating on nickel, tin and alloys thereof
CN106810474A (en) A kind of preparation method of Xue Fo Shi sodium salts
CN110735159A (en) Electroplating formula of alloy metal materials
RU2447201C1 (en) Solution for compaction of anode-oxide coat from aluminium alloys

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20191220

WD01 Invention patent application deemed withdrawn after publication