CN110565083A - Solution suitable for aluminum alloy passivation process - Google Patents

Solution suitable for aluminum alloy passivation process Download PDF

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Publication number
CN110565083A
CN110565083A CN201911014536.8A CN201911014536A CN110565083A CN 110565083 A CN110565083 A CN 110565083A CN 201911014536 A CN201911014536 A CN 201911014536A CN 110565083 A CN110565083 A CN 110565083A
Authority
CN
China
Prior art keywords
surfactant
aluminum alloy
solution suitable
passivation process
alloy passivation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911014536.8A
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Chinese (zh)
Inventor
程峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xuzhou Guoyi Aluminum Alloy Packing Box Co Ltd
Original Assignee
Xuzhou Guoyi Aluminum Alloy Packing Box Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xuzhou Guoyi Aluminum Alloy Packing Box Co Ltd filed Critical Xuzhou Guoyi Aluminum Alloy Packing Box Co Ltd
Priority to CN201911014536.8A priority Critical patent/CN110565083A/en
Publication of CN110565083A publication Critical patent/CN110565083A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)

Abstract

The invention relates to a solution suitable for an aluminum alloy passivation process, which comprises an additive and a carrier, wherein the raw materials in the formula comprise the following components in percentage by weight: 0.5-6% of nitric acid, 10-35% of surfactant, 1-10% of surfactant, 0-3% of sodium fluoride, 0-2.5% of stabilizer, 5-20% of deionized water, 10-20% of amino acid and 30-60% of catalyst.

Description

Solution suitable for aluminum alloy passivation process
Technical Field
The invention discloses a solution suitable for an aluminum alloy passivation process.
Background
Aluminum is a silver-white light metal, has ductility, can form a layer of oxide film that prevents metal corrosion in humid air, and the wide application of aluminium is in each field, and aluminium is comparatively easy to be oxidized in the air, receives the corruption, all will carry out passivation to the aluminum alloy before using usually, and among the prior art, because hydrofluoric acid has very big harm nature to the human body, and can release a large amount of harmful gas in the processing procedure, harm operating personnel's health and cause the pollution to the environment.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides the solution suitable for the aluminum alloy passivation process, which avoids the harm of hydrofluoric acid to human bodies, does not release a large amount of gas harmful to the human bodies in the using process, reduces the environmental pollution, and is economic and efficient.
In order to achieve the purpose, the invention is realized by the following technical scheme: the solution suitable for the aluminum alloy passivation process comprises the following raw materials in percentage by weight: 0.5-6% of nitric acid, 10-35% of surfactant, 1-10% of surfactant, 0-3% of sodium fluoride, 0-2.5% of stabilizer, 5-20% of deionized water, 10-20% of amino acid and 30-60% of catalyst.
Has the advantages that: the product prepared by the method avoids the harm of hydrofluoric acid to human bodies, does not release a large amount of gas harmful to human bodies in the using process, reduces the environmental pollution, and is economical and efficient.
Detailed Description
Example 1
The solution suitable for the aluminum alloy passivation process comprises the following raw materials in percentage by weight: 0.5% of nitric acid, 10% of surfactant, 1% of sodium fluoride, 1% of stabilizer, 5% of deionized water, 10% of amino acid and 30% of catalyst, wherein the aluminum alloy is not passivated sufficiently and still subjected to oxidation during use.
Example 2
The solution suitable for the aluminum alloy passivation process comprises the following raw materials in percentage by weight: 6% of nitric acid, 35% of surfactant, 10% of surfactant, 3% of sodium fluoride, 2.5% of stabilizer, 20% of deionized water, 20% of amino acid and 60% of catalyst, and at the moment, the production cost is high and the cost performance is low.
Example 3
The solution suitable for the aluminum alloy passivation process comprises the following raw materials in percentage by weight: 4% nitric acid, 23% surfactant, 5% surfactant, 1.5% sodium fluoride, 1.25% stabilizer, 13% deionized water, 15% amino acid and 45% catalyst, so that the harm of hydrofluoric acid to human bodies is avoided, a large amount of gas harmful to the human bodies is not released in the using process, the environmental pollution is reduced, and the method is economical and efficient.

Claims (4)

1. The solution suitable for the aluminum alloy passivation process comprises an additive and a carrier, and is characterized in that the solution comprises the following raw materials in percentage by weight: 0.5-6% of nitric acid, 10-35% of surfactant, 1-10% of surfactant, 0-3% of sodium fluoride, 0-2.5% of stabilizer, 5-20% of deionized water, 10-20% of amino acid and 30-60% of catalyst.
2. The solution suitable for the aluminum alloy passivation process according to claim 1, wherein the raw materials in the formula comprise, by weight: 0.5% of nitric acid, 10% of surfactant, 1% of sodium fluoride, 1% of stabilizer, 5% of deionized water, 10% of amino acid and 30% of catalyst.
3. The solution suitable for the aluminum alloy passivation process according to claim 1, wherein the raw materials in the formula comprise, by weight: 6% of nitric acid, 35% of surfactant, 10% of surfactant, 3% of sodium fluoride, 2.5% of stabilizer, 20% of deionized water, 20% of amino acid and 60% of catalyst.
4. The solution suitable for the aluminum alloy passivation process according to claim 1, wherein the raw materials in the formula comprise, by weight: 4% of nitric acid, 23% of surfactant, 5% of surfactant, 1.5% of sodium fluoride, 1.25% of stabilizer, 13% of deionized water, 15% of amino acid and 45% of catalyst.
CN201911014536.8A 2019-10-24 2019-10-24 Solution suitable for aluminum alloy passivation process Pending CN110565083A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911014536.8A CN110565083A (en) 2019-10-24 2019-10-24 Solution suitable for aluminum alloy passivation process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911014536.8A CN110565083A (en) 2019-10-24 2019-10-24 Solution suitable for aluminum alloy passivation process

Publications (1)

Publication Number Publication Date
CN110565083A true CN110565083A (en) 2019-12-13

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911014536.8A Pending CN110565083A (en) 2019-10-24 2019-10-24 Solution suitable for aluminum alloy passivation process

Country Status (1)

Country Link
CN (1) CN110565083A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111893471A (en) * 2020-08-01 2020-11-06 安徽家园铝业有限公司 High-weather-resistance aluminum alloy chromium-free passivator and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060214137A1 (en) * 2005-03-25 2006-09-28 Bulk Chemicals, Inc. Phosphonic acid and polyvinyl alcohol conversion coating
CN1962939A (en) * 2005-11-08 2007-05-16 佛山市顺德区汉达精密电子科技有限公司 Solution formulation for passivation technology for aluminum alloy containing silicon, copper, and magnesium
CN101892477A (en) * 2010-06-21 2010-11-24 华南理工大学 Treatment solution for preparing aluminum alloy surface amorphous composite passivation film, preparation method and application
CN107641461A (en) * 2015-10-16 2018-01-30 奎克化学(中国)有限公司 conversion film based on metal organic system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060214137A1 (en) * 2005-03-25 2006-09-28 Bulk Chemicals, Inc. Phosphonic acid and polyvinyl alcohol conversion coating
CN1962939A (en) * 2005-11-08 2007-05-16 佛山市顺德区汉达精密电子科技有限公司 Solution formulation for passivation technology for aluminum alloy containing silicon, copper, and magnesium
CN101892477A (en) * 2010-06-21 2010-11-24 华南理工大学 Treatment solution for preparing aluminum alloy surface amorphous composite passivation film, preparation method and application
CN107641461A (en) * 2015-10-16 2018-01-30 奎克化学(中国)有限公司 conversion film based on metal organic system

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111893471A (en) * 2020-08-01 2020-11-06 安徽家园铝业有限公司 High-weather-resistance aluminum alloy chromium-free passivator and preparation method thereof

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Application publication date: 20191213

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