CN110551432A - Photochromic spray for fresh flowers - Google Patents

Photochromic spray for fresh flowers Download PDF

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Publication number
CN110551432A
CN110551432A CN201910864749.3A CN201910864749A CN110551432A CN 110551432 A CN110551432 A CN 110551432A CN 201910864749 A CN201910864749 A CN 201910864749A CN 110551432 A CN110551432 A CN 110551432A
Authority
CN
China
Prior art keywords
photochromic
parts
spray
flowers
spraying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910864749.3A
Other languages
Chinese (zh)
Inventor
汪丰
孟继本
刘宗
张丽鑫
席志强
孟祥美
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Fuxin Sunshine Technology Co Ltd
Original Assignee
Tianjin Fuxin Sunshine Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Fuxin Sunshine Technology Co Ltd filed Critical Tianjin Fuxin Sunshine Technology Co Ltd
Priority to CN201910864749.3A priority Critical patent/CN110551432A/en
Publication of CN110551432A publication Critical patent/CN110551432A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G5/00Floral handling
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G7/00Botany in general
    • A01G7/06Treatment of growing trees or plants, e.g. for preventing decay of wood, for tingeing flowers or wood, for prolonging the life of plants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N3/00Preservation of plants or parts thereof, e.g. inhibiting evaporation, improvement of the appearance of leaves or protection against physical influences such as UV radiation using chemical compositions; Grafting wax
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Environmental Sciences (AREA)
  • Forests & Forestry (AREA)
  • Ecology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Botany (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Toxicology (AREA)
  • Dentistry (AREA)
  • Zoology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention provides a photochromic spray for fresh flowers, which comprises the following formula: 0.5-1 part of phenoxyethanol, 7-10 parts of methacrylic resin polymer, 2-5 parts of solvent, 2-5 parts of photochromic raw powder, 3-7 parts of dispersing agent, 4-6 parts of adhesive, 2-5 parts of light stabilizer and 60-70 parts of distilled water, wherein the photochromic raw powder and the light stabilizer are dissolved in the solvent, the distilled water and other components are added for emulsification by an emulsifying machine, and the photochromic spray is obtained after uniform dispersion. And spraying the prepared photochromic spraying substance on the flowers, wherein the photochromic spraying substance is changed into various colors from colorless or from colored to colorless, and the effect is displayed after the photochromic spraying substance is dried and colored. The photochromic spray can be well attached to flowers, part of the photochromic spray directly enters cell walls, the color changing time is long, the color changing effect is durable, and the photochromic spray cannot be washed away by rainwater; can be repeatedly sprayed, has strong fatigue resistance, and can at least keep the whole flowering phase of the flowers.

Description

Photochromic spray for fresh flowers
Technical Field
The invention relates to the field of organic materials, in particular to a photochromic spray for fresh flowers.
Background
The spraying that discolours has at present a lot, but most is the temperature sensing discolours, and does not have special flowers on the market at present, especially the spraying thing that the flower was used, and most all are ordinary water-soluble organic dyestuff, and itself just has the colour, makes flowers color through spraying or rhizome absorption, and the mode of coloring moreover is mostly the aqueous adsorption coloring, and the time of coloring reaches several hours, and the flower is colored the back colour and is distributed uncontrollably inhomogeneous, and flowers are mostly living body pruning flowers, can not be used in flowers cultivated in a pot. Has great improvement space.
Disclosure of Invention
The invention aims to provide a photochromic spray for fresh flowers, which is mainly applied to various fresh flowers, so that the fresh flowers can change color under the sunlight or ultraviolet rays, and can recover the color under the condition of no sunlight or ultraviolet rays, thereby improving the enjoyment of appreciation.
The technical scheme of the invention is as follows:
A photochromic spray coating comprises the following formula:
0.5-1 part of phenoxyethanol, degerming and antisepticising
7-10 parts of methacrylic resin polymer as filler
2-5 parts of ethyl acetate or propyl acetate or butyl acetate or 1, 2-dichloroethane or 1, 4-dichloroethane as solvent
2-5 parts of photochromic raw powder
3-7 parts of dispersing agent
4-6 parts of adhesive
2-5 parts of light stabilizer to improve photochromic weatherability
60-70 parts of distilled water
Wherein the diffusing agent is preferably ethoxy modified polytrisiloxane, which can improve the surface tension of leaves on the surface of plants, so that photochromic molecules can enter cell walls.
The light stabilizer is preferably 770, i.e., bis-2, 2,6, 6-tetramethylpiperidinol sebacate.
The preparation method comprises the following specific steps: dissolving the photochromic compound and the light stabilizer in a solvent, adding distilled water and other components, emulsifying by using an emulsifying machine, and dispersing uniformly to obtain the photochromic spray.
And spraying the prepared photochromic spraying substance on the flowers, wherein the photochromic spraying substance is changed into various colors from colorless or from colored to colorless, and the effect is displayed after the photochromic spraying substance is dried and colored.
The invention has the advantages and positive effects that:
1. The photochromic spraying material of the fresh flowers is developed, so that the fresh flowers can show the colors except for the flowers under the sunlight, can be changed into the colors from the colors according to the different selected photochromic raw powders, can also be changed into the colors from the colors without the colors, can show various colors when being sprayed on the plants and the flowers, and increases the ornamental value and the interest.
2. The spray-coated plant is completely green and harmless to the plant and flower, and the plant and flower cannot wither to influence the growth of the plant and flower.
3. The photochromic spray is used on flowers, can be well attached to the flowers, and part of the photochromic spray directly enters cell walls, so that the photochromic spray has longer color change time and lasting color change effect and cannot be washed away by rainwater; can be repeatedly sprayed, has strong fatigue resistance, and can at least keep the whole flowering phase of the flowers.
Drawings
FIG. 1 is a photograph showing the discoloration of a flower sprayed with the spray of the present invention. The left big picture is the original flower, and the right six small pictures are the color changes at the time of spraying, 5min, 10min, 20min, 24h and 48h after spraying.
Detailed Description
example 1
A photochromic spray coating comprises the following formula:
0.5kg of phenoxyethanol
7kg of methacrylic resin Polymer
2kg of ethyl acetate
2kg of a photochromic base powder
3kg of dispersing agent
4kg of adhesive
2kg of light stabilizer
60kg of distilled water
The preparation method comprises the following specific steps: dissolving photochromic raw powder and light stabilizer in ethyl acetate solvent, adding distilled water and other components, emulsifying by an emulsifying machine, and dispersing uniformly to obtain the photochromic spray.
The photochromic compound of the embodiment is carmine after being sprayed on petals, and can be seen by combining the attached drawings, after the spraying, photos are recorded after 5min, 10min, 20min, 24h and 48h, the color is slightly reduced after 5min, and then the color is kept all the time, so that the photochromic compound has good ornamental value.
Example 2
a photochromic spray coating comprises the following formula:
1kg of phenoxyethanol
10kg of methacrylic resin Polymer
5kg of ethyl acetate
5kg of photochromic raw powder
7kg of dispersing agent
6kg of adhesive
5kg of light stabilizer
70kg of distilled water
The preparation procedure is the same as example 1, and the photochromic raw powder used in this example is a blue powder which appears blue after being irradiated with light. When sprayed on yellow roses, the color of the coating turns to a less visible blue color and returns to a light color in the absence of light.
While one embodiment of the present invention has been described in detail, the description is only a preferred embodiment of the present invention and should not be taken as limiting the scope of the invention. All equivalent changes and modifications made within the scope of the present invention shall fall within the scope of the present invention.

Claims (3)

1. The photochromic spray for fresh flowers is characterized by comprising the following formula:
0.5-1 part of phenoxyethanol
7-10 parts of methacrylic resin polymer
2-5 parts of solvent
2-5 parts of photochromic raw powder
3-7 parts of dispersing agent
4-6 parts of adhesive
2-5 parts of light stabilizer
60-70 parts of distilled water.
2. The photochromic spray for fresh flowers as claimed in claim 1, wherein: the solvent is at least one of ethyl acetate, propyl acetate, butyl acetate, 1, 2-dichloroethane and 1, 4-dichloroethane.
3. The method for producing a photochromic spray for fresh flowers as claimed in claim 1 or 2, wherein: the preparation method comprises the following specific steps: dissolving the photochromic raw powder and the light stabilizer in a solvent, adding distilled water and other components, emulsifying by using an emulsifying machine, and dispersing uniformly to obtain the photochromic spray.
CN201910864749.3A 2019-09-09 2019-09-09 Photochromic spray for fresh flowers Pending CN110551432A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910864749.3A CN110551432A (en) 2019-09-09 2019-09-09 Photochromic spray for fresh flowers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910864749.3A CN110551432A (en) 2019-09-09 2019-09-09 Photochromic spray for fresh flowers

Publications (1)

Publication Number Publication Date
CN110551432A true CN110551432A (en) 2019-12-10

Family

ID=68740156

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910864749.3A Pending CN110551432A (en) 2019-09-09 2019-09-09 Photochromic spray for fresh flowers

Country Status (1)

Country Link
CN (1) CN110551432A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101698766A (en) * 2009-10-19 2010-04-28 广东三和化工科技有限公司 Household allochroic emulsion paint and preparation method thereof
CN102140288A (en) * 2011-05-13 2011-08-03 武汉大学 Ice-covering-proof coating containing electrolyte
CN103468074A (en) * 2013-09-03 2013-12-25 吴江市冰心文教用品有限公司 Photochromic paint
CN103690453A (en) * 2013-12-27 2014-04-02 天津孚信达光电科技有限公司 Novel photochromic nail polish
CN106245869A (en) * 2016-08-22 2016-12-21 桐乡嘉力丰实业股份有限公司 A kind of light sensation color-changing wallpaper and preparation technology thereof
CN107828269A (en) * 2017-12-04 2018-03-23 昆山阿基里斯人造皮有限公司 A kind of compound levelling agent of high temperature resistant and preparation method thereof
CN109535952A (en) * 2018-11-22 2019-03-29 中国石油大学(北京) A kind of ability of reverse photochromism coating and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101698766A (en) * 2009-10-19 2010-04-28 广东三和化工科技有限公司 Household allochroic emulsion paint and preparation method thereof
CN102140288A (en) * 2011-05-13 2011-08-03 武汉大学 Ice-covering-proof coating containing electrolyte
CN103468074A (en) * 2013-09-03 2013-12-25 吴江市冰心文教用品有限公司 Photochromic paint
CN103690453A (en) * 2013-12-27 2014-04-02 天津孚信达光电科技有限公司 Novel photochromic nail polish
CN106245869A (en) * 2016-08-22 2016-12-21 桐乡嘉力丰实业股份有限公司 A kind of light sensation color-changing wallpaper and preparation technology thereof
CN107828269A (en) * 2017-12-04 2018-03-23 昆山阿基里斯人造皮有限公司 A kind of compound levelling agent of high temperature resistant and preparation method thereof
CN109535952A (en) * 2018-11-22 2019-03-29 中国石油大学(北京) A kind of ability of reverse photochromism coating and preparation method thereof

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Application publication date: 20191210

RJ01 Rejection of invention patent application after publication