CN110528817A - A kind of floor tile with enamel layer - Google Patents

A kind of floor tile with enamel layer Download PDF

Info

Publication number
CN110528817A
CN110528817A CN201910829127.7A CN201910829127A CN110528817A CN 110528817 A CN110528817 A CN 110528817A CN 201910829127 A CN201910829127 A CN 201910829127A CN 110528817 A CN110528817 A CN 110528817A
Authority
CN
China
Prior art keywords
enamel
layer
thickness
enamel layer
millimeter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910829127.7A
Other languages
Chinese (zh)
Other versions
CN110528817B (en
Inventor
耿云
孙金红
徐仲民
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zibo Advances Chemical Machinery Co Ltd
Original Assignee
Zibo Advances Chemical Machinery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zibo Advances Chemical Machinery Co Ltd filed Critical Zibo Advances Chemical Machinery Co Ltd
Priority to CN201910829127.7A priority Critical patent/CN110528817B/en
Publication of CN110528817A publication Critical patent/CN110528817A/en
Application granted granted Critical
Publication of CN110528817B publication Critical patent/CN110528817B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • E04F15/10Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
    • E04F15/107Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials composed of several layers, e.g. sandwich panels
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/18Separately-laid insulating layers; Other additional insulating measures; Floating floors
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/04Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Floor Finish (AREA)

Abstract

The embodiment of the present application provides a kind of floor tile with enamel layer.The floor tile with enamel layer in the embodiment of the present application, comprising: brick body and functional layer;Functional layer includes metal foil, and invests the enamel layer of metal foil outer surface in packet, and the thickness range of metal foil is 10 millimeters, and the ingredient of enamel layer includes iron oxide, zinc oxide and pigment, and function layer surface is through anti-skidding processing;Brick body includes enamel portion and brick portion, and enamel portion covers the surface in brick portion at least partly;Functional layer is at least set to the side that brick body is provided with enamel portion, and at least side of the covering enamel portion backwards to brick portion;If the thickness in enamel portion, less than 0.5 millimeter, the thickness range of enamel layer is 0.5~0.8 millimeter;If the thickness in enamel portion is more than or equal to 0.5 millimeter, the thickness range of enamel layer is 0.8~1.0 millimeter;If the thickness in enamel portion, less than 0.8 millimeter, functional layer is set in brick portion at least in enamel portion in the marginal position of enamel portion circumferential direction.

Description

A kind of floor tile with enamel layer
Technical field
This application involves building material technical fields, specifically, this application involves a kind of floors with enamel layer Brick.
Background technique
Traditional ceramic tile, floor tile are metal oxide and half-metal oxide with fire resisting, via grinding, mixing, pressure System, the process of glazing, sintering, and a kind of porcelain of the acid and alkali-resistance formed or stone matter etc., building or ornament materials.Its raw material is more It is mixed by clay, quartz sand etc..Be widely used in building, field of constructional ornament, be layed in metope, on ground as building The structural material and functional material of object.
Existing ceramic tile, floor tile are mostly designed using improving non-skid property, improving aesthetics as target.With life The raising of quality, people also proposed more various requirements to ceramic tile, floor tile.In particular, being used in ceramic tile, floor tile In certain particular surroundings, such as hospital, generally require ceramic tile, floor tile has the specific function cooperated with use environment.
In view of this, special propose the application.
Summary of the invention
The application is directed to the shortcomings that existing way, proposes a kind of floor tile with enamel layer, such as cures to cooperate In the environment more demanding to sanitation degree such as institute.
The embodiment of the present application provides a kind of floor tile with enamel layer, comprising: brick body and functional layer;
The functional layer includes metal foil, and invests the enamel layer of metal foil outer surface in packet, and enamel layer is one Kind inorganic matter enamel, the thickness range of the metal foil are 10 millimeters, and the ingredient of enamel layer includes iron oxide, zinc oxide and face Material, function layer surface is through anti-skidding processing;
Brick body includes enamel portion and brick portion, and enamel portion covers the surface in brick portion at least partly, and brick body is with a thickness of 8 millis Rice;
Functional layer is at least set to the side that brick body is provided with enamel portion, and at least covering enamel portion is backwards to the one of brick portion Side;
Wherein, the setting range of the thickness of enamel layer and functional layer in brick body is determined according to the thickness in enamel portion;
If the thickness in enamel portion, less than 0.5 millimeter, the thickness range of enamel layer is 0.5~0.8 millimeter;If enamel portion Thickness is more than or equal to 0.5 millimeter, then the thickness range of enamel layer is 0.8~1.0 millimeter;
If the thickness in enamel portion less than 0.8 millimeter, functional layer at least enamel portion enamel portion circumferential direction marginal position, It is set in brick portion.
In the application an optional embodiment, enamel layer includes: base stock;
The ingredient of base stock includes zirconium oxide and silica, if the thickness in enamel portion less than 0.5 millimeter, zirconium oxide and oxygen The range of mass ratio of the SiClx in base stock is 1:10 to 3:10.
In the application an optional embodiment, if the thickness in enamel portion is less than 0.5 millimeter, base stock is in enamel layer In mass percent range are as follows: 45%~70%.
It further include potassium oxide and boron oxide in base stock in the application an optional embodiment;
If the thickness of enamel layer is greater than the thickness in enamel portion, the mass percent of potassium oxide and boron oxide in base stock The sum of be not less than 5%.
In the application an optional embodiment, if the thickness in enamel portion is less than 0.5 millimeter, boron oxide is in base stock In mass percent be not less than 3%.
It further include antibacterial agent in enamel layer in the application an optional embodiment;
Antibacterial agent includes at least one of silver ion antimicrobial agent and titanium dioxide.
In the application an optional embodiment, if the thickness in enamel portion, less than 0.8 millimeter, antibacterial agent is silver ion Antibacterial agent.
Based on the same inventive concept, the embodiment of the present application further provides a kind of floor tile with enamel layer, uses In preparing the floor tile with enamel layer in foregoing embodiments, the floor tile with enamel layer includes:
Vitreous enamel is coated on the side that brick body is provided with enamel portion, and at least covering enamel portion is backwards to the one of brick portion Side obtains precast body floor tile;
Precast body floor tile is statically placed in air pressure less than or equal in the environment of 41325 Pascals, makes a reservation for stand until reaching Time;
Precast body floor tile after sintering standing, obtains the floor tile with enamel layer.
In the application an optional embodiment, according to the thickness of enamel layer, predetermined time of repose is determined;
If the thickness of enamel layer, less than 0.7 millimeter, the range of predetermined time of repose is 2 hours~4 hours;
If the thickness of enamel layer is more than or equal to 0.7 millimeter, the range of predetermined time of repose is 5 hours~8 hours.
In the application an optional embodiment, the temperature range of sintering is 760~860 degrees Celsius.
Technical solution provided by the embodiments of the present application, at least has the following beneficial effects:
1) floor tile provided by the embodiments of the present application with enamel layer is used, in existing ceramic tile, the base of floor tile On plinth, functional layer is increased.Functional layer can increase the function being adapted with use environment for ceramic tile, floor tile, additionally it is possible to increase The service life of ceramic tile, floor tile.The ingredient of enamel layer includes the metal oxide beneficial to human body, such as iron oxide, zinc oxide. The ingredient of enamel layer further includes pigment.Function layer surface is through anti-skidding processing.Under the scene using floor heating heat supply, metal oxide What is played is more preferable to the beneficial effect of human body.It gains everything and lose nothing to indoor environment and health.Functional layer steel plate makees enamel The carrier application of slip, forms composite material, and intensity wants tens times high compared with Ceramic Tiles.
2) use the floor tile provided by the embodiments of the present application with enamel layer, can directly existing ceramic tile, Use on plate brick, and designed according to the actual conditions of existing ceramic tile, floor tile so that according to different ceramic tiles, The floor tile with enamel layer that plate brick obtains has uniform service performance.
Specific embodiment
Those skilled in the art of the present technique are appreciated that unless otherwise defined, all terms used herein (including technology Term and scientific term), there is meaning identical with the general understanding of those of ordinary skill in the application fields.Also answer It should be appreciated that those terms such as defined in the general dictionary, it should be understood that have in the context of the prior art The consistent meaning of meaning otherwise with idealization or too formal will not contain and unless by specific definitions as here Justice is explained.
Those skilled in the art of the present technique are appreciated that unless expressly stated, singular " one " used herein, " one It is a ", " described " and "the" may also comprise plural form.It is to be further understood that being arranged used in the description of the present application Diction " comprising " refer to that there are the feature, integer, step, operation, element and/or component, but it is not excluded that in the presence of or addition Other one or more features, integer, step, operation, element, component and/or their group.Wording used herein " and/ Or " it include one or more associated wholes for listing item or any cell and all combinations.
A kind of floor tile with enamel layer provided by the present application, it is intended to solve ceramic tile in the prior art, The technical problem that plate brick can not be adapted with practical service environment.
How the technical solution of the application and the technical solution of the application are solved with specifically embodiment below above-mentioned Technical problem is described in detail.These specific embodiments can be combined with each other below, for the same or similar concept Or process may repeat no more in certain embodiments.
The embodiment of the present application provides a kind of floor tile with enamel layer, comprising: brick body and functional layer.
The functional layer includes metal foil, and invests the enamel layer of metal foil outer surface, the metallic steel in packet The thickness range of plate is 10 millimeters, and the ingredient of enamel layer includes the metal oxide beneficial to human body, such as iron oxide, zinc oxide. The ingredient of enamel layer further includes pigment.Function layer surface is through anti-skidding processing.Under the scene using floor heating heat supply, metal oxide What is played is more preferable to the beneficial effect of human body.It gains everything and lose nothing to indoor environment and health.Functional layer steel plate makees enamel The carrier application of slip, forms composite material, and intensity wants tens times high compared with Ceramic Tiles.
Brick body includes enamel portion and brick portion, and enamel portion covers the surface in brick portion at least partly.Brick body can be with existing porcelain Brick or floor tile.The floor tile with enamel layer in the embodiment of the present application, can be by existing ceramic tile or floor Brick is improved and is obtained.In the embodiment of the present application, to the requirement of brick body unrestriction, the enamel portion and brick portion for constituting brick body can be with Any mode is cooperated.For enamel layer relative to brick body, ingredient design can be more flexible, can be added with and be conducive in enamel layer Improve the ingredient with the use environment of floor tile of enamel layer, such as fungicide etc..
Functional layer is at least set to the side that brick body is provided with enamel portion, and at least covering enamel portion is backwards to the one of brick portion Side.
Wherein, the setting range of the thickness of enamel layer and functional layer in brick body is determined according to the thickness in enamel portion.
If the thickness in enamel portion, less than 0.5 millimeter, the thickness range of enamel layer is 0.5~0.8 millimeter;If enamel portion Thickness is more than or equal to 0.5 millimeter, then the thickness range of enamel layer is 0.8~1.0 millimeter.
The floor tile with enamel layer in the embodiment of the present application, according to the case where the enamel portion of brick body to enamel layer Thickness is designed.The application applicant has found through a large number of experiments, in the production of the floor tile with enamel layer Cheng Zhong, the bonding state of enamel layer and enamel portion, is on the one hand determined by sintering process;On the one hand by the thickness and enamel of enamel layer The thickness in portion determines.Using the thickness of the enamel layer of the embodiment of the present application introduction and the thickness ratio relationship in enamel portion, Ke Yitong Lower sintering temperature is crossed, so that enamel layer penetrates into the gap in enamel portion, and passes through formed with the ingredient in enamel portion The mode for learning key combines, and obtains the floor tile with enamel layer that enamel layer and enamel portion are well combined.Also, enamel layer Ingredient is different from the ingredient in enamel portion, and the two, due to the difference of ingredient, can make the presence of interface between the two in cohesive process, By the thickness ratio relationship in the embodiment of the present application, the interface between enamel layer and enamel portion can be largely destroyed, Increase the combination degree of the two.Thickness in the embodiment of the present application, for the floor tile with enamel layer after the completion of sintering The thickness of corresponding construction.
If the thickness in enamel portion less than 0.8 millimeter, functional layer at least enamel portion enamel portion circumferential direction marginal position, It is set in brick portion.
The floor tile with enamel layer in the embodiment of the present application, also according to the combination model between enamel portion and brick portion Enclose, pair the setting range of enamel layer designed.Present applicant is found through a large number of experiments, passes through the application The setting range of enamel layer in embodiment, enables enamel layer and the good combination in enamel portion, and enamel layer can be with The part in brick portion combines, and increases adhesive ability of the enamel layer in brick body.Functional layer is at least in enamel portion in enamel portion circumferential direction Marginal position, be set in brick portion, the position be enamel portion and brick portion binding site edge, then in the embodiment of the present application Technical solution, additionally it is possible to increase the binding ability between enamel portion and brick portion.Functional components are added in enamel layer, so that warding off Higher cost of the cost of enamel coating relative to enamel portion is then needing between enamel layer auxiliary enamel portion and brick portion as much as possible In conjunction with when, just enamel layer is set in the circumferential direction of enamel portion and brick portion link position, avoid improve cost.
In one embodiment of the application, enamel layer includes: base stock.The ingredient of base stock includes zirconium oxide and silica, If the thickness in enamel portion, less than 0.5 millimeter, the range of the mass ratio of zirconium oxide and silica in base stock is 1:10 to 3: 10。
Present applicant finds that the ingredient of enamel layer will affect between enamel layer and enamel portion through a large number of experiments Binding performance.The floor tile with enamel layer in the embodiment of the present application, enamel portion thickness less than 0.5 millimeter, it is right The composition proportion of base stock has carried out targeted design, so that the interface between enamel layer and enamel portion largely disappears It loses.Also, when the thickness in enamel portion is less than 0.5 millimeter, enamel layer is also provided at enamel portion in the margin location of enamel portion circumferential direction It sets, the proportion of the base stock in the embodiment of the present application, additionally it is possible to realize good combination of the enamel layer at this location with brick portion, Enable the floor tile with enamel layer in the embodiment of the present application to eliminate interface as far as possible at various locations, improves to have and ward off The structural behaviour and mechanical property of the floor tile of enamel layer.Further such that when there is enamel layer in the embodiment of the present application Floor tile use be possible to medical instrument carrying occur hospital is this, the wheel of hospital bed grinds the part of ceramic tile, floor tile It presses in more serious scene, the wearability and service life of the floor tile with enamel layer can be effectively improved.
In addition, the enamel layer in the embodiment of the present application can also include fluxing agent and adhesive agent in addition to base stock.In It, can also be targetedly in enamel layer in the environment that certain appearance properties to the floor tile with enamel layer require Add colorant.
In one embodiment of the application, if the thickness in enamel portion less than 0.5 millimeter, quality of the base stock in enamel layer The range of percentage are as follows: 45%~70%.
Present applicant finds that the content of each component of enamel layer also can be to enamel layer and glaze through a large number of experiments Binding performance between matter portion, and obtain the floor tile with enamel layer mechanical property.Pass through the embodiment of the present application In be directed to base stock proportion design, enable to enamel layer and enamel portion to be preferably combined as a whole.
It further include potassium oxide and boron oxide in base stock in one embodiment of the application.If the thickness of enamel layer is greater than glaze The thickness in matter portion, then the sum of the mass percent of potassium oxide and boron oxide in base stock is not less than 5%.If the thickness in enamel portion Less than 0.5 millimeter, then mass percent of the boron oxide in base stock is not less than 3%.Make in the floor tile with enamel layer With in the process, inevitably continually there is hospital bed wheel, the wheel of medical instrument rolls it the case where.Due to enamel layer and The location of enamel portion difference, the force-bearing situation of the two are also different.Present applicant is found through a large number of experiments, is warded off The respective force-bearing situation of enamel coating and enamel portion is influenced by the thickness of the two.Then there is the thickness of such as enamel layer in the two thickness When degree is greater than the relationship of the thickness in enamel portion, the ingredient of base stock is designed, can effectively background enamel layer and enamel portion by Connection relationship that is different degrees of when rolling, both keeping.
It further include antibacterial agent in enamel layer in one embodiment of the application;Antibacterial agent includes silver ion antimicrobial agent and dioxy Change at least one of titanium.If the thickness in enamel portion, less than 0.8 millimeter, antibacterial agent is silver ion antimicrobial agent.
In the embodiment of the present application, designed for the functionality of the floor tile with enamel layer.In enamel layer Antibacterial agent is increased, the floor tile with enamel layer is enabled to reduce bacterium, fungi on it attached in use , reduce bacterium, fungi breed a possibility that.It is such to be directed to antibacterial agent especially under hospital, this usage scenario in kindergarten Design can effectively improve the sanitation degree in usage scenario.Applicants experimentally found that enamel is arranged in brick body When layer, the antibacterial agent in enamel layer will affect the combination of enamel layer and enamel portion;And antibacterial agent can occur during the sintering process The phenomenon that shifting into enamel portion will affect antibacterial, the bactericidal effect of the floor tile with enamel layer.In the embodiment of the present application The floor tile with enamel layer can efficiently solve the above problem.
Using the recovery method of lithium bromide refrigerating agent provided by the embodiments of the present application, at least may be implemented following beneficial to effect Fruit:
1) floor tile provided by the embodiments of the present application with enamel layer is used, in existing ceramic tile, the base of floor tile On plinth, functional layer is increased.Functional layer can increase the function being adapted with use environment for ceramic tile, floor tile, additionally it is possible to increase The service life of ceramic tile, floor tile.The ingredient of enamel layer includes the metal oxide beneficial to human body, such as iron oxide, zinc oxide. The ingredient of enamel layer further includes pigment.Function layer surface is through anti-skidding processing.Under the scene using floor heating heat supply, metal oxide What is played is more preferable to the beneficial effect of human body.It gains everything and lose nothing to indoor environment and health.Functional layer steel plate makees enamel The carrier application of slip, forms composite material, and intensity wants tens times high compared with Ceramic Tiles.
2) use the floor tile provided by the embodiments of the present application with enamel layer, can directly existing ceramic tile, Use on plate brick, and designed according to the actual conditions of existing ceramic tile, floor tile so that according to different ceramic tiles, The floor tile with enamel layer that plate brick obtains has uniform service performance.
Term " first ", " second " be used for descriptive purposes only and cannot be understood as indicating or suggesting relative importance or Implicitly indicate the quantity of indicated technical characteristic." first " is defined as a result, the feature of " second " can be expressed or imply Ground includes one or more of the features.In the description of the present invention, unless otherwise indicated, the meaning of " plurality " is two or It is more than two.
The above is only some embodiments of the application, it is noted that those skilled in the art are come It says, under the premise of not departing from the application principle, several improvements and modifications can also be made, these improvements and modifications also should be regarded as The protection scope of the application.

Claims (7)

1. a kind of floor tile with enamel layer characterized by comprising brick body and functional layer;
The functional layer includes metal foil, and invests the enamel layer of metal foil outer surface in packet, and enamel layer is a kind of nothing Machine object enamel, the thickness range of the metal foil are 10 millimeters, and the ingredient of enamel layer includes iron oxide, zinc oxide and pigment, Function layer surface is through anti-skidding processing;
Brick body includes enamel portion and brick portion, and the enamel portion covers the surface in the brick portion at least partly, brick body With a thickness of 8 millimeters;
The functional layer is at least set to the side that brick body is provided with enamel portion, and at least covers the enamel portion backwards The side in the brick portion;
Wherein, the setting range of the thickness of the enamel layer and the functional layer in brick body is according to the enamel portion Thickness determines;
If the thickness in the enamel portion, less than 0.5 millimeter, the thickness range of the enamel layer is 0.5~0.8 millimeter;If described The thickness in enamel portion is more than or equal to 0.5 millimeter, then the thickness range of the enamel layer is 0.8~1.0 millimeter;
If the thickness in the enamel portion, less than 0.8 millimeter, the functional layer is at least in the enamel portion in the enamel portion week To marginal position, be set in the brick portion.
2. the floor tile according to claim 1 with enamel layer, which is characterized in that the enamel layer includes: matrix Agent;
The ingredient of described matrix agent includes zirconium oxide and silica, if the thickness in the enamel portion less than 0.5 millimeter, the oxygen The range for changing the mass ratio of zirconium and silica in described matrix agent is 1:10 to 3:10.
3. the floor tile according to claim 2 with enamel layer, which is characterized in that if the thickness in the enamel portion is small In 0.5 millimeter, then the range of mass percent of the described matrix agent in the enamel layer are as follows: 45%~70%.
4. the floor tile according to claim 2 with enamel layer, which is characterized in that further include oxygen in described matrix agent Change potassium and boron oxide;
If the thickness of the enamel layer is greater than the thickness in the enamel portion, the potassium oxide and boron oxide are in described matrix agent The sum of mass percent be not less than 5%.
5. the floor tile according to claim 4 with enamel layer, which is characterized in that if the thickness in the enamel portion is small In 0.5 millimeter, then mass percent of the boron oxide in described matrix agent is not less than 3%.
6. the floor tile according to any one of claims 1 to 5 with enamel layer, which is characterized in that the enamel layer In further include antibacterial agent;
The antibacterial agent includes at least one of silver ion antimicrobial agent and titanium dioxide.
7. the floor tile according to claim 6 with enamel layer, which is characterized in that if the thickness in the enamel portion is small In 0.8 millimeter, then the antibacterial agent is silver ion antimicrobial agent.
CN201910829127.7A 2019-09-03 2019-09-03 Floor tile with enamel glaze layer Active CN110528817B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910829127.7A CN110528817B (en) 2019-09-03 2019-09-03 Floor tile with enamel glaze layer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910829127.7A CN110528817B (en) 2019-09-03 2019-09-03 Floor tile with enamel glaze layer

Publications (2)

Publication Number Publication Date
CN110528817A true CN110528817A (en) 2019-12-03
CN110528817B CN110528817B (en) 2020-11-17

Family

ID=68666688

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910829127.7A Active CN110528817B (en) 2019-09-03 2019-09-03 Floor tile with enamel glaze layer

Country Status (1)

Country Link
CN (1) CN110528817B (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201273041Y (en) * 2008-09-29 2009-07-15 浙江开尔实业有限公司 Enamel decorating sound-absorbing slab
CN202164770U (en) * 2011-07-15 2012-03-14 中盛建材有限公司 Novel porcelain aluminum veneer
KR20140049104A (en) * 2012-10-12 2014-04-25 (주)엘지하우시스 Energy saving decoration sheet
CN204510672U (en) * 2015-01-20 2015-07-29 四川汇丰陶瓷有限公司 Functional form ceramic tile
CN208899799U (en) * 2018-08-03 2019-05-24 江苏新丽源南亚新材料有限公司 A kind of enamelled pressed steel

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201273041Y (en) * 2008-09-29 2009-07-15 浙江开尔实业有限公司 Enamel decorating sound-absorbing slab
CN202164770U (en) * 2011-07-15 2012-03-14 中盛建材有限公司 Novel porcelain aluminum veneer
KR20140049104A (en) * 2012-10-12 2014-04-25 (주)엘지하우시스 Energy saving decoration sheet
CN204510672U (en) * 2015-01-20 2015-07-29 四川汇丰陶瓷有限公司 Functional form ceramic tile
CN208899799U (en) * 2018-08-03 2019-05-24 江苏新丽源南亚新材料有限公司 A kind of enamelled pressed steel

Also Published As

Publication number Publication date
CN110528817B (en) 2020-11-17

Similar Documents

Publication Publication Date Title
CN110776257B (en) Ceramic glaze with antibacterial function and preparation method and application thereof
CN105298009B (en) A kind of vermiculite calcium silicates composite plate of releasable negative oxygen ion and preparation method thereof
CN101024582A (en) Method for producing metal enamel
CN107882205A (en) A kind of Novel fireproof earthquake-proof energy-saving wall structure and its application
CN105948501B (en) Super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant and preparation method thereof
CN103242731B (en) Disconnected hot coating
CN103467136A (en) Negative-ion eco-ceramic tile and preparation method thereof
KR100985416B1 (en) interior/exterior panel for building contruction use and fabrication method thereof
CN110528817A (en) A kind of floor tile with enamel layer
CN207469489U (en) A kind of building heat preservation and structure-integrated composite insulation boards
KR200497538Y1 (en) Flooring material
KR20060110890A (en) The invention of multi-functional tile by special additive
HUE027457T2 (en) Method of manufacturing a decoration element on both sides of a glass or ceramic panel and panel obtained by this method
CN110644705A (en) Polycrystalline mosaic plate and preparation method thereof
CN106116458A (en) Antibacterial Antique Imitation Tiles and preparation method thereof
AU2021100793A4 (en) Decorative magnesium oxychloride cement board doped with waste red brick powder
CN207553483U (en) A kind of composite ceramic brick
CN105038454A (en) Building energy-saving thin-layer paint and preparation method therefor
NL2028460B1 (en) Floor tile with porcelain enamel layer
JP2001106564A (en) Manufacturing method of moisture-controllable tile and moisture-controllable tile
CN207211591U (en) A kind of imitative stone product with air-cleaning function
KR101406750B1 (en) Mat block and method of manufacturing the same
KR101406747B1 (en) Mat block and method of manufacturing the same
CN202131732U (en) Inorganic thermal insulating decoration board
CN106049788B (en) A kind of fire prevention baking-free ceramic plate and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant