CN105948501B - Super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant and preparation method thereof - Google Patents
Super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant and preparation method thereof Download PDFInfo
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- CN105948501B CN105948501B CN201610281043.0A CN201610281043A CN105948501B CN 105948501 B CN105948501 B CN 105948501B CN 201610281043 A CN201610281043 A CN 201610281043A CN 105948501 B CN105948501 B CN 105948501B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The present invention relates to super spar ecology ceramic tiles of a kind of negative oxygen ion Buddha's warrior attendant and preparation method thereof, belong to the technical field of improvement of ecological ceramic tile.The super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant of the present invention, including ceramic tile blank and cover coat, cover coat are made of the raw material of following weight percentage：Potassium feldspar 20 30%, albite 10 15%, zinc oxide 3 5%, high temperature frit 10 20%, wollastonite 3 5%, kaolin 8 10%, corundum 3 5%, barium carbonate 5 10% burn talcum 3 5%, rare earth indium composite material powder 2 7%, tourmaline 1 2%.The super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant of the present invention, formula is simple, and not only hardness is high, and corrosion resistance, resistance to acid and alkali, wearability significantly improve, and radioactivity is up to standard, the releasing negative oxygen ion that can stablize；Invention also provides a kind of simple, energy-saving and environment-friendly preparation methods.
Description
Technical field
The present invention relates to super spar ecology ceramic tiles of a kind of negative oxygen ion Buddha's warrior attendant and preparation method thereof, belong to changing for ecological ceramic tile
Into technical field.
Background technology
Negative oxygen ion, also referred to as anion, " vitamin " being referred to as in air.Based on enable air ionization generate bear from
The reason of son, the negative-ion fiber or textile studied both at home and abroad at present are all by means of terres rares that certain contains trace-level activity
Ore or natural mineral matter, are added to using different technologies in textile material, the effect of with generating negative ions.Anion
It is a kind of far-infrared radiation material very useful to health, the number of anion in air, by geographical conditions particularity
Influence and content is different.Nearby and in forest content is more for park, suburb field, beach, lake, waterfall.Therefore, when people into
When entering above-mentioned place, brains is pure and fresh, and breathing is happy and frank.But in existing indoor design, central heating and cold air
The air-conditioning system of equipment, anion are often purged, and synthetic fibers, carpet carry positive charge, also easy absorption anion, reinforcing bar,
Fiberboard all absorbs anion.Therefore, it when people enter noisy crowded crowd, or enter in air-conditioned room, then makes one to feel
Sultry, unsmooth breath etc..
With the development of ceramic function technology, people's living standards continue to improve, people anticipate to the environmental protection of living environment
Knowledge is more and more stronger, does not require nothing more than living environment health, but also comfortably to have healthcare function.Then negative ion health material is answered
It transports and gives birth to, a kind of new anion function ceramic material is gradually recognized by people, and goes out various ring health cares with this material preparation
The ceramic new product of health.The existing Ceramic Tiles with anion function, not only hardness is low, corrosion resistance, resistance to acid and alkali, wear-resisting
Property is poor, and radioactivity is not up to standard, the releasing negative oxygen ion that can not stablize, and using being extremely restricted, the prior art is also
It is to be improved and developed.
Invention content
The purpose of the present invention is to provide a kind of super spar ecology ceramic tiles of negative oxygen ion Buddha's warrior attendant, and formula is simple, not only firmly
Degree is high, and corrosion resistance, resistance to acid and alkali, wearability significantly improve, and radioactivity is up to standard, the releasing negative oxygen ion that can stablize；
Invention also provides a kind of simple, energy-saving and environment-friendly preparation methods.
The super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant of the present invention, including ceramic tile blank and cover coat, cover coat by
The raw material of following weight percentage is made：Potassium feldspar 20-30%, albite 10-15%, zinc oxide 3-5%, high temperature frit
10-20%, wollastonite 3-5%, kaolin 8-10%, corundum 3-5%, barium carbonate 5-10% burn talcum 3-5%, and rare earth indium is multiple
Condensation material powder 2-7%, tourmaline 1-2%.
Preferably, cover coat is made of the raw material of following weight percentage：Potassium feldspar 25-30%, albite 10-
12%, zinc oxide 3-5%, high temperature frit 10-15%, wollastonite 3-5%, kaolin 8-10%, corundum 3-5%, barium carbonate 5-
8%, burn talcum 3-5%, rare earth indium composite material powder 2-3%, tourmaline 1-2%.
The mass content of each ingredient is as follows in the high temperature frit：Silicon 45-50%, aluminium 20-25%, calcium 8-10%, magnesium 1-
3%, potassium 3-5%, sodium 1-3%, barium 5-7%, zinc 5-8%.
The rare earth indium composite material powder energy sustained release negative oxygen ion, grain size 10-15nm, in the particle size range
Powder on the one hand can make anion be easier discharge, maintain higher burst size, on the other hand can make prepared Ceramic Tiles
The more smooth exquisiteness of glaze.Indium accounts for the 18-22% of rare earth indium composite material powder quality.Rare earth indium composite material is commercially available material,
It is preferred that producer is Hunan Research Institute of Rare Earth Metal Materials.
The rare earth indium composite material powder is used in combination with tourmaline, and the two mutually cooperates with, and it is dilute to overcome exclusive use
A kind of this material containing negative oxygen ion of native indium composite material powder there are the drawbacks of, the releasing negative oxygen ion of ceramic tile stabilization can be made.
The thickness of the ceramic tile blank is 12 ± 0.2mm, and overglaze layer thickness is 0.5 ± 0.1mm.
Each raw material in the cover coat mutually cooperates with, and each raw material is indispensable, obtains a kind of translucent, hardness
Height, corrosion resistance, resistance to acid and alkali, wearability are good, and radioactivity is up to standard, can stablize the glaze of releasing negative oxygen ion.
The preparation method of the super spar ecology ceramic tile of the negative oxygen ion Buddha's warrior attendant, includes the following steps：
(1) water, methylcellulose and sodium tripolyphosphate are added into the raw material of cover coat and are mixed into glaze slip, glaze slip is carried out
Ball milling screens, and then dries, beats powder and screen again；
(2) glaze after dressing sieve selects will be broken with stamp-pad ink carrier according to 3:2 mass ratio mixing, it is small then to carry out ball milling 3-5
When, negative oxygen ion glaze slip is made, crosses 140 mesh standard sieves；
(3) negative oxygen ion glaze slip obtained by step (2) is printed onto ceramic tile blank surface with 100 mesh screen mesh printing plates and printing machine
On；
(4) ceramic tile semi-finished product obtained by step (3) are burnt into through ceramic roller kiln at 1100-1200 DEG C, then it is polished, beat
The super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant is made in wax, glazing antifouling process.
In step (1), the quality of the water of addition, methylcellulose and sodium tripolyphosphate is respectively cover coat raw material gross mass
30%, 0.1-0.2% and 0.3-0.4%.
In step (1), ball milling glaze slip fineness is sieved to 325 mesh, and 100ml glaze slips is taken to tail within 0.1 gram；Powder fineness is beaten to exist
325 mesh sieve, and 100 grams of dressing sieves is taken to tail at 0.1 gram or less.
In step (2), stamp-pad ink carrier is that 98% water and 2% methylcellulose form by mass percentage.
Compared with prior art, the present invention having the advantages that：
(1) formula is simple, the super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant prepared, not only hardness height, corrosion resistance, resistance to
Acid-base property, wearability significantly improve, and radioactivity is up to standard, the releasing negative oxygen ion that can stablize；
(2) negative oxygen ion of the super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant described in, release can not only eliminate haze, disappear
It except formaldehyde, goes to eliminate the unusual smell, and air, health care can be purified；
(3) preparation method of the super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant is simple, energy conservation and environmental protection.
Specific implementation mode
With reference to embodiment, the present invention is further illustrated, but it is not intended to limit the implementation of the present invention.
Raw materials used in embodiment is commercially available material.
Embodiment 1
A kind of super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant, including ceramic tile blank and cover coat, cover coat is by following weight
The raw material of percentage composition is made：Potassium feldspar 20%, albite 11%, zinc oxide 5%, high temperature frit 20%, wollastonite 5% are high
Ridge soil 10%, corundum 5%, barium carbonate 10% burn talcum 5%, rare earth indium composite material powder 7%, tourmaline 2%.
The rare earth indium composite material powder grain size is 10nm, and indium accounts for the 18% of rare earth indium composite material powder quality.
The preparation method of the super spar ecology ceramic tile of the negative oxygen ion Buddha's warrior attendant, includes the following steps：
(1) water, methylcellulose and sodium tripolyphosphate are added into the raw material of cover coat and are mixed into glaze slip, to glaze slip ball milling
Fineness is sieved to 325 mesh, and 100ml glaze slips is taken to tail within 0.1 gram；Then it dries, beat powder fineness and sieved in 325 mesh, take 100 grams of powder
It tails at 0.1 gram or less；The quality of the water of addition, methylcellulose and sodium tripolyphosphate is respectively cover coat raw material gross mass
30%, 0.1% and 0.3%.
(2) it is (fine for 98% water and 2% methyl by mass percentage with stamp-pad ink carrier that the glaze after dressing sieve selects will be broken
Dimension element composition) according to 3:2 mass ratio mixing, then carries out ball milling 3 hours, and negative oxygen ion glaze slip is made, it is accurate to cross 140 targets
Sieve.
(3) negative oxygen ion glaze slip obtained by step (2) is printed onto ceramic tile blank surface with 100 mesh screen mesh printing plates and printing machine
On；
(4) ceramic tile semi-finished product obtained by step (3) are burnt into through ceramic roller kiln at 1100 DEG C, then polished, waxing, on
The super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant is made in light antifouling process.
The thickness of ceramic tile blank obtained is 11.8mm, and overglaze layer thickness is 0.6mm.
Embodiment 2
A kind of super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant, including ceramic tile blank and cover coat, cover coat is by following weight
The raw material of percentage composition is made：Potassium feldspar 30%, albite 15%, zinc oxide 3%, high temperature frit 18%, wollastonite 5% are high
Ridge soil 8%, corundum 5%, barium carbonate 8% burn talcum 3%, rare earth indium composite material powder 4%, tourmaline 1%.
The rare earth indium composite material powder grain size is 15nm, and indium accounts for the 22% of rare earth indium composite material powder quality.
The preparation method of the super spar ecology ceramic tile of the negative oxygen ion Buddha's warrior attendant, includes the following steps：
(1) water, methylcellulose and sodium tripolyphosphate are added into the raw material of cover coat and are mixed into glaze slip, to glaze slip ball milling
Fineness is sieved to 325 mesh, and 100ml glaze slips is taken to tail within 0.1 gram；Then it dries, beat powder fineness and sieved in 325 mesh, take 100 grams of powder
It tails at 0.1 gram or less；The quality of the water of addition, methylcellulose and sodium tripolyphosphate is respectively cover coat raw material gross mass
30%, 0.2% and 0.4%.
(2) it is (fine for 98% water and 2% methyl by mass percentage with stamp-pad ink carrier that the glaze after dressing sieve selects will be broken
Dimension element composition) according to 3:2 mass ratio mixing, then carries out ball milling 5 hours, and negative oxygen ion glaze slip is made, it is accurate to cross 140 targets
Sieve.
(3) negative oxygen ion glaze slip obtained by step (2) is printed onto ceramic tile blank surface with 100 mesh screen mesh printing plates and printing machine
On；
(4) ceramic tile semi-finished product obtained by step (3) are burnt into through ceramic roller kiln at 1200 DEG C, then polished, waxing, on
The super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant is made in light antifouling process.
The thickness of ceramic tile blank obtained is 12.2mm, and overglaze layer thickness is 0.4mm.
Embodiment 3
A kind of super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant, including ceramic tile blank and cover coat, cover coat is by following weight
The raw material of percentage composition is made：Potassium feldspar 25%, albite 15%, zinc oxide 5%, high temperature frit 15%, wollastonite 5% are high
Ridge soil 10%, corundum 3%, barium carbonate 8% burn talcum 5%, rare earth indium composite material powder 7%, tourmaline 2%.
The rare earth indium composite material powder grain size is 12nm, and indium accounts for the 20% of rare earth indium composite material powder quality.
The preparation method of the super spar ecology ceramic tile of the negative oxygen ion Buddha's warrior attendant, includes the following steps：
(1) water, methylcellulose and sodium tripolyphosphate are added into the raw material of cover coat and are mixed into glaze slip, to glaze slip ball milling
Fineness is sieved to 325 mesh, and 100ml glaze slips is taken to tail within 0.1 gram；Then it dries, beat powder fineness and sieved in 325 mesh, take 100 grams of powder
It tails at 0.1 gram or less；The quality of the water of addition, methylcellulose and sodium tripolyphosphate is respectively cover coat raw material gross mass
30%, 0.2% and 0.3%.
(2) it is (fine for 98% water and 2% methyl by mass percentage with stamp-pad ink carrier that the glaze after dressing sieve selects will be broken
Dimension element composition) according to 3:2 mass ratio mixing, then carries out ball milling 4 hours, and negative oxygen ion glaze slip is made, it is accurate to cross 140 targets
Sieve.
(3) negative oxygen ion glaze slip obtained by step (2) is printed onto ceramic tile blank surface with 100 mesh screen mesh printing plates and printing machine
On；
(4) ceramic tile semi-finished product obtained by step (3) are burnt into through ceramic roller kiln at 1150 DEG C, then polished, waxing, on
The super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant is made in light antifouling process.
The thickness of ceramic tile blank obtained is 12.0mm, and overglaze layer thickness is 0.5mm.
Embodiment 4
A kind of super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant, including ceramic tile blank and cover coat, cover coat is by following weight
The raw material of percentage composition is made：Potassium feldspar 28%, albite 14%, zinc oxide 3%, high temperature frit 19%, wollastonite 3% are high
Ridge soil 8%, corundum 3%, barium carbonate 9% burn talcum 5%, rare earth indium composite material powder 6%, tourmaline 2%.
The rare earth indium composite material powder grain size is 13nm, and indium accounts for the 21% of rare earth indium composite material powder quality.
The preparation method of the super spar ecology ceramic tile of the negative oxygen ion Buddha's warrior attendant, includes the following steps：
(1) water, methylcellulose and sodium tripolyphosphate are added into the raw material of cover coat and are mixed into glaze slip, to glaze slip ball milling
Fineness is sieved to 325 mesh, and 100ml glaze slips is taken to tail within 0.1 gram；Then it dries, beat powder fineness and sieved in 325 mesh, take 100 grams of powder
It tails at 0.1 gram or less；The quality of the water of addition, methylcellulose and sodium tripolyphosphate is respectively cover coat raw material gross mass
30%, 0.1% and 0.4%.
(2) it is (fine for 98% water and 2% methyl by mass percentage with stamp-pad ink carrier that the glaze after dressing sieve selects will be broken
Dimension element composition) according to 3:2 mass ratio mixing, then carries out ball milling 3 hours, and negative oxygen ion glaze slip is made, it is accurate to cross 140 targets
Sieve.
(3) negative oxygen ion glaze slip obtained by step (2) is printed onto ceramic tile blank surface with 100 mesh screen mesh printing plates and printing machine
On；
(4) ceramic tile semi-finished product obtained by step (3) are burnt into through ceramic roller kiln at 1180 DEG C, then polished, waxing, on
The super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant is made in light antifouling process.
The green body thickness of ceramic tile obtained is 12.1mm, and overglaze layer thickness is 0.6mm, the mean release of negative oxygen ion
For：3000-6000/cm3, so that indoor negative oxygen ion concentration is higher than using concentration possessed by common ceramic tile, make household more
It is comfortable happy.
Radio-activity testing is carried out to ceramic tile obtained, test result shows the super spar ecology of negative oxygen ion Buddha's warrior attendant obtained
The equal ＜ 0.6 of the inside and outside Irradiation index of ceramic tile, radioactivity is small, well below construction material standard GB/T 6566-2001《It builds
Build material radionuclide limitation》In regulation (radioactivity of A class finishing materials will meet the He of External Exposure Index≤1.0 simultaneously
Outreach services≤1.3).
Claims (10)
1. a kind of super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant, including ceramic tile blank and cover coat, it is characterised in that：Cover coat by
The raw material of following weight percentage is made：Potassium feldspar 20-30%, albite 10-15%, zinc oxide 3-5%, high temperature frit
10-20%, wollastonite 3-5%, kaolin 8-10%, corundum 3-5%, barium carbonate 5-10% burn talcum 3-5%, and rare earth indium is multiple
Condensation material powder 2-7%, tourmaline 1-2%.
2. the super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant according to claim 1, it is characterised in that：Cover coat is by following heavy
The raw material of amount percentage composition is made：Potassium feldspar 25-30%, albite 10-15%, zinc oxide 3-5%, high temperature frit 18-19%,
Wollastonite 3-5%, kaolin 8-10%, corundum 3-5%, barium carbonate 5-8% burn talcum 3-5%, rare earth indium composite material powder
2-3%, tourmaline 1-2%.
3. the super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant according to claim 1, it is characterised in that：In high temperature frit respectively at
The mass content divided is as follows：Silicon 45-50%, aluminium 20-25%, calcium 8-10%, magnesium 1-3%, potassium 3-5%, sodium 1-3%, barium 5-
7%, zinc 5-8%.
4. the super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant according to claim 1, it is characterised in that：Rare earth indium composite material
The grain size of powder is 10-15nm, and indium accounts for the 18-22% of rare earth indium composite material powder quality.
5. the super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant according to claim 1, it is characterised in that：The thickness of ceramic tile blank
For 12 ± 0.2mm, overglaze layer thickness is 0.5 ± 0.1mm.
6. a kind of preparation method of any super spar ecology ceramic tiles of negative oxygen ion Buddha's warrior attendant of claim 1-5, feature exist
In including the following steps：
(1) water, methylcellulose and sodium tripolyphosphate are added into the raw material of cover coat and are mixed into glaze slip, ball milling is carried out to glaze slip
Then screening dries, beats powder and screen again；
(2) glaze after dressing sieve selects will be broken with stamp-pad ink carrier according to 3:2 mass ratio mixing, then carries out ball milling, negative oxygen is made
Ion glaze slip, sieving；
(3) negative oxygen ion glaze slip obtained by step (2) is printed onto with 100 mesh screen mesh printing plates and printing machine on ceramic tile blank surface；
(4) ceramic tile semi-finished product obtained by step (3) are burnt into through ceramic roller kiln at 1180-1200 DEG C, negative oxygen ion gold is made
Rigid super spar ecology ceramic tile.
7. the preparation method of the super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant according to claim 6, it is characterised in that：Step
(1) in, the quality of the water of addition, methylcellulose and sodium tripolyphosphate is respectively the 30% of cover coat raw material gross mass, 0.1-
0.2% and 0.3-0.4%.
8. the preparation method of the super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant according to claim 6, it is characterised in that：Step
(1) in, ball milling glaze slip fineness is sieved to 325 mesh, and 100ml glaze slips is taken to tail within 0.1 gram；It beats powder fineness to sieve in 325 mesh, take
100 grams of dressing sieves are tailed at 0.1 gram or less.
9. the preparation method of the super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant according to claim 6, it is characterised in that：Step
(2) in, stamp-pad ink carrier is that 98% water and 2% methylcellulose form by mass percentage.
10. the preparation method of the super spar ecology ceramic tile of negative oxygen ion Buddha's warrior attendant according to claim 6, it is characterised in that：Step
Suddenly in (2), ball milling 3-5 hours；Cross 140 mesh standard sieves.
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| CN108331281B (en) * | 2018-01-11 | 2019-02-01 | 广东百强陶瓷有限公司 | A kind of superbright anion glazed tile and its production technology |
| CN108595039A (en) * | 2018-07-12 | 2018-09-28 | 福建序源堂陶瓷文化有限公司 | A kind of ceramic mouse pad of sustainable releasing negative oxygen ion |
| CN108911788A (en) * | 2018-07-24 | 2018-11-30 | 信阳市上天梯非金属矿管理区非金属矿技术开发应用研究所 | With the function ceramics brick and preparation method thereof that can excite releasing negative oxygen ion surface layer |
| CN109437569B (en) * | 2018-12-14 | 2021-08-31 | 广东金意陶陶瓷集团有限公司 | Negative ion ceramic tile and preparation method thereof |
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| CN105948501A (en) | 2016-09-21 |
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Denomination of invention: Negative oxygen ion adamantine superlite ecological ceramic tile and its preparation method Effective date of registration: 20230129 Granted publication date: 20180828 Pledgee: Zibo Zichuan District sub branch of China Post Savings Bank Co.,Ltd. Pledgor: Shandong shiziwang New Material Technology Co.,Ltd. Registration number: Y2023980030872 |
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