CN105948501A - Negative oxygen ion diamond super-spar ecological ceramic tile and preparation method thereof - Google Patents
Negative oxygen ion diamond super-spar ecological ceramic tile and preparation method thereof Download PDFInfo
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- CN105948501A CN105948501A CN201610281043.0A CN201610281043A CN105948501A CN 105948501 A CN105948501 A CN 105948501A CN 201610281043 A CN201610281043 A CN 201610281043A CN 105948501 A CN105948501 A CN 105948501A
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- oxygen ion
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Abstract
The invention relates to a negative oxygen ion diamond super-spar ecological ceramic tile and a preparation method thereof, and belongs to the technical field of the improvement of ecological tiles. The negative oxygen ion diamond super-spar ecological ceramic tile comprises a tile blank and a surface glaze layer. The surface glaze layer is prepared by the following raw materials by weight percentage: 20-30% of potash feldspar, 10-15% of albite, 3-5% of zinc oxide, 10-20% of a high-temperature frit, 3-5% of wollastonite, 8-10% of kaolin, 3-5% of corundum, 5-10% of barium carbonate, 3-5% of calcinedtalc, 2-7% of rare-earth indium composite material powders and 1-2% of tourmalinite. The negative oxygen ion diamond super-spar ecological ceramic tile provided in the invention is simple in formulation, high in hardness, strong in corrosion resistance, acid resistance and alkali resistance, significantly improved in wear resistance and qualified in radioactivity. Meanwhile, the negative oxygen ion diamond super-spar ecological ceramic tile can stably release negative oxygen ions. The invention also provides a simple, energy-saving and environment-friendly preparation method.
Description
Technical field
The present invention relates to a kind of negative oxygen ion Buddha's warrior attendant and surpass spar ecology ceramic tile and preparation method thereof, belong to the improvement technology of ecological ceramic tile
Field.
Background technology
Negative oxygen ion, also referred to as anion, " vitamin " being referred to as in air.Anion can be produced based on making air ionization
Reason, the negative-ion fiber of at present both at home and abroad research or textile all by means of certain contain trace-level activity rare earth ore or
Natural mineral matter, uses different technologies to add in textile material, is allowed to the effect with generating negative ions.Anion is a kind of
The far-infrared radiation material being highly profitable health, in air, the number of anion, is affected by geographical conditions particularity and is contained
Amount difference.Park, field, suburb, beach, lake, content is more near waterfall and in forest.Therefore, when in people's entrance
The when of stating place, brains is pure and fresh, breathes happy and frank.But, in existing indoor design, central heating and cold air set
Standby air conditioning system, anion is often purged, and synthetic fibers, carpet are with positive charge, the most easily absorbs anion, reinforcing bar,
Fibre board all absorbs anion.Therefore, when people enter in noisy crowded crowd, or entrance air-conditioned room, then people is made to feel
Sultry, hypopnea etc..
Along with the development of pottery function technology, improving constantly of people's living standard, the environmental consciousness of living environment is more come by people
The strongest, do not require nothing more than living environment health, but also want comfortable and there is health care.Then negative ion health material arises at the historic moment,
A kind of new anion function ceramic material is gradually recognized by people, and prepares the pottery of various environment protection health newly with this material
Product.The existing Ceramic Tiles with anion function, not only hardness is low, and corrosion resistance, resistance to acids and bases, wearability are poor,
And radioactivity is the most up to standard, it is impossible to enough stable releasing negative oxygen ions, application is extremely restricted, and prior art needs to change
Enter and develop.
Summary of the invention
It is an object of the invention to provide a kind of negative oxygen ion Buddha's warrior attendant and surpass spar ecology ceramic tile, its formula is simple, and not only hardness is high,
Corrosion resistance, resistance to acids and bases, wearability significantly improve, and radioactivity is up to standard, it is possible to stable releasing negative oxygen ion；This
Bright provide a kind of simple, preparation method of energy-conserving and environment-protective simultaneously.
Negative oxygen ion Buddha's warrior attendant of the present invention surpasses spar ecology ceramic tile, and including ceramic tile blank and cover coat, cover coat is by following heavy
The raw material of amount percentage composition is made: potassium feldspar 20-30%, albite 10-15%, zinc oxide 3-5%, high temperature frit 10-20%,
Wollastonite 3-5%, Kaolin 8-10%, corundum 3-5%, brium carbonate 5-10%, burn Talcum 3-5%, rare earth indium composite powder
Body 2-7%, tourmaline 1-2%.
Preferably, cover coat is made up of the raw material of following weight percentage: potassium feldspar 25-30%, albite 10-12%, oxygen
Change zinc 3-5%, high temperature frit 10-15%, wollastonite 3-5%, Kaolin 8-10%, corundum 3-5%, brium carbonate 5-8%, burn
Talcum 3-5%, rare earth indium composite material powder 2-3%, tourmaline 1-2%.
In described high temperature frit, the mass content of each composition is as follows: silicon 45-50%, aluminum 20-25%, calcium 8-10%, magnesium 1-3%,
Potassium 3-5%, sodium 1-3%, barium 5-7%, zinc 5-8%.
Described rare earth indium composite material powder energy sustained release negative oxygen ion, its particle diameter is 10-15nm, the powder in this particle size range
On the one hand body can make anion be easier to release, maintains higher burst size, on the other hand can make prepared Ceramic Tiles glaze more
Smooth exquisiteness.Indium accounts for the 18-22% of rare earth indium composite material powder quality.Rare earth indium composite is commercially available material, preferably producer
For Hunan Research Institute of Rare Earth Metal Materials.
Described rare earth indium composite material powder and tourmaline compound use, both are the most collaborative, overcome and are used alone rare earth indium again
This kind of drawback existed containing negative oxygen ion material of condensation material powder body, can make the releasing negative oxygen ion that ceramic tile is stable.
The thickness of described ceramic tile blank is 12 ± 0.2mm, and cover coat thickness is 0.5 ± 0.1mm.
Each raw material in described cover coat is the most collaborative, and each raw material is indispensable, obtain a kind of translucent, hardness is high, resistance to
Corrosivity, resistance to acids and bases, wearability are good, and radioactivity is up to standard, it is possible to stablize the glaze of releasing negative oxygen ion.
Described negative oxygen ion Buddha's warrior attendant surpasses the preparation method of spar ecology ceramic tile, comprises the following steps:
(1) in the raw material of cover coat, add water, methylcellulose and sodium tripolyphosphate and be mixed into glaze slip, glaze slip is carried out ball milling
Screening, then dries, beats powder and screen；
(2) glaze after playing dressing sieve choosing mixes according to the mass ratio of 3:2 with stamp-pad ink carrier, then carries out ball milling 3-5 hour,
Make negative oxygen ion glaze slip, cross 140 mesh standard sieves；
(3) step (2) gained negative oxygen ion glaze slip 100 mesh screen mesh printing plates and printing machine are printed onto on ceramic tile blank surface；
(4) step (3) gained ceramic tile semi-finished product are burnt till at ceramic roller kiln is at 1100-1200 DEG C, more polished, waxing,
The antifouling process of glazing, prepares negative oxygen ion Buddha's warrior attendant and surpasses spar ecology ceramic tile.
In step (1), the quality of the water of addition, methylcellulose and sodium tripolyphosphate is respectively cover coat raw material gross mass
30%, 0.1-0.2% and 0.3-0.4%.
In step (1), ball milling glaze slip fineness, to 325 mesh sieves, takes 100ml glaze slip and tails within 0.1 gram；Beat powder fineness to exist
325 mesh sieves, take 100 grams of dressing sieves and tail over below 0.1 gram.
In step (2), stamp-pad ink carrier is made up of the methylcellulose of the water that weight/mass percentage composition is 98% and 2%.
The present invention compared with prior art, has the advantages that
(1) formula is simple, and the negative oxygen ion Buddha's warrior attendant prepared surpasses spar ecology ceramic tile, and not only hardness is high, corrosion resistance, acidproof
Alkalescence, wearability significantly improve, and radioactivity is up to standard, it is possible to stable releasing negative oxygen ion；
(2) the negative oxygen ion Buddha's warrior attendant described in surpasses spar ecology ceramic tile, and the negative oxygen ion of its release can not only eliminate haze, eliminates first
Aldehyde, goes to eliminate the unusual smell, and can purify air, health care；
(3) negative oxygen ion Buddha's warrior attendant surpasses the preparation method of spar ecology ceramic tile simply, energy-conserving and environment-protective.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated, but it is not limiting as the enforcement of the present invention.
Raw materials used in embodiment it is commercially available material.
Embodiment 1
A kind of negative oxygen ion Buddha's warrior attendant surpasses spar ecology ceramic tile, and including ceramic tile blank and cover coat, cover coat is contained by following weight percent
The raw material of amount is made: potassium feldspar 20%, albite 11%, zinc oxide 5%, high temperature frit 20%, wollastonite 5%, Kaolin
10%, corundum 5%, brium carbonate 10%, burns Talcum 5%, rare earth indium composite material powder 7%, tourmaline 2%.
Described rare earth indium composite material powder particle diameter is 10nm, and indium accounts for the 18% of rare earth indium composite material powder quality.
Described negative oxygen ion Buddha's warrior attendant surpasses the preparation method of spar ecology ceramic tile, comprises the following steps:
(1) in the raw material of cover coat, add water, methylcellulose and sodium tripolyphosphate and be mixed into glaze slip, to glaze slip ball milling fineness
To 325 mesh sieves, take 100ml glaze slip and tail within 0.1 gram；Then dry, beat powder fineness at 325 mesh sieves, take 100 grams
Dressing sieve tails over below 0.1 gram；The quality of the water, methylcellulose and the sodium tripolyphosphate that add is respectively the total matter of cover coat raw material
30%, 0.1% and the 0.3% of amount.
(2) glaze after dressing sieve selects will be broken with stamp-pad ink carrier (by the water that weight/mass percentage composition is 98% and the methylcellulose of 2%
Composition) mix according to the mass ratio of 3:2, then carry out ball milling 3 hours, make negative oxygen ion glaze slip, cross 140 mesh standard sieves.
(3) step (2) gained negative oxygen ion glaze slip 100 mesh screen mesh printing plates and printing machine are printed onto on ceramic tile blank surface；
(4) step (3) gained ceramic tile semi-finished product are burnt till at 1100 DEG C through ceramic roller kiln, more polished, waxing, on
The antifouling process of light, prepares negative oxygen ion Buddha's warrior attendant and surpasses spar ecology ceramic tile.
The thickness of the ceramic tile blank prepared is 11.8mm, and cover coat thickness is 0.6mm.
Embodiment 2
A kind of negative oxygen ion Buddha's warrior attendant surpasses spar ecology ceramic tile, and including ceramic tile blank and cover coat, cover coat is contained by following weight percent
The raw material of amount is made: potassium feldspar 30%, albite 15%, zinc oxide 3%, high temperature frit 18%, wollastonite 5%, Kaolin
8%, corundum 5%, brium carbonate 8%, burns Talcum 3%, rare earth indium composite material powder 4%, tourmaline 1%.
Described rare earth indium composite material powder particle diameter is 15nm, and indium accounts for the 22% of rare earth indium composite material powder quality.
Described negative oxygen ion Buddha's warrior attendant surpasses the preparation method of spar ecology ceramic tile, comprises the following steps:
(1) in the raw material of cover coat, add water, methylcellulose and sodium tripolyphosphate and be mixed into glaze slip, to glaze slip ball milling fineness
To 325 mesh sieves, take 100ml glaze slip and tail within 0.1 gram；Then dry, beat powder fineness at 325 mesh sieves, take 100 grams
Dressing sieve tails over below 0.1 gram；The quality of the water, methylcellulose and the sodium tripolyphosphate that add is respectively the total matter of cover coat raw material
30%, 0.2% and the 0.4% of amount.
(2) glaze after dressing sieve selects will be broken with stamp-pad ink carrier (by the water that weight/mass percentage composition is 98% and the methylcellulose of 2%
Composition) mix according to the mass ratio of 3:2, then carry out ball milling 5 hours, make negative oxygen ion glaze slip, cross 140 mesh standard sieves.
(3) step (2) gained negative oxygen ion glaze slip 100 mesh screen mesh printing plates and printing machine are printed onto on ceramic tile blank surface；
(4) step (3) gained ceramic tile semi-finished product are burnt till at 1200 DEG C through ceramic roller kiln, more polished, waxing, on
The antifouling process of light, prepares negative oxygen ion Buddha's warrior attendant and surpasses spar ecology ceramic tile.
The thickness of the ceramic tile blank prepared is 12.2mm, and cover coat thickness is 0.4mm.
Embodiment 3
A kind of negative oxygen ion Buddha's warrior attendant surpasses spar ecology ceramic tile, and including ceramic tile blank and cover coat, cover coat is contained by following weight percent
The raw material of amount is made: potassium feldspar 25%, albite 15%, zinc oxide 5%, high temperature frit 15%, wollastonite 5%, Kaolin
10%, corundum 3%, brium carbonate 8%, burns Talcum 5%, rare earth indium composite material powder 7%, tourmaline 2%.
Described rare earth indium composite material powder particle diameter is 12nm, and indium accounts for the 20% of rare earth indium composite material powder quality.
Described negative oxygen ion Buddha's warrior attendant surpasses the preparation method of spar ecology ceramic tile, comprises the following steps:
(1) in the raw material of cover coat, add water, methylcellulose and sodium tripolyphosphate and be mixed into glaze slip, to glaze slip ball milling fineness
To 325 mesh sieves, take 100ml glaze slip and tail within 0.1 gram；Then dry, beat powder fineness at 325 mesh sieves, take 100 grams
Dressing sieve tails over below 0.1 gram；The quality of the water, methylcellulose and the sodium tripolyphosphate that add is respectively the total matter of cover coat raw material
30%, 0.2% and the 0.3% of amount.
(2) glaze after dressing sieve selects will be broken with stamp-pad ink carrier (by the water that weight/mass percentage composition is 98% and the methylcellulose of 2%
Composition) mix according to the mass ratio of 3:2, then carry out ball milling 4 hours, make negative oxygen ion glaze slip, cross 140 mesh standard sieves.
(3) step (2) gained negative oxygen ion glaze slip 100 mesh screen mesh printing plates and printing machine are printed onto on ceramic tile blank surface；
(4) step (3) gained ceramic tile semi-finished product are burnt till at 1150 DEG C through ceramic roller kiln, more polished, waxing, on
The antifouling process of light, prepares negative oxygen ion Buddha's warrior attendant and surpasses spar ecology ceramic tile.
The thickness of the ceramic tile blank prepared is 12.0mm, and cover coat thickness is 0.5mm.
Embodiment 4
A kind of negative oxygen ion Buddha's warrior attendant surpasses spar ecology ceramic tile, and including ceramic tile blank and cover coat, cover coat is contained by following weight percent
The raw material of amount is made: potassium feldspar 28%, albite 14%, zinc oxide 3%, high temperature frit 19%, wollastonite 3%, Kaolin
8%, corundum 3%, brium carbonate 9%, burns Talcum 5%, rare earth indium composite material powder 6%, tourmaline 2%.
Described rare earth indium composite material powder particle diameter is 13nm, and indium accounts for the 21% of rare earth indium composite material powder quality.
Described negative oxygen ion Buddha's warrior attendant surpasses the preparation method of spar ecology ceramic tile, comprises the following steps:
(1) in the raw material of cover coat, add water, methylcellulose and sodium tripolyphosphate and be mixed into glaze slip, to glaze slip ball milling fineness
To 325 mesh sieves, take 100ml glaze slip and tail within 0.1 gram；Then dry, beat powder fineness at 325 mesh sieves, take 100 grams
Dressing sieve tails over below 0.1 gram；The quality of the water, methylcellulose and the sodium tripolyphosphate that add is respectively the total matter of cover coat raw material
30%, 0.1% and the 0.4% of amount.
(2) glaze after dressing sieve selects will be broken with stamp-pad ink carrier (by the water that weight/mass percentage composition is 98% and the methylcellulose of 2%
Composition) mix according to the mass ratio of 3:2, then carry out ball milling 3 hours, make negative oxygen ion glaze slip, cross 140 mesh standard sieves.
(3) step (2) gained negative oxygen ion glaze slip 100 mesh screen mesh printing plates and printing machine are printed onto on ceramic tile blank surface；
(4) step (3) gained ceramic tile semi-finished product are burnt till at 1180 DEG C through ceramic roller kiln, more polished, waxing, on
The antifouling process of light, prepares negative oxygen ion Buddha's warrior attendant and surpasses spar ecology ceramic tile.
The base substrate thickness of the ceramic tile prepared is 12.1mm, and cover coat thickness is 0.6mm, and the mean release of its negative oxygen ion is:
3000-6000/cm3, make the negative oxygen ion concentration of indoor higher than the concentration using common ceramic tile to be had, make household the most comfortable pleased
Hurry up.
Prepared ceramic tile is carried out radio-activity testing, and test result shows, in the negative oxygen ion Buddha's warrior attendant prepared surpasses spar ecology ceramic tile,
The equal ＜ of Outreach services 0.6, radioactivity is little, and well below construction material standard GB/T 6566-2001, " construction material is put
Penetrating property radionuclides limitation " in regulation (radioactivity of A class finishing material to meet External Exposure Index≤1.0 and Outreach services simultaneously
≤1.3)。
Claims (10)
1. negative oxygen ion Buddha's warrior attendant surpasses a spar ecology ceramic tile, including ceramic tile blank and cover coat, it is characterised in that: cover coat by
The raw material of following weight percentage is made: potassium feldspar 20-30%, albite 10-15%, zinc oxide 3-5%, high temperature frit
10-20%, wollastonite 3-5%, Kaolin 8-10%, corundum 3-5%, brium carbonate 5-10%, burn Talcum 3-5%, and rare earth indium is multiple
Condensation material powder body 2-7%, tourmaline 1-2%.
Negative oxygen ion Buddha's warrior attendant the most according to claim 1 surpasses spar ecology ceramic tile, it is characterised in that: cover coat is by following heavy
The raw material of amount percentage composition is made: potassium feldspar 25-30%, albite 10-12%, zinc oxide 3-5%, high temperature frit 10-15%,
Wollastonite 3-5%, Kaolin 8-10%, corundum 3-5%, brium carbonate 5-8%, burn Talcum 3-5%, rare earth indium composite material powder
2-3%, tourmaline 1-2%.
Negative oxygen ion Buddha's warrior attendant the most according to claim 1 surpasses spar ecology ceramic tile, it is characterised in that: high temperature frit respectively becomes
The mass content divided is as follows: silicon 45-50%, aluminum 20-25%, calcium 8-10%, magnesium 1-3%, potassium 3-5%, sodium 1-3%, barium 5-7%,
Zinc 5-8%.
Negative oxygen ion Buddha's warrior attendant the most according to claim 1 surpasses spar ecology ceramic tile, it is characterised in that: rare earth indium composite
The particle diameter of powder body is 10-15nm, and indium accounts for the 18-22% of rare earth indium composite material powder quality.
Negative oxygen ion Buddha's warrior attendant the most according to claim 1 surpasses spar ecology ceramic tile, it is characterised in that: the thickness of ceramic tile blank
Being 12 ± 0.2mm, cover coat thickness is 0.5 ± 0.1mm.
6. the arbitrary described negative oxygen ion Buddha's warrior attendant of claim 1-5 surpasses the preparation method of spar ecology ceramic tile, it is characterised in that
Comprise the following steps:
(1) in the raw material of cover coat, add water, methylcellulose and sodium tripolyphosphate and be mixed into glaze slip, glaze slip is carried out ball milling
Screening, then dries, beats powder and screen；
(2) glaze after playing dressing sieve choosing mixes according to the mass ratio of 3:2 with stamp-pad ink carrier, then carries out ball milling, makes negative oxygen
Ion glaze slip, sieves；
(3) step (2) gained negative oxygen ion glaze slip 100 mesh screen mesh printing plates and printing machine are printed onto on ceramic tile blank surface；
(4) step (3) gained ceramic tile semi-finished product are burnt till at ceramic roller kiln is at 1100-1200 DEG C, prepare negative oxygen ion gold
Just super spar ecology ceramic tile.
Negative oxygen ion Buddha's warrior attendant the most according to claim 6 surpasses the preparation method of spar ecology ceramic tile, it is characterised in that: step
(1) in, the quality of the water of addition, methylcellulose and sodium tripolyphosphate is respectively the 30% of cover coat raw material gross mass, 0.1-0.2%
And 0.3-0.4%.
Negative oxygen ion Buddha's warrior attendant the most according to claim 6 surpasses the preparation method of spar ecology ceramic tile, it is characterised in that: step
(1), in, ball milling glaze slip fineness, to 325 mesh sieves, takes 100ml glaze slip and tails within 0.1 gram；Beat powder fineness at 325 mesh sieves,
Take 100 grams of dressing sieves to tail over below 0.1 gram.
Negative oxygen ion Buddha's warrior attendant the most according to claim 6 surpasses the preparation method of spar ecology ceramic tile, it is characterised in that: step
(2), in, stamp-pad ink carrier is made up of the methylcellulose of the water that weight/mass percentage composition is 98% and 2%.
Negative oxygen ion Buddha's warrior attendant the most according to claim 6 surpasses the preparation method of spar ecology ceramic tile, it is characterised in that: step
Suddenly in (2), ball milling 3-5 hour；Cross 140 mesh standard sieves.
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| CN108331281A (en) * | 2018-01-11 | 2018-07-27 | 广东百强陶瓷有限公司 | A kind of superbright anion glazed tile and its production technology |
| CN108595039A (en) * | 2018-07-12 | 2018-09-28 | 福建序源堂陶瓷文化有限公司 | A kind of ceramic mouse pad of sustainable releasing negative oxygen ion |
| CN108911788A (en) * | 2018-07-24 | 2018-11-30 | 信阳市上天梯非金属矿管理区非金属矿技术开发应用研究所 | With the function ceramics brick and preparation method thereof that can excite releasing negative oxygen ion surface layer |
| CN109437569A (en) * | 2018-12-14 | 2019-03-08 | 广东金意陶陶瓷集团有限公司 | Negative ion ceramic ceramic tile and preparation method thereof |
| CN110482860A (en) * | 2019-09-24 | 2019-11-22 | 福建省德化县紫嘉工艺有限公司 | A kind of ceramic ware for daily use easy to clean and preparation method thereof |
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| CN115572069A (en) * | 2022-11-08 | 2023-01-06 | 广东欧文莱陶瓷有限公司 | Easy-to-clean frosted mutton tallow glaze for rock plates and preparation method thereof |
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| CN109437569B (en) * | 2018-12-14 | 2021-08-31 | 广东金意陶陶瓷集团有限公司 | Negative ion ceramic tile and preparation method thereof |
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| CN115572069A (en) * | 2022-11-08 | 2023-01-06 | 广东欧文莱陶瓷有限公司 | Easy-to-clean frosted mutton tallow glaze for rock plates and preparation method thereof |
| CN115572069B (en) * | 2022-11-08 | 2023-04-25 | 广东欧文莱陶瓷有限公司 | Easily-cleaned frosted goat fat glaze for rock plates and preparation method thereof |
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Denomination of invention: Negative oxygen ion adamantine superlite ecological ceramic tile and its preparation method Effective date of registration: 20230129 Granted publication date: 20180828 Pledgee: Zibo Zichuan District sub branch of China Post Savings Bank Co.,Ltd. Pledgor: Shandong shiziwang New Material Technology Co.,Ltd. Registration number: Y2023980030872 |