CN110527567A - M100车用甲醇燃料性能改良剂及制备方法 - Google Patents

M100车用甲醇燃料性能改良剂及制备方法 Download PDF

Info

Publication number
CN110527567A
CN110527567A CN201910821087.1A CN201910821087A CN110527567A CN 110527567 A CN110527567 A CN 110527567A CN 201910821087 A CN201910821087 A CN 201910821087A CN 110527567 A CN110527567 A CN 110527567A
Authority
CN
China
Prior art keywords
methanol fuel
vehicles
methanol
performance improver
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910821087.1A
Other languages
English (en)
Inventor
熊易
任火仙
熊韶鑫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen Rongyichao Technology Co Ltd
Original Assignee
Shenzhen Rongyichao Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Rongyichao Technology Co Ltd filed Critical Shenzhen Rongyichao Technology Co Ltd
Priority to CN201910821087.1A priority Critical patent/CN110527567A/zh
Publication of CN110527567A publication Critical patent/CN110527567A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/14—Use of additives to fuels or fires for particular purposes for improving low temperature properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1608—Well defined compounds, e.g. hexane, benzene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00—Specifically adapted fuels
    • C10L2270/02—Specifically adapted fuels for internal combustion engines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

本发明公开一种M100车用甲醇燃料性能改良剂及其制备方法，该改良剂包括：异丙醇、甲基叔丁基醚、乙醇胺、环己醇、吐温80、油酸、甲基异丁基醚、异戊烷、石油醚(沸程60～90℃)。本发明将甲醇与性能改良剂经过混合、搅拌、静置生成M100车用甲醇燃料成品。M100车用甲醇燃料在不改变现行发动机结构的条件下使用，解决车用甲醇燃料直接在发动机使用出现的油品遇水分层、乳化，低温启动困难、高温气阻，腐蚀溶胀，动力下降、油耗增高等问题。

Description

M100车用甲醇燃料性能改良剂及制备方法
技术领域
本发明涉及甲醇燃料技术领域，特别涉及一种M100车用甲醇燃料性能改良剂及制备方法。
背景技术
我国是一个人口大国，工业和民用能源需求量巨大，同时，我国又是一个煤矿资源丰富且石油资源贫乏的国家，基本国情因素决定着我国经济高速发展，必然面临着经济增长和环境保护的双重压力。问题为能源和资源消耗大国，中国的资源环境矛盾日益突出。改变能源生产和消费方式，开发利用可再生能源燃料等可再生清洁能源资源对建立可持续的能源系统，促进国民经济发展和环境保护具有重大意义。近年来，随着国家对能源安全和环境保护的不断重视，一系列政策法规相继出台。
2009年12月国家标准《车用甲醇汽油(M85)》正式实施，为高比例车用甲醇汽油提供了标准依据。
甲醇可以用煤及天然气等作原料大规模生产的液态燃料，生产工艺成熟，储存使用安全可靠。车用甲醇汽油是将甲醇以掺混的方式添加在汽油里，制备成甲醇汽油进行掺烧，是最为简单的甲醇燃料使用方法，通常根据甲醇含量，将甲醇汽油分为M3～M85，其中M表示甲醇，数字表示甲醇的体积分数。
近年来，(M3～M85)甲醇汽油的研究应用已经取得了一定的成效，但基于甲醇的理化性质，高比例甲醇汽油直接在发动机中使用，仍会出现低温环境下冷启动困难、动力下降、腐蚀性等一系列问题。
发明内容
本发明针对上述的技术问题，提供一种M100车用甲醇燃料性能改良剂及制备方法，将甲醇与性能改良剂经过混合、搅拌、静置生成M100车用甲醇燃料成品。M100车用甲醇燃料在不改变现行发动机结构的条件下使用，解决车用甲醇燃料直接在发动机使用出现的油品遇水分层、乳化，低温启动困难、高温气阻，腐蚀溶胀，动力下降、油耗增高等问题。
为实现上述目的，本发明具体技术方案如下：
一种M100车用甲醇燃料性能改良剂，其包括质量百分数的以下组分为原料调配制成：
优选地，该改良剂与甲醇的体积比为：1∶(40～60)。
进一步地，该改良剂与甲醇的体积比为：1∶49。
本发明上述的M100车用甲醇燃料性能改良剂，是一种复合添加剂，采用下述方法制备得到：
将异丙醇、甲基叔丁基醚、乙醇胺混合升温回流反应180～240min，得到组分A；
将环己醇、吐温80、油酸混合反应90～120min，得到组分B；
将甲基叔丁基醚、异戊烷、石油醚与得到的组分A、组分B混合均匀得到性能改良剂。
其中，将甲基叔丁基醚、异戊烷、石油醚、组分A、组分B进行混合时，控制混合温度为10～20℃。
将本发明制备的性能改良剂加入甲醇中，在常温和常压条件下进行物理调和，即可调配得到M100车用甲醇燃料，且配制的M100车用甲醇燃料符合GB/T 23799-2009车用甲醇汽油(M85)规定的技术要求。
对比现有技术，本发明M100车用甲醇燃料性能改良剂具有以下优点：
(1)与甲醇互溶效果好，产品透明清亮，无杂质，-35℃条件下不分层；
(2)抗水性好，抗水比例达1％，稳定性好，保存期可达一年以上；
(3)台架试验表明，其冷启动、动力性、燃油经济性、环保性与95#汽油基本相当；
(4)铜片腐蚀试验表明，本发明M100车用甲醇燃料性能改良剂的腐蚀性较小。
具体实施方式
下列实施例仅用于对本发明进行详细说明，但应理解的是本发明的范围并不限于这些实施例。
实施例1：
在带有机械搅拌、温度计、加料漏斗、冷凝管的四口瓶中依次加入5g异丙醇、10g甲基叔丁基醚、4g乙醇胺，升温至80℃反应2小时后，降至室温，得到组分A19g。
将12g环己醇、12g吐温80、12g油酸加入四口瓶中，升温至回流，反应1.5小时，得到组分B 36g。
将15g甲基叔丁基醚、15g异戊烷、15g石油醚与上述组分A、组分B加入反应瓶中，控制温度在15℃，充分搅拌均匀后得到性能改良剂淡黄色液体100g，20℃密度0.7994g/cm3。
将20.0mL上述性能改良剂加入980.0mL甲醇(纯度99.9％)中，调配成1000mL的M100车用甲醇燃料。
实施例2：
按照实施例1组分比例，工业制备性能改良剂。取性能改良剂2.0L与甲醇98.0L调配成100L M100车用甲醇燃料，进行台架试验。
检测依据GB 18285-2005《点燃式发动机汽车排气污染物排放限值及测量方法(双怠速法及简易工况法)》、GB/T 12547-2009《汽车最低稳定车速试验方法》、GB/T 12543-2009《汽车加速性能试验方法》、GB/T 12544-2012《汽车最高车速试验方法》、GB/T12545.1-2008《乘用车燃料消耗量试验方法》等标准，试验用油为国标95#汽油和调配好的M100车用甲醇燃料，测试结果如下：
(1)、动力方面，M100车用甲醇燃料输出扭力比国标95#汽油低0.32％，底盘输出功率低0.16％；40～80Km/h加速距离增加0.4％，加速时间增加0.67％；从油耗上看，M100车用甲醇燃料比国标95#汽油平均高1.11％。
(2)、环保方面，经汽车稳态工况排气污染物测试，M100车用甲醇燃料与国标95#汽油比较，排气污染物CO平均下降94.3％，HC平均下降98.9％。
(3)、冷启动方面，-20℃环境下多次测试表明，国标95#汽油与M100车用甲醇燃料均可正常启用。
实施例3：
在50L反应釜中依次加入1.44kg异丙醇、2.88kg甲基叔丁基醚、1.15kg乙醇胺，升温至80℃反应2小时后，降至室温得到产品A。
将3.46kg环己醇、3.46kg吐温80、3.46kg油酸加入反应釜中，升温至回流温度反应1.5h，得到产品B。
将、4.32kg甲基叔丁基醚、4.32kg异戊烷、4.32kg石油醚以及上述得到的产品A、产品B一起加入反应釜中，控制反应温度10℃，充分搅拌得到淡黄色的性能改良剂液体产品28.81Kg，20℃密度0.7994g/cm3。
以30L性能改良剂与1470L甲醇(纯度99.9％)调配成M100车用甲醇燃料1500L，台架试验结果如下：
(1)、动力方面，M100车用甲醇燃料输出扭力比国标95#汽油低0.46％，底盘输出功率低0.17％；40～80Km/h加速距离增加0.42％，加速时间增加0.71％；从油耗上看，M100车用甲醇燃料比国标95#汽油平均高1.2％。
(2)、环保方面，经汽车稳态工况排气污染物测试，M100车用甲醇燃料与国标95#汽油比较，排气污染物CO平均下降92.6％，HC平均下降98.9％。
(3)、冷启动方面，-20℃环境下多次测试表明，国标95#汽油与M100车用甲醇燃料均可正常启用。
以上内容是结合具体的优选实施方式对本发明所作的进一步详细说明，不能认定本发明的具体实施只局限于这些说明。对于本发明所属技术领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干简单推演或替换，都应当视为属于本发明的保护范围。

Claims (5)

1.一种M100车用甲醇燃料性能改良剂，其特征在于，包括以下组分质量百分数为原料：
2.根据权利要求1所述的M100车用甲醇燃料性能改良剂，其特征在于，该改良剂与甲醇的体积比为：1∶(40～60)。
3.根据权利要求1所述的M100车用甲醇燃料性能改良剂，其特征在于，该改良剂与甲醇的体积比为：1∶49。
4.根据权利要求1-3任一项所述的M100车用甲醇燃料性能改良剂的制备方法，其特征在于，包括以下步骤：
(1)、将异丙醇、甲基叔丁基醚、乙醇胺混合升温回流反应180～240min，得到组分A；
(2)、将环己醇、吐温80、油酸混合反应90～120min，得到组分B；
(3)、将甲基叔丁基醚、异戊烷、石油醚与得到的组分A、组分B混合均匀得到性能改良剂。
5.根据权利要求4所述的制备方法，其特征在于，步骤(3)中，将甲基叔丁基醚、异戊烷、石油醚、组分A、组分B进行混合时，控制混合温度为10℃～20℃。
CN201910821087.1A 2019-08-30 2019-08-30 M100车用甲醇燃料性能改良剂及制备方法 Pending CN110527567A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910821087.1A CN110527567A (zh) 2019-08-30 2019-08-30 M100车用甲醇燃料性能改良剂及制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910821087.1A CN110527567A (zh) 2019-08-30 2019-08-30 M100车用甲醇燃料性能改良剂及制备方法

Publications (1)

Publication Number Publication Date
CN110527567A true CN110527567A (zh) 2019-12-03

Family

ID=68665931

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910821087.1A Pending CN110527567A (zh) 2019-08-30 2019-08-30 M100车用甲醇燃料性能改良剂及制备方法

Country Status (1)

Country Link
CN (1) CN110527567A (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113088349A (zh) * 2021-04-09 2021-07-09 重庆邑丰新能源有限公司 一种民用改性甲醇燃料及其制备方法
CN114032124A (zh) * 2021-07-30 2022-02-11 三亚星油藤科技服务有限公司 一种甲醇车用m100甲醇燃料母液添加剂及其制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060174538A1 (en) * 2005-02-07 2006-08-10 Mao-Sheng Lee Vehicle fuel composition
CN101724474A (zh) * 2008-10-14 2010-06-09 陈若歆 M15～m100络合甲醇汽油制造模式与气体常温液化掺烧技术
CN103805300A (zh) * 2014-01-21 2014-05-21 山西佳新能源化工实业有限公司 高比例车用甲醇燃料复合添加剂
CN104479764A (zh) * 2014-11-06 2015-04-01 金景达(北京)环保热力科技有限公司 一种非金属纳米量子点复合添加剂及其改性高效环保甲醇燃料
CN109337721A (zh) * 2018-11-26 2019-02-15 苑瀚文 一种含有变性甲醇的汽油及其制备方法
CN110157498A (zh) * 2019-04-19 2019-08-23 寇延华 一种车用epm45航醇燃料及制作方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060174538A1 (en) * 2005-02-07 2006-08-10 Mao-Sheng Lee Vehicle fuel composition
CN101724474A (zh) * 2008-10-14 2010-06-09 陈若歆 M15～m100络合甲醇汽油制造模式与气体常温液化掺烧技术
CN103805300A (zh) * 2014-01-21 2014-05-21 山西佳新能源化工实业有限公司 高比例车用甲醇燃料复合添加剂
CN104479764A (zh) * 2014-11-06 2015-04-01 金景达(北京)环保热力科技有限公司 一种非金属纳米量子点复合添加剂及其改性高效环保甲醇燃料
CN109337721A (zh) * 2018-11-26 2019-02-15 苑瀚文 一种含有变性甲醇的汽油及其制备方法
CN110157498A (zh) * 2019-04-19 2019-08-23 寇延华 一种车用epm45航醇燃料及制作方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113088349A (zh) * 2021-04-09 2021-07-09 重庆邑丰新能源有限公司 一种民用改性甲醇燃料及其制备方法
CN114032124A (zh) * 2021-07-30 2022-02-11 三亚星油藤科技服务有限公司 一种甲醇车用m100甲醇燃料母液添加剂及其制备方法

Similar Documents

Publication Publication Date Title
CN101235325B (zh) 一种甲醇柴油燃料及其制备方法
CN101935561B (zh) 一种甲醇柴油及其制备方法
CN104119968B (zh) 一种车用新型燃料
CN101220301A (zh) 一种甲醇汽油燃料及其制备方法
CN102517101B (zh) 一种车用甲醇柴油燃料及其制备方法
CN110527567A (zh) M100车用甲醇燃料性能改良剂及制备方法
CN101144041A (zh) 一种车用汽油抗爆剂混合物
CN101285011B (zh) 一种含水甲醇汽油及其制备方法
CN101544918A (zh) M15-m85车用醇醚燃料及其配制方法
CN102533351B (zh) 一种醇醚燃料
CN101429461A (zh) 车用复合甲醇汽油
CN103305292B (zh) 一种醇醚燃料及其制备方法
CN104498112B (zh) M85甲醇汽油复合添加剂
CN101215483A (zh) 节能减排型甲醇柴油
CN104263427A (zh) 一种车用醇醚汽油
CN104946319A (zh) 高清洁新型车用甲醇汽油m85
CN102559294A (zh) 一种醇醚柴油
CN101302449A (zh) 高清洁大比例甲醇汽油
CN101921632A (zh) 采用天然纳米二氧化硅粉改性甲醇汽油
CN103695045B (zh) 一种醇醚燃料及其制备方法
CN100357406C (zh) 合成车用燃料及其制备方法
CN103525481B (zh) 醇基生物柴油
CN102260546B (zh) 生物甲醇大比例替代柴油及其配制方法
CN107858180B (zh) 一种生物质基γ戊内酯-汽油调和燃料及其制备方法
CN114921270B (zh) 一种增效的乙醇汽油及其制备方法和应用

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20191203

RJ01 Rejection of invention patent application after publication