CN110520104A - Cosmetic cosmetic composition with improved oil absorption capacity, smear and mouldability with and preparation method thereof - Google Patents
Cosmetic cosmetic composition with improved oil absorption capacity, smear and mouldability with and preparation method thereof Download PDFInfo
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- CN110520104A CN110520104A CN201780083217.5A CN201780083217A CN110520104A CN 110520104 A CN110520104 A CN 110520104A CN 201780083217 A CN201780083217 A CN 201780083217A CN 110520104 A CN110520104 A CN 110520104A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/022—Powders; Compacted Powders
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/025—Explicitly spheroidal or spherical shape
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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Abstract
The present invention relates to a kind of cosmetic cosmetic composition and preparation method thereof, which includes globular powder and nonvolatile oil, and is prepared with certain hardness, so that oil absorption capacity is improved, smear and mouldability.Cosmetic cosmetic composition of the invention is by the way that the globular powder with excellent sebum oil absorption capacity and nonvolatile oil are mixed into mud, then by compressing and removing part oil, to be prepared as the hardness for having certain, to improve mouldability, it is few with winged powder, skin can be equably applied to and improve the persistent effect of dressing without card line phenomenon, and blur effect is excellent.
Description
Technical field
This application claims in submission on November 11st, 2016 Koran Office, application No. is No. 10-2016-0150209, and
In submission on November 7th, 2017 Koran Office, application No. is the preferential of No. 10-2017-0147055 South Korea patent application
Power, entire contents are hereby incorporated by reference in the application.
The present invention relates to a kind of cosmetic cosmetic composition and preparation method thereof, which includes
Globular powder and nonvolatile oil, and prepared with certain degree of hardness, to improve oil absorption capacity, smear and mouldability.
Background technique
On the market, compressing powder forms the cosmetic cosmetic product series of such as pressed cake or dual-purpose muffin.No
It is same as granular powder, compressing powder needs in the state of forming with stability.That is, in order to avoid because of external impact
Caused fragmentation, needs are designed to be able to bear certain physical impact under compression.In addition, and granular powder
Difference also needs to be designed to be picked amount that is certain and being suitable for smearing with cosmetic applicators such as common powder puffs, and utilizes
When powder puff pats compressing powder, the phenomenon that not having winged powder.
The powder used for cosmetic as powder contents is usually mixed in the common compressing powder composition being designed in this way
End and oily adhesive, and these ingredients are crushed and are compressed so that it is shaped.
Oily adhesive is mainly used for enhancing the coherency of powder, helps to shape in compressing powder, prevent by outside
It impacts and is crushed, and prevent from flying powder when taking compressing powder with cosmetic applicators.But although it can be subtracted using oily adhesive
Fly powder less, but heavy feeling can be generated when applied to the skin.
The wet type method of forming is that one kind can reduce the method because using disadvantage caused by oil binder as described above.In
In the wet type method of forming, the adhesive of oil-containing is mixed in powder contents mud is made, by the Contents Fill of mud in appearance
After in device, by squeezing and aspirating extract oil to prepare compressing powder.Hardness of dosage form etc. can change according to the extruding,
The function of composition can change according to the hardness.In addition, this kind of wet type method of forming is by making compared with dry formed method
Use oily adhesive as solvent, so as to uniform mixed-powder particle.
In addition, the mouldability of common compressing powder is different according to the type of powder, and applied also according to powder
The layer type of agent and it is different.In general, can be used comprising the globular powder such as nylon powder, PMMA powder and silica to mention
The use feeling of high powder, and when being applied to skin, globular powder has excellent oil absorption capacity and ductility, to be suitble to
The material to apply some make up as makeup.But when globular powder is excessively used, there is the shortcomings that being difficult to compression forming.
Therefore, there is an urgent need to study the compressed dosage forms that can be improved the globular powder of mouldability and smear.
[related fields bibliography]
[patent document]
(patent document 1) Korean Patent Publication No. 2013-055333 " composition and preparation method thereof that applies some make up of refining the make-up "；
(patent document 2) Korean Patent Publication No. 2015-0023306 is " non-comprising non-volatile alkymer, wax and high-content
The cosmetics solid composite of volatility phenylating silicone oil ".
Summary of the invention
Technical problem
To solve the above-mentioned problems, the present inventor, which confirms, works as containing globular powder and nonvolatile oil, and with
When certain hardness prepares cosmetic cosmetic composition, oil absorption capacity, smear and mouldability can be improved, so as to complete
The present invention.
Therefore, the purpose of the present invention is to provide the cosmetics with improved oil absorption capacity, smear and mouldability
Cosmetic compositions, with and preparation method thereof
Technical solution
To achieve the goals above, the present invention provides a kind of cosmetic cosmetic composition, and it includes spherical powders and non-
Ethereal oil, and be 5-12 based on hardness measured by JIS K 6031.
Wherein, the globular powder may include selected from hexamethylene diisocyanate/trihydroxy methyl caprolactone cross-linked polymeric
Object, vinyldimethicone/polymethyl siloxane silsesquioxane cross-linked polymer (VINYL DIMETHICONE/
METHICONE SILSESQUIOXANE CROSSPOLYMER), silica, polymethyl methacrylate, polyurethane, poly- first
One of base silsesquioxane and nylon or many kinds of substance.
Wherein, the globular powder can for by selected from silica, polymethyl methacrylate, silsesquioxane resin and
The globular powder of one of nylon or many kinds of substance through being combined.
Wherein, the composite spherical powder may include six through being combined by silica and polymethyl methacrylate
Methylene diisocyanate/trihydroxy methyl caprolactone cross-linked polymer globular powder.
Wherein, the cosmetic composition can further include vinyldimethicone/polymethyl siloxane silicon
Sesquioxyalkane cross-linked polymer globular powder.
Wherein, the average grain diameter (D50) of the composite spherical powder can be 1-10 μm.
Wherein, the nonvolatile oil can include dimethyl silicone polymer, SILIBIONE OIL 70047 V20 and three silicon oxygen containing being selected from
Alkane/dimethyl silicone polymer silicone oil；Include cetanol ethylhexoate, isopropyl palmitate, isopropyl myristate, alkyl
The Esters oil of benzoic ether, succinic acid diethoxy ethyl ester and pentaerythritol tetraoctyl stearate；And include mineral oil, different ten
Six alkane, Permethyl 99A, hendecane, saualane, Nexbase 2004, alpha-olefin low polymers and Parleam hydrocarbon-type oil in
One or more substances.
Wherein, globular powder of the cosmetic composition containing 50-80 weight % and 20-50 weight %'s is non-volatile
Property oil.
Wherein, the cosmetic cosmetic composition can be for selected from adornment foremilk (makeup primer), foundation emulsion
(foundation), sun screen (makeup base), dual-purpose muffin (two-way cake), pressed cake (pact), powder,
The dosage form of brow powder, and eye shadow.
In addition, the present invention provides a kind of preparation method of cosmetic cosmetic composition characterized by comprising
1) globular powder and nonvolatile oil are mixed；And
2) said mixture compression forming is made by the pressure of 25-150kgf, to remove part nonvolatile oil, with preparation
The muffin dosage form for being 5-12 based on hardness measured by JIS K 6031.
The effect of invention
Cosmetic cosmetic composition of the invention is by the way that globular powder and nonvolatile oil are mixed into mud, so
Afterwards by compressing and removing part oil, with certain hardness, to improve mouldability, and have that fly powder few, it can be with
It is equably applied to skin and improves the persistent effect of dressing without card line phenomenon, and blur effect is excellent.
Detailed description of the invention
Fig. 1 shows the photo for comparing the card powder phenomenon of the composition of (a) embodiment 1 and (b) comparative example 3.
Fig. 2 shows the photos of the mouldability for the composition for comparing (a) embodiment 1 and (b) comparative example 2.
Fig. 3 shows the photo of the smear of the composition of embodiment 1.
Fig. 4 shows the photo of the smear of the composition of comparative example 1.
Fig. 5 shows the photo of the smear of the composition of comparative example 3.
Specific embodiment
Hereinafter, will be carried out to the present invention detailed to allow those skilled in the art more easily to implement the present invention
Explanation.However, the present invention can be embodied in many different forms, and do not limited by embodiment set forth herein.
The present invention provides a kind of cosmetic cosmetic composition, containing globular powder and nonvolatile oil, and is based on JIS
Hardness measured by K 6031 is 5~12.The hardness is preferably 8-10.
When preparing the composition, the hardness can be determined during compressing and removing part oil, and hardness can
To influence mouldability and smear.It, can be due to remaining oil mass mistake if the hardness of composition is excessively lower than above range
Greatly, lead to that excessive composition, and the hardness of composition may be speckled on spreader when use finishes (Pay off)
It may be gradually decreased with being used continuously.In addition, if the hardness of composition is apparently higher than above range, then dosage form can
It can be easily broken or crack, and when in use, in fact it could happen that the shortcomings that can not almost being picked with spreader.
In addition, the hardometer of JIS K 6031A type can be used based on hardness measured by JIS K 6031 to be surveyed
Amount.
The globular powder is that grain shape is spherical powder, and is comprised in cosmetic cosmetic composition,
To assign smooth and frivolous sense of touch.The globular powder can be such that light is diffused to all directions, and due to its shape and
There is excellent ductility on the skin.In addition, compared with flakelike powder also there are the hiding skins such as pore and acne trace to lack
Sunken effect.Globular powder has the effect of oil suction, and can be applied to skin frivolously, and is not easy to agglomerate, so that card powder is existing
As less.The cosmetic cosmetic composition comprising globular powder has excellent adhesive force and oil absorption capacity to skin as a result,.
However, when cosmetic cosmetic composition contains a large amount of globular powder, due to the hole and repulsive force between powder particle
And have the shortcomings that be difficult to form.
The present inventor is to containing more globular powder and can realizing that the makeup of portable compressed configuration applies some make up
Composition is studied, and result confirmation, which is worked as, contains globular powder and nonvolatile oil, and prepares composition to fix hardness
When, compression forming ability can be improved.
In the present invention, workable globular powder is not particularly limited, and the nothing in type commonly used in the art can be used
Machine particle, organic granular and organic-inorganic compound particle.
The globular powder may include selected from hexamethylene diisocyanate/trihydroxy methyl caprolactone cross-linked polymer, second
Alkenyl dimethyl silicone polymer/polymethyl siloxane silsesquioxane cross-linked polymer, silica, poly-methyl methacrylate
One of ester, polyurethane, poly methyl silsesquioxane and nylon or many kinds of substance.
In addition, the globular powder can for by selected from silica, polymethyl methacrylate, silsesquioxane resin and
The globular powder of one of nylon or many kinds of substance through being combined.
" compound " powder referred to by mixing two or more, by combining respective feature scarce to reduce
Point plays mixing (hybrid) technology of advantage.
The composite spherical powder is preferably EPU-2X on sale on the market (hexamethylene diisocyanate/tri- hydroxyl first
Base caprolactone cross-linked polymer & polymethyl methacrylate, silica ((HDI/Trimethylol Hexyllactone
Crosspolymer&Polymethyl Methacrylate, silica), SUNJIN BEAUTY SCIENCE company), it is
Hexamethylene diisocyanate/trihydroxy methyl caprolactone crosslinking by silica and polymethyl methacrylate through being combined
Polymer drops sprills.The globular powder is easy to press due to having the K value that can determine pliability higher, but due to making
Recovery rate (Recovery rate is extruded rear restorable property) for elasticity indexes is lower instead and is easy to compress, from
And there is excellent mouldability.
In addition, the cosmetic cosmetic composition can be further containing as KSP-101, (SHIN-ETSU HANTOTAI (SHINETSU) is public
Department) sell vinyldimethicone/polymethyl siloxane silsesquioxane cross-linked polymer globular powder.
Wherein, the composite spherical powder is containing 70-99 weight % by silica and polymethyl methacrylate
Hexamethylene diisocyanate through being combined/trihydroxy methyl caprolactone cross-linked polymer globular powder and 1-30 weight
Measure vinyldimethicone/polymethyl siloxane silsesquioxane cross-linked polymer globular powder of %.
The average grain diameter (D50) of the composite spherical powder can be 1-10 μm, preferably 3-7 μm.When globular powder
When average grain diameter is more than 10 μm, then it is difficult to carry out compression forming, when being dropped, it may appear that it is steady that dosage form breaks etc. can influence dosage form
Qualitative problem, it is therefore desirable to which average grain diameter is appropriately controlled in above range.
Cosmetic cosmetic composition of the invention can contain nonvolatile oil, to improve the knot between globular powder particle
With joint efforts.The nonvolatile oil can include dimethyl silicone polymer, SILIBIONE OIL 70047 V20 and trisiloxanes/poly- diformazan containing being selected from
The silicone oil of radical siloxane；Comprising cetanol ethylhexoate, isopropyl palmitate, isopropyl myristate, alkyl benzoate,
The Esters oil of succinic acid diethoxy ethyl ester and pentaerythritol tetraoctyl stearate；And include mineral oil, isohexadecane, different ten
Dioxane, hendecane, saualane, Nexbase 2004, alpha-olefin low polymers and Parleam one of hydrocarbon-type oil or more
Kind substance, the oil are preferably silicone oil, more preferably dimethyl silicone polymer.
Wherein, globular powder of the cosmetic composition containing 50-80 weight % and 20-50 weight %'s is non-volatile
Property oil.When the amount of globular powder is greater than or the amount of nonvolatile oil is less than above range, then it will appear winged powder phenomenon, and form
Property be deteriorated, therefore should suitably adjust use.
It is highly preferred that the present invention provides a kind of cosmetic cosmetic composition, which is characterized in that the makeup applies some make up
Composition includes two isocyanide of hexa-methylene by silica and polymethyl methacrylate through being combined of 50-80 weight %
Acid esters/trihydroxy methyl caprolactone cross-linked polymer globular powder；With the silica of 20-50 weight %, and be based on JIS K
Hardness measured by 6031 is 5-12.The cosmetic cosmetic composition may further include vinylpolydimethyl silicon oxygen
Alkane/polymethyl siloxane silsesquioxane cross-linked polymer globular powder.
Wherein, the cosmetic cosmetic composition can be for selected from adornment foremilk, foundation emulsion, sun screen, dual-purpose muffin, compacting
Dosage form in muffin, powder, brow powder, and eye shadow.The dosage form is preferably adornment foremilk.
The present invention provides a kind of preparation method of cosmetic cosmetic composition characterized by comprising
1) globular powder and nonvolatile oil are mixed；And
2) said mixture compression forming is made by the pressure of 25-150kgf, to remove part nonvolatile oil, with preparation
The muffin dosage form for being 5-12 based on hardness measured by JIS K 6031.
The preparation method is that wet process, the wet type state refers to, because being more than water suction/oil suction limiting value of powder
And when powder being made to contain significantly greater than its water suction/oil absorption capacity oil, mobility state possessed by powder.It is spherical by mixing
Powder and nonvolatile oil, and oil is added until the mixture becomes mud, to prepare the powder of the wet type state.
Under wet type state, nonvolatile oil can complete cladding powder particle, therefore moulding moulded have compared to common
More soft and smooth use feeling.By it is a certain amount of in wet type state and at the Contents Fill of mud in disk, by squeezing and aspirating
After extracting part oil, compression forming.
Forming ability by muffin type composition prepared by common dry process is bad, and is applied to after dry
When skin, the limitation with the decline of its adhesive force.In addition, if a small amount of oil is mixed in wherein with powder, composition at
Type is not only bad, but also is difficult to permeate oil well between the particle of powder, to be difficult to that oil is made to be completely coated with powder.
In order to overcome these limitations, the preparation method is that preparing composition by using wet process, also
It is to say, after enough oil is mixed with powder, extra oil than necessary is finally removed, to make combination of the invention
Object can obtain excellent mouldability etc..
In the preparation method, the globular powder may include selected from hexamethylene diisocyanate/trihydroxy methyl oneself
Lactone cross polymer, vinyldimethicone/polymethyl siloxane silsesquioxane cross-linked polymer, titanium dioxide
One of silicon, polymethyl methacrylate, polyurethane, poly methyl silsesquioxane and nylon or a variety of nothings.
In addition, the globular powder can be for by being selected from silica, poly-methyl methacrylate in the preparation method
The globular powder of ester, one of silsesquioxane resin and nylon or many kinds of substance through being combined.
In the preparation method, the composite spherical powder preferably includes EPU-2X on sale on the market (six methylenes
Group diisocyanate/trihydroxy methyl caprolactone cross-linked polymer & polymethyl methacrylate, silica ((HDI/
Trimethylol Hexyllactone Crosspolymer&Polymethyl Methacrylate, silica), SUNJIN
BEAUTY SCIENCE company), it is different for the hexa-methylene two by silica and polymethyl methacrylate through being combined
Cyanate/trihydroxy methyl caprolactone cross-linked polymer globular powder.
In addition, the cosmetic cosmetic composition can be further containing as KSP-101 in the preparation method
Vinyldimethicone/polymethyl siloxane silsesquioxane cross-linked polymeric that (SHIN-ETSU HANTOTAI (SHINETSU) company) sells
Object globular powder.
In the preparation method, the nonvolatile oil can include dimethyl silicone polymer, the poly- silicon of ring first containing being selected from
Oxygen alkane and trisiloxanes/dimethyl silicone polymer silicone oil；Include cetanol ethylhexoate, isopropyl palmitate, nutmeg
Isopropyl propionate, alkyl benzoate, succinic acid diethoxy ethyl ester and pentaerythritol tetraoctyl stearate Esters oil；And packet
Containing mineral oil, isohexadecane, Permethyl 99A, hendecane, saualane, Nexbase 2004, alpha-olefin low polymers and the poly- isobutyl of hydrogenation
One of hydrocarbon-type oil of alkene or many kinds of substance.The oil is preferably dimethyl silicone polymer.
In the preparation method, globular powder of the cosmetic cosmetic composition containing 50-80 weight % and
The nonvolatile oil of 20-50 weight %.If the amount of globular powder is greater than the amount of above range or nonvolatile oil less than above-mentioned
Range is then likely to occur winged powder phenomenon, and mouldability is deteriorated, therefore should suitably adjust use.
In addition, the present invention provides a kind of cosmetic cosmetic composition, which is characterized in that pass through above-mentioned preparation method system
It is standby.
In addition, the cosmetic cosmetic composition can also contain lubricant component, moisturizer, softening agent, interfacial activity
Agent, organic and inorganic pigment, organic dust, ultraviolet absorbing agent, preservative, thickener, fungicide, antioxidant, plant mention
Take one of object, pH adjusting agent, alcohol, pigment, fragrance, blood circulation accelerant, cold feeling agent, antiperspirant or a variety of.
Cosmetic cosmetic composition of the invention be by the way that composite spherical powder and nonvolatile oil are mixed into mud,
Then it compresses and removes part oil to make it have certain hardness, so that mouldability is improved, and few with powder is flown, it can be equably
Being applied in skin and wrinkle of skin does not have card powder phenomenon, and improves the persistent effect of dressing, and blur effect is excellent.
Hereinafter, by preferred embodiment below to help to understand the present invention, but in those skilled in the art should understand that
That following embodiment is only example of the invention, can be carry out various modifications within the scope of scope of the invention and technical idea and
Variation, also, these modifications and variations belong in attached claim scope.
The preparation of<embodiment 1-2>cosmetic cosmetic composition
By the cosmetic cosmetic composition of the formula preparation Examples 1 and 2 of following table 1.
1) after globular powder being mixed 2 minutes by using Henschel mixer (Henschel mixer), crushing and mistake
Filter.
2) nonvolatile oil is sprayed in a mist form on above-mentioned mixture 1), and by using universal mixer
Mixing 5-10 minutes.
3) a certain amount of above-mentioned mixture 2) is placed on disk, then carries out compression forming and removes part oil, with system
Standby cosmetic cosmetic composition.Following table 1 shows the ingredient and condition of formula.
[table 1]
The preparation of<comparative example 1~3>cosmetic cosmetic composition
By the formula of following table 2, by with the embodiment 1,2 identical methods, prepare the cosmetic of comparative example 1-3
Cosmetic compositions.In particular, the composition prepared when comparative example 3 by conventional dry process.
[table 2]
<EXPERIMENTAL EXAMPLE 1>hardness measurement
After being formed respectively to the cosmetic cosmetic composition of Examples 1 and 2 and comparative example 1-3 in disk, base
Hardness is measured in JIS K 6031.By in aforementioned manners, measuring its hardness at 10 randomly selected points, and calculate average
Value, measurement result are shown in the following table 3.
[table 3]
| Difference | Embodiment 1 | Embodiment 2 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Hardness | 10 | 8 | It is unable to measure | 15 | It is unable to measure |
The sensory evaluation of<EXPERIMENTAL EXAMPLE 2>cosmetic composition used for cosmetic
Women of 30 ages at 20-40 years old is selected, them is allowed to actually use the embodiment 1,2 being prepared by a conventional method
With the cosmetic cosmetic composition of comparative example 1-3, then product effect is compared.Test item be oil absorption capacity, at
Type flies that few powder, uniform smear, card powder phenomenon be few, dressing persistence, blur effect.After each project to be evaluated, 0 is provided
~15 score simultaneously calculates average mark.For the correctness for ensuring data, 5 experiments, result such as the following table 4 are repeated respectively
It is shown.When average mark is less than 4.0, it is labeled as "×", when for 4.0~8.0, is labeled as " △ ", when for 8.1~12.0,
Labeled as "○", when more than 12.0, it is labeled as " ◎ ".
In addition, Fig. 1 shows the photo of the winged powder phenomenon of the composition of comparative example 1 and comparative example 3, Fig. 2 shows ratios
Compared with the photo of embodiment 1 and the mouldability of the composition of comparative example 2, Fig. 3-5 shows embodiment 1, comparative example 1 and comparative example 3
Composition smear photo.
[table 4]
| Project | Embodiment 1 | Embodiment 2 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Oil absorption | ◎ | ◎ | △ | ○ | ○ |
| Mouldability | ◎ | ◎ | × | × | × |
| It is few to fly powder | ◎ | ◎ | ○ | △ | × |
| Uniform smear | ◎ | ◎ | × | △ | × |
| Card powder phenomenon is few | ○ | ◎ | × | ○ | × |
| Dressing persistence | ◎ | ◎ | △ | ○ | △ |
| Blur effect | ○ | ◎ | ◎ | ○ | △ |
As shown in the above table 4, it can be seen that compared to comparative example 1-3, the oil absorption capacity of the composition of Examples 1 and 2,
Mouldability, to fly the overall effects such as few few powder, uniform smear, card powder phenomenon, dressing persistence and blur effect more excellent, especially
It, can determine that the overall effect of the different comparative example 2 of hardness is bad.In addition, as illustrated in fig. 1 and 2, it may be determined that when coating is implemented
When the composition of example 1, card powder phenomenon is few, as shown in Fig. 2, compared with the composition of comparative example 2, the composition of embodiment 1
Mouldability is more excellent, as shown in Fig. 3 to 5, it has been confirmed that compared with the composition of comparative example 1 and 3, the composition of embodiment 1
It can smear more smooth and uniform.
Claims (10)
1. a kind of cosmetic cosmetic composition, which is characterized in that include globular powder and nonvolatile oil, and be based on JIS K
Hardness measured by 6031 is 5-12.
2. cosmetic cosmetic composition according to claim 1, which is characterized in that the globular powder includes to be selected from six
Methylene diisocyanate/trihydroxy methyl caprolactone cross-linked polymer, vinyldimethicone/polymethyl siloxane silicon
In sesquioxyalkane cross-linked polymer, silica, polymethyl methacrylate, polyurethane, poly methyl silsesquioxane and nylon
It is one or more.
3. cosmetic cosmetic composition according to claim 1, which is characterized in that the globular powder is by being selected from two
The ball of one of silica, polymethyl methacrylate, silsesquioxane resin and nylon or many kinds of substance through being combined
Sprills.
4. cosmetic cosmetic composition according to claim 3, which is characterized in that the composite spherical powder include by
The hexamethylene diisocyanate of silica and polymethyl methacrylate through being combined/trihydroxy methyl caprolactone crosslinking is poly-
Close object globular powder.
5. cosmetic cosmetic composition according to claim 3, which is characterized in that the cosmetic cosmetic composition
Further include vinyldimethicone/polymethyl siloxane silsesquioxane cross-linked polymer globular powder.
6. cosmetic cosmetic composition according to claim 3, which is characterized in that the composite spherical powder is averaged
Partial size (D50) is 1-10 μm.
7. cosmetic cosmetic composition according to claim 1, which is characterized in that the nonvolatile oil, which contains, to be selected from
Include dimethyl silicone polymer, SILIBIONE OIL 70047 V20 and trisiloxanes/dimethyl silicone polymer silicone oil；Include cetanol ethyl
Capronate, isopropyl palmitate, isopropyl myristate, alkyl benzoate, succinic acid diethoxy ethyl ester and pentaerythrite
The Esters oil of pentaerythritol tetraisostearate；And include mineral oil, isohexadecane, Permethyl 99A, hendecane, saualane, the hydrogenation poly- last of the ten Heavenly stems
One of hydrocarbon-type oil of alkene, alpha-olefin low polymers and Parleam or many kinds of substance.
8. cosmetic cosmetic composition according to claim 1, which is characterized in that the cosmetic composition contains
The globular powder of 50-80 weight % and the nonvolatile oil of 20-50 weight %.
9. cosmetic cosmetic composition according to claim 1, which is characterized in that the cosmetic cosmetic composition
For the dosage form in adornment foremilk, foundation emulsion, sun screen, dual-purpose muffin, pressed cake, powder, brow powder, and eye shadow.
10. a kind of preparation method of cosmetic cosmetic composition characterized by comprising
1) globular powder and nonvolatile oil are mixed；And
2) mixture compression forming is made by the pressure of 25-150kgf, to remove part nonvolatile oil, is based on preparation
Hardness measured by JIS K 6031 is the muffin dosage form of 5-12.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20160150209 | 2016-11-11 | ||
| KR10-2016-0150209 | 2016-11-11 | ||
| KR10-2017-0147055 | 2017-11-07 | ||
| KR1020170147055A KR102336132B1 (en) | 2016-11-11 | 2017-11-07 | Makeup cosmetic composition having improved absorbing abilities, coating properties and formability, and method for preparing the same |
| PCT/KR2017/012556 WO2018088779A1 (en) | 2016-11-11 | 2017-11-08 | Makeup cosmetic composition having improved oil absorption capacity, spreadability and compactibility, and method for preparing same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110520104A true CN110520104A (en) | 2019-11-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201780083217.5A Pending CN110520104A (en) | 2016-11-11 | 2017-11-08 | Cosmetic cosmetic composition with improved oil absorption capacity, smear and mouldability with and preparation method thereof |
Country Status (2)
| Country | Link |
|---|---|
| KR (1) | KR102336132B1 (en) |
| CN (1) | CN110520104A (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| USD947844S1 (en) * | 2018-11-16 | 2022-04-05 | Samsung Electronics Co., Ltd. | Foldable display |
| KR102552785B1 (en) | 2018-12-14 | 2023-07-10 | (주)아모레퍼시픽 | Cosmetic composition of powder form suitable for covering the skin pores |
| CN115887298A (en) * | 2021-08-20 | 2023-04-04 | 苏州安特化妆品股份有限公司 | Transparent soft mist pressed powder and preparation process thereof |
| KR20230107008A (en) | 2022-01-07 | 2023-07-14 | (주)아모레퍼시픽 | Powder composition for removing oil from hair |
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| Publication number | Publication date |
|---|---|
| KR20180053232A (en) | 2018-05-21 |
| KR102336132B1 (en) | 2021-12-07 |
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