TWI753967B - Makeup cosmetic composition having improved sebum absorbing abilities, coating properties and formability, and method for preparing the same - Google Patents
Makeup cosmetic composition having improved sebum absorbing abilities, coating properties and formability, and method for preparing the same Download PDFInfo
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- TWI753967B TWI753967B TW106138836A TW106138836A TWI753967B TW I753967 B TWI753967 B TW I753967B TW 106138836 A TW106138836 A TW 106138836A TW 106138836 A TW106138836 A TW 106138836A TW I753967 B TWI753967 B TW I753967B
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- 239000000203 mixture Substances 0.000 title claims abstract description 85
- 239000002537 cosmetic Substances 0.000 title claims abstract description 64
- 238000000034 method Methods 0.000 title claims abstract description 17
- 239000011248 coating agent Substances 0.000 title abstract description 3
- 210000002374 sebum Anatomy 0.000 title abstract 3
- 238000000576 coating method Methods 0.000 title abstract 2
- 239000000843 powder Substances 0.000 claims abstract description 148
- 239000003921 oil Substances 0.000 claims abstract description 35
- 239000000346 nonvolatile oil Substances 0.000 claims abstract description 32
- 238000002156 mixing Methods 0.000 claims abstract description 10
- -1 hexyl lactone Chemical class 0.000 claims description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 229920006037 cross link polymer Polymers 0.000 claims description 20
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 20
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 20
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 18
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 17
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 16
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 13
- 239000002552 dosage form Substances 0.000 claims description 11
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 9
- BANXPJUEBPWEOT-UHFFFAOYSA-N 2-methyl-Pentadecane Chemical compound CCCCCCCCCCCCCC(C)C BANXPJUEBPWEOT-UHFFFAOYSA-N 0.000 claims description 8
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 claims description 8
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 claims description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 8
- SGVYKUFIHHTIFL-UHFFFAOYSA-N 2-methylnonane Chemical compound CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 claims description 6
- 229920002545 silicone oil Polymers 0.000 claims description 6
- 238000000748 compression moulding Methods 0.000 claims description 5
- 229940043268 2,2,4,4,6,8,8-heptamethylnonane Drugs 0.000 claims description 4
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims description 4
- LPGFSDGXTDNTCB-UHFFFAOYSA-N [3-(16-methylheptadecanoyloxy)-2,2-bis(16-methylheptadecanoyloxymethyl)propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCC(C)C)(COC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C LPGFSDGXTDNTCB-UHFFFAOYSA-N 0.000 claims description 4
- SWQUTKGVXGTROS-UHFFFAOYSA-N bis(2-ethoxyethyl) butanedioate Chemical compound CCOCCOC(=O)CCC(=O)OCCOCC SWQUTKGVXGTROS-UHFFFAOYSA-N 0.000 claims description 4
- 229940086555 cyclomethicone Drugs 0.000 claims description 4
- 229940119676 diethoxyethyl succinate Drugs 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 229920006007 hydrogenated polyisobutylene Polymers 0.000 claims description 4
- KUVMKLCGXIYSNH-UHFFFAOYSA-N isopentadecane Natural products CCCCCCCCCCCCC(C)C KUVMKLCGXIYSNH-UHFFFAOYSA-N 0.000 claims description 4
- 239000002480 mineral oil Substances 0.000 claims description 4
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 claims description 4
- 229940032094 squalane Drugs 0.000 claims description 4
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004711 α-olefin Substances 0.000 claims description 4
- 210000004709 eyebrow Anatomy 0.000 claims description 3
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 claims description 3
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 239000010696 ester oil Substances 0.000 claims description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 2
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 13
- 238000010521 absorption reaction Methods 0.000 abstract description 8
- 239000002002 slurry Substances 0.000 abstract description 7
- 230000037303 wrinkles Effects 0.000 abstract description 3
- 238000010410 dusting Methods 0.000 abstract 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 16
- 238000002360 preparation method Methods 0.000 description 16
- 239000004677 Nylon Substances 0.000 description 7
- 229920001778 nylon Polymers 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 6
- 238000013329 compounding Methods 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 238000005282 brightening Methods 0.000 description 4
- DLAHAXOYRFRPFQ-UHFFFAOYSA-N dodecyl benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1 DLAHAXOYRFRPFQ-UHFFFAOYSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229920003217 poly(methylsilsesquioxane) Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- ZONJATNKKGGVSU-UHFFFAOYSA-M 14-methylpentadecanoate Chemical compound CC(C)CCCCCCCCCCCCC([O-])=O ZONJATNKKGGVSU-UHFFFAOYSA-M 0.000 description 1
- SAPGBCWOQLHKKZ-UHFFFAOYSA-N 6-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCOC(=O)C(C)=C SAPGBCWOQLHKKZ-UHFFFAOYSA-N 0.000 description 1
- 208000002874 Acne Vulgaris Diseases 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 206010000496 acne Diseases 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- DCAYPVUWAIABOU-UHFFFAOYSA-N alpha-n-hexadecene Natural products CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011246 composite particle Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000007542 hardness measurement Methods 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- BVHBZCZOVYDVIE-UHFFFAOYSA-N isocyanic acid;2-methylprop-2-enoic acid Chemical compound N=C=O.CC(=C)C(O)=O BVHBZCZOVYDVIE-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229940042472 mineral oil Drugs 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical class CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/022—Powders; Compacted Powders
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/025—Explicitly spheroidal or spherical shape
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
Description
本發明是有關於一種包括球狀粉末及非揮發性油而以固定硬度製備,藉此吸油能力、塗抹性及成形性提高的彩妝化妝品組成物及其製備方法。 The present invention relates to a color cosmetic cosmetic composition comprising spherical powder and non-volatile oil and prepared with fixed hardness, thereby improving oil absorption capacity, spreadability and formability, and a preparation method thereof.
壓縮粉末於市場上形成如粉餅或兩用粉餅等的彩妝化妝品製品系列。不同於粉狀粉末,壓縮粉末在成形狀態下需要具有穩定性。即,為了避免因外部衝擊所引起的碎裂,將其設計為在壓縮狀態能承受大於固定物理衝擊的力。並且,不同於粉狀粉末,通常會以粉撲等化妝工具沾取壓縮粉末,因此應將壓縮粉末設計為使得粉撲等化妝工具能沾取到固定且適於塗抹的壓縮粉末量,且應將壓縮粉末設計為利用粉撲拍打壓縮粉末時,粉末不會有飛粉現象。 Compressed powders are marketed to form a range of cosmetic products such as pressed powders or dual-purpose powders. Unlike powdered powders, compressed powders need to be stable in the shaped state. That is, in order to avoid fragmentation due to external impact, it is designed to withstand a force greater than a fixed physical impact in a compressed state. Also, unlike powdered powders, compressed powders are usually dipped in cosmetic tools such as puffs. Therefore, compressed powders should be designed so that cosmetic tools such as puffs can be applied to a fixed amount of compressed powder suitable for application, and the compressed powder should be compressed. The powder is designed so that when the powder is tapped with the puff to compress the powder, the powder will not fly off.
以前述方式設計的壓縮粉末組成物中通常混合有作為粉 末內容物(content)的化妝用粉末及油質黏合劑等,藉由對上述成分進行粉碎及壓縮而成形。 Compressed powder compositions designed in the foregoing manner are usually mixed with Cosmetic powders and oily binders, etc. of the final contents are formed by pulverizing and compressing the above-mentioned components.
油質黏合劑主要用於藉由提高粉末的凝聚性,因而於壓縮粉末時有助於成形、防止因外部衝擊引起的碎裂,且防止利用化妝工具沾取壓縮粉末時的飛粉現象。然而,雖然使用油質黏合劑可減少飛粉,但存在於塗抹至皮膚時產生厚重感的情形。 Oil-based binders are mainly used to improve the cohesiveness of powders, thus helping to form when compressing powders, preventing breakage caused by external impact, and preventing flying powder when using cosmetic tools to pick up compressed powders. However, although the use of oil-based binders can reduce fly powder, there are cases where it creates a heavy feel when applied to the skin.
欲減少如上所述的因使用油質黏合劑產生的缺點的成形法為濕式成形法。於濕式成形法中,將包括油的黏合劑混合至粉末內容物而製成漿料狀態,將漿料狀態的內容物填充至容器,之後藉由壓榨及抽吸而萃取油來製造壓縮粉末。劑型的硬度等特性會根據上述壓榨而不同,組成物的功能亦會根據上述硬度而發生變化。並且,與乾式成形法相比,此種濕式成形法是將油質黏合劑用作溶劑,從而可均勻地混合粉末粒子。 A molding method for reducing the above-mentioned disadvantages due to the use of an oily binder is a wet molding method. In the wet molding method, a binder including oil is mixed into the powder content to make a slurry state, the content in the slurry state is filled into a container, and then the oil is extracted by pressing and suction to produce a compressed powder . The properties such as the hardness of the dosage form vary according to the above-mentioned pressing, and the function of the composition also changes according to the above-mentioned hardness. In addition, compared with the dry molding method, this wet molding method uses an oily binder as a solvent, so that powder particles can be uniformly mixed.
壓縮粉末的成形性通常會根據粉末的種類而不同,並且亦根據粉末塗覆劑的種類而不同。通常,為了改善粉末的使用感,可與如尼龍粉末、聚甲基丙烯酸甲酯(Polymethyl Methacrylate,PMMA)粉末及氧化矽等球狀粉末一同使用,球狀粉末於塗抹至皮膚時具有卓越吸油能力與良好延展性,因此適於用作彩妝化妝品的材料。然而,過量的球狀粉末具有難以壓縮成形的缺點。 The formability of the compressed powder generally differs depending on the type of powder, and also varies depending on the type of powder coating agent. Usually, in order to improve the use feeling of powder, it can be used together with spherical powder such as nylon powder, polymethyl methacrylate (PMMA) powder and silicon oxide. The spherical powder has excellent oil absorption ability when applied to the skin With good ductility, it is suitable for use as a material for make-up cosmetics. However, an excess of spherical powder has the disadvantage of being difficult to compression-form.
因此,實情為急需對可提高成形性及塗抹性的球狀粉末的壓縮劑型的製造方法進行研究。 Therefore, there is an urgent need to study a method for producing a compressed dosage form of spherical powder which can improve moldability and spreadability.
(專利文獻1)韓國公開專利第2013-055333號“補妝用化妝 品組成物及製備方法” (Patent Document 1) Korean Laid-Open Patent No. 2013-055333 "Makeup for Touch-Up Makeup" Product composition and preparation method"
(專利文獻2)韓國公開專利第2015-0023306號“包括非揮發性烴化油、蠟及高含量的非揮發性苯基化矽油的化妝品固體組成物” (Patent Document 2) Korean Laid-Open Patent No. 2015-0023306 "Cosmetic Solid Composition Containing Nonvolatile Hydrocarbonated Oil, Wax, and High Content of Nonvolatile Phenylated Silicone Oil"
為了解決上述問題,本發明人等人確認到如下情形而完成本發明:若包括球狀粉末及非揮發性油而以固定硬度製備彩妝化妝品組成物,則吸油能力、塗抹性及成形性提高。 In order to solve the above-mentioned problems, the present inventors completed the present invention by confirming that the oil absorption ability, spreadability and moldability are improved when a color cosmetic cosmetic composition is prepared with a fixed hardness including spherical powder and a nonvolatile oil.
因此,本發明的目的在於提供一種吸油能力、塗抹性及成形性提高的彩妝化妝品組成物及其製備方法。 Therefore, the object of the present invention is to provide a color cosmetic cosmetic composition with improved oil absorption capacity, spreadability and formability, and a preparation method thereof.
為了達成上述目的,本發明提供一種彩妝化妝品組成物,其特徵在於包括球狀粉末及非揮發性油,依據日本工業標準(Japanese Industrial Standards,JIS)K 6031測定到的硬度為5至12。 In order to achieve the above object, the present invention provides a color cosmetic composition, which is characterized by comprising spherical powder and non-volatile oil, and the hardness measured according to Japanese Industrial Standards (JIS) K 6031 is 5 to 12.
此時,上述球狀粉末可包括選自由六亞甲基二異氰酸酯/三羥甲基己基內酯交聯聚合物、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷倍半矽氧烷交聯聚合物、氧化矽、聚甲基丙烯酸甲酯、聚胺基甲酸酯、聚甲基倍半矽氧烷及尼龍所組成的族群中的一種以上。 At this time, the spherical powder may comprise a cross-linked polymer of hexamethylene diisocyanate/trimethylol hexyl lactone, vinyl polydimethylsiloxane/polymethylsiloxane sesquisiloxane One or more of the group consisting of alkane cross-linked polymer, silicon oxide, polymethyl methacrylate, polyurethane, polymethylsilsesquioxane and nylon.
此時,上述球狀粉末可為由選自由氧化矽、聚甲基丙烯酸甲酯、倍半矽氧烷樹脂及尼龍所組成的族群中的一種以上複合化而成的球狀粉末。 In this case, the spherical powder may be a spherical powder formed by compounding at least one selected from the group consisting of silicon oxide, polymethyl methacrylate, silsesquioxane resin, and nylon.
此時,複合化而成的上述球狀粉末可包括由氧化矽與聚甲基丙烯酸甲酯複合化而成的六亞甲基二異氰酸酯/三羥甲基己基內酯交聯聚合物球狀粉末。 At this time, the compounded spherical powder may include hexamethylene diisocyanate/trimethylol hexyllactone cross-linked polymer spherical powder compounded by silicon oxide and polymethyl methacrylate .
此時,上述化妝品組成物可更包括乙烯基聚二甲基矽氧烷/聚甲基矽氧烷倍半矽氧烷交聯聚合物球狀粉末。 At this time, the above cosmetic composition may further comprise vinyl polydimethylsiloxane/polymethylsiloxane silsesquioxane cross-linked polymer spherical powder.
此時,複合化而成的上述球狀粉末的平均粒徑(D50)可為1μm至10μm。 At this time, the average particle diameter (D50) of the spherical powder obtained by compounding may be 1 μm to 10 μm.
此時,上述非揮發性油可包括選自由包括聚二甲基矽氧烷、環甲聚矽氧烷及三矽氧烷/聚二甲基矽氧烷的矽油;包括乙基己酸鯨蠟酯、棕櫚酸異丙酯、肉豆蔻酸異丙酯、苯甲酸烷基酯、琥珀酸二乙氧基乙酯及季戊四醇四異硬脂酸酯的酯類油;及包括礦物油、異十六烷、異癸烷、十一烷、角鯊烷、氫化聚癸烯、α-烯烴低聚物及氫化聚異丁烯的烴類油所組成的族群中的一種以上。 In this case, the above-mentioned non-volatile oils may include silicone oils selected from the group consisting of polydimethylsiloxane, cyclomethicone, and trisiloxane/polydimethylsiloxane; including cetyl ethylhexanoate esters, isopropyl palmitate, isopropyl myristate, alkyl benzoate, diethoxyethyl succinate, and pentaerythritol tetraisostearate; and oils including mineral oil, isohexadecanoate One or more of the group consisting of hydrocarbon oils of alkane, isodecane, undecane, squalane, hydrogenated polydecene, α-olefin oligomer and hydrogenated polyisobutylene.
此時,上述化妝品組成物可包括50重量%至80重量%的球狀粉末及20重量%至50重量%的非揮發性油。 At this time, the above cosmetic composition may include 50% by weight to 80% by weight of spherical powder and 20% by weight to 50% by weight of nonvolatile oil.
此時,上述彩妝化妝品組成物可為選自由妝前乳、粉底、妝前底霜、兩用粉餅、粉餅、粉、眉粉及眼影所組成的族群中的劑型。 In this case, the above-mentioned makeup cosmetic composition may be a dosage form selected from the group consisting of primer, foundation, primer, dual-purpose powder, pressed powder, powder, eyebrow powder, and eye shadow.
並且,本發明提供一種彩妝化妝品組成物的製備方法,其特徵在於包括:1)混合球狀粉末與非揮發性油的步驟;及2)以25kgf至150kgf的壓力壓縮成形上述混合物,藉此去除一部分非揮發性油而製備成依據JIS K 6031測定到的硬度為5 至12的粉餅劑型的步驟。 Furthermore, the present invention provides a method for preparing a color cosmetic composition, which is characterized by comprising: 1) a step of mixing spherical powder and non-volatile oil; and 2) compression molding the above mixture with a pressure of 25kgf to 150kgf, thereby removing the A part of non-volatile oil is prepared so that the hardness measured according to JIS K 6031 is 5 Steps to 12 pressed powder dosage forms.
本發明的彩妝化妝品組成物是於將球狀粉末與非揮發性油混合而製成漿料形態後,壓縮及去除一部分油而以固定硬度製備,從而提高成形性,具有飛粉較少、可均勻地塗抹至皮膚、於皮膚皺紋等處無卡粉現象、化妝持久力提高的效果,且提亮效果優異。 The color cosmetic composition of the present invention is prepared by mixing spherical powder and non-volatile oil to form a slurry, compressing and removing a part of the oil to prepare a fixed hardness, thereby improving the formability, and has less flying powder and can be Evenly applied to the skin, no sticking of powder on skin wrinkles, etc., the effect of improving makeup staying power, and excellent brightening effect.
圖1(a)與圖1(b)分別是對實施例1與比較例3的組成物的卡粉現象進行比較的照片。 1( a ) and FIG. 1( b ) are photographs for comparing the powder sticking phenomenon of the compositions of Example 1 and Comparative Example 3, respectively.
圖2(a)與圖2(b)分別是對實施例1與比較例2的組成物的成形性進行比較的照片。 FIG. 2( a ) and FIG. 2( b ) are photographs for comparing the formability of the compositions of Example 1 and Comparative Example 2, respectively.
圖3是表示實施例1的組成物的塗抹性的照片。 3 is a photograph showing the spreadability of the composition of Example 1. FIG.
圖4是表示比較例1的組成物的塗抹性的照片。 4 is a photograph showing the spreadability of the composition of Comparative Example 1. FIG.
圖5是表示比較例3的組成物的塗抹性的照片。 5 is a photograph showing the spreadability of the composition of Comparative Example 3. FIG.
以下,詳細地進行說明,以便在本發明所屬的技術領域內具有常識者可容易地實施。然而,本發明能夠以多種不同的形態實現,並不限定於此處所說明的實施例。 Hereinafter, it demonstrates in detail so that a person with ordinary knowledge in the technical field to which the present invention pertains can easily implement. However, the present invention can be realized in various forms, and is not limited to the embodiments described here.
本發明提供一種彩妝化妝品組成物,其特徵在於包括球狀粉末及非揮發性油,依據JIS K 6031測定到的硬度為5至12。上述硬度較佳為可為8至10。 The present invention provides a color makeup cosmetic composition, which is characterized by comprising spherical powder and non-volatile oil, and the hardness measured according to JIS K 6031 is 5 to 12. The above-mentioned hardness may preferably be 8 to 10.
於製備組成物時,可於壓縮及去除一部分油的過程中決定上述硬度,硬度會對成形性及塗抹性產生影響。於組成物的硬度過度地低於上述範圍的情形時,油的殘留量較多,故而於使用(Pay off)時會於塗抹器等沾染過多的組成物,因持續使用而組成物的硬度會逐漸變得更低。並且,於組成物的硬度過度地高於上述範圍的情形時,會產生如下缺點:劑型會容易地破碎或龜裂,於使用時幾乎不沾染至塗抹器等。 In the preparation of the composition, the above-mentioned hardness can be determined in the process of compressing and removing a part of the oil, and the hardness affects the formability and spreadability. When the hardness of the composition is excessively lower than the above-mentioned range, the residual amount of oil is large, so the applicator will be stained with too much composition during use (pay off), and the hardness of the composition will decrease due to continuous use. gradually become lower. In addition, when the hardness of the composition is excessively higher than the above-mentioned range, there is a disadvantage that the dosage form is easily broken or cracked, and the applicator is hardly stained during use.
並且,依據JIS K 6301測定到的上述硬度可使用JIS K 6301 A型硬度計測定。 In addition, the above-mentioned hardness measured according to JIS K 6301 can be measured using a JIS K 6301 A type durometer.
上述球狀粉末是具有球形顆粒的粉末,且包括於彩妝化妝品組成物中而賦予光滑且輕薄的觸感。上述球狀粉末具有使光朝向所有方向擴散的效果,且因其形狀而對皮膚具有優異的延展性。並且,與板狀粉末相比,其具有遮蔽毛孔或痘痕等皮膚瑕疵的效果。球狀粉末具有吸油效果,不凝聚而輕薄地塗抹至皮膚,因此卡粉現象較少。因此,包括球狀粉末的彩妝化妝品組成物對皮膚具有優異的貼附性及吸油能力。然而,含有大量的球狀粉末的彩妝化妝品組成物具有因粉末粒子間的空隙及斥力而難以成形的缺點。 The aforementioned spherical powder is a powder having spherical particles, and is included in a color cosmetic composition to impart a smooth and light touch. The spherical powder described above has the effect of diffusing light in all directions, and has excellent ductility to the skin due to its shape. In addition, compared to the tabular powder, it has the effect of concealing skin imperfections such as pores and acne marks. The spherical powder has an oil-absorbing effect and is applied lightly to the skin without agglomeration, so there is less powder sticking. Therefore, the color cosmetic composition including the spherical powder has excellent adhesion to the skin and oil absorption ability. However, a color cosmetic composition containing a large amount of spherical powder has a disadvantage that it is difficult to mold due to the voids and repulsion between powder particles.
本發明人等人對球狀粉末含量較高、且可實現為以方便攜帶的方式壓縮而成的形態的彩妝化妝品組成物進行研究,其結果確認到當包括球狀粉末及非揮發性油而以固定硬度製備組成物時,可改善壓縮成形性。 The inventors of the present invention conducted research on a color cosmetic cosmetic composition with a high content of spherical powder and a form that can be compressed in a portable manner, and as a result, confirmed that when the spherical powder and non-volatile oil are included, the When the composition is prepared with a fixed hardness, the compression formability can be improved.
未特別限制可使用於本發明的球狀粉末,可使用本技術領域內通常使用的種類的無機粒子、有機粒子及有機無機複合粒 子。 The spherical powder that can be used in the present invention is not particularly limited, and inorganic particles, organic particles, and organic-inorganic composite particles of the types generally used in this technical field can be used son.
上述球狀粉末可包括選自由六亞甲基二異氰酸酯/三羥甲基己基內酯交聯聚合物、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷倍半矽氧烷交聯聚合物、氧化矽、聚甲基丙烯酸甲酯、聚胺基甲酸酯、聚甲基倍半矽氧烷及尼龍所組成的族群中的一種以上。 Said spherical powder may comprise selected from the group consisting of hexamethylene diisocyanate/trimethylolcaprolactone cross-linked polymer, vinyl polydimethylsiloxane/polymethylsiloxane silsesquioxane cross-linked One or more of the group consisting of polymer, silicon oxide, polymethyl methacrylate, polyurethane, polymethylsilsesquioxane and nylon.
並且,上述球狀粉末可為由選自由氧化矽、聚甲基丙烯酸甲酯、倍半矽氧烷樹脂及尼龍所組成的族群中的一種以上複合化而成的球狀粉末。 In addition, the spherical powder may be a spherical powder formed by compounding at least one selected from the group consisting of silicon oxide, polymethyl methacrylate, silsesquioxane resin, and nylon.
上述複合化是指如下混合技術:混合兩種以上的粉末,藉此結合各者的特性而減少缺點、發揮優點。 The above-mentioned compounding refers to a mixing technique in which two or more kinds of powders are mixed and the characteristics of each are combined to reduce disadvantages and exert advantages.
複合化而成的上述球狀粉末較佳為可為作為EPU-2X(六亞甲基二異氰酸酯/三羥甲基己基內酯交聯聚合物&聚甲基丙烯酸甲酯、氧化矽(HDI/Trimethylol Hexyllactone Crosspolymer & Polymethyl Methacrylate,silica),SUNJIN BEAUTY SCIENCE公司)而市售的由氧化矽與聚甲基丙烯酸甲酯複合化而成的六亞甲基二異氰酸酯/三羥甲基己基內酯交聯聚合物球狀粉末,上述球狀粉末因對柔滑感產生影響的K值(K value)較高而容易按壓,相反地,因彈性指數即恢復率(Recovery rate)(按壓後欲恢復至原狀的性質)較低而易於壓縮,因此成形性良好。 The compounded spherical powder is preferably used as EPU-2X (hexamethylene diisocyanate/trimethylolcaprolactone cross-linked polymer & polymethyl methacrylate, silicon oxide (HDI/ Trimethylol Hexyllactone Crosspolymer & Polymethyl Methacrylate, silica), SUNJIN BEAUTY SCIENCE Company) and the commercially available hexamethylene diisocyanate/trimethylol hexyl lactone cross-linking compounded by silicon oxide and polymethyl methacrylate Polymer spherical powder, the above spherical powder is easy to be pressed due to the high K value (K value) that affects the smoothness. Properties) are low and easy to compress, so the formability is good.
並且,上述彩妝化妝品組成物可更包括作為KSP-101(SHINETSU公司)而市售的乙烯基聚二甲基矽氧烷/聚甲基矽氧烷倍半矽氧烷交聯聚合物球狀粉末。 In addition, the above-mentioned color cosmetic composition may further include vinyl polydimethylsiloxane/polymethylsiloxane silsesquioxane cross-linked polymer spherical powder commercially available as KSP-101 (SHINETSU Corporation) .
此時,複合化而成的上述球狀粉末可包括70重量%至99重量%的由氧化矽與聚甲基丙烯酸甲酯複合化而成的六亞甲基二 異氰酸酯/三羥甲基己基內酯交聯聚合物球狀粉末、及1重量%至30重量%的乙烯基聚二甲基矽氧烷/聚甲基矽氧烷倍半矽氧烷交聯聚合物球狀粉末。 At this time, the compounded spherical powder may include 70% by weight to 99% by weight of hexamethylene dimethacrylate compounded by silicon oxide and polymethyl methacrylate Isocyanate/Trimethylolhexyllactone Crosspolymer Spherical Powder, and 1% to 30% by Weight of Vinyl Dimethicone/Polymethylsiloxane Silsesquioxane Crosspolymer Spherical powder.
複合化而成的上述球狀粉末的平均粒徑(D50)可為1μm至10μm、較佳為3μm至7μm。若球狀粉末的平均粒徑超過10μm,則會難以壓縮成形,且劑型穩定性方面(諸如於掉落時劑型碎裂)產生問題,因此於上述範圍內適當地調節。 The average particle diameter (D50) of the compounded spherical powder may be 1 μm to 10 μm, preferably 3 μm to 7 μm. If the average particle diameter of the spherical powder exceeds 10 μm, compression molding becomes difficult, and problems arise in the aspect of dosage form stability such as breakage of the dosage form when dropped, so it is appropriately adjusted within the above range.
為了提高球狀粉末粒子間的結合力,本發明的彩妝化妝品組成物可包括非揮發性油。上述非揮發性油可包括選自由包括聚二甲基矽氧烷、環甲聚矽氧烷及三矽氧烷/聚二甲基矽氧烷的矽油;包括乙基己酸鯨蠟酯、棕櫚酸異丙酯、肉豆蔻酸異丙酯、苯甲酸烷基酯、琥珀酸二乙氧基乙酯及季戊四醇四異硬脂酸酯的酯類油;及包括礦物油、異十六烷、異癸烷、十一烷、角鯊烷、氫化聚癸烯、α-烯烴低聚物及氫化聚異丁烯的烴類油所組成的族群中的一種以上,上述油較佳為可為矽油、更佳為聚二甲基矽氧烷。 In order to improve the binding force between spherical powder particles, the color cosmetic composition of the present invention may include a non-volatile oil. The above-mentioned non-volatile oils may include silicone oils selected from the group consisting of polydimethylsiloxane, cyclomethicone, and trisiloxane/polydimethylsiloxane; including cetyl ethylhexanoate, palm Ester oils of isopropyl acid, isopropyl myristate, alkyl benzoate, diethoxyethyl succinate and pentaerythritol tetraisostearate; and including mineral oil, isohexadecane, isohexadecane One or more of the group consisting of hydrocarbon oils of decane, undecane, squalane, hydrogenated polydecene, alpha-olefin oligomers and hydrogenated polyisobutene, the above-mentioned oils are preferably silicone oil, more preferably It is polydimethylsiloxane.
此時,上述化妝品組成物可包括50重量%至80重量%的球狀粉末及20重量%至50重量%的非揮發性油。若球狀粉末的量多於上述範圍、或非揮發性油的量少於上述範圍,則會發生飛粉,且成形性會變差,因此需適當地調節使用球狀粉末及非揮發性油。 At this time, the above cosmetic composition may include 50% by weight to 80% by weight of spherical powder and 20% by weight to 50% by weight of nonvolatile oil. If the amount of the spherical powder is larger than the above range or the amount of the non-volatile oil is less than the above range, fly powder will occur and the moldability will be deteriorated. Therefore, it is necessary to adjust the use of the spherical powder and the non-volatile oil appropriately. .
更佳地,本發明提供一種彩妝化妝品組成物,其特徵在於包括50重量%至80重量%的由氧化矽與聚甲基丙烯酸甲酯複合化而成的六亞甲基二異氰酸酯/三羥甲基己基內酯交聯聚合物球狀粉末、及20重量%至50重量%的聚二甲基矽氧烷,依據JIS K 6031測定到的硬度為5至12,上述化妝品組成物可更包括乙烯基聚二 甲基矽氧烷/聚甲基矽氧烷倍半矽氧烷交聯聚合物球狀粉末。 More preferably, the present invention provides a color makeup cosmetic composition, which is characterized by comprising 50% to 80% by weight of hexamethylene diisocyanate/trimethylol which is compounded by silicon oxide and polymethyl methacrylate. Hexyllactone cross-linked polymer spherical powder, and 20% to 50% by weight of polydimethylsiloxane, the hardness measured according to JIS K 6031 is 5 to 12, and the cosmetic composition may further include ethylene base polydi Methylsiloxane/polymethylsiloxane silsesquioxane cross-linked polymer spherical powder.
此時,上述彩妝化妝品組成物可為選自由妝前乳、粉底、妝前底霜、兩用粉餅、粉餅、粉、眉粉及眼影所組成的族群中的劑型,上述劑型較佳為可為妝前乳。 At this time, the above-mentioned makeup cosmetic composition may be a dosage form selected from the group consisting of a primer, a foundation, a primer before makeup, a dual-purpose powder, a powder, a powder, an eyebrow powder and an eye shadow, and the dosage form is preferably a Makeup primer.
並且,本發明提供一種彩妝化妝品組成物的製備方法,其特徵在於包括:1)混合球狀粉末與非揮發性油的步驟;及2)以25kgf至150kgf的壓力壓縮成形上述混合物,藉此去除一部分非揮發性油而製備成依據JIS K 6031測定到的硬度為5至12的粉餅劑型的步驟。 Furthermore, the present invention provides a method for preparing a color cosmetic composition, which is characterized by comprising: 1) a step of mixing spherical powder and non-volatile oil; and 2) compression molding the above mixture with a pressure of 25kgf to 150kgf, thereby removing the A step of preparing a pressed powder with a hardness of 5 to 12 as measured in accordance with JIS K 6031 from a part of the non-volatile oil.
上述製備方法為濕式製程,上述濕式狀態是指粉末超出可吸收/吸油的極限值而包括較其吸收/吸油能力更多的油時具有流動性的狀態。上述製備方法是以如下方式進行製備:混合球狀粉末與非揮發性油,添加油直至上述混合物成為漿料狀態為止。 The above-mentioned preparation method is a wet process, and the above-mentioned wet state refers to a state in which the powder has fluidity when the powder exceeds the limit value of absorbing/absorbing oil and contains more oil than its absorbing/absorbing capacity. The above-mentioned preparation method is prepared by mixing spherical powder and non-volatile oil, and adding oil until the above-mentioned mixture becomes a slurry state.
於濕式狀態下,非揮發性油完全塗覆粉末粒子的外圍,藉此可預期較普通成形更為柔滑的使用感。將固定量的以濕式狀態成為漿料的內容物填充至盤中,之後藉由壓榨及抽吸來萃取出油的一部分而壓縮成形。 In the wet state, the non-volatile oil completely coats the periphery of the powder particles, whereby a smoother feeling in use than ordinary molding can be expected. A fixed amount of the content which was made into a slurry in a wet state is filled in a pan, and then a part of the oil is extracted by pressing and suction, and compression molding is performed.
藉由通常的乾式製程製備的粉餅型組成物存在如下極限:成形性不優異,因此於乾燥後而塗抹至皮膚的情形時貼附性下降。並且,若混合少量的油與粉末,則組成物的成形性不優異,油難以細密地滲透至粉末之間,故難以完全包覆粉末。 A pressed powder composition prepared by a normal dry process has a limit in that it is not excellent in formability, and therefore, when it is dried and applied to the skin, the adhesiveness decreases. In addition, when a small amount of oil and powder are mixed, the formability of the composition is not excellent, and it is difficult for the oil to penetrate finely between the powders, so that it is difficult to completely coat the powder.
為了克服此種極限,本發明的製備方法利用濕式製程製備組成物,本發明的組成物可藉由如下製程獲得優異的成形性 等:於將足量的油與粉末混合後,保留最終所需的量的油之後,去除多餘的油。 In order to overcome this limitation, the preparation method of the present invention utilizes a wet process to prepare the composition, and the composition of the present invention can obtain excellent formability through the following process Etc.: After mixing a sufficient amount of oil with the powder, after retaining the final desired amount of oil, remove the excess oil.
於上述製備方法中,上述球狀粉末可包括選自由六亞甲基二異氰酸酯/三羥甲基己基內酯交聯聚合物、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷倍半矽氧烷交聯聚合物、氧化矽、聚甲基丙烯酸甲酯、聚胺基甲酸酯、聚甲基倍半矽氧烷及尼龍所組成的族群中的一種以上。 In the above-mentioned preparation method, the above-mentioned spherical powder may comprise a compound selected from the group consisting of hexamethylene diisocyanate/trimethylol hexyl lactone cross-linked polymer, vinyl polydimethylsiloxane/polymethylsiloxane One or more of the group consisting of semi-siloxane cross-linked polymer, silicon oxide, polymethyl methacrylate, polyurethane, polymethyl silsesquioxane and nylon.
並且,於上述製備方法中,上述球狀粉末可為由選自由氧化矽、聚甲基丙烯酸甲酯、倍半矽氧烷樹脂及尼龍所組成的族群中的一種以上複合化而成的球狀粉末。 In addition, in the above preparation method, the spherical powder may be a spherical powder formed by compounding at least one kind selected from the group consisting of silicon oxide, polymethyl methacrylate, silsesquioxane resin and nylon. powder.
於上述製備方法中,複合化而成的上述球狀粉末較佳為可包括作為EPU-2X(六亞甲基二異氰酸酯/三羥甲基己基內酯交聯聚合物&聚甲基丙烯酸甲酯、氧化矽(HDI/Trimethylol Hexyllactone Crosspolymer & Polymethyl Methacrylate,silica),SUNJIN BEAUTY SCIENCE公司)而市售的由氧化矽與聚甲基丙烯酸甲酯複合化而成的六亞甲基二異氰酸酯/三羥甲基己基內酯交聯聚合物球狀粉末。 In the above-mentioned preparation method, the above-mentioned spherical powder formed by compounding may preferably include as EPU-2X (hexamethylene diisocyanate/trimethylol hexyl lactone cross-linked polymer & polymethyl methacrylate) , Silicon oxide (HDI/Trimethylol Hexyllactone Crosspolymer & Polymethyl Methacrylate, silica), SUNJIN BEAUTY SCIENCE Company) and the commercially available hexamethylene diisocyanate/trimethylol which is compounded by silicon oxide and polymethyl methacrylate Hexyllactone cross-linked polymer spherical powder.
並且,於上述製備方法中,上述彩妝化妝品組成物可更包括作為KSP-101(SHINETSU公司)而市售的乙烯基聚二甲基矽氧烷/聚甲基矽氧烷倍半矽氧烷交聯聚合物球狀粉末。 In addition, in the above preparation method, the above-mentioned color cosmetic composition may further comprise vinyl polydimethylsiloxane/polymethylsiloxane silsesquioxane cross-linked commercially available as KSP-101 (SHINETSU company). Interpolymer spherical powder.
於上述製備方法中,上述非揮發性油可包括選自由包括聚二甲基矽氧烷、環甲聚矽氧烷及三矽氧烷/聚二甲基矽氧烷的矽油;包括乙基己酸鯨蠟酯、棕櫚酸異丙酯、肉豆蔻酸異丙酯、苯甲酸烷基酯、琥珀酸二乙氧基乙酯及季戊四醇四異硬脂酸酯的酯 類油;及包括礦物油、異十六烷、異癸烷、十一烷、角鯊烷、氫化聚癸烯、α-烯烴低聚物及氫化聚異丁烯的烴類油所組成的族群中的一種以上,上述油較佳為可為聚二甲基矽氧烷。 In the above-mentioned preparation method, the above-mentioned non-volatile oil may comprise a silicone oil selected from the group consisting of polydimethylsiloxane, cyclomethicone, and trisiloxane/polydimethylsiloxane; including ethyl hexane Esters of cetyl acid, isopropyl palmitate, isopropyl myristate, alkyl benzoate, diethoxyethyl succinate and pentaerythritol tetraisostearate oils; and of the group consisting of hydrocarbon oils comprising mineral oils, isohexadecane, isodecane, undecane, squalane, hydrogenated polydecenes, alpha-olefin oligomers, and hydrogenated polyisobutenes More than one, the above-mentioned oil can preferably be polydimethylsiloxane.
於上述製備方法中,上述化妝品組成物可包括50重量%至80重量%的球狀粉末及20重量%至50重量%的非揮發性油。若球狀粉末的量多於上述範圍、或非揮發性油的量少於上述範圍,則會發生飛粉,且成形性會變差,因此適當地調節使用球狀粉末及非揮發性油。 In the above preparation method, the above cosmetic composition may include 50% to 80% by weight of spherical powder and 20% to 50% by weight of non-volatile oil. If the amount of the spherical powder is larger than the above range or the amount of the nonvolatile oil is less than the above range, fly powder will occur and the formability will be deteriorated. Therefore, the spherical powder and the nonvolatile oil are appropriately adjusted and used.
並且,本發明提供一種彩妝化妝品組成物,其特徵在於藉由上述製備方法而製備。 Furthermore, the present invention provides a color cosmetic composition, characterized by being prepared by the above-mentioned preparation method.
除此之外,上述彩妝化妝品組成物可更包括保持成分、保濕劑、軟化劑、界面活性劑、有機顏料、無機顏料、有機粉體、紫外線吸收劑、防腐劑、增黏劑、殺菌劑、抗氧化劑、植物萃取物、pH值調整劑、酒精、色素、香料、血行促進劑、冷感劑、止汗劑中的任一種以上。 In addition, the above-mentioned makeup and cosmetic compositions may further include retaining ingredients, moisturizing agents, softeners, surfactants, organic pigments, inorganic pigments, organic powders, ultraviolet absorbers, preservatives, tackifiers, bactericides, Any one or more of antioxidants, plant extracts, pH adjusters, alcohols, pigments, fragrances, blood flow enhancers, cooling agents, and antiperspirants.
本發明的彩妝化妝品組成物是於將複合化而成的球狀粉末與非揮發性油混合而製成漿料形態後,壓縮及去除一部分油而以固定硬度製備,從而提高成形性,具有飛粉較少、可均勻地塗抹至皮膚、於皮膚皺紋等處無卡粉現象、化妝持久力提高的效果,且提亮效果優異。 The color cosmetic composition of the present invention is prepared by mixing the compounded spherical powder and non-volatile oil to form a slurry, compressing and removing a part of the oil to prepare a fixed hardness, thereby improving the formability, and has the advantages of flying Less powder, can be applied evenly to the skin, no sticking of powder on skin wrinkles, etc., the effect of improving makeup staying power, and excellent brightening effect.
以下,為了有助於理解本發明而提出較佳的實施例,但於本技術領域內具有常識者應明白,下述實施例僅用以例示本發明,可於本發明的範疇及技術思想範圍內實現各種變更及修正,此種變更及修正當然亦屬於隨附的發明申請專利範圍。 Below, in order to facilitate understanding of the present invention, preferred embodiments are proposed, but those with common knowledge in the technical field should understand that the following embodiments are only used to illustrate the present invention, and can be used within the scope of the present invention and the scope of technical ideas Various changes and corrections are realized within the scope of the invention, and such changes and corrections of course also belong to the scope of the accompanying invention patent application.
按照下述表1的配方製備實施例1及實施例2的彩妝化妝品組成物。 The color cosmetic cosmetic compositions of Examples 1 and 2 were prepared according to the formulations in Table 1 below.
1)於利用亨舍爾混合機將球狀粉末混合2分鐘後,進行粉碎及過濾。 1) After mixing the spherical powder with a Henschel mixer for 2 minutes, pulverization and filtration were performed.
2)向上述1)的混合物噴塗上述非揮發性油,利用萬能混合機混合5分鐘至10分鐘。 2) Spray the above-mentioned non-volatile oil on the mixture of the above-mentioned 1), and mix for 5 minutes to 10 minutes with a universal mixer.
3)將固定量的上述2)的混合物放置至盤上,之後壓縮成形及去除一部分油而製備彩妝化妝品組成物。於下述表1中表示配方的組成及條件。 3) A fixed amount of the mixture of the above-mentioned 2) is placed on a plate, and then compression-molded and a part of oil is removed to prepare a color cosmetic composition. The composition and conditions of the formulation are shown in Table 1 below.
按照下述表2的配方而藉由與上述實施例1及實施例2相同的方法製備比較例1至比較例3的彩妝化妝品組成物。特別是,比較例3是藉由通常的乾式製程而製備組成物。 The color cosmetic cosmetic compositions of Comparative Examples 1 to 3 were prepared by the same method as in Examples 1 and 2 described above according to the formulations in Table 2 below. In particular, in Comparative Example 3, a composition was prepared by a normal dry process.
於分別在盤中成形上述實施例1、實施例2及比較例1至比較例3的彩妝化妝品組成物後,依據JIS K 6031測定硬度。 求出藉由上述方法而於隨機選定的10處位置測定到的硬度的平均值,測定結果示於下述表3。 The hardness was measured in accordance with JIS K 6031 after the color cosmetic cosmetic compositions of Example 1, Example 2, and Comparative Examples 1 to 3 were formed in trays, respectively. The average value of the hardness measured at 10 randomly selected positions by the method described above was obtained, and the measurement results are shown in Table 3 below.
以30名20歲至40歲的女性為對象而使其實際使用藉由現有的方法製備的上述實施例1至實施例2及比較例1至比較例3的彩妝化妝品組成物,之後對製品的效果進行比較。試驗項目為吸油能力、成形性、飛粉較少、均勻的塗抹性、卡粉現象較少、化妝持久力及提亮效果。於對各項目進行評估後,給出0至15的分數而計算其平均分數。為了確保資料的準確性而分別反覆實施5次,將其結果記載至下述表4。若平均分數未滿4.0,則表示為“×”,若為4.0至8.0,則表示為“△”,若為8.1至12.0,則表示為“○”,若超過12.0,則表示為“◎”。 30 women between the ages of 20 and 40 were subjected to practical use of the color cosmetic cosmetic compositions of Examples 1 to 2 and Comparative Examples 1 to 3 prepared by conventional methods. compare the effects. The test items are oil absorption ability, formability, less powder fly, even spreadability, less powder sticking, makeup staying power and brightening effect. After evaluating each item, a score from 0 to 15 was given and the average score was calculated. In order to ensure the accuracy of the data, the experiment was repeated five times, and the results were recorded in Table 4 below. If the average score is less than 4.0, it is indicated as "×", if it is 4.0 to 8.0, it is indicated as "△", if it is 8.1 to 12.0, it is indicated as "○", and if it exceeds 12.0, it is indicated as "◎" .
並且,將對實施例1與比較例3的組成物的卡粉現象進行比較的照片示於圖1(a)與圖1(b),將對實施例1與比較例2的組成物的成形性進行比較的照片示於圖2(a)與圖2(b),將表示實施例1、比較例1及比較例3的組成物的塗抹性的照片示於圖3至圖5。 1( a ) and FIG. 1( b ), photographs comparing the powder sticking phenomenon of the compositions of Example 1 and Comparative Example 3 are shown in Figs. 1( a ) and 1 ( b ). The photographs for comparing the properties are shown in FIGS. 2( a ) and 2 ( b ), and the photographs showing the smearability of the compositions of Example 1, Comparative Example 1, and Comparative Example 3 are shown in FIGS. 3 to 5 .
如上述表4所示,可知實施例1及實施例2的組成物的吸油能力、成形性、飛粉較少、均勻的塗抹性、卡粉現象較少、化妝持久力及提亮效果等整體效果優於比較例1至比較例3,特別是可確認到存在硬度差異的比較例2的整體效果欠佳。並且,如圖1(a)至圖2(b)所示,可確認到於塗抹實施例1的組成物的情形時,卡粉現象非常少,如圖2(a)與圖2(b)所示,可確認到實施例1的組成物的成形性優於比較例2的組成物,如圖3至圖5所示,可確認到實施例1的組成物較比較例1及比較例3的組成物柔滑且均勻地塗抹。 As shown in Table 4 above, it can be seen that the compositions of Examples 1 and 2 have overall oil absorption capacity, moldability, less powder flying, uniform spreadability, less powder sticking, makeup staying power, and brightening effect. The effect is better than that of Comparative Examples 1 to 3, and in particular, the overall effect of Comparative Example 2, in which a difference in hardness was confirmed, was poor. In addition, as shown in Fig. 1(a) to Fig. 2(b), it can be confirmed that when the composition of Example 1 is applied, the phenomenon of powder sticking is very small, as shown in Fig. 2(a) and Fig. 2(b) As shown, it can be confirmed that the formability of the composition of Example 1 is better than that of the composition of Comparative Example 2, and as shown in FIGS. The composition spreads smoothly and evenly.
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