CN110519989A - Fungicidal composition and application thereof - Google Patents

Fungicidal composition and application thereof Download PDF

Info

Publication number
CN110519989A
CN110519989A CN201880025066.2A CN201880025066A CN110519989A CN 110519989 A CN110519989 A CN 110519989A CN 201880025066 A CN201880025066 A CN 201880025066A CN 110519989 A CN110519989 A CN 110519989A
Authority
CN
China
Prior art keywords
bacterium
spp
azoles
triazole
spore
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201880025066.2A
Other languages
Chinese (zh)
Inventor
J·T·布里斯托
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Rotam Chemical Co Ltd
Original Assignee
Jiangsu Rotam Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Rotam Chemical Co Ltd filed Critical Jiangsu Rotam Chemical Co Ltd
Publication of CN110519989A publication Critical patent/CN110519989A/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention provides Fungicidal composition, the composition includes benzamide type fungicide, strobilurin fungicide and triazole type fungicide.The composition shows to act synergistically in handling and/or controlling a series of fungal infections.A kind of method for controlling mycotic infection of plant is provided, this method includes applying benzamide type fungicide, strobilurin fungicide and triazole type fungicide to these plants, to one or more part or to its location.

Description

Fungicidal composition and application thereof
The present invention relates to Fungicidal compositions with synergy, show to act synergistically when being especially included in combination Three kinds of active components composition.The invention further relates to the combinations of this active component to prevent and/or handle plant With the purposes of plant part fungal infection, and prevention and/or the method for handling plant and plant part fungal infection.
Pathogen including fungi is the main source of crop disease.Fungicide is to kill or inhibit fungi or true The chemical agent of bacterium sample biological growth.Therefore, fungicide is the very important tool for cover crop from fungal infection. Fungal infection would generally generate significant economic impact to the yield and quality of crop.Therefore, it is intended that exploitation has high-level function The fungicide of effect.It is of course possible to which developing just can control or prevent fungal infection using minimum Fungicidal active ingredient It is also useful that aspect, which shows the active Fungicidal composition of high level, because such composition can reduce adverse environment Influence.
Surprisingly, it has been found that formamide kills very compared with the activity of the identical fungicidal component of exclusive use The combination of microbial inoculum, strobilurin fungicide and triazole antifungal agents shows synergistic activity.
Therefore, in a first aspect, the present invention provides include carboxamide fungicides, strobilurin fungicide and three The Fungicidal composition of azoles fungicide.
In a further aspect, the present invention provides the method for controlling mycotic infection of plant, this method includes to these Plant applies carboxamide fungicides, thermophilic ball to one or more part (for example, leaf or seed) or to its location Fruit umbrella element fungicide and triazole antifungal agents.This method will be defined above before or after being included in fungal infection Fungicidal component is applied to plant, plant part or its location.
Again in a further aspect, the present invention provides carboxamide fungicides, strobilurin fungicide and triazoles to kill Purposes of the epiphyte pharmaceutical in the fungal infection of control plant or plant part.
As used in this specification, term "comprising" indicate include indicated element but be not excluded for there is also its His element.
As used herein, " plant " refers to all plants and plant population, as desired with undesirable wild plant Or crop plants.
As used herein, " plant part " refers to all parts and the organ of plant, as bud, leaf, needle, bar, stem, Fructification, fruit, seed, root, stem tuber and rhizome.Further comprise harvested material and trophism and reproduction sexual reproduction Material, such as cutting, stem tuber, separate living tissue, rhizome, offset, seed, single and multiple plant cells and any other plant Tissue.
Term " ambient enviroment " or the ground that " location " refers to the place of plant growth, the propagation material of plant is sowed The place that the propagation material of side or plant will be sowed.
When the effect that some Fungicidal active ingredients are administered in combination is more more effective than the effect summation that it is respectively administered alone, this Kind effect referred to as " acts synergistically "." synergistic effect " is the interaction of two or more factors, so that effect when combination Fruit is greater than the effect predicted based on the reaction to each factor individually applied.It is surprising that it has been found that when combination Or when being used together, above-mentioned three kinds of fungicidal components are in control fungal infection (including preventing, reducing or eliminating fungal infection) Active aspect shows to act synergistically.
Compared with each component is used alone, the synergistic effect for the fungicide combination for forming present invention basis can be provided Multiple advantages.Particularly, when above-mentioned three kinds of fungicidal components are applied in combination, the rate of application of every kind of component be can be significantly reduced, High-caliber fungicidal efficiency is kept simultaneously.The rate of application for reducing these active constituents is also more environmentally-friendly.In addition, prior It is that the horizontal ability that the amount of the applied active constituent of reduction still reaches desired Fungicidally active simultaneously can be used for reducing Or prevent development of the targeted fungal to active constituent generation resistance.
Three kinds of Fungicidal active ingredients being used in the present invention are respectively in the art to the effect of plant growth It is known.They all disclose the Britain crop protection committee that is disclosed in (The British Crop Protection Killing harmful organism handbook (The Pesticides Manual) Council.), in the 12nd edition, 2000.Many Compound or commercially available.
The present invention uses carboxamide fungicides.In the art for suitable benzamide compound in the present invention It is known and many of these kind is commercially available.Suitable benzamide compound with Fungicidally active includes benzene Base-benzamide, such as benodanil, flutolanil and mebenil；Thiophene-carboxamides, such as isopropyl metsulfovax；Pyridyl group-alkyl-benzene Formamide, such as fluopyram；Furans-formamide, such as fenfuram；Oxathiin-formamide (oxathin- ), such as carboxin and oxycarboxin carboxamide；Thiazole carboxamides, such as thifluzamide；Pyrazolecarboxamide, such as benzene And alkene fluorine bacterium azoles, biphenyl pyrrole bacterium amine, fluxapyroxad, furametpyr, isopyrazam, fluorine azoles bacterium aniline, pyrrole metsulfovax and fluorine Azoles ring bacterium amine；And pyridine-2-carboxamide, such as Boscalid.
Present invention discover that pyridine carboxamide is especially effective in the present invention.Boscalid be used in the present invention it is special Preferred formamide.
The present invention further uses strobilurin fungicide.Suitable strobilurin fungicide reactive compound is Known in the art and many kind is commercially available.Suitable strobilurin compound packet with Fungicidally active Include strobilurin fungicide, such as fluoxastrobin and Man Duo bacterium ester (mandestrobin)；Methoxy acrylic is thermophilic Cone umbrella element fungicide, for example, nitrile Fluoxastrobin, must fluorine bacterium ester (bifujunzhi), coumoxystrobin, Enestroburin, fluorine bacterium mite Ester, first fragrant bacterium ester (jiaxiangjunzhi), ZEN 90160 and pyraoxystrobin；Methoxybenzene carbamate class strobilurins kill Epiphyte pharmaceutical, such as pyraclostrobin, azoles amine bacterium ester and chlorine nalidixic bacterium ester；Methoxyimino acetic amide class strobilurin fungicide Agent, such as dimoxystrobin, alkene oxime amine, SSF 126 and orysastrobin；It is killed with methoxyimino acetate esters strobilurins Epiphyte pharmaceutical, such as kresoxim-methyl and trifloxystrobin.
Preferred strobilurin fungicide is methoxy acrylic strobilurin fungicide and methoxyl group Carbanilic acid esters strobilurin fungicide.ZEN 90160 is the thermophilic cone umbrella of particularly preferred methoxy acrylic Plain fungicide.Pyraclostrobin is particularly preferred methoxybenzene carbamate class strobilurin fungicide.
The present invention further uses triazole antifungal agents.Suitable triazole Fungicidal active compound is known in the art And many of these kinds are commercially available.Suitable triazole compounds with Fungicidally active include amisulbrom, connection Benzotriazole alcohol, fluotrimazole, triazbutil and health azoles triazole, for example, azaconazole, bromuconazole, ciproconazole, diclobutrazol, Difenoconazole, olefin conversion, olefin conversion-M, epoxiconazole, etaconazole, benzoxazole, Fluquinconazole, Flusilazole, Flutriafol, Fluconazole, Furconazole_cis, hexaconazole, ciproconazole (huanjunzuo), glyoxalin, kind bacterium azoles, metconazole, nitrile bacterium azoles, penconazole, propiconazole, third Sulphur bacterium azoles, chlorobenzene quinoline azoles (quinconazole), simeconazoles, Tebuconazole, tetrachloro ether azoles, triazolone, Triadimenol, triticonazole, alkene Imitate azoles and uniconazole P-P (uniconazole-P).
It is health azoles triazole it is preferable to use the triazole antifungal agents in the present invention.Prothioconazoles are particularly preferably to be used in Triazole in the present invention.
In a particularly preferred embodiment, the present invention uses Boscalid, ZEN 90160 and/or pyrazoles ether bacterium The combination of ester and prothioconazoles.
In the present compositions, benzamide compound is preferably pressed following amount and is existed: by weight from 2% to 35%, more preferably from 3% to 30%, and more preferably by weight from 4% to 25%.In the composition by weight from 5% to 24% formamide is particularly preferred.
In the present compositions, strobilurin compound is preferably pressed following amount and is existed: by weight from 2% to 35%, more preferably from 5% to 30%, and more preferably by weight from 4% to 25%.In the composition by weight from 7% to 21% strobilurin compound is particularly preferred.
In the present compositions, triazole compounds are preferably pressed following amount and are existed: by weight from 2% to 45%, More preferably from 3% to 40%, and more preferably by weight from 4% to 35%.In the composition by weight from 6% to 30% triazole compounds are particularly preferred.
Benzamide compound, strobilurin compound and triazole compounds can be by any of the above-mentioned synergistic effect of offer Weight ratio is present in composition or for the present invention.Preferably, benzamide compound, thermophilic cone umbrella are used by following weight ratio Plain compound and triazole compounds: from 0.5 to 3.0 formamide: from 0.5 to 4.0 strobilurins: the three of from 0.5 to 3.5 Azoles, more preferably from 0.75 to 2.5 formamide: from 0.75 to 3.5 strobilurins: 0.85 to 3.0 triazole, and it is more excellent The formamide of selection of land from 1.0 to 2.0: from 1.0 to 2.8 strobilurins: 1.2 to 2.5 triazole.Particularly preferred formamide Compound, strobilurin compound and triazole compounds weight ratio are then described in the specific example being listed below.
Composition of the invention can be prepared in a conventional manner and be provided with any suitable formulation, such as logical It crosses benzamide compound and strobilurin compound and triazole compounds together with one or more suitable for preparation type Auxiliary agent mixing.The suitable auxiliary agents that can be contained in composition of the present invention are all conventional preparation adjuvant or component, As one or more extenders, carrier, solvent, surfactant, stabilizer, defoaming agent, antifreezing agent, preservative, antioxidant, Colorant, thickener, solid adhesive agent and inert filler.This analog assistant is well known in the art, and is commercially available 's.Their purposes in the preparation of composition of the present invention are clear for those of ordinary skill in the art.
Preparation type suitable for composition of the present invention include soluble concentrate (SL), missible oil (EC), aqueous emulsion (EW), Microemulsion (ME), suspending agent (SC), oil-suspending agent (OD), suspension seed-coating agent (FS), water dispersible granules (WG), soluble granule (SG), wettable powder (WP), solvable pulvis (SP), granule (GR), microcapsulated granule (CG), granula subtilis (FG), big granula (GG), aqueous suspoemulsion (SE), microcapsule suspending agent (CS) and fine granule (MG).Following paragraphs will describe fungicide composite Exemplary formulation, including water dispersible granules (WG), suspending agent (SC), missible oil (EC), wettable powder (WP) and aqueous emulsion (EW).
The Fungicidal composition may include one or more inert fillers.This kind of inert filler is known in the art , and be commercially available.Suitable filler includes for example natural grinding mineral, such as kaolin, aluminium oxide, talcum, white Chalk, quartz, attapulgite, montmorillonite and diatomite；Or the grinding mineral of synthesis, such as the silicic acid of high degree of dispersion, aluminium oxide, Silicate and calcium phosphate and calcium monohydrogen phosphate.Suitable inert filler for particle includes for example, what is crushed and be classified is natural Mineral (such as calcite, marble, float stone, sepiolite and dolomite) or inorganic and organic abrasive material synthesis particle, even With the particle (such as sawdust, cocoanut shell, corncob and tobacco stem) of organic material.
Fungicidal composition of the invention optionally includes one or more surfactants, and one or more surfaces are living Property agent be preferably non-ionic, cationic and/or anionic in nature, and be have good emulsification, point Scattered and wetting characteristics surfactant mixture, this depends on the property for having reactive compound to be prepared.Suitable surface Activating agent is well known in the art, and is commercially available.
The surfactant can be ionic or non-ionic emulsifier, dispersing agent or wetting agent.It can be used Example is the salt of polyacrylic acid；Lignosulfonates；The salt of benzene sulfonic acid or naphthalene sulfonic acids；Ethylene oxide and fatty alcohol or and fatty acid Or the condensation polymer with fatty amine；Substituted phenol, especially alkyl phenol；Sulfosuccinate ester salt；Taurine derivatives, especially Alkyl taurine ester；Or polyethoxylated phenol or alcohol phosphate.When reactive compound and/or inert carrier and/or auxiliary agent/ When adjuvant final application carrier insoluble in water and for the composition is water, it usually needs at least one surface-active The presence of agent.
The example of suitable surfactant is oxyethylated (POE) sorbitan ester, such as POE (20) dehydration D-sorbite trioleate and oxyethylated (POE) sorbitol ester, such as six oleate of POE (40) D-sorbite.POE (20) sorbitan trioleate can be by the sale of UniqEMA trade mark entitled ATLAS G1086 and CIRRASOL G1086 Lower commercially available from.POE sorbitan ester and the combination of POE sorbitol ester allow the HLB of optimizing surface activating agent (hydrophilic Lipophilic balance) value, in order to obtain highest quality aqueous emulsion (minimum hanging drop) when the composition to be added in water.Compared with The aqueous emulsion of high-quality can typically reach best fungicide performance.
Suitable anionic surfactant can be both so-called soluble soaps and solvable synthetic surface reactive compound. The soap that can be used in the composition is alkali metal, alkaline-earth metal or higher fatty acids (C10-C22) be substituted ammonium salt or without Substituted ammonium salt, for example, the sodium salt or sylvite of oleic acid or stearic sodium salt or sylvite or natural acid mixture.
The amount for being present in the surfactant in composition will depend on the factors such as preparation type used.
Fungicidal composition of the present invention optionally further includes one or more polymer stabilizers.It can use Suitable polymeric stabilizers in the present invention include but is not limited to: polypropylene, polyisobutene, polyisoprene, monoolefine and Copolymer, polyacrylate, polystyrene, polyvinyl acetate, polyurethanes or the polyamide of alkadienes.It is suitable steady Determine agent to be well known in the art, and is commercially available.
It has been generally acknowledged that above-mentioned surfactant and polymer stabilizer assigns stability to the composition, this is allowed for Composition can be formulated, stores, transports and apply.
Suitable defoaming agent include normally can in agrochemical composition all substances for this purpose.Properly Defoaming agent be known in the art and be commercially available.Particularly preferred defoaming agent is dimethyl silicone polymer and perfluor The mixture of alkyl phosphoric acid, silicone defomaing agent that such as can be commercially available from GE or Compton (Compton).
The suitable organic solvent that can be used in these compositions can be selected from all conventional organic solvents, these routines Organic solvent can sufficiently dissolve one or more used reactive compounds.For active ingredient in composition of the present invention For object, suitable organic solvent is also known in the art.It can be mentioned that the following terms is as preferred: N- crassitude Ketone, n-octylpyrrolidone, cyclohexyl -1- pyrrolidones；Or paraffin hydrocarbon, isoparaffin, ring paraffin hydrocarbon and aromatic hydrocarbon it is mixed Close object, such as SOLVESSOTM200.Suitable solvent is commercially available.
Suitable preservative includes that all can normally be used in the agrochemical composition of this type for this purpose Substance and be equally well known in the art.The suitable preservative that can be mentioned that includes Tolylfluanid, such as(commercially available from Beyer Co., Ltd (Bayer AG)) and benzoisothiazolinone, such as(from Bayer Company (Bayer AG) is commercially available).
Suitable antioxidant is all substances that can be normally used in agrochemical composition for this purpose, such as originally Known to field.Preferably Butylated Hydroxytoluene.
Suitable thickener includes all substances that can be normally used in agrochemical composition for this purpose.Properly Thickener include, for example, xanthan gum, PVOH, cellulose and its derivates, hydrated silicate clay, aluminium-magnesium silicate or they Mixture.Furthermore such thickener is as is generally known in the art and is commercially available.
Fungicidal composition of the present invention can further include one or more solid adhesive agents.This kind of adhesive agent exists It is known in this field, and is commercially available.They include organic bond, these organic bonds include tackifier, Such as cellulose or the cellulose being substituted, natural and synthetic polymer in powder, particle or form crystal lattice and inorganic Adhesive, such as gypsum, silica or cement.
In addition, composition of the present invention can also include water according to preparation.
Formamide, strobilurins and triazole component are in composition of the invention, method and on the way using (use) Ratio, such as can be changed according to factors such as usage type, soil types, season, weather, edaphology, vegetation types, But make one or more benzamide compounds, one or more strobilurin compounds and one or more triazoles Object is closed to apply with effective quantity to provide desired effect.It can readily determine that by carrying out test for one group of given item The rate of application of the composition of part.
One or more benzamide compounds, one or more strobilurin compounds and one or more triazoles Close the rate of application of the total amount of object typically from about 50 grams/ha (g/ha) to about 1500g/ha, preferably from 100g/ha to In the range of 1000g/ha.In general, when using following compound favourable outcome will be obtained: from about 40g/ha to about 500g/ha, The benzamide compound of preferably about 50g/ha to about 300g/ha；From about 50g/ha to about 300g/ha, preferably from about 70g/ The strobilurin compound of ha to about 250g/ha；With from about 50g/ha to 500g/ha, preferably about 60g/ha to about 350g/ The triazole compounds of ha.When being used as benzamide compound, pyridine acyl bacterium preferably is applied by the ratio from 50g/ha to 240g/ha Amine.When being used as strobilurin fungicide, ZEN 90160 preferably is applied by the ratio from 70g/ha to 200g/ha, it is excellent Selection of land applies pyraclostrobin by the ratio from 70g/ha to 200g/ha.When prothioconazoles are used as triazole compounds, preferably Ground is by the ratio application from 60g/ha to 300g/ha.
It is directly (i.e. undiluted) using or after being diluted with suitable solvent (especially water) using as described above Such preparation can handle plant, plant part and/or its location and protect it by spraying, toppling over or submerge From the influence of fungal infection.It is usually preferable that these preparations can be diluted with water before administration.It can use in this field The method known applies these compositions and preparation.Method include coating, spraying, dipping, impregnate, injection, irrigate etc..
It can be by active component simultaneously and/or continuously, preferably with short time interval (such as on the same day) application In plant, plant part and/or its location for wishing to be controlled.Active component can be applied to plant in any order Object, one or more parts (such as leaf or seed) of the plant, and/or its location.Every kind of component can only be applied one Secondary or application is multiple.Preferably, repeatedly by each application in component, especially from 2 to 5 times.Can in any order by Active fungicidal component is applied to target plant, vegetable material or plant part or location.
It can be by any suitable form administration of active ingredients described above.Typically, as discussed above, it can incite somebody to action Active component is administered as preparation, i.e., comprising one or more active components together with other carrier, surfactant or Other are conventionally used for the composition of the adjuvant for promoting application together in preparation technique.
In the case that active component is administered simultaneously in the present invention, they can be used as the group comprising Fungicidally active component Object application is closed, these components can obtain the preparation source being individually separated and mix that (referred to as bucket is mixed in this case Object, instant, spray liquid or slurry) (optionally together with other pesticides) or these components can be used as list One preparation mixture source (referred to as premix, concentrate, preparation compound (or product)) and obtain (and optionally with Other pesticides mix), especially as composition of the present invention.
Composition, method and purposes of the invention can be used for preventing and/or controlling a series of fungal infection in plants.
These fungicidal components can be applied to any growth phase (including plant propagation material, such as plant of plant Son), be applied to sprout before (i.e. plant from soil sprout before period) plant location, be applied to sprouting after (i.e. plant After being sprouted in soil) or plant location or plant in two or more these stages.In one embodiment, By fungicidal component, the stage (i.e. seedling sprouts the stage between plant maturation) is applied to plant after sprouting the last stage and sprouting Object.In one embodiment, application includes seed treatment before sprouting.In one preferred embodiment, it will directly kill true Bacterium component is applied in the leaf portion (or leaf) of plant.
The compositions and methods of the invention are suitable for the extensive plant of process range.The plant that the usable present invention is handled Object includes cereal, such as wheat, barley, rye, oat, corn, rice, sorghum, triticale and respective crop；Beet, such as sugar Garden beet and fodder beet；Fruit, such as the operatic circle, drupe and mushy fruit (such as apple, grape, pears, Lee, peach, almond, cherry With citrus fruit (such as citrus, lemon, grape fruit and tangerine))；Berry, such as strawberry, raspberry and blackberry, blueberry；Leguminous plant, Such as beans, hyacinth bean, pea, soybean and peanut；Oilseed plant, such as rape, canola, leaf mustard and sunflower；Cucurbit Section, such as cucurbita pepo, cucumber and muskmelon；Vegetables, for example, spinach, romaine lettuce, asparagus, cabbage, carrot, tomato, potato, Pimiento and sprouts of vegetable vegetables (for example, garlic, leek and onion)；Ornamental plant, such as flower, shrub, broad leaf tree and evergreen tree (such as coniferals) and sugarcane.
The present invention is especially effective and useful in processing leguminous plant, fruit, cereal and Curcurbitaceae.When for handling When soybean, grape, wheat and cucumber, the present invention is very favorable.
Present invention prevention can be used and/or the fungal infection handled includes these in following: quasi- sausage Phoma (Allantophomopsis spp.), Alternaria (Alternaria spp.), fibert fungi (Anisogramma spp.), Ascochyta (Ascochyta spp.), aspergillus (Aspergillus spp.), Aureobasidium (Aureobasidium Spp.), Bipolaris (Bipolaris spp.), happiness golden sponge category (Blumeriella spp.), Botryosphaeria (Botryosphaeria spp.), Botrytis (Botrytis spp.), Cercospora (Cercospora spp.), Cladosporium (Cladosporium spp.), cochliobolus category (Cochilobolus spp.), sheath Phoma sp Pseudomonas (Coleophoma Spp.), colletotrichum (Colletotrichum spp.), Corynespora (Corynespora spp.), seat shell category (Diaporthe spp.), Asia are every spore shell category (Didymella spp.), Elsinoe (Elsinoe spp.), Erysiphe (Erysiphe spp.), prominent navel Helminthosporium (Exserohilum spp.), Fusarium (Fusarium spp.), Capsid protein (Fusicoccum spp.), gibberella category (Gibberella spp.), small cluster shell category (Glomerella spp.), Guignardia Belong to (Guignardia spp.), glue Rust (Gymnosporangium spp.), Helminthosporium (Helminthosporium Spp.), ball obstructs spore category (Kabatiella spp.), Leptosphaeria (Leptosphaeria spp.), Microsphaera (Microsphaera spp.), chain sclerotinia sclerotiorum belong (Monilinia spp.), mycosphaerella (Mycosphaerella spp.), Eye plaque category (Oculimacula spp.), powder spore category (Oidium spp.), Penicillium (Penicillium spp.), frost Mould category (Peronospora spp.), Phakopsora (Phakopsora spp.), Phomopsis (Phomopsis spp.), Phyllosticta (Phyllosticta spp.), capsule spore Pseudomonas (Physalospora spp.), section Chytridium (Physoderma Spp.), Phytophthora (Phytophthora spp.), Plasmopara (Plasmopara spp.), Podosphaera (Podosphaera spp.), pseudo-cercospora (Pseudocercospora spp.), false white enzyme category (Pseudoperonospora Spp.), handle rust belongs to (Puccinia spp.), Pyrenophora (Pyrenophora spp.), Rhizoctonia (Rhizoctonia Spp.), rhizopus (Rhizopus spp.), beak genuss (Rhynchosporium spp.), sclerotinia category (Sclerotinia Spp.), Septoria (Septoria spp.), hair mycosphaerella (Setosphaeria spp.), Sphaerotheca (Sphaerotheca spp.), the more born of the same parents Pseudomonas of shell (Stagonospora spp.), Stemphylium (Stemphylium spp.), Lid scab rust belongs to (Thekopsora spp.), Tranzschelia (Tranzschelia spp.), Uncinula (Uncinula Spp.), Uromyces (Uromyces spp.), tikka Pseudomonas (Valdensinia spp.), Venturia (Venturia Spp.), thermophilic fruit knife spore Pseudomonas (Wilsonomyces spp.) and connect Saksenaea (Zygophiala spp.).
Particularly, can be used present invention prevention and/or processing fungal infection be it is below these: quasi- sausage Phoma sp Spore (Allantophomopsis cytisporea), lycopod intend sausage Phoma sp bacterium (Allantophomopsis Lycopodina), melon alternaric bacteria (Alternaria cucumerina), apple alternaric bacteria (Alternaria mali), The short stalk of green onion alternaric bacteria (Alternaria porri), fibert east wilt (Anisogramma anomala), corn is mould (Aureobasidium zeae), southern corn leaf blight (Bipolaris maydis), leaf spot fungi (Blumeriella Jaapii), grape seat chamber bacterium (Botryosphaeria dothidea), blunt grape seat chamber bacterium (Botryosphaeria Obtuse), botrytis (Botrytis cinerea), peanut Cercospora bacteria (Cercospora arachidicola), beet Brown patch germ (Cercospora beticola), melon tail spore bacterium (Cercospora citrulina), Cercospora kikuchii (Cercospora kikuchii), Germ To Soybean Frogeye Leaf Spot (Cercospora sojina), sorghum leaf purple spot bacterium (Cercospora Sorghi), Gray Leaf Spot Pathogen (Cercospora zeae-maydis), cladosporium carpophilum (Cladosporium Carpophilum), hickory nut scab (Cladosporium caryigenums), standing grain cochliobolus (Cochilobolus Sativus), charcoal color spore chamber bacterium (Cochliobolus carbonum), different cochliobolus (Cochliobolus Heterostrophus), sheath Phoma sp der Pilz (Coleophoma empetri), sharp spore anthrax-bacilus (Colletotrichum Acutatum), potato anthrax bacteria (Colletotrichum coccodes), glue born of the same parents' anthrax-bacilus (Colletotrichum Gloeosporioides), standing grain raw anthrax-bacilus (Colletotrichum graminicola), melon anthrax (Colletotrichum orbiculare), tack anthrax-bacilus (Colletotrichum truncatum), how main rod spore mould Seat shell (Diaporthe phaseolum), Didymella bryoniae between (Corynespora cassiicola), Kidney bean (Didymella bryoniae), Elsinochrome (Elsinoe ampelina), two spore powdery mildews (Erysiphe Cichoracearum), specialized form wheat powdery mildew (Erysiphe graminis f.sp.tritici), the leaf blight of corn Bacterium (Exserohilum turcicum), blueberry end maize ear rot bacterium (Fusicoccum putrefaciens), apple anthrax bacteria (Glomerella cingulate), grape Guignardia (Guignardia bidwellii), Wen Quince aecidium (Gymnosporangium clavipes), America rust of apple (Gymnosporangium yamadai) bacterium (Gymnosporangium juniperi- Virginianae), maize ball obstructs spore bacterium (Kabatiella zeae), rape black shank bacterium (Leptosphaeria Biglobosa), real-time fluorescent RCR ulcer bacteria (Leptosphaeria maculans), Monilinia fructicola (Winter) Honey (Monilinia fructicola), drupe chain sclerotinia sclerotiorum (Monilinia laxa), angle spot spherical cavity bacterium (Mycosphaerella Angulate), strawberry spherical cavity bacterium (Mycosphaerella fragariae), apple fruit black spot bacterium (Mycosphaerella Pomi), cereal eye spot bacterium (Oculimacula acuformis), wheat Phyllostachys pubescens (Oculimacula Yallundae), shallot downy mildew (Peronospora destructor), downy mildew bacterium (Peronospora Manshurica), Phakopsora pachyrhizi (Phakopsora pachyrhizi), cowpox Phomopsis (Phomopsis Vaccinia), grape branch-rot bacterium (Phomopsis viticola), maize phyllosticta (Phyllosticta maydis), Cowpox phyllosticta (Phyllosticta vaccinia), cowpox capsule spore bacterium (Physalospora vaccinia), maize section Chytrid (Physoderma maydis), Phytophthora nicotianae germ (Phytophthora nicotianae), Plasmopara viticola (Plasmopara viticola), white cross hair list softgel shell (Podosphaera leucotricha), brown spot of grape bacterium (Pseudocercospora vitis), bacterium of downy mildew of cucumber (Pseudoperonospora cubensis), humulus grass vacation downy mildew (Pseudoperonospora humuli), Puccina sorghi (Puccinia sorghi), peanut handle rest fungus (Puccinia Arachidis), standing grain hat handle rest fungus (Puccinia coronata), corn rust bacterium (Puccinia polyspora), concealment Handle rest fungus (Puccinia recondata), corn rust bacterium (Puccinia sorghi), circle nuclear cavity bacteria (Pyrenophora Teres), couchgrass nuclear cavity bacteria (Pyrenophora tritici-repentis), Rhizoctonia solani Kuhn (Rhizoctonia Solani), barley leaf blotch bacterium (Rhynchosporium secalis), sclerotinite (Sclerotinia Sclerotiorum), Sclerotium rolfsii (Sclerotium rolfsii), soybean septoria musiva (Septoria glycines), leaf Blight bacterium (Septoria tritici), Exserohilum turcicum (Setosphaeria turcica), monofilament shell powdery mildew (Sphaerotheca fuliginea), thin careless monofilament shell bacterium (Sphaerotheca humuli), strawberry powdery mildew (Sphaerotheca macularis), the more spores of wheat shell (Stagonosora nodorum), expansion crawl handle are mould (Stemphylium vesicarium), blueberry leaf rust bacterium (Thekopsora minima), the double born of the same parents' aecidiums of wart (Tranzschelia discolor), grape snag shell (Uncinula necator), tikka sclerotinite (Valdensinia Heterodoxa), black star germ (Venturia inaequalis), pear cucumerinum (Venturia pirina), thermophilic fruit knife Spore bacterium (Wilsonomyces carpophilus) and fly excrement germ (Zygophiala jamaicensis).
For example, it present invention can be advantageously used in prevention and/or handle the following fungal infection of berry: by rod method Alternaria leaf spot and fruit rot caused by species；The anthrax as caused by colletotrichum species or Elsinochrome species Disease；The Botrytis gray mold as caused by botrytis；The leaf spot as caused by mycosphaerella species or Septoria species and Scar spot；Chain sclerotinia sclerotiorum belong wilt disease and mummy berry as caused by chain sclerotinia sclerotiorum species；As caused by Phomopsis species Phomopsis leaf spot, branch-rot and fruit rot；As caused by Sphaerotheca species, Microsphaera species or powder spore species Powdery mildew；As Asia brachyplast wilt disease caused by spore shell species or Phoma species；By blueberry leaf rust bacterium or tikka bacterium Caused leaf rust；Leaf spot in the blueberry as caused by tikka sclerotinite；With by sheath Phoma sp der Pilz, mango anthrax bacteria (Glomerella cingulata), cowpox phyllosticta (Phyllosticta vaccinii), cowpox capsule spore bacterium (Physalospora vaccinii), lycopod intend sausage Phoma sp bacterium, quasi- sausage Phoma sp spore, blueberry end maize ear rot bacterium (Fusicoccum putrefaciens), Penicillium species, cowpox Phomopsis (Phomopsis vaccinii), sharp spore Fruit rot in short youngberry (in addition to strawberry) caused by anthrax-bacilus or potato anthrax bacteria.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungi of bulb vegetable Infection: the Botrytis leaf blight as caused by Botrytis species；The Botrytis neck rot as caused by Botrytis species；By Purple spot caused by green onion alternaric bacteria and leaf blight；By the mould caused Stemphylium leaf blight of expansion crawl handle and stalk rot；With by Downy mildew caused by shallot downy mildew.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungal infection of carrot: The Alternaria leaf spot as caused by Alternaria；The Cercospora leaf spot as caused by Cercospora；It is white as caused by Erysiphe Powder disease；With the south root rot as caused by Sclerotium rolfsii.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungi of cucurbitaceae vegetable Infection: by the microbial downy mildew of cucumber downy mildew；The Alternaria wilt disease as caused by melon alternaric bacteria；By melon tail spore bacterium Caused Cercospora leaf spot；By the microbial blight dis-ease of watermelon grafting；Drawn by monofilament shell powdery mildew or cucumber powdery mildew's pathogen The powdery mildew risen；The anthracnose as caused by melon anthrax；With Fusarium wilt disease and sickle-like bacteria as caused by Fusarium Belong to wilt disease.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungal infection of grape: by The microbial angular leaf spot of angle spot spherical cavity；The anthracnose as caused by Elsinochrome；The black rot as caused by grape Guignardia；By grape Downy mildew caused by Pseudoperonospora cubensis；By the microbial leaf blight of brown spot of grape；By the microbial Phomopsis of grape branch-rot Belong to sugarcane and leaf spot；The powdery mildew as caused by grape snag shell；The anthracnose as caused by glue born of the same parents' anthrax-bacilus；By Cladosporium or song Summer fruit rot (sour rot) caused by mould category；With the Botrytis gray mold as caused by botrytis.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungal infection of hops: The downy mildew as caused by humulus grass vacation downy mildew；With by cucumber powdery mildew's pathogen, thin careless monofilament shell bacterium, strawberry powdery mildew or Sphaerotheca Caused powdery mildew.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungal infection of American pistachios: The alternariosis late blight as caused by Alternaria；The flower of the Botrytis as caused by botrytis and spray wilt disease；With by Portugal Fringe caused by grape ulcer bacteria and spray wilt disease.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungal infection of the operatic circle: by Alternaria scar spot caused by apple alternaric bacteria；The scab of apple as caused by black star germ；The hardship as caused by colletotrichum Maize ear rot；By the microbial black rot/Frogeye Leaf Spot of blunt grape seat chamber；The penicilliosis as caused by Penicillium；By apple stain Germ Brooks (Brooks) spot；By the germ fly dung spot of fly excrement；The gray mold as caused by Botrytis； By the microbial pear scab of pear scab；The powdery mildew as caused by white cross hair list softgel shell；By the microbial coal of grape ulcer Dirty disease, white rot；By the microbial Chinese juniper glue rust of America rust of apple (Gymnosporangium yamadai)；He citrus rust as caused by Wen Quince aecidium.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungal infection of drupe: by Alternaria leaf spot caused by Alternaria；The anthracnose as caused by colletotrichum；The blossom rot as caused by chain sclerotinia sclerotiorum belong； The brown rot as caused by chain sclerotinia sclerotiorum belong；The leaf spot as caused by leaf spot fungi；By Sphaerotheca, caused by Podosphaera Powdery mildew；The ripened fruit as caused by Monilinia fructicola (Winter) Honey, drupe chain sclerotinia sclerotiorum, botrytis or rhizopus is rotted Disease；The rust as caused by wart double born of the same parents' aecidiums；The shot hole as caused by cladosporium carpophilum；With by the thermophilic microbial moth of fruit knife spore Hole.
By other examples, the following fungi sense of prevention and/or the woody nut of processing present invention can be advantageously used in Dye: the Alternaria leaf spot as caused by Alternaria；The anthracnose as caused by colletotrichum；The flower as caused by chain sclerotinia sclerotiorum belong Maize ear rot；The east hazel epidemic disease as caused by the wilt of fibert east；The leaf rust as caused by wart double born of the same parents' aecidiums；By thermophilic fruit branch spore Shot hole caused by mould or black star germ；The green fruit rot disease as caused by botrytis；With it is microbial by thermophilic fruit knife spore Cavity.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungal infection of barley: by Diplostomiasis caused by Alternaria or Helminthosporium；By the microbial powdery mildew of specialized form wheat powdery mildew；By the more born of the same parents Pseudomonas of shell Or leaf blight caused by Septoria and bran blight；Rust caused by being belonged to by handle rust；The spot blight as caused by standing grain cochliobolus；By Brown spot caused by couchgrass nuclear cavity bacteria；Head blight and shot hole as caused by Fusarium (Fusarium spp.)；By circle core The microbial net blotch of chamber；By the microbial brown stain disease of barley leaf blotch；Or by wheat Phyllostachys pubescens (Oculimacula ) or the microbial eye spot of cereal eye spot yallundae.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungal infection of wheat: by Diplostomiasis caused by Alternaria or Helminthosporium；By the microbial powdery mildew of specialized form wheat powdery mildew；By the more born of the same parents Pseudomonas of shell Or leaf blight caused by Septoria and bran blight；Rust caused by being belonged to by handle rust；The spot blight as caused by standing grain cochliobolus；By Brown spot caused by couchgrass nuclear cavity bacteria；The head blight as caused by Fusarium and shot hole；The bran as caused by wheat shell more spores Blight；Speckled leaf blotch caused by lipoxygenase；With the leaf rust as caused by Puccinia recondita.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungal infection of oat: by Diplostomiasis caused by Alternaria or Helminthosporium；By the microbial powdery mildew of specialized form wheat powdery mildew；By the more born of the same parents Pseudomonas of shell Or leaf blight caused by Septoria and bran blight；Rust caused by being belonged to by handle rust；The spot blight as caused by standing grain cochliobolus；By Brown spot caused by couchgrass nuclear cavity bacteria；Crown rust caused by handle rest fungus is preced with as standing grain and by the microbial eye spot of cereal eye spot Disease.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungal infection of sorghum: by Anthracnose caused by the raw anthrax-bacilus of standing grain；By the microbial gray leaf spot of sorghum leaf purple spot；It becomes rusty with as caused by Puccina sorghi Disease.
By other examples, it present invention can be advantageously used in prevention and/or handle the following true of rye and triticale Bacterium infection: the diplostomiasis as caused by Alternaria or Helminthosporium；By the microbial powdery mildew of specialized form wheat powdery mildew；By shell Leaf blight caused by more born of the same parents Pseudomonas or Septoria and bran blight；Rust caused by being belonged to by handle rust；As caused by standing grain cochliobolus Spot blight；The brown spot as caused by couchgrass nuclear cavity bacteria；The head blight as caused by Fusarium and shot hole；Draw with being belonged to by handle rust The rust risen.
By other examples, present invention can be advantageously used in prevention and/or handle pearl millet, broomcorn millet or teosinte with Lower fungal infection: the head blight as caused by Fusarium or shot hole, and caused rust is belonged to by handle rust.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungal infection of corn: by Anthracnose leaf blight and stalk rot caused by the raw anthrax-bacilus of standing grain；By the short stalk of corn, mould, maize ball obstructs spore bacterium (Kabatiella Zeae eye spot caused by)；By the microbial gray leaf spot of grey leaf spot disease of maize；The leaf spot as caused by Alternaria；By leaf Pinta bacterium or the microbial northern com leaf blight of the leaf blight of corn；By the microbial northern com leaf spot of charcoal color spore chamber；By Maize, which is saved, saves Chytridium brown spot caused by chytrid；The general rust as caused by corn handle rest fungus；Caused by corn rust bacterium Southern rust；By different cochliobolus or the microbial southern corn leaf blight of corn southern leaf blight；Caused by southern corn leaf blight Yellow leaf blight；Fusarium and gibberella category ear rot caused by being belonged to by Fusarium or gibberella；Obstructed by maize ball Eye spot caused by spore bacterium or the short stalk of corn are mould；With the stalk rot as caused by Fusarium, gibberella category or colletotrichum.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungi of canola Infection: the sclerotinia category stem rot as caused by sclerotinite；The Alternaria black spot as caused by Alternaria, leaf spot and stem spot Disease；With the black shin as caused by crucifer canker bacterium (Leptosphaeria maculans) or rape black shank bacterium Disease.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungi sense of leguminous vegetable Dye: Alternaria wilt disease and leaf spot as caused by Alternaria；The anthracnose as caused by colletotrichum；Drawn by Ascochyta The Ascochyta wilt disease and leaf spot risen；The Cercospora leaf spot as caused by Cercospora；By the germ frost of Phytophthora nicotianae Mildew；The mycosphaerella wilt disease as caused by mycosphaerella；The powdery mildew as caused by Erysiphe；It is become rusty by Uromyces or layer Rust caused by Pseudomonas；The Septoria scar spot as caused by Septoria；Belong to caused sclerotinia category rot disease with by sclerotinia And white mould.
By other examples, prevention and/or the following fungal infection of processed soybeans present invention can be advantageously used in: by The microbial air net wilt disease of miliary damping-off；The anthracnose as caused by tack anthrax-bacilus；The rod method as caused by Alternaria Belong to leaf spot；The brown spot as caused by soybean septoria musiva；By the microbial Cercospora wilt disease of purple spot of soybean and leaf spot and Purple spot；By the microbial downy mildew of downy mildew；By the microbial frog eye leaf spot of grey speck of soybean；By seat between Kidney bean Beanpod caused by shell and stem wilt disease；The powdery mildew as caused by Erysiphe；The rust as caused by handle rust category or Phakopsora；By Target spot caused by how main rod spore mould；The sclerotinia category stem rot as caused by sclerotinite；The rust of the soybean as caused by Phakopsora pachyrhizi Disease；With by the microbial frog eye leaf spot of grey speck of soybean.
By other examples, it present invention can be advantageously used in prevention and/or handle the following fungal infection of peanut: by The microbial Rhizoctonia pod rot of miliary damping-off；By the microbial early stage leaf spot of the cercospora brown spot of peanut；It becomes rusty with by peanut handle Microbial leaf rust.
In an embodiment of the invention, handled plant is selected from leguminous plant, fruit, cereal and Curcurbitaceae.
In yet another embodiment of the present invention, handled plant is selected from soybean, grape, wheat and cucumber.
As set forth above, it is possible to be used to handle a series of different fungal infections for composition of the invention, method and purposes. In an embodiment of the invention, fungal infection is selected from soybean rust, Botrytis gray mold and powdery mildew.
Embodiments of the present invention are further described by explanation in the following example.
In the following example, unless otherwise indicated, percentage is weight percent.
Example
When the effect of two or more active compounds, which is greater than, to be administered alone the effect of every kind of reactive compound When summation, the combination of both or more reactive compounds has synergistic effect.
It can be right by following " Colby (Cole's ratio) formula " (S.R.Colby, Weeds [weeds] 15,20-22,1967) The expection activity of the given combination of two kinds of reactive compounds is calculated:
E=A+B- (A × B/100) I
Wherein:
A=when with m (gram/ha, that is, g/ha) dosage use compound A when, percentage effect of compound A；
B=is when using compound B with the dosage of n (g/ha), percentage effect of compound B；
E=is when being used together compound A and B with the dosage of n (g/ha) with m (g/ha) respectively, the percentage function of estimation Effect.
It can be right by following " Colby (Cole's ratio) formula " (S.R.Colby, Weeds [weeds] 15,20-22,1967) The expection activity of the given combination of three kinds of reactive compounds is calculated:
E=(A+B+C)-(A × B+A × C+B × C)/100+ (A × B × C/10000) II
Wherein:
A=is when using compound A with the dosage of m (g/ha), percentage effect of compound A；
B=is when using compound B with the dosage of n (g/ha), percentage effect of compound B；
C=is when using compound C with the dosage of p (g/ha), percentage effect of compound C；
E=is when being used together compound A and B and C with the dosage of p (g/ha) with m (g/ha), n (g/ha) respectively, estimation Percentage effect.
" it is expected that effect " value in the following table 7 to 10 is calculated based on above-mentioned Formula II.
The preparation of preparation
A) water dispersible granules (WG)
By by the active constituent of fine gtinding and auxiliary agent (0.5 weight %(NaLS), Wei Teke company (Witco Inc.), Greenwich (Greenwich)；5 weight %88B (sodium lignin sulfonate), dimension Shi Weike company (Westvaco Corp)；Potassium carbonate (balance to 100%)) it is mixed in compressed gas, it then soaks, squeezes simultaneously It is dried to obtain water dispersible granules (WG) in pneumatic convey drier.
Table 1 summarizes the embodiment of water-dispersible grain agent formulation of the invention.
Table 1
B) suspending agent (SC)
By by the active constituent of fine gtinding and auxiliary agent (the triphenylethylene base benzene of the propylene glycol of 10 weight %, 5 weight % Phenol ethoxylate, the sodium lignin sulfonate of 1 weight %, the carboxymethyl cellulose of 1 weight %, 1 weight % silicone oil (with 75 The form of the aqueous emulsion of weight %), the xanthan gum of 0.1 weight %, NIPACIDE BIT20 of 0.1 weight %, water (balance extremely 100 weight %)) it mixes to prepare suspending agent (SC).
Table 2 summarizes the embodiment of aqueous suspension agent of the invention.
Table 2
Component % by weight
Boscalid 7.5
ZEN 90160 21
Prothioconazoles 11.25
Propylene glycol 10
Tristyrylphenol ethoxylates 5
Sodium lignin sulfonate 1
Carboxymethyl cellulose 1
Silicone oil (in the form of 75% aqueous emulsion) 1
Xanthan gum 0.1
NIPACIDE BIT 20 0.1
Water It balances to 100
C) missible oil (EC)
By by active constituent and auxiliary agent (50g tristyrylphenol ethoxylates, 1g silicone oil, 300g N- first Base -2-Pyrrolidone, SOLVESSOTM200 (balance to 1kg)) and mix to prepare missible oil (EC).
Table 3 summarizes the embodiment of missible oil of the invention.
Table 3
Component Weight (g)
Boscalid 50
ZEN 90160 70
Prothioconazoles 61.25
Tristyrylphenol ethoxylates 50
Silicone oil 1
N-methyl-2-pyrrolidone 300
SOLVESSOTM 200 It balances to 1000
D) wettable powder (WP)
By mixing the active constituent of fine gtinding, (50g Dispersogen 1494, (balance is extremely for kaolin with auxiliary agent 1000g)), Air mill is then carried out to prepare wettable powder (WP) by jet mill.
Table 4 summarizes the embodiment of wettable powder formulation of the invention.
Table 4
E) aqueous emulsion (EW)
By by the active constituent of fine gtinding and auxiliary agent (200g SOLVESSOTM200,50g EL360 (ethoxylation Soybean oil), (balance to 100 weight %)) mixes to prepare aqueous emulsion for 30g 70B (calcium dodecyl benzene sulfonate) and water (EW)。
Table 5 summarizes the embodiment of water and milk agent formulation of the invention.
Table 5
Component Weight (g)
Boscalid 75
ZEN 90160 210
Prothioconazoles 112.5
SOLVESSOTM 200 200
EL360 (soybean oil of ethoxylation) 50
70B (calcium dodecyl benzene sulfonate) 30
Water It balances to 1000
According to above method, with a certain amount of active constituent prothioconazoles and/or Boscalid and/or ZEN 90160 and/ Or pyraclostrobin prepares different preparations.As shown in embodiment 1 to 32, the details of preparation is as shown in table 6 below.
Table 6
WP=wettable powder；EC=missible oil；WG=water dispersible granules；SC=suspending agent；EW=aqueous emulsion.
In table 6, embodiment 10,11,17,18,24,25,31 and 32 is the example of the present composition.Remaining is implemented Example is proposed for being used as omparison purpose.
Biological example
Research about soybean-soybean rust (Phakopsora pachyrhizi)
Bean plant is sprayed with the conidial suspension of Phakopsora pachyrhizi, and in 20 DEG C and 100% relative atmospheric It cultivates to be incubated under damp condition and continues 48 hours.Then the composition spray prepared according to the embodiment 1 to 32 such as listed in table 6 Spill plant.
Then, it is kept for 10 days in the greenhouse by processed plant under the conditions of 15 DEG C and 80% relative atmospheric humidity, it The severity of fungal infection is assessed afterwards.Then measurement composition is the effect of handling in terms of fungal infection.
Result the effect of Fungicidal composition is listed in the following table 7.
It is in table 7 the result shows that, it is a kind of or only compared with the combined composition of two kinds of Fungicidal active ingredients with being used only, Fungicidal composition of the invention comprising Boscalid, ZEN 90160 or pyraclostrobin and prothioconazoles becomes rusty in processed soybeans It is more superior in terms of effect of disease.
Furthermore, the results showed that, the effect of composition of the invention, which is higher than, is based on 3- component Cole ratio (Colby) equation II Expection effect, it was demonstrated that the composition handle and/or prevent soybean rust in terms of show unexpected synergistic effect.
About the research of grape-Botrytis gray mold (botrytis)
Mattae is sprayed with the conidial suspension of the pathogen of Botrytis cinerea, and in 20 DEG C and 100% relative atmospheric It is cultivated under conditions of humidity and continues 48 hours.Then with the combination prepared according to the embodiment 1 to 32 such as listed in the above table 6 Object sprays plant.
After processing, plant is kept for 10 days in greenhouse under the conditions of 15 DEG C and 80% relative atmospheric humidity, is assessed later The severity of fungal infection.Then measurement composition is the effect of handling in terms of fungal infection.
Result the effect of Fungicidal composition is listed in the following table 8.
It is in table 8 the result shows that, and combined composition a kind of or using only two kinds of Fungicidal active ingredients is used only It compares, the Fungicidal composition of the invention comprising Boscalid, ZEN 90160 or pyraclostrobin and prothioconazoles is being handled It is more superior in terms of effect in Botrytis gray mold.
Furthermore, the results showed that, the effect of composition of the invention, is higher than based on 3- component Cole ratio (Colby) equation II It is expected that effect, it was demonstrated that the composition is handling and/or preventing to show unexpected synergistic effect in Botrytis gray mold.
Example 4
Research about wheat-powdery mildew (specialized form wheat powdery mildew)
Wheat plant is sprayed with the conidial suspension of specialized form wheat powdery mildew, and at 20 DEG C and 100% It is cultivated under conditions of relative atmospheric humidity and continues 48 hours.Then it is prepared with according to the example 1 to 32 such as listed in the above table 6 Composition sprayed plant.
Then, it is kept for 10 days in the greenhouse by processed plant under the conditions of 15 DEG C and 80% relative atmospheric humidity, it The severity of fungal infection is assessed afterwards.The result the effect of Fungicidal composition of different preparations is listed in following table 9.
It is in table 9 the result shows that, it is a kind of or only compared with the combined composition of two kinds of Fungicidal active ingredients with being used only, Function of the Fungicidal composition comprising Boscalid, ZEN 90160 and/or pyraclostrobin and prothioconazoles in processing powdery mildew Efficacious prescriptions face is more superior.
Furthermore, the results showed that, the effect of composition of the invention, is higher than based on 3- component Cole ratio (Colby) equation It is expected that effect, display three-dimensional (three-way) composition shows unexpected association in terms of handling and/or preventing powdery mildew Same effect.
Research about cucumber-powdery mildew (monofilament shell powdery mildew)
Cucumber plant is sprayed with the conidial suspension of monofilament shell powdery mildew, and relatively large in 20 DEG C and 100% It is cultivated under conditions of air humidity degree and continues 48 hours.Then with the group prepared according to the embodiment 1 to 32 such as listed in the above table 6 It closes object and sprays plant.
Then, it is kept for 10 days in the greenhouse by processed plant under the conditions of 15 DEG C and 80% relative atmospheric humidity, it The severity of fungal infection is assessed afterwards.The result the effect of Fungicidal composition of different preparations is listed in following table 10 In.
It is in table 10 the result shows that, and a kind of or only combined composition phase of two kinds of Fungicidal active ingredients is used only Than the Fungicidal composition comprising Boscalid, ZEN 90160 and/or pyraclostrobin and prothioconazoles is in processing powdery mildew It is more superior in terms of effect.
In addition, result illustrates, the effect of composition of the invention, is higher than based on 3- component Cole ratio (Colby) equation It is expected that effect, shows that these compositions show unexpected synergistic effect in terms of handling and/or preventing powdery mildew.
Therefore exemplary embodiments of the present invention are described in detail.Although the description is related to specific embodiment, It is it will be apparent to one skilled in the art that can use the modification of these details to practice the present invention.Therefore, the present invention does not answer It is construed as limited to embodiment described in this paper.

Claims (81)

1. a kind of Fungicidal composition, the composition includes that carboxamide fungicides, strobilurin fungicide and triazole are killed Epiphyte pharmaceutical.
2. composition according to claim 1, wherein the carboxamide fungicides be phenyl-benzamide, thiophene-carboxamides, Pyridyl group-alkyl-benzamide, furans-formamide, oxathiin-formamide, thiazole carboxamides, pyrazolecarboxamide, Or pyridine-2-carboxamide.
3. composition according to claim 2, wherein the carboxamide fungicides are selected from the following terms: benodanil, fluorine acyl Amine and mebenil；Isopropyl metsulfovax；Fluopyram；Fenfuram；Carboxin and oxycarboxin；Thifluzamide；Benzo alkene Fluorine bacterium azoles, biphenyl pyrrole bacterium amine, fluxapyroxad, furametpyr, isopyrazam, fluorine azoles bacterium aniline, pyrrole metsulfovax and fluorine azoles ring Bacterium amine；And Boscalid.
4. composition according to claim 1 or 2, wherein the carboxamide fungicides are pyridine carboxamides.
5. composition according to claim 4, wherein the carboxamide fungicides are Boscalids.
6. composition according to any preceding claims, wherein the strobilurin fungicide be strobilurins, Methoxy acrylic strobilurins, methoxybenzene carbamate class strobilurins, methoxyimino acetic amide Class strobilurins or methoxyimino acetate esters strobilurins.
7. composition according to claim 6, wherein the strobilurin fungicide is selected from fluoxastrobin and Man Duo bacterium Ester；Nitrile Fluoxastrobin, must fluorine bacterium ester, coumoxystrobin, Enestroburin, fluorine bacterium mite ester, first fragrant bacterium ester, ZEN 90160 and pyraoxystrobin；Hundred Triprolidine Hydrochloride, azoles amine bacterium ester and chlorine nalidixic bacterium ester；Dimoxystrobin, alkene oxime amine, SSF 126 and orysastrobin；Kresoxim-methyl and trifloxystrobin.
8. composition according to claim 6 or 7, wherein the strobilurin fungicide is methoxy acrylic Strobilurins.
9. composition according to claim 8, wherein the strobilurin fungicide is ZEN 90160.
10. composition according to claim 6 or 7, wherein the strobilurin fungicide is methoxybenzene amino first Esters of gallic acid strobilurins.
11. composition according to claim 10, wherein the strobilurin fungicide is pyraclostrobin.
12. composition according to any preceding claims, wherein the triazole antifungal agents are selected from amisulbrom, biphenyl Triadimenol, fluotrimazole, triazbutil and health azoles triazole.
13. composition according to claim 12, wherein the triazole antifungal agents are health azoles triazoles.
14. composition according to claim 13, wherein the triazole antifungal agents are health azoles triazoles selected from the following: A Zha Health azoles, bromuconazole, ciproconazole, diclobutrazol, difenoconazole, olefin conversion, olefin conversion-M, epoxiconazole, etaconazole, nitrile benzene Azoles, Fluquinconazole, Flusilazole, Flutriafol, Fluconazole, furconazole_cis, hexaconazole, ciproconazole, glyoxalin, kind bacterium azoles, metconazole, nitrile bacterium Azoles, penconazole, propiconazole, prothioconazoles, chlorobenzene quinoline azoles, simeconazoles, Tebuconazole, tetrachloro ether azoles, triazolone, Triadimenol, sterilizing Azoles, uniconazole P and uniconazole P-P.
15. composition according to claim 14, wherein the triazole antifungal agents are prothioconazoles.
16. composition according to any preceding claims, wherein the carboxamide fungicides with by weight from 2% to 35% amount exists.
17. composition according to claim 16, wherein the carboxamide fungicides are with by weight from 4% to 25% Amount exists.
18. composition according to claim 17, wherein the carboxamide fungicides are with by weight from 5% to 24% Amount exists.
19. composition according to any preceding claims, wherein the strobilurin fungicide with by weight from 2% to 35% amount exists.
20. composition according to claim 19, wherein the strobilurin fungicide with by weight from 4% to 25% amount exists.
21. composition according to claim 20, wherein the strobilurin fungicide with by weight from 7% to 21% amount exists.
22. composition according to any preceding claims, wherein the triazole antifungal agents with by weight from 2% to 45% amount exists.
23. composition according to claim 22, wherein the triazole antifungal agents are with by weight from 4% to 35% amount In the presence of.
24. composition according to claim 23, wherein the triazole antifungal agents are with by weight from 6% to 30% amount In the presence of.
25. composition according to any preceding claims, wherein pressing from 0.5 to 3.0 formamide: from 0.5 to 4.0 Strobilurins: the weight ratio of from 0.5 to 3.5 triazole using the carboxamide fungicides, the strobilurin fungicide, With the triazole antifungal agents.
26. composition according to claim 25, wherein pressing from 0.75 to 2.5 formamide: from 0.75 to 3.5 thermophilic ball Fruit umbrella element: the weight ratio of 0.85 to 3.0 triazole using the carboxamide fungicides, the strobilurin fungicide and this three Azoles fungicide.
27. composition according to claim 26, wherein pressing from 1.0 to 2.0 formamide: from 1.0 to 2.8 thermophilic cone Umbrella element: the weight ratio of 1.2 to 2.5 triazole uses the carboxamide fungicides, the strobilurin fungicide and the triazole Fungicide.
28. composition according to any preceding claims, the composition further includes one kind selected from the following terms Or a variety of auxiliary agents: extender, carrier, solvent, surfactant, stabilizer, defoaming agent, antifreezing agent, preservative, antioxidant, Colorant, thickener, solid adhesive agent and inert filler.
29. composition according to any preceding claims, wherein the composition be soluble concentrate (SL), missible oil (EC), Aqueous emulsion (EW), microemulsion (ME), suspending agent (SC), oil-suspending agent (OD), suspension seed-coating agent (FS), water dispersible granules (WG), Soluble granule (SG), wettable powder (WP), solvable pulvis (SP), granule (GR), microcapsulated granule (CG), granula subtilis (FG), Big granula (GG), aqueous suspoemulsion (SE), microcapsule suspending agent (CS) or fine granule (MG).
30. a kind of method for controlling mycotic infection of plant, this method includes to these plants, to one or more portion Divide or applies carboxamide fungicides, strobilurin fungicide and triazole antifungal agents to its location.
31. according to the method for claim 30, wherein pressing from 0.5 to 3.0 formamide: from 0.5 to 4.0 thermophilic cone umbrella Element: the weight ratio of from 0.5 to 3.5 triazole uses the carboxamide fungicides, the strobilurin fungicide and the triazole Fungicide.
32. according to the method for claim 31, wherein pressing from 0.75 to 2.5 formamide: from 0.75 to 3.5 thermophilic cone Umbrella element: the weight ratio of 0.85 to 3.0 triazole uses the carboxamide fungicides, the strobilurin fungicide and the triazole Fungicide.
33. according to the method for claim 32, wherein pressing from 1.0 to 2.0 formamide: from 1.0 to 2.8 thermophilic cone umbrella Element: the weight ratio of 1.2 to 2.5 triazole is killed using the carboxamide fungicides, the strobilurin fungicide and the triazole Epiphyte pharmaceutical.
34. the method according to any one of claim 30 to 33, wherein the carboxamide fungicides are phenyl-benzoyls Amine, thiophene-carboxamides, pyridyl group-alkyl-benzamide, furans-formamide, oxathiin-formamide, thiazole formyl Amine, pyrazolecarboxamide or pyridine-2-carboxamide.
35. according to the method for claim 34, wherein the carboxamide fungicides are selected from the following terms: benodanil, fluorine acyl Amine and mebenil；Isopropyl metsulfovax；Fluopyram；Fenfuram；Carboxin and oxycarboxin；Thifluzamide；Benzo alkene Fluorine bacterium azoles, biphenyl pyrrole bacterium amine, fluxapyroxad, furametpyr, isopyrazam, fluorine azoles bacterium aniline, pyrrole metsulfovax and fluorine azoles ring Bacterium amine；And Boscalid.
36. the method according to claim 34 or 35, wherein the carboxamide fungicides are pyridine carboxamides.
37. according to the method for claim 36, wherein the carboxamide fungicides are Boscalids.
38. the method according to any one of claim 30 to 37, wherein the strobilurin fungicide is thermophilic cone Umbrella element, methoxy acrylic strobilurins, methoxybenzene carbamate class strobilurins, methoxyimino second Amides strobilurins or methoxyimino acetate esters strobilurins.
39. according to the method for claim 38, wherein the strobilurin fungicide is selected from fluoxastrobin and Man Duo bacterium Ester；Nitrile Fluoxastrobin, must fluorine bacterium ester, coumoxystrobin, Enestroburin, fluorine bacterium mite ester, first fragrant bacterium ester, ZEN 90160 and pyraoxystrobin；Pyrrole Azoles kresoxim-methyl, azoles amine bacterium ester and chlorine nalidixic bacterium ester；Dimoxystrobin, alkene oxime amine, SSF 126 and orysastrobin；Kresoxim-methyl and oxime bacterium Ester.
40. the method according to claim 38 or 39, wherein the strobilurin fungicide is methoxy acrylate Class strobilurins.
41. according to the method for claim 40, wherein the strobilurin fungicide is ZEN 90160.
42. the method according to claim 38 or 39, wherein the strobilurin fungicide is methoxybenzene amino first Esters of gallic acid strobilurins.
43. according to the method for claim 42, wherein the strobilurin fungicide is pyraclostrobin.
44. the method according to any one of claim 30 to 43, wherein the triazole antifungal agents be selected from amisulbrom, Bitertanol, fluotrimazole, triazbutil and health azoles triazole.
45. according to the method for claim 44, wherein the triazole antifungal agents are health azoles triazoles.
46. according to the method for claim 45, wherein the triazole antifungal agents are health azoles triazoles selected from the following: A Zhakang Azoles, bromuconazole, ciproconazole, diclobutrazol, difenoconazole, olefin conversion, olefin conversion-M, epoxiconazole, etaconazole, benzoxazole, Fluquinconazole, Flusilazole, Flutriafol, Fluconazole, furconazole_cis, hexaconazole, ciproconazole, glyoxalin, kind bacterium azoles, metconazole, nitrile bacterium azoles, Penconazole, propiconazole, prothioconazoles, chlorobenzene quinoline azoles, simeconazoles, Tebuconazole, tetrachloro ether azoles, triazolone, Triadimenol, triticonazole, Uniconazole P and uniconazole P-P.
47. according to the method for claim 46, wherein the triazole antifungal agents are prothioconazoles.
48. the method according to any one of claim 30 to 47, wherein the fungal infection for being controlled and/or being handled includes One of the following terms is a variety of: quasi- sausage Phoma (Allantophomopsis spp.), Alternaria (Alternaria spp.), fibert fungi (Anisogramma spp.), Ascochyta (Ascochyta spp.), aspergillus (Aspergillus spp.), Aureobasidium (Aureobasidium spp.), Bipolaris (Bipolaris spp.), happiness gold Sponge (Blumeriella spp.), Botryosphaeria (Botryosphaeria spp.), Botrytis (Botrytis Spp.), Cercospora (Cercospora spp.), Cladosporium (Cladosporium spp.), cochliobolus category (Cochilobolus spp.), sheath Phoma sp Pseudomonas (Coleophoma spp.), colletotrichum (Colletotrichum Spp.), Corynespora (Corynespora spp.), seat shell category (Diaporthe spp.), Asia are every spore shell category (Didymella Spp.), Elsinoe (Elsinoe spp.), Erysiphe (Erysiphe spp.), prominent navel Helminthosporium (Exserohilum Spp.), Fusarium (Fusarium spp.), Capsid protein (Fusicoccum spp.), gibberella category (Gibberella Spp.), small cluster shell category (Glomerella spp.), ball seat Pseudomonas (Guignardia spp.), glue Rust (Gymnosporangium spp.), Helminthosporium (Helminthosporium spp.), ball obstruct spore category (Kabatiella Spp.), Leptosphaeria (Leptosphaeria spp.), Microsphaera (Microsphaera spp.), chain sclerotinia sclerotiorum belong (Monilinia spp.), mycosphaerella (Mycosphaerella spp.), eye plaque category (Oculimacula spp.), powder Spore category (Oidium spp.), Penicillium (Penicillium spp.), Peronospora (Peronospora spp.), layer rest fungus Belong to (Phakopsora spp.), Phomopsis (Phomopsis spp.), Phyllosticta (Phyllosticta spp.), capsule Spore Pseudomonas (Physalospora spp.), section Chytridium (Physoderma spp.), Phytophthora (Phytophthora Spp.), Plasmopara (Plasmopara spp.), Podosphaera (Podosphaera spp.), pseudo-cercospora (Pseudocercospora spp.), false white enzyme category (Pseudoperonospora spp.), handle rust belong to (Puccinia Spp.), Pyrenophora (Pyrenophora spp.), Rhizoctonia (Rhizoctonia spp.), rhizopus (Rhizopus Spp.), beak genuss (Rhynchosporium spp.), sclerotinia category (Sclerotinia spp.), Septoria (Septoria spp.), hair mycosphaerella (Setosphaeria spp.), Sphaerotheca (Sphaerotheca spp.), shell More born of the same parents Pseudomonas (Stagonospora spp.), Stemphylium (Stemphylium spp.), lid scab rust belong to (Thekopsora Spp.), Tranzschelia (Tranzschelia spp.), Uncinula (Uncinula spp.), Uromyces (Uromyces spp.), tikka Pseudomonas (Valdensinia spp.), Venturia (Venturia spp.), thermophilic fruit knife spore bacterium Belong to (Wilsonomyces spp.) and connects Saksenaea (Zygophiala spp.).
49. according to the method for claim 48, wherein the fungal infection for being controlled and/or being handled includes in the following terms One or more: quasi- sausage Phoma sp spore (Allantophomopsis cytisporea), lycopod intend sausage Phoma sp bacterium (Allantophomopsis lycopodina), melon alternaric bacteria (Alternaria cucumerina), apple alternaric bacteria (Alternaria mali), green onion alternaric bacteria (Alternaria porri), fibert east wilt (Anisogramma Anomala), short stalk mould (Aureobasidium zeae), the southern corn leaf blight (Bipolaris maydis), leaf spot of corn Bacterium (Blumeriella jaapii), grape seat chamber bacterium (Botryosphaeria dothidea), blunt grape seat chamber bacterium (Botryosphaeria obtuse), botrytis (Botrytis cinerea), peanut Cercospora bacteria (Cercospora Arachidicola), sugar beet leaf spot bacteria (Cercospora beticola), melon tail spore bacterium (Cercospora Citrulina), Cercospora kikuchii (Cercospora kikuchii), Germ To Soybean Frogeye Leaf Spot (Cercospora sojina), Sorghum leaf purple spot bacterium (Cercospora sorghi), Gray Leaf Spot Pathogen (Cercospora zeae-maydis), thermophilic fruit branch spore Mould (Cladosporium carpophilum), hickory nut scab (Cladosporium caryigenums), standing grain revolve spore chamber Bacterium (Cochilobolus sativus), charcoal color spore chamber bacterium (Cochliobolus carbonum), different cochliobolus (Cochliobolus heterostrophus), sheath Phoma sp der Pilz (Coleophoma empetri), sharp spore anthrax-bacilus (Colletotrichum acutatum), potato anthrax bacteria (Colletotrichum coccodes), glue born of the same parents' anthrax-bacilus It is (Colletotrichum gloeosporioides), standing grain raw anthrax-bacilus (Colletotrichum graminicola), melon Anthrax-bacilus (Colletotrichum orbiculare), tack anthrax-bacilus (Colletotrichum truncatum), how main stick Seat shell (Diaporthe phaseolum), Didymella bryoniae between spore mould (Corynespora cassiicola), Kidney bean (Didymella bryoniae), Elsinochrome (Elsinoe ampelina), two spore powdery mildews (Erysiphe Cichoracearum), specialized form wheat powdery mildew (Erysiphe graminis f.sp.tritici), the leaf blight of corn Bacterium (Exserohilum turcicum), blueberry end maize ear rot bacterium (Fusicoccum putrefaciens), apple anthrax bacteria (Glomerella cingulate), grape Guignardia (Guignardia bidwellii), Wen Quince aecidium (Gymnosporangium clavipes), America rust of apple (Gymnosporangium yamadai) bacterium (Gymnosporangium juniperi- Virginianae), maize ball obstructs spore bacterium (Kabatiella zeae), rape black shank bacterium (Leptosphaeria Biglobosa), real-time fluorescent RCR ulcer bacteria (Leptosphaeria maculans), Monilinia fructicola (Winter) Honey (Monilinia fructicola), drupe chain sclerotinia sclerotiorum (Monilinia laxa), angle spot spherical cavity bacterium (Mycosphaerella Angulate), strawberry spherical cavity bacterium (Mycosphaerella fragariae), apple fruit black spot bacterium (Mycosphaerella Pomi), cereal eye spot bacterium (Oculimacula acuformis), wheat Phyllostachys pubescens (Oculimacula Yallundae), shallot downy mildew (Peronospora destructor), downy mildew bacterium (Peronospora Manshurica), Phakopsora pachyrhizi (Phakopsora pachyrhizi), cowpox Phomopsis (Phomopsis Vaccinia), grape branch-rot bacterium (Phomopsis viticola), maize phyllosticta (Phyllosticta maydis), Cowpox phyllosticta (Phyllosticta vaccinia), cowpox capsule spore bacterium (Physalospora vaccinia), maize section Chytrid (Physoderma maydis), Phytophthora nicotianae germ (Phytophthora nicotianae), Plasmopara viticola (Plasmopara viticola), white cross hair list softgel shell (Podosphaera leucotricha), brown spot of grape bacterium (Pseudocercospora vitis), bacterium of downy mildew of cucumber (Pseudoperonospora cubensis), humulus grass vacation downy mildew (Pseudoperonospora humuli), Puccina sorghi (Puccinia sorghi), peanut handle rest fungus (Puccinia Arachidis), standing grain hat handle rest fungus (Puccinia coronata), corn rust bacterium (Puccinia polyspora), concealment Handle rest fungus (Puccinia recondata), corn rust bacterium (Puccinia sorghi), circle nuclear cavity bacteria (Pyrenophora Teres), couchgrass nuclear cavity bacteria (Pyrenophora tritici-repentis), Rhizoctonia solani Kuhn (Rhizoctonia Solani), barley leaf blotch bacterium (Rhynchosporium secalis), sclerotinite (Sclerotinia Sclerotiorum), Sclerotium rolfsii (Sclerotium rolfsii), soybean septoria musiva (Septoria glycines), leaf Blight bacterium (Septoria tritici), Exserohilum turcicum (Setosphaeria turcica), monofilament shell powdery mildew (Sphaerotheca fuliginea), thin careless monofilament shell bacterium (Sphaerotheca humuli), strawberry powdery mildew (Sphaerotheca macularis), the more spores of wheat shell (Stagonosora nodorum), expansion crawl handle are mould (Stemphylium vesicarium), blueberry leaf rust bacterium (Thekopsora minima), the double born of the same parents' aecidiums of wart (Tranzschelia discolor), grape snag shell (Uncinula necator), tikka sclerotinite (Valdensinia Heterodoxa), black star germ (Venturia inaequalis), pear cucumerinum (Venturia pirina), thermophilic fruit knife Spore bacterium (Wilsonomyces carpophilus) and fly excrement germ (Zygophiala jamaicensis).
50. the method according to any one of claim 30 to 49, wherein the one or more formamides applied are antifungal The total amount of agent, one or more strobilurin fungicides and one or more triazole antifungal agents be from about 50g/ha to In the range of about 1500g/ha.
51. the method according to any one of claim 30 to 50, wherein should by the amount application from 40g/ha to 500g/ha Carboxamide fungicides.
52. the method according to any one of claim 30 to 51, wherein should by the amount application from 50g/ha to 300g/ha Strobilurin fungicide.
53. the method according to any one of claim 30 to 52, wherein should by the amount application from 50g/ha to 500g/ha Triazole antifungal agents.
54. the method according to any one of claim 30 to 53, wherein using according to claim 1 to any one of 29 The composition.
55. the method according to any one of claim 30 to 54, wherein the state and after sprouting during the stage before sprouting, These fungicide compositions are administered on these plants.
56. carboxamide fungicides, strobilurin fungicide and triazole antifungal agents are in control plant or plant part Purposes in fungal infection.
57. purposes according to claim 56, wherein pressing from 0.5 to 3.0 formamide: from 0.5 to 4.0 thermophilic cone umbrella Element: the weight ratio of from 0.5 to 3.5 triazole uses the carboxamide fungicides, the strobilurin fungicide and the triazole Fungicide.
58. purposes according to claim 57, wherein pressing from 0.75 to 2.5 formamide: from 0.75 to 3.5 thermophilic cone Umbrella element: the weight ratio of 0.85 to 3.0 triazole uses the carboxamide fungicides, the strobilurin fungicide and the triazole Fungicide.
59. purposes according to claim 58, wherein pressing from 1.0 to 2.0 formamide: from 1.0 to 2.8 thermophilic cone umbrella Element: the weight ratio of 1.2 to 2.5 triazole is killed using the carboxamide fungicides, the strobilurin fungicide and the triazole Epiphyte pharmaceutical.
60. the purposes according to any one of claim 56 to 59, wherein the carboxamide fungicides are phenyl-benzoyls Amine, thiophene-carboxamides, pyridyl group-alkyl-benzamide, furans-formamide, oxathiin-formamide, thiazole formyl Amine, pyrazolecarboxamide or pyridine-2-carboxamide.
61. purposes according to claim 60, wherein the carboxamide fungicides are selected from the following terms: benodanil, fluorine acyl Amine and mebenil；Isopropyl metsulfovax；Fluopyram；Fenfuram；Carboxin and oxycarboxin；Thifluzamide；Benzo alkene Fluorine bacterium azoles, biphenyl pyrrole bacterium amine, fluxapyroxad, furametpyr, isopyrazam, fluorine azoles bacterium aniline, pyrrole metsulfovax and fluorine azoles ring Bacterium amine；And Boscalid.
62. the purposes according to claim 60 or 61, wherein the carboxamide fungicides are pyridine carboxamides.
63. purposes according to claim 62, wherein the carboxamide fungicides are Boscalids.
64. the purposes according to any one of claim 56 to 63, wherein the strobilurin fungicide is thermophilic cone Umbrella element, methoxy acrylic strobilurins, methoxybenzene carbamate class strobilurins, methoxyimino second Amides strobilurins or methoxyimino acetate esters strobilurins.
65. purposes according to claim 64, wherein the strobilurin fungicide is selected from fluoxastrobin and Man Duo bacterium Ester；Nitrile Fluoxastrobin, must fluorine bacterium ester, coumoxystrobin, Enestroburin, fluorine bacterium mite ester, first fragrant bacterium ester, ZEN 90160 and pyraoxystrobin；Pyrrole Azoles kresoxim-methyl, azoles amine bacterium ester and chlorine nalidixic bacterium ester；Dimoxystrobin, alkene oxime amine, SSF 126 and orysastrobin；Kresoxim-methyl and oxime bacterium Ester.
66. the purposes according to claim 64 or 65, wherein the strobilurin fungicide is methoxy acrylate Class strobilurins.
67. purposes according to claim 66, wherein the strobilurin fungicide is ZEN 90160.
68. the purposes according to claim 66 or 67, wherein the strobilurin fungicide is methoxybenzene amino first Esters of gallic acid strobilurins.
69. purposes according to claim 68, wherein the strobilurin fungicide is pyraclostrobin.
70. the purposes according to any one of claim 56 to 69, wherein the triazole antifungal agents be selected from amisulbrom, Bitertanol, fluotrimazole, triazbutil and health azoles triazole.
71. purposes according to claim 70, wherein the triazole antifungal agents are health azoles triazoles.
72. purposes according to claim 71, wherein the triazole antifungal agents are health azoles triazoles selected from the following: A Zhakang Azoles, bromuconazole, ciproconazole, diclobutrazol, difenoconazole, olefin conversion, olefin conversion-M, epoxiconazole, etaconazole, benzoxazole, Fluquinconazole, Flusilazole, Flutriafol, Fluconazole, furconazole_cis, hexaconazole, ciproconazole, glyoxalin, kind bacterium azoles, metconazole, nitrile bacterium azoles, Penconazole, propiconazole, prothioconazoles, chlorobenzene quinoline azoles, simeconazoles, Tebuconazole, tetrachloro ether azoles, triazolone, Triadimenol, triticonazole, Uniconazole P and uniconazole P-P.
73. the purposes according to claim 72, wherein the triazole antifungal agents are prothioconazoles.
74. the purposes according to any one of claim 56 to 73, wherein the fungal infection for being controlled and/or being handled includes One of the following terms is a variety of: quasi- sausage Phoma, Alternaria, fibert fungi, Ascochyta, aspergillus, short handle Mould category, Bipolaris, happiness golden sponge category, Botryosphaeria, Botrytis, Cercospora, Cladosporium, cochliobolus category, sheath stem The mould category of point, colletotrichum, Corynespora, seat shell category, Asia are every spore shell category, Elsinoe, Erysiphe, prominent navel Helminthosporium, sickle Knife Pseudomonas, Capsid protein, gibberella category, small cluster shell category, ball seat Pseudomonas, glue Rust, Helminthosporium, ball obstruct spore category, small spherical cavity Pseudomonas, chain sclerotinia sclerotiorum belong, mycosphaerella, eye plaque category, powder spore category, Penicillium, white enzyme category, Phakopsora, is intended Microsphaera Phoma, Phyllosticta, capsule spore Pseudomonas, section Chytridium, Phytophthora, Plasmopara, Podosphaera, pseudo-cercospora, vacation White enzyme category, handle rust category, Pyrenophora, Rhizoctonia, rhizopus, beak genuss, sclerotinia category, Septoria, hair mycosphaerella, list The more born of the same parents Pseudomonas of softgel shell category, shell, Stemphylium, lid scab rust category, Tranzschelia, Uncinula, Uromyces, tikka bacterium Category, Venturia, thermophilic fruit knife spore Pseudomonas and connect Saksenaea.
75. purposes according to claim 74, wherein the fungal infection for being controlled and/or being handled includes in the following terms One or more: quasi- sausage Phoma sp spore, lycopod intend sausage Phoma sp bacterium, melon alternaric bacteria, apple alternaric bacteria, green onion chain lattice The short stalk of spore bacterium, fibert east wilt, corn mould, southern corn leaf blight, leaf spot fungi, grape ulcer bacterium, blunt grape seat Chamber bacterium, botrytis, peanut Cercospora bacteria, sugar beet leaf spot bacteria, melon tail spore bacterium, Cercospora kikuchii, Germ To Soybean Frogeye Leaf Spot, It is sorghum leaf purple spot bacterium, Gray Leaf Spot Pathogen, cladosporium carpophilum, Ka Liji pityrosporion ovale, standing grain cochliobolus, charcoal color spore chamber bacterium, different It is cochliobolus, sheath Phoma sp der Pilz, sharp spore anthrax-bacilus, potato anthrax bacteria, glue born of the same parents anthrax-bacilus, the raw anthrax-bacilus of standing grain, melon Seat shell, Didymella bryoniae, Elsinochrome, two spore powdery mildews, specialization between anthrax-bacilus, tack anthrax-bacilus, how main rod spore mould, Kidney bean Type wheat powdery mildew, Exserohilum turcicum, blueberry end maize ear rot bacterium, apple anthrax bacteria, grape Guignardia, Wen Quince aecidium, America rust of apple (Gymnosporangium yamadai) bacterium, maize ball stalk spore bacterium, rape black shank bacterium, crucifer canker bacterium, U.S. Australia type drupe are brown Maize ear rot bacterium, drupe chain sclerotinia sclerotiorum, angle spot spherical cavity bacterium, strawberry spherical cavity bacterium, apple fruit black spot bacterium, cereal eye spot bacterium, wheat-based are rotten Germ, shallot downy mildew, downy mildew bacterium, Phakopsora pachyrhizi, cowpox Phomopsis, grape branch-rot bacterium, maize phyllosticta, Cowpox phyllosticta, cowpox capsule spore bacterium, maize save chytrid, Phytophthora nicotianae germ, Plasmopara viticola, white cross hair list softgel shell, Portugal Grape brown patch germ, bacterium of downy mildew of cucumber, humulus grass vacation downy mildew, Puccina sorghi, peanut handle rest fungus, standing grain are preced with handle rest fungus, corn rust Bacterium, Puccinia recondita, corn rust bacterium, circle nuclear cavity bacteria, couchgrass nuclear cavity bacteria, Rhizoctonia solani Kuhn, barley leaf blotch bacterium, nuclear disk Bacterium, Sclerotium rolfsii, soybean septoria musiva, leaf spoting bacteria, leaf spot fungi, monofilament shell powdery mildew, thin careless monofilament shell bacterium, strawberry white powder The more spores of germ, wheat shell, crawl handle is mould for expansion, blueberry leaf rust bacterium, the double born of the same parents' aecidiums of wart, grape snag shell, tikka sclerotinite, black Star germ, pear cucumerinum, thermophilic fruit knife spore bacterium and fly excrement germ.
76. the purposes according to any one of claim 56 to 75, wherein the one or more formamides applied are antifungal The total amount of agent, one or more strobilurin fungicides and one or more triazole antifungal agents is from about 50g/ha to about In the range of 1500g/ha.
77. the purposes according to any one of claim 56 to 76, wherein should by the amount application from 40g/ha to 500g/ha Carboxamide fungicides.
78. the purposes according to any one of claim 56 to 77, wherein should by the amount application from 50g/ha to 300g/ha Strobilurin fungicide.
79. the purposes according to any one of claim 56 to 78, wherein should by the amount application from 50g/ha to 500g/ha Triazole antifungal agents.
80. the purposes according to any one of claim 56 to 79, wherein using according to claim 1 to any one of 29 The composition.
81. the purposes according to any one of claim 56 to 80, wherein the state and after sprouting during the stage before sprouting, These fungicide compositions are administered on these plants.
CN201880025066.2A 2017-05-04 2018-04-16 Fungicidal composition and application thereof Pending CN110519989A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB1707082.2A GB2562080B (en) 2017-05-04 2017-05-04 A fungicidal composition and the use thereof
GB1707082.2 2017-05-04
PCT/CN2018/083144 WO2018201882A1 (en) 2017-05-04 2018-04-16 Fungicidal composition and use thereof

Publications (1)

Publication Number Publication Date
CN110519989A true CN110519989A (en) 2019-11-29

Family

ID=59065436

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201880025066.2A Pending CN110519989A (en) 2017-05-04 2018-04-16 Fungicidal composition and application thereof

Country Status (5)

Country Link
CN (1) CN110519989A (en)
AR (1) AR111377A1 (en)
BR (1) BR102017022433A8 (en)
GB (1) GB2562080B (en)
WO (1) WO2018201882A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114828635A (en) * 2019-12-05 2022-07-29 Upl有限责任公司 Fungicidal combinations

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1563731A1 (en) 2004-02-12 2005-08-17 Bayer CropScience S.A. Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting the ergosterol biosynthesis
CN110476999A (en) * 2019-08-23 2019-11-22 安徽省农业科学院植物保护与农产品质量安全研究所 The development of pyraclostrobin, prothioconazoles suspending agent and suspension seed-coating agent

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101217873A (en) * 2005-07-06 2008-07-09 巴斯福股份公司 Fungicidal mixtures made from 1-methylpyrazol-4-ylcarboxanilides
CN101232808A (en) * 2005-07-28 2008-07-30 拜尔农作物科学股份公司 Synergistic fungicidal active substance combinations containing a carboxamide, an azole, a second azole or a strobilurine
CN101808521A (en) * 2007-09-26 2010-08-18 巴斯夫欧洲公司 ternary fungicidal compositions comprising boscalid and chlorothalonil
CN101848639A (en) * 2007-07-20 2010-09-29 巴斯夫欧洲公司 Compositions comprising alcohol alkoxylates, and use of the alcohol alkoxylates as adjuvant for the agrochemical sector
CN104981162A (en) * 2012-11-30 2015-10-14 拜耳作物科学股份公司 Ternary fungicidal mixtures
CN105211070A (en) * 2015-10-09 2016-01-06 广东中迅农科股份有限公司 Composition pesticide containing prothioconazoles and nitre benzene bacterium ester and oxime bacterium ester
CN105766945A (en) * 2014-12-23 2016-07-20 沈阳中化农药化工研发有限公司 Fungicidal composition and application thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PE20070409A1 (en) * 2005-06-29 2007-05-07 Basf Ag FUNGICIDE MIXTURES BASED ON PYRAZOLCARBOXYL ACID BIPHENYLAMIDES DISUSTITUTED IN 2.4
WO2007003644A1 (en) * 2005-07-06 2007-01-11 Basf Aktiengesellschaft Fungicidal mixtures made from 1-methylpyrazol-4-ylcarboxanilides
US8859558B2 (en) * 2010-06-07 2014-10-14 Dow Agrosciences, Llc. Pyrazinyl carboxamides as fungicides
CN103918677A (en) * 2013-01-12 2014-07-16 王学权 Thifluzamide-containing sterilization composition
CN104094947B (en) * 2013-06-09 2015-11-18 江苏辉丰农化股份有限公司 There is the bactericidal composition of synergistic effect

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101217873A (en) * 2005-07-06 2008-07-09 巴斯福股份公司 Fungicidal mixtures made from 1-methylpyrazol-4-ylcarboxanilides
CN101232808A (en) * 2005-07-28 2008-07-30 拜尔农作物科学股份公司 Synergistic fungicidal active substance combinations containing a carboxamide, an azole, a second azole or a strobilurine
CN101848639A (en) * 2007-07-20 2010-09-29 巴斯夫欧洲公司 Compositions comprising alcohol alkoxylates, and use of the alcohol alkoxylates as adjuvant for the agrochemical sector
CN101808521A (en) * 2007-09-26 2010-08-18 巴斯夫欧洲公司 ternary fungicidal compositions comprising boscalid and chlorothalonil
CN104981162A (en) * 2012-11-30 2015-10-14 拜耳作物科学股份公司 Ternary fungicidal mixtures
CN105766945A (en) * 2014-12-23 2016-07-20 沈阳中化农药化工研发有限公司 Fungicidal composition and application thereof
CN105211070A (en) * 2015-10-09 2016-01-06 广东中迅农科股份有限公司 Composition pesticide containing prothioconazoles and nitre benzene bacterium ester and oxime bacterium ester

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114828635A (en) * 2019-12-05 2022-07-29 Upl有限责任公司 Fungicidal combinations

Also Published As

Publication number Publication date
GB201707082D0 (en) 2017-06-21
WO2018201882A1 (en) 2018-11-08
BR102017022433A8 (en) 2022-09-13
BR102017022433A2 (en) 2018-05-08
GB2562080A (en) 2018-11-07
GB2562080B (en) 2022-01-12
AR111377A1 (en) 2019-07-03

Similar Documents

Publication Publication Date Title
JP5107940B2 (en) Fungicidal composition
CN102524266B (en) Fungicidal compositions
CN109566651A (en) A kind of bactericidal composition
CN109310090A (en) Kill pest composition
CN110519989A (en) Fungicidal composition and application thereof
CN108719300A (en) A kind of bactericidal composition
CN109566627A (en) A kind of bactericidal composition
CN109566641A (en) A kind of bactericidal composition
CN109566636A (en) A kind of bactericidal composition
CN109566642A (en) A kind of bactericidal composition
CN109566625A (en) A kind of bactericidal composition
CN109566630A (en) A kind of bactericidal composition
CN109380236A (en) A kind of bactericidal composition
CN109566624A (en) A kind of bactericidal composition
CN116634876A (en) Mixtures and compositions comprising Fusarium A, fusarium B and fungicides
CN108522519A (en) A kind of bactericidal composition
CN109717194A (en) A kind of bactericidal composition
CN109380232A (en) A kind of bactericidal composition
CN108522516A (en) A kind of bactericidal composition
CN109380241A (en) A kind of bactericidal composition
CN109566637A (en) A kind of bactericidal composition
CN108719315A (en) A kind of bactericidal composition
CN106982842A (en) A kind of bactericidal composition
CN106982851A (en) A kind of bactericidal composition
CN106922701A (en) A kind of bactericidal composition

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination