CN110499105A - A kind of environment-friendly water-based glue - Google Patents
A kind of environment-friendly water-based glue Download PDFInfo
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- CN110499105A CN110499105A CN201810465622.XA CN201810465622A CN110499105A CN 110499105 A CN110499105 A CN 110499105A CN 201810465622 A CN201810465622 A CN 201810465622A CN 110499105 A CN110499105 A CN 110499105A
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- environment
- glue
- friendly water
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
- C09J9/02—Electrically-conducting adhesives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to chemical technology field, in particular a kind of environment-friendly water-based glue is made of: 100~120 parts of polyester the component of following weight ratio, 30~50 parts of butylene glycol aerylate, 30~50 parts of trimethylolpropane, 25~45 parts of polyimides, 45~65 parts of poly- isobutyl ester, 55~75 parts of phenolic resin, 20~40 parts of acetone, 10~30 parts of dibutyl phthalate, 10~20 parts of triphenyl phosphate, 8~10 parts of acrylamide, 15~35 parts of butanediol, 15~20 parts of styrene.The present invention is by being added mould inhibitor, it can be achieved that the environment-friendly water-based stronger mildew resistance of glue, effectively improves the quality guarantee time limit of the environment-friendly water-based glue；By the way that antistatic agent is added, it can be achieved that the environment-friendly water-based stronger antistatic property of glue, guarantees safety in use；By addition antibacterial agent, it can be achieved that the anti-microbial property of the environment-friendly water-based glue, further ensures its service life.
Description
Technical field
The present invention relates to chemical technology field, specially a kind of environment-friendly water-based glue.
Background technique
Glue plays a very important role in production and life, and is widely used in vaerious fields, and the film that glue is formed can be right
Object plays the role of decoration, protection and beautiful, although most of glue production at present on the market is simple, price cheaply simultaneously
Function is relatively simple, can only simply be used as decoration, and in some special operating environments, simple glue is not
It is able to satisfy the required of people.In consideration of it, it is proposed that a kind of environment-friendly water-based glue.
Summary of the invention
The purpose of the present invention is to provide a kind of environment-friendly water-based glue, to solve the problems mentioned in the above background technology.
To achieve the above object, the invention provides the following technical scheme:
A kind of environment-friendly water-based glue, is made of the component of following weight ratio: 100~120 parts of polyester, butylene glycol aerylate 30
~50 parts, 30~50 parts of trimethylolpropane, 25~45 parts of polyimides, 45~65 parts of poly- isobutyl ester, phenolic resin 55~75
Part, 20~40 parts of acetone, 10~30 parts of dibutyl phthalate, 10~20 parts of triphenyl phosphate, 8~10 parts of acrylamide,
15~35 parts of butanediol, 15~20 parts of styrene.
As a preference of the present invention, including the component of following ratio: 100 parts of polyester, 30 parts of butylene glycol aerylate, three hydroxyls
30 parts of methylpropane, 25 parts of polyimides, 45 parts of poly- isobutyl ester, 55 parts of phenolic resin, 20 parts of acetone, dibutyl phthalate
10 parts, 10 parts of triphenyl phosphate, 8 parts of acrylamide, 15 parts of butanediol, 15 parts of styrene.
As a preference of the present invention, further including 3~5 parts of glue auxiliary agent, glue forms a film 5~7 parts of reinforcing agent, adhesive 6~8
Part, 2~4 parts of mould inhibitor, 3~5 parts of antistatic agent, 4~6 parts and 50~90 parts of water of antibacterial agent.
As a preference of the present invention, further including 3 parts of glue auxiliary agent, glue forms a film 5 parts of reinforcing agent, 6 parts of adhesive, mould inhibitor
2 parts, 3 parts of antistatic agent, 4 parts and 50 parts of water of antibacterial agent.
As a preference of the present invention, one of glue selection of auxiliary polyurethane, Lauxite or emulsion acrylic resin.
As a preference of the present invention, adhesive selects epoxy resin hot setting adhesive, polyurethanes thermosetting property gluing
One of agent, organic silicon hot setting adhesive or polyimide hot setting adhesive.
As a preference of the present invention, mould inhibitor selects pentachlorophenol and its sodium salt, daconil M, between toluene chlorine
Phenol, p-chloro-m-xylol, o-phenyl phenol and its sodium salt, diiodomethyl are to one in methylbenzene sulfone or benzyl acetate bromide
Kind.
As a preference of the present invention, antibacterial agent selects vanilla aldehyde compound, ethyl vanillin aldehydes compound, anilid
One of class compound, thiazole compound, isothiazolone derivative, quaternary ammonium compound or phenolic compound.
Compared with prior art, the beneficial effects of the present invention are: the present invention is by being added mould inhibitor, it can be achieved that the environment-protective water
The property stronger mildew resistance of glue, effectively improves the quality guarantee time limit of the environment-friendly water-based glue；By the way that antistatic agent is added, it can be achieved that should
The environment-friendly water-based stronger antistatic property of glue, guarantees safety in use；By the way that antibacterial agent is added, it can be achieved that the ring
The anti-microbial property of water-retaining property glue further ensures its service life.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Technical solution provided by the invention:
Embodiment 1
A kind of environment-friendly water-based glue, is made of the component of following weight ratio: 100~120 parts of polyester, butylene glycol aerylate 30
~50 parts, 30~50 parts of trimethylolpropane, 25~45 parts of polyimides, 45~65 parts of poly- isobutyl ester, phenolic resin 55~75
Part, 20~40 parts of acetone, 10~30 parts of dibutyl phthalate, 10~20 parts of triphenyl phosphate, 8~10 parts of acrylamide,
15~35 parts of butanediol, 15~20 parts of styrene.
Specifically, the specific composition of the above component are as follows: 100 parts of polyester, 30 parts of butylene glycol aerylate, trimethylolpropane
30 parts, 25 parts of polyimides, 45 parts of poly- isobutyl ester, 55 parts of phenolic resin, 20 parts of acetone, 10 parts of dibutyl phthalate, phosphorus
10 parts of triphenyl phosphate ester, 8 parts of acrylamide, 15 parts of butanediol, 15 parts of styrene
Environment-friendly water-based glue in the present embodiment further include: 3~5 parts of glue auxiliary agent, glue forms a film 5~7 parts of reinforcing agent, adhesive
6~8 parts, 2~4 parts of mould inhibitor, 3~5 parts of antistatic agent, 4~6 parts and 50~90 parts of water of antibacterial agent.
Specifically, the specific composition of the above component are as follows: 3 parts of glue auxiliary agent, glue forms a film 5 parts of reinforcing agent, and 6 parts of adhesive,
2 parts of mould inhibitor, 3 parts of antistatic agent, 4 parts and 50 parts of water of antibacterial agent.
In the present embodiment, one of glue selection of auxiliary polyurethane, Lauxite or emulsion acrylic resin.
Further, glue auxiliary agent is preferably polyurethane, and polyurethane belongs to synthesis used additives, can enhance various liquid in glue
Mutual fusion between body.
In the present embodiment, adhesive selects epoxy resin hot setting adhesive, polyurethanes hot setting adhesive, organic
One of silicon class hot setting adhesive or polyimide hot setting adhesive.
Further, adhesive is preferably epoxy resin hot setting adhesive, epoxy resin hot setting adhesive category
In sqtructural adhesive, main body sizing can be made to form net type or three-dimensional-structure, increase glue-line cohesive strength.
In the present embodiment, mould inhibitor select pentachlorophenol and its sodium salt, daconil M, to chlorine m-cresol, to chlorine
Between xylenol, o-phenyl phenol and its sodium salt, diiodomethyl to one of methylbenzene sulfone or benzyl acetate bromide.
Further, mould inhibitor is preferably pentachlorophenol and its sodium salt, such toxicity of compound is lower, cheap, system
Standby convenient, sterility is high, does not pollute processed material, and chemical stability is good, non-discolouring, non-volatile, and durability is high.
In the present embodiment, antibacterial agent selects vanilla aldehyde compound, ethyl vanillin aldehydes compound, anilid class chemical combination
One of object, thiazole compound, isothiazolone derivative, quaternary ammonium compound or phenolic compound.
Further, antibacterial agent is preferably vanilla aldehyde compound, such compound environment protection health, has good sterilization
Or inhibit the function of microorganism, and heat resistance is strong, facile hydrolysis, does not improve its use while ensure that glue long service life
Safety.
Embodiment 2
A kind of environment-friendly water-based glue, is made of the component of following weight ratio: 100~120 parts of polyester, butylene glycol aerylate 30
~50 parts, 30~50 parts of trimethylolpropane, 25~45 parts of polyimides, 45~65 parts of poly- isobutyl ester, phenolic resin 55~75
Part, 20~40 parts of acetone, 10~30 parts of dibutyl phthalate, 10~20 parts of triphenyl phosphate, 8~10 parts of acrylamide,
15~35 parts of butanediol, 15~20 parts of styrene.
Specifically, the specific composition of the above component are as follows: 110 parts of polyester, 40 parts of butylene glycol aerylate, trimethylolpropane
40 parts, 35 parts of polyimides, 55 parts of poly- isobutyl ester, 65 parts of phenolic resin, 30 parts of acetone, 20 parts of dibutyl phthalate, phosphorus
15 parts of triphenyl phosphate ester, 9 parts of acrylamide, 25 parts of butanediol, 18 parts of styrene.
Environment-friendly water-based glue in the present embodiment further include: 3~5 parts of glue auxiliary agent, glue forms a film 5~7 parts of reinforcing agent, glue
6~8 parts of stick, 2~4 parts of mould inhibitor, 3~5 parts of antistatic agent, 4~6 parts and 50~90 parts of water of antibacterial agent.
Specifically, the specific composition of the above component are as follows: 4 parts of glue auxiliary agent, glue forms a film 6 parts of reinforcing agent, and 7 parts of adhesive,
3 parts of mould inhibitor, 4 parts of antistatic agent, 5 parts and 70 parts of water of antibacterial agent.
In the present embodiment, one of glue selection of auxiliary polyurethane, Lauxite or emulsion acrylic resin.
Further, glue auxiliary agent is preferably Lauxite, and Lauxite belongs to bridging property auxiliary agent, is a kind of with reaction
The compound of property group, can react to form cross-linked structure with matrix in adhesive, so as to improve the original performance of adhesive.
In the present embodiment, adhesive selects epoxy resin hot setting adhesive, polyurethanes hot setting adhesive, organic
One of silicon class hot setting adhesive or polyimide hot setting adhesive.
Further, adhesive is preferably polyurethanes hot setting adhesive, and polyurethanes hot setting adhesive belongs to knot
Structure adhesive can effectively accelerate glue curing, reinforce the adhesive property of glue.
In the present embodiment, mould inhibitor select pentachlorophenol and its sodium salt, daconil M, to chlorine m-cresol, to chlorine
Between xylenol, o-phenyl phenol and its sodium salt, diiodomethyl to one of methylbenzene sulfone or benzyl acetate bromide.
Further, mould inhibitor is preferably o-phenyl phenol and its sodium salt, such compound and TBZ are used in mixed way in latex
Show that superior anti-mold effect, general dosage 0.6% or so, no color or smell have the sweet tea smell of burning, health environment-friendly in coating.
In the present embodiment, antibacterial agent selects vanilla aldehyde compound, ethyl vanillin aldehydes compound, anilid class chemical combination
One of object, thiazole compound, isothiazolone derivative, quaternary ammonium compound or phenolic compound.
Further, antibacterial agent is preferably ethyl vanillin aldehydes compound, such compound has stronger anti-microbial property,
Ensure that the quality guarantee time limit and service life of glue, and such compound is not soluble in water, highly-safe, colorless and odorless, toxicity compared with
It is low.
Embodiment 3
A kind of environment-friendly water-based glue, is made of the component of following weight ratio: 100~120 parts of polyester, butylene glycol aerylate 30
~50 parts, 30~50 parts of trimethylolpropane, 25~45 parts of polyimides, 45~65 parts of poly- isobutyl ester, phenolic resin 55~75
Part, 20~40 parts of acetone, 10~30 parts of dibutyl phthalate, 10~20 parts of triphenyl phosphate, 8~10 parts of acrylamide,
15~35 parts of butanediol, 15~20 parts of styrene.
Specifically, the specific composition of the above component are as follows: 120 parts of polyester, 50 parts of butylene glycol aerylate, trimethylolpropane
50 parts, 45 parts of polyimides, 65 parts of poly- isobutyl ester, 75 parts of phenolic resin, 40 parts of acetone, 30 parts of dibutyl phthalate, phosphorus
20 parts of triphenyl phosphate ester, 10 parts of acrylamide, 35 parts of butanediol, 20 parts of styrene.
Environment-friendly water-based glue in the present embodiment further include: 3~5 parts of glue auxiliary agent, glue forms a film 5~7 parts of reinforcing agent, glue
6~8 parts of stick, 2~4 parts of mould inhibitor, 3~5 parts of antistatic agent, 4~6 parts and 50~90 parts of water of antibacterial agent.
Specifically, the specific composition of the above component are as follows: 5 parts of glue auxiliary agent, glue forms a film 7 parts of reinforcing agent, and 8 parts of adhesive,
4 parts of mould inhibitor, 5 parts of antistatic agent, 6 parts and 90 parts of water of antibacterial agent.
In the present embodiment, one of glue selection of auxiliary polyurethane, Lauxite or emulsion acrylic resin.
Further, glue auxiliary agent is preferably emulsion acrylic resin, and emulsion acrylic resin belongs to stability auxiliary agent,
Purposes is the service life and resistance to storage performance in order to improve glue.
In the present embodiment, adhesive selects epoxy resin hot setting adhesive, polyurethanes hot setting adhesive, organic
One of silicon class hot setting adhesive or polyimide hot setting adhesive.
Further, adhesive is preferably organic silicon hot setting adhesive, and organic silicon hot setting adhesive belongs to knot
Structure adhesive can effectively reduce glue-line rigidity, increase the toughness of glue, extends glue service life.
In the present embodiment, mould inhibitor select pentachlorophenol and its sodium salt, daconil M, to chlorine m-cresol, to chlorine
Between xylenol, o-phenyl phenol and its sodium salt, diiodomethyl to one of methylbenzene sulfone or benzyl acetate bromide.
Further, mould inhibitor is preferably diiodomethyl to methylbenzene sulfone, such compound is strong for mould rejection ability,
Toxicity is low.With mercury type antimildew disinfectant and with confection is made, complete protective effect is played to material, become a kind of anti-mildew,
The ideal mould inhibitor of anti-algae and resistance to bacterium.Colourless transparent liquid is easy to mix with water, and low concentration can suppress development of microorganisms,
Stablize in acid, alkali, adds water not decompose, fabulous anti-mold effect is shown in latex paint, can preferably be subjected to slacking.
In the present embodiment, antibacterial agent selects vanilla aldehyde compound, ethyl vanillin aldehydes compound, anilid class chemical combination
One of object, thiazole compound, isothiazolone derivative, quaternary ammonium compound or phenolic compound.
Further, antibacterial agent is preferably anilid class compound, such compound not only has good antibiotic property
Can, and energy colorless and odorless, toxicity is lower, and can improve the adhesive property of glue.
Water-based glue that 3 groups of embodiments obtain and traditional glue are compared into experiment, after a period of use, obtained
Correlation data it is as follows:
Compared by above-mentioned experimental data it can be concluded that, the anti-microbial property of environment-friendly water-based glue of the invention, antistatic property and anti-
Mouldiness can be far superior to traditional glue, have stronger practicability.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry
For personnel it should be appreciated that the present invention is not limited to the above embodiments, described in the above embodiment and specification is only the present invention
Preference, be not intended to limit the invention, without departing from the spirit and scope of the present invention, the present invention also has various
Changes and improvements, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by institute
Attached claims and its equivalent thereof.
Claims (8)
1. a kind of environment-friendly water-based glue, it is characterised in that: be made of the component of following weight ratio: 100~120 parts of polyester, fourth
30~50 parts of butanediol acrylate, 30~50 parts of trimethylolpropane, 25~45 parts of polyimides, 45~65 parts of poly- isobutyl ester,
55~75 parts of phenolic resin, 20~40 parts of acetone, 10~30 parts of dibutyl phthalate, 10~20 parts of triphenyl phosphate, third
8~10 parts of acrylamide, 15~35 parts of butanediol, 15~20 parts of styrene.
2. environment-friendly water-based glue according to claim 1, it is characterised in that: the component including following ratio: polyester 100
Part, 30 parts of butylene glycol aerylate, 30 parts of trimethylolpropane, 25 parts of polyimides, 45 parts of poly- isobutyl ester, phenolic resin 55
Part, 20 parts of acetone, 10 parts of dibutyl phthalate, 10 parts of triphenyl phosphate, 8 parts of acrylamide, 15 parts of butanediol, styrene
15 parts.
3. environment-friendly water-based glue according to claim 1, it is characterised in that: further include 3~5 parts of glue auxiliary agent, glue at
5~7 parts of film reinforcing agent, 6~8 parts of adhesive, 2~4 parts of mould inhibitor, 3~5 parts of antistatic agent, 4~6 parts of antibacterial agent and water 50~
90 parts.
4. environment-friendly water-based glue according to claim 1, it is characterised in that: further include 3 parts of glue auxiliary agent, glue film forming increases
Strong 5 parts of agent, 6 parts of adhesive, 2 parts of mould inhibitor, 3 parts of antistatic agent, 4 parts and 50 parts of water of antibacterial agent.
5. environment-friendly water-based glue according to claim 1, it is characterised in that: glue selection of auxiliary polyurethane, Lauxite
Or one of emulsion acrylic resin.
6. environment-friendly water-based glue according to claim 1, it is characterised in that: adhesive selects epoxy resin thermosetting cement
One in stick, polyurethanes hot setting adhesive, organic silicon hot setting adhesive or polyimide hot setting adhesive
Kind.
7. environment-friendly water-based glue according to claim 1, it is characterised in that: mould inhibitor select pentachlorophenol and its sodium salt,
Daconil M, to chlorine m-cresol, p-chloro-m-xylol, o-phenyl phenol and its sodium salt, diiodomethyl to methyl
One of benzene sulfone or benzyl acetate bromide.
8. environment-friendly water-based glue according to claim 1, it is characterised in that: antibacterial agent selects vanilla aldehyde compound, second
Basic note grass aldehyde compound, anilid class compound, thiazole compound, isothiazolone derivative, quaternary ammonium compound
Or one of phenolic compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810465622.XA CN110499105A (en) | 2018-05-16 | 2018-05-16 | A kind of environment-friendly water-based glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810465622.XA CN110499105A (en) | 2018-05-16 | 2018-05-16 | A kind of environment-friendly water-based glue |
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| Publication Number | Publication Date |
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| CN110499105A true CN110499105A (en) | 2019-11-26 |
Family
ID=68584672
Family Applications (1)
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| CN201810465622.XA Pending CN110499105A (en) | 2018-05-16 | 2018-05-16 | A kind of environment-friendly water-based glue |
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Application publication date: 20191126 |