CN110495459A - A kind of Pesticidal combination of flonicamid and triacontanol - Google Patents
A kind of Pesticidal combination of flonicamid and triacontanol Download PDFInfo
- Publication number
- CN110495459A CN110495459A CN201910720761.7A CN201910720761A CN110495459A CN 110495459 A CN110495459 A CN 110495459A CN 201910720761 A CN201910720761 A CN 201910720761A CN 110495459 A CN110495459 A CN 110495459A
- Authority
- CN
- China
- Prior art keywords
- triacontanol
- flonicamid
- pesticidal combination
- aphid
- fruit
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to technical field of pesticide.On the basis of flonicamid original single dose, it compounds with long-acting, wide spectrum triacontanol, using the plant growth regulation of triacontanol, enhances to the absorption of flonicamid and in the intracorporal conduction of plant, improve and permeated from leaf portion to stem, root, and then improves the preventive effect for aphid.Flonicamid of the present invention and triacontanol Pesticidal combination, active constituent are flonicamid and triacontanol, and flonicamid and triacontanol mass ratio are 99~11:1, and the content of active component is 3~50%wt.Pesticidal combination provided by the invention, have efficiently, insecticidal spectrum is wide, low toxicity, synergistic effect are significant, bioactive substance administration dosage is few, and delaying drug resistance simultaneously reduces use cost and the adverse effect to ecological environment.Suitable for preventing and treating the aphid fruit and vegetables.Especially suitable for the prevention and control of aphids on the fruit trees such as the vegetables such as cucumber and apple.
Description
Technical field
The invention belongs to technical field of pesticide, are related to pesticide combination technology, in particular to a kind of Pesticidal combination.
Background technique
Flonicamid, chemical name: N- cyanogen methyl -4- (trifluoromethyl) niacinamide；Molecular formula: C9H6F3N3O, relatively
Molecular weight: 229.2, structural formula is as follows:
Flonicamid is effective to various suckings pest, and has good osmosis.It can from root to stem,
Leaf portion infiltration, but it is relatively weak from leaf portion to stem, root osmosis, and the medicine is by hindering pest act of sucking to cause to imitate: evil
Worm stops sucking quickly after taking in medicament, last hungry and dead, parses according to the insect sucking behavior (EMIF) of electronics, can make aphid
Lancet tissue Deng sucking property pest can not be inserted into plant tissue and cause to imitate.
Triacontanol, molecular formula: C30H62O, structural formula are as follows:
Triacontanol is a kind of natural Long carbon chain plant growth regulator, chemical name N-triacontanol, structural formula CH3
(CH2) 28CH2OH, also known as melissyl alcohol are the natural biological products of the purification from honeybee wax.With hestening rooting, germination,
It blooms, cauline leaf growth and precocious effect, has and improve the different physiological roles such as chlorophyll content, enhancing photosynthesis.In crop
It grows and uses early period, germination percentage can be improved, improve seedling quality, increase effective tillering.It uses, can increase in the growth intermediary and later stages
Number of flowers, percentage of fertile fruit and mass of 1000 kernel.Suitable for rice, corn, sorghum, cotton, soybean, tobacco, beet, sugarcane, peanut, vegetable
The various crops such as dish, fruit tree, flowers and laminaria culture.
The anti-effective component flonicamid effect used that eliminates aphis gradually decreases at present, and flonicamid is by leaf portion
Relatively weak to stem, root osmosis, various aphids are more and more stronger for the resistance of drug.
In prior art data, the correlation technique data that compounds of the flonicamid with triacontanol is not found.
Summary of the invention
Aiming at the problem that decline it is an object of the invention to the control efficiency caused by aphid enhances flonicamid resistance,
The Pesticidal combination of a kind of flonicamid with good preventive effect and triacontanol is provided.
The object of the present invention is achieved like this, on the basis of flonicamid original single dose, with long-acting, wide spectrum three
Ten alkanols compounding is enhanced using the plant growth regulation of triacontanol to the absorption of flonicamid and in plant
Interior conduction improves and is permeated from leaf portion to stem, root, and then improves the preventive effect for aphid.
Flonicamid of the present invention and triacontanol Pesticidal combination, active constituent are flonicamid and 30
Alkanol, flonicamid and triacontanol mass ratio are 99~11:1, and the content of active component is 3~50%wt.
Flonicamid of the present invention and triacontanol Pesticidal combination, active constituent are flonicamid and 30
Alkanol, flonicamid and triacontanol weight ratio are 79~52:1；The content of active component is 6-50%wt.
Flonicamid of the invention and triacontanol Pesticidal combination, dosage form be missible oil, wettable powder, suspending agent,
One of granule, microemulsion, aqueous emulsion, water-dispersible granules.
Flonicamid of the invention and triacontanol Pesticidal combination, auxiliary element include acceptable organic solvent,
Emulsifier, surfactant, inert filler etc.；
Acceptable organic solvent includes fat hydrocarbon organic solvent, arene organic solvent, plant oil solvent, alcohols
Organic solvent, lipid organic solvent or organic solvent of ketone etc.；
Adoptable surfactant has anionic surfactant and nonionic surface active agent；
Other auxiliary elements further include xanthan gum, and the thickeners such as sodium carboxymethyl starch, ethylene glycol, glycerine, urea etc. are antifreeze
Agent；The fillers such as kaolin, bentonite, attapulgite, charcoal acid calcium and the acceptable stabilizer of other pesticidal preparations, safener,
Colorant etc..
Pesticidal combination provided by the invention, with efficient, insecticidal spectrum is wide, less toxic, synergistic effect is significant, biological active matter
Matter administration dosage is few, and delaying drug resistance simultaneously reduces use cost and the adverse effect to ecological environment.Suitable for prevention and treatment vegetables and fruit
Aphid etc. in tree has obvious effects on, this two kinds of components compounding, can the pest resistant for other insecticides have very
Good insect killing effect.Especially suitable for the prevention and control of aphids on the fruit trees such as the vegetables such as cucumber and apple.
Specific embodiment
It is further described below with reference to the technical solution that embodiment is related to invention, to facilitate reason of the invention
Solution, but not as the limitation to technical solution, in addition to specifically mentioned, component ratio is weight percentage.
Embodiment 1
4% flonicamid triacontanol microemulsion
Raw material group become 3.9% flonicamid raw medicine, 0.1% triacontanol raw medicine, 5%N, dinethylformamide, 10%
Cyclohexanone, 10% toluene, 5% phenethyl phenolformaldehyde resin polyoxyethylene ether, 3% calcium dodecyl benzene sulfonate, 7% alkyl phenol
Polyoxyethylene ether, 5% ethylene glycol, remaining is supplied with water, and routinely micro emulsion mode is prepared.
Field trial:
Experimental pharmacy is 4% flonicamid triacontanol microemulsion, and comparison medicament is 10% flonicamid water dispersion
Granula (Japanese Ishihara Sangyo Kaisha, Ltd.), controlling object, Cucumber blight；It is as follows for the control rate data of aphid:
Temperature is at 20-25 DEG C when medication, and weather is with fine to based on cloudy, and synergy is imitated after flonicamid and triacontanol compounding
Fruit is obvious.
Embodiment 2
6% flonicamid triacontanol missible oil
Raw material composition: 5.5% flonicamid raw medicine, 0.5% triacontanol raw medicine, 8%N, dinethylformamide, 10% the third
Ketone, 4% calcium dodecyl benzene sulfonate, 5% triphenoethyl benzene phenol polyethenoxy ether, 3% phenethyl phenolformaldehyde resin polyoxy second
Alkene ether, remaining is supplied with toluene.Routinely missible oil mode is prepared.
Field trial:
Experimental pharmacy is 6% flonicamid triacontanol missible oil, and comparison medicament is 10% flonicamid water dispersible granular
Agent (Japanese Ishihara Sangyo Kaisha, Ltd.)；Controlling object, apple aphid；It is as follows for the control rate data of aphid:
Temperature is at 20-25 DEG C when medication, and weather is with fine to based on cloudy, and synergy is imitated after flonicamid and triacontanol compounding
Fruit is obvious.
Embodiment 3
13% flonicamid triacontanol aqueous emulsion
Raw material composition: 12.5% flonicamid raw medicine, 0.5% triacontanol raw medicine, 5% acetone, 15% dimethylbenzene, 2%0
Dialkyl benzene sulfonic acids calcium, 3% triphenoethyl benzene phenol polyethenoxy ether, 2% phenethyl phenolformaldehyde resin polyoxyethylene ether, 8%
Polyoxyethylene nonylphenol ether, 5% ethylene glycol, remaining is supplied with water.Routinely water and milk mode is matched.
Field trial 1:
Experimental pharmacy is 13% flonicamid triacontanol aqueous emulsion, and comparison medicament is 10% flonicamid water dispersion
Granula (Japanese Ishihara Sangyo Kaisha, Ltd.)；Controlling object, Cucumber blight；It is as follows for the control rate data of aphid:
Temperature is at 20-25 DEG C when medication, and weather is with fine to based on cloudy, and synergy is imitated after flonicamid and triacontanol compounding
Fruit is obvious.
Embodiment 4
16% flonicamid triacontanol suspending agent；
Raw material group becomes 15.7% flonicamid raw medicine, 0.3% triacontanol raw medicine, 1.2% pull open powder, 1% di-2-ethylhexylphosphine oxide
Bitter edible plant sodium sulfonate, 1.3% calcium dodecyl benzene sulfonate, 3% triphenoethyl benzene phenol polyethenoxy ether, 1.5% white carbon black, 0.25% is yellow
Virgin rubber, remaining is supplied with water, and routinely suspending agent production method is prepared.
Field trial:
Experimental pharmacy is 16% flonicamid triacontanol suspending agent, and comparison medicament is 10% flonicamid water dispersion
Granula (Japanese Ishihara Sangyo Kaisha, Ltd.)；Controlling object, apple aphid；It is as follows for the control rate data of aphid:
Temperature is at 20-25 DEG C when medication, and weather is with fine to based on cloudy, and synergy is imitated after flonicamid and triacontanol compounding
Fruit is obvious.
Embodiment 5
24% flonicamid triacontanol suspending agent；
Raw material group become 23.7% flonicamid raw medicine, 0.3% triacontanol raw medicine, 1.5% polyoxyethylene alkyl ether, 1%
Dispersing agent pull open powder, 3% calcium dodecyl benzene sulfonate, 2% white carbon black, 0.15% xanthan gum, 5% ethylene glycol, remaining is mended with water
Foot, routinely suspending agent production method is prepared.
Field trial:
Experimental pharmacy is 24% flonicamid triacontanol suspending agent, and comparison medicament is 10% flonicamid water dispersion
Granula (Japanese Ishihara Sangyo Kaisha, Ltd.)；Controlling object, Cucumber blight；It is as follows for the control rate data of aphid:
Temperature is at 20-25 DEG C when medication, and weather is with fine to based on cloudy, and synergy is imitated after flonicamid and triacontanol compounding
Fruit is obvious.
Embodiment 6
40% flonicamid triacontanol water dispersion granule
Raw material composition: 39.4% flonicamid raw medicine, 0.6% triacontanol raw medicine；3% calcium dodecyl benzene sulfonate, 15%
Di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 3% naphthalenesulfonate formaldehyde condensation compound, 5% calcium lignosulfonate, 5% sodium carboxymethyl starch, remaining use
Ammonium sulfate is supplied, and routinely extrusion granulation mode is prepared.
Field trial:
Experimental pharmacy is 40% flonicamid triacontanol water dispersion granule, and comparison medicament is 10% flonicamid water
Dispersible granule (Japanese Ishihara Sangyo Kaisha, Ltd.)；Controlling object, apple aphid；Its control rate data for being directed to aphid is such as
Under:
Temperature is at 20-25 DEG C when medication, and weather is with fine to based on cloudy, and synergy is imitated after flonicamid and triacontanol compounding
Fruit is obvious.
Embodiment 7
50% flonicamid triacontanol wettable powder
Raw material composition: 49.5% flonicamid raw medicine, 0.5% triacontanol raw medicine；15% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 5%
Naphthalenesulfonate formaldehyde condensation compound, 7% calcium lignosulfonate, remaining is supplied with kaolin, and routinely extrusion granulation mode is prepared.
Field trial:
Experimental pharmacy is 50% flonicamid triacontanol wettable powder, and comparison medicament is 10% flonicamid moisture
Scattered seed agent (Japanese Ishihara Sangyo Kaisha, Ltd.)；Controlling object, apple aphid；It is as follows for the control rate data of aphid:
Temperature is at 20-25 DEG C when medication, and weather is with fine to based on cloudy, and synergy is imitated after flonicamid and triacontanol compounding
Fruit is obvious.
Claims (5)
1. the Pesticidal combination of a kind of flonicamid and triacontanol, active constituent is flonicamid and triacontanol, fluorine
Pyridine insect amide and triacontanol mass ratio are 99~11:1, and the content of active component is 3~50%wt.
2. the Pesticidal combination of flonicamid according to claim 1 and triacontanol, it is characterised in that: fluorine pyridine worm acyl
Amine and triacontanol weight ratio are 79~52:1；The content of active component is 6-50 %wt.
3. the Pesticidal combination of flonicamid according to any one of claims 1 or 2 and triacontanol, feature exist
In: dosage form is one of missible oil, wettable powder, suspending agent, granule, microemulsion, aqueous emulsion, water-dispersible granules.
4. the Pesticidal combination of flonicamid according to any one of claims 1 or 2 and triacontanol, feature exist
In: it eliminates aphis suitable for anti-.
5. the Pesticidal combination of flonicamid according to any one of claims 1 or 2 and triacontanol, feature exist
In: it eliminates aphis suitable for anti-.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910720761.7A CN110495459A (en) | 2019-08-06 | 2019-08-06 | A kind of Pesticidal combination of flonicamid and triacontanol |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910720761.7A CN110495459A (en) | 2019-08-06 | 2019-08-06 | A kind of Pesticidal combination of flonicamid and triacontanol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110495459A true CN110495459A (en) | 2019-11-26 |
Family
ID=68587960
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910720761.7A Pending CN110495459A (en) | 2019-08-06 | 2019-08-06 | A kind of Pesticidal combination of flonicamid and triacontanol |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110495459A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1081670A (en) * | 1992-07-23 | 1994-02-09 | 石原产业株式会社 | Amide compound and salt thereof, their manufacturing process and pesticide composition thereof |
-
2019
- 2019-08-06 CN CN201910720761.7A patent/CN110495459A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1081670A (en) * | 1992-07-23 | 1994-02-09 | 石原产业株式会社 | Amide compound and salt thereof, their manufacturing process and pesticide composition thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张国平 等: "《100种常见农业化学物质使用指南》", 31 December 1994, 中国农业出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102771510B (en) | Insecticidal composition containing fosthiazate | |
| CN105613490A (en) | Attractant for grub imagoes | |
| EP1896045B1 (en) | Composition comprising brassicacea seeds meal and their use as biopesticides in plants | |
| CN103651519A (en) | Compound pesticide composition containing flonicamid and bifenthrin | |
| CN101385457B (en) | Insecticidal composition containing avermectin and indoxacarb | |
| CN101836643A (en) | Pesticide preparation for controlling vegetable pests of diamondback moth and the like | |
| JP2018510125A (en) | Limonene: formulation and pesticide use | |
| CN102960354A (en) | Chlorantraniliprole-lufenuron insecticidal composition | |
| CN100355345C (en) | Traditional Chinese medicine composite biological pesticide using crusta as main material | |
| CN107372662A (en) | A kind of sugar orange plantation special plant insecticide and preparation method thereof | |
| CN102669157B (en) | Mite-killing composition and preparation thereof | |
| CN110495459A (en) | A kind of Pesticidal combination of flonicamid and triacontanol | |
| CN109699645A (en) | A kind of citrus tip killing agent and its preparation, application method and application | |
| CN106561656B (en) | A kind of Pesticidal combination containing Celastrus angulatus and multiple killing teichomycin | |
| HRP960515A2 (en) | Pesticidal formulation | |
| CN103300036A (en) | Insecticidal composition containing flonicamid | |
| CN109938030A (en) | A kind of fluridone complex weedicide and preparation method thereof | |
| CN104522006B (en) | A kind of preventing and treating Lepidoptera and homoptera pest compositions | |
| KR20000076074A (en) | Pesticidal 1-arylpyrazoles | |
| CN105994275A (en) | Pesticide composition containing chromafenozide and biogenic sources | |
| CN102792972A (en) | Insecticide compound comprising guadipyr and metarrhizium anisopliae | |
| CN103039533B (en) | Slow-release attractant for fruit piercing moth | |
| CN110506761A (en) | A kind of agricultural spray agent | |
| CN103300037A (en) | Insecticidal composition containing lufenuron and cyantraniliprole | |
| CN104322535B (en) | A kind of insect-killing composition, preparation and purposes thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191126 |
|
| RJ01 | Rejection of invention patent application after publication |