CN110467348A - The preparation method of glassware - Google Patents

The preparation method of glassware Download PDF

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Publication number
CN110467348A
CN110467348A CN201910679557.5A CN201910679557A CN110467348A CN 110467348 A CN110467348 A CN 110467348A CN 201910679557 A CN201910679557 A CN 201910679557A CN 110467348 A CN110467348 A CN 110467348A
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CN
China
Prior art keywords
parts
glass
glassware
preparation
ingredient
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910679557.5A
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Chinese (zh)
Inventor
孙稚雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Evergreen Glass Technology Development Co Ltd
Original Assignee
Jiangsu Evergreen Glass Technology Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Evergreen Glass Technology Development Co Ltd filed Critical Jiangsu Evergreen Glass Technology Development Co Ltd
Priority to CN201910679557.5A priority Critical patent/CN110467348A/en
Publication of CN110467348A publication Critical patent/CN110467348A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B25/00Annealing glass products
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002Use of waste materials, e.g. slags

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a kind of preparation methods of glassware, the following steps are included: (1) ingredient: being put into after ingredient is mixed and stirred for uniformly in molten cellar and carry out calcining 5-8 hours formation glass metals of fusing, (2) it is melted: the raw material prepared is formed into glass metal by the high-temperature heating of melting furnaces, (3) it shapes: the glass metal melted is transformed into the figurate solid articles of tool, (4) it anneals: the glassware of forming is placed in 600-850 DEG C of baking oven, it is slowly annealed, prevents the generation of fracture phenomena.Preparation method of the invention is easy to operate, at low cost, economic and environment-friendly, the glass of various shapes that can be prepared according to the method for the present invention has good heat resistance, chemical stability, high-intensitive and low expansion, the production efficiency for improving glassware shortens the glassware production time.

Description

The preparation method of glassware
Technical field
The present invention relates to a kind of glass technology fields, more particularly to a kind of preparation method of glassware.
Background technique
Tempered glass is using most common glass post-processing product, windshield, the window of the vehicles such as automobile, train Glass, the glass gate of luxurious hotel and partition, glass desk-top and many glass curtain walls all use tempered glass.This is because steel The intensity for changing glass is 3~5 times of plate glass, and resistance to thermal shocks is also preferable, and it is broken after in small granular, will not be to people Big injury is caused, so being called safety glass.The production of tempered glass is very simple, plate glass cutting, edging or punching Afterwards, it is sent into 650 DEG C or more of annealing furnace and heats, then anxious blow a cold wind over is quenched, and forms permanent pressure on the glass surface Stress greatly improves intensity, and here it is tempered glass.Tempered glass cannot be processed cutting again, otherwise can once be made It is so fried that crush;
Currently, tempered glass surface has the glass of compression, also known as strengthened glass, glass is carried out using toughening method Enhancing.Tempered glass belongs to safety glass, and tempered glass is a kind of prestressed glass in fact, for improve glass intensity, usually Using the method for chemistry or physics, pressure is answered in glass surface formation, glass bears external force and offsets skin stress first, thus Improve bearing capacity, the crushing resistance of reinforcing glass itself, cold and heat, impact etc..When glass is destroyed by external force, fragment meeting At similar cellular obtuse angle broken particle, it is not easy to cause serious injury human body.Tempered glass has good thermal stability, The temperature difference that can be born is 3 times of simple glass, can bear 300 DEG C of difference variation;
Laminated glass be pressed from both sides between two or more layers glass upper polyvinyl alcohol contracting fourth vinegar (PVB) intermediate coat, poly- carbonic acid junket plate, The plastic materials such as poly- ammonia junket plate, acrylic acid junket plate, are processed into through high temperature and pressure, and the laminated glass articles intermediate materials of kiln are Polyethylene ferment contracting fourth junket (PVB) film, PVB film has good caking property, toughness and elasticity, fierce by external force in laminated glass When shock, this tunic can absorb largely can be shocking, and glass fragment can be firmly adhered on PVB intermediate coat, and glass fragment will not disperse, To make the issuable laminated glass that is reduced to a minimum that injures have fail-safe in i.e. natural pond, drop throat, control sunlight special Property and UV resistance feature.As needed, common float glass tempered glass LOW-E glass can be selected and strive the first original for laminated glass Piece, to make laminated glass that there is different performances.
Summary of the invention
It is easy to operate the invention mainly solves the technical problem of providing a kind of preparation method of glassware, it is at low cost, Economic and environment-friendly, the glass of various shapes that can be prepared according to the method for the present invention has good heat resistance, and chemical stability is high Intensity and low expansion improve the production efficiency of glassware, shorten the glassware production time.
In order to solve the above technical problems, one technical scheme adopted by the invention is that: a kind of preparation method of glassware, The following steps are included:
(1) ingredient: ingredient is mixed and stirred for uniformly, the mix being stirred is put into molten cellar calcines later Fusing 5-8 hours, and the temperature in molten cellar is set in 1000-1800 DEG C, high temperature makes various matter melts and mutually melts Conjunction forms glass metal;
(2) it is melted: the raw material prepared being passed through to the high-temperature heating of melting furnaces, forms the glass metal of uniform bubble-free, it is described Melting furnaces include: pot furnace and tank furnace, and the pot furnace is that frit is contained in crucible, are put in crucible externally heating, pot furnace Enter the 1-20 crucibles, form glass metal, frit is melted the tank furnace in kiln pond, and open fire adds on metal level top Heat forms glass metal;
(3) it shapes: the glass metal melted being transformed into the figurate solid articles of tool, the glass metal is cooled down To 450-800 DEG C, glass is changed into mouldable state by viscous fluid, and the forming side includes artificial forming and mechanical molding;
(4) it anneals: the glassware of forming being placed in 600-850 DEG C of baking oven, is slowly annealed, since glass exists It shaped and is subjected to fierce temperature change and change in shape in, this variation leaves thermal stress, this heat in glass Stress can reduce the intensity and thermal stability of glassware, if directly cooling, it is likely that in cooling procedure or later deposit Put, transport and use process in voluntarily rupture, in order to eliminate fracture phenomena, glassware must anneal after forming.
It further says, the glass includes the ingredient of following parts by weight: 6-9 parts of gravel, 12-14 parts of lime stone, white clouds 8-12 parts of stone, 12-22 parts of saltcake, 2-12 parts of quartz, 6-10 parts of soda ash, 6-10 parts of the cullet of recycling and 3-8 parts of aluminium powder.
It further says, the glass includes the ingredient of following parts by weight: 7-9 parts of gravel, 16-17 parts of lime stone, white clouds 7-8 parts of stone, 15-18 parts of saltcake, 8-9 parts of quartz, 8-10 parts of soda ash, 8-10 parts of cullet and 7-8 parts of aluminium powder.
Further say, the glass includes the ingredient of following parts by weight: 8 parts of gravel, 16 parts of lime stone, 8 parts of dolomite, 16 parts of saltcake, 9 parts of quartz, 8 parts of soda ash, 10 parts of cullet and 8 parts of aluminium powder.
It further says, the glassware is glass, glass bowl or vial.
It further says, the temperature when melting step is 1300~1600 ゜ C.
It further says, the temperature when melting step is 1500 ゜ C.
Beneficial effects of the present invention:
The preparation method of glassware of the invention, it is easy to operate, it is at low cost, it is economic and environment-friendly, according to the method for the present invention may be used The glass of various shapes of preparation has good heat resistance, chemical stability, and high-intensitive and low expansion improves glass The production efficiency of vessel shortens the glassware production time.
Specific embodiment
The preferred embodiments of the present invention will be described in detail below so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that so as to make a clearer definition of the protection scope of the present invention.
A kind of embodiment: preparation method of glassware, it is characterised in that: the following steps are included:
(1) ingredient: ingredient is mixed and stirred for uniformly, the mix being stirred is put into molten cellar calcines later Fusing 5-8 hours, and the temperature in molten cellar is set in 1000-1800 DEG C, high temperature makes various matter melts and mutually melts Conjunction forms glass metal;
(2) it is melted: the raw material prepared being passed through to the high-temperature heating of melting furnaces, forms the glass metal of uniform bubble-free, it is described Melting furnaces include: pot furnace and tank furnace, and the pot furnace is that frit is contained in crucible, are put in crucible externally heating, pot furnace Enter the 1-20 crucibles, form glass metal, frit is melted the tank furnace in kiln pond, and open fire adds on metal level top Heat forms glass metal;
(3) it shapes: the glass metal melted being transformed into the figurate solid articles of tool, the glass metal is cooled down To 450-800 DEG C, glass is changed into mouldable state by viscous fluid, and the forming side includes artificial forming and mechanical molding;
(4) it anneals: the glassware of forming being placed in 600-850 DEG C of baking oven, is slowly annealed, since glass exists It shaped and is subjected to fierce temperature change and change in shape in, this variation leaves thermal stress, this heat in glass Stress can reduce the intensity and thermal stability of glassware, if directly cooling, it is likely that in cooling procedure or later deposit Put, transport and use process in voluntarily rupture, in order to eliminate fracture phenomena, glassware must anneal after forming.
The glass includes the ingredient of following parts by weight: 6-9 parts of gravel, 12-14 parts of lime stone, 8-12 parts of dolomite, awns 12-22 parts of nitre, 2-12 parts of quartz, 6-10 parts of soda ash, 6-10 parts of the cullet of recycling and 3-8 parts of aluminium powder.
The glass includes the ingredient of following parts by weight: 7-9 parts of gravel, 16-17 parts of lime stone, 7-8 parts of dolomite, saltcake 15-18 parts, 8-9 parts of quartz, 8-10 parts of soda ash, 8-10 parts of cullet and 7-8 parts of aluminium powder.
The glass includes the ingredient of following parts by weight: 8 parts of gravel, 16 parts of lime stone, 8 parts of dolomite, 16 parts of saltcake, stone 9 parts of English, 8 parts of soda ash, 10 parts of cullet and 8 parts of aluminium powder.
The glassware is glass, glass bowl or vial.
The temperature when melting step is 1300~1600 ゜ C.
The temperature when melting step is 1500 ゜ C.
Working principle of the present invention is as follows:
The preparation method of glassware of the invention, it is easy to operate, it is at low cost, it is economic and environment-friendly, according to the method for the present invention may be used The glass of various shapes of preparation has good heat resistance, chemical stability, and high-intensitive and low expansion improves glass The production efficiency of vessel shortens the glassware production time.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure transformation made by bright description is applied directly or indirectly in other relevant technical fields, and similarly wraps It includes in scope of patent protection of the invention.

Claims (7)

1. a kind of preparation method of glassware, it is characterised in that: the following steps are included:
(1) ingredient: ingredient is mixed and stirred for uniformly, the mix being stirred is put into molten cellar carries out calcining fusing later 5-8 hours, and the temperature in molten cellar is set in 1000-1800 DEG C, high temperature makes various matter melts and mutually merges shape At glass metal;
(2) it is melted: the raw material prepared being passed through to the high-temperature heating of melting furnaces, forms the glass metal of uniform bubble-free, the melting furnaces It include: pot furnace and tank furnace, the pot furnace is that frit is contained in crucible, is put into 1- in crucible externally heating, pot furnace 20 crucibles form glass metal, and frit is melted the tank furnace in kiln pond, and open fire heats on metal level top, Form glass metal;
(3) it shapes: the glass metal melted being transformed into the figurate solid articles of tool, the glass metal is cooled to 450-800 DEG C, glass is changed into mouldable state by viscous fluid, and the forming side includes artificial forming and mechanical molding;
(4) it anneals: the glassware of forming being placed in 600-850 DEG C of baking oven, is slowly annealed, since glass is shaping Fierce temperature change and change in shape are subjected in crossing into, this variation leaves thermal stress, this thermal stress in glass The intensity and thermal stability of glassware can be reduced, if directly cooling, it is likely that in cooling procedure or later storage, fortune It is voluntarily ruptured in defeated and use process, in order to eliminate fracture phenomena, glassware must anneal after forming.
2. the preparation method of glassware according to claim 1, it is characterised in that: the glass includes following parts by weight Ingredient: 6-9 parts of gravel, 12-14 parts of lime stone, 8-12 parts of dolomite, 12-22 parts of saltcake, 2-12 parts of quartz, soda ash 6-10 Part, 6-10 parts of the cullet of recycling and 3-8 parts of aluminium powder.
3. the preparation method of glassware according to claim 2, it is characterised in that: the glass includes following parts by weight Ingredient: 7-9 parts of gravel, 16-17 parts of lime stone, 7-8 parts of dolomite, 15-18 parts of saltcake, 8-9 parts of quartz, 8-10 parts of soda ash, 8-10 parts and aluminium powder 7-8 parts of cullet.
4. the preparation method of glassware according to claim 3, it is characterised in that: the glass includes following parts by weight Ingredient: 8 parts of gravel, 16 parts of lime stone, 8 parts of dolomite, 16 parts of saltcake, 9 parts of quartz, 8 parts of soda ash, 10 parts of cullet and aluminium powder 8 parts.
5. the preparation method of glassware according to claim 1, it is characterised in that: the glassware be glass, Glass bowl or vial.
6. the preparation method of glassware according to claim 1, it is characterised in that: the temperature when melting step is 1300~1600 ゜ C.
7. the preparation method of glassware according to claim 1, it is characterised in that: the temperature when melting step is 1500゜C。
CN201910679557.5A 2019-07-26 2019-07-26 The preparation method of glassware Pending CN110467348A (en)

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CN201910679557.5A CN110467348A (en) 2019-07-26 2019-07-26 The preparation method of glassware

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Application Number Priority Date Filing Date Title
CN201910679557.5A CN110467348A (en) 2019-07-26 2019-07-26 The preparation method of glassware

Publications (1)

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CN110467348A true CN110467348A (en) 2019-11-19

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20190026692A (en) * 2016-07-01 2019-03-13 삐에르화브르데르모-코스메띠끄 New white patterned thistle water extract and its use in dermatology and skin cosmetics

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20190026692A (en) * 2016-07-01 2019-03-13 삐에르화브르데르모-코스메띠끄 New white patterned thistle water extract and its use in dermatology and skin cosmetics
KR102459649B1 (en) 2016-07-01 2022-10-26 삐에르화브르데르모-코스메띠끄 Novel white thistle aqueous extract and its use in dermatology and skin cosmetics

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Application publication date: 20191119