CN110423010A - High strength glass product - Google Patents

High strength glass product Download PDF

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Publication number
CN110423010A
CN110423010A CN201910679556.0A CN201910679556A CN110423010A CN 110423010 A CN110423010 A CN 110423010A CN 201910679556 A CN201910679556 A CN 201910679556A CN 110423010 A CN110423010 A CN 110423010A
Authority
CN
China
Prior art keywords
parts
high strength
glass product
strength glass
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910679556.0A
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Chinese (zh)
Inventor
孙稚雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Evergreen Glass Technology Development Co Ltd
Original Assignee
Jiangsu Evergreen Glass Technology Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Evergreen Glass Technology Development Co Ltd filed Critical Jiangsu Evergreen Glass Technology Development Co Ltd
Priority to CN201910679556.0A priority Critical patent/CN110423010A/en
Publication of CN110423010A publication Critical patent/CN110423010A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002Use of waste materials, e.g. slags
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C11/00Multi-cellular glass ; Porous or hollow glass or glass particles
    • C03C11/007Foam glass, e.g. obtained by incorporating a blowing agent and heating

Abstract

The invention discloses a kind of high strength glass products, including following raw material by weight: 60-80 parts of coating nano flyash, 40-60 parts of silica, 20-30 parts of cullet, 15-25 parts of aluminium hydroxide, 10-20 parts of calcirm-fluoride, 20-30 parts of zirconium oxide, 10-20 parts of glass bead, 8-12 parts of ceramic sand, 5-15 parts of glass fibre, 5-15 parts of hauynite, 5-15 parts of carbon dust, adularia 10-20 parts of dam and 3-7 parts of additive.By the above-mentioned means, foam glass aperture of the present invention is more uniform, and mostly lipostomous, high specific surface area.

Description

High strength glass product
Technical field
The invention belongs to glassware technical fields, more particularly to a kind of high strength glass product.
Background technique
China has been achieved for two a little progress in terms of the research of novel wall material, and the method for producing foam glass has very More, the requirement to properties of foam glass is also higher and higher.The primary raw material of foam glass is post-consumer glass and flyash etc., is passed through Two other a little auxiliary materials are added, by broken, ball milling and after evenly mixing, using the mistake of preheating, melting softening, foaming and fortune fire What journey was formed has some such as heat-insulated, sound absorptions, moisture-proof, fire prevention superior function novel environmental-friendly construction material.
Summary of the invention
The invention mainly solves the technical problem of providing a kind of high strength glass products, and foam glass aperture is more uniform, And mostly lipostomous, high specific surface area.
In order to solve the above technical problems, one technical scheme adopted by the invention is that: a kind of high strength glass product is provided, Including following raw material by weight: 60-80 parts of coating nano flyash, 40-60 parts of silica, 20-30 parts of cullet, 15-25 parts of aluminium hydroxide, 10-20 parts of calcirm-fluoride, 20-30 parts of zirconium oxide, 10-20 parts of glass bead, 8-12 parts of ceramic sand, glass 5-15 parts of fiber, 5-15 parts of hauynite, 5-15 parts of carbon dust, adularia 10-20 parts of dam and 3-7 parts of additive;
The coating nano flyash the preparation method comprises the following steps: flyash is carried out ball milling decentralized processing for 24 hours with alcohol, then to The deionized water for being equivalent to its weight 2-4% alkyl glycosides, the phosphate trimethylbenzene vinegar of 1-3%, 7-9% is wherein added, in 60-70 Agitating and heating 40-50min in DEG C water bath with thermostatic control, obtains dispersion liquid, then is added inside dispersion liquid and is equivalent to its weight 18-22%'s Concentration is the aluminum sulfate solution of 20-30%, while it is 9-10 that appropriate ammonium hydroxide, which is added, to adjust pH value, is filtered, washed, is dried Afterwards, in 580-640 DEG C of sintering 1-3h, cooled to room temperature is milled, is ground into nanometer powder to obtain the final product.
Further say, including following raw material by weight: 70 parts of coating nano flyash, 50 parts of silica, 25 parts of cullet, 20 parts of aluminium hydroxide, 15 parts of calcirm-fluoride, 25 parts of zirconium oxide, 15 parts of glass bead, 10 parts of ceramic sand, glass fibers 10 parts of dimension, 10 parts of hauynite, 10 parts of carbon dust, 15 parts of dam adularia and 5 parts of additive.
It further says, the additive includes following component by weight percentage: foaming agent 30-40%, foam stabilizer 25-35% and exciting agent 30-40%.
It further says, the additive includes following component by weight percentage: foaming agent 35%, foam stabilizer 30% With exciting agent 35%.
It further says, the foaming agent is one of calcium carbonate, sodium bicarbonate or silicon carbide or two kinds or more.
Further say, the steady, infusion be one of silicone resin polyethers lotion, polyacrylamide or polyvinyl alcohol or Two kinds of person or more.
It further says, the exciting agent is aluminium sulfate or silicate.
The beneficial effects of the present invention are: intensity of the present invention is high, corrosion-resistant, service life is high, has good market prospects.
Specific embodiment
The preferred embodiments of the present invention will be described in detail below so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that so as to make a clearer definition of the protection scope of the present invention.
Embodiment: a kind of high strength glass product, the present invention include following raw material by weight: coating nanometer fine coal 60-80 parts grey, 40-60 parts of silica, 20-30 parts of cullet, 15-25 parts of aluminium hydroxide, 10-20 parts of calcirm-fluoride, zirconium oxide 20-30 parts, 10-20 parts of glass bead, 8-12 parts of ceramic sand, 5-15 parts of glass fibre, 5-15 parts of hauynite, 5-15 parts of carbon dust, Adularia 10-20 parts and additive 3-7 parts of dam;
The coating nano flyash the preparation method comprises the following steps: flyash is carried out ball milling decentralized processing for 24 hours with alcohol, then to The deionized water for being equivalent to its weight 2-4% alkyl glycosides, the phosphate trimethylbenzene vinegar of 1-3%, 7-9% is wherein added, in 60-70 Agitating and heating 40-50min in DEG C water bath with thermostatic control, obtains dispersion liquid, then is added inside dispersion liquid and is equivalent to its weight 18-22%'s Concentration is the aluminum sulfate solution of 20-30%, while it is 9-10 that appropriate ammonium hydroxide, which is added, to adjust pH value, is filtered, washed, is dried Afterwards, in 580-640 DEG C of sintering 1-3h, cooled to room temperature is milled, is ground into nanometer powder to obtain the final product.
Including following raw material by weight: 70 parts of coating nano flyash, 50 parts of silica, 25 parts of cullet, 20 parts of aluminium hydroxide, 15 parts of calcirm-fluoride, 25 parts of zirconium oxide, 15 parts of glass bead, 10 parts of ceramic sand, 10 parts of glass fibre, blue party 10 parts of stone, 10 parts of carbon dust, 15 parts of dam adularia and 5 parts of additive.
The additive includes following component by weight percentage: foaming agent 30-40%, foam stabilizer 25-35% and swash Send out agent 30-40%.
The additive includes following component by weight percentage: foaming agent 35%, foam stabilizer 30% and exciting agent 35%.
The foaming agent is one of calcium carbonate, sodium bicarbonate or silicon carbide or two kinds or more.
The steady, infusion is one of silicone resin polyethers lotion, polyacrylamide or polyvinyl alcohol or two kinds or more.
The exciting agent is aluminium sulfate or silicate.
Working principle of the present invention is as follows: intensity of the present invention is high, corrosion-resistant, and service life is high, before having good market Scape.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure transformation made by bright specification is applied directly or indirectly in other relevant technical fields, and is similarly included in In scope of patent protection of the invention.

Claims (7)

1. a kind of high strength glass product, it is characterised in that: including following raw material by weight: coating nano flyash 60-80 parts, 40-60 parts of silica, 20-30 parts of cullet, 15-25 parts of aluminium hydroxide, 10-20 parts of calcirm-fluoride, zirconium oxide 20- 30 parts, 10-20 parts of glass bead, 8-12 parts of ceramic sand, 5-15 parts of glass fibre, 5-15 parts of hauynite, 5-15 parts of carbon dust, dam ice 10-20 parts and additive 3-7 parts of feldspar;
The coating nano flyash the preparation method comprises the following steps: flyash is carried out ball milling decentralized processing for 24 hours with alcohol, then thereto The deionized water for being equivalent to its weight 2-4% alkyl glycosides, the phosphate trimethylbenzene vinegar of 1-3%, 7-9% is added, in 60-70 DEG C of perseverance Agitating and heating 40-50min in tepidarium obtains dispersion liquid, then the concentration for being equivalent to its weight 18-22% is added inside dispersion liquid For the aluminum sulfate solution of 20-30%, while it is 9-10 that appropriate ammonium hydroxide, which is added, to adjust pH value, after being filtered, washed, being dried, In 580-640 DEG C of sintering 1-3h, cooled to room temperature, milling is ground into nanometer powder to obtain the final product.
2. a kind of high strength glass product according to claim 1, it is characterised in that: including following original by weight Material: 70 parts of coating nano flyash, 50 parts of silica, 25 parts of cullet, 20 parts of aluminium hydroxide, 15 parts of calcirm-fluoride, zirconium oxide 25 parts, 15 parts of glass bead, 10 parts of ceramic sand, 10 parts of glass fibre, 10 parts of hauynite, 10 parts of carbon dust, 15 parts of dam adularia and 5 parts of additive.
3. a kind of high strength glass product according to claim 1, it is characterised in that: the additive is by weight percentage Meter includes following component: foaming agent 30-40%, foam stabilizer 25-35% and exciting agent 30-40%.
4. a kind of high strength glass product according to claim 3, it is characterised in that: the additive is by weight percentage Meter includes following component: foaming agent 35%, foam stabilizer 30% and exciting agent 35%.
5. a kind of high strength glass product according to claim 3, it is characterised in that: the foaming agent is calcium carbonate, carbon One of sour hydrogen sodium or silicon carbide or two kinds or more.
6. a kind of high strength glass product according to claim 3, it is characterised in that: the steady, infusion is poly- for silicone resin One of ether lotion, polyacrylamide or polyvinyl alcohol or two kinds or more.
7. a kind of high strength glass product according to claim 3, it is characterised in that: the exciting agent be aluminium sulfate or Silicate.
CN201910679556.0A 2019-07-26 2019-07-26 High strength glass product Pending CN110423010A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910679556.0A CN110423010A (en) 2019-07-26 2019-07-26 High strength glass product

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910679556.0A CN110423010A (en) 2019-07-26 2019-07-26 High strength glass product

Publications (1)

Publication Number Publication Date
CN110423010A true CN110423010A (en) 2019-11-08

Family

ID=68412482

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910679556.0A Pending CN110423010A (en) 2019-07-26 2019-07-26 High strength glass product

Country Status (1)

Country Link
CN (1) CN110423010A (en)

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Application publication date: 20191108