CN110396815A - A kind of colored fiber fabric and its production method - Google Patents
A kind of colored fiber fabric and its production method Download PDFInfo
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- CN110396815A CN110396815A CN201910594850.1A CN201910594850A CN110396815A CN 110396815 A CN110396815 A CN 110396815A CN 201910594850 A CN201910594850 A CN 201910594850A CN 110396815 A CN110396815 A CN 110396815A
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- 239000004744 fabric Substances 0.000 title claims abstract description 125
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 116
- 239000000835 fiber Substances 0.000 title claims abstract description 39
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 claims abstract description 67
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims abstract description 66
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 53
- 239000007789 gas Substances 0.000 claims abstract description 43
- 238000000151 deposition Methods 0.000 claims abstract description 41
- 229910052786 argon Inorganic materials 0.000 claims abstract description 33
- 239000002131 composite material Substances 0.000 claims abstract description 30
- 229910010037 TiAlN Inorganic materials 0.000 claims abstract description 25
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000001301 oxygen Substances 0.000 claims abstract description 20
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 20
- 238000001771 vacuum deposition Methods 0.000 claims abstract description 5
- 239000010410 layer Substances 0.000 claims description 210
- 230000008021 deposition Effects 0.000 claims description 29
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 27
- 229910052719 titanium Inorganic materials 0.000 claims description 20
- 239000011241 protective layer Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 17
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- 229910010038 TiAl Inorganic materials 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052681 coesite Inorganic materials 0.000 claims description 3
- 229910052906 cristobalite Inorganic materials 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052682 stishovite Inorganic materials 0.000 claims description 3
- 229910052905 tridymite Inorganic materials 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 230000005611 electricity Effects 0.000 claims 4
- 229910001873 dinitrogen Inorganic materials 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 26
- 230000003647 oxidation Effects 0.000 abstract description 8
- 238000007254 oxidation reaction Methods 0.000 abstract description 8
- 239000010408 film Substances 0.000 description 91
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 10
- 239000000460 chlorine Substances 0.000 description 10
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- 229910052751 metal Inorganic materials 0.000 description 10
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
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- 238000009776 industrial production Methods 0.000 description 4
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- 238000004544 sputter deposition Methods 0.000 description 4
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- 238000004043 dyeing Methods 0.000 description 3
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- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 3
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Physical Vapour Deposition (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention provides a kind of production method of colored fiber fabric, comprising the following steps: by vacuum deposition, at least one surface of fabric lining deposits one or more layers composite film, and the composite film includes buffer layer, reflecting layer and the layer that adds lustre to from bottom to top；The layer that adds lustre to includes TiAlOx and/or TiAlN；When depositing each layer of the composite film, it is both needed to be continually fed into working gas, the working gas includes argon gas and/or nitrogen and/or oxygen.Production method provided by the invention solves the problems, such as that metallic diaphragm is easily oxidized, improve the oxidation resistance of fabric lining superficial film, the adjustment control of the colored film more durable for depositing its surface, fabric lining color is simple and easy, is suitable for industrialized production.The present invention also provides a kind of colored fibers, have color abundant and good color fastness, can be prepared by industrial method.
Description
Technical field
The present invention relates to fabric lining vacuum dye technology more particularly to a kind of colored fiber fabric and its production methods.
Background technique
It is a kind of green and healthy tencel fabric using evaporating deposition technique in fabric lining surface depositional coating
Color technology utilizes the interaction generated between light and film such as reflection, folding while not influencing fabric lining basic performance
Penetrate, scatter, diffraction and interference etc. can achieve the purpose painted to fabric lining, entire production process does not have exhaust gas and waste water
It is discharged, metallic element included in the film layer on fabric lining surface is safe and harmless to human body.At present about vacuum deposition
Film layer is in the research of fabric lining coloring, and the overwhelming majority only resides within laboratory stage, not can be carried out industrialized production,
The durability and wearability of fabric lining are not considered in laboratory using the presented color of film layer interference.
Applicant has found there is more mushy spy according to fabric lining itself during successfully realizing industrial production
Point, if in its surface composite film structure that only depositing metal membrane layer or metal/transparent medium combine, although can be realized
Coloring, and simple process, but it is attached to the metallic diaphragm on fabric lining surface since oxygen can not be prevented to enter from fabric one side,
And the chemical activity of metallic film is all relatively active, is easy to react and be corroded with oxygen, fabric lining is in use
There is uneven color, color fastness cannot be up to state standards, and influence the service life of fabric lining.In addition, single membrane system
It is more single with the color of double membrane systems, it is not abundant enough, it is not able to satisfy the use demand of consumer.
Therefore, it is necessary to need to develop a kind of new film layer structure, rich colors both can be enough generated, color fastness also can
It is up to standard, meet the industrial production demand of fabric lining.
Summary of the invention
In view of the above-mentioned drawbacks in the prior art, the present invention provides a kind of production method of colored fiber fabric, the production
The fabric lining that method obtains, surface are assembly of thin films structure, improve anti-oxidant, the resistance to corrosion of film layer, make fiber
The colored film of web surface deposition is more longlasting, solves the problems, such as that fabric lining color fastness is not up to standard in the prior art.Meanwhile
Multi-layer film structure production method provided by the invention can pass through the superposition of different film layers and thicknesses of layers in process of production
Variation come achieve the purpose that color regulate and control, so that fiber is showed richer color.
To achieve the above object, the production method of colored fiber fabric provided by the invention, comprising the following steps:
By vacuum deposition, by vacuum deposition, at least one surface of fabric lining deposits one or more layers composite membrane
Layer, the composite film includes buffer layer, reflecting layer and the layer that adds lustre to from bottom to top；
The layer that adds lustre to includes TiAlOxAnd/or TiAlN；
When depositing each layer of the composite film, it is both needed to be continually fed into gas, the gas includes oxygen and/or argon gas
And/or nitrogen.
In order to solve the problems, such as that metallic diaphragm is easily oxidized, the oxidation resistance of fabric lining superficial film is improved, it is made
The colored film more durable of surface deposition, the present invention designs the composite film structure of multilayer, from the substrate of fabric lining
Start to be sequentially depositing that buffer layer, reflecting layer, add lustre to layer outward from interior.
Reflecting layer in composite film is usually the relatively active metallic film of chemical activity, according to the inherent characteristic of metal
There can be very high reflectivity to the visible light of a certain wave band, be mainly used for the one side close to the layer that adds lustre in reflection arrival reflecting layer
The visible light of the visible light of a certain wave band, other wave bands is absorbed, so that the reflected light after screening by reflecting layer be made to enter
Being incident upon has stronger light when adding lustre to level.Metallic film is typically easy to react and be corroded with oxygen, and fabric lining
Itself be to be prepared by no several fibers, have between fiber it is more porous, therefore can not prevent oxygen from fabric one side enter
It is attached to the reflecting layer of fabric surface, fabric lining is caused to occur uneven color in use, color fastness cannot reach
To national standard, the service life of fabric lining is influenced.The present invention increases buffer layer between reflecting layer and fabric lining, resistance
It is directly contacted every air with reflecting layer, avoids the problem of oxidation of reflecting layer metallic film.
The layer that adds lustre to is the main film layer for making fabric lining that color be presented, and by adjusting adding lustre to, a layer thicknesses of layers can achieve control
The purpose of system and adjustment color, makes fabric lining show different colors, by increasing buffer layer, guarantees the color of fabric lining
Fastness, while the operating process of color control is simple, this is very favorable for industrialized production.
In the present invention, the layer that adds lustre to uses TiAlOxAnd/or TiAlN, wherein TiAlOxFor non-stoichiometric compound, X refers to oxygen
It is not exclusively saturated on the cationic form of compound, that is, there is non-stoichiometric compound.Life of the visible light in nano-scale thickness
Two secondary reflections occur for chromatograph upper and lower surfaces, and form interference and be added or the effect subtracted each other of interference, different wave length it is visible
Interference of light effect is not also identical, it is possible to by adjusting the thickness of layer of adding lustre to, come adjust different wave length visible light reflection
Intensity, the final purpose for realizing adjustment color.TiAlOxOr TiAlN is as the layer that adds lustre to, the membranous layer binding force and high temperature of film
Oxidation resistance is strong, and wearability is excellent, while having the advantages that sputter rate is fast, can be improved production efficiency, is suitble to industrialization
Production.
In process of production, it needs to be continually fed into working gas and carries out film deposition, in addition to necessary argon gas, according to film layer
Demand can also be passed through nitrogen, oxygen as working gas, such as oxygen element in film layer of adding lustre to and nitrogen can pass through
The form for being passed through working gas is realized.
Further, inventor is had found by many experiments, as above-mentioned TiAlOxAnd/or TiAlN adds lustre to the thickness control of layer
When system is in 10-100nm, by adjusting the thickness for the tunic layer that adds lustre to, the color of fabric lining can change.With the layer that adds lustre to
Successively there is yellow, red, purple, blue, green in the increase of thickness, fabric lining surface, and when adding lustre to, thickness degree reaches 100nm
Afterwards, thicknesses of layers is continued growing, the color on fabric lining surface enters next identical color again from green to yellow
Period.That is, the variation of film layer and the variation of color are in corresponding relationship, and has the characteristics that cyclically-varying.Due to film
The blocked up wear resistance that can reduce composite film of layer, and will affect the feel of fabric lining, therefore, produced generally for improving
Efficiency can select add lustre to layer thickness control in 10-100nm, i.e. in first color period, thickness of adding lustre at this time degree is most thin,
The abrasion resistance properties of fiber are preferable.
According to above content it can be appreciated that if two surfaces in substrate deposit composite film, fabric lining
There is color on two surfaces, and when the thicknesses of layers difference of two sides, the color that two surfaces are presented is different, will obtain two-sided
The fabric lining of color.For the fabric lining of Double-faced-color, since two sides are deposited with composite film, oxidation resistance is more
Add outstanding.
Production electric current when in order to guarantee that layer thickness control of adding lustre to is added lustre to layer in 10-100nm, described in deposition is usual
Control produces power control in 12-210kW in 30-500A.
Further, the face liber obtained using production method of the present invention, layer thicknesses of layers is added lustre to not in surface
Together, the color presented would also vary from, and in order to realize the above-mentioned color period, while guarantee that the equal of color is presented in fabric lining
Even property is imitated inventors have found that selecting the layer that adds lustre to described in TiAl alloy target material deposition of the atomic ratio of Ti and Al for 1:4-4:1
Fruit is best.
Further, with TiAlOxAnd/or on the basis of TiAlN is as the layer that adds lustre to, reflecting layer selects Ti, SS (stainless
The abbreviation of steel), at least one of TiAl, Cu and Ag, these materials and the layer that adds lustre to are with good binding force, while it is chemically
Matter is to torpescence, to human body and safe and harmless.
Further, in order to realize the function of screening and strong reflection of the reflecting layer to visible light, while not to the layer that adds lustre to
The color presented has an impact, and needs to control the reflector thickness within the scope of 33-250nm.To guarantee the reflection
Production electric current when layer thickness control is added lustre to layer in 33-250nm, described in deposition is normally controlled in 15-120A, produces power control
System is within the scope of 6-50kW.
Further, it when selecting buffer layer, needs it to possess good anti-oxidant, resistance to corrosion, plays buffering effect,
Damage when reducing reflecting layer sputtering to fabric surface, is also used as the protective layer in reflecting layer, prevents oxygen and moisture from fibre
The dimension non-overlay film side of fabric enters reflecting layer, is corroded to reflecting layer and is aoxidized.Meanwhile buffer layer also wants energy and fabric lining
And there is good cohesive force in reflecting layer, guarantees that subsequent film is perfectly adhered to fabric lining surface.Based on the above reasons and
Add lustre to the selection in layer and reflecting layer, and the present invention selects Ti and/or TiN as buffer layer,
Further, the color presented in order to not influence fabric lining needs to control the thicknesses of layers of buffer layer, invention
People is by a large amount of practice discoveries, when buffer layer is with a thickness of 10-100nm, with good anti-oxidant, resistance to corrosion,
It is more preferable with the binding force in fabric lining and reflecting layer simultaneously.To guarantee that the buffer layer thickness control in 10-100nm, deposits
Production electric current when adding lustre to layer is normally controlled in 10-120A, produces power control within the scope of 4-50kW.
Further, except above-mentioned buffer layer, reflecting layer and adding lustre in addition to layer, the composite film can also include protective layer,
Such as TiO2And/or SiO2And/or the film layers such as TiN, protective layer are the film layers of top in composite film, are on the one hand for protecting
Add lustre to layer, and the layer that avoids adding lustre to falls off in use, causes fabric lining surface mottled, and then asking for irregular colour occur
On the other hand topic can hinder oxygen to enter reflecting layer, improve the durability of schemochrome fabric lining.TiO2、SiO2These
Transparent film layer is smaller as the Color influences that fabric lining is finally presented in protective film, but the sputter rate of these film layers is relatively
It is low, and the faster TiAlN thin film of sputter rate, when thicknesses of layers is excessive, certain influence can be generated to color.
Further, it in order to realize above-mentioned defencive function, avoids influencing the color of fabric lining, while only more shadows
Industrial production efficiency is rung, needs to control the protective layer thickness in 10-70nm.Antiwear property this for TiAlN compared with
For the strong layer that adds lustre to, with excellent binding force, antioxygenic property and wearability, therefore it can not have to apply protection again
Layer.Production electric current when to guarantee that protective layer thickness control adds lustre to layer in 10-700nm, described in deposition is normally controlled in
Production electric current is 10-90A, produces power control in 4-38kW.
Further, in the implementation of the present invention, inventors have found that when needing nitrogen or oxygen to mix work with argon gas
When for working gas, if nitrogen or oxygen proportion are too low, not exclusively, film layer composition is inconsistent, leads for the nitridation or oxidation of metal
Uneven color is caused, if nitrogen or oxygen proportion are too high, it will cause gas wastes, improve production cost.Therefore, working gas
Flowrate proportioning need control just will form outstanding film layer structure in a certain range.By many experiments, inventor's selection
By working gas burden control in following range: when the working gas is argon gas and nitrogen, the then flow-rate ratio of argon gas and nitrogen
For 1:0.5-4；When the working gas is argon gas and oxygen, then the flow-rate ratio of argon gas and oxygen is 1:0.5-4.It is readily appreciated that
If not Nitrogen element or oxygen element in film layer, need to only be passed through argon gas as working gas.
Further, in implementation process of the present invention, the thickness in order to guarantee each film layer produces electric current within the above range
Outside, it is also necessary to control production speed and sputtering time.The production speed, refers to base fabric movement speed, is to influence deposition of thick
One of factor of degree.Speed of production is adjustable in the present invention, range 1-20m/min.It is appreciated that speed of production hair
Changing causes thicknesses of layers to change then fabric lining can be changed therewith by the time used in each film layer target.In order to protect
The thickness for demonstrate,proving each film layer is stable within the above range, while adjusting speed of production, equal proportion is also wanted to adjust each film layer target
General power.There are mainly two types of methods, first is that the quantity of increase and decrease target；Second is that the production electric current of every kind of target of increase and decrease.
Working vacuum degree is also an important factor for realizing production method of the present invention, if vacuum degree is excessively high, coating chamber
Interior gas flow is very few, and the working gas of sputtering can be caused inadequate, and then influences sputter rate；If vacuum degree is too low, plate
The indoor gas flow of film is excessive, and target atom or molecule can be stopped to be splashed to fiber surface, can also reduce sputter rate.Therefore,
Practice discovery through inventor needs to control working vacuum degree within the scope of 8.0E-2-3E-1Pa in process of production, with
Reach optimal sedimentation state.
The present invention also provides a kind of by colored fiber obtained by aforementioned production method, which has abundant
Color and good color fastness, and can be prepared by industrial method.
Colored fiber production method provided by the invention, has the advantage that
1, it by using evaporating deposition technique, is formed including buffer layer, reflecting layer, the layer that adds lustre on fabric lining surface
Composite film, the composite film have good corrosion resistance, wear-resisting property, by be arranged in reflecting layer and fabric lining
Between buffer layer, barrier air directly contacted with reflecting layer, avoid the problem of oxidation of reflecting layer metallic film.
2, using TiAlOx and/or TiAlN as the layer that adds lustre to, by adjusting the thickness for the tunic layer that adds lustre to, fabric lining
Color will change, and with the increase for the thickness degree that adds lustre to, yellow, red, purple, indigo plant successively occurs in fabric lining surface
Color, green, operating process is simple, quick, and the controllability that color is presented in fabric lining is high, is suitable for automation and large-scale industrial
Production.
3, TiAlN film is as the layer that adds lustre to, and membranous layer binding force and high-temperature oxidation resistance are strong, and wearability is excellent, simultaneously
Have the advantages that sputter rate is fast, can be improved production efficiency, is suitble to industrialized production.
4, by deposition protective layer, protection composite film is not easy to be oxidized, and promotes anti-oxidant, the anticorrosive energy of fabric lining
Power increases the service life of fabric lining.
5, fabric lining provided by the invention has good color fastness, meets GB/T 2660-2017 " shirt " standard
It is required that.
6, the feel of the fabric lining after plated film and non-coated fibers fabric is not much different, and the taking of fabric lining is very
It is good.
7, the fabric lining produced has metallic luster, has very much novelty compared with the color that traditional dyeing and finishing technology dyes
Property, more there is stylishness, the Double-faced-color fabric lining that traditional dyeing and finishing cannot achieve can be provided.
8, method provided by the invention it is anhydrous in process of production, without chemical industry material, compared to traditional dyeing technology, greatly
Water resource has been saved, has also been discharged without waste liquid, sludge, toxic gas in production, reduces the pollution to environment, therefore there is green
The advantage of environmental protection.
It in the present invention, can also be combined with each other between above-mentioned each technical solution, to realize more preferred assembled schemes.This
Other feature and advantage of invention will illustrate in the following description, also, certain advantages can become from specification it is aobvious and
It is clear to, or understand through the implementation of the invention.The objectives and other advantages of the invention can by specification, claims with
And it is achieved and obtained in specifically noted content in attached drawing.
Detailed description of the invention
Attached drawing is only used for showing the purpose of specific embodiment, and is not to be construed as limiting the invention, in entire attached drawing
In, identical reference symbol indicates identical component.
Fig. 1 is the structure diagram of the colored fiber of deposition composite film provided by the invention；
Fig. 2 is the visible reflectance light that layer power is the spring Asia 46KW textile fiber fabric surface that adds lustre in the embodiment of the present invention 1
Spectrogram；
Fig. 3 is the visible reflectance light that layer power is the spring Asia 92KW textile fiber fabric surface that adds lustre in the embodiment of the present invention 1
Spectrogram；
Fig. 4 is the visible reflectance light that layer power is the spring Asia 115KW textile fiber fabric surface that adds lustre in the embodiment of the present invention 1
Spectrogram；
Fig. 5 is the visible reflectance light that layer power is the spring Asia 138KW textile fiber fabric surface that adds lustre in the embodiment of the present invention 1
Spectrogram；
Fig. 6 is the visible reflectance light that layer power is the spring Asia 160KW textile fiber fabric surface that adds lustre in the embodiment of the present invention 1
Spectrogram；
Fig. 7 is the visible reflectance spectrogram of the Central European root yarn fiber web surface of the embodiment of the present invention 3；
Fig. 8 is the visible reflectance spectrogram of the Central European root yarn fiber web surface of the embodiment of the present invention 4.
Appended drawing reference:
1- fabric lining substrate；2- buffer layer；The reflecting layer 3-；4- adds lustre to layer；5- protective layer.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention
In attached drawing, technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is
A part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art
Every other embodiment obtained without making creative work, shall fall within the protection scope of the present invention.
In the preparation method specific implementation process of fabric lining surface deposition composite film of the invention, mainly include with
Lower step:
1, fiber base cloth is cleaned first, then dries most of moisture in fabric, keep surface cleaning.
The temperature dried at this time is 50-110 DEG C, and for fabric lining, the too low then drying effect of drying temperature is bad,
The moisture and gas in fiber base cloth cannot be removed, the gas inside base fabric is caused to escape to form gas-bearing formation, hinders film deposition, most
Cause color fastness bad eventually, and the too high tendering of fiber for being easy to make to form base fabric of drying temperature, influence the performance of fabric lining.This
The mode dried in invention can be used the first patent application of inventor (application number: 201810654518.5) the method into
Row, so that having better adhesive force between base fabric and adhesion layer and the layer that adds lustre to.
2, fiber base cloth is fitted into unwinding device, applying tension-proof fabric can entirely transport on transmission device
Row.
3, according to actual production demand, in order to increase the cohesive force of scrim surfaces and composite film, also for promotion base fabric
The compactness of surface recombination film layer, if the moisture of base fabric is excessively high, after base fabric is first sent into the progress reheating drying of heating room,
Processing chamber is re-fed into be produced.The temperature setting of reheating drying is 40-150 DEG C, fiber higher for moisture content
For base fabric, heating, drying is carried out under atmospheric environment, base fabric can get damp again quickly, and therefore, the secondary drying heating needs
It carries out under vacuum environment, and constantly takes the vapor of evaporation from cavity away while heating.
4, according to process requirements, working gas is filled with to each processing chamber.Working gas can be argon gas, argon gas and oxygen
Mixed gas, mixed gas, argon gas and the oxygen of argon gas and nitrogen and the mixed gas of nitrogen, adjust the stream for being filled with gas
Amount guarantees that the vacuum degree of each processing chamber is 8.0E-2-3E-1Pa.
When buffer layer, adjusting total production electric current is 10-120A, and corresponding production power is that (this is production vehicle to 4-50KW
Production power bracket when speed is 1m/min, with the raising production power also equal proportion increase of production speed), film thickness 10-
100nm,；
When deposition of reflective layer, adjusting total production electric current is 15-120A, and corresponding production power is that (this is production vehicle to 6-50KW
Production power bracket when speed is 1m/min, with the raising production power also equal proportion increase of production speed), film thickness 33-
250nm；
When deposition is added lustre to layer, the atomic ratio using Ti and Al in target is 1:1-4:1, and adjusting total production electric current is 30-
500A, corresponding production power are that (this is the production power bracket produced when speed is 1m/min to 12-210KW, with production speed
Raising production power also equal proportion increase), film thickness 10-100nm；
When depositing protective layer, adjusting total production electric current is 10-90A, and production power is that (this is that production speed is to 4-38KW
Production power bracket when 1m/min, with the raising production power also equal proportion increase of production speed), film thickness 10-70nm.
5, it shuts down and deflates after producing, take out fabric lining, sampling carries out color fastness detection to fabric lining, remaining fine
Dimension fabric is put into storage cloth room, completes production.
Specified otherwise is needed, color possessed by fabric lining, because of thicknesses of layers difference, the color presented is had
Institute is different, while the fabric lining obtained using production method, and the color presented is mostly tertiary colour, and so-called tertiary colour refers to
There is also other assisted colors in addition to a dominant hue, for example, fabric color is bluish violet in the embodiment of the present invention 3, i.e., simultaneously
It is tertiary colour with blue and two kinds of colors of purple.
Embodiment 1
Specifically to produce step for scrim surfaces are spun using magnetron sputtering coil film coating technology deposition composite film in spring Asia
It is rapid as follows:
1, spring Asia needed for production is spun and gets out and carry out cleaning, drying, removed surface blot, remove moisture removal.
2, the spring Asia Jing Guo pre-treatment is spun on access unwinding device and fabric is made to keep smooth on its surface, then sealed
Chamber starts to be evacuated, and is sputtered whole targets needed for this production to target table when vacuum degree is raised to 5.0E-3Pa
Face is cleared up.
3, base fabric can first pass through heating room before entering processing chamber, and it is fine to spin the low synthesis of this moisture content for spring Asia
It can also be directly by without carrying out heating, drying for dimension.Surface buffer layer TiN is spun in spring Asia, uses titanium as target
Material, quantity are 4, and the production electric current of each target is set as 30A, and corresponding general power is 47KW, argon flow 150Sccm,
Nitrogen flow is 560Sccm, and the vacuum degree of processing chamber is maintained at 1.5E-1Pa during target as sputter；Then in buffer layer TiN
Upper beginning deposition of reflective layer, reflecting layer use metal Ti, and quantity is 3, and the production electric current of each target is 30A, corresponding total work
Rate is 34KW, argon flow 420Sccm, and Chamber vacuum degree is 1.0E-1Pa when deposition；It continues thereafter in reflecting layer Ti layers of table
Face deposits layer TiAlN that add lustre to, and the atomic ratio of Ti and Al is 1:1 in titanium aluminium target used, and the production electric current of each target is 30A,
Test 4 targets, 8 targets, 11 targets, 13 targets and 15 targets respectively, corresponding general power be respectively 46KW, 92KW, 115KW,
138KW and 160KW, argon flow 150Sccm, nitrogen flow 400Sccm, working vacuum degree 9.6E-2Pa；Finally exist
Add lustre to layer TiAlN layers and deposit protective layer TiN above, use Ti target as target, quantity is 3, the production electric current of each target
For 30A, corresponding general power is 38KW, and argon flow 160Sccm, nitrogen amount stream is 560Sccm, vacuum degree during target as sputter
It is maintained at 1.6E-1Pa.
4, it shuts down, post-depositional sample is sampled, inspection after deflating, visible reflectance spectrogram is tested, by this reality
It applies 5 kinds of samples in example and color fastness detection is carried out with traditional detection method.
The color fastness detection includes fastness to soaping (sample), colour fastness to rubbing, chlorine-resistant water colour fastness, the drift of non-chlorine
Color fastness, colour fasteness to dry cleaning, Actual laundering color fastness (ready-made clothes, fabric), colour fastness to perspiration, color fastness to water, light shine
Test including color fastness, color fastness to sea water, saliva color fastness, the testing result of 5 kinds of samples in the present embodiment can expire
The requirement of sufficient GB/T 2660-2017 " shirt " standard is graded with perspiration fastness at 2 grades or more wherein soaping.
Attached drawing 2,3,4,5,6 be respectively add lustre to layer power be 46KW, 92KW, 115KW, 138KW and 160KW when spring Asia spin
Visible reflectance spectrogram, the increase tunic thickness of adding lustre to production power is also increasing, from attached drawing as can be seen that difference is added lustre to
The corresponding most strong reflection wave band of layer thicknesses of layers is different, is followed successively by red, purple, blue, green as thicknesses of layers increases color
Color.
In the film layer structure of the present embodiment sample, buffer layer TiN film layer is with a thickness of 90nm, reflecting layer Ti thicknesses of layers
When 186nm, 46KW, 92KW, 115KW, 138KW and 160KW, layer TiAlN thicknesses of layers that add lustre to be respectively 20nm, 40nm, 50nm,
60nm and 70nm, protective layer TiN film layer is with a thickness of 70nm.
Embodiment 2
By for scrim surfaces are spun using magnetron sputtering coil film coating technology plating composite film in spring Asia, specific production is walked
It is rapid as follows:
1, spring Asia needed for production is spun and gets out and carry out cleaning, drying, removed surface blot, remove moisture removal.
2, the spring Asia Jing Guo pre-treatment is spun on access unwinding device and fabric is made to keep smooth on its surface, then sealed
Chamber starts to be evacuated, and is sputtered whole targets needed for this production to target table when vacuum degree is raised to 5.0E-3Pa
Face is cleared up.
3, base fabric can first pass through heating room before entering processing chamber, and it is fine to spin the low synthesis of this moisture content for spring Asia
It can also be directly by without carrying out heating, drying for dimension.Surface buffer layer TiN is spun in spring Asia, uses titanium as target,
Quantity is 4, and the production electric current of each target is set as 30A, and corresponding general power is 48.9KW, argon flow 150Sccm, nitrogen
Throughput is 560Sccm, and the vacuum degree of processing chamber is maintained at 1.7E-1Pa during target as sputter；Then on buffer layer TiN
Start deposition of reflective layer, reflecting layer uses metal Ti, and quantity is 3, and the production electric current of each target is 30A, corresponding general power
For 38KW, argon flow 410Sccm, Chamber vacuum degree is 9.8E-2Pa when deposition；It continues thereafter in reflecting layer Ti layer surface
Layer TiAlN that add lustre to is deposited, the atomic ratio of Ti and Al is 1:1 in titanium aluminium target used, and the production electric current of each target is 30A, target
Material quantity is 7, corresponding general power 82kW, argon flow 160Sccm, nitrogen flow 410Sccm, and working vacuum degree is
9.7E-2Pa。
4, it shuts down, post-depositional sample is sampled, inspection after deflating, visible reflectance spectrogram is tested, by this reality
It applies the sample in example and color fastness detection is carried out with traditional detection method.
The color fastness detection includes fastness to soaping (sample), colour fastness to rubbing, chlorine-resistant water colour fastness, the drift of non-chlorine
Color fastness, colour fasteness to dry cleaning, Actual laundering color fastness (ready-made clothes, fabric), colour fastness to perspiration, color fastness to water, light shine
Test including color fastness, color fastness to sea water, saliva color fastness, the sample detection result in the present embodiment are able to satisfy GB/T
The requirement of 2660-2017 " shirt " standard, wherein perspiration fastness grading is at 3 grades or more, and soaping fastness is at 2 grades or more.
In the film layer structure of the present embodiment sample, buffer layer TiN film thickness is 94nm, and reflecting layer Ti film thickness is 207nm, is added lustre to
Layer TiAlN film thickness is respectively 35nm.
Embodiment 3
By for Europe root yarn scrim surfaces are using magnetron sputtering coil film coating technology plating composite film, specific production is walked
It is rapid as follows:
1, Europe root yarn needed for production is got out and is carried out cleaning, drying, remove surface blot, remove moisture removal.
2, the Europe root yarn Jing Guo pre-treatment is accessed on unwinding device and fabric is made to keep smooth on its surface, then sealed
Chamber starts to be evacuated, and is sputtered whole targets needed for this production to target table when vacuum degree is raised to 5.0E-3Pa
Face is cleared up.
3, base fabric can first pass through heating room before entering processing chamber, and the synthesis low for Europe this moisture content of root yarn is fine
It can also be directly by without carrying out heating, drying for dimension.The Europe surface Gen Sha buffer layer TiN uses titanium as target,
Quantity is 4, and the production electric current of each target is set as 25A, and corresponding general power is 38.6KW, argon flow 150Sccm, nitrogen
Throughput is 560Sccm, and the vacuum degree of processing chamber is maintained at 1.8E-1Pa during target as sputter；Then on buffer layer TiN
Start deposition of reflective layer, reflecting layer uses metal Ti, and quantity is 2, and the production electric current of each target is 25A, corresponding general power
For 16.1KW, argon flow 400Sccm, Chamber vacuum degree is 1.2E-1Pa when deposition；It continues thereafter in reflecting layer Ti layers of table
Face deposits layer TiAlN that add lustre to, and the atomic ratio of Ti and Al is 1:1 in titanium aluminium target used, and the production electric current of each target is 30A,
Target quantity is 8, corresponding general power 90.6kW, argon flow 150Sccm, nitrogen flow 400Sccm, working vacuum degree
For 1.3E-1Pa；Protective layer TiN is finally deposited above layer TiAlN layers adding lustre to, and uses Ti target as target, quantity is 3, often
The production electric current of a target is 30A, and corresponding general power is 37.5KW, and argon flow 150Sccm, nitrogen amount stream is 550Sccm,
Vacuum degree is maintained at 1.9E-1Pa during target as sputter.
4, it shuts down, post-depositional sample is sampled, inspection after deflating, visible reflectance spectrogram is tested, by this reality
It applies the sample in example and color fastness detection is carried out with traditional detection method.
The color fastness detection includes fastness to soaping (sample), colour fastness to rubbing, chlorine-resistant water colour fastness, the drift of non-chlorine
Color fastness, colour fasteness to dry cleaning, Actual laundering color fastness (ready-made clothes, fabric), colour fastness to perspiration, color fastness to water, light shine
Test including color fastness, color fastness to sea water, saliva color fastness, the sample detection result in the present embodiment are able to satisfy GB/T
The requirement of 2660-2017 " shirt " standard, wherein perspiration fastness grading is at 3 grades or more, and soaping fastness is at 2 grades or more.
Attached drawing 7 is the visible reflectance spectrogram of Europe root yarn, from figure 7 it can be seen that Europe root yarn is at 430nm and 460nm
There is strong reflection, illustrates that Film color is bluish violet.
In the film layer structure of the present embodiment sample, buffer layer TiN film thickness is 74nm, and reflecting layer Ti film thickness is 88nm, is added lustre to
Layer TiAlN film thickness is respectively 39nm, and protective layer TiN film layer is with a thickness of 72nm.
Embodiment 4
By for Europe root yarn scrim surfaces are using magnetron sputtering coil film coating technology deposition composite film, specific production is walked
It is rapid as follows:
1, Europe root yarn needed for production is got out and is carried out cleaning, drying skill, remove surface blot, remove moisture removal.
2, the Europe root yarn Jing Guo pre-treatment is accessed on unwinding device and fabric is made to keep smooth on its surface, then sealed
Chamber starts to be evacuated, and is sputtered whole targets needed for this production to target table when vacuum degree is raised to 5.0E-3Pa
Face is cleared up.
3, base fabric can first pass through heating room before entering processing chamber, and the synthesis low for Europe this moisture content of root yarn is fine
It can also be directly by without carrying out heating, drying for dimension.The Europe surface Gen Sha buffer layer TiN uses titanium as target,
Quantity is 4, and the production electric current of each target is set as 25A, and corresponding general power is 34.1KW, argon flow 150Sccm, nitrogen
Throughput is 560Sccm, and the vacuum degree of processing chamber is maintained at 1.8E-1Pa during target as sputter；Then on buffer layer TiN
Start deposition of reflective layer, reflecting layer uses metal TiAl target, and the atomic ratio of Ti and Al are 1:1, and target quantity is 4, each target
The production electric current of material is 30A, and corresponding general power is 45.5KW, argon flow 400Sccm, and Chamber vacuum degree is when deposition
1.3E-1Pa；It continues thereafter with and deposits layer TiAlN that add lustre to, the atom of Ti and Al in titanium aluminium target used in reflecting layer TiAl layer surface
Than being 30A for the production electric current of 1:1, each target, target quantity is 8, corresponding general power 91.2kW, and argon flow is
150Sccm, nitrogen flow 400Sccm, working vacuum degree 1.3E-1Pa；Finally protect adding lustre to deposit above layer TiAlN layers
Sheath TiN uses Ti target as target, and quantity is 3, and the production electric current of each target is 30A, and corresponding general power is
37.9KW, argon flow 150Sccm, nitrogen amount stream are 550Sccm, and vacuum degree is maintained at 1.9E-1Pa during target as sputter.
4, it shuts down, post-depositional sample is sampled, inspection after deflating, visible reflectance spectrogram is tested, by this reality
It applies the sample in example and color fastness detection is carried out with traditional detection method.
The color fastness detection includes fastness to soaping (sample), colour fastness to rubbing, chlorine-resistant water colour fastness, the drift of non-chlorine
Color fastness, colour fasteness to dry cleaning, Actual laundering color fastness (ready-made clothes, fabric), colour fastness to perspiration, color fastness to water, light shine
Test including color fastness, color fastness to sea water, saliva color fastness, the sample detection result in the present embodiment are able to satisfy GB/T
The requirement of 2660-2017 " shirt " standard, wherein perspiration fastness grading is at 3 grades or more, and soaping fastness is at 2 grades or more.
Attached drawing 8 be Europe root yarn visible reflectance spectrogram as the spectrogram of embodiment 3 at 430nm and 460nm
There is strong reflection.Illustrate that Ti and TiAl are little as color fastness and Color influences of the reflecting layer to film layer, meets preferred Ti in invention
Explanation as reflecting layer.
In the film layer structure of the present embodiment sample, buffer layer TiN film thickness is 65nm, and reflecting layer TiAl film thickness is 180nm, raw
Chromatograph TiAlN film thickness is respectively 40nm, and protective layer TiN film layer is with a thickness of 72nm.
Embodiment 5
By for scrim surfaces are spun using magnetron sputtering coil film coating technology plating composite film in spring Asia, specific production is walked
It is rapid as follows:
1, spring Asia needed for production is spun and gets out and carry out pre-treating technology, removed surface blot, remove moisture removal.
2, the spring Asia Jing Guo pre-treatment is spun on access unwinding device and fabric is made to keep smooth on its surface, then sealed
Chamber starts to be evacuated, and is sputtered whole targets needed for this production to target table when vacuum degree is raised to 5.0E-3Pa
Face is cleared up.
3, base fabric can first pass through heating room before entering processing chamber, and it is fine to spin the low synthesis of this moisture content for spring Asia
It can also be directly by without carrying out heating, drying for dimension.Surface buffer layer TiN is spun in spring Asia, uses titanium as target,
Quantity is 4, and the production electric current of each target is set as 30A, and corresponding general power is 44.1KW, argon flow 160Sccm, nitrogen
Throughput is 560Sccm, and the vacuum degree of processing chamber is maintained at 1.6E-1Pa during target as sputter；Then on buffer layer TiN
Start deposition of reflective layer, reflecting layer uses metal Ti, and quantity is 3, and the production electric current of each target is 30A, corresponding general power
For 37KW, argon flow 410Sccm, Chamber vacuum degree is 1.0E-1Pa when deposition；It continues thereafter in reflecting layer Ti layer surface
Layer TiAlN that add lustre to is deposited, the atomic ratio of Ti and Al is 1:1 in titanium aluminium target used, and the production electric current of each target is 30A, target
Material quantity is 8, corresponding general power 92.7kW, argon flow 160Sccm, nitrogen flow 410Sccm, and working vacuum degree is
9.7E-2Pa；Protective layer TiN is finally deposited above layer TiAlN layers adding lustre to, and uses Ti target as target, quantity is 3, each
The production electric current of target is 30A, and corresponding general power is 34KW, and argon flow 150Sccm, nitrogen amount stream is 550Sccm, target
Vacuum degree is maintained at 1.8E-1Pa during sputtering.
4, it shuts down, post-depositional sample is sampled, inspection after deflating, visible reflectance spectrogram is tested, by this reality
It applies the sample in example and color fastness detection is carried out with traditional detection method.
The color fastness detection includes fastness to soaping (sample), colour fastness to rubbing, chlorine-resistant water colour fastness, the drift of non-chlorine
Color fastness, colour fasteness to dry cleaning, Actual laundering color fastness (ready-made clothes, fabric), colour fastness to perspiration, color fastness to water, light shine
Test including color fastness, color fastness to sea water, saliva color fastness, the sample detection result in the present embodiment are able to satisfy GB/T
The requirement of 2660-2017 " shirt " standard, wherein perspiration fastness grading is at 3 grades or more, and soaping fastness is at 2 grades or more.
In the film layer structure of the present embodiment sample, buffer layer TiN film thickness is 84nm, and reflecting layer TiAl film thickness is 202nm, raw
Chromatograph TiAlN film thickness is respectively 40nm, and protective layer TiN film layer is with a thickness of 65nm.
Finally, it should be noted that the above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；To the greatest extent
Pipe present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that: its according to
So be possible to modify the technical solutions described in the foregoing embodiments, or to some or all of the technical features into
Row equivalent replacement；And these are modified or replaceed, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution
The range of scheme.
Claims (10)
1. a kind of production method of colored fiber fabric, which comprises the following steps:
By vacuum deposition, at least one surface of fabric lining deposits one or more layers composite film, and the composite film is certainly
It is lower and upper including buffer layer, reflecting layer and the layer that adds lustre to；
The layer that adds lustre to includes TiAlOxAnd/or TiAlN；
When depositing each layer of the composite film, it is both needed to be continually fed into working gas, the working gas includes argon gas and/or nitrogen
Gas and/or oxygen.
2. the production method of colored fiber fabric according to claim 1, which is characterized in that add lustre to what layer used described in deposition
The atomic ratio of target, Ti and Al are 1:1-4:1.
3. the production method of colored fiber fabric according to claim 1, which is characterized in that raw when adding lustre to described in deposition layer
Electricity production stream is 30-500A, and production power is 12-210kW；The layer that adds lustre to a thickness of 10-100nm.
4. the production method of colored fiber fabric according to claim 1, which is characterized in that the buffer layer include Ti and/
Or TiN.
5. the production method of colored fiber fabric according to claim 1, which is characterized in that raw when depositing the buffer layer
Electricity production stream is 10-120A, and production power is 4-50kW；The buffer layer thickness is 10-100nm.
6. the production method of colored fiber fabric according to claim 1, which is characterized in that the reflecting layer includes Ti, no
Become rusty at least one of steel, TiAl, Cu and Ag.
7. the production method of colored fiber fabric according to claim 1, which is characterized in that raw when depositing the reflecting layer
Electricity production stream is 15-120A, and production power is 6-50kW；The reflector thickness is 33-250nm.
8. the production method of colored fiber fabric according to claim 1, which is characterized in that the composite film further includes protecting
Sheath, the protective layer include TiO2And/or SiO2And/or TiN.
9. the production method of colored fiber fabric according to claim 7, which is characterized in that raw when depositing the protective layer
Electricity production stream is 10-90A, and production power is 4-38kW；The protective layer thickness is 10-70nm.
10. a kind of colored fiber fabric, which is characterized in that using any one of claim 1-10 the method, in fibrous face
Material surface deposition composite film obtains.
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| CN111593557A (en) * | 2020-06-03 | 2020-08-28 | 广东欣丰科技有限公司 | Colored antibacterial fabric and manufacturing method thereof |
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| JP2017061719A (en) * | 2015-09-24 | 2017-03-30 | 公益財団法人若狭湾エネルギー研究センター | Forming method for a colored silicon thin film |
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