CN110384637A

CN110384637A - A kind of sunlight screening skin-protecting product substituting ultraviolet absorbing agent

Info

Publication number: CN110384637A
Application number: CN201910817000.3A
Authority: CN
Inventors: 陈潇
Original assignee: Shanghai Keyan Biotechnology Co Ltd
Current assignee: Shanghai Keyan Biotechnology Co Ltd
Priority date: 2019-08-30
Filing date: 2019-08-30
Publication date: 2019-10-29

Abstract

The present invention relates to skin care fields, relate more specifically to a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent.The raw material of the sunlight screening skin-protecting product includes biological carbohydrate gum -4, silk ball fungus extract and edelweiss extract.The sunlight screening skin-protecting product of substitution ultraviolet absorbing agent provided by the invention, can replace the sun-prevention components such as conventional Orangic sunscreen, absorb full wave ultraviolet light, improve SPF and stability, improve skin elasticity and wrinkling resistance, and be suitable for all types of skin.And the present invention passes through the combination of each component of the sunlight screening skin-protecting product, moreover it is possible to which effectively defence blue light and feux rouges avoid electronic product etc. to the injury of skin, achievees the effect that protect at many levels.

Description

A kind of sunlight screening skin-protecting product substituting ultraviolet absorbing agent

Technical field

The present invention relates to skin care fields, more particularly it relates to a kind of sun-proof shield for substituting ultraviolet absorbing agent Skin product.

Background technique

Solar radiation is radiated including about 5% ultraviolet light (UV), and wavelength is 200nm~400nm, is divided into 320~400nm (UVA), three areas 290~320nm (UVB) and 200~290nm (UVC).Most UVC radiation is absorbed by ozone layer, therefore right The harm of human body main composition is UVA and UVB radiation.UVA can cause the DNA structure in Skin Cell damage and protein and The destruction of other biological molecule influences the immune system function of human body, causes dermal lesions and wrinkle, or even cause cancer.UVB Skin can be caused to generate erythema and blister, generate melanin pigmentation, reduce the amount of the enzyme of antioxidation in skin, weaken skin The ability of free radical resisting.Therefore, it defends UVA and UVB radiation to escape injury protection human body, delays senescence most important.

Sun-screening agent common at present has Orangic sunscreen and inorganic sunscreen, and conventional organic sunscreen ingredient is easy by skin It absorbs, enters in internal metabolism cycle, to generate stimulation to skin, bring security risk, and it is mainly absorbed The UVA of long wavelength, it is relatively small to the absorption of the UVB of medium wavelength.And it is airtight when the inorganic sunscreen use of routine, it is sticky, It is easy to produce heavy feeling, so that skin is easy whiting, influence the sensory experience of user.It is easy blocking pore simultaneously, it cannot It is used for a long time.And this kind of sun-prevention components mainly absorbs the UVB of medium wavelength, and it is insufficient to the absorption of the UVA of long wavelength.In Under the premise of guaranteeing sun-proof result, make every effort to find some mild skin care ingredient synergy to improve sun-proof result, to subtract Few sun-screening agent dosage reduces the possible irritation of sun-screening agent and security risks, develops more mild effective high-tech Skill sunscreen cosmetic.

Patent document CN102302417A is by oceanic shellfish active peptide, marine collagen protein peptides, algal polysaccharides and sun-screening agent It is combined, while reducing sun-screening agent dosage, improves its sun-proof ability and Product Safety.Patent document CN201510104419.6 provides a kind of containing navel shape seaweed extract, Dunaliella salina algae extract, haematococcus pluvialis extraction The cosmetic composition of object, sea water pearls powder, but its ultraviolet radiation absorption, sun-proof ability are not mentioned significantly It rises, also there is still a need for the bis-ethylhexoxyphenol methoxyphenyl triazine of 0.4~35% content, diethylamino hydroxybenzoyl benzoyl The organic uv absorbers such as hexyl-benzoate can be only achieved satisfactory SPF.

In addition, in the whole people's all nets, no matter everybody mobile phone works or entertains not from the age of hand, in face of electronic product when Between absolutely than contact daylight it is more.The blue light discharged in the middle can penetrate epidermis, and the situation of microgroove and relaxation occurs in accelerated ageing. Although more and more research reports think feux rouges also to skin moreover, influence of the feux rouges to skin is small far beyond ultraviolet light Cause a degree of harm.Few it is therefore desirable to develop a organic sunscreen Ingredient Amount, SPF is high, fully absorb or The light such as full wave ultraviolet light, blue light, feux rouges are reflected, and are suitable for the safe and stable sun-proof skin care of all types of skins Product.

Summary of the invention

To solve the above-mentioned problems, the present invention provides a kind of sunlight screening skin-protecting products for substituting ultraviolet absorbing agent, described anti- The raw material for shining skin care item includes biological carbohydrate gum -4, silk ball fungus extract and edelweiss extract.

As a preferred technical solution of the present invention, the silk ball fungus extract and the edelweiss extract Weight ratio is (0.2~5): 1.

As a preferred technical solution of the present invention, the silk ball fungus extract and the edelweiss extract Weight ratio is (0.3~3): 1.

As a preferred technical solution of the present invention, the weight ratio of the biology carbohydrate gum -4 and the silk ball fungus extract For (0.6~6): 1.

As a preferred technical solution of the present invention, the raw material of the sunlight screening skin-protecting product by weight, including 3~6 The biological carbohydrate gum -4 of part, 1~5 part of silk ball fungus extract and 1~5 part of edelweiss extract.

As a preferred technical solution of the present invention, the raw material of the sunlight screening skin-protecting product by weight, including 4~5 The biological carbohydrate gum -4 of part, 1~3 part of silk ball fungus extract and 1~3 part of edelweiss extract.

As a preferred technical solution of the present invention, the raw material of the sunlight screening skin-protecting product further include 0.1~2 parts by weight without Machine sun-screening agent.

As a preferred technical solution of the present invention, the inorganic sunscreen is selected from zinc oxide, titanium dioxide, oxidation One of iron, silica are a variety of.

As a preferred technical solution of the present invention, the raw material of the sunlight screening skin-protecting product further include moisturizer, emollient, Emulsifier, Orangic sunscreen, additive.

As a preferred technical solution of the present invention, the sunlight screening skin-protecting product be selected from suncream, sunscreen, sun water, One of suntan lotion, sun-proof facial mask, sun-proof foundation emulsion, sun-proof essence, sun-proof condensation, sun protection gel and sunscreen spray are more Kind.

Compared with the prior art, the invention has the following beneficial effects: substitution ultraviolet absorbing agent provided by the invention is anti- Skin care item are shone by the synergistic effect between biological carbohydrate gum -4, silk ball fungus extract and edelweiss, can replace having for routine The sun-prevention components such as machine sun-screening agent can absorb full wave ultraviolet light, improve SPF and stability, improve skin elasticity and resist Wrinkle ability, and it is suitable for all types of skin；And sunlight screening skin-protecting product provided by the invention is extracted by further addition butterflybush flower Object acts synergistically with glucityl rutin, can be further reduced the dosage of conventional sunscreen agent, improves SPF and stabilization Property.In addition, passing through the combination of large biological molecule film technique and the sun-proof technology of biological composition in the present invention, biological sugar is utilized Under synergistic effect between the Multiple components such as glue -4, edelweiss extract, inorganic sunscreens ingredient, routine can not only be substituted Chemical sunscreen ingredients, reduce the dosage of chemical sunscreen ingredients, moreover it is possible to effectively defence the light such as blue light and feux rouges, avoid electronics These harmful light that the equipment such as product issue penetrate skin, and for extended residual inside skin, stimulation skin generates active oxidation Substance, accelerated oxidation are led to aging, fragile, dry and water shortage；Also it helps avoid upsetting point of melatonin because of these light It secretes, causes pigementation, free radical increases or even blackening, the appearance for the problems such as spot and wrinkle occur.

Specific embodiment

The detailed description for preferred implementation method of the invention below of participating in the election of and including embodiment this hair can be more easily to understand Bright content.Unless otherwise defined, all technologies used herein and scientific term have common with fields of the present invention The normally understood identical meaning of technical staff.When there is a conflict, the definition in this specification shall prevail.

Equivalent, concentration or other values or parameter are excellent with range, preferred scope or a series of upper limit preferred values and lower limit When the Range Representation that choosing value limits, this should be understood as specifically disclosing by any range limit or preferred value and any range Any pairing of lower limit or preferred value is formed by all ranges, regardless of whether the range separately discloses.For example, when open When range " 1 to 5 ", described range should be interpreted as including range " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to 5 ", " 1 to 3 and 5 " etc..When numberical range is described herein, unless otherwise stated, otherwise the range is intended to include its end Value and all integers and score in the range.

Singular includes that plural number discusses object, unless the context clearly dictates otherwise." optional " or it is " any It is a kind of " refer to that the item described thereafter or event may or may not occur, and the description include situation that event occurs and The situation that event does not occur.

Approximate term in specification and claims is used to modify quantity, and it is specific to indicate that the present invention is not limited to this Quantity further includes the acceptable modified part without will lead to the change of dependency basis this function close with the quantity.Phase It answers, modifies a numerical value with " about ", " about " etc., mean that the present invention is not limited to the exact numericals.In some examples, approximate Term likely corresponds to the precision of the instrument of measurement numerical value.In present specification and claims, range limits can be with Combination and/or exchange, these ranges if not stated otherwise include all subranges contained therebetween.

In addition, indefinite article "an" before element of the present invention or component and "one" quantitative requirement to element or component (i.e. frequency of occurrence) unrestriction.Therefore "one" or "an" should be read as including one or at least one, and odd number The element or component of form also include plural form, unless the obvious purport of the quantity refers to singular.

Illustrate the present invention below by way of specific embodiment, but is not limited to specific examples presented below.

The present invention provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, the sunlight screening skin-protecting product includes biology sugar Glue -4, silk ball fungus extract and edelweiss extract.

Biological carbohydrate gum -4

Biological carbohydrate gum -4 is by biofermentation technique by plant fermentation come L-fucose, 2- containing acetyl collateralization The high molecular polymer of D- galactolipin and glucuronic acid repetitive unit.It has effects that moisturizing is repaired, while can be in skin table Face forms physics barrier film, prevents dust or fine grained pollutant from adhering to, and then can also reduce the generation of skin surface free radical. In addition, biological carbohydrate gum -4 forms ventilative sugared film on the skin, brilliant skin sense is not only provided, a kind of day of skin is more considered as Right protective agent can form one layer of tridimensional network in skin surface.This layer have defencive function active film just as Human body second layer skin is the same, can limit the extraneous invasion for skin, such as ultraviolet light, pollution, heavy metal ion, reduce Product irritation.And -4 water binding ability of biological carbohydrate gum is very strong, even if soaking effect is good in the environment of low humidity, simultaneously Ventilative sugared film is formed in skin surface, prevents moisture of skin from evaporating once again, and there is instant and long-acting replenishing water and preserving moisture effect.This Outside, -4 pairs of ultraviolet lights of biological carbohydrate gum also have certain barriering effect, and skin is enabled to be effectively protected in atmosphere pollution and light pollution.

Silk ball fungus extract

Sparassis crispa also known as silk ball mushroom, containing a large amount of protein, carbohydrate, multivitamin, a variety of amino acid and Dietary fiber and ash content, minerals etc..Wherein, Sparassis crispa contains a large amount of beta glucan, and beta glucan is a kind of bioactivity Substance has the multiple functions such as immunological regulation, anti-inflammatory, antiviral, anti-oxidant, anti-radiation；Vitamin E, dimension life in Sparassis crispa Plain C has antioxidation；Contain a large amount of antioxidant in Sparassis crispa, such as hepatocuprein can effectively clear body Interior free radical prevents active oxygen from playing the role of anti-oxidant, anti-aging to the damage of body.

In one embodiment, silk ball fungus extract of the present invention is purchased from South Korea biospectrum.

Inorganic sunscreen

Inorganic sunscreen is a kind of white inorganic mineral dust, and sun-proof mechanism is related with powder diameter size.Work as partial size When larger, sun-proof mechanism is simple covering effect, and this kind of powder forms coating in skin surface, being irradiated to skin surface Ultraviolet reflection or scatter out, to reduce into the ultraviolet light content in skin, belong to physical shielding action, institute To be also referred to as ultraviolet light screener, anti-sunlight function is weaker.But with the reduction of powder diameter, such sun-screening agent is to the anti-of ultraviolet light It penetrates, scattering power reduction, and the absorbability of UVB is remarkably reinforced, when partial size is small arrives nanoscale, sun-proof mechanism is can be anti- It penetrates, scatter UVA, and UVB can be absorbed, anti-sunlight function is stronger.

Preferably, inorganic sunscreen of the present invention in zinc oxide, titanium dioxide, iron oxide, silica one Kind is a variety of.

It is highly preferred that inorganic sunscreen of the present invention is selected from zinc oxide and titanium dioxide.

It is further preferred that the partial size of zinc oxide of the present invention is 30~100nm.

It is further preferred that the partial size of titanium dioxide of the present invention is 30~120nm.

Partial size of the present invention be average grain diameter, average grain diameter be in size distribution curve cumulative distribution be 50% when most The equivalent diameter of bulky grain.For one by the molecular practical population of the different grain of size and shape, with one by equal The hypothetical particle faciation ratio of one spheroidal particle composition claims the diameter of this spheroidal particle if the partial size overall length of the two is identical For the average grain diameter of practical population.The test method of average grain diameter is known to those skilled in the art.

In one embodiment, the raw material of sunlight screening skin-protecting product of the present invention further includes Orangic sunscreen, moisturizer, profit Skin agent, emulsifier, additive.

Orangic sunscreen

Orangic sunscreen is a kind of organic compound to ultraviolet light with preferable absorption, also referred to as ultraviolet radiation absorption Agent.This substance energy selective absorbing ultraviolet light, molecular structure is different, selects the wave band of the ultraviolet light absorbed also different, some Sun-screening agent mainly absorbs UVB, some sun-screening agents mainly absorb UVA, and some sun-screening agents belong to broad spectrum sunscreen, can absorb UVB, and UVA can be absorbed.The luminous energy of the ultraviolet light of absorption is converted to thermal energy by this kind of sun-screening agent, while its own structure does not occur Variation.

In a preferred embodiment, Orangic sunscreen of the present invention is selected from benzoate, salicylic acid, meat One of cinnamic acid salt, benzophenone class, triazines, triazole type sun-screening agent are a variety of.

As the example of benzoate sun-screening agent, including but not limited to, p-aminobenzoic acid, p-aminobenzoic acid list are sweet Grease, Uvinul A Plus.

As the example of salicylic acid salt sun-screening agent, including but not limited to, amyl salicylate, salicylate, salicylic acid are high Ester, octyl salicylate, phenyl salicylate, benzyl salicylate, salicylic acid are to isopropanol phenyl ester.

As the example of cinnamic acid salt sun-screening agent, including but not limited to, cinnamic acid monooctyl ester, 4- isopropyl cinnamic acid second Ester, 2,5- diisopropyl methyl cinnamate, 2,4- diisopropyl methyl cinnamate, p-methoxycinnamic acid propyl ester, to methoxyl group Isopropyl cinnamate, ethylhexyl methoxy cinnamate.

As the example of benzophenone class sun-screening agent, including but not limited to, 2,4-DihydroxyBenzophenone, 2,2 '-dihydroxy -4- Methoxy benzophenone.

As the example of triazines sun-screening agent, including but not limited to, bis-ethylhexoxyphenol methoxyphenyl triazine, ethyl Hexyl triazinone.

As the example of triazole type sun-screening agent, including but not limited to, 2,2 '-hydroxy-5-methyl base phenyl benzotriazole, 2- (2 '--5 '-t-octyl phenyl of hydroxyl) benzotriazole.

Preferably, Orangic sunscreen of the present invention is selected from Uvinul A Plus, ethylhexyl Triazinone, bis-ethylhexoxyphenol methoxyphenyl triazine, ethylhexyl methoxy cinnamate, di-2-ethylhexylphosphine oxide-benzotriazole tetramethyl One of base butylphenol is a variety of.

Uvinul A Plus: oil-soluble UVA sun-screening agent, can anti-part UVB, being widely used in has In the sunscreen formula of high sun protection factor, the ultraviolet light in daylight can be effectively absorbed, prevents human skin sunburn, tanned, sunburn, The ultraviolet light of absorbable 340~400nm.

Uvinul T 150: oil-soluble UV sun-screening agent can absorb the ultraviolet light of 280~380nm.

Bis-ethylhexoxyphenol methoxyphenyl triazine: wide spectrum UV sun-screening agent can absorb the ultraviolet light of UVB and UVA wave band, The ultraviolet light of absorbable 310~343nm.

Ethylhexyl methoxy cinnamate: UV sun-screening agent can effectively prevent the ultraviolet light of 280-310nm, and absorptivity is high, Non-stimulated to skin, safety is good.

Di-2-ethylhexylphosphine oxide-benzotriazole tetramethyl butyl phenol: newer broad spectrum sunscreen can absorb ultraviolet (UV) A and UVB, Good light stability is not absorbed by the skin, and can absorb the ultraviolet light of 305~360nm.

Moisturizer

In one embodiment, moisturizer of the present invention is selected from polyalcohols, natural polysaecharides, betaines moisturizing One of agent is a variety of.

As the example of polyalcohols moisturizer, including but not limited to, glycerol, 1,3-PD, 2- methyl-1,3- the third two Alcohol, erythrite, gluconic acid, 1,2,6- hexanetriol, inositol, lactitol.

As the example of natural polysaecharides moisturizer, including but not limited to, hyaluronic acid, heparin, gathers hyaluronan Their alkali metal salt under glucuronic acid, pectin and appropriate situation.

As the example of betaines moisturizer, including but not limited to, glycine betaine and its derivative.What can be enumerated has, Decyl betaine, lauryl betaine.

Preferably, moisturizer of the present invention is selected from glycerol, 1,2- pentanediol, propylene glycol, Sodium Hyaluronate, beet root and mentions Take one of object or a variety of.

Beet root extract: having strong hygroscopicity, can provide large quantity of moisture for skin, the formation for protein, DNA is repaired, and the activity of enzyme is very important, and has brilliant osmotic pressure adjustment effect.

Emollient

In one embodiment, emollient of the present invention is selected from ring five dimethyl silicone polymer, polydimethylsiloxanes Alkane, cyclohexasiloxane, diisopropyl sebacate, carbonic acid dioctyl ester, glycerol three (thylhexoic acid) ester, Permethyl 99A, isononanoic acid are different One of nonyl ester, cetostearyl alcohol ethylhexoate, jojoba seed oil, saualane, vaseline are a variety of.

Preferably, emollient of the present invention is ring five dimethyl silicone polymer and/or carbonic acid dioctyl ester.

Emulsifier

In one embodiment, emulsifier of the present invention is selected from methyl sesquistearate, cetostearyl alcohol - 6 olive oleate of polyethers, glycerin monostearate and polyethylene glycol stearate, stearine, cetearyl glucose Glycosides, PEG-10 Polydimethylsiloxane, lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone, the poly- diformazan of PEG-9 One of radical siloxane, Plantacare 818 are a variety of.

Preferably, emulsifier of the present invention is Plantacare 818.

Plantacare 818: one kind of new non-ionic surfactants has both conventional nonionic and anion surface active The characteristic of agent, acidproof, alkaline-resisting, insensitive to electrolyte and skin compatibility are good.Making emulsifier has the stimulation for reducing formula Property, the effects of increasing the moistening effect of formula, improve the efficiency of functional product.The moistening effect that lotion can be improved, to function Energy property product more has good slow release effect, has good compatibility, can be used in multiple skin care products.

Edelweiss extract

Edelweiss contains the chemical components such as caffeic acid, vanillic acid, aldehyde compound containing phenolic hydroxyl group, has height From imperial ability, atrocious weather and other growing environments can be resisted.Minerals rich in, natural beauty in its active constituent Bai Chengfen and aromatising essence, can mild and deep layer cleaning skin, remove pollution in the grease and pore of epidermis, while skin of releiving Skin tense situation releives to skin tool, calm, anti-oxidant and nourishing protective effect.The active ingredient for extracting edelweiss is answered Use in daily whitening product, can effectively releive, calm skin, harmful substance in skin is discharged, have preferable whitening, moisturizing, Moisturizing and anti-wrinkle effect can give skin thoughtful nourishing care, allow skin to stay pale for a long time delicate.

In one embodiment, edelweiss extract of the present invention is purchased from dutch royal Royal DSM group.

It is found by the applicant that biological carbohydrate gum -4 is added and silk ball fungus extract, edelweiss mention simultaneously in sunlight screening skin-protecting product When taking object, can while reducing organic sunscreen Ingredient Amount, significantly improve suncream to the absorption of whole wave band ultraviolet with Reflecting effect improves SPF.The sticky and heavy feeling of suncream can also be significantly improved simultaneously.Itself the possible reason is due to It is improved under synergistic function between biological carbohydrate gum -4 and silk ball fungus extract, edelweiss extract effective component purple The activity of outer line absorption ingredient and susceptibility to ultraviolet light increase absorption and reflection to ultraviolet light, thus seldom being added It measures, or even be added without conventional organic sunscreen ingredient can also have very high SPF.Biological carbohydrate gum -4 is via fermentation work What skill was obtained from natural plants, L-fucose, 2-D- galactolipin and glucuronic acid repetitive unit containing acetyl collateralization High molecular polymer, in silk ball fungus extract beta glucan, in edelweiss extract containing phenolic hydroxyl group Can be good at dispersing between aldehyde compound etc. it is compatible obtain stable system, avoid corresponding ingredient in system high temperature, Chemical structure changes and loses sun-proof result under the effects of intensive ultraviolet.Simultaneously when in use, with the ring five in system The volatilization of the ingredients such as dimethyl silicone polymer, water, the inorganic particulates ingredients such as zinc oxide, titanium dioxide in system and above-mentioned acetyl The effects of L-fucose of collateralization, 2-D- galactolipin, glucuronic acid, beta glucan, aldehyde compound containing phenolic hydroxyl group, Be dispersed in inorganic particulate in mentioned component, and wherein acetyl group, aldehydic acid base isopolarity group under the action of quickly Gel forms protective film in skin surface, reduces the transmitance of ultraviolet light.Simultaneously as said components are to zinc oxide, titanium dioxide The gel stability of the ingredients such as titanium acts on, and avoids above-mentioned inorganic particulate ingredient to the infiltration inside skin, the pore that results in blockage, allergy Etc. symptoms appearance, since the synergistic function of above-mentioned effective component reduces zinc oxide, titanium dioxide to a certain extent The dosage of equal ingredients is not easy that skin is made to whiten, improves the sense of user to further improve the sticky and heavy feeling of suncream Official's experience.

In addition, silk ball fungus extract and edelweiss extract can increase to a certain extent biological carbohydrate gum -4 and have Active force between the ingredients such as machine sun-screening agent combines these components and is stabilized in biological carbohydrate gum -4, silk ball fungus extract and high mountain In the cavity formed between the components such as HUORONGCAO extract, the stability of these ingredients is improved, these ingredients is avoided to absorb purple Small molecule is resolved into after outside line, is accelerated by the absorption of skin.In traditional sunlight screening skin-protecting product, since organic sunscreen ingredient is in purple Small molecule compound is decomposed to form under the action of outside line, these compounds make in the absorbability for substantially losing ultraviolet light Suncream cannot be persistently sun-proof.Meanwhile above-mentioned small molecule compound is quickly absorbed by endothelial cell, it is unnecessary to generate to skin Stimulation, cause the side reactions such as allergy, erythema, redness, limit its application.And silk ball fungus extract, high mountain in the present invention HUORONGCAO extract, and biological carbohydrate gum -4 wait under the synergistic effect between ingredients, while significantly improving sun-proof ability, mention Its high safety widens it and uses object range.

Preferably, the weight ratio of silk ball fungus extract of the present invention and the edelweiss extract be (0.2~ 5): 1.

It is highly preferred that the weight ratio of silk ball fungus extract of the present invention and the edelweiss extract be (0.3~ 3): 1.

It is further preferred that the weight ratio of silk ball fungus extract of the present invention and the edelweiss extract is 1: 1。

It is further preferred that it is of the present invention biology carbohydrate gum -4 and the silk ball fungus extract weight ratio be (0.6~ 6): 1.

It is found by the applicant that when silk ball fungus extract is compounded at a specific ratio with edelweiss extract for skin care item, The sun-proof skin care effect of skin care item can be significantly improved.Specifically, the SPF of skin care item can be significantly improved, using very On a small quantity, in the case where or even without using conventional organic sunscreen ingredient, very high sun-proof index can still be obtained.Secondly, also The elasticity and anti-aging ability of skin can be improved to a certain extent.Moreover, preparing resulting skin care item with excellent high temperature Stability can play lasting anti-sunlight function.Itself the possible reason is, in edelweiss extract contain amino acid, albumen The ingredients such as matter, polysaccharide, flavones, saponin(e, cumarin, organic acid, can mild and deep layer cleaning inner skin, remove the oil of epidermis Pollution in rouge and pore, promote effective component in edelweiss extract and silk ball fungus extract and dermal endothelial cell it Between active force.On the one hand, work is cooperateed between edelweiss extract and silk ball fungus extract and human epidermal cell Under, the activity of GSH (glutathione) can be activated and improve, cutin HaCaT cell is under the induction of UVB in inhibition epidermis Consumption to GSH, and intraepidermal GSH has the function of small molecule antioxidant, can consume in epidermis due to ultraviolet light irradiation The free radical of formation.On the other hand, the aldehydes chemical combination containing phenolic hydroxyl group in edelweiss extract and silk ball fungus extract The chemical components such as object can absorb ultraviolet light, inhibit the shape of melanin under the action of between cell tissue corresponding in epidermis At, while promoting the synthesis of keratohyalin, increase the thickness of stratum granulosum in epidermis, resists and protection skin is to ultraviolet light It destroys, improves the quality of skin.

In addition, the effective components such as all kinds of glucans, protein in silk ball fungus extract are in edelweiss extract Under synergistic effect between the effective components such as amino acid, organic acid, by components such as various enzymes in human epidermal cell Activation, helps that human keratinous formation cell and fibroblast is protected not to be destroyed, and reduces its death under UVB irradiation Rate.Can promote simultaneously with the amino acid such as proline, glycine, hydroxyproline, oxylysine in activating skin, make above-mentioned Under the effects of corresponding enzyme of the aminoacid ingredient in epidermal cell, the ultraviolet light even absorbed can dehydrating condensation form peptide Chain eventually forms collagen further across the process of procollagen, improves the thickness of skin corium, to improve skin Elasticity and wrinkling resistance, have skin anti-aging moist.And in L-fucose, the 2-D- galactolipin being branched containing acetyl Under synergistic effect between glucuronic acid, beta glucan, aldehyde compound containing phenolic hydroxyl group etc., system can be protected In high active ingredient, avoid its under the conditions ofs high temperature, intensive ultraviolet etc. go bad and fail.

In a preferred embodiment, the raw material of sunlight screening skin-protecting product of the present invention by weight, including 3~6 The biological carbohydrate gum -4 of part, 1~5 part of silk ball fungus extract and 1~5 part of edelweiss extract.

In a kind of preferred embodiment, the raw material of sunlight screening skin-protecting product of the present invention by weight, including 4~ 5 parts of biological carbohydrate gums -4,1~3 part of silk ball fungus extract and 1~3 part of edelweiss extract.

In a preferred embodiment, the raw material of sunlight screening skin-protecting product of the present invention further include 0.1~2 parts by weight without Machine sun-screening agent.

Additive

In one embodiment, additive of the present invention includes that freshener, antioxidant, preservative, functionality help Agent.

As the example of freshener, including but not limited to, peppermint derivative, mint extract.What can be enumerated has peppermint Oil, menthol, peppermint oil, menthyl lactate, N-Ethyl-p-menthane-3-carboxamide, menthyl acetate, menthone glycerol ketals.

As the example of antioxidant, including but not limited to, vitamin, its derivative and salt, what can be enumerated has, depending on Huang Alcohol, dehydroretinol, pyridoxol, pyridoxal, Vitamin D3, tocopherol, tocotrienols, tocopherol acetate；Fullerene.

As the example of preservative, including but not limited to, chemical preservative, what can be enumerated has, paraben esters, oxybenzene first Ester, Nipasol, Phenoxyethanol；Plant extracts or fraction with antioxidation, what can be enumerated has, witch hazel, rose Rare, capsicum fruit, Chinese prickly ash fruit, pasque flower, Spain moss tongue fur.

In a preferred embodiment, freshener of the present invention is selected from menthanol lactic acid ester, peppermint oil, menthol One of or it is a variety of.

Menthanol lactic acid ester: a kind of peppermint derivative belongs to cold-type yellow (clear) product, has slight peppermint fragrance, tastes several Insipidness, but with lasting, pleasant cooling effect, it is identified as fabulous without adverse reaction such as calcination Feel, the freshener of excitement and tingling sensation, is mainly used in the products such as daily chemical products, medicine preparation, dental products and candy.

Peppermint oil: peppermint stem and leaf takes off brain through steam distillation, part and processes volatile oil obtained, and main component is L- peppermint Alcohol not only there is stronger pharmacological action such as to refresh oneself, is antibacterial, wind-dispelling, but also have pleasant fragrance, in medicine, health, food It all has and is widely applied in the fields such as product, beverage, daily-use chemical industry,

Menthol: a kind of important fragrance, wherein l-menthol, which acts on skin, has ice to feel well refrigerant sense, and has cleaning, suppression The effect of liquefaction part, anti-inflammatory anti-itch, convergence, has the function that purification, skin of waking up, and l-menthol can promote active constituent through skin Skin improves absorption of the skin to active constituent, wakes up tired obscure skin.

The effects of by using the fresheners such as menthol, peppermint oil and emulsifier, biological carbohydrate gum -4 and water, it may make up micro emulsion System forms sustained release inclusion enclave, greatly improves the water solubility of peppermint oil, and reduces the rate of volatilization of the fresheners such as peppermint oil, Have the function of sustained release, can heavy long-time discharge cool feeling, when being used for sunlight screening skin-protecting product of the present invention, can play calm Skin prevents the effect of skin heat ageing.

In a preferred embodiment, antioxidant of the present invention is tocopherol and/or fullerene.

In a preferred embodiment, preservative of the present invention be selected from capsicum berry extract, Chinese prickly ash berry extract, One of pasque flower extract, Spain's moss tongue fur extract are a variety of.

Spain moss tongue fur extract of the present invention is commercially available or makes by oneself, wherein the preparation method comprises the following steps: Spain moss tongue fur mentions Take object can by Spain's moss lichenin it is broken after, extract or be heated to reflux or supercritical fluid extraction or other means in room temperature It obtains, liquid or ether, petroleum ether, chloroform or ethyl acetate that Extraction solvent, which is water and ethyl alcohol, to be mixed with arbitrary proportion etc. One of organic solvent or a variety of miscible liquid or liquid carbon dioxide in any proportion.

In a preferred embodiment, functional aid of the present invention include polyurethane -11, acrylic acid (ester) altogether Polymers, xanthan gum, oligofructose, Olibanum extract, 4- tert-butyl ring ethyl alcohol, Caulis Sacchari sinensis extract, cardamon seed be oily, thin flower bashfully Blade of grass extracts.

Polyurethane -11: can be used as stabilizer, can form cross-linked network with polyalcohol and utilize terminal group firmly stable Grease and water phase powder make the product have the function of form a film waterproofness, reduction skin irritation, raising moisturizing etc..

Acrylic acid (ester) copolymer: acrylate can be with the total of the polymer that comonomer is generated through copolyreaction with other Claim.The absorbable reduction of grease on the face is glossy, and collocation other materials such as glycerol, ring first silicone grease, Alphalin alcohol, vegetable oil etc. have The characteristic of time controlled released extends the effect of product whereby and reduces the direct irritation of product.

Xanthan gum: for vegetalitas colloid polysaccharide body, can be used as thickener, emulsification stabilization agent, yellow compared to other colloids Virgin rubber is bigger in various temperature and stability range under pH value, is particularly suitable as the matrix of smart oil-like emulsions.

Oligofructose: also known as fructooligosaccharide, is the mixture of ketose, Nystose and sugarcane sugar etc..It is oligomeric Fructose makes an addition to cosmetics, can inhibit the growth of facial skin surface harmful bacteria, and can effectively slow down pigementation, and desalination is simultaneously Color spot is eliminated, and can promote the generation of skin vitamin D, increases skin moisture-keeping.

Olibanum extract: the natural extract extracted from the resin of India boswellia serrata tree.Contained masticinic acid in olibanum And other organic acids have substantially reduced wrinkle, delay senescence, anti-inflammatory, analgesic effect.Olibanum extract cream rich in Fragrant acid has obvious desalination microgroove, promotes facial remarks circulating effect, can be used as natural antidotal agent addition and is making up In product.

Caulis Sacchari sinensis extract: being naturally occurring higher aliphatic for 1- n-octacosanol.N-octacosanol is universally acknowledged Antifatigue substance, be what raw material extracted by pure plant rice bran wax and sugarcane wax.

Cardamon seed oil: cardamon seed oil also has effects that moisturizing, nourishes rough skin.

It is thin to spend bashfully leaf extract: to re-form active constituent containing healing, epithelium, can be re-formed in healing and epithelium Auxiliary adjuvant is acted effectively as in the process.

In a preferred embodiment, sunlight screening skin-protecting product of the present invention further includes glucityl rutin.

Glucityl rutin: there are extremely strong absorption and superpower light resistance to ultraviolet light, reduce ultraviolet light to skin Stimulation.And then reduce resulting inflammatory factor and oxygen radical etc..

In a preferred embodiment, sunlight screening skin-protecting product of the present invention further includes 0.1~0.3 parts by weight butterflybush flower Extract.

Flos Buddlejae extract

Butterflybush flower is conventional Chinese medicine, has the effect of heat-clearing nourishing the liver, removing nebula, is mainly used for red eye, swell pain, liver void mesh Secretly, ancient medicine is usually used in eye disease.Its effective component is flavones, benzyl carbinol glycoside compound, the work with anti peroxidation of lipid With.

Flos Buddlejae extract is rich in a variety of flavonoids, benzyl carbinol glycoside, triterpene and its saponin(e as full effect light stabilizer Class, monoterpenes, iridoid substance, have to the resistant function of ultraviolet light, infrared ray and blue light, to skin have it is sun-proof and The effect of after-sun recovery；And Flos Buddlejae extract has antimicrobial antiphlogistic, sun-proof moisturizing maintains cutaneous immunisation balance and redox The effect of balance.

In one embodiment, the weight ratio of Flos Buddlejae extract of the present invention and the glucityl rutin is 1:(8 ~12).

Preferably, the weight ratio of Flos Buddlejae extract of the present invention and the glucityl rutin is 1:10.

It can be in not increase it is found by the applicant that a certain amount of Flos Buddlejae extract is added in suncream in the present invention While learning sun-prevention component, the SPF and safety in utilization of suncream are improved, especially when the butterflybush flower in system mentions Take the weight ratio of object and glucityl rutin about within the scope of 1:10 when, said effect is more significant.It may be due to butterflybush flower The ingredients energy such as a variety of flavonoids, benzyl carbinol glycoside, triterpene and its saponins, monoterpenes, iridoid substance in extract Synergistic function occurs between the groups such as enough and the catechol in glucityl rutin, polyhydroxy hexatomic ring, increases to each wavelength The absorption of ultraviolet light improves the SPF of suncream.Further, since the special aggregated structure of glucityl rutin, with it is close Under the effects of covering the intermolecular hydrogen bonding between flower extract, the cavity structure with particular size is formed, and due to these skies Cavity configuration is mainly by the diethylamino hydroxyl Benzoylbenzene in the structure compositions, with system such as the hexatomic ring containing hydroxyl isopolarity group There is stronger active force, or even due to above-mentioned specific cavity structure between the components such as hexyl formate, Uvinul T 150 The acute ingredients such as Uvinul T 150 in system may be coated in cavity, avoid its premature decomposition, cannot play While continuing sun-proof, it is also easy to the problem of the bringing secure context that be absorbed by the body.

In a preferred embodiment, Flos Buddlejae extract of the present invention is purchased from Lv Ke company, France.

In addition, applicant has been surprisingly found that, by the combination of large biological molecule film technique and the sun-proof technology of biological composition, Under the synergistic effect between the Multiple components such as biological carbohydrate gum -4, edelweiss extract, inorganic sunscreens ingredient, not only Conventional chemical sunscreen ingredients can be substituted, the dosage of chemical sunscreen ingredients is reduced, moreover it is possible to the effectively defence light such as blue light and feux rouges Line, these the harmful light for avoiding the equipment such as electronic product from issuing are through skin, and inside skin, stimulation skin produces extended residual Liveliness proof oxidation material, accelerated oxidation are led to aging, fragile, dry and water shortage；Also it helps avoid upsetting because of these light and take off The secretion of black hormone causes pigementation, and free radical increases or even blackening, the appearance for the problems such as spot and wrinkle occur.

In one embodiment, sunlight screening skin-protecting product of the present invention be selected from suncream, sunscreen, sun water, suntan lotion, One of sun-proof facial mask, sun-proof foundation emulsion, sun-proof essence, sun-proof condensation, sun protection gel and sunscreen spray are a variety of.

The parts by weight of the raw material of sunlight screening skin-protecting product of the present invention are obtained according to the parts by weight of the skin care item of this field routine. Routinely prepared by skin care item preparation method for the raw material of sunlight screening skin-protecting product of the present invention.

Embodiment

The present invention is specifically described below by embodiment.It is necessarily pointed out that following embodiment is only used In the invention will be further described, it should not be understood as limiting the scope of the invention, professional and technical personnel in the field The some nonessential modifications and adaptations made according to the content of aforementioned present invention, still fall within protection scope of the present invention.

In addition, if without other explanations, it is raw materials used to be all commercially available.

Embodiment 1

The embodiment of the present invention 1 provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, the sunlight screening skin-protecting product Raw material by weight, including 3 parts of glycerol, 2 parts of 1,2- pentanediols, 3 parts of propylene glycol, 0.05 part of Sodium Hyaluronate, 0.1 portion of beet Root extract, 3 parts of ring five dimethyl silicone polymers, 3 parts of carbonic acid dioctyl esters, 3 parts of Plantacare 818s, 0.05 part of lignocaine oxybenzene The own ester of formylbenzoate, 0.05 part of Uvinul T 150,0.05 part of bis-ethylhexoxyphenol methoxyphenyl triazine, 0.08 Part ethylhexyl methoxy cinnamate, 0.05 part of di-2-ethylhexylphosphine oxide-benzotriazole tetramethyl butyl phenol, 0.05 part of titanium dioxide, 0.05 part of zinc oxide, 0.1 part of menthanol lactic acid ester, 0.5 part of menthol, 0.5 portion of peppermint oil, 0.1 part of tocopherol, 0.1 part of fowler Alkene, 0.1 part of capsicum berry extract, 0.2 part of Chinese prickly ash berry extract, 0.2 part of pasque flower extract, 0.2 part of Spain moss tongue fur Extract, 0.5 part of oligofructose, 1 part of Olibanum extract, 1 part of 4- tert. butyl cyclohexanol, 1 part of Caulis Sacchari sinensis extract, 0.5 part of red bean Cool seed oil, 0.5 part thin colored bashfully leaf extract, 1 part of glucityl rutin, 3 parts of biological carbohydrate gums -4,1 part of silk ball fungus extract, 1 Part edelweiss extract, 70 parts of water.

The glycerol CAS is 56-81-5.

The 1,2- pentanediol CAS is 5343-92-0.

The propylene glycol CAS is 57-55-6.

The Sodium Hyaluronate CAS is 9067-32-7.

The beet root extract CAS is 89957-90-4.

The ring five dimethyl silicone polymer CAS is 541-02-6.

The carbonic acid dioctyl ester CAS is 1680-31-5.

The Plantacare 818 CAS is 54549-25-6.

The Uvinul A Plus CAS is 302776-68-7.

The Uvinul T 150 CAS is 88122-99-0.

The bis-ethylhexoxyphenol methoxyphenyl triazine CAS is 187393-00-6.

The ethylhexyl methoxy cinnamate CAS is 5466-77-3.

The di-2-ethylhexylphosphine oxide-benzotriazole tetramethyl butyl phenol CAS is 103597-45-1.

The titanium dioxide is purchased from Eurocostech Co., Ltd., partial size 30nm.

The zinc oxide is purchased from Eurocostech Co., Ltd., partial size 30nm.

The menthanol lactic acid ester CAS is 59259-38-0.

The menthol CAS is 89-78-1.

The peppermint oil CAS is 68917-18-0.

The tocopherol is purchased from Eurocostech Co., Ltd..

The fullerene CAS is 131159-39-2.

The capsicum berry extract is purchased from Eurocostech Co., Ltd..

The Chinese prickly ash berry extract is purchased from Eurocostech Co., Ltd..

The pasque flower extract is purchased from Eurocostech Co., Ltd..

The preparation method of the Spain moss tongue fur extract includes the following steps:

By Spain's moss lichenin it is broken after, using second alcohol and water mixed solution carry out ultrasonic extraction, obtain filtrate after filtering, Solvent is removed by vacuum distillation, obtains Spain's moss tongue fur extract.

The oligofructose CAS is 308066-66-2.

The Olibanum extract is purchased from Eurocostech Co., Ltd..

The 4- tert. butyl cyclohexanol CAS is 98-52-2.

The Caulis Sacchari sinensis extract CAS is 91722-22-4.

The cardamon seed oil is purchased from Eurocostech Co., Ltd..

Bashfully leaf extract is purchased from Eurocostech Co., Ltd. to the thin flower.

The glucityl rutin No. CAS is 130603-71-3.

Described biology carbohydrate gum -4CAS numbers are 283602-75-5.

The silk ball fungus extract is purchased from South Korea biospectrum.

The edelweiss extract is purchased from dutch royal Royal DSM group.

This example discloses the preparation method of the sunlight screening skin-protecting product of the substitution ultraviolet absorbing agent, comprising the following steps:

(1) glycerol, 1,2- pentanediol, propylene glycol, Sodium Hyaluronate, beet root extract and water are put into water phase pot, 80 DEG C are heated to, is stirred, is kept the temperature spare；

(2) by ring five dimethyl silicone polymer, carbonic acid dioctyl ester, Plantacare 818, biological carbohydrate gum -4, glucityl rutin, Uvinul A Plus, Uvinul T 150, bis-ethylhexoxyphenol methoxyphenyl triazine, methoxy Base 2-Ethylhexyl cinnamate, di-2-ethylhexylphosphine oxide-benzotriazole tetramethyl butyl phenol, titanium dioxide, zinc oxide are put into oily phase pot, are added Heat is stirred to 80 DEG C, is kept the temperature spare；

(3) material for obtaining step (1) and step (2) is added in emulsion pot, and constant temperature stirring, emulsifying is cooled to 40 DEG C are extracted hereinafter, menthanol lactic acid ester, menthol, peppermint oil, tocopherol, fullerene, capsicum berry extract, Chinese prickly ash fruit is added Object, pasque flower extract, Spain's moss tongue fur extract, oligofructose, Olibanum extract, 4- tert. butyl cyclohexanol, sugarcane Extract, cardamon seed be oily, thin flower bashfully leaf extract, silk ball fungus extract, edelweiss extract, and cream is sufficiently stirred It discharges after change, obtains the anti-sunlight screening skin-protecting product.

Embodiment 2

The embodiment of the present invention 2 provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, the sunlight screening skin-protecting product Raw material by weight, including 5 parts of glycerol, 4 parts of 1,2- pentanediols, 5 parts of propylene glycol, 0.15 part of Sodium Hyaluronate, 0.3 portion of beet Root extract, 8 parts of ring five dimethyl silicone polymers, 8 parts of carbonic acid dioctyl esters, 6 parts of Plantacare 818s, 0.3 part of lignocaine oxybenzene The own ester of formylbenzoate, 0.2 part of Uvinul T 150,0.15 part of bis-ethylhexoxyphenol methoxyphenyl triazine, 0.3 part Ethylhexyl methoxy cinnamate, 0.3 part of di-2-ethylhexylphosphine oxide-benzotriazole tetramethyl butyl phenol, 1 part of titanium dioxide, 1 part of oxidation Zinc, 0.5 part of menthanol lactic acid ester, 1 part of menthol, 1 portion of peppermint oil, 0.5 part of tocopherol, 0.5 part of fullerene, 0.5 part of capsicum fruit Extract, 0.5 part of Chinese prickly ash berry extract, 0.5 part of pasque flower extract, 0.5 part of Spain's moss tongue fur extract, 1.5 parts it is low Fructooligosaccharides, 3 parts of Olibanum extracts, 3 parts of 4- tert. butyl cyclohexanols, 3 parts of Caulis Sacchari sinensis extracts, 1 part of cardamon seed oil, 1 part thin flower contain Shy leaf extract, 3 parts of glucityl rutins, 6 parts of biological carbohydrate gums -4,5 parts of silk ball fungus extracts, 5 parts of edelweiss extracts, 100 parts of water.

The glycerol CAS is 56-81-5.

The 1,2- pentanediol CAS is 5343-92-0.

The propylene glycol CAS is 57-55-6.

The Sodium Hyaluronate CAS is 9067-32-7.

The beet root extract CAS is 89957-90-4.

The ring five dimethyl silicone polymer CAS is 541-02-6.

The carbonic acid dioctyl ester CAS is 1680-31-5.

The Plantacare 818 CAS is 54549-25-6.

The Uvinul A Plus CAS is 302776-68-7.

The Uvinul T 150 CAS is 88122-99-0.

The bis-ethylhexoxyphenol methoxyphenyl triazine CAS is 187393-00-6.

The ethylhexyl methoxy cinnamate CAS is 5466-77-3.

The zinc oxide is purchased from Eurocostech Co., Ltd., partial size 30nm.

The menthanol lactic acid ester CAS is 59259-38-0, is purchased from Eurocostech Co., Ltd..

The menthol CAS is 89-78-1.

The peppermint oil CAS is 68917-18-0.

The tocopherol is purchased from Eurocostech Co., Ltd..

The fullerene CAS is 131159-39-2.

The capsicum berry extract is purchased from Eurocostech Co., Ltd..

The Chinese prickly ash berry extract is purchased from Eurocostech Co., Ltd..

The pasque flower extract is purchased from Eurocostech Co., Ltd..

The oligofructose CAS is 308066-66-2.

The Olibanum extract is purchased from Eurocostech Co., Ltd..

The 4- tert. butyl cyclohexanol CAS is 98-52-2.

The Caulis Sacchari sinensis extract CAS is 91722-22-4.

The cardamon seed oil is purchased from Eurocostech Co., Ltd..

The glucityl rutin No. CAS is 130603-71-3.

Described biology carbohydrate gum -4CAS numbers are 283602-75-5.

The silk ball fungus extract is purchased from South Korea biospectrum.

The edelweiss extract is purchased from dutch royal Royal DSM group.

(1) glycerol, 1,2- pentanediol, propylene glycol, Sodium Hyaluronate, beet root extract and water are put into water phase pot, 85 DEG C are heated to, is stirred, is kept the temperature spare；

(2) by ring five dimethyl silicone polymer, carbonic acid dioctyl ester, Plantacare 818, biological carbohydrate gum -4, glucityl rutin, Uvinul A Plus, Uvinul T 150, bis-ethylhexoxyphenol methoxyphenyl triazine, methoxy Base 2-Ethylhexyl cinnamate, di-2-ethylhexylphosphine oxide-benzotriazole tetramethyl butyl phenol, titanium dioxide, zinc oxide are put into oily phase pot, are added Heat is stirred to 85 DEG C, is kept the temperature spare；

(3) material for obtaining step (1) and step (2) is added in emulsion pot, and constant temperature stirring, emulsifying is cooled to 40 DEG C are extracted hereinafter, menthanol lactic acid ester, menthol, peppermint oil, tocopherol, fullerene, capsicum berry extract, Chinese prickly ash fruit is added Object, pasque flower extract, Spain's moss tongue fur extract, oligofructose, Olibanum extract, 4- tert. butyl cyclohexanol, sugarcane Extract, cardamon seed be oily, thin flower bashfully extract by leaf extract, silk ball fungus extract, edelweiss extract, butterflybush flower Object discharges after emulsification is sufficiently stirred, obtains the anti-sunlight screening skin-protecting product.

Embodiment 3

The embodiment of the present invention 3 provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, the sunlight screening skin-protecting product Raw material by weight, including 4 parts of glycerol, 3 parts of 1,2- pentanediols, 4 parts of propylene glycol, 0.1 part of Sodium Hyaluronate, 0.2 portion of beet Root extract, 7 parts of ring five dimethyl silicone polymers, 7 parts of carbonic acid dioctyl esters, 4 parts of Plantacare 818s, 0.1 part of lignocaine oxybenzene The own ester of formylbenzoate, 0.1 part of Uvinul T 150,0.1 part of bis-ethylhexoxyphenol methoxyphenyl triazine, 0.1 part of first Oxygroup 2-Ethylhexyl cinnamate, 0.1 part of di-2-ethylhexylphosphine oxide-benzotriazole tetramethyl butyl phenol, 0.2 part of titanium dioxide, 0.2 part of oxidation Zinc, 0.2 part of menthanol lactic acid ester, 0.6 part of menthol, 0.6 portion of peppermint oil, 0.3 part of tocopherol, 0.3 part of fullerene, 0.3 part it is peppery Green pepper berry extract, 0.3 part of Chinese prickly ash berry extract, 0.3 part of pasque flower extract, 0.3 part of Spain's moss tongue fur extract, 1 part Oligofructose, 2 parts of Olibanum extracts, 2 parts of 4- tert. butyl cyclohexanols, 1.5 parts of Caulis Sacchari sinensis extracts, 0.6 part of cardamon seed oil, 0.6 Part is thin to spend bashfully leaf extract, 2 parts of glucityl rutins, 4.5 biological carbohydrate gums -4,2 parts of silk ball fungus extracts, 2 parts of high mountain tinder Careless extract, 0.2 part of Flos Buddlejae extract, 80 parts of water.

The glycerol CAS is 56-81-5.

The 1,2- pentanediol CAS is 5343-92-0.

The propylene glycol CAS is 57-55-6.

The Sodium Hyaluronate CAS is 9067-32-7.

The beet root extract CAS is 89957-90-4.

The ring five dimethyl silicone polymer CAS is 541-02-6.

The carbonic acid dioctyl ester CAS is 1680-31-5.

The Plantacare 818 CAS is 54549-25-6.

The Uvinul A Plus CAS is 302776-68-7.

The Uvinul T 150 CAS is 88122-99-0.

The bis-ethylhexoxyphenol methoxyphenyl triazine CAS is 187393-00-6.

The ethylhexyl methoxy cinnamate CAS is 5466-77-3.

The zinc oxide is purchased from Eurocostech Co., Ltd., partial size 30nm.

The menthol CAS is 89-78-1.

The peppermint oil CAS is 68917-18-0.

The tocopherol is purchased from Eurocostech Co., Ltd..

The fullerene CAS is 131159-39-2.

The capsicum berry extract is purchased from Eurocostech Co., Ltd..

The Chinese prickly ash berry extract is purchased from Eurocostech Co., Ltd..

The pasque flower extract is purchased from Eurocostech Co., Ltd..

The oligofructose CAS is 308066-66-2.

The Olibanum extract is purchased from Eurocostech Co., Ltd..

The 4- tert. butyl cyclohexanol CAS is 98-52-2.

The Caulis Sacchari sinensis extract CAS is 91722-22-4.

The cardamon seed oil is purchased from Eurocostech Co., Ltd..

The glucityl rutin No. CAS is 130603-71-3.

Described biology carbohydrate gum -4CAS numbers are 283602-75-5.

The silk ball fungus extract is purchased from South Korea biospectrum.

The edelweiss extract is purchased from dutch royal Royal DSM group.

The Flos Buddlejae extract is purchased from Lv Ke company, France.

Embodiment 4

The embodiment of the present invention 4 provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, the sunlight screening skin-protecting product Raw material by weight, including 5 parts of glycerol, 2 parts of 1,2- pentanediols, 2 parts of propylene glycol, 0.1 part of Sodium Hyaluronate, 0.2 portion of beet Root extract, 4 parts of ring five dimethyl silicone polymers, 2 parts of carbonic acid dioctyl esters, 3 parts of Plantacare 818s, 0.1 part of lignocaine oxybenzene The own ester of formylbenzoate, 0.1 part of Uvinul T 150,0.1 part of bis-ethylhexoxyphenol methoxyphenyl triazine, 0.1 part of first Oxygroup 2-Ethylhexyl cinnamate, 0.1 part of di-2-ethylhexylphosphine oxide-benzotriazole tetramethyl butyl phenol, 0.2 part of titanium dioxide, 0.2 part of oxidation Zinc, 0.2 part of menthanol lactic acid ester, 0.6 part of menthol, 0.6 portion of peppermint oil, 0.3 part of tocopherol, 0.3 part of fullerene, 0.2 part it is peppery Green pepper berry extract, 0.2 part of Chinese prickly ash berry extract, 0.2 part of pasque flower extract, 0.2 part of Spain's moss tongue fur extract, 1 part Oligofructose, 2 parts of Olibanum extracts, 2 parts of 4- tert. butyl cyclohexanols, 1.5 parts of Caulis Sacchari sinensis extracts, 0.6 part of cardamon seed oil, 0.6 Part is thin to spend bashfully leaf extract, 1 part of glucityl rutin, 4 biological carbohydrate gums -4,3 parts of silk ball fungus extracts, 3 parts of edelweiss Extract, 0.1 part of Flos Buddlejae extract, 80 parts of water.

The glycerol CAS is 56-81-5.

The 1,2- pentanediol CAS is 5343-92-0.

The propylene glycol CAS is 57-55-6.

The Sodium Hyaluronate CAS is 9067-32-7.

The beet root extract CAS is 89957-90-4.

The ring five dimethyl silicone polymer CAS is 541-02-6.

The carbonic acid dioctyl ester CAS is 1680-31-5.

The Plantacare 818 CAS is 54549-25-6.

The Uvinul A Plus CAS is 302776-68-7.

The Uvinul T 150 CAS is 88122-99-0.

The bis-ethylhexoxyphenol methoxyphenyl triazine CAS is 187393-00-6.

The ethylhexyl methoxy cinnamate CAS is 5466-77-3.

The zinc oxide is purchased from Eurocostech Co., Ltd., partial size 30nm.

The menthol CAS is 89-78-1.

The peppermint oil CAS is 68917-18-0.

The tocopherol is purchased from Eurocostech Co., Ltd..

The fullerene CAS is 131159-39-2.

The capsicum berry extract is purchased from Eurocostech Co., Ltd..

The Chinese prickly ash berry extract is purchased from Eurocostech Co., Ltd..

The pasque flower extract is purchased from Eurocostech Co., Ltd..

The oligofructose CAS is 308066-66-2.

The Olibanum extract is purchased from Eurocostech Co., Ltd..

The 4- tert. butyl cyclohexanol CAS is 98-52-2.

The Caulis Sacchari sinensis extract CAS is 91722-22-4.

The cardamon seed oil is purchased from Eurocostech Co., Ltd..

The glucityl rutin No. CAS is 130603-71-3.

Described biology carbohydrate gum -4CAS numbers are 283602-75-5.

The silk ball fungus extract is purchased from South Korea biospectrum.

The edelweiss extract is purchased from dutch royal Royal DSM group.

The Flos Buddlejae extract is purchased from Lv Ke company, France.

This example discloses the preparation method of the sunlight screening skin-protecting product of the substitution ultraviolet absorbing agent, and specific embodiment is same Embodiment 3.

Embodiment 5

The embodiment of the present invention 5 provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, the sunlight screening skin-protecting product Raw material by weight, including 5 parts of glycerol, 2 parts of 1,2- pentanediols, 2 parts of propylene glycol, 0.1 part of Sodium Hyaluronate, 0.2 portion of beet Root extract, 4 parts of ring five dimethyl silicone polymers, 2 parts of carbonic acid dioctyl esters, 3 parts of Plantacare 818s, 0.1 part of lignocaine oxybenzene The own ester of formylbenzoate, 0.1 part of Uvinul T 150,0.1 part of bis-ethylhexoxyphenol methoxyphenyl triazine, 0.1 part of first Oxygroup 2-Ethylhexyl cinnamate, 0.1 part of di-2-ethylhexylphosphine oxide-benzotriazole tetramethyl butyl phenol, 0.2 part of titanium dioxide, 0.2 part of oxidation Zinc, 0.2 part of menthanol lactic acid ester, 0.6 part of menthol, 0.6 portion of peppermint oil, 0.3 part of tocopherol, 0.3 part of fullerene, 0.2 part it is peppery Green pepper berry extract, 0.2 part of Chinese prickly ash berry extract, 0.2 part of pasque flower extract, 0.2 part of Spain's moss tongue fur extract, 1 part Oligofructose, 2 parts of Olibanum extracts, 2 parts of 4- tert. butyl cyclohexanols, 1.5 parts of Caulis Sacchari sinensis extracts, 0.6 part of cardamon seed oil, 0.6 Part is thin to spend bashfully leaf extract, 3 parts of glucityl rutins, 5 biological carbohydrate gums -4,4 parts of silk ball fungus extracts, 4 parts of edelweiss Extract, 0.3 part of Flos Buddlejae extract, 80 parts of water.

The glycerol CAS is 56-81-5.

The 1,2- pentanediol CAS is 5343-92-0.

The propylene glycol CAS is 57-55-6.

The Sodium Hyaluronate CAS is 9067-32-7.

The beet root extract CAS is 89957-90-4.

The ring five dimethyl silicone polymer CAS is 541-02-6.

The carbonic acid dioctyl ester CAS is 1680-31-5.

The Plantacare 818 CAS is 54549-25-6.

The Uvinul A Plus CAS is 302776-68-7.

The Uvinul T 150 CAS is 88122-99-0.

The bis-ethylhexoxyphenol methoxyphenyl triazine CAS is 187393-00-6.

The ethylhexyl methoxy cinnamate CAS is 5466-77-3.

The zinc oxide is purchased from Eurocostech Co., Ltd., partial size 30nm.

The menthol CAS is 89-78-1.

The peppermint oil CAS is 68917-18-0.

The tocopherol is purchased from Eurocostech Co., Ltd..

The fullerene CAS is 131159-39-2.

The capsicum berry extract is purchased from Eurocostech Co., Ltd..

The Chinese prickly ash berry extract is purchased from Eurocostech Co., Ltd..

The pasque flower extract is purchased from Eurocostech Co., Ltd..

The oligofructose CAS is 308066-66-2.

The Olibanum extract is purchased from Eurocostech Co., Ltd..

The 4- tert. butyl cyclohexanol CAS is 98-52-2.

The Caulis Sacchari sinensis extract CAS is 91722-22-4.

The cardamon seed oil is purchased from Eurocostech Co., Ltd..

The glucityl rutin No. CAS is 130603-71-3.

Described biology carbohydrate gum -4CAS numbers are 283602-75-5.

The silk ball fungus extract is purchased from South Korea biospectrum.

The edelweiss extract is purchased from dutch royal Royal DSM group.

The Flos Buddlejae extract is purchased from Lv Ke company, France.

Comparative example 1

Comparative example 1 of the invention provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, and specific embodiment is same Embodiment 3, the difference is that, the raw material of the sunlight screening skin-protecting product does not include biological carbohydrate gum -4.

Comparative example 2

Comparative example 2 of the invention provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, and specific embodiment is same Embodiment 3, the difference is that, the raw material of the sunlight screening skin-protecting product does not include silk ball fungus extract.

Comparative example 3

Comparative example 3 of the invention provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, and specific embodiment is same Embodiment 3, the difference is that, the raw material of the sunlight screening skin-protecting product does not include edelweiss extract.

Comparative example 4

Comparative example 4 of the invention provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, and specific embodiment is same Embodiment 3, the difference is that, the raw material of the sunlight screening skin-protecting product does not include biological carbohydrate gum -4 and silk ball fungus extract.

Comparative example 5

Comparative example 5 of the invention provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, and specific embodiment is same Embodiment 3, the difference is that, the raw material of the sunlight screening skin-protecting product does not include biological carbohydrate gum -4 and edelweiss extract.

Comparative example 6

Comparative example 6 of the invention provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, and specific embodiment is same Embodiment 3, the difference is that, the raw material of the sunlight screening skin-protecting product does not include that silk ball fungus extract and edelweiss extract Object.

Comparative example 7

Comparative example 7 of the invention provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, and specific embodiment is same Embodiment 3, the difference is that, the parts by weight of the silk ball fungus extract are 0.1.

Comparative example 8

Comparative example 8 of the invention provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, and specific embodiment is same Embodiment 3, the difference is that, the parts by weight of the edelweiss extract are 0.1.

Comparative example 9

Comparative example 1 of the invention provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, and specific embodiment is same Embodiment 3, the difference is that, the parts by weight of the Flos Buddlejae extract are 0.01.

Comparative example 10

Comparative example 10 of the invention provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, and specific embodiment is same Embodiment 3, the difference is that, the parts by weight of the glucityl rutin are 0.2.

Comparative example 11

Comparative example 11 of the invention provides a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, and specific embodiment is same Embodiment 3, the difference is that, the raw material of the sunlight screening skin-protecting product does not include that glucityl rutin, biological carbohydrate gum -4, Sparassis crispa mention Take object, edelweiss extract, Flos Buddlejae extract.

Performance evaluation

1, sun-proof function is tested: substituting the sun-proof of ultraviolet absorbing agent for what Examples 1 to 5 and comparative example 1~12 provided Skin conditioner carries out sun-proof function test.

(1) PFA is tested

Number of subjects: totally 3 people, women the age 31~40 years old, meet subject and volunteer inclusion criteria

Skin type: type III；

Inclusion criteria: 18-60 years old healthy volunteer, men and women；Subject should not have light sensitive dermatoses history；By Examination person's skin type is III, IV type；Such as anti-inflammatory agent, antihistamine had not been taken drugs before test；Recipient site selects back. Recipient site skin colour is uniform, without mole or other color spots etc..

The method of inspection: it tests according to the specific requirement of " cosmetics safety technical specification " (version in 2015).Subject Position of leaning forward is taken, its back is taken to be irradiated.The minimum that prediction subjects skin irradiates ultraviolet light before examining first 2~4 hours is held Continuous property melanism amount (MPPD value) adjusts ultraviolet irradiating dose according to prediction result, is used for sample survey.When sample survey first One is selected to be not less than 30cm at subject back²Normal skin region, by 2.00 ± 0.05mg/cm²Amount of samples use Measuring samples or standard reference material are uniformly applied in above-mentioned zone (for using latex finger cot coating uniformly difficult by latex finger cot Finger coating can be used directly in the big stronger product of viscosity of degree, powder product etc., and pays attention to clean finger before coating every time), etc. To 15-30min.Then ultraviolet irradiating dose appropriate is selected, point three kinds of situations are irradiated: (1) subjects skin does not apply Sample；(2) standard control sample is applied；(3) measuring samples are applied.Observation experiment as a result, record three kinds of situations respectively after 2 hours MPPD value.

PFA value calculating method: the MPPD/ of PFA=sample protecting skin does not add the MPPD of protecting skin.Sample or standard items The PFA value of single subject is calculated with following formula: calculating the arithmetic mean that sample protects whole subject's PFA values, takes its integer Part is the PFA value of the measurement sample.The sampling error of estimation mean can calculate the standard deviation and standard error of this group of data, It asks 95% credibility interval (95%CI) of mean to be no more than the 17% of mean, it is straight otherwise should to increase number of subjects's (being no more than 25) To meeting above-mentioned requirements.It the results are shown in Table 1.

It is found according to PFA test method, the PFA value of standard items is 4.4, is carried out to Examples 1 to 5 and comparative example 1~12 PFA test, test result are shown in Table 1.

(2) SPF is tested

Skin type: type III

Inclusion criteria: 18-60 years old healthy volunteer, men and women；Previously unglazed perceptual history of disease, does not make at no distant date With the photosensitive drug of influence；Subjects skin's type is I, II, type III, i.e., sensitive to daylight or ultraviolet light irradiation reaction, photograph Easily occur tanning severely and being less prone to pigmentation person after penetrating；It is recipient site skin non-pigment calmness, inflammation, scar, mole, more Hair etc.；The anti-inflammatory drugs such as gestation, lactation, oral or external application corticosteroid hormone or it is one month nearly in once received similar examination The person of testing should exclude outside subject；The interval time that same subject participates in SPF test should not be shorter than two months.

The method of inspection: it tests according to the specific requirement of " cosmetics safety technical specification " (version in 2015).Subject Position of leaning forward is taken, its back is taken to be irradiated.The minimal erythema dose for examining first 24 hours prediction subjects skins to irradiate ultraviolet light (med value) adjusts ultraviolet irradiating dose according to prediction result, is used for sample survey.Examine the same day first at subject back Selection one is not less than 30cm²Normal skin region, by 2.00 ± 0.05mg/cm²Amount of samples will be to using latex finger cot Sample product or standard reference material be uniformly applied in above-mentioned zone (for use latex finger cot be coated with the big viscosity of uniform difficulty compared with Finger coating can be used directly in strong product, powder product etc., and pays attention to clean finger before coating every time), wait 15-30min.So After select ultraviolet irradiating dose appropriate, point three kinds of situations are irradiated: (1) subjects skin does not apply sample；(2) standard is applied Control sample；(3) measuring samples are applied.Observation experiment after 16~24 hours as a result, record the med value of three kinds of situations respectively.

Spf value calculation method: sample or standard items calculate the spf value of single subject with following formula: the protection of SPF=sample The MED/ of skin does not add the MED of protecting skin.The arithmetic mean that sample protects whole subject's spf values is calculated, its integer portion is taken Divide the spf value of the as measurement sample.The sampling error of estimation mean can calculate the standard deviation and standard error of this group of data, it is desirable that 95% credibility interval (95%CI) of mean is no more than the 17% of mean, otherwise should increase number of subjects's (be no more than 25) until Meet above-mentioned requirements.

It is found according to SPF test method, the spf value of standard items is 17.7, is carried out to Examples 1 to 5 and comparative example 1~12 SPF test, test result are shown in Table 1.

2, stability test: the sun-proof shield for the substitution ultraviolet absorbing agent that Examples 1 to 5 and comparative example 1~12 are provided Skin product are individually positioned in 45min at 110 DEG C or are exposed to 60min under UVB, have seen whether that thinning, discoloration, layering and hardness become Phenomena such as change, and grading, it is divided into 0~4 grade, wherein 0 grade is without thinning, discoloration, lamination and firmness change, 1 grade For slight thinning, discoloration, no layering and firmness change, 2 grades increase for discoloration and thinning phenomenon, and no lamination, hardness slightly has Variation, 3 grades are slightly lamination, and firmness change increases, and 4 grades, to have obvious layering and firmness change, obtain heat-resistant stable Property and resistance to ultraviolet stability, the results are shown in Table 1.

3, security test: the sun-proof shield for the substitution ultraviolet absorbing agent that Examples 1 to 5 and comparative example 1~12 are provided Skin product carry out security test, and the specific test method is as follows: the volunteer for choosing skin sensitivity, having minor wound, to sensitive portion Position uses the sunlight screening skin-protecting product of the substitution ultraviolet absorbing agent containing Examples 1 to 5 and the offer of comparative example 1~12 respectively, and to survey It tries area skin and carries out safety evaluatio, evaluation index are as follows: scratchiness, tight feeling, excitement, rubescent, dry sensation, inflammation, and It is divided into 0~4 grade, index grade is as follows: 0 grade: without sensitivity response；1 grade: dry skin, slightly itch；2 grades: skin is slightly sent out Red, scratchiness increases；3 grades: faint erythema, a small amount of red capillary；4 grades: erythema, a large amount of red capillarys, inflammation.Test result is shown in Table 1.

4, Heavy metal: the sunlight screening skin-protecting product for the substitution ultraviolet absorbing agent that Examples 1 to 5 is provided is by country's food The domestic no special inspection body that puts on record is assert by product pharmaceuticals administration general bureau --- Hangzhou Xi Ke detection technique Co., Ltd carries out Heavy metal analysis finds mercury content≤1, and arsenic content≤2, lead content≤10, cadmium content≤5 meet " cosmetics safety technology rule Model " (version in 2015).

The test of 1 performance characterization of table

By 1 test result of table it is found that the sunlight screening skin-protecting product of substitution ultraviolet absorbing agent provided by the invention is using very When a small amount of organic and inorganic sunscreen, still there is excellent sun-proof performance, PFA up to 18 or so, SPF up to 51 or more, can Substitute conventional sunscreen agent；And sunlight screening skin-protecting product provided by the invention have high heat-resistant stable, stable ultraviolet resistance and Safety, suitable for all types of skin.

In addition, recognizing in the feedback of the sunlight screening skin-protecting product user of applicant in the present invention, produced for a long time in face of electronics The consumer of product feels that skin is intensely dark when not using the sunlight screening skin-protecting product in the present invention, and skin becomes dry aging, but It is after using the sunlight screening skin-protecting product in the embodiment of the present invention, even if for a long time in face of mobile phone, TV, computer screen etc., also not The problems such as will appear dim apparent skin, aging.

Example above-mentioned is merely illustrative, and is used to explain the present invention some features of the method.Appended right is wanted The range as wide as possible for being intended to require to be contemplated that is sought, and embodiments as presented herein is only according to all possible implementation The explanation of the embodiment of the combined selection of example.Therefore, the purpose of applicant is that the attached claims are not illustrated this hair The exemplary selectional restriction of bright feature.Some numberical ranges used also include sub- model in the claims It encloses, the variation in these ranges should also be construed to be covered by the attached claims in the conceived case.

Claims

1. a kind of sunlight screening skin-protecting product for substituting ultraviolet absorbing agent, which is characterized in that the raw material of the sunlight screening skin-protecting product includes life Object carbohydrate gum -4, silk ball fungus extract and edelweiss extract.

2. the sunlight screening skin-protecting product of substitution ultraviolet absorbing agent according to claim 1, which is characterized in that the Sparassis crispa mentions Taking the weight ratio of object and the edelweiss extract is (0.2~5): 1.

3. the sunlight screening skin-protecting product of substitution ultraviolet absorbing agent according to claim 2, which is characterized in that the Sparassis crispa mentions Taking the weight ratio of object and the edelweiss extract is (0.3~3): 1.

4. the sunlight screening skin-protecting product of substitution ultraviolet absorbing agent according to claim 1, which is characterized in that the biology sugar The weight ratio of glue -4 and the silk ball fungus extract is (0.6~6): 1.

5. the sunlight screening skin-protecting product of ultraviolet absorbing agent is substituted described in any one according to claim 1, which is characterized in that described The raw material of sunlight screening skin-protecting product by weight, including 3~6 parts of biological carbohydrate gums -4,1~5 part of silk ball fungus extract and 1~5 part of height Mountain HUORONGCAO extract.

6. the sunlight screening skin-protecting product of substitution ultraviolet absorbing agent according to claim 5, which is characterized in that the sun-proof skin care The raw material of product by weight, including 4~5 parts of biological carbohydrate gums -4,1~3 part of silk ball fungus extract and 1~3 part of edelweiss Extract.

7. the sunlight screening skin-protecting product of ultraviolet absorbing agent is substituted described in any one according to claim 1~6, which is characterized in that The raw material of the sunlight screening skin-protecting product further includes 0.1~2 parts by weight of inorganic sun-screening agent.

8. the sunlight screening skin-protecting product of substitution ultraviolet absorbing agent according to claim 7, which is characterized in that the inorganic sunscreens Agent is selected from one of zinc oxide, titanium dioxide, iron oxide, silica or a variety of.

9. the sunlight screening skin-protecting product of substitution ultraviolet absorbing agent according to claim 7, which is characterized in that the sun-proof skin care The raw material of product further includes Orangic sunscreen, moisturizer, emollient, emulsifier, additive.

10. the sunlight screening skin-protecting product of substitution ultraviolet absorbing agent according to claim 1, which is characterized in that the sun-proof shield Skin product be selected from suncream, sunscreen, sun water, suntan lotion, sun-proof facial mask, sun-proof foundation emulsion, sun-proof essence, sun-proof condensation, One of sun protection gel and sunscreen spray are a variety of.