CN108014060B - Sunscreen synergistic composition and application thereof - Google Patents

Abstract

The invention provides a sunscreen synergistic composition and application thereof, wherein the composition comprises 50-80% of tocopherol acetate, 10-15% of ascorbyl tetraisopalmitate, 20-30% of ginger root extract and 0.1-0.3% of bisabolol in percentage by weight; the sunscreen cosmetic is prepared by selecting four active functional components and scientifically proportioning, is used for preparing the sunscreen cosmetic, synergistically enhances the sunscreen effect of the sunscreen agent, reduces the type and the dosage of the sunscreen agent, and improves the safety, the effectiveness and the skin feeling of the sunscreen cosmetic; the invention can bring good economic benefit for enterprises and has wide application prospect.

Description

Sunscreen synergistic composition and application thereof

Technical Field

The invention relates to the field of cosmetics, in particular to a sunscreen synergistic composition and application thereof.

Background

The destruction of the ozone layer leads to a remarkable increase of skin diseases caused by excessive sunlight irradiation worldwide, and the skin sunscreen has attracted much attention. The ultraviolet spectrum in sunlight is in the wavelength range of 200-400nm and can be divided into 3 wave bands, namely short-wave Ultraviolet (UVC) with the wavelength of 200-290nm, medium-wave Ultraviolet (UVB) with the wavelength of 290-320nm and long-wave Ultraviolet (UVA) with the wavelength of 320-400 nm. The penetration depth of ultraviolet light through the skin varies with the wavelength. The penetration ability of UVC is poor, and UVC in sunlight is almost completely absorbed by an ozone layer and cannot reach the ground, so that the UVC is harmless to human bodies. UVA has strong penetrating power, and more than 95% of daily skin-contacted ultraviolet rays are UVA, so that the UVA has the greatest damage to the skin. UVA can penetrate through epidermis to attack the dermis layer, so that collagen and elastin in the skin are seriously injured, the self-protection capability of dermal cells is poor, and a small amount of UVA can cause great damage. Over time, the skin develops problems of sagging, wrinkles, blemishes, and the like. UVB oxidizes the lipid layer of the epidermis with protective effect to dry the skin; further denaturalize nucleic acid and protein in epidermal cells to produce symptoms such as acute dermatitis (i.e. sunburn) and the like, and the skin becomes red and painful. Severe conditions, such as prolonged exposure to sunlight, also tend to cause skin cancer. In addition, long-term damage of UVB also causes melanocyte mutation, which causes sun spots difficult to eliminate, and skin sunscreen has attracted much attention.

The most effective and convenient ultraviolet protection means for outdoor activities at present is the correct use of sunscreen cosmetics. The ultraviolet protection technology of the existing sunscreen cosmetics mainly focuses on physical protection, chemical protection or a stage of combining physical protection and chemical protection. The principle of physical protection is to scatter ultraviolet rays by reflection. Its advantages are high light stability, broad range of protection, high molecular weight, and no absorption by skin, so it is safe to sensitive skin. Titanium dioxide and zinc oxide are the most common physical uv screeners. However, it has certain limitations, generally a thick and heavy texture, easily whitened after being applied, and relatively weak protective ability. The chemical ultraviolet absorbent can convert light energy into heat energy, fluorescence or phosphorescence by absorbing ultraviolet rays, has strong ultraviolet protection capability in a certain wavelength range, is light and thin in texture, and is partially soluble in water. The disadvantages are that the molecular weight is small, the skin can be infiltrated, the skin has potential danger, and a plurality of skin problems such as free radical, light allergy, contact dermatitis, cancer cell proliferation and the like can be caused; at the same time, photodegradation, which reduces the uv absorption of the chemical sunscreen, is likely to occur.

With the update of national regulations, products with high sun protection indexes appear in the market, and the current products can only be achieved by increasing the dosage of the sun protection agents or compounding various sun protection agents to achieve higher sun protection indexes. The problem that the use of the sunscreen agent is increased, the irritation of the product is increased, the skin feel is greasy and heavy, and the use feeling is not satisfactory is solved.

CN101721320A discloses a waterproof aerosol sunscreen cream and a preparation method thereof, wherein the sunscreen cream is prepared by mixing special denatured ethanol, aminomethyl propanol, deionized water, octyl methoxycinnamate, methyl anthranilate, cyclomethicone, tocopherol acetate and dimethyl ether according to a certain proportion. Each part of sunscreen cream comprises 40-45% of special denatured ethanol, 0.35-0.5% of aminomethyl propanol, 7.5-10% of octyl methoxycinnamate, 4-6% of methyl anthranilate, 3-4% of cyclomethicone, 0.5-0.8% of tocopherol acetate, 30-35% of dimethyl ether and the balance of deionized water. CN106265171A discloses a skin care composition with antioxidant and anti-aging effects and a preparation method thereof, the skin care composition contains an effective amount of active ingredients and the balance of auxiliary ingredients, the active ingredients include dimethyl methoxy chromanol, winged seed moringa seed oil, squalane, ascorbyl tetraisopalmitate, tocopheryl acetate and bisabolol, and the skin care composition with antioxidant and anti-aging effects can effectively remove free radicals on the surface layer of skin, keep the water content of the skin, improve the darkness of the skin, lighten facial wrinkles and delay the formation of wrinkles. CN105796442A discloses a multifunctional cream, which comprises a first component, a second component and a third component, wherein the first component comprises a first skin conditioner and an emulsifier, and the first skin conditioner comprises petrolatum, meadowfoam seed oil, polydimethylsiloxane and tocopheryl acetate; the second component comprises a second skin conditioner and a second additive, wherein the second skin conditioner comprises bisabolol, stearic acid, brassinosteroids and a ginger root extract; the third component comprises water, glycerol, a third skin conditioner and a third additive, wherein the third skin conditioner comprises dipotassium glycyrrhizinate, hydroxyisoleucine, calendula seed oil, sodium hyaluronate and hydrolyzed rice protein; has mild and non-irritant effects and is suitable for infants.

In conclusion, the technology and the product have no sun-screening effect or have complicated sun-screening components, poor sun-screening effect and heavy skin feeling after being smeared, and cannot meet the requirements of consumers on sun-screening products.

With the increasing importance of consumers on the requirements of safety, effectiveness and use feeling of sunscreen products, the current products cannot effectively meet the continuously improved requirements of consumers on sunscreen products. How to realize the purpose of reducing the dosage of the sun-screening agent with irritation and poor smearing sense while ensuring the sun-screening effect with high index has important research significance and great market value.

Disclosure of Invention

Aiming at the market demand and the defects of the prior art, the invention provides a sunscreen synergistic composition and application thereof, which can be applied to sunscreen cosmetics by reasonably selecting active ingredients and scientifically proportioning to coordinate and enhance the sunscreen effect of a sunscreen agent, reduce the type and dosage of the sunscreen agent, improve the safety, effectiveness and skin feel of the product, and have wide market value and application prospect.

In order to achieve the purpose of the invention, the following technical scheme is adopted:

in a first aspect, the present invention provides a sunscreen synergistic composition;

the sunscreen synergistic composition comprises the following components in percentage by weight:

wherein the sum of the weight percentages of the components is not more than 100%.

The sunscreen product in the prior art is improved mainly by increasing the dosage of the sunscreen agent, and due to the defect that the sunscreen agent has certain irritation and poor spreadability, with the increase of the type and dosage of the sunscreen agent, the irritation and greasy feeling of the product are also improved. How to reduce the dosage of the sun-screening agent with irritation and poor smearing sense while ensuring the sun-screening effect with high index is the technical difficulty of the research of the invention. In order to overcome the defects of the existing high-sun-screening-index sun-screening product, the inventor fully researches the principle and technology of skin sun screening in the long-term production practice process, screens various active ingredients, and finally obtains the sun-screening synergistic composition provided by the invention through reasonable selection and scientific proportioning, wherein the sun-screening synergistic composition is not a sun-screening agent and has high safety; when the sunscreen composition is applied to sunscreen cosmetics, the components synergistically enhance the sunscreen effect of the sunscreen agent, and the type and the using amount of the sunscreen agent can be reduced. Therefore, the safety, effectiveness and use feeling of the product can be improved.

Preferably, the weight percentage of the tocopherol acetate is 50-80%, for example 50%, 55%, 60%, 65%, 70%, 75% or 80%, preferably 50-70%, more preferably 60-70%.

Preferably, the weight percentage of ascorbyl tetraisopalmitate is 10-15%, for example 10%, 11%, 12%, 13%, 14% or 15%, preferably 12-15%, more preferably 12-14%.

Preferably, the weight percentage of the ginger root extract is 20-30%, for example, 20%, 21%, 22%, 23%, 24%, 25%, 26%, 27%, 28%, 29% or 30%, preferably 22-28%, and more preferably 23-26%.

Preferably, the weight percentage of the bisabolol is 0.1 to 0.3%, for example, 0.1%, 0.15%, 0.2%, 0.25%, or 0.3%, preferably 0.15 to 0.3%, and more preferably 0.15 to 0.25%.

Preferably, the sunscreen synergistic composition comprises the following components in percentage by weight:

wherein the sum of the weight percentages of the components is not more than 100%.

Preferably, the sunscreen synergistic composition comprises the following components in percentage by weight:

wherein the sum of the weight percentages of the components is not more than 100%.

In a second aspect, the present invention provides a composition according to the first aspect for use in the preparation of a sunscreen cosmetic.

In a third aspect, the present invention provides a cosmetic product comprising a composition according to the first aspect.

Preferably, the composition is added in an amount of 0.1 to 1% by weight, for example, 0.1%, 0.3%, 0.5%, 0.7%, 0.8% or 1%, preferably 0.5 to 1%, and more preferably 0.6 to 0.9% in the sunscreen cosmetic.

Preferably, the cosmetic also comprises a phase A, wherein the phase A is any one or a combination of at least two of EDTA disodium, sodium chloride, butanediol, glycerol, p-hydroxyacetophenone, silica and sodium hyaluronate.

Preferably, the disodium EDTA is 0.01-0.03% by weight, for example, 0.01%, 0.02% or 0.03%, preferably 0.02%.

Preferably, the sodium chloride is present in an amount of 0.30-0.60% by weight, for example 0.30%, 0.40%, 0.50% or 0.60%, preferably 0.50%.

Preferably, the weight percentage of the butanediol is between 2 and 5%, and may be, for example, 2%, 3%, 4% or 5%, preferably 3%.

Preferably, the glycerol is present in a percentage of 1 to 3% by weight, and may be, for example, 1%, 2% or 3%, preferably 2%.

Preferably, the weight percentage of p-hydroxyacetophenone is 0.2 to 0.6%, for example, may be 0.2%, 0.3%, 0.5% or 0.6%, preferably 0.5%.

Preferably, the silica is present in a percentage by weight of 0.2 to 0.6%, for example 0.2%, 0.5% or 0.6%, preferably 0.5%.

Preferably, the sodium hyaluronate is present in a weight percentage of 0.01-0.03%, for example 0.01%, 0.02% or 0.03%, preferably 0.02%.

Preferably, the cosmetic further comprises a phase B, wherein the phase B is any one or a combination of at least two of cetyl PEG/PPG-10/1 polydimethylsiloxane, sorbitan sesquioleate, bis-ethylhexyloxyphenol methoxyphenyl triazine, diethylamino hydroxybenzoyl hexyl benzoate, ethylhexyl methoxycinnamate, 4-methylbenzylidene camphor, p-methoxy isoamyl cinnamate, dioctyl carbonate, zinc oxide and cyclopentadimethylsiloxane.

Preferably, the cetyl PEG/PPG-10/1 dimethicone is present in a weight percentage of 1.0 to 3.0%, for example 1.0%, 2.0% or 3.0%, preferably 2.0%.

Preferably, the sorbitan sesquioleate is 0.3-0.6% by weight, for example, may be 0.3%, 0.4%, 0.5% or 0.6%, preferably 0.5%.

Preferably, the bis-ethylhexyloxyphenol methoxyphenyl triazine is present in an amount of 0.5 to 2% by weight, and may be, for example, 0.5%, 0.7%, 0.9%, 1% or 2%, preferably 2%.

Preferably, the weight percentage of the diethylamino hydroxybenzoyl hexyl benzoate is 0.5-3%, for example 0.5%, 1%, 2% or 3%, preferably 3%.

Preferably, the weight percentage of ethylhexyl methoxycinnamate is 8-12%, for example 8%, 9%, 10%, 11% or 12%, preferably 10%.

Preferably, the percentage by weight of the 4-methylbenzylidene camphor is between 0.5 and 2%, and may be, for example, 0.5%, 0.6%, 0.8%, 1% or 2%, preferably 2%.

Preferably, the weight percentage of the p-methoxy isoamyl cinnamate is 1-4%, for example, 1%, 2%, 3% or 4%, preferably 4%.

Preferably, the weight percentage of the dioctyl carbonate is 1-4%, for example, 1%, 2%, 3% or 4%, preferably 3%.

Preferably, the zinc oxide is present in a percentage of 2 to 5% by weight, for example 2%, 3%, 4%, 5% or 6%, preferably 6%.

Preferably, the weight percentage of cyclopentadimethylsiloxane is between 28 and 32%, and may be, for example, 28%, 29%, 30%, 31% or 32%, preferably 30%.

Preferably, the cosmetic also comprises a phase C, wherein the phase C comprises the sunscreen synergistic composition and also comprises phenoxyethanol and/or essence.

Preferably, the phenoxyethanol is present in an amount of 0.1 to 0.4% by weight, for example 0.1%, 0.2%, 0.3% or 0.4%, preferably 0.3%.

Preferably, the perfume is present in an amount of 0.05-0.2% by weight, for example 0.05%, 0.1%, 0.15% or 0.2%, preferably 0.1%.

Preferably, the sunscreen composition is present in an amount of 0.1 to 1% by weight, for example 0.1%, 0.5%, 0.8% or 1%, preferably 0.8%.

In a fourth aspect, the present invention provides a method for preparing a cosmetic according to the third aspect, specifically comprising the steps of:

(1) mixing the phase A raw material with water according to the formula amount, heating to 78-82 ℃, for example 78 ℃, 80 ℃ or 82 ℃, preferably 80 ℃, and uniformly stirring and dispersing for later use;

(2) heating the phase B raw material to 78-82 deg.C, such as 78 deg.C, 80 deg.C or 82 deg.C, preferably 80 deg.C, stirring to dissolve uniformly;

(3) adding the phase A raw material into the phase B for homogenizing and emulsifying, and cooling after emulsifying;

(4) cooling to 43-47 deg.C, such as 43 deg.C, 45 deg.C or 47 deg.C, preferably 45 deg.C, adding phase C raw materials according to formula amount, stirring to disperse uniformly, and vacuum degassing to obtain the final product.

Compared with the prior art, the invention has the following advantages:

(1) the sunscreen synergistic composition disclosed by the invention is composed of a plurality of stable functional components, is definite in components, stable in properties, not a sunscreen agent, and high in safety, and can be applied to sunscreen cosmetics in a low dosage and synergize the action of the sunscreen agent, so that the variety and dosage of the sunscreen agent are reduced;

(2) the sunscreen synergistic composition provided by the invention is applied to sunscreen cosmetics, so that the safety, effectiveness and use feeling of the product are improved;

(3) the preparation method provided by the invention is simple and efficient, saves manpower and material resources, and is convenient to popularize.

Detailed Description

To further illustrate the technical means and effects of the present invention, the following further describes the technical solution of the present invention with reference to the preferred embodiments of the present invention, but the present invention is not limited to the scope of the embodiments.

Example 1

A sunscreen synergistic composition was prepared according to the following formulation:

the four components are uniformly mixed according to the formula to obtain the sunscreen synergistic composition.

Example 2

A sunscreen synergistic composition was prepared according to the following formulation:

the four components are uniformly mixed according to the formula to obtain the sunscreen synergistic composition.

Example 3

A sunscreen synergistic composition was prepared according to the following formulation:

the four components are uniformly mixed according to the formula to obtain the sunscreen synergistic composition.

Comparative example 1

The conditions were the same as in example 1 except that tocopherol acetate was absent as compared with example 1.

Comparative example 2

The conditions were the same as in example 1 except that the ascorbyl tetraisopalmitate was absent as compared with example 1.

Comparative example 3

The conditions were the same as in example 1 except that the ginger root extract was lacking, as compared with example 1.

Comparative example 4

The conditions were the same as in example 1 except that bisabolol was absent, compared to example 1.

Examples 4 to 7

Sunscreen emulsions were prepared with the formulation shown in table 1:

TABLE 1

Wherein, the sunscreen synergistic composition in the examples 4-7 adopts the formula of the example 1;

the preparation method of the emulsion comprises the following steps:

(1) mixing the phase A raw material with water, heating to 80 ℃, and stirring and dispersing uniformly for later use;

(2) heating the phase B raw material to 80 ℃, and stirring and dissolving uniformly;

(3) pumping the raw material of the phase A into the phase B for homogenizing and emulsifying, and cooling after the emulsification is finished;

(4) and cooling to 45 ℃, adding the C-phase raw material, uniformly stirring and dispersing, and vacuumizing and defoaming to obtain the sunscreen emulsion.

Examples 8 to 11

Sunscreen emulsions were prepared with the formulation shown in table 2:

TABLE 2

Wherein, the sunscreen synergistic composition in the example 8 adopts the sunscreen synergistic composition in the example 1; the sunscreen synergistic composition in example 9 adopts the sunscreen synergistic composition in example 2, and the sunscreen synergistic compositions in examples 10-11 adopt the sunscreen synergistic composition in example 3;

the preparation of the emulsions of examples 8 to 11 was carried out in the same manner as in examples 4 to 7.

Comparative example 5

Compared with example 4, the conditions are the same as example 4 except that no sunscreen synergistic composition is added.

Comparative example 6

The conditions were the same as in example 4 except that no ascorbyl tetraisopalmitate, ginger root extract and bisabolol were added, compared to example 4.

Comparative example 7

The conditions were the same as in example 4 except that tocopherol acetate, ginger root extract and bisabolol were not added, compared to example 4.

Comparative example 8

The conditions were the same as in example 4 except that tocopherol acetate, ascorbyl tetraisopalmitate and bisabolol were not added, compared to example 4.

Comparative example 9

The conditions were the same as in example 4 except that tocopherol acetate, ascorbyl tetraisopalmitate and ginger root extract were not added, compared to example 4.

Comparative example 10

The conditions were the same as in example 5 except that no sunscreen building composition was added as compared to example 5.

Comparative example 11

The conditions were the same as in example 6 except that no sunscreen building composition was added as compared to example 6.

Comparative example 12

The conditions were the same as in example 7 except that no sunscreen building composition was added as compared to example 7.

Comparative example 13

The conditions were the same as in example 8 except that no sunscreen building composition was added as compared to example 8.

Comparative example 14

The conditions were the same as in example 9 except that no sunscreen building composition was added as compared to example 9.

Comparative example 15

The conditions were the same as in example 10 except that no sunscreen building composition was added as compared to example 10.

Comparative example 16

The conditions were the same as in example 11 except that no sunscreen building composition was added as compared to example 11.

Comparative example 17

The conditions were the same as in example 4 except that the sunscreen synergistic composition obtained in comparative example 1 was used, as compared with example 4.

Comparative example 18

The conditions were the same as in example 4 except that the sunscreen synergistic composition obtained in comparative example 2 was used, as compared with example 4.

Comparative example 19

The conditions were the same as in example 4 except that the sunscreen synergistic composition obtained in comparative example 3 was used, as compared with example 4.

Comparative example 20

The conditions were the same as in example 4 except that the sunscreen synergistic composition obtained in comparative example 4 was used, as compared with example 4.

Test for Sun protection Effect

1. Sun Protection Factor (SPF): also known as the solar protection factor, indicates how high the sunscreen product can exert the sunscreen effect. The larger the SPF value, the better the sunscreen effect. It is determined based on the Minimum Erythemal Dose (MED) of the skin. After use of the sunscreen, the minimum erythema dose of the skin increases, and the sun protection factor SPF of the sunscreen is then:

the SPF index is useful for evaluating the protection against UVB.

2. Long-wave ultraviolet protection index (PFA value) of sunscreen cosmetic: also known as the UVA protection index. UVA in sunlight strikes the skin, primarily producing the physiological effects of skin darkening, measured as the minimum sustained amount of darkening (MPPD). MPPD is the minimum ultraviolet irradiation dose or the minimum irradiation time required for 2-4h after irradiation to produce slight blackening on the skin at the whole irradiation site.

Examples 4-11 were selected and the control samples were comparative examples 5-20. The sunscreen effect of the product was tested according to the sunscreen cosmetic sun protection index test method (human method) in the technical safety standards for cosmetics (2015 edition), and the test results are shown in table 3:

TABLE 3

As can be seen from table 3, the sun protection index of the sunscreen emulsion prepared in example 4 with the added sunscreen synergistic composition is significantly improved compared with that of the sunscreen emulsion without the added sunscreen synergistic composition (comparative example 5). The sun protection indices of the sunscreen emulsions with a single sunscreen synergistic composition component (comparative examples 4-7) and sunscreen emulsions lacking either component (comparative examples 17-20) were also somewhat improved over the sunscreen emulsions without a sunscreen synergistic composition (comparative example 1), but the improvement was far less effective than the compositions. The results of the tests show that the sunscreen synergistic composition needs specific scientific combination and proportion to achieve obvious sunscreen effect, and the ideal sunscreen promoting effect and synergistic effect cannot be achieved by a single component or lack of any component.

Skin irritation test

The sunscreen emulsion obtained in example 8 was taken, the control sample was comparative example 13, 20 women and 10 men were used as subjects, 0.03mL of the sample was taken in a chamber of a spot test tape by a syringe, and the spot test tape with the sample was immediately stuck to the normal skin of the left forearm from the lower part in the longitudinal direction while gently pressing the chamber one by one to expel air and uniformly distributing the test substance. The test site is marked for easy observation. Every 24 hours the patch was applied and then later half an hour the patch was removed and examined according to the CTFA guidelines. The patch test was performed 6 times in total, and on day 6 after completion of the skin application, additional examination was performed to observe delayed reactions. The data is compared by using the last check result;

the criteria for the skin irritation test are shown in Table 4, and the results are shown in Table 5:

TABLE 4

TABLE 5

Number of times of skin sticking	Example 8	Comparative example 13
			1	0	0
2	0	0
			3	0	0
4	0	0
			5	0	0
6	0	1 time of
			Day 6 after completion	0	0
Total up to	0	1 time of

As can be seen from Table 5, example 8, which is an emulsion containing the sunscreen boosting composition of the present invention, has no irritation to the skin and no positive reaction, while comparative example 13 shows a positive reaction, indicating that the sunscreen product containing the composition is safer and milder.

Sensory evaluation test

The sunscreen emulsions prepared in example 7 and comparative example 13, which had almost the same sun protection index, were selected according to an in-cosmetic sensory analysis method and subjected to skin feel evaluation;

(1) evaluation items: spreadability, freshness, absorbency, mildness, overall effect;

(2) a grading system: the score is 1-10, and the higher the score is, the stronger the characteristic of the project index is;

(3) the experimental scheme is as follows: selecting 10 trained evaluators, female, aged 25-35 years; the preparation is carried out in a constant temperature independent environment (22 +/-1 ℃), the relative humidity is 50 +/-5%, and the preparation is carried out after the rest is carried out for 1 hour;

the results are shown in Table 6:

TABLE 6

	Example 7	Comparative example 13
			Spreadability	8.5	7.5
Degree of freshness	7.5	7
			Absorbency of	7.5	6.8
Mildness property	8.5	8.2
			Overall effect	8.0	7.0

As can be seen from Table 6, the sun-screening emulsion of example 7 has 5 evaluation indexes leading overall to the sun-screening emulsion of comparative example 13. The sunscreen emulsion containing the sunscreen synergistic composition is better in use feeling than the common sunscreen emulsion under the same sunscreen index, and is better in spreadability, freshness, absorbability, mildness and overall effect.

In conclusion, the invention provides a sunscreen synergistic composition and application thereof, wherein four active functional components are selected, and a scientific and reasonable proportion is obtained through a large number of experimental demonstrations, so that the sunscreen synergistic composition is used for preparing sunscreen cosmetics, the sunscreen effect of a sunscreen agent is synergistically enhanced, the types and the dosage of the sunscreen agent are reduced, and the safety, the effectiveness and the skin feeling of the sunscreen cosmetics are improved. The invention can bring good economic benefit for enterprises and has wide application prospect.

The applicant states that the present invention is illustrated in detail by the above examples, but the present invention is not limited to the above detailed methods, i.e. it is not meant that the present invention must rely on the above detailed methods for its implementation. It should be understood by those skilled in the art that any modification of the present invention, equivalent substitutions of the raw materials of the product of the present invention, addition of auxiliary components, selection of specific modes, etc., are within the scope and disclosure of the present invention.

Claims (42)

1. A cosmetic comprising a phase A, a phase B and a phase C;

the phase A is any one or the combination of at least two of EDTA disodium, sodium chloride, butanediol, glycerol, p-hydroxyacetophenone, silica and sodium hyaluronate;

the phase B is any one or the combination of at least two of cetyl PEG/PPG-10/1 polydimethylsiloxane, sorbitan sesquioleate, bis-ethylhexyloxyphenol methoxyphenyl triazine, diethylamino hydroxybenzoyl hexyl benzoate, ethylhexyl methoxycinnamate, 4-methylbenzylidene camphor, p-methoxy isoamyl cinnamate, dioctyl carbonate, zinc oxide and cyclopenta dimethyl siloxane;

the phase C comprises a sun-screening synergistic composition and also comprises phenoxyethanol and/or essence;

the sunscreen synergistic composition comprises the following components in percentage by weight:

wherein the sum of the weight percentages of the components is 100 percent;

the addition amount of the sunscreen synergistic composition accounts for 0.6 to 0.9 percent of the weight of the cosmetic;

the cosmetic is prepared by the following method:

(1) mixing the phase A raw material with water according to the formula amount, heating to 78-82 ℃, and uniformly stirring and dispersing for later use;

(2) heating the phase B raw material to 78-82 ℃ according to the formula amount, and uniformly stirring and dissolving;

(3) adding the phase A raw material into the phase B for homogenizing and emulsifying, and cooling after emulsifying;

(4) cooling to 43-47 deg.C, adding C phase raw materials according to formula amount, stirring, dispersing, and vacuum degassing to obtain the final product.

2. The cosmetic according to claim 1, wherein the weight percentage of disodium EDTA is 0.01 to 0.03%.

3. The cosmetic according to claim 1, wherein said disodium EDTA is present in an amount of 0.02% by weight.

4. The cosmetic according to claim 1, wherein the weight percentage of sodium chloride is 0.30 to 0.60%.

5. The cosmetic according to claim 1, wherein the sodium chloride is present in an amount of 0.50% by weight.

6. The cosmetic according to claim 1, wherein the butylene glycol is present in an amount of 2 to 5% by weight.

7. The cosmetic according to claim 1, wherein the butylene glycol is present in an amount of 3% by weight.

8. The cosmetic according to claim 1, wherein the glycerin is present in an amount of 1 to 3% by weight.

9. Cosmetic product according to claim 1, characterized in that the percentage by weight of glycerin is 2%.

10. The cosmetic according to claim 1, wherein the weight percentage of p-hydroxyacetophenone is 0.2 to 0.6%.

11. The cosmetic according to claim 1, wherein the weight percentage of p-hydroxyacetophenone is 0.5%.

12. Cosmetic product according to claim 1, characterized in that said silica is present in a percentage by weight of between 0.2 and 0.6%.

13. Cosmetic product according to claim 1, characterized in that said silica is present in a percentage by weight of 0.5%.

14. The cosmetic according to claim 1, wherein the sodium hyaluronate is present in an amount of 0.01 to 0.03% by weight.

15. The cosmetic according to claim 1, wherein the sodium hyaluronate is present in an amount of 0.02% by weight.

16. The cosmetic according to claim 1, wherein the cetyl PEG/PPG-10/1 dimethicone is present in an amount of 1.0 to 3.0% by weight.

17. The cosmetic product according to claim 1, wherein the cetyl PEG/PPG-10/1 dimethicone is present in an amount of 2.0% by weight.

18. The cosmetic according to claim 1, wherein the sorbitan sesquioleate is present in an amount of 0.3 to 0.6% by weight.

19. The cosmetic according to claim 1, characterized in that the sorbitan sesquioleate is present in a percentage by weight of 0.5%.

20. The cosmetic according to claim 1, wherein the bis-ethylhexyloxyphenol methoxyphenyl triazine is contained in an amount of 0.5 to 2% by weight.

21. The cosmetic according to claim 1, wherein the bis-ethylhexyloxyphenol methoxyphenyl triazine is present in an amount of 2% by weight.

22. The cosmetic according to claim 1, wherein the weight percentage of diethylamino hydroxybenzoyl hexyl benzoate is 0.5-3%.

23. The cosmetic according to claim 1, wherein the diethylamino hydroxybenzoyl hexyl benzoate is present in an amount of 3% by weight.

24. The cosmetic according to claim 1, wherein the weight percentage of ethylhexyl methoxycinnamate is 8-12%.

25. The cosmetic according to claim 1, wherein the weight percentage of ethylhexyl methoxycinnamate is 10%.

26. The cosmetic according to claim 1, wherein the 4-methylbenzylidene camphor is present in an amount of 0.5 to 2% by weight.

27. The cosmetic according to claim 1, wherein the 4-methylbenzylidene camphor is present in an amount of 2% by weight.

28. The cosmetic according to claim 1, wherein said isoamyl p-methoxycinnamate is present in an amount ranging from 1 to 4% by weight.

29. The cosmetic according to claim 1, wherein said isoamyl p-methoxycinnamate is present in a weight percentage of 4%.

30. The cosmetic according to claim 1, wherein the dioctyl carbonate is 1 to 4% by weight.

31. The cosmetic according to claim 1, wherein the dioctyl carbonate is present in an amount of 3% by weight.

32. The cosmetic according to claim 1, wherein the zinc oxide is present in an amount of 2 to 6% by weight.

33. The cosmetic according to claim 1, wherein the zinc oxide is present in an amount of 6% by weight.

34. The cosmetic according to claim 1, wherein the cyclopentadimethylsiloxane is present in an amount of 28 to 32% by weight.

35. The cosmetic according to claim 1, wherein the cyclopentadimethylsiloxane is present in an amount of 30% by weight.

36. The cosmetic according to claim 1, wherein the phenoxyethanol is present in an amount of 0.1 to 0.4% by weight.

37. The cosmetic of claim 1, wherein the phenoxyethanol is present in an amount of 0.3% by weight.

38. The cosmetic according to claim 1, wherein the essence is present in an amount of 0.05 to 0.2% by weight.

39. The cosmetic according to claim 1, wherein the perfume is present in an amount of 0.1% by weight.

40. The cosmetic according to claim 1, wherein the sunscreen composition is present in an amount of 0.1 to 1% by weight.

41. The cosmetic according to claim 1, wherein the sunscreen composition is present in an amount of 0.8% by weight.

42. A process for the preparation of a cosmetic product according to any one of claims 1 to 41, comprising the steps of:

(1) mixing the phase A raw material with water according to the formula amount, heating to 78-82 ℃, and uniformly stirring and dispersing for later use;

(2) heating the phase B raw material to 78-82 ℃ according to the formula amount, and uniformly stirring and dissolving;

(3) adding the phase A raw material into the phase B for homogenizing and emulsifying, and cooling after emulsifying;

(4) cooling to 43-47 deg.C, adding C phase raw materials according to formula amount, stirring, dispersing, and vacuum degassing to obtain the final product.