CN110368974B - 用于二氧化碳还原反应的新型氮掺杂的铜纳米催化剂 - Google Patents

用于二氧化碳还原反应的新型氮掺杂的铜纳米催化剂 Download PDF

Info

Publication number
CN110368974B
CN110368974B CN201910293182.9A CN201910293182A CN110368974B CN 110368974 B CN110368974 B CN 110368974B CN 201910293182 A CN201910293182 A CN 201910293182A CN 110368974 B CN110368974 B CN 110368974B
Authority
CN
China
Prior art keywords
copper
nanoparticles
component
nanocatalyst
optionally
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201910293182.9A
Other languages
English (en)
Chinese (zh)
Other versions
CN110368974A (zh
Inventor
陈书堂
陈固纲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honda Motor Co Ltd
Original Assignee
Honda Motor Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honda Motor Co Ltd filed Critical Honda Motor Co Ltd
Publication of CN110368974A publication Critical patent/CN110368974A/zh
Application granted granted Critical
Publication of CN110368974B publication Critical patent/CN110368974B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00—Nitrogen; Compounds thereof
    • C01B21/06—Binary compounds of nitrogen with metals, with silicon, or with boron, or with carbon, i.e. nitrides; Compounds of nitrogen with more than one metal, silicon or boron
    • C01B21/0615—Binary compounds of nitrogen with metals, with silicon, or with boron, or with carbon, i.e. nitrides; Compounds of nitrogen with more than one metal, silicon or boron with transition metals other than titanium, zirconium or hafnium
    • C01B21/0625—Binary compounds of nitrogen with metals, with silicon, or with boron, or with carbon, i.e. nitrides; Compounds of nitrogen with more than one metal, silicon or boron with transition metals other than titanium, zirconium or hafnium with copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/33—Electric or magnetic properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0072—Preparation of particles, e.g. dispersion of droplets in an oil bath
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/50—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/052—Electrodes comprising one or more electrocatalytic coatings on a substrate
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C25B11/065—Carbon
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/075—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0803—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0875—Gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0892—Materials to be treated involving catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201910293182.9A 2018-04-13 2019-04-12 用于二氧化碳还原反应的新型氮掺杂的铜纳米催化剂 Expired - Fee Related CN110368974B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15/953,079 US10883183B2 (en) 2018-04-13 2018-04-13 Method of preparing copper-copper nitride nanocatalysts for carbon dioxides reduction reaction
US15/953,079 2018-04-13

Publications (2)

Publication Number Publication Date
CN110368974A CN110368974A (zh) 2019-10-25
CN110368974B true CN110368974B (zh) 2022-04-26

Family

ID=68053183

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910293182.9A Expired - Fee Related CN110368974B (zh) 2018-04-13 2019-04-12 用于二氧化碳还原反应的新型氮掺杂的铜纳米催化剂

Country Status (4)

Country Link
US (1) US10883183B2 (enExample)
JP (1) JP7113781B2 (enExample)
CN (1) CN110368974B (enExample)
DE (1) DE102019203866A1 (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11267712B2 (en) * 2018-10-10 2022-03-08 Honda Motor Co., Ltd. Tuning products selectivity of CO2 reduction reaction with surface ligands
US11519087B2 (en) 2020-09-30 2022-12-06 Ut-Battelle, Llc Alloy based electrochemical catalyst for conversion of carbon dioxide to hydrocarbons
CN113249748B (zh) * 2021-04-21 2022-08-12 北京航天动力研究所 一种氮掺杂的氧化亚铜电催化剂、制备方法、电极及应用
US12080895B2 (en) * 2022-08-09 2024-09-03 Honda Motor Co., Ltd. Method for the synthesis of high efficiency PT branched nanocatalysts
CN115710724B (zh) * 2022-11-06 2025-07-08 浙江工业大学 一种用于电催化还原二氧化碳的非金属掺杂铜基催化材料及其制备方法和应用
CN116288418B (zh) * 2023-02-16 2025-09-05 国家能源集团新能源技术研究院有限公司 碳基疏水催化电极材料的制备及其在二氧化碳电催化中的应用

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6033422B2 (ja) * 1981-10-26 1985-08-02 三菱瓦斯化学株式会社 炭酸エステルの製造法
AU2004264436B2 (en) * 2003-08-14 2010-11-25 Monsanto Technology Llc Transition metal-carbide and nitride containing catalysts , their preparation and use as oxidation and dehydrogenation catalysts
WO2005060610A2 (en) 2003-12-11 2005-07-07 The Trustees Of Columbia University In The City Ofnew York Nano-sized particles, processes of making, compositions and uses thereof
GB0409877D0 (en) 2004-04-30 2004-06-09 Univ Manchester Preparation of nanoparticle materials
US7208133B2 (en) 2004-11-22 2007-04-24 International Business Machines Corporation Method for the preparation of IV-VI semiconductor nanoparticles
CN101583425A (zh) * 2005-02-17 2009-11-18 孟山都技术公司 含过渡金属的催化剂、包含含过渡金属的催化剂的催化剂组合物、它们的制备方法和作为氧化催化剂的用途
CA2649513A1 (en) 2006-04-12 2007-10-25 Nanomas Technologies, Inc. Nanoparticles, methods of making, and applications using same
KR100797484B1 (ko) * 2006-08-29 2008-01-23 삼성전기주식회사 큐빅 형태의 구리 나노입자의 제조방법
WO2008033388A2 (en) * 2006-09-12 2008-03-20 Qd Vision, Inc. A composite including nanoparticles, methods, and products including a composite
KR100814295B1 (ko) 2006-10-10 2008-03-18 삼성전기주식회사 구리 나노입자의 제조방법 및 그에 의해 제조된 구리나노입자
KR20090012605A (ko) 2007-07-30 2009-02-04 삼성전기주식회사 금속 나노입자의 제조방법
KR20090032839A (ko) 2007-09-28 2009-04-01 삼성전기주식회사 구리계 나노입자의 제조방법
KR20090032841A (ko) * 2007-09-28 2009-04-01 삼성전기주식회사 로드 형태를 포함하는 금속 나노입자의 제조방법
CN101327433A (zh) * 2008-07-30 2008-12-24 中国科学院山西煤炭化学研究所 一种纳米金属碳化物催化剂及制备和应用
US8486305B2 (en) 2009-11-30 2013-07-16 Lockheed Martin Corporation Nanoparticle composition and methods of making the same
CN101805011B (zh) 2010-04-06 2011-11-09 厦门大学 Cu2O超细纳米粒子与自组装纳米微球及其制备方法
US8845878B2 (en) * 2010-07-29 2014-09-30 Liquid Light, Inc. Reducing carbon dioxide to products
JP2012184451A (ja) * 2011-03-03 2012-09-27 Hitachi Cable Ltd 金属微粒子の製造方法及びそれにより得られる金属ペースト並びに金属皮膜
CN102941350B (zh) * 2012-11-06 2015-04-22 南京工业大学 一种纳米铜粉的制备方法
US8852835B2 (en) * 2012-12-12 2014-10-07 Xerox Corporation Black toner
CN103933978B (zh) * 2014-04-10 2015-12-30 中国科学院福建物质结构研究所 一种用于二氧化碳催化转化的负载型纳米催化剂及其制备方法和应用
WO2015195650A1 (en) 2014-06-16 2015-12-23 Kansas State University Research Foundation Direct transformation of bulk materials to nanoparticles
EP3169434A1 (en) * 2014-07-14 2017-05-24 Yeda Research and Development Co., Ltd. Copper nanoparticles for oxidation of pollutants
KR101725315B1 (ko) 2015-04-15 2017-04-10 성균관대학교산학협력단 다양한 크기 조절 및 대용량 합성이 가능한 균일한 구리 나노결정 및 이의 제조 방법
US20170314148A1 (en) 2016-05-02 2017-11-02 Ut-Battelle, Llc Electrochemical catalyst for conversion of co2 to ethanol

Also Published As

Publication number Publication date
US20190316264A1 (en) 2019-10-17
CN110368974A (zh) 2019-10-25
JP7113781B2 (ja) 2022-08-05
JP2019205993A (ja) 2019-12-05
DE102019203866A1 (de) 2019-10-17
US10883183B2 (en) 2021-01-05

Similar Documents

Publication Publication Date Title
US10883183B2 (en) Method of preparing copper-copper nitride nanocatalysts for carbon dioxides reduction reaction
US11131031B2 (en) High-yield preparation of two-dimensional copper nanosheets
Nasretdinova et al. Methylviologen mediated electrochemical synthesis of catalytically active ultrasmall bimetallic PdAg nanoparticles stabilized by CTAC
Ilyas et al. FeNi@ CNS nanocomposite as an efficient electrochemical catalyst for N2-to-NH3 conversion under ambient conditions
US11253920B2 (en) Method for preparation of copper nanocubes utilizing tributylphosphine as a ligand
US12186811B2 (en) Synthetic method for preparing small palladium nanocubes
WO2020115758A1 (en) Fe/Fe3C ENCAPSULATED N-CNT ELECTRODE FOR ELECTROCHEMICAL APPLICATIONS AND METHOD OF PREPARATION THEREOF
Jiwanti et al. Electrochemical reduction of CO 2 using palladium modified boron-doped diamond electrodes: enhancing the production of CO
Zhang et al. Enhancing electrochemical nitrogen reduction with Ru nanowires via the atomic decoration of Pt
Uthirakumar et al. Accelerating photoelectrochemical CO2RR selectively of C2+ products by integrating Ag/Pd cocatalysts on Cu/Cu2O/CuO heterojunction nanorods
Ji et al. Orientated dominating charge separation via crystal facet homojunction inserted into BiOBr for solar-driven CO2 conversion
Ayán-Varela et al. Efficient Pt electrocatalysts supported onto flavin mononucleotide–exfoliated pristine graphene for the methanol oxidation reaction
Zhang et al. Monotonically increasing relationship between conversion selectivity from CO2 to CO and the interface area of Cu-Ag biphasic electrochemical catalyst
CN113774423B (zh) 铜基复合纳米材料及其制备方法和应用
Marepally et al. Supported metallic nanoparticles prepared by an organometallic route to boost the electrocatalytic conversion of CO2
Xue et al. Recent Advances on CO2 Electrochemical Reduction over Cu‐Based Nanocrystals
KR20210061496A (ko) 금속 나노 클러스터 촉매 및 그 제조 방법, 금속 나노 클러스터 촉매를 이용한 요소 합성 방법, 및 금속 나노 클러스터 촉매를 포함하는 전기 화학 시스템
US20220411944A1 (en) Catalyst compositions, processes for forming the catalyst compositions, and uses thereof
CN111013658B (zh) 用表面配体调节co2还原反应的产物选择性
Choi et al. Promoting nitrogen electroreduction to ammonia with bismuth nanocrystals and potassium cations in water
US20240390881A1 (en) Method for synthesis of copper-nickel polyhedral nanocrystals
US20250305166A1 (en) Electronic structure modulation of unusual phase of metal nanomaterials for catalysis
CN115992359B (zh) 一种氮掺杂碳纳米管包裹超细金属纳米粒子的材料及其制备方法和应用
US20250263856A1 (en) Unconventional phase janus nanostructures for electrocatalytic carbon dioxide reduction
Zhang et al. Wide pH range electrocatalytic nitrate reduction to ammonia over high-performance hollow Cu3P nanocubes

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20220426