CN110367584A - A kind of tobacco additive agent and its application - Google Patents
A kind of tobacco additive agent and its application Download PDFInfo
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- CN110367584A CN110367584A CN201910574812.XA CN201910574812A CN110367584A CN 110367584 A CN110367584 A CN 110367584A CN 201910574812 A CN201910574812 A CN 201910574812A CN 110367584 A CN110367584 A CN 110367584A
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- Prior art keywords
- tobacco
- additive agent
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- tobacco additive
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- 241000208125 Nicotiana Species 0.000 title claims abstract description 187
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 187
- 239000000654 additive Substances 0.000 title claims abstract description 74
- 230000000996 additive effect Effects 0.000 title claims abstract description 74
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 68
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 117
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 99
- 239000000284 extract Substances 0.000 claims abstract description 58
- 235000019504 cigarettes Nutrition 0.000 claims abstract description 56
- 235000013311 vegetables Nutrition 0.000 claims abstract description 33
- 239000002994 raw material Substances 0.000 claims abstract description 16
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 62
- 238000000605 extraction Methods 0.000 claims description 39
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 36
- 238000002360 preparation method Methods 0.000 claims description 31
- 239000000843 powder Substances 0.000 claims description 23
- WNGSUWLDMZFYNZ-UHFFFAOYSA-N Leonurine Chemical compound COC1=CC(C(=O)OCCCCN=C(N)N)=CC(OC)=C1O WNGSUWLDMZFYNZ-UHFFFAOYSA-N 0.000 claims description 18
- 229940056319 ferrosoferric oxide Drugs 0.000 claims description 18
- 239000008187 granular material Substances 0.000 claims description 13
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 12
- 239000000725 suspension Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 7
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 235000019441 ethanol Nutrition 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 150000002926 oxygen Chemical class 0.000 claims 1
- 210000003296 saliva Anatomy 0.000 claims 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 15
- 239000003546 flue gas Substances 0.000 abstract description 15
- 235000009508 confectionery Nutrition 0.000 abstract description 6
- 239000003205 fragrance Substances 0.000 abstract description 6
- 239000000706 filtrate Substances 0.000 description 24
- XKABJYQDMJTNGQ-VIFPVBQESA-N n-nitrosonornicotine Chemical compound O=NN1CCC[C@H]1C1=CC=CN=C1 XKABJYQDMJTNGQ-VIFPVBQESA-N 0.000 description 14
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- 238000001354 calcination Methods 0.000 description 10
- 238000001035 drying Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 235000019580 granularity Nutrition 0.000 description 8
- 239000000523 sample Substances 0.000 description 6
- 235000019505 tobacco product Nutrition 0.000 description 5
- 238000001291 vacuum drying Methods 0.000 description 5
- BXYPVKMROLGXJI-JTQLQIEISA-N 3-[(2s)-1-nitrosopiperidin-2-yl]pyridine Chemical compound O=NN1CCCC[C@H]1C1=CC=CN=C1 BXYPVKMROLGXJI-JTQLQIEISA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000013068 control sample Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000006101 laboratory sample Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000008442 polyphenolic compounds Chemical class 0.000 description 2
- 235000013824 polyphenols Nutrition 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- 125000003349 3-pyridyl group Chemical group N1=C([H])C([*])=C([H])C([H])=C1[H] 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- -1 N- nitrosamine compound Chemical class 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000019506 cigar Nutrition 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000005291 magnetic effect Effects 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- 150000004005 nitrosamines Chemical class 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 235000019587 texture Nutrition 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/24—Treatment of tobacco products or tobacco substitutes by extraction; Tobacco extracts
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/302—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by natural substances obtained from animals or plants
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Botany (AREA)
- Manufacture Of Tobacco Products (AREA)
Abstract
The present invention relates to technical field of cigarettes, and in particular to a kind of tobacco additive agent and its application.The present invention provides a kind of tobacco additive agent, the raw material including following parts by weight: propylene glycol and 8-45 parts of vegetables glycerol, and 1-5 parts of tobacco extract.Tobacco additive agent provided by the invention can be effectively suppressed since the addition of PG and VG leads to the sweet sense of flue gas, greatly strengthens suction mouthfeel, while improving fragrance when suction, keeps flue gas softer.
Description
Technical field
The present invention relates to technical field of cigarettes, and in particular to a kind of tobacco additive agent and its application.
Background technique
Main product form of the traditional cigarette (or traditional point lit cigarettes) as tobacco consumption, has more than 100 years
History.Increasing with the public to the reinforcement and government of cigarette recognizing dangers to cigarette control dynamics, countries in the world tobacco
Enterprise strengthens the exploitation to new tobacco products.New tobacco products to be to heat non-combustion-type cigarette as representative at present, wherein
Closest to traditional cigarette in terms of physiology impression, sucking, there is good development potentiality.
Studies have shown that most of harmful components are that tobacco passes through during high-temp combustion in traditional point lit cigarettes flue gas
What the reactions such as thermal cracking, thermal synthesis generated.Wherein, the peculiar N- nitrosamine compound of tobacco is not only Huffman inventory and the U.S.
Important compound in food and medicine Surveillance Authority " harmful and potentially harmful substance list in tobacco product and flue gas ", and
Important component in international cancer research institution " 28 kinds of harmful substances in smoke-free tobacco product " list, there are mainly four types of shapes
Formula: N- nitrosonornicotine (NNN), N- nitrosoanabasine (NAT), N- nitroso anabasine (NAB) and 4- (methyl nitrous
Amido) -1- (3- pyridyl group) -1- butanone (NNK).Wherein, N- nitrosonornicotine (NNN) is the generation in tobacco-specific nitrosamine
Table compound.Therefore, how to reduce the burst size of N- nitrosonornicotine in tobacco smoke is that domestic and international cigarette enterprise is ground
One of Main way studied carefully.
Compared to traditional point lit cigarettes, the characteristics of heating non-combustion-type cigarette is heating tobacco rather than burning tobacco, is kept away
Exempt from Pintsch process when result of combustion of tobacco, so that burst size of harmful components substantially reduces in the main flume for generating it, and
It is supplied to the certain tobacco feature impression of consumer.However compared to traditional point lit cigarettes, non-combustion-type cigarette is heated in perfume (or spice)
Gas, jealous etc. still have larger gap, have seriously affected consumer and degree is approved and received to it.
Prior art CN108835714A discloses a kind of tobacco filler of dual-purpose type cigarette, including tobacco material, institute
It states and is added with PG (propylene glycol) and VG (vegetables glycerol) in tobacco material, in the tobacco material hundred parts of weight shared by PG and VG
Than for 5%-50%, in the tobacco material shared by moisture content hundred parts of weight than being 5%-10%.Above scheme provides dual-purpose
The tobacco filler of type cigarette, when as the non-burning suction of low temperature, " bubble tabacco water in smog when can reduce baking conventional cigarette
The acid smell of sample ", the fragrance for making it burn when aspirating closer to conventional cigarette.However in the tobacco filler of above scheme offer
It is laid particular stress on since the addition of PG and VG will lead to flue gas sweet sense, affects impression when suction, reduce suction mouthfeel.
Summary of the invention
It is an object of the invention to overcome to lay particular stress on since the addition of PG and VG easily leads to flue gas sweet sense in the prior art, shadow
The problem of ringing suction mouthfeel, to provide a kind of tobacco additive agent and its application.
In order to achieve the above objectives, the present invention adopts the following technical scheme:
A kind of tobacco additive agent, the raw material including following parts by weight: propylene glycol and 8-45 parts of vegetables glycerol, tobacco extract
1-5 parts.
Preferably, the tobacco extract is to be prepared into from Yunnan tobacco and Zimbabwe's tobacco leaf by ethyl alcohol extraction
It arrives.
Preferably, the preparation method of the tobacco extract includes the following steps: Yunnan tobacco and Zimbabwe's tobacco leaf
It is added in the ethanol water that mass fraction is 40-60% and is extracted, filtered after extraction, obtain filtrate, filtrate concentration
Drying is to get the tobacco extract.
Preferably, the extraction temperature is 20-40 DEG C, and the extraction time is 6-8 hours.
Preferably, the weight ratio of the Yunnan tobacco and Zimbabwe's tobacco leaf is 1:0.8-1.2.
It preferably, further include 0.01-0.5 parts of leonurine hydrochloride.
It preferably, further include 0.1-1.5 parts of ferroso-ferric oxide modified aluminas.
Preferably, the preparation method of the ferroso-ferric oxide modified aluminas includes the following steps:
1) alumina powder is calcined at 500-600 DEG C, obtains calcined aluminium oxide；
2) calcined aluminium oxide is added in hydroxyethyl cellulose aqueous solution, stirs, obtains aluminum oxide suspension；
3) nano ferriferrous oxide granule is added into the aluminum oxide suspension that step 2) obtains, continues to stir, vacuum is dry
Dry, crushing obtains the modified aluminas.
Preferably, the mass ratio of the nano ferriferrous oxide granule and the alumina powder is 1:10-20.
Preferably, the propylene glycol is 4-41 parts.
Preferably, the vegetables glycerol is 4-41 parts.
The present invention also provides a kind of tobacco additive agents described above in point lit cigarettes and/or heating non-combustion-type cigarette
In application.
The tobacco additive agent can be added in tobacco material in the present invention, and the moisture content in the tobacco material is
6-9%.Preferably, the tobacco material is Filamentous, particle or sheet.When the tobacco additive agent is applied to heating non-combustion-type
When in cigarette, optionally, cigarette paper used is cigar roll paper.
Beneficial effects of the present invention:
1) present invention provides a kind of tobacco additive agent, the raw material including following parts by weight: propylene glycol and vegetables glycerol 8-45
Part, 1-5 parts of tobacco extract.The present invention adds tobacco extract on the basis of propylene glycol, vegetables glycerol, is extracted using tobacco
The volatile materials such as the alcohols, aldehydes, lower fatty acid and its ester that contain in object effectively inhibit the addition due to PG and VG to lead
The sweet sense for causing flue gas, greatly strengthens suction mouthfeel, while improving fragrance when suction, keeps flue gas softer.
2) present invention provides a kind of tobacco additive agent, and further, the tobacco extract is from Yunnan tobacco and Jin Ba
It is prepared in cloth Wei tobacco leaf by ethyl alcohol extraction；The weight ratio of the Yunnan tobacco and Zimbabwe's tobacco leaf is 1:0.8-1.2.
The tobacco extract that the present invention is obtained from the Yunnan tobacco and Zimbabwe's tobacco leaf of specific proportion by alcohol extracting, more conducively inhibits
Since the addition of PG and VG leads to the sweet sense of flue gas, make that fragrance is plentiful, texture is obviously improved.
3) present invention provides a kind of tobacco additive agent, further includes 0.01-0.5 parts of leonurine hydrochloride further.Hair
Bright people passes through a large amount of experimental study, has been surprisingly found that the leonurine hydrochloride of specific quantity is added in tobacco material can be effective
The burst size of N- nitrosonornicotine in flue gas is reduced, this may be since the unique steric configuration of leonurine is more conducive to it
It has an effect with nitrosamines substance, to effectively reduce the burst size of N- nitrosonornicotine in flue gas.
4) present invention provides a kind of tobacco additive agent, further includes ferroso-ferric oxide modified aluminas 0.1-1.5 further
Part.Being modified using ferroso-ferric oxide to aluminium oxide for the invention, makes its modified aluminium oxide be provided with magnetics
Characteristic.Inventor passes through a large amount of experimental study, it is found that aluminium oxide modified can effectively reduce N- nitroso in flue gas and drop
The burst size of nicotine.
5) present invention provides a kind of tobacco additive agent, further, by carrying out alumina powder at 500-600 DEG C
Calcining, makes it possess gap structure abundant, then under the adhesive effect of hydroxyethyl cellulose, makes nano ferriferrous oxide
Grain is distributed in around aluminium oxide, and by vacuum drying, crushing obtains modified aluminas, and the modified aluminas is possessing abundant sky
Also there is magnetism characteristic on the basis of gap, substantially increase the adsorption capacity of N- nitrosonornicotine in flue gas.Further, exist
In the preparation process of modified aluminas, the mass ratio of the nano ferriferrous oxide granule and the alumina powder is 1:10-
20.Under this special ratios, the nano ferriferrous oxide granule is only seldom partially coated on around aluminium oxide, above-mentioned state
Modified aluminas be more conducive to adsorb N- nitrosonornicotine, it is modified oxidized when nano ferriferrous oxide granule additional amount is excessive
Aluminium will appear decline to the adsorption capacity of N- nitrosonornicotine.
Specific embodiment
There is provided following embodiments is to preferably further understand the present invention, it is not limited to the best embodiment party
Formula is not construed as limiting the contents of the present invention and protection scope, anyone under the inspiration of the present invention or by the present invention and its
The feature of his prior art is combined and any and identical or similar product of the present invention for obtaining, all falls within of the invention
Within protection scope.
Specific experiment step or condition person are not specified in embodiment, according to the literature in the art described routine experiment
The operation of step or condition can carry out.Reagents or instruments used without specified manufacturer, being can be by commercially available acquisition
Conventional reagent product.
Embodiment 1
Present embodiments provide a kind of tobacco additive agent, including the following raw material: 4g propylene glycol, 41g vegetables glycerol, 1g tobacco
Extract.
The preparation method of the tobacco extract includes the following steps: 100g Yunnan tobacco and 80g Zimbabwe tobacco leaf
It is added in the ethanol water that 1000ml mass fraction is 40% and is extracted, filtered after extraction, obtain filtrate, filtrate is dense
Contracting is dry to get the tobacco extract；The extraction temperature is 20 DEG C, and the extraction time is 8 hours.
Above-mentioned tobacco additive agent the preparation method is as follows: by propylene glycol, vegetables glycerol and tobacco extract be uniformly mixed i.e.
Obtain the tobacco additive agent.
Embodiment 2
Present embodiments provide a kind of tobacco additive agent, including the following raw material: 41g propylene glycol, 4g vegetables glycerol, 5g tobacco
Extract.
The preparation method of the tobacco extract includes the following steps: 100g Yunnan tobacco and 120g Zimbabwe tobacco leaf
It is added in the ethanol water that 1500ml mass fraction is 60% and is extracted, filtered after extraction, obtain filtrate, filtrate is dense
Contracting is dry to get the tobacco extract；The extraction temperature is 40 DEG C, and the extraction time is 6 hours.
Above-mentioned tobacco additive agent the preparation method is as follows: by propylene glycol, vegetables glycerol and tobacco extract be uniformly mixed i.e.
Obtain the tobacco additive agent.
Embodiment 3
Present embodiments provide a kind of tobacco additive agent, including the following raw material: 12g propylene glycol, 12g vegetables glycerol, 2g cigarette
Careless extract.
The preparation method of the tobacco extract includes the following steps: to add 50g Yunnan tobacco and 50g Zimbabwe tobacco leaf
Enter and extracted in the ethanol water for being 50% to 1000ml mass fraction, filtered after extraction, obtains filtrate, filtrate concentration
Drying is to get the tobacco extract；The extraction temperature is 30 DEG C, and the extraction time is 7 hours.
Above-mentioned tobacco additive agent the preparation method is as follows: by propylene glycol, vegetables glycerol and tobacco extract be uniformly mixed i.e.
Obtain the tobacco additive agent.
Embodiment 4
Present embodiments provide a kind of tobacco additive agent, including the following raw material: 12g propylene glycol, 12g vegetables glycerol, 2g cigarette
Careless extract, 0.01g leonurine hydrochloride.
The preparation method of the tobacco extract includes the following steps: to add 50g Yunnan tobacco and 50g Zimbabwe tobacco leaf
Enter and extracted in the ethanol water for being 50% to 1000ml mass fraction, filtered after extraction, obtains filtrate, filtrate concentration
Drying is to get the tobacco extract；The extraction temperature is 30 DEG C, and the extraction time is 7 hours.
Above-mentioned tobacco additive agent the preparation method is as follows: by propylene glycol, vegetables glycerol, tobacco extract and leonurine salt
Hydrochlorate is uniformly mixed up to the tobacco additive agent.
Embodiment 5
Present embodiments provide a kind of tobacco additive agent, including the following raw material: 20g propylene glycol, 5g vegetables glycerol, 4g tobacco
Extract, 0.5g leonurine hydrochloride.
The preparation method of the tobacco extract includes the following steps: to add 50g Yunnan tobacco and 50g Zimbabwe tobacco leaf
Enter and extracted in the ethanol water for being 50% to 1000ml mass fraction, filtered after extraction, obtains filtrate, filtrate concentration
Drying is to get the tobacco extract；The extraction temperature is 30 DEG C, and the extraction time is 7 hours.
Above-mentioned tobacco additive agent the preparation method is as follows: by propylene glycol, vegetables glycerol, tobacco extract and leonurine salt
Hydrochlorate is uniformly mixed up to the tobacco additive agent.
Embodiment 6
Present embodiments provide a kind of tobacco additive agent, including the following raw material: 12g propylene glycol, 12g vegetables glycerol, 2g cigarette
Careless extract, 0.01g leonurine hydrochloride, 0.1g ferroso-ferric oxide modified aluminas.
The preparation method of the tobacco extract includes the following steps: to add 50g Yunnan tobacco and 50g Zimbabwe tobacco leaf
Enter and extracted in the ethanol water for being 50% to 1000ml mass fraction, filtered after extraction, obtains filtrate, filtrate concentration
Drying is to get the tobacco extract；The extraction temperature is 30 DEG C, and the extraction time is 7 hours.
The preparation method of the ferroso-ferric oxide modified aluminas includes the following steps:
1) 100g alumina powder is subjected at 500 DEG C calcining 0.5h, the powder of 30 mesh granularities is ground into after calcining, is obtained
To calcined aluminium oxide；
2) calcined aluminium oxide is added in the hydroxyethyl cellulose aqueous solution that 200ml mass fraction is 10%, is stirred
10min is mixed, aluminum oxide suspension is obtained；
3) 10g nano ferriferrous oxide granule is added into the aluminum oxide suspension that step 2) obtains, continues to stir
30min, vacuum drying, the powder for being ground into 30 mesh granularities obtain the modified aluminas.
Above-mentioned tobacco additive agent the preparation method is as follows: by propylene glycol, vegetables glycerol, tobacco extract, leonurine salt
Hydrochlorate and ferroso-ferric oxide modified aluminas are uniformly mixed up to the tobacco additive agent.
Embodiment 7
Present embodiments provide a kind of tobacco additive agent, including the following raw material: 14g propylene glycol, 10g vegetables glycerol, 2g cigarette
Careless extract, 0.2g leonurine hydrochloride, 1.5g ferroso-ferric oxide modified aluminas.
The preparation method of the tobacco extract includes the following steps: to add 50g Yunnan tobacco and 50g Zimbabwe tobacco leaf
Enter and extracted in the ethanol water for being 50% to 1000ml mass fraction, filtered after extraction, obtains filtrate, filtrate concentration
Drying is to get the tobacco extract；The extraction temperature is 30 DEG C, and the extraction time is 7 hours.
The preparation method of the ferroso-ferric oxide modified aluminas includes the following steps:
1) 100g alumina powder is subjected at 600 DEG C calcining 0.5h, the powder of 30 mesh granularities is ground into after calcining, is obtained
To calcined aluminium oxide；
2) calcined aluminium oxide is added in the hydroxyethyl cellulose aqueous solution that 200ml mass fraction is 10%, is stirred
10min is mixed, aluminum oxide suspension is obtained；
3) 5g nano ferriferrous oxide granule is added into the aluminum oxide suspension that step 2) obtains, continues to stir 30min,
Vacuum drying, the powder for being ground into 30 mesh granularities obtain the modified aluminas.
Above-mentioned tobacco additive agent the preparation method is as follows: by propylene glycol, vegetables glycerol, tobacco extract, leonurine salt
Hydrochlorate and ferroso-ferric oxide modified aluminas are uniformly mixed up to the tobacco additive agent.
Embodiment 8
Present embodiments provide a kind of tobacco additive agent, including the following raw material: 4g propylene glycol, 4g vegetables glycerol, 2g tobacco
Extract, 0.8g ferroso-ferric oxide modified aluminas.
The preparation method of the tobacco extract includes the following steps: to add 50g Yunnan tobacco and 50g Zimbabwe tobacco leaf
Enter and extracted in the ethanol water for being 50% to 1000ml mass fraction, filtered after extraction, obtains filtrate, filtrate concentration
Drying is to get the tobacco extract；The extraction temperature is 30 DEG C, and the extraction time is 7 hours.
The preparation method of the ferroso-ferric oxide modified aluminas includes the following steps:
1) 100g alumina powder is subjected at 550 DEG C calcining 0.5h, the powder of 30 mesh granularities is ground into after calcining, is obtained
To calcined aluminium oxide；
2) calcined aluminium oxide is added in the hydroxyethyl cellulose aqueous solution that 200ml mass fraction is 12%, is stirred
10min is mixed, aluminum oxide suspension is obtained；
3) 10g nano ferriferrous oxide granule is added into the aluminum oxide suspension that step 2) obtains, continues to stir
30min, vacuum drying, the powder for being ground into 30 mesh granularities obtain the modified aluminas.
Above-mentioned tobacco additive agent the preparation method is as follows: by propylene glycol, vegetables glycerol, tobacco extract and ferroso-ferric oxide
Modified aluminas is uniformly mixed up to the tobacco additive agent.
Embodiment 9
Present embodiments provide a kind of tobacco additive agent, including the following raw material: 12g propylene glycol, 12g vegetables glycerol, 2g cigarette
Careless extract, 0.01g tea polyphenols.
The preparation method of the tobacco extract includes the following steps: to add 50g Yunnan tobacco and 50g Zimbabwe tobacco leaf
Enter and extracted in the ethanol water for being 50% to 1000ml mass fraction, filtered after extraction, obtains filtrate, filtrate concentration
Drying is to get the tobacco extract；The extraction temperature is 30 DEG C, and the extraction time is 7 hours.
Above-mentioned tobacco additive agent the preparation method is as follows: by propylene glycol, vegetables glycerol, tobacco extract and tea polyphenols mix
Uniformly up to the tobacco additive agent.
Embodiment 10
Present embodiments provide a kind of tobacco additive agent, including the following raw material: 12g propylene glycol, 12g vegetables glycerol, 2g cigarette
Careless extract, 0.01g leonurine hydrochloride, 0.1g ferroso-ferric oxide modified aluminas.
The preparation method of the tobacco extract includes the following steps: to add 50g Yunnan tobacco and 50g Zimbabwe tobacco leaf
Enter and extracted in the ethanol water for being 50% to 1000ml mass fraction, filtered after extraction, obtains filtrate, filtrate concentration
Drying is to get the tobacco extract；The extraction temperature is 30 DEG C, and the extraction time is 7 hours.
The preparation method of the ferroso-ferric oxide modified aluminas includes the following steps:
1) 100g alumina powder is subjected at 500 DEG C calcining 0.5h, the powder of 30 mesh granularities is ground into after calcining, is obtained
To calcined aluminium oxide；
2) calcined aluminium oxide is added in the hydroxyethyl cellulose aqueous solution that 200ml mass fraction is 10%, is stirred
10min is mixed, aluminum oxide suspension is obtained；
3) 100g nano ferriferrous oxide granule is added into the aluminum oxide suspension that step 2) obtains, continues to stir
30min, vacuum drying, the powder for being ground into 30 mesh granularities obtain the modified aluminas.
Above-mentioned tobacco additive agent the preparation method is as follows: by propylene glycol, vegetables glycerol, tobacco extract, leonurine salt
Hydrochlorate and ferroso-ferric oxide modified aluminas are uniformly mixed up to the tobacco additive agent.
Embodiment 11
Present embodiments provide a kind of tobacco additive agent, including the following raw material: 12g propylene glycol, 12g vegetables glycerol, 2g cigarette
Careless extract, 0.01g leonurine hydrochloride, 0.1g alumina powder and nano ferriferrous oxide granule (wherein, four oxygen of nanometer
The mass ratio for changing three iron particles and alumina powder is 1:10, and alumina powder passes through 500 DEG C of calcining 0.5h).
The preparation method of the tobacco extract includes the following steps: to add 50g Yunnan tobacco and 50g Zimbabwe tobacco leaf
Enter and extracted in the ethanol water for being 50% to 1000ml mass fraction, filtered after extraction, obtains filtrate, filtrate concentration
Drying is to get the tobacco extract；The extraction temperature is 30 DEG C, and the extraction time is 7 hours.
Above-mentioned tobacco additive agent the preparation method is as follows: by propylene glycol, vegetables glycerol, tobacco extract, leonurine salt
Hydrochlorate, alumina powder and nano ferriferrous oxide granule are uniformly mixed up to the tobacco additive agent.
Comparative example 1
This comparative example provides a kind of tobacco additive agent, including the following raw material: 12g propylene glycol, 12g vegetables glycerol.
Above-mentioned tobacco additive agent adds the preparation method is as follows: being uniformly mixed propylene glycol, vegetables glycerol up to the tobacco
Add agent.
Test example 1
It selects Yunnan brand cigarette (point lit cigarettes) as blank cigarette, extracts laboratory sample by GB/T5606.1,
7 blank cigarette samples are prepared, then one of blank cigarette sample obtains embodiment 1-5 and comparative example 1 as control sample
Tobacco additive agent be uniformly sprayed onto respectively according to 1% additive amount for accounting for pipe tobacco weight on the pipe tobacco of the remaining blank cigarette
(one blank cigarette sample of the corresponding sprinkling of the additive of each embodiment or comparative example), according to " cigarette "
The aesthetic quality of GB5606.4-2005 Sensory Quality of Cigarette technical requirements evaluating cigarette, wherein being in each index
Score value more high organoleptic quality is better.
Influence of 1 tobacco additive agent of table to Sensory Quality of Cigarette
From the data in table 1, it can be seen that the present invention adds tobacco extract, three kinds of components on the basis of propylene glycol, vegetables glycerol
It cooperates and is remarkably improved fragrance, the harmony of cigarette, while effectively improving flue gas irritation.Surprisingly benefit is female
The addition of potash hydrochloride also has having some improvement for the fragrance of cigarette, harmony and flue gas irritation.
Test example 2
It selects Yunnan brand cigarette (point lit cigarettes) as blank cigarette, extracts laboratory sample by GB/T5606.1,
13 blank cigarette samples are prepared, then one of blank cigarette sample obtains embodiment 1-11 and comparative example 1 as control sample
To tobacco additive agent be uniformly sprayed on the pipe tobacco of the remaining blank cigarette respectively according to 1% additive amount for accounting for pipe tobacco weight
(one blank cigarette sample of the corresponding sprinkling of the additive of each embodiment or comparative example), using tobacco business standard YC/T184-
Gas-chromatography-thermal energy analysis combined instrument (GC-TEA) in the measurement of 2004 tobaccos and the peculiar N- nitrosamine of tobacco product tobacco is fixed
Measure the burst size of distinctive N- nitrosonornicotine (NNN) in analysis detection cigarette smoke.
The application effect (ng/ branch) of 2 tobacco additive agent of table N- nitrosonornicotine release peculiar to tobacco in cigarette smoke
| Sample | NNN |
| Control sample | 3.59 |
| Embodiment 1 | 3.50 |
| Embodiment 2 | 3.46 |
| Embodiment 3 | 3.49 |
| Embodiment 4 | 3.21 |
| Embodiment 5 | 3.11 |
| Embodiment 6 | 2.93 |
| Embodiment 7 | 2.55 |
| Embodiment 8 | 3.35 |
| Embodiment 9 | 3.47 |
| Embodiment 10 | 3.05 |
| Embodiment 11 | 3.10 |
| Comparative example 1 | 3.57 |
Test example 3
The tobacco additive agent that embodiment 1 and comparative example 1 are obtained as heating non-combustion-type cigarette additive formulations it
One, it is added in new cigarette tobacco material according to 1% additive amount for accounting for tobacco material weight, smoking result shows to compare
It is fragrant in the heating non-combustion type cigarette gas of tobacco additive agent prepared by additive prepared by addition comparative example 1, addition embodiment 1
Taste obviously increases, and irritation decline, sweet sense is substantially reduced.
Obviously, the above embodiments are merely examples for clarifying the description, and does not limit the embodiments.It is right
For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or
It changes.There is no necessity and possibility to exhaust all the enbodiments.And it is extended from this it is obvious variation or
It changes still within the protection scope of the invention.
Claims (10)
1. a kind of tobacco additive agent, which is characterized in that the raw material including following parts by weight: propylene glycol and 8-45 parts of vegetables glycerol,
1-5 parts of tobacco extract.
2. tobacco additive agent according to claim 1, which is characterized in that the tobacco extract is from Yunnan tobacco and saliva
It is prepared in Ba Buwei tobacco leaf by ethyl alcohol extraction.
3. tobacco additive agent according to claim 1 or 2, which is characterized in that the Yunnan tobacco and Zimbabwe's tobacco leaf
Weight ratio be 1:0.8-1.2.
4. tobacco additive agent according to claim 1-3, which is characterized in that further include leonurine hydrochloride
0.01-0.5 parts.
5. tobacco additive agent according to claim 1-4, which is characterized in that further include the modified oxygen of ferroso-ferric oxide
Change aluminium 0.1-1.5 parts.
6. tobacco additive agent according to claim 5, which is characterized in that the preparation of the ferroso-ferric oxide modified aluminas
Method includes the following steps:
1) alumina powder is calcined at 500-600 DEG C, obtains calcined aluminium oxide；
2) calcined aluminium oxide is added in hydroxyethyl cellulose aqueous solution, stirs, obtains aluminum oxide suspension；
3) nano ferriferrous oxide granule is added into the aluminum oxide suspension that step 2) obtains, continues to stir, be dried in vacuo, powder
It is broken to obtain the modified aluminas.
7. tobacco additive agent according to claim 6, which is characterized in that the nano ferriferrous oxide granule and the oxygen
The mass ratio for changing aluminium powder is 1:10-20.
8. tobacco additive agent according to claim 1-7, which is characterized in that the propylene glycol is 4-41 parts.
9. tobacco additive agent according to claim 1-8, which is characterized in that the vegetables glycerol is 4-41 parts.
10. the described in any item tobacco additive agents of claim 1-9 are in point lit cigarettes and/or heating non-combustion-type cigarette
Using.
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| CN101015391A (en) * | 2007-03-08 | 2007-08-15 | 云南烟草科学研究院 | Composite additive for reducing harmful constituents in cigarette smoke gas and use thereof |
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