CN110358644A - One kind brightening piece and preparation method thereof - Google Patents
One kind brightening piece and preparation method thereof Download PDFInfo
- Publication number
- CN110358644A CN110358644A CN201910736357.9A CN201910736357A CN110358644A CN 110358644 A CN110358644 A CN 110358644A CN 201910736357 A CN201910736357 A CN 201910736357A CN 110358644 A CN110358644 A CN 110358644A
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- China
- Prior art keywords
- woven fabrics
- piece
- bleaching agent
- solar energy
- carrier non
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses one kind to brighten piece and preparation method thereof, and the one kind invented herein brightens piece with good whitening effect, and clothing has adsorbed solar energy bleaching agent in washing process.Under the influence of light, the bleaching agent becomes more active to clothing during drying, the oxidation material of transition state can be formed, and the substance reacts with the spot (such as tea, coffee, red wine ...) that can be bleached, be translated into colourless and usually water-soluble form removal.Clothing is set to reach whiter, brighter, more gorgeous feeling.
Description
Technical field
The present invention relates to field of daily chemicals more particularly to one kind to brighten piece and preparation method thereof.
Background technique
White articles generally have slight suction to the blue light (450-480nm) in visible light (wave-length coverage 400-800nm)
It receives, and causes blue deficiency, make its yellowish, give outmoded unclean sense since whiteness is affected.
The fabrics such as light color or natural fiber, regenerated fiber and the synthetic fibers of white place meeting yellowing after a period of time.It is general
It is yellow as ultraviolet light irradiation causes fabric yellowing, and to change with ultraviolet wavelength the reason is that complicated, do not cause the degree of yellowing also not
Together, the ultraviolet wavelength for causing yellowing is about 200-331nm, and influencing maximum wavelength is 279-292nm；Heat, light or other spokes
It penetrates, chemicals and biodegrade can also make fiber degradation and cause yellowing；Such as non-ironing anti-creasing agent, antibacterial are added in textile finishing
Deodorant, oils, lubricant, resin, fluorescent whitening agent and metallic compound can also cause yellowing；Oxygen causes ultraviolet light irradiation
Yellowing effect is very big；Perspire, home washings and bleaching and residue for generating etc. can all cause yellowing.
Fluorescent whitening agent is added in current most of washings to improve the whiteness of fabric.Common fluorescent whitening agent is hexichol
Two class of ethylene biphenyl sulfonic acid (DSBP) and diaminobenzil triazine sulfonic acid (CCDAS), launches wave
The invisible ultraviolet light of long 340nm-380nm, yellowing caused by being not only able to effectively make up matrix due to blue light defect, and
The light intensity of blue wave band is increased, is visually significantly improved the whiteness and brightness of fabric in this way, but spot is not gone
Except effect.
Summary of the invention
To solve the disadvantage that the prior art and deficiency, one kind is provided and brightens piece and preparation method thereof, to provide a kind of tool
There is the carrier non-woven fabrics of solar energy bleaching agent.
One kind brightens piece and preparation method thereof provided for achieving the object of the present invention, is floated by carrier non-woven fabrics, solar energy
White dose and surfactant composition, the carrier non-woven fabrics is by Artificial Fibers cloth or synthetic fiber cloth or Artificial Fibers cloth and conjunction
It is combined at both fiber cloths.
As a further improvement of the foregoing solution, the solar energy bleaching agent and surfactant and carrier non-woven fabrics
Quality proportioning is respectively as follows: 0.15~0.45:0.02~0.08:1.
As a further improvement of the foregoing solution, the Artificial Fibers cloth be common viscose fiber in viscose rayon, it is strong
Any one of power viscose rayon, modified viscose fiber.
As a further improvement of the foregoing solution, the synthetic fiber cloth is polyolefin fibrids, polypropylene fibre, appointing in terylene
It is a kind of.
As a further improvement of the foregoing solution, the solar energy bleaching agent, can during cloth drying under the influence of light
To become active bleaching agent, form the transition oxide matter to react with the spot that can be bleached, be translated into it is colourless and
Usually water-soluble form.
As a further improvement of the foregoing solution, the solar energy bleaching agent isSerial Tinolux PSA15
With any one of Tinolux BMC or their combination.
As a further improvement of the foregoing solution, the surfactant is fatty glyceride, fatty acid sorbitan, gathers
Any one of sorb ester or their combination.
Preparation method comprises the following steps that
(1) viscose rayon is uniformly mixed, is sufficiently impregnated in solar energy bleaching agent solution, obtain being attached with solar energy drift
White dose of viscose rayon；
(2) viscose rayon for obtaining step (1) combs uniformly, and the viscose rayon lapping after combing is reticulated structure
Loose fabric；
(3) draw forming is carried out to the loose fabric of reticular structure, obtains staple fibre fabric, the artificial fibre after counter extensioin
Dimension fabric and synthetic fiber fabric carry out compound obtaining carrier non-woven fabrics；
(4) compound obtained carrier non-woven fabrics is carried out dehydrating, dewatered carrier non-woven fabrics is carried out at drying
Reason, by carrier non-woven fabrics clot after drying；
(5) by surfactant solution rotary printing in any side by step (4) treated carrier non-woven fabrics,
Drying, clot obtain the carrier non-woven fabrics with solar energy bleaching agent, that is, brighten piece.
The beneficial effects of the present invention are:
Compared with prior art, the invention has the following advantages that the one kind invented herein, which brightens piece, has good brighten
Effect, clothing have adsorbed solar energy bleaching agent in washing process.Under the influence of light, the bleaching agent becomes clothing during drying
It is more active, the oxidation material of transition state can be formed, and the substance and the spot that can bleach are (such as tea, coffee, red
Wine ...) it reacts, it is translated into colourless and usually water-soluble form removal.To reach pure white effect, and it is non-fluorescence
The vision of brightening agent brightens, and clothing is made to reach whiter, brighter, more gorgeous feeling.
Detailed description of the invention
Below in conjunction with attached drawing, specific embodiments of the present invention will be described in further detail, in which:
Fig. 1 washs forward and backward effect picture for white fabrics, wherein (a) is that the effect picture for brightening piece is not used, it (b) is to make
With the effect picture for brightening piece；
Fig. 2 is the effect picture that finished product brightens piece, wherein (a) is the Local map that finished product brightens piece；(b) piece is brightened for finished product
Lateral optical microscope；(c) longitudinal optical microscope of piece is brightened for finished product.
Specific embodiment
Embodiment 1
Take carrier non-woven fabrics 2g, wherein fiber cloth is by 70% viscose rayon and 30% polyolefin fibrids (polypropylene
Fiber) composition, each to form with the weight ratio of carrier non-woven fabrics successively are as follows: 1: solar energy bleaching agent (Series
Tinolux PSA 15) 0.15: surfactant (fatty glyceride) 0.02.
Preparation method including the following steps:
(1) viscose rayon is sent into shredding case and is uniformly mixed, sufficiently impregnated, obtain attached in solar energy bleaching agent solution
Have the viscose rayon of solar energy bleaching agent；
(2) viscose rayon for obtaining step (1) is sent into carding machine combing uniformly, and the viscose rayon after combing is sent into paving
Net machine, lapping reticulate the loose fabric of structure；
(3) draw forming is carried out to the loose fabric of reticular structure, obtains staple fibre fabric, the artificial fibre after counter extensioin
Dimension fabric and synthetic fiber fabric carry out compound obtaining carrier non-woven fabrics；
(4) compound obtained carrier non-woven fabrics is carried out dehydrating with roll, dewatered carrier non-woven fabrics is carried out
Drying and processing, by carrier non-woven fabrics clot after drying；
(5) by solar energy bleaching agent by rotary printing by any one of step (4) treated carrier non-woven fabrics
Side, drying, clot obtain the carrier non-woven fabrics with solar energy bleaching agent, that is, brighten piece.
Embodiment 2
Take carrier non-woven fabrics 2g, wherein fiber cloth is made of 70% viscose rayon and 30% polypropylene fibre, each composition and load
The weight ratio of body non-woven fabrics is successively are as follows: 1: solar energy bleaching agent (Serial Tinolux PSA 15 and Tinolux
BMC is with the combination of arbitrary proportion) 0.45: surfactant (fatty acid sorbitan) 0.08.
Preparation method including the following steps:
(1) viscose rayon is sent into shredding case and is uniformly mixed, sufficiently impregnated, obtain attached in solar energy bleaching agent solution
Have the viscose rayon of solar energy bleaching agent；
(2) viscose rayon for obtaining step (1) is sent into carding machine combing uniformly, and the viscose rayon after combing is sent into paving
Net machine, lapping reticulate the loose fabric of structure；
(3) draw forming is carried out to the loose fabric of reticular structure, obtains staple fibre fabric, the artificial fibre after counter extensioin
Dimension fabric and synthetic fiber fabric carry out compound obtaining carrier non-woven fabrics；
(4) compound obtained carrier non-woven fabrics is carried out dehydrating with roll, dewatered carrier non-woven fabrics is carried out
Drying and processing, by carrier non-woven fabrics clot after drying；
(5) by solar energy bleaching agent by rotary printing by any one of step (4) treated carrier non-woven fabrics
Side, drying, clot obtain the carrier non-woven fabrics with solar energy bleaching agent, that is, brighten piece.
Embodiment 3
Take carrier non-woven fabrics 2g, wherein fiber cloth is made of 30% viscose rayon and 70% terylene, each composition and load
The weight ratio of body non-woven fabrics is successively are as follows: 1: solar energy bleaching agent (Serial Tinolux PSA 15) 0.3: surface-active
Agent (polysorbate) 0.05.
Preparation method including the following steps:
(1) viscose rayon is sent into shredding case and is uniformly mixed, sufficiently impregnated, obtain attached in solar energy bleaching agent solution
Have the viscose rayon of solar energy bleaching agent；
(2) viscose rayon for obtaining step (1) is sent into carding machine combing uniformly, and the viscose rayon after combing is sent into paving
Net machine, lapping reticulate the loose fabric of structure；
(3) draw forming is carried out to the loose fabric of reticular structure, obtains staple fibre fabric, the artificial fibre after counter extensioin
Dimension fabric and synthetic fiber fabric carry out compound obtaining carrier non-woven fabrics；
(4) compound obtained carrier non-woven fabrics is carried out dehydrating with roll, dewatered carrier non-woven fabrics is carried out
Drying and processing, by carrier non-woven fabrics clot after drying；
(5) by solar energy bleaching agent by rotary printing by any one of step (4) treated carrier non-woven fabrics
Side, drying, clot obtain the carrier non-woven fabrics with solar energy bleaching agent, that is, brighten piece.
Embodiment 4
Take carrier non-woven fabrics 2g, wherein fiber cloth is made of 40% viscose rayon and 60% terylene, each composition and load
The weight ratio of body non-woven fabrics is successively are as follows: 1: solar energy bleaching agent (Serial Tinolux BMC) 0.3: surfactant
(fatty glyceride, fatty acid sorbitan, polysorbate are with the combination of arbitrary proportion) 0.05.
Preparation method including the following steps:
(1) viscose rayon is sent into shredding case and is uniformly mixed, sufficiently impregnated, obtain attached in solar energy bleaching agent solution
Have the viscose rayon of solar energy bleaching agent；
(2) viscose rayon for obtaining step (1) is sent into carding machine combing uniformly, and the viscose rayon after combing is sent into paving
Net machine, lapping reticulate the loose fabric of structure；
(3) draw forming is carried out to the loose fabric of reticular structure, obtains staple fibre fabric, the artificial fibre after counter extensioin
Dimension fabric and synthetic fiber fabric carry out compound obtaining carrier non-woven fabrics；
(4) compound obtained carrier non-woven fabrics is carried out dehydrating with roll, dewatered carrier non-woven fabrics is carried out
Drying and processing, by carrier non-woven fabrics clot after drying；
(5) by solar energy bleaching agent by rotary printing by any one of step (4) treated carrier non-woven fabrics
Side, drying, clot obtain the carrier non-woven fabrics with solar energy bleaching agent, that is, brighten piece.
Whitening effect
The whitening effect for brightening piece that the present embodiment 1 manufactures is detected using the following method:
Muti-piece cotton after washing surface can bleach spot be removed, and surface is relatively white, with standard byssus meat
Eye does not see significant change.
Become with muti-piece byssus after washing in full-automatic leucometer (WSD-3C) identification embodiment 1 and the color difference of standard cotton cloth
Change, data are as follows:
The calculation formula of color difference △ E are as follows:
Its specific effect is as shown in Figure 1 and Figure 2
Content in the present invention represents desired value under this condition, but be not necessarily most just when.Obviously, the technology of this field
Various changes and modifications can be made to the invention by personnel without departing from the spirit and scope of the present invention.If in this way, the present invention
These modifications and variations within the scope of the claims of the present invention and its equivalent technology, then the present invention be also intended to encompass this
Including a little modification and variations.
Above embodiments are not limited to the technical solution of the embodiment itself, can be incorporated between embodiment new
Embodiment.The above embodiments are merely illustrative of the technical solutions of the present invention and is not intended to limit it, all without departing from the present invention
Any modification of spirit and scope or equivalent replacement, shall fall within the scope of the technical solution of the present invention.
Claims (8)
1. one kind brightens piece and preparation method thereof, it is characterised in that: by carrier non-woven fabrics, solar energy bleaching agent and surface-active
Agent composition, the carrier non-woven fabrics are compound by Artificial Fibers cloth or synthetic fiber cloth or both Artificial Fibers cloth and synthetic fiber cloth
It forms.
2. one kind according to claim 1 brightens piece and preparation method thereof, it is characterised in that: the solar energy bleaching agent with
And the quality proportioning of surfactant and carrier non-woven fabrics is respectively as follows: 0.15~0.45:0.02~0.08:1.
3. one kind according to claim 1 brightens piece and preparation method thereof, it is characterised in that: the Artificial Fibers cloth is viscous
Any one of common viscose fiber, strong viscose rayon, modified viscose fiber in glue fiber.
4. one kind according to claim 1 brightens piece and preparation method thereof, it is characterised in that: the synthetic fiber cloth is poly-
Any one of olefine fibre, polypropylene fibre, terylene.
5. one kind according to claim 1 brightens piece and preparation method thereof, it is characterised in that: the solar energy bleaching agent exists
Under the influence of light, active bleaching agent can be become during cloth drying, form the transition to react with the spot that can be bleached
Oxidation material is translated into colourless and usually water-soluble form.
6. one kind according to claim 5 brightens piece and preparation method thereof, it is characterised in that: the solar energy bleaching agent isAny one of serial Tinolux PSA 15 and Tinolux BMC or their combination.
7. one kind according to claim 1 brightens piece and preparation method thereof, it is characterised in that: the surfactant is rouge
Any one of fatty acid glyceride, fatty acid sorbitan, polysorbate or their combination.
8. a kind of preparation method for brightening piece according to claim 3, it is characterised in that: comprise the following steps that
(1) viscose rayon is uniformly mixed, is sufficiently impregnated in solar energy bleaching agent solution, obtain being attached with solar energy bleaching agent
Viscose rayon；
(2) viscose rayon for obtaining step (1) combs uniformly, and the viscose rayon lapping after combing is reticulated the loose of structure
Fabric；
(3) draw forming is carried out to the loose fabric of reticular structure, obtains staple fibre fabric, the staple fibre face after counter extensioin
Material carries out compound obtaining carrier non-woven fabrics with synthetic fiber fabric；
(4) compound obtained carrier non-woven fabrics is carried out dehydrating, drying and processing is carried out to dewatered carrier non-woven fabrics, is dried
By carrier non-woven fabrics clot after dry；
(5) surfactant solution rotary printing is dried in any side by step (4) treated carrier non-woven fabrics
Dry, clot obtains the carrier non-woven fabrics with solar energy bleaching agent, that is, brightens piece.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910736357.9A CN110358644A (en) | 2019-08-09 | 2019-08-09 | One kind brightening piece and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910736357.9A CN110358644A (en) | 2019-08-09 | 2019-08-09 | One kind brightening piece and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110358644A true CN110358644A (en) | 2019-10-22 |
Family
ID=68223620
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910736357.9A Pending CN110358644A (en) | 2019-08-09 | 2019-08-09 | One kind brightening piece and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN88100807A (en) * | 1987-02-19 | 1988-09-28 | 普罗格特-甘布尔公司 | That can improve scourability contains detergent for washing clothes and the substrate of the dirty polymkeric substance of the method that scribbles |
| US20030207630A1 (en) * | 1995-12-19 | 2003-11-06 | Newlund Laboratories, Inc. | Method of making a laundry detergent article containing detergent formulations |
| CN1749475A (en) * | 2004-11-29 | 2006-03-22 | 李春辉 | Solar light catalytic bleaching agent and its dipping and bleaching method and rolling bleaching method |
| CN203653515U (en) * | 2013-12-21 | 2014-06-18 | 陈伟钿 | Portable clothes-washing tablet |
| WO2015082251A1 (en) * | 2013-12-03 | 2015-06-11 | Little Island Patents Limited | Cleaning additives in the form of a sheet |
| EP3444328A1 (en) * | 2017-08-18 | 2019-02-20 | The Procter & Gamble Company | Cleaning agent |
-
2019
- 2019-08-09 CN CN201910736357.9A patent/CN110358644A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN88100807A (en) * | 1987-02-19 | 1988-09-28 | 普罗格特-甘布尔公司 | That can improve scourability contains detergent for washing clothes and the substrate of the dirty polymkeric substance of the method that scribbles |
| US20030207630A1 (en) * | 1995-12-19 | 2003-11-06 | Newlund Laboratories, Inc. | Method of making a laundry detergent article containing detergent formulations |
| CN1749475A (en) * | 2004-11-29 | 2006-03-22 | 李春辉 | Solar light catalytic bleaching agent and its dipping and bleaching method and rolling bleaching method |
| WO2015082251A1 (en) * | 2013-12-03 | 2015-06-11 | Little Island Patents Limited | Cleaning additives in the form of a sheet |
| CN203653515U (en) * | 2013-12-21 | 2014-06-18 | 陈伟钿 | Portable clothes-washing tablet |
| EP3444328A1 (en) * | 2017-08-18 | 2019-02-20 | The Procter & Gamble Company | Cleaning agent |
Non-Patent Citations (2)
| Title |
|---|
| 刘云等: "阳光因子的洗涤漂白性能研究", 《精细与专业化学》 * |
| 张贵民: "环保型光漂白剂在洗衣粉中的应用", 《中国洗涤用品工业》 * |
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Application publication date: 20191022 |