CN106351006A - Fiber cloth with color protection and adsorption functions as well as preparation method and application thereof - Google Patents
Fiber cloth with color protection and adsorption functions as well as preparation method and application thereof Download PDFInfo
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- CN106351006A CN106351006A CN201610714558.5A CN201610714558A CN106351006A CN 106351006 A CN106351006 A CN 106351006A CN 201610714558 A CN201610714558 A CN 201610714558A CN 106351006 A CN106351006 A CN 106351006A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/48—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation
- D04H1/485—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation in combination with weld-bonding
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/74—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being orientated, e.g. in parallel (anisotropic fleeces)
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/61—Polyamines polyimines
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- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
- D06M2101/08—Esters or ethers of cellulose
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Abstract
The invention discloses fiber cloth with color protection and adsorption functions as well as a preparation method and application thereof. The preparation method comprises: weighing a certain amount of water-soluble high molecular polymer and dissolving into de-ionized water to obtain a high molecular polymer water solution; adding a pH (Potential of Hydrogen) regulator, a surfactant and an auxiliary agent into the high molecular polymer water solution; stirring until the components are completely dissolved; putting viscose fibers, polyester fibers and functional fibers into a water solution after stirring and dissolving; reacting at 50 DEG C to 80 DEG C for 15 minutes to 60 minutes; carrying out filtering and drying treatment on the reacted solution to obtain cross-color-proof fibers; laying the dried cross-color-proof fibers to form a net; furthermore, fixing the net into cloth; carrying out hot pressing operation to form the fiber cloth with the color protection and adsorption functions. The fiber cloth prepared by the preparation method provided by the invention can strongly adsorb an active dye, dust scale and mites in a water solution; a dark color caused by the fact that colorful ions and stains are mixed is effectively prevented, and the color of clothes keeps more bright and lasting.
Description
Technical field
The present invention relates to daily use chemicals washing product technical field and in particular to a kind of fiber cloth with color fixative and adsorption function and
Preparation Method And The Use.
Background technology
In daily Household laundry processes, often all medicated clothings to be washed are placed in washing machine together and are washed
Wash, if but when washing together with dark medicated clothing and light color medicated clothing, often occur that clothes fades and lead to light medicated clothing showing by colour contamination
As.In order to solve this problem, people generally select medicated clothing Wash Separately, or carry out some pre- places before laundry premise
Reason, is such as soaked with saline or Alumen, but so not only water wasting expense is electric, also makes the step of laundry operations become very loaded down with trivial details, no
The efficient easily life requirement of people can be met.
Although there being the detergent of some anti-colour contamination in prior art, it is mainly addition phosphoric acid in traditional detergent
Salt component, but phosphate substances easily cause environment and pollution, also have certain infringement to staff, are therefore highly desirable to develop
Go out a kind of environmental protection easily anti-colour contamination material.
Content of the invention
For this reason, the present invention provides a kind of fiber cloth with color fixative and adsorption function and its production and use, with power
The problem existing above certainly or is at least alleviated in diagram.
According to an aspect of the present invention, provide a kind of preparation method of the fiber cloth with color fixative and adsorption function, bag
Include following steps: weigh a certain amount of high molecular weight water soluble polymer and be dissolved in deionized water, obtaining concentration is 10g/l-30g/l
High molecular polymer aqueous solution；Add ph regulator, surfactant and auxiliary agent in described high molecular polymer aqueous solution,
Stir to being completely dissolved；Viscose rayon, polyster fibre and functional fiber are put in the aqueous solution after described stirring and dissolving, plus
Heat, to 50 DEG C～80 DEG C, is reacted 15 minutes～60 minutes；Described reacted solution is filtered and dried, is had
There is the anti-colour contamination fiber of color fixative and adsorption function；Described dried anti-colour contamination fiber lay down is set as net, and then fixed network becomes cloth, and
Carry out hot press operation, to have the fiber cloth of color fixative and adsorption function described in being formed.
Alternatively, in preparation in accordance with the present invention, step into the net for anti-colour contamination fleece-laying is also included: in paving
Be set as net before in described anti-colour contamination fiber add softener, wherein, described softener include silica gel, ceramide, Oleum Cocois,
In polyquaternary ammonium salt regulator, ceramide -1, Merquat 280, positive polyquaternary ammonium salt -19, gemini cationic softener extremely
Few one kind.
Alternatively, in preparation in accordance with the present invention, cloth technique is become to be suitable for use with dry carding, cross lapping, pin
At least one in thorn and spun lacing.
Alternatively, in preparation in accordance with the present invention, high molecular weight water soluble polymer includes following at least one: fine
Tie up plain ether, polyvinyl pyrrolidone, polyvinylpyridine glycine betaine, polyvinyl imidazol, polyvinyl ammoxidation pyridine, gather
Allylcarbinol, polyvinyl, peroxidase and cationic modified starch.
Alternatively, in preparation in accordance with the present invention, water-soluble cellulose ether includes methylcellulose, hydroxypropyl first
At least one in base cellulose, hydroxyethyl cellulose, hydroxyethylmethyl-cellulose, hydroxypropyl cellulose, hydroxybutyl cellulose.
Alternatively, in preparation in accordance with the present invention, functional fiber includes thermoplastic fibre, anti-bacterial fibre, resists
At least one in electrostatic fibre or environment-protection fiber；High molecular polymer is 1:1～1:8 with the mass ratio of described viscose rayon.
Alternatively, in preparation in accordance with the present invention, ph regulator be sodium hydroxide, potassium hydroxide, potassamide or
Sodamide., the ph making the anti-colour contamination high polymer aqueous solution after regulation is 11-13.
Alternatively, in preparation in accordance with the present invention, auxiliary agent includes antibacterial, preservative and colour fixative, lives in surface
Property agent include anion surfactant and, nonionic surfactant；Wherein, antibacterial includes triclocarban, two between chlorine
At least one in cresols, o-phenyl phenol and clove oil；Preservative includes potassium sorbate, sodium benzoate, isothiazoline
At least one in ketone, P-hydroxybenzoic acid sodium, dimethyl hydantoin；Colour fixative is, in nitrite and perborate
At least one.Anion surfactant include sodium alkyl benzene sulfonate, alkenyl sulphonate, in alkyl sulfate and laureth
At least one of sodium sulfovinate.Nonionic surfactant includes ethoxylated fat race alkylamine, Decyl Polyglucoside, cocoyl Portugal
At least one in glucosides, fatty alcohol-polyoxyethylene ether, glutamic acid lauryl alcohol ester.
According to another aspect of the present invention, provide a kind of fiber cloth with color fixative and adsorption function, by as above institute
The preparation method stated is obtained.
According to another aspect of the present invention, provide a kind of fiber cloth with color fixative and adsorption function be used for adsorbing water-soluble
Reactive dye, dust and dirt, nuisance, acarid and fluorescent whitening agent etc. in liquid, and prevent clothes color union dyeing colour contamination, keep medicated clothing beautiful
The purposes of beautiful color.
Technology according to the present invention scheme, can prevent the principle of colour contamination generation using high polymer, will viscose rayon, terylene fibre
Peacekeeping functional fiber is immersed in the alkaline aqueous solution of high molecular polymer, obtains the fiber with anti-colour contamination effect.Afterwards,
This anti-colour contamination fiber lapping is become cloth, you can obtain the fiber cloth with color fixative and adsorption function.The fibre being obtained according to the present invention
Various reactive dye ions in dimension cloth energy strong adsorption aqueous solution and dust and dirt, nuisance, acarid and fluorescent whitening agent etc., thus
Prevent the mutual string dye of the medicated clothing and light medicated clothing in laundry processes, easily fading.In daily laundering process, should
Fiber cloth is put into and is shuffled in medicated clothing, you can prevent clothes color union dyeing colour contamination, protects the beautiful color of medicated clothing.
Brief description
In order to realize above-mentioned and related purpose, herein in conjunction with explained below and accompanying drawing, some illustrative sides to be described
Face, these aspects indicate can be to put into practice the various modes of principles disclosed herein, and all aspects and its equivalent aspect
It is intended to fall under in the range of theme required for protection.By detailed description below be read in conjunction with the accompanying, the disclosure above-mentioned
And other purpose, feature and advantage will be apparent from.Throughout the disclosure, identical reference generally refers to identical
Part or element.
Fig. 1 shows the preparation method of the fiber cloth with color fixative and adsorption function according to an embodiment of the invention
100 flow chart；
Fig. 2 shows the schematic diagram of the fiber cloth with color fixative and adsorption function according to an embodiment of the invention.
Specific embodiment
The exemplary embodiment of the disclosure is described in more detail below.Although describe hereinafter the example of the disclosure
Property embodiment is it being understood, however, that may be realized in various forms the disclosure and should not being limited by embodiments set forth here.
On the contrary, these embodiments are provided to be able to be best understood from the disclosure, and can be complete by the scope of the present disclosure
Convey to those skilled in the art.
The invention discloses a kind of fiber cloth with color fixative and adsorption function and its production and use.Fig. 1 illustrates
The flow chart of the preparation method 100 of the fiber cloth with color fixative and adsorption function according to an embodiment of the invention, such as Fig. 1
Shown, the method starts from step s110.
Step s110 is dissolved in deionized water it is necessary first to weigh a certain amount of high molecular weight water soluble polymer, obtains
To the high molecular polymer aqueous solution for 10g/l-30g/l for the concentration.Wherein, high molecular weight water soluble polymer can choose cellulose
Ether, polyvinyl pyrrolidone, polyvinylpyridine glycine betaine, polyvinyl imidazol, polyvinyl ammoxidation pyridine, polyethylene
Base ethanol, polyvinyl, peroxidase or cationic modified starch.
Cellulose ether is the macromolecular compound with ether structure being made up of cellulose.Each Portugal in cellulose macromolecule
Grape glycosyl ring contains three hydroxyls, and the primary hydroxyl on the 6th carbon atom, the secondary hydroxyl on second and third carbon atom, in hydroxyl
Hydrogen is generated cellulose and clicks here by alkyl replacement and adds caption ether derivative.It is hydroxyl in cellulosic polymer
The product that hydrogen is replaced by alkyl.Cellulose is a kind of polyhydroxy macromolecular compound both not dissolved and not melted.Cellulose
Then water, dilute alkaline soln and organic solvent can be dissolved in after etherified, and there is thermoplasticity.Water-soluble cellulose ether in the present invention,
Methylcellulose, hydroxyethylmethyl-cellulose, carboxymethyl cellulose, ethyl cellulose, benzylcellulose, ethoxy can be chosen
Cellulose, hydroxypropyl methyl cellulose, cyanethyl cellulose, benzyl cyanethyl cellulose, carboxymethyl hydroxyethyl cellulose or benzene
Base cellulose etc. is it is also possible to choose the mixture of wherein two or more.
Subsequently, in step s120, high molecular polymer aqueous solution adds ph regulator, surfactant and helps
Agent, stirs to being completely dissolved.
Wherein, ph regulator can select the arbitrarily alkaline matter such as sodium hydroxide, potassium hydroxide, potassamide or Sodamide.,
The invention is not limited in this regard, as long as can make the ph of the high molecular polymer aqueous solution after regulation be 11-13.
Surfactant is described as " industrial monosodium glutamate ", refers to there is fixing hydrophilic lipophilic group, in the surface energy of solution
Align, and the material that surface tension is remarkably decreased can be made.It is a big class organic compound, the great characteristic of property, application
Extremely flexibly, extensively, there are very big practical value and theory significance.Surfactant due to have moistening or anti-stick, emulsifying or
The series of physical chemical action such as breakdown of emulsion, foaming or froth breaking and solubilising, dispersion, washing, anti-corrosion, antistatic and accordingly reality
Application, becomes that a class is versatile and flexible, broad-spectrum fine chemical product.Surfactant is except in daily life as washing
Wash agent, other application almost can cover all of field of fine chemical.In formula, the Main Function of surfactant:
It is the emulsifying capacity improving between component, so that them can be more efficiently mixed each other: two is control system in foaming process
There is suitable surface tension, produce good bubble network structure, therefore, also referred to as foam stabiliser.
Surfactant in the present invention mainly includes anion surfactant and nonionic surfactant, wherein,
Anion surfactant can choose sodium alkyl benzene sulfonate, alkenyl sulphonate, in alkyl sulfate or laureth sulphuric acid
Ester sodium etc., or select the mixture of wherein two or more.Nonionic surfactant can choose ethoxylated fat race alkane
Base amine, Decyl Polyglucoside, Coco-Glucoside, fatty alcohol-polyoxyethylene ether or glutamic acid lauryl alcohol ester etc., or select two of which
Or multiple mixture.Certainly, surfactant can also choose other common existing materials, and the present invention does not limit to this
System.
Auxiliary agent includes antibacterial, preservative and colour fixative.Wherein, antibacterial is exactly the material of energy bacteria growing inhibiting.Suppression
Microbial inoculum possibly cannot kill antibacterial, but it can suppress the growth of antibacterial, and prevention bacteria breed is excessive, health risk.All of
Quintessence oil, more or less has the ability of bacteria growing inhibiting.Some quintessence oils only suppress the growth of some special pathogenic bacterias, and some are smart
Oil, the species of suppression pathogenic bacteria is a lot.Meanwhile, very small amount of quintessence oil just can produce good fungistatic effect, such as Flos Caryophylli, smoke clothing
Grass, Herba Rosmarini Officinalis, the quintessence oil such as Salvia japonica Thunb. and Herba thymi vulgariss, antibacterial effect is all fine.Specifically, the antibacterial in the present invention can select
Select triclocarban, parachlorometaxylenol, o-phenyl phenol and clove oil etc., or the mixing selecting wherein two or more
Thing.
Preservative (preservative) refers to naturally occurring or synthetic chemical composition, for add food, medicine, pigment,
Biological sample etc., with the corruption postponing growth of microorganism or chemical change causes.The preservative of the present invention can be chosen any one
Plant or multiple existing preservative ingredient, such as nitrite, potassium sorbate, sodium benzoate, dehydroactic acid and sodium salt, nipalgin
Esters (i.e. parabenses), sodium diacetate, sodium lactate, isothiazolone, P-hydroxybenzoic acid sodium or dimethyl second
In interior uride.
Colour fixative be can colour fixative and meat product color and luster non-pigmented material, be also colour former.The color development of China's regulation
Agent has sodium nitrate (potassium), 4 kinds of sodium nitrite (potassium).In fruit juice, the colour fixative of application has ascorbic acid, arabo-ascorbic acid, Fructus Citri Limoniae
Acid.Sodium sulfite, sodium sulfite is used in drinks production.In food processing process, add appropriate chemical substance, with
In food, some composition effects, make product assume good color and luster, this kind of material is referred to as colour former or photoghraphic coupler.Color development can be promoted
Material be referred to as color auxiliary.In meat is pickled, the most frequently used colour former is in nitrate, nitrite and perborate, sends out
Color auxiliary agent is l- ascorbic acid (i.e. vc), l- sodium ascorbate and nicotiamide (i.e. vpp) etc..Colour fixative in the present invention can be adopted
With any one or more composition above-mentioned, this is not restricted.
Subsequently, in step s130, viscose rayon, polyster fibre and functional fiber are put into after described stirring and dissolving
In aqueous solution, it is heated to 50 DEG C～80 DEG C, react 15 minutes～60 minutes.Wherein, viscose rayon refers to from timber and plant ligusticumic
The alpha-cellulose extracting in the cellulosic materials such as bar, or with cotton linter as raw material, processed one-tenth spinning solution, then through wet spinning
The staple fibre made.Viscose rayon belongs to regenerated celulose fibre.It is with native cellulose as raw material, through alkalization, aging, sulphur
The operations such as change make soluble cellulose sulphonic acid ester, are re-dissolved in sig water and make viscose glue, make through wet spinning.Using difference
Raw material and spinning technique, common viscose fiber, koplon and high tenacity staple fibre etc. can be respectively obtained.
Common viscose fiber has general physical and mechanical propertiess and chemical property, divides cotton, wool type and long wire type again, is commonly called as artificial
Cotton, man-made hair and artificial silk.Koplon has the higher degree of polymerization, strength and wet modulus.High-tenacity viscose glue is fine
Dimension has higher strength and fatigue performance.
Terylene is the important kind of one of synthetic fibers, is the trade name of China's polyester fiber.It is with essence neighbour's benzene
Through esterification or ester exchange and polycondensation reaction, prepared becoming is fine high for raw material for dioctyl phthalate or dimethyl terephthalate (DMT) and ethylene glycol
Polymers polyethylene terephthalate, the fiber made through spinning and post processing.
Functional fiber can select as any one in thermal shrinkage fiber, anti-bacterial fibre, antistatic fibre or environment-protection fiber etc.
Plant or the mixture of two or more.Wherein, thermal shrinkage fiber's such as polypropylene section fibre etc.；After adding this fiber,
The intensity of the fiber cloth finally obtaining is improved significantly.Anti-bacterial fibre is made by mixing antibacterial in spinning liquid, with
The inorganic antibacterial fiber that nanoscale contains silver zeolite is the most famous, and it has broad-spectrum antiseptic, heat stability is good, function is lasting, safety can
The features such as lean on, will not develop immunity to drugs；After adding this fiber, the disinfecting mite-removing ability of the fiber cloth finally obtaining substantially increases
By force.Antistatic fibre, by the modification to synthetic fibers, adds antistatic additive in polymeric inner or introduces Third monomer
Fiber is made to have antistatic effect in itself；After adding this fiber, the antistatic effect of the fiber cloth finally obtaining is notable.Environmental protection
Fiber can select as natural color cotton and Pilus Caprae seu Oviss, the rabbit hair；Or bast-fibre, such as Caulis et Folium Lini, Boehmeria, Corchorus olitorius L. etc., have natural
Antibacterial, bacteriostasis property, have certain health care, uvioresistant and electrostatic-proof function simultaneously, are that natural environmental protection is fine
Dimension.
After viscose rayon, polyster fibre and functional fiber are put in solution, high molecular polymer can be at these
The adsorption group that the Surface Creation of fiber firmly uniformly adheres to.Wherein, high molecular polymer and the mass ratio of viscose rayon are 1:1
～1:8.It should be appreciated that the addition sequence of this several fiber of the present invention does not limit.
Subsequently, in step s140, reacted solution is filtered and dried, obtained with color fixative and absorption
The anti-colour contamination fiber of function.Wherein, being dried both can be with normal temperature drying it is also possible to put suitable heat drying in an oven.
Subsequently, in step s150, dried anti-colour contamination fiber lay down is set as net, and then fixed network becomes cloth, and carry out heat
Press operation, to have the fiber cloth of color fixative and adsorption function described in being formed, prepared fiber cloth is as shown in Figure 2.By this side
The fiber cloth that method obtains is a kind of non-woven fabrics, also known as adhesive-bonded fabric, is to be made up of fiber that orient or random, is ring of new generation
Protect material, there is protection against the tide, ventilative, pliable and tough, light weight, not combustion-supporting, easy decomposition, nontoxic nonirritant, rich color, price low
Honest and clean, recyclable the features such as.Common adhesive-bonded fabric is through batch mixing, shredding, comb using various natural fibers or staple fibre
Reason, lapping, then set, arrangement and be obtained.
Wherein, in becoming cloth operation, hot pressing can make thermal shrinkage fiber solidify, to improve the intensity of fiber cloth.Cheng Bugong
Skill can be with any conventional techniques such as dry carding, cross lapping, the direct Cheng Bufa of spray webbing, acupuncture and spun lacing, and the present invention is to this
It is not restricted.
In addition, carry out before being laid to net can also to described anti-colour contamination fiber in add softener, to improve this fibre
The lubricity of dimension, carding operation when conveniently being weaved cotton cloth, the fiber cloth surface irregularity obtaining after preventing fiber knotting.Its tool
Body dosage is not restricted, as long as uniformly can coat on the surface of anti-colour contamination fiber.Softener can select silica gel, nerve
Amide, Oleum Cocois, polyquaternary ammonium salt regulator, ceramide -1, Merquat 280, positive polyquaternary ammonium salt -19 or gemini cation
In softening agent, or the mixture selecting wherein two or more.
Experiment effect 1
Choose in the cylinder of medicated clothing input washing machine that some easily fade, and put into the detergent with fluorescent whitening agent,
In accordance with the washing instructions on laundry care label.Choose simultaneously and put into the fiber cloth of piece preparation in accordance with the present invention preparation
Washing machine drum, and carry out general washing step.After washing finishes, take out this fiber cloth, observe the face of medicated clothing and fiber cloth
Color state.
It can be seen that those colors taken off firmly have been adsorbed on this fibre plate, washed medicated clothing does not have color to mix completely
Dye colour contamination phenomenon, medicated clothing also keeps beautiful color.In experimentation, general medicated clothing does not just go here and there dye completely using a piece of fiber cloth
Color phenomenon, colour darkness and clothing amount according to clothes can suitably increase consumption.After micro- sem observation, in medicated clothing before and after laundry
Acarid also significantly reduce, in fiber cloth in addition to having dyestuff, be also attached with dust and dirt and some other harmful substance it is seen that its
Strong adsorption acts on.Medicated clothing distributes novel aroma, assists in removing the unpleasant abnormal flavour such as fetid sweat.In addition, using tool detection cleaning mixture
In fluorescent whitening agent, find add fiber cloth after, the fluorescent whitening agent in solution also significantly reduces.Detection fibers cloth finds it
Also there is fluorescence phenomenon it is seen that this fiber cloth also fluorescent whitening agent in adsorbable solution.
Experiment effect 2
Configure the special red dye solution of medicated clothing of same concentration in two living large beakers, respectively put one piece respectively
Pure cotton cloth, one of beaker adds the fiber cloth with color fixative and adsorption function according to the present invention.Stir one with Glass rod
After fixing time, take out pure cotton cloth and fiber cloth, observe the color of solution and cloth.Now, add the solution bleach of fiber cloth saturating
Bright, pure cotton cloth also keeps original color, and fiber cloth absorbing dye becomes red；The solution of cloth still keeps red without added fiber
Color, pure cotton cloth is also incarnadined.
The fiber cloth that preparation in accordance with the present invention is obtained, has color fixative in efficacy of adsorption, in daily washing process,
Only appropriate fiber cloth need to be added, you can the various reactive dye ions in strong adsorption aqueous solution and dust and dirt, nuisance, acarid
With fluorescent whitening agent etc., thus preventing the mutual string dye of the medicated clothing and light medicated clothing in laundry processes, easily fading.Daily
In laundering process, this fiber cloth is put into and shuffles in medicated clothing, you can prevent clothes color union dyeing colour contamination, protection medicated clothing is beautiful
Beautiful color.For a user, different colours need not be cleaned separately, depth medicated clothing can be washed together, either light tone, dark color are gone back
White, only need to add a piece of can perfect absorbing dye, saving time in water and electric saving, drastically increases Consumer's Experience.And,
Fiber cloth in the present invention contains antibacterial, rich in superpower sterilization factors, suppresses the acarid in medicated clothing to grow, the skin of protection user
Skin health.
In description mentioned herein, illustrate a large amount of details.It is to be appreciated, however, that the enforcement of the present invention
Example can be put into practice in the case of not having these details.In some instances, known method, knot are not been shown in detail
Structure and technology, so as not to obscure the understanding of this description.
Similarly it will be appreciated that in order to simplify the disclosure and help understand one or more of each inventive aspect,
Above in the description to the exemplary embodiment of the present invention, each feature of the present invention is grouped together into single embodiment sometimes
Or in descriptions thereof.However, the method for the disclosure should be construed to reflect an intention that i.e. required for protection
Invention requires than the feature more features being expressly recited in each claim.More precisely, as following right will
As asking book to be reflected, inventive aspect is all features less than single embodiment disclosed above.Therefore, it then follows concrete
Claims of embodiment are thus expressly incorporated in this specific embodiment, and wherein each claim itself is as this
The separate embodiments of invention.
As used in this, unless specifically stated so, come using ordinal number " first ", " second ", " the 3rd " etc.
Description plain objects are merely representative of the different instances being related to similar object, and are not intended to imply that the object being so described must
Must have the time upper, spatially, sequence aspect or given order in any other manner.
Although the present invention is described according to the embodiment of limited quantity, benefit from above description, the art
Interior it is clear for the skilled person that it can be envisaged that other embodiments in the scope of the present invention thus describing.Additionally, it should be noted that
Language used in this specification primarily to the purpose of readable and teaching and select, rather than in order to explain or limit
Determine subject of the present invention and select.Therefore, in the case of without departing from the scope of the appended claims and spirit, for this
For the those of ordinary skill of technical field, many modifications and changes will be apparent from.For the scope of the present invention, to this
It is illustrative and not restrictive for inventing done disclosure, and it is intended that the scope of the present invention be defined by the claims appended hereto.
Claims (10)
1. a kind of preparation method of the fiber cloth with color fixative and adsorption function, comprises the following steps:
Weigh a certain amount of high molecular weight water soluble polymer to be dissolved in deionized water, obtain the high score that concentration is 10g/l-30g/l
Sub- aqueous solutions of polymers；
Add ph regulator, surfactant and auxiliary agent in described high molecular polymer aqueous solution, stir to being completely dissolved；
Viscose rayon, polyster fibre and functional fiber are put in the aqueous solution after described stirring and dissolving, be heated to 50 DEG C～
80 DEG C, react 15 minutes～60 minutes；
Described reacted solution is filtered and dried, is obtained the anti-colour contamination fiber with color fixative and adsorption function；
Described dried anti-colour contamination fiber lay down is set as net, and then fixed network becomes cloth, and carry out hot press operation, to form described tool
There is the fiber cloth of color fixative and adsorption function.
2. step into the net for anti-colour contamination fleece-laying described is also included by the preparation method of fiber cloth as claimed in claim 1:
Be laid to net before to described anti-colour contamination fiber in add softener, wherein, described softener include silica gel, nerve acyl
Amine, Oleum Cocois, polyquaternary ammonium salt regulator, ceramide -1, Merquat 280, positive polyquaternary ammonium salt -19, gemini cation are soft
At least one in soft dose.
3. the preparation method of fiber cloth as claimed in claim 1, wherein said one-tenth cloth technique is suitable for use with dry carding, intersection
At least one in lapping, acupuncture and spun lacing.
4. the preparation method of fiber cloth as claimed in claim 1, wherein said high molecular weight water soluble polymer include with down to
Few one kind:
Cellulose ether, polyvinyl pyrrolidone, polyvinylpyridine glycine betaine, polyvinyl imidazol, polyvinyl ammoxidation
Pyridine, polyvinyl ethanol, polyvinyl, peroxidase and cationic modified starch.
5. the preparation method of the fiber cloth as described in claim 1 or 4, wherein said water-soluble cellulose ether includes Methyl cellulose
In element, hydroxypropyl methyl cellulose, hydroxyethyl cellulose, hydroxyethylmethyl-cellulose, hydroxypropyl cellulose, hydroxybutyl cellulose
At least one.
6. the preparation method of fiber cloth as claimed in claim 1, wherein, described functional fiber includes thermoplastic fibre, resists
At least one in bacterium fiber, antistatic fibre or environment-protection fiber；Described high molecular polymer and the quality of described viscose rayon
Than for 1:1～1:8.
7. the preparation method of fiber cloth as claimed in claim 1, wherein said ph regulator be sodium hydroxide, potassium hydroxide,
Potassamide or Sodamide., the ph making the anti-colour contamination high polymer aqueous solution after regulation is 11-13.
8. the preparation method of fiber cloth as claimed in claim 1, described auxiliary agent includes antibacterial, preservative and colour fixative, institute
State surfactant and include anion surfactant and nonionic surfactant；
Wherein, described antibacterial includes in triclocarban, parachlorometaxylenol, o-phenyl phenol and clove oil at least one
Kind；
Described preservative includes potassium sorbate, sodium benzoate, isothiazolone, P-hydroxybenzoic acid sodium, dimethyl hydantoin
In at least one；
Described colour fixative is at least one in nitrate, nitrite and perborate；
Described anion surfactant include sodium alkyl benzene sulfonate, alkenyl sulphonate, in alkyl sulfate and laureth
At least one of sodium sulfovinate；
Described nonionic surfactant includes ethoxylated fat race alkylamine, Decyl Polyglucoside, Coco-Glucoside, fatty alcohol
At least one in polyoxyethylene ether, glutamic acid lauryl alcohol ester.
9. a kind of fiber cloth with color fixative and adsorption function, the preparation method any one of claim 1-8 is obtained.
10. there is color fixative as claimed in claim 9 and the fiber cloth of adsorption function is used for reactive dye, dirt in adsorption aqueous solution
Dirt, nuisance, acarid and fluorescent whitening agent, and prevent medicated clothing color union dyeing colour contamination, the purposes of the holding beautiful color of medicated clothing.
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| CN201610714558.5A CN106351006A (en) | 2016-08-24 | 2016-08-24 | Fiber cloth with color protection and adsorption functions as well as preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107604414A (en) * | 2017-08-22 | 2018-01-19 | 珠海市奥美伦精细化工有限公司 | A kind of aluminium and aluminium alloy anode oxide high temperature is without nickel sealer |
| CN107780209A (en) * | 2017-11-01 | 2018-03-09 | 山东国丰君达化工科技股份有限公司 | One kind inhales color fibre cloth production process |
| CN110055745A (en) * | 2019-05-14 | 2019-07-26 | 广东柏堡龙股份有限公司 | A kind of preparation method of functional fibre |
| CN110485180A (en) * | 2019-08-09 | 2019-11-22 | 山西大学 | One kind is anti-to dye cloth and preparation method thereof |
| CN111020069A (en) * | 2019-12-09 | 2020-04-17 | 沈阳翰皇日用品有限公司 | Suede leather care reducing agent |
| CN113417142A (en) * | 2021-06-22 | 2021-09-21 | 杭州萧山凤凰纺织有限公司 | Antibacterial non-woven fabric and preparation method thereof |
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| CN103938298A (en) * | 2013-01-18 | 2014-07-23 | 孙剑锋 | Preparation method of dye-absorption fibers and preparation method of dye-absorption non-woven cloth |
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| CN103938298A (en) * | 2013-01-18 | 2014-07-23 | 孙剑锋 | Preparation method of dye-absorption fibers and preparation method of dye-absorption non-woven cloth |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107604414A (en) * | 2017-08-22 | 2018-01-19 | 珠海市奥美伦精细化工有限公司 | A kind of aluminium and aluminium alloy anode oxide high temperature is without nickel sealer |
| CN107780209A (en) * | 2017-11-01 | 2018-03-09 | 山东国丰君达化工科技股份有限公司 | One kind inhales color fibre cloth production process |
| CN110055745A (en) * | 2019-05-14 | 2019-07-26 | 广东柏堡龙股份有限公司 | A kind of preparation method of functional fibre |
| CN110055745B (en) * | 2019-05-14 | 2021-11-05 | 广东柏堡龙股份有限公司 | Preparation method of functional fiber |
| CN110485180A (en) * | 2019-08-09 | 2019-11-22 | 山西大学 | One kind is anti-to dye cloth and preparation method thereof |
| CN111020069A (en) * | 2019-12-09 | 2020-04-17 | 沈阳翰皇日用品有限公司 | Suede leather care reducing agent |
| CN113417142A (en) * | 2021-06-22 | 2021-09-21 | 杭州萧山凤凰纺织有限公司 | Antibacterial non-woven fabric and preparation method thereof |
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