CN110358544A - A kind of preparation method of soil tailored version environmental protection auxiliary agent - Google Patents
A kind of preparation method of soil tailored version environmental protection auxiliary agent Download PDFInfo
- Publication number
- CN110358544A CN110358544A CN201910681148.9A CN201910681148A CN110358544A CN 110358544 A CN110358544 A CN 110358544A CN 201910681148 A CN201910681148 A CN 201910681148A CN 110358544 A CN110358544 A CN 110358544A
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- CN
- China
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- parts
- soil
- auxiliary agent
- environmental protection
- rhamnolipid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000002689 soil Substances 0.000 title claims abstract description 24
- 239000012752 auxiliary agent Substances 0.000 title claims abstract description 16
- 230000007613 environmental effect Effects 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 24
- FCBUKWWQSZQDDI-UHFFFAOYSA-N rhamnolipid Chemical compound CCCCCCCC(CC(O)=O)OC(=O)CC(CCCCCCC)OC1OC(C)C(O)C(O)C1OC1C(O)C(O)C(O)C(C)O1 FCBUKWWQSZQDDI-UHFFFAOYSA-N 0.000 claims abstract description 14
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 12
- 235000011187 glycerol Nutrition 0.000 claims abstract description 12
- 229930182470 glycoside Natural products 0.000 claims abstract description 12
- 235000021419 vinegar Nutrition 0.000 claims abstract description 12
- 239000000052 vinegar Substances 0.000 claims abstract description 12
- 239000002023 wood Substances 0.000 claims abstract description 12
- -1 alkyl glycosides Chemical class 0.000 claims abstract description 11
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 11
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 11
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 7
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 7
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229940068918 polyethylene glycol 400 Drugs 0.000 claims description 4
- 229960005150 glycerol Drugs 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 239000000575 pesticide Substances 0.000 abstract description 7
- 230000006872 improvement Effects 0.000 abstract description 4
- 238000003756 stirring Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 5
- 201000010099 disease Diseases 0.000 description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 4
- 241000238631 Hexapoda Species 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 239000003337 fertilizer Substances 0.000 description 3
- 150000002338 glycosides Chemical class 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- HVCOBJNICQPDBP-UHFFFAOYSA-N 3-[3-[3,5-dihydroxy-6-methyl-4-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxyoxan-2-yl]oxydecanoyloxy]decanoic acid;hydrate Chemical compound O.OC1C(OC(CC(=O)OC(CCCCCCC)CC(O)=O)CCCCCCC)OC(C)C(O)C1OC1C(O)C(O)C(O)C(C)O1 HVCOBJNICQPDBP-UHFFFAOYSA-N 0.000 description 1
- 208000019901 Anxiety disease Diseases 0.000 description 1
- 229930186217 Glycolipid Natural products 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 230000036506 anxiety Effects 0.000 description 1
- 239000003876 biosurfactant Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000003900 soil pollution Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/14—Soil-conditioning materials or soil-stabilising materials containing organic compounds only
- C09K17/18—Prepolymers; Macromolecular compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Zoology (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Soil Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A kind of soil tailored version environmental protection auxiliary agent includes the following steps progress, by volume parts: 30-60 parts of rhamnolipid, 1-60 parts of fatty alcohol polyoxyethylene ether, 1-50 parts of wood vinegar, 1-60 parts of sodium lauroyl sarcosine, 1-60 parts of glycerine, 1-60 parts of polyethylene glycol 400,1-10 parts of alkyl glycosides are uniformly mixed.The present invention can significantly improve pesticide efficacy, improvement soil.
Description
Technical field
The present invention relates to agriculturally applied technical fields, and it is particularly applicable to multiple kinds of crops and the underground disease pests of landscape flower
Evil prevention and treatment and soil conditioning, improvement.
Background technique
Along with " environment protective plant protecting " theory in global wide-scale distribution, more and more countries are all reducing the residual permission maximum of agriculture
Amount, this trend future can also constantly continue.China has begun the implementation of " chemical fertilizer zero growth rate, pesticide reduction " action, China
More efficient, more environmentally friendly, safer plant protection technology is just urgently called, to reduce agriculture chemical usage amount, promotes peasant economy
Income.
And farmer how to be allowed " with less pesticide, to there is better effect, this is exactly the dance that agricultural agent is put expertise to good use
Platform.As the lasting depth of National agricultural strategy and policy promotes, auxiliary agent, especially tank-mix adjuvants start before moving towards platform, move towards
The center of industry trend.The especially new change of planting patterns promotes pesticide application technology, application equipment, insecticide-applying way, towards essence
Standard, low amounts develop target, variable, automation direction, and the research of the dosage form, preparation or the auxiliary agent that match therewith then becomes China
The important directions of pesticidal preparations development.But domestic tank-mix adjuvants at present, such as mineral oil, vegetable oil, organosilicon auxiliary agent, plant
Object essential oil auxiliary agent is mainly used in the page and sprays, and due to the limitation of R&D direction and raw material, the above auxiliary agent is to underground disease pest
Harmful synergy is very faint, does not propose the function of improvement soil more much.The present invention combines domestic auxiliary agent underground application effect at present
Fruit is faint, and domestic since soil supplies anxiety, cannot lie fallow, soil hardening, acidification, alkalization, salinization, organic substance seriously lack
Phenomena such as weary, has carried out comprehensive consideration, and having invented one kind has significant soil conditioning function, apparent to underground pest and disease damage synergy
Agricultural and environment-protecting auxiliary agent.
Summary of the invention
The object of the present invention is to provide a kind of preparation methods of soil tailored version environmental protection auxiliary agent.
Raw material including following volumes part: 30-60 parts of rhamnolipid, 1-60 parts of fatty alcohol polyoxyethylene ether, wood vinegar 1-
50 parts, 1-60 parts of sodium lauroyl sarcosine, 1-60 parts of glycerine, 1-60 parts of polyethylene glycol 400,1-10 parts of alkyl glycosides.
The preparation method of the soil tailored version environmental protection auxiliary agent, the specific steps are as follows: by rhamnolipid, fatty alcohol polyoxy second
Alkene ether, wood vinegar, sodium lauroyl sarcosine, glycerine, polyethylene glycol 400, alkyl glycosides are uniformly mixed.
Technical solution of the present invention foundation:
1, the rhamnolipid in the present invention is a kind of biosurfactant, has good wetting, emulsification, dispersion, osmotic work
Can, it can all degrade, have no toxic side effect to people and animals.Existing numerous studies and practical application confirm that rhamnolipid can be used in agriculture
Crop, veterinary antibiotics, on flowers for stimulating growth, assist absorption nutrition, increase pesticide and fertilizer function and effect etc..Sandlwood
Glycolipid biology surfactant, which has the carboxyl by the function of part microelement chelating, ionized out under weakly alkaline environment, can fix root
Microelement around being reduces a possibility that microelement quickly scatters and disappears in the soil, ensure that the long-term effect of fertilizer.To alkali
Property soil environment improvement can play useful effect, be the modified good additive of basic soil.To change soil hardening ring
Border condition.In addition, rhamnolipid has the function of good inhibition fungi, for crops seed dressing and inhibit fungi, mould
Experiment, has been found.
2, the fatty alcohol polyoxyethylene ether in the present invention has excellent wetability and water-retaining property, is conducive to medicaments uniformity suction
It receives, while playing the role of soil moisturizing.And can washed off soil heavy metal, reduce heavy metal in soil harm.Fatty alcohol polyoxy
Vinethene also has good permeability, can promote drug by insect body wall, reaches target target position.Simultaneously can promote medicine company into
Enter deep subsoil, plant root is made to form isolation strip with earth layer in spite of illness, reduces the soil-borne of disease.
3, the wood vinegar in the present invention is a kind of plant acid, has good bactericidal properties, can be used as soil sterilants, contain simultaneously
There is organic matter abundant.
4, the present invention in alkyl glycosides have good wetability and film forming, can to need to by stomata breathe insect exhale
Haustorium official carries out physical containment, and insect is caused to be choked to death.The effect that synergy can be really played to pesticide, improves applying pesticides
Dead worm rate.There is nitrogen fixation and heavy metal leaching simultaneously, reduce soil pollution.
5, the sodium lauroyl sarcosine in the present invention, glycerine, polyethylene glycol 400 have good water-retaining property and chesson
Effect, increase the gas permeability of soil.
Specific implementation method
Embodiment 1
1, by 30 parts of rhamnolipid of volume parts, 20 parts of fatty alcohol polyoxyethylene ether, 10 parts of wood vinegar, 10 portions of alkyl sugar
Glycosides, 10 parts of sodium lauroyl sarcosines, 10 parts of glycerine, 10 parts of polyethylene glycol 400s are implanted sequentially in agitator tank.
2, it by 240 revs/min of the rotating-speed modulation of reaction kettle, stirs 30 minutes, stops stirring, close agitator tank.
3, it is observed after standing 30 minutes, such as without layering, as finished product.If any layering, can continue to stir, up to no layering.
Embodiment 2
4, by 40 parts of rhamnolipid of volume parts, 20 parts of fatty alcohol polyoxyethylene ether, 15 parts of wood vinegar, 10 portions of alkyl sugar
Glycosides, 5 parts of sodium lauroyl sarcosines, 5 parts of glycerine, 5 parts of polyethylene glycol 400s are implanted sequentially in agitator tank.
5, it by 240 revs/min of the rotating-speed modulation of reaction kettle, stirs 30 minutes, stops stirring, close agitator tank.
6, it is observed after standing 30 minutes, such as without layering, as finished product.If any layering, can continue to stir, up to no layering.
Embodiment 3
7, by 50 parts of rhamnolipid of volume parts, 10 parts of fatty alcohol polyoxyethylene ether, 10 parts of wood vinegar, 10 portions of alkyl sugar
Glycosides, 10 parts of sodium lauroyl sarcosines, 5 parts of glycerine, 5 parts of polyethylene glycol 400s are implanted sequentially in agitator tank.
8, it by 240 revs/min of the rotating-speed modulation of reaction kettle, stirs 30 minutes, stops stirring, close agitator tank.
9, it is observed after standing 30 minutes, such as without layering, as finished product.If any layering, can continue to stir, up to no layering.
Claims (5)
1. a kind of soil tailored version environmental protection auxiliary agent, which is characterized in that the raw material including following volumes part: 30-60 parts of rhamnolipid,
1-60 parts of fatty alcohol polyoxyethylene ether, 1-50 parts of wood vinegar, 1-60 parts of sodium lauroyl sarcosine, 1-60 parts of glycerine, poly- second two
400 1-60 parts of alcohol, 1-10 parts of alkyl glycosides.
2. a kind of soil tailored version environmental protection auxiliary agent, which is characterized in that the raw material including following volumes part: 30 parts of rhamnolipid,
20 parts of fatty alcohol polyoxyethylene ether, 10 parts of wood vinegar, 10 parts of alkyl glycosides, 10 parts of sodium lauroyl sarcosines, 10 parts of glycerine,
10 parts of polyethylene glycol 400s.
3. a kind of soil tailored version environmental protection auxiliary agent, which is characterized in that the raw material including following volumes part: by 40 parts of volume parts
Rhamnolipid, 20 parts of fatty alcohol polyoxyethylene ether, 15 parts of wood vinegar, 10 parts of alkyl glycosides, 5 parts of sodium lauroyl sarcosines, 5 parts
Glycerine, 5 parts of polyethylene glycol 400s.
4. a kind of soil tailored version environmental protection auxiliary agent, which is characterized in that the raw material including following volumes part: 50 parts of rhamnolipid,
10 parts of fatty alcohol polyoxyethylene ether, 10 parts of wood vinegar, 10 parts of alkyl glycosides, 10 parts of sodium lauroyl sarcosines, 5 parts of glycerine, 5
Part polyethylene glycol 400.
5. a kind of preparation method of such as 1,2,3 embodiment of claim, which is characterized in that specific step is as follows: rhamnolipid, rouge
Fat alcohol polyoxyethylene ether, wood vinegar, alkyl glycosides, sodium lauroyl sarcosine, glycerine, polyethylene glycol 400 are uniformly mixed.
Priority Applications (1)
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CN201910681148.9A CN110358544A (en) | 2019-07-26 | 2019-07-26 | A kind of preparation method of soil tailored version environmental protection auxiliary agent |
Applications Claiming Priority (1)
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CN201910681148.9A CN110358544A (en) | 2019-07-26 | 2019-07-26 | A kind of preparation method of soil tailored version environmental protection auxiliary agent |
Publications (1)
Publication Number | Publication Date |
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CN110358544A true CN110358544A (en) | 2019-10-22 |
Family
ID=68222438
Family Applications (1)
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CN201910681148.9A Pending CN110358544A (en) | 2019-07-26 | 2019-07-26 | A kind of preparation method of soil tailored version environmental protection auxiliary agent |
Country Status (1)
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CN (1) | CN110358544A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112159666A (en) * | 2020-10-10 | 2021-01-01 | 天津华勘环保科技有限公司 | Composite biological cleaning agent for nickel-polluted soil |
CN114176077A (en) * | 2021-12-09 | 2022-03-15 | 中化化工科学技术研究总院有限公司 | Barrel-mixed spraying aid containing rhamnolipid and preparation method and application thereof |
WO2024073332A1 (en) * | 2022-09-26 | 2024-04-04 | Stepan Company | Hard surface cleaning compositions comprising rhamnolipids and sarcosinate co-surfactant |
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CN104263375A (en) * | 2014-09-22 | 2015-01-07 | 安徽大泽生物肥料科技有限公司 | Composite soil conditioner and preparation method and use thereof |
CN106172391A (en) * | 2016-07-05 | 2016-12-07 | 南京科翼新材料有限公司 | A kind of agricultural builder containing sodium cocoyl glutamate |
CN106852208A (en) * | 2016-12-30 | 2017-06-16 | 山东本源生态农业科技有限公司 | A kind of soil-repairing agent and its production and use, a kind of rehabilitating soil, the method for increasing crop yield |
CN109439333A (en) * | 2018-09-18 | 2019-03-08 | 睢宁新威农业机械有限公司 | Phosphatization soil modifying agent |
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2019
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CN112159666A (en) * | 2020-10-10 | 2021-01-01 | 天津华勘环保科技有限公司 | Composite biological cleaning agent for nickel-polluted soil |
CN114176077A (en) * | 2021-12-09 | 2022-03-15 | 中化化工科学技术研究总院有限公司 | Barrel-mixed spraying aid containing rhamnolipid and preparation method and application thereof |
WO2024073332A1 (en) * | 2022-09-26 | 2024-04-04 | Stepan Company | Hard surface cleaning compositions comprising rhamnolipids and sarcosinate co-surfactant |
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Application publication date: 20191022 |