CN110358148A - A kind of novel environment-friendly water-based resin phase transformation hydrated agent and its manufacturing process - Google Patents
A kind of novel environment-friendly water-based resin phase transformation hydrated agent and its manufacturing process Download PDFInfo
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Abstract
The invention discloses a kind of novel environment-friendly water-based resin phase transformation hydrated agent and its manufacturing process, relate generally to new material technology field, including fatty acid 10%-28%, trimethylamine 72%-88%, inorganic salts 0.5%-1%, inorganic strong alkali 1%-2.5%, load weighted fatty acid and trimethylamine are added in reaction kettle, heat temperature raising stirring, it is reacted 5.5-6.5 hours at 90 DEG C ± 5 DEG C, is then cooled to 50 DEG C ± 5 DEG C；Then successively load weighted inorganic salts, inorganic strong alkali are added in reaction kettle, continue to be stirred to react 0.5-1.5 hours at 50 DEG C ± 5 DEG C, obtain novel environment-friendly water-based resin phase transformation hydrated agent, breach that water-base resin stability existing for the current existing aqueous phase reversal hydration method of resin is poor, is easy layering, to resin bad adaptability, complex process, preparation process complexity, it is difficult to control, and the problems such as higher cost, have the characteristics that volume is few, stability is good, simple process adaptable to resin.
Description
Technical field
The invention mainly relates to new material technology field, specifically a kind of novel environment-friendly water-based resin phase transformation hydrated agent and its
Manufacturing process.
Background technique
Thermosetting resin (refers mainly to phenolic resin, epoxy resin, furane resins, organic siliconresin, polyurethane resin, second
Alkenyl esters resin and unsaturated polyester resin) as the nonmetallic anti-corrosion material of production thermosetting property and structural material, it is excellent with its
Physical and mechanical property and corrosion resistance, good weatherability, long-life and convenient processing performance, are widely used in anticorrosion, stone
Oil, metallurgy, electric power, space flight, aviation, national defence, heat exchange, dirt-proof, ship, ocean engineering protection, pharmacy, building materials, is given chemical industry
The industries such as draining, engineering machinery, environmental protection.But these thermosetting resins produced and used extensively both at home and abroad at present all exist in life
Smell is big, cross-linking monomer and organic solvent are volatile, long-term use temperature is low, operation before production, use process neutralization are fully cured
The disadvantage of bad environments.
Thermosetting resin is not soluble in water, is dissolved only in the organic solvents such as aromatic hydrocarbon, alcohol, ketone and esters.Organic solvent is inflammable, easy
The disadvantages of quick-fried, toxic, pollution environment, damage operator's health, knot production, storage and transportation and construction bring inconvenience.With ring
The enhancing for protecting consciousness, takes water as a solvent or the water-base resin of decentralized medium is more and more taken seriously.Using water as decentralized medium or molten
The water-base resin of agent is not only environmentally friendly material, and application property is good that (low viscosity, impregnability be good, room temperature curing, nontoxic
Property, volatility be small, environmental-friendly etc.), it can construct on wet surface, it is of less demanding to construction environment, it is easy to clean, storage and transportation and make
With safety, price is also cheap, thus becomes the developing direction of domestic and international production of resins application.
The distinguishing feature of water-base resin is: to inorganic face, filler and glass fibre wellability are good, have good mechanicalness
Energy, processing performance are good and have the characteristics that anti-flammability, low-shrinkage.
As countries in the world are to the pay attention to day by day of environmental protection, exploitation does not contain volatile organic compounds, prepares ring
Water-base resin, coating and the product of guarantor's type have become the new development trend of Resin Industry.
The main preparation methods of water-base resin:
1. direct emulsion process
Direct emulsion process is also known as Mechanical Method.Refer to after resin is added in blender, the aqueous solution of emulsifier is added, passes through
Uniform particle is dispersed in water by mechanical stirring；Resin and emulsifier can also directly be mixed, after being heated to temperature appropriate
Mechanical stirring is carried out, gradually adds water in whipping process, forms lotion.The characteristics of direct emulsion process is low in cost, preparation process
Simply.Shortcoming is that the aqueous resin dispersion system stability for preparing is poor, and the size of dispersion particle it is larger > 10 μm.
Phase transformation 2. (phase reversal) method
Phase inversion is the volume by changing water phase, and polymer is transformed into oil-in-water state from Water-In-Oil state, is
A method of effectively preparing macromolecule water baseization system.The advantages of phase inversion is, can by most macromolecule resin,
Corresponding water baseization system is made in the method for crossing physics emulsification, has greatly widened it and has prepared range.
3. chemic modified method
Chemic modified method is also known as self-emulsification.It is to be introduced polar group on molecular resin skeleton by chemical reaction,
Hydrophilic and oleophilic amphipathic characteristic is made it have, to have the function of being similar to surfactant.The characteristics of chemic modified method is system
The emulsion-stabilizing obtained, particle size is small, mostly nanoscale, but its preparation process is complicated, it is difficult to control, and higher cost.
4. curing agent emulsion process
Curing agent emulsion process be by polyamine curing agent chain extension, grafting, at salt, become aqueous dispersible curing agent.This
Kind curing agent has the molecular structure of resin, can be used as cationic emulsifier and emulsifies to resin, obtains stable cream
Liquid.
Thermosetting resin mutually becomes aqueous thermosetting resin, and key is that organic solvent resin is dissolved in water or is scattered in water,
Form the phase transformation hydrated agent of uniform and stable liquid.Phase transformation hydrated agent not only plays chemistry to resin and changes in resin hydration process
The effect of property, and play phase reversal to resin.
Therefore, a kind of novel aqueous resin phase transformation hydrated agent new and effective, adaptable to resin is developed, in thermosetting property
Production of resins and its composite material manufacture view have vast market prospect, for reducing environmental pollution, sustainable development war
Slightly it is of great significance to.
Summary of the invention
In view of the deficiencies in the prior art and defect, the present invention provides a kind of novel environment-friendly water-based resin phase transformation water
Agent and its manufacturing process have the characteristics that comprehensive hydrating capacity is good, strong to various resin conformabilities.
In order to solve the above-mentioned technical problem, the present invention adopts the following technical scheme:
A kind of novel environment-friendly water-based resin phase transformation hydrated agent, it is characterised in that: according to weight percent, including fatty acid
10%-28%, trimethylamine 72%-88%, inorganic salts 0.5%-1%, inorganic strong alkali 1%-2.5%.
As a further improvement of the present invention, fatty acid includes oleic acid, linoleic acid, linolenic acid, olive oil, rapeseed oil, jade
One kind of rice bran oil, oleum sojae, palmitic acid, coconut oil, palm oil, octanoic acid, capric acid, lauric acid, myristic acid, arachidic acid etc. is several
Kind.
As a further improvement of the present invention, organic amine include hydramine, fatty amine, aromatic amine, aliphatic cyclic amine, amide, piperidines,
The one or more of pyridine, picoline.
As a further improvement of the present invention, inorganic salts include carbonate, sulfate, nitrate, silicate, phosphate etc.
One or more.
As a further improvement of the present invention, inorganic strong alkali include sodium hydroxide, potassium hydroxide, lithium hydroxide one kind or
It is several.
A kind of manufacturing process of novel environment-friendly water-based resin phase transformation hydrated agent according to claim 1, feature exist
In: include the following steps,
(1) load weighted fatty acid and trimethylamine are added in reaction kettle, heat temperature raising stirring is anti-at 90 DEG C ± 5 DEG C
It answers 5.5-6.5 hours, is then cooled to 50 DEG C ± 5 DEG C；
(2) then successively load weighted inorganic salts, inorganic strong alkali are added in reaction kettle, continue to stir at 50 DEG C ± 5 DEG C
Reaction 0.5-1.5 hours is mixed, novel environment-friendly water-based resin phase transformation hydrated agent is obtained.
Compared with prior art, the device have the advantages that are as follows:
(1) novel environment-friendly water-based resin phase transformation hydrated agent of the invention breaches the current existing aqueous phase reversal water of resin
Water-base resin stability existing for change method is poor, is easy layering, is complicated to resin bad adaptability, complex process, preparation process, difficult
With control, and the problems such as higher cost, have the characteristics that volume is few, stability is good, simple process adaptable to resin, passes through
To aqueous unsaturated polyester resin, vinyl ester resin, the ring for using novel environment-friendly water-based resin phase transformation hydrated agent of the invention
The detection of oxygen resin shelf characteric, the storage stability of water-base resin was at 90 days or so.
(2) using the water-base resin of novel environment-friendly water-based resin phase transformation hydrated agent of the invention, 30%~120% can be added
Water aquation is carried out to resin, the water-base resin after phase transformation aquation, which is stored, to be stablized, in production of resins, use process, low smell ring
Protect, water-base resin casting matrix can under conditions of not changing existing System Curing At Room Temperature complete room temperature curing, water-base resin and system
Product solidification, contraction is small, and flame retardant property is good.
(3) novel environment-friendly water-based resin phase transformation hydrated agent of the invention and its method of manufacturing technology provide one kind more
Effective industrialized production water-base resin methods and techniques, have vast market prospect in terms of manufacturing environment-friendly composite material.
Specific embodiment
In order to which technical solution of the present invention and beneficial effect are more clearly understood, combined with specific embodiments below to the present invention
It is described in further detail, it should be understood that the specific embodiments described herein are only used for understanding the present invention, and do not have to
Of the invention, the every other implementation obtained by those of ordinary skill in the art without making creative efforts in limiting
Example, shall fall within the protection scope of the present invention.
A kind of novel environment-friendly water-based resin phase transformation hydrated agent, it is characterised in that: according to weight percent, including fatty acid
10%-28%, trimethylamine 72%-88%, inorganic salts 0.5%-1%, inorganic strong alkali 1%-2.5%.
Fatty acid includes oleic acid, linoleic acid, linolenic acid, olive oil, rapeseed oil, corn oil, oleum sojae, palmitic acid, coconut
The one or more of oil, palm oil, octanoic acid, capric acid, lauric acid, myristic acid, arachidic acid etc..
Organic amine includes hydramine (such as triisopropanolamine), fatty amine (such as benzyl dimethylamine), aromatic amine (such as aniline), alicyclic ring
The one or more of amine (such as triethylenediamine), amide (such as acetamide), piperidines, pyridine, picoline.
Inorganic salts include the one or more of carbonate, sulfate, nitrate, silicate, phosphate etc..
Inorganic strong alkali includes the one or more of sodium hydroxide, potassium hydroxide, lithium hydroxide.
A kind of a kind of manufacturing process of novel environment-friendly water-based resin phase transformation hydrated agent according to claim 1, it is special
Sign is: includes the following steps,
(1) load weighted fatty acid and trimethylamine are added in reaction kettle, heat temperature raising stirring is anti-at 90 DEG C ± 5 DEG C
It answers 5.5-6.5 hours, is then cooled to 50 DEG C ± 5 DEG C；
(2) then successively load weighted inorganic salts, inorganic strong alkali are added in reaction kettle, continue to stir at 50 DEG C ± 5 DEG C
Reaction 0.5-1.5 hours is mixed, novel environment-friendly water-based resin phase transformation hydrated agent is obtained.
Embodiment 1
A kind of novel environment-friendly water-based resin phase transformation hydrated agent provided in this embodiment, the following institute of the weight percent of each component
Show:
| Fatty acid | Linoleic acid | 100% | 12.5% |
| Trimethylamine | Triisopropanolamine | 100% | 86% |
| Inorganic salts | Sodium metasilicate: potassium silicate=3:1 | 100% | 1% |
| Inorganic strong alkali | Sodium hydroxide | 100% | 0.5% |
Preparation method:
1, load weighted saturated fatty acid 12.5% and trimethylamine 86% are added in reaction kettle, heat temperature raising stirring,
It is reacted 5.5 hours at 90 DEG C, is then cooled to 50 DEG C.
2, then load weighted inorganic salts 1%, inorganic strong alkali 0.5% are added in reaction kettle, continue to stir at 50 DEG C
Reaction 1 hour, obtains novel environment-friendly water-based resin phase transformation hydrated agent.
Embodiment 2:
A kind of novel environment-friendly water-based resin phase transformation hydrated agent provided in this embodiment, the following institute of the weight percent of each component
Show:
| Fatty acid | Octanoic acid | 100% | 20% |
| Trimethylamine | Triethylenediamine | 100% | 78% |
| Inorganic salts | Tertiary sodium phosphate: sodium metasilicate=3:2 | 100% | 1% |
| Inorganic strong alkali | Sodium hydroxide: lithium hydroxide=2:1 | 100% | 1% |
Preparation method:
1, load weighted fatty acid 20% and trimethylamine 78% are added in reaction kettle, heat temperature raising stirring, at 95 DEG C
Reaction 6 hours, is then cooled to 55 DEG C.
2, then load weighted inorganic salts 1%, inorganic strong alkali 1% are added in reaction kettle, it is anti-continues stirring at 55 DEG C
It answers 1 hour, obtains novel environment-friendly water-based resin phase transformation hydrated agent.
Embodiment 3:
A kind of novel environment-friendly water-based resin phase transformation hydrated agent provided in this embodiment, the following institute of the weight percent of each component
Show:
Preparation method:
1, load weighted fatty acid 15% and trimethylamine 83.5% are added in reaction kettle, heat temperature raising stirring, 85
DEG C reaction 6.5 hours, be then cooled to 45 DEG C.
2, then load weighted inorganic salts 0.5%, inorganic strong alkali 1% are added in reaction kettle, continue to stir at 45 DEG C
Reaction 1.5 hours, obtains novel environment-friendly water-based resin phase transformation hydrated agent.
Embodiment 4:
A kind of novel environment-friendly water-based resin phase transformation hydrated agent provided in this embodiment, the following institute of the weight percent of each component
Show:
| Fatty acid | Rapeseed oil: oleum sojae=1:2 | 100% | 22% |
| Trimethylamine | Benzyl dimethylamine: triethanolamine=1:3 | 100% | 76% |
| Inorganic salts | Tertiary sodium phosphate | 100% | 0.5% |
| Inorganic strong alkali | Sodium hydroxide | 100% | 1.5% |
Preparation method:
1, load weighted fatty acid 22% and trimethylamine 76% are added in reaction kettle, heat temperature raising stirring, at 90 DEG C
± 5 DEG C are reacted 6 hours, are then cooled to 45 DEG C.
2, then load weighted inorganic salts 0.5%, inorganic strong alkali 1.5% are added in reaction kettle, continue to stir at 45 DEG C
Reaction 1.3 hours is mixed, novel environment-friendly water-based resin phase transformation hydrated agent is obtained.
Embodiment 5:
A kind of novel environment-friendly water-based resin phase transformation hydrated agent provided in this embodiment, the following institute of the weight percent of each component
Show:
| Fatty acid | Lauric acid: palmitic acid=2:3 | 100% | 27% |
| Trimethylamine | Aniline: dimethylamine=1:3 | 100% | 72% |
| Inorganic salts | Sodium sulphate: sodium metasilicate=1:4 | 100% | 0.5% |
| Inorganic strong alkali | Sodium hydroxide: potassium hydroxide=2:1 | 100% | 0.5% |
Preparation method:
1, load weighted saturated fatty acid 27% and trimethylamine 72% are added in reaction kettle, heat temperature raising stirring,
90 DEG C are reacted 6 hours, are then cooled to 50 DEG C.
2, then load weighted inorganic salts 0.5%, inorganic strong alkali 0.5% are added in reaction kettle, continue to stir at 45 DEG C
Reaction 1 hour is mixed, novel environment-friendly water-based resin phase transformation hydrated agent is obtained.
It is compared by many experiments, for unsaturated polyester resin, vinyl ester resin, epoxy resin, phenolic resin, furan
For furane resins, organic siliconresin and polyurethane resin, novel environment-friendly water-based resin phase transformation hydrated agent dosage 2.5%-7%,
When water consumption is within the scope of 50%-60%, water-base resin intensity is high, presentation quality is good, water absorption rate is low, contraction is small, flame retardant property
Good, integrated performance index height；When novel environment-friendly water-based resin phase transformation hydrated agent dosage is lower than 2.5%, water-base resin storage is stablized
Property is poor；When novel environment-friendly water-based resin phase transformation hydrated agent dosage is more than 7%, although water-base resin storage stability is extended,
But water-base resin higher cost.
Claims (6)
1. a kind of novel environment-friendly water-based resin phase transformation hydrated agent, it is characterised in that: according to weight percent, including fatty acid
10%-28%, trimethylamine 72%-88%, inorganic salts 0.5%-1%, inorganic strong alkali 1%-2.5%.
2. a kind of novel environment-friendly water-based resin phase transformation hydrated agent according to claim 1, it is characterised in that: fatty acid includes
Oleic acid, linoleic acid, linolenic acid, olive oil, rapeseed oil, corn oil, oleum sojae, palmitic acid, coconut oil, palm oil, octanoic acid, the last of the ten Heavenly stems
The one or more of acid, lauric acid, myristic acid, arachidic acid etc..
3. a kind of novel environment-friendly water-based resin phase transformation hydrated agent according to claim 1, it is characterised in that: organic amine includes
The one or more of hydramine, fatty amine, aromatic amine, aliphatic cyclic amine, amide, piperidines, pyridine, picoline.
4. a kind of novel environment-friendly water-based resin phase transformation hydrated agent according to claim 1, it is characterised in that: inorganic salts include
The one or more of carbonate, sulfate, nitrate, silicate, phosphate etc..
5. a kind of novel environment-friendly water-based resin phase transformation hydrated agent according to claim 1, it is characterised in that: inorganic strong alkali packet
Include the one or more of sodium hydroxide, potassium hydroxide, lithium hydroxide.
6. a kind of a kind of manufacturing process of novel environment-friendly water-based resin phase transformation hydrated agent according to claim 1, feature
It is: includes the following steps,
(1) load weighted fatty acid and trimethylamine are added in reaction kettle, heat temperature raising stirring, in 90 DEG C of ± 5 DEG C of reactions
5.5-6.5 hours, then it is cooled to 50 DEG C ± 5 DEG C；
(2) then successively load weighted inorganic salts, inorganic strong alkali are added in reaction kettle, it is anti-continues stirring at 50 DEG C ± 5 DEG C
It answers 0.5-1.5 hours, obtains novel environment-friendly water-based resin phase transformation hydrated agent.
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| CN104593165A (en) * | 2014-12-31 | 2015-05-06 | 广州市标榜汽车用品实业有限公司 | High-solid-content engine appearance heavy greasy dirt cleaning agent and preparation method thereof |
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