CN103866619B - A kind of cationic rosin size sizing agent and preparation method thereof - Google Patents
A kind of cationic rosin size sizing agent and preparation method thereof Download PDFInfo
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- CN103866619B CN103866619B CN201410062539.XA CN201410062539A CN103866619B CN 103866619 B CN103866619 B CN 103866619B CN 201410062539 A CN201410062539 A CN 201410062539A CN 103866619 B CN103866619 B CN 103866619B
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Abstract
The present invention relates to a kind of cationic rosin size sizing agent and preparation method thereof, cationic rosin size sizing agent is made up of according to weight ratio following composition: cationic rosin size is 6 ~ 8 parts, vinyl acetate is 9 ~ 12 parts, polyacrylonitrile is 2 ~ 3 parts, tetradecyl methylacrylate is 5 ~ 6 parts, polyoxyethylene sorbitol acid anhydride tristearate is 12 ~ 15 parts, alum is 3 ~ 4 parts, deionized water is 240 ~ 260 parts.The preparation method of cationic rosin size sizing agent is heating, composite, reaction, cooling etc.The cationic rosin size sizing agent prepared has good dewatering ability and high-temperature stability, and can improve the ring crush intensity of paper significantly.
Description
Technical field
The present invention relates to a kind of sizing agent and preparation method thereof, particularly relate to and a kind ofly there is good stability and sizing agent of the ring crush intensity of paper and preparation method thereof can be significantly improved.
Background technology
Paper, in preparation process, by glue-applying technique, can give the physical property that paper is certain, prevents infiltration and the diffusion of some fluids.Conventional paper is after paper technology terminates, if without applying glue process, the existence in a large amount of spaces is had in the middle of string in paper, and these strings itself are with a large amount of oh groups, due to the existence of these oh groups, when paper and liquid comes into contact, liquid can enter paper inside, affect the intensity of paper, limit effective use of paper.
The range of application of cationic rosin size sizing agent is comparatively wide, and present stage, most cation colophony size was applied to after in paper technology, and the ring crush intensity of paper improves little, still limits widely using of paper.
Summary of the invention
The technical problem solved: conventional sizing agent less stable, and the ring crush intensity of the paper prepared is too low, limits the problem of the use of paper.
Technical scheme: the invention discloses a kind of cationic rosin size sizing agent and preparation method thereof, cationic rosin size sizing agent is made up of according to weight ratio following composition: cationic rosin size is 6 ~ 8 parts, vinyl acetate is 9 ~ 12 parts, polyacrylonitrile is 2 ~ 3 parts, tetradecyl methylacrylate is 5 ~ 6 parts, polyoxyethylene sorbitol acid anhydride tristearate is 12 ~ 15 parts, alum is 3 ~ 4 parts, deionized water is 240 ~ 260 parts.
A kind of preparation method of cationic rosin size sizing agent, preparation method comprises the steps: (1) by stainless steel cauldron heating temperatures to 45 DEG C, in reactor, add after temperature constant that cationic rosin size is 6 ~ 8 parts, vinyl acetate is 9 ~ 12 parts, polyacrylonitrile is 2 ~ 3 parts, tetradecyl methylacrylate is 5 ~ 6 parts, carry out sufficient mechanical agitation, be stirred to and mix; (2) in stainless steel cauldron, add that polyoxyethylene sorbitol acid anhydride tristearate is 12 ~ 15 parts, deionized water is 240 ~ 260 parts again, mechanical agitation oar is used to carry out abundant stirring and emulsifying, be stirred to mixed liquor and become emulsion, continue to stir 30min after becoming emulsion; (3) in stainless steel cauldron, adding alum is 3 ~ 4 parts, carries out stirring abundant reaction, and mixing time is 2h; (4), after reaction terminates, the sizing agent prepared is slowly cooled to room temperature.
The cationic rosin size added in the preparation process of cationic rosin size sizing agent is preferably 8 parts.
The polyoxyethylene sorbitol acid anhydride tristearate added in the preparation process of cationic rosin size sizing agent is preferably 12 parts.
The alum added in stainless steel cauldron in the preparation process of cationic rosin size sizing agent is preferably 4 parts.
Beneficial effect: the present invention prepares cationic rosin size sizing agent and has good stability, under 3000rpm, centrifugal 30 to 50min does not have lamination, heat after 12 to 24h without lamination at 50 DEG C, paper is after sizing agent process of the present invention, ring crush index is increased to 7.9 to 8.2 by 5.3, improves the ring crush intensity of paper.
Detailed description of the invention
Embodiment 1
A kind of preparation method of cationic rosin size sizing agent, preparation method comprises the steps: (1) by stainless steel cauldron heating temperatures to 45 DEG C, in reactor, add after temperature constant that cationic rosin size is 6kg, vinyl acetate is 12kg, polyacrylonitrile is 2kg, tetradecyl methylacrylate is 5kg, carry out sufficient mechanical agitation, be stirred to and mix; (2) in stainless steel cauldron, add that polyoxyethylene sorbitol acid anhydride tristearate is 12kg, deionized water is 240kg again, use mechanical agitation oar to carry out abundant stirring and emulsifying, being stirred to mixed liquor becomes emulsion, continues to stir 30min after becoming emulsion; (3) in stainless steel cauldron, adding alum is 4kg, carries out stirring abundant reaction, and mixing time is 2h; (4), after reaction terminates, the sizing agent prepared is slowly cooled to room temperature.
Embodiment 2
A kind of preparation method of cationic rosin size sizing agent, preparation method comprises the steps: (1) by stainless steel cauldron heating temperatures to 45 DEG C, in reactor, add after temperature constant that cationic rosin size is 7kg, vinyl acetate is 10kg, polyacrylonitrile is 3kg, tetradecyl methylacrylate is 5kg, carry out sufficient mechanical agitation, be stirred to and mix; (2) in stainless steel cauldron, add that polyoxyethylene sorbitol acid anhydride tristearate is 13kg, deionized water is 260kg again, use mechanical agitation oar to carry out abundant stirring and emulsifying, being stirred to mixed liquor becomes emulsion, continues to stir 30min after becoming emulsion; (3) in stainless steel cauldron, adding alum is 3kg, carries out stirring abundant reaction, and mixing time is 2h; (4), after reaction terminates, the sizing agent prepared is slowly cooled to room temperature.
Embodiment 3
A kind of preparation method of cationic rosin size sizing agent, preparation method comprises the steps: (1) by stainless steel cauldron heating temperatures to 45 DEG C, in reactor, add after temperature constant that cationic rosin size is 8kg, vinyl acetate is 9kg, polyacrylonitrile is 2kg, tetradecyl methylacrylate is 6kg, carry out sufficient mechanical agitation, be stirred to and mix; (2) in stainless steel cauldron, add that polyoxyethylene sorbitol acid anhydride tristearate is 15kg, deionized water is 250kg again, use mechanical agitation oar to carry out abundant stirring and emulsifying, being stirred to mixed liquor becomes emulsion, continues to stir 30min after becoming emulsion; (3) in stainless steel cauldron, adding alum is 4kg, carries out stirring abundant reaction, and mixing time is 2h; (4), after reaction terminates, the sizing agent prepared is slowly cooled to room temperature.
By the sizing agent of embodiment 1, embodiment 2, embodiment 3 respectively centrifugal 30min, 40min, 50min at 3,000 rpm, more another Example 1, embodiment 2, embodiment 3 sizing agent at 50 DEG C, heat 12h, 18h, 24h respectively.Observe the stability of sizing agent.Result is as follows.
By mass concentration be 7wt% needle slurry stir, the cationic rosin size sizing agent of embodiment 1, embodiment 2, embodiment 3 is added respectively in needle slurry, sizing agent addition is the 1.1wt% of paper weight, stir after adding sizing agent, again paper is carried out handsheet, paper is quantitatively 30g/m
2, the dry post curing of paper, be cooled to room temperature after slaking, measure the ring crush intensity of embodiment 1, embodiment 2, embodiment 3, bioassay standard is GB/T2679.8-1995.Mensuration numerical value is as follows.Carry out comparative example experiment, technique is identical with embodiment simultaneously, does not add sizing agent.
Comparative example | Embodiment 1 | Embodiment 2 | Embodiment 3 | |
Ring crush index (Nm/g) | 5.3 | 8.1 | 7.9 | 8.2 |
The ring crush index of paper is improved significantly, and improves the intensity of paper, effectively expands the scope of application of plain paper.
Claims (4)
1. a cationic rosin size sizing agent, is characterized in that cationic rosin size sizing agent is made up of according to weight ratio following composition: cationic rosin size is 6 ~ 8 parts, vinyl acetate is 9 ~ 12 parts, polyacrylonitrile is 2 ~ 3 parts, tetradecyl methylacrylate is 5 ~ 6 parts, polyoxyethylene sorbitol acid anhydride tristearate is 12 ~ 15 parts, alum is 3 ~ 4 parts, deionized water is 240 ~ 260 parts;
The preparation method of described a kind of cationic rosin size sizing agent, comprise the steps: that (1) is by stainless steel cauldron heating temperatures to 45 DEG C, in reactor, add after temperature constant that cationic rosin size is 6 ~ 8 parts, vinyl acetate is 9 ~ 12 parts, polyacrylonitrile is 2 ~ 3 parts, tetradecyl methylacrylate is 5 ~ 6 parts, carry out sufficient mechanical agitation, be stirred to and mix; (2) in stainless steel cauldron, add that polyoxyethylene sorbitol acid anhydride tristearate is 12 ~ 15 parts, deionized water is 240 ~ 260 parts again, mechanical agitation oar is used to carry out abundant stirring and emulsifying, be stirred to mixed liquor and become emulsion, continue to stir 30min after becoming emulsion; (3) in stainless steel cauldron, adding alum is 3 ~ 4 parts, carries out stirring abundant reaction, and mixing time is 2h; (4), after reaction terminates, the sizing agent prepared is slowly cooled to room temperature.
2. a kind of cationic rosin size sizing agent according to claim 1, is characterized in that the cationic rosin size added in preparation process is 8 parts.
3. a kind of cationic rosin size sizing agent according to claim 1, is characterized in that the polyoxyethylene sorbitol acid anhydride tristearate added in preparation process is 12 parts.
4. a kind of cationic rosin size sizing agent according to claim 1, is characterized in that the alum added in stainless steel cauldron in preparation process is 4 parts.
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CN104060493A (en) * | 2014-06-20 | 2014-09-24 | 苏州锐耐洁电子科技新材料有限公司 | Scent type water-resistant paper pulp additive |
CN106120435B (en) * | 2016-06-23 | 2017-10-24 | 福建希源纸业有限公司 | A kind of production method for regenerating true qualities transfer printing paper |
CN106758498B (en) * | 2016-12-21 | 2018-02-13 | 南昌市龙然实业有限公司 | Water resistant oil resistant Cationic dispersed rosin size |
CN106592335B (en) * | 2016-12-21 | 2018-02-13 | 南昌市龙然实业有限公司 | Cation colophony size for food wrapper |
Citations (4)
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CN1184184A (en) * | 1997-12-03 | 1998-06-10 | 中国科学院广州化学研究所 | Sizing synergist and its use |
CN1334888A (en) * | 1998-12-07 | 2002-02-06 | 赫尔克里士公司 | Sizing composition |
CN1851123A (en) * | 2006-05-30 | 2006-10-25 | 朱勇强 | Glueing method for papermaking process |
CN102472018A (en) * | 2009-07-23 | 2012-05-23 | 赫尔克里士公司 | Sizing composition for hot penetrant resistance |
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JP3477932B2 (en) * | 1995-07-04 | 2003-12-10 | 荒川化学工業株式会社 | Rosin-based emulsion sizing agent for papermaking and paper sizing method |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1184184A (en) * | 1997-12-03 | 1998-06-10 | 中国科学院广州化学研究所 | Sizing synergist and its use |
CN1334888A (en) * | 1998-12-07 | 2002-02-06 | 赫尔克里士公司 | Sizing composition |
CN1851123A (en) * | 2006-05-30 | 2006-10-25 | 朱勇强 | Glueing method for papermaking process |
CN102472018A (en) * | 2009-07-23 | 2012-05-23 | 赫尔克里士公司 | Sizing composition for hot penetrant resistance |
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