CN106120435B - A kind of production method for regenerating true qualities transfer printing paper - Google Patents

A kind of production method for regenerating true qualities transfer printing paper Download PDF

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Publication number
CN106120435B
CN106120435B CN201610461830.3A CN201610461830A CN106120435B CN 106120435 B CN106120435 B CN 106120435B CN 201610461830 A CN201610461830 A CN 201610461830A CN 106120435 B CN106120435 B CN 106120435B
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China
Prior art keywords
parts
rosin
sizing agent
true qualities
consumption
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Expired - Fee Related
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CN201610461830.3A
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Chinese (zh)
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CN106120435A (en
Inventor
陈承勇
刘家锦
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Zhangzhou Huixin Paper Co Ltd
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FUJIAN XIYUAN PAPER INDUSTRY Co Ltd
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Publication of CN106120435A publication Critical patent/CN106120435A/en
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H15/00Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
    • D21H15/02Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
    • D21H15/10Composite fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/62Rosin; Derivatives thereof
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/66Salts, e.g. alums
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16Sizing or water-repelling agents

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Paper (AREA)

Abstract

The present invention relates to field of papermaking, a kind of production method for regenerating true qualities transfer printing paper is provided, solve transfer printing paper of the prior art and there is the too poor or too strong defect of low tensile strength, easy hair loss, dry linting, moisture absorption intensity, preparation including slurry, the raw material that the preparation of the slurry is used is true qualities wood pulp, masson pine and waste paper regenerated slurry, and the consumption of the true qualities wood pulp, masson pine and waste paper regenerated slurry is:1:1:0.5, during slurrying, beating degree is controlled 50~650SR, 4.0~6.0g of weight in wet base, concentration 2.7~3.4%, adjuvant is also added with the pulping process, the adjuvant is cationic rosin size sizing agent and aluminum sulfate, the consumption of the cationic rosin size sizing agent is the 0.4~0.5% of oven dry stock weight, and the consumption of the aluminum sulfate is the 0.1~0.3% of oven dry stock weight.

Description

A kind of production method for regenerating true qualities transfer printing paper
Technical field
The present invention relates to field of papermaking, more particularly to a kind of production method for regenerating true qualities transfer printing paper.
Background technology
Transfer printing paper is a kind of new industrial paper, is mainly used in the printing technology of textile.With traditional printing and dyeing Technique compares, and has clear advantage using transfer printing paper stamp, and it is transferred, and pattern flower-shape is true to nature, decorative pattern is careful, level Clearly, third dimension is strong;Non-environmental-pollution problem.
At present, transfer printing paper is had been applied in increasing industry, such as fabric printing, building decoration, tourism and Product development, leather and the ceramic product stamp in advertising field etc..Transfer printing in different industries, to transfer printing paper Performance requirement is different, thus various transfer printing papers emerge in an endless stream, and yield and consumption are also being increased rapidly.State The transfer printing paper of interior application relies primarily on import, and domestic transfer printing paper yield is less, the problem of quality also has certain, but Its impetus developed rapidly is very important.The today especially developed rapidly in digital technology, transfer printing paper is high with these Science and technology is combined, and will have broader development space, and market prospects are had an optimistic view of.
But transfer printing paper generally existing tensile strength in the market is low, easy hair loss, dry linting, moisture absorption intensity are too poor Or too strong etc. defect, the hygroscopicity of transfer printing paper is too poor to cause color ink to cut marks, and moisture absorption intensity crosses conference and causes calico paper to become Shape.
The content of the invention
Therefore, for above content, the present invention provides a kind of production method for regenerating true qualities transfer printing paper, solves existing There is the too poor or too strong defect of low tensile strength, easy hair loss, dry linting, moisture absorption intensity in the transfer printing paper in technology.
To reach above-mentioned purpose, the present invention is achieved by the following technical solutions:One kind regeneration true qualities transfer printing paper Production method, include the preparation of slurry, the raw material that the preparation of the slurry is used for true qualities wood pulp, masson pine and Waste paper regenerated slurry, the consumption of the true qualities wood pulp, masson pine and waste paper regenerated slurry is:1:1:0.5, during slurrying, beat The degree of beating is controlled 50~650Adjuvant is also added with SR, 4.0~6.0g of weight in wet base, concentration 2.7~3.4%, the pulping process, The adjuvant is cationic rosin size sizing agent and aluminum sulfate, and the consumption of the cationic rosin size sizing agent is oven dry stock weight 0.4~0.5%, the consumption of the aluminum sulfate is the 0.1~0.3% of oven dry stock weight, the cationic rosin size sizing agent by with Each raw material composition of lower parts by weight:10~20 parts of esterified rosin, modified rich 15~25 parts of horse rosin, Malin's acid resin 15~20 Part, 5~10 parts of acetic acid, 5~15 parts of polyoxyethylene sorbitol acid anhydride tristearate, 1- sulfydryls are for 3~5 parts of dodecane, methyl-prop 10~20 parts of olefin(e) acid dimethylamino ethyl ester, 12~15 parts of potassium peroxydisulfate, 10~25 parts of cetyl trimethyl ammonium halide, propylene 10~15 parts of acid amides, 80~120 parts of deionized water.
Further improving is:The cationic rosin size sizing agent is made up of each raw material of following parts by weight:Esterification pine Fragrant 15~20 parts, modified rich 20~25 parts of horse rosin, 17~20 parts of Malin's acid resin, 8~10 parts of acetic acid, polyoxyethylene sorbitol 10~15 parts of acid anhydride tristearate, 1- sulfydryls are for 3~5 parts of dodecane, 15~20 parts of dimethylaminoethyl methacrylate, mistake 2~5 parts of potassium sulfate, 16~25 parts of cetyl trimethyl ammonium halide, 13~15 parts of acrylamide, deionized water 100~120 Part.
Further improving is:The preparation method of the cationic rosin size sizing agent is:First by esterified rosin, modification Rich horse rosin, Malin's acid resin are heated to 160~170 DEG C, and melting, polyoxyethylene sorbitol is added in another heater in advance Acid anhydride tristearate, 1- sulfydryls are for dodecane, dimethylaminoethyl methacrylate, cetyl trimethyl ammonium halide, one Half deionized water, is heated to 60~70 DEG C, stirs, be slowly dropped into potassium peroxydisulfate, be added followed by acetic acid and acryloyl Amine, the esterified rosin melted in advance, modified rich horse rosin, Malin's acid resin are finally mixed, add another with said mixture The deionized water of half, grinds through colloid mill, obtains cationic rosin size sizing agent.
Further improving is:The consumption of the cationic rosin size sizing agent is the 0.45% of oven dry stock weight, the sulfuric acid The consumption of aluminium is the 0.2% of oven dry stock weight.
Further improving is:Apply pH value after cationic rosin size sizing agent to control 4.0~6.5.
By using preceding solution, the beneficial effects of the invention are as follows:The regeneration true qualities transfer printing paper of the present invention, bag Include the preparation of slurry, the raw material that the preparation of the slurry is used is true qualities wood pulp, masson pine and waste paper regenerated slurry, institute The consumption for stating true qualities wood pulp, masson pine and waste paper regenerated slurry is:1:1:0.5, on traditional transfer printing paper material Masson pine is all used, the application replaces a part in the selection of raw material with true qualities wood pulp and waste paper regenerated slurry Masson pine, true qualities wood pulp cellulose is longer, and paper can be made to have enough tensile strength, surface not hair loss, dry linting, And waste paper regenerated slurry is the recycling from waste paper, the cost of raw material is reduced.Also added with auxiliary in pulping process Agent, the adjuvant is cationic rosin size sizing agent and aluminum sulfate, and cationic rosin size sizing agent uses special formula, That is, 10~20 parts of esterified rosin, modified rich 15~25 parts of horse rosin, 15~20 parts of Malin's acid resin, 5~10 parts of acetic acid, polyoxy 5~15 parts of ethene sorbitol anhydride tristearate, 1- sulfydryls are for 3~5 parts of dodecane, dimethylaminoethyl methacrylate 10 ~20 parts, 12~15 parts of potassium peroxydisulfate, 10~25 parts of cetyl trimethyl ammonium halide, 10~15 parts of acrylamide, deionization 80~120 parts of water, and addition control can preferably control the hygroscopicity of obtained paper the 0.4~0.5% of oven dry stock weight, Avoid hygroscopicity is too poor from occurring that color ink cuts marks or hygroscopicity is excessive causes transfer printing paper to deform, the intensity and durability of paper are all It is improved.
Embodiment
Describe embodiments of the present invention in detail below with reference to specific embodiment, how skill is applied to the present invention whereby Art means solve technical problem, and reach the implementation process of technique effect and can fully understand and implement according to this.
Unless otherwise specified, the conventional hand that the technological means employed in embodiment is well known to those skilled in the art Section, the reagent and product used is also available commercial.The source of agents useful for same, trade name and it is necessary to list it Constituent person, indicates on the first appearance.
Embodiment one
A kind of production method for regenerating true qualities transfer printing paper, includes the preparation of slurry, the preparation use of the slurry Raw material is true qualities wood pulp, masson pine and waste paper regenerated slurry, and the true qualities wood pulp, masson pine and waste paper are again Giving birth to the consumption starched is:1:1:0.5, during slurrying, beating degree is controlled 500SR, weight in wet base 4.0g, concentration 2.7%, the pulping process In be also added with adjuvant, the adjuvant is cationic rosin size sizing agent and aluminum sulfate, cationic rosin size applying glue The consumption of agent is the 0.4% of oven dry stock weight, and the consumption of the aluminum sulfate is the 0.1% of oven dry stock weight, applies cationic rosin size and applies PH value control is 4.0 after jelly, and the cationic rosin size sizing agent is made up of each raw material of following parts by weight:Esterified rosin 10 Part, modified rich 15 parts of horse rosin, 15 parts of Malin's acid resin, 5 parts of acetic acid, 5 parts of polyoxyethylene sorbitol acid anhydride tristearate, 1- mercaptos Base is for 3 parts of dodecane, 10 parts of dimethylaminoethyl methacrylate, 12 parts of potassium peroxydisulfate, cetyl trimethyl ammonium halide 10 parts, 10 parts of acrylamide, 80 parts of deionized water.The preparation method of the cationic rosin size sizing agent is:First will esterification Rosin, modified rich horse rosin, Malin's acid resin are heated to 160 DEG C, and melting in advance adds polyoxyethylene mountain in another heater Pears alcohol acid anhydride tristearate, 1- sulfydryls are for dodecane, dimethylaminoethyl methacrylate, cetyl trimethyl halogenation The deionized water of ammonium, half, is heated to 60 DEG C, stirs, be slowly dropped into potassium peroxydisulfate, is added followed by acetic acid and acryloyl Amine, the esterified rosin melted in advance, modified rich horse rosin, Malin's acid resin are finally mixed, add another with said mixture The deionized water of half, grinds through colloid mill, obtains cationic rosin size sizing agent.
After the completion of prepared by slurry, paper pulp is surfed the Net, the dehydration of control wet end, shaping, then be through squeezing, top sizing, drying Regeneration true qualities transfer printing paper is made.
Embodiment two
A kind of production method for regenerating true qualities transfer printing paper, includes the preparation of slurry, the preparation use of the slurry Raw material is true qualities wood pulp, masson pine and waste paper regenerated slurry, and the true qualities wood pulp, masson pine and waste paper are again Giving birth to the consumption starched is:1:1:0.5, during slurrying, beating degree is controlled 550In SR, weight in wet base 5g, concentration 3.0%, the pulping process Adjuvant is also added with, the adjuvant is cationic rosin size sizing agent and aluminum sulfate, the cationic rosin size sizing agent Consumption be the 0.45% of oven dry stock weight, the consumption of the aluminum sulfate is the 0.2% of oven dry stock weight, applies cationic rosin size applying glue PH value control is 5.0 after agent, and the cationic rosin size sizing agent is made up of each raw material of following parts by weight:Esterified rosin 15 Part, modified rich 20 parts of horse rosin, 17 parts of Malin's acid resin, 8 parts of acetic acid, 10 parts of polyoxyethylene sorbitol acid anhydride tristearate, 1- Sulfydryl is for 3 parts of dodecane, 15 parts of dimethylaminoethyl methacrylate, 2 parts of potassium peroxydisulfate, cetyl trimethyl ammonium halide 16 parts, 13 parts of acrylamide, 100 parts of deionized water.The preparation method of the cationic rosin size sizing agent is:First will esterification Rosin, modified rich horse rosin, Malin's acid resin are heated to 165 DEG C, and melting in advance adds polyoxyethylene mountain in another heater Pears alcohol acid anhydride tristearate, 1- sulfydryls are for dodecane, dimethylaminoethyl methacrylate, cetyl trimethyl halogenation The deionized water of ammonium, half, is heated to 65 DEG C, stirs, be slowly dropped into potassium peroxydisulfate, is added followed by acetic acid and acryloyl Amine, the esterified rosin melted in advance, modified rich horse rosin, Malin's acid resin are finally mixed, add another with said mixture The deionized water of half, grinds through colloid mill, obtains cationic rosin size sizing agent.
Embodiment three
A kind of production method for regenerating true qualities transfer printing paper, includes the preparation of slurry, the preparation use of the slurry Raw material is true qualities wood pulp, masson pine and waste paper regenerated slurry, and the true qualities wood pulp, masson pine and waste paper are again Giving birth to the consumption starched is:1:1:0.5, during slurrying, beating degree is controlled 650SR, weight in wet base 6.0g, concentration 3.4%, the pulping process In be also added with adjuvant, the adjuvant is cationic rosin size sizing agent and aluminum sulfate, cationic rosin size applying glue The consumption of agent is the 0.5% of oven dry stock weight, and the consumption of the aluminum sulfate is the 0.3% of oven dry stock weight, applies cationic rosin size and applies PH value control is 6.5 after jelly, and the cationic rosin size sizing agent is made up of each raw material of following parts by weight:Esterified rosin 20 Part, modified rich 25 parts of horse rosin, 20 parts of Malin's acid resin, 10 parts of acetic acid, 15 parts of polyoxyethylene sorbitol acid anhydride tristearate, 1- Sulfydryl is for 5 parts of dodecane, 20 parts of dimethylaminoethyl methacrylate, 15 parts of potassium peroxydisulfate, cetyl trimethyl halogenation 25 parts of ammonium, 15 parts of acrylamide, 120 parts of deionized water.The preparation method of the cationic rosin size sizing agent is:First by ester Change rosin, modified rich horse rosin, Malin's acid resin and be heated to 170 DEG C, melting, polyoxyethylene is added in another heater in advance Sorbitol anhydride tristearate, 1- sulfydryls are for dodecane, dimethylaminoethyl methacrylate, cetyl trimethyl halogenation The deionized water of ammonium, half, is heated to 70 DEG C, stirs, be slowly dropped into potassium peroxydisulfate, is added followed by acetic acid and acryloyl Amine, the esterified rosin melted in advance, modified rich horse rosin, Malin's acid resin are finally mixed, add another with said mixture The deionized water of half, grinds through colloid mill, obtains cationic rosin size sizing agent.
Wherein, in the present invention, each raw material components and content of the cationic rosin size sizing agent are equal in following scope The purpose of the present invention can be achieved:10~20 parts of esterified rosin, modified rich 15~25 parts of horse rosin, 15~20 parts of Malin's acid resin, 5~10 parts of acetic acid, 5~15 parts of polyoxyethylene sorbitol acid anhydride tristearate, 1- sulfydryls are for 3~5 parts of dodecane, methacrylic acid 10~20 parts of dimethylamino ethyl ester, 12~15 parts of potassium peroxydisulfate, 10~25 parts of cetyl trimethyl ammonium halide, acrylamide 10~15 parts, 80~120 parts of deionized water.
Described above, only using the embodiment of this origination techniques content, any those skilled in the art use this wound Make done modifications and changes, all belong to the scope of the claims of this creation opinion, and be not limited to those disclosed embodiments.

Claims (4)

1. a kind of production method for regenerating true qualities transfer printing paper, includes the preparation of slurry, it is characterised in that the system of the slurry The standby raw material used is true qualities wood pulp, masson pine and waste paper regenerated slurry, the true qualities wood pulp, masson pine And the consumption of waste paper regenerated slurry is:1:1:0.5, during slurrying, beating degree is controlled in 50~65 ° of SR, 4.0~6.0g of weight in wet base, concentration 2.7~3.4%, adjuvant is also added with the pulping process, the adjuvant is cationic rosin size sizing agent and sulfuric acid Aluminium, the consumption of the cationic rosin size sizing agent is the 0.4~0.5% of oven dry stock weight, and the consumption of the aluminum sulfate is over dry The 0.1~0.3% of weight is starched, the cationic rosin size sizing agent is made up of each raw material of following parts by weight:Esterified rosin 10~ 20 parts, modified rich 15~25 parts of horse rosin, 15~20 parts of Malin's acid resin, 5~10 parts of acetic acid, polyoxyethylene sorbitol acid anhydride three it is hard 5~15 parts of resin acid ester, 1- sulfydryls are for 3~5 parts of dodecane, 10~20 parts of dimethylaminoethyl methacrylate, potassium peroxydisulfate 12~15 parts, 10~25 parts of cetyl trimethyl ammonium halide, 10~15 parts of acrylamide, 80~120 parts of deionized water;
The preparation method of the cationic rosin size sizing agent is:First by esterified rosin, modified rich horse rosin, Malin's acid resin 160~170 DEG C are heated to, in advance melting, polyoxyethylene sorbitol acid anhydride tristearate, 1- sulfydryls are added in another heater For dodecane, dimethylaminoethyl methacrylate, cetyl trimethyl ammonium halide, half deionized water, be heated to 60~70 DEG C, stir, be slowly dropped into potassium peroxydisulfate, be added followed by acetic acid and acrylamide, will finally melt in advance Esterified rosin, modified rich horse rosin, Malin's acid resin are mixed with said mixture, second half deionized water are added, through glue Body grinder is ground, and obtains cationic rosin size sizing agent.
2. the production method of regeneration true qualities transfer printing paper according to claim 1, it is characterised in that:The cation pine The consumption of balosam sizing agent is the 0.45% of oven dry stock weight, and the consumption of the aluminum sulfate is the 0.2% of oven dry stock weight.
3. the production method of regeneration true qualities transfer printing paper according to claim 1, it is characterised in that:Apply cation pine PH value control is 4.0~6.5 after balosam sizing agent.
4. a kind of production method for regenerating true qualities transfer printing paper, includes the preparation of slurry, it is characterised in that the system of the slurry The standby raw material used is true qualities wood pulp, masson pine and waste paper regenerated slurry, the true qualities wood pulp, masson pine And the consumption of waste paper regenerated slurry is:1:1:0.5, during slurrying, beating degree is controlled in 50~65 ° of SR, 4.0~6.0g of weight in wet base, concentration 2.7~3.4%, adjuvant is also added with the pulping process, the adjuvant is cationic rosin size sizing agent and sulfuric acid Aluminium, the consumption of the cationic rosin size sizing agent is the 0.4~0.5% of oven dry stock weight, and the consumption of the aluminum sulfate is over dry The 0.1~0.3% of weight is starched, the cationic rosin size sizing agent is made up of each raw material of following parts by weight:Esterified rosin 15~ 20 parts, modified rich 20~25 parts of horse rosin, 17~20 parts of Malin's acid resin, 8~10 parts of acetic acid, polyoxyethylene sorbitol acid anhydride three it is hard 10~15 parts of resin acid ester, 1- sulfydryls are for 3~5 parts of dodecane, 15~20 parts of dimethylaminoethyl methacrylate, potassium peroxydisulfate 2~5 parts, 16~25 parts of cetyl trimethyl ammonium halide, 13~15 parts of acrylamide, 100~120 parts of deionized water;
The preparation method of the cationic rosin size sizing agent is:First by esterified rosin, modified rich horse rosin, Malin's acid resin 160~170 DEG C are heated to, in advance melting, polyoxyethylene sorbitol acid anhydride tristearate, 1- sulfydryls are added in another heater For dodecane, dimethylaminoethyl methacrylate, cetyl trimethyl ammonium halide, half deionized water, be heated to 60~70 DEG C, stir, be slowly dropped into potassium peroxydisulfate, be added followed by acetic acid and acrylamide, will finally melt in advance Esterified rosin, modified rich horse rosin, Malin's acid resin are mixed with said mixture, second half deionized water are added, through glue Body grinder is ground, and obtains cationic rosin size sizing agent.
CN201610461830.3A 2016-06-23 2016-06-23 A kind of production method for regenerating true qualities transfer printing paper Expired - Fee Related CN106120435B (en)

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CN108316045B (en) * 2017-12-28 2020-02-28 仙鹤股份有限公司 Natural color transfer printing base paper production method
CN108252156A (en) * 2018-01-09 2018-07-06 广东鼎全新材料股份有限公司 Regenerated papermaking Coating digital thermal transfer printing paper and preparation method

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