CN110345816A - A kind of MULTILAYER COMPOSITE camouflage cloth of high thermal inertia - Google Patents

A kind of MULTILAYER COMPOSITE camouflage cloth of high thermal inertia Download PDF

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Publication number
CN110345816A
CN110345816A CN201910641525.6A CN201910641525A CN110345816A CN 110345816 A CN110345816 A CN 110345816A CN 201910641525 A CN201910641525 A CN 201910641525A CN 110345816 A CN110345816 A CN 110345816A
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phase
camouflage
coating
cloth
change
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CN110345816B (en
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何�雄
何欣怡
王娜
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SICHUAN HANGLONG AVIATION INDUSTRIAL Co Ltd
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SICHUAN HANGLONG AVIATION INDUSTRIAL Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D191/00Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
    • C09D191/06Waxes
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • C23C14/16Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • C23C14/20Metallic material, boron or silicon on organic substrates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24Vacuum evaporation
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41HARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H3/00Camouflage, i.e. means or methods for concealment or disguise
    • F41H3/02Flexible, e.g. fabric covers, e.g. screens, nets characterised by their material or structure
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Textile Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Engineering & Computer Science (AREA)
  • Laminated Bodies (AREA)
  • Aiming, Guidance, Guns With A Light Source, Armor, Camouflage, And Targets (AREA)

Abstract

The present invention provides a kind of MULTILAYER COMPOSITEs of high thermal inertia to pretend cloth, is related to camouflage material field.A kind of MULTILAYER COMPOSITE camouflage cloth of high thermal inertia, including base fabric, the two sides of the base fabric are equipped with phase-change material coating, wherein a phase-change material coating is equipped with camouflage coating far from the side of the base fabric, another phase-change material coating is equipped with thermal infrared highly-reflective coating far from the side of base fabric.The present invention has the pseudo- reload request being suitable under varying environment, and near-infrared and thermal infrared camouflage performance can be achieved at the same time, reduce the technical effect for the probability that target is detected by infrared detector.

Description

A kind of MULTILAYER COMPOSITE camouflage cloth of high thermal inertia
Technical field
The invention belongs to camouflage material fields, specifically, being related to the optics camouflage cloth compatible with thermal infrared.
Background technique
Camouflage is to improve equipment, personnel's battlefield survival, promotes the effective means of army's overall combat effectiveness.From On wave band point, camouflage be divided into optical camouflage (including visible light wave range 380nm-760nm and near infrared band 760nm-1200nm), Thermal infrared camouflage (3 μm -5 μm and 8 μm -12 μm) and radar deception etc..Camouflage painting cloth is the basis of camouflage equipment, and tradition is pseudo- Dress cloth is only applicable in the camouflage of target of visible light wave range (380nm-760nm), can only tackle the scouting of visible light wave range, does not have close The camouflage performance of infrared band and Thermal infrared bands.Development for the multibands Intelligence Technology such as optics on battlefield and thermal infrared is answered With the development of the optics camouflage painting cloth compatible with thermal infrared is very urgent.
There are larger differences for the infrared signature of natural background and artificial material, one reason for this is that due to natural back Contain water in scape, causes it with biggish thermal inertia.Thermal inertia is both the physical quantity for measuring substance thermal inertia size, and degree The physical quantity for measuring heat transfer rate on different medium interface, shows as hot object and is restored to its ambient enviroment thermal equilibrium state Preceding time lag, its energy exchange between object and environment is related, to influence the temperature change of object and infrared Radiation characteristic.Under same heating condition, the thermal inertia of usual camouflage material or equipment is smaller than the thermal inertia of background locating for it, Temperature fluctuation ratio background is big in one day, is easy to form the apparent temperature difference with background, to easily be detected by infrared detector.
Summary of the invention
For deficiency above-mentioned in the prior art, the purpose of the present invention is to provide a kind of MULTILAYER COMPOSITE of high thermal inertia puppets Cloth is filled, while realizing near-infrared and thermal infrared camouflage performance, the pseudo- reload request suitable for varying environment condition.
In order to achieve the above object, the solution that the present invention uses is:
A kind of MULTILAYER COMPOSITE camouflage cloth of high thermal inertia, including base fabric, the two sides of the base fabric are equipped with phase-change material painting Layer, wherein a phase-change material coating is equipped with camouflage coating far from the side of base fabric, another phase-change material coating is separate The side of base fabric is equipped with thermal infrared highly-reflective coating.
Preferably, the phase-change material coating includes composite phase-change wax, adhesive and solvent, and the composite phase-change wax includes 5 DEG C of phase-change wax, 10 DEG C of phase-change wax, 15 DEG C of phase-change wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax and 30 DEG C of phase-change wax, the adhesive For polyurethane resin or acrylate, the solvent is one or more of in dimethylformamide, toluene and dimethylbenzene.
Preferably, each component of the phase-change material coating by weight, 5 DEG C of phase-change wax 3%-8%, 10 DEG C of phase-change wax 8%-12%, 15 DEG C of phase-change wax 3%-8%, 20 DEG C of phase-change wax 8%-12%, 25 DEG C of phase-change wax 10%-15%, 30 DEG C of phase-change wax 3%-8%, adhesive 35%-60%, solvent 1%-10%.
Preferably, the camouflage coating is green camouflage coating or ashen camouflage coating, or by green camouflage coating and soil The camouflage painting coating that color camouflage coating is constituted.
Preferably, the thermal infrared highly-reflective coating is prepared by vacuum evaporatation.
Preferably, base fabric two sides are coated with phase-change material coating, one layer of phase-change material coating therein is far from base fabric The step of side coats camouflage coating, obtains just making camouflage cloth, vacuum evaporation coating film preparation thermal infrared highly-reflective coating is, with first System camouflage cloth is substrate, and metallic aluminium is target, and another layer of phase-change material coating plates aluminium film far from the side of base fabric, then in aluminium film A upper plating protective layer, protective layer NiCr;The operating parameter of vacuum evaporatation is background vacuum: 2.0 × 10-3Pa- 1.0×10-4Pa, Ar flow: 30Sccm, sputtering power: 500W, sputtering time: metallic aluminium 15min, NiCr 5min.
Preferably, the fabric in the base fabric face selects high-strength Oxford cloth, woven dacron or blend polyester cloth.
Preferably, the phase-change material coating with a thickness of 20um-30um.
Preferably, the aluminium film with a thickness of 0.012um-0.015um.
The beneficial effects of the present invention are:
(1) composite phase-change wax is made of the phase-change wax of different phase transition temperatures, so that camouflage cloth is in biggish environment temperature wave The certain temperature range of dynamic lower holding, improves the thermal inertia of camouflage cloth, composite phase-change wax is utilized to reduce camouflage cloth and nature ring The temperature difference in border makes to pretend cloth and the infrared intensity difference of natural environment is smaller;
(2) phase-change material coating layer thickness is 20um-30um, and phase transformation coating material phase transformation effect is good at this time, flexibility is good, shape At the easy plated film of camouflage cloth;If phase-change material coating is too thin, phase transformation effect is poor;If coating is too thick, camouflage cloth flexibility is poor, plated film Easy to fall off, service performance is poor;
(3) the phase-change material coating metal-coated membrane by vacuum evaporatation on camouflage cloth, operation is easy, film is pure Spend it is high, high-quality and rate of film build is high, while thickness of metal film be 0.012um-0.015um, one side metal film it is infrared instead Penetrate that ability is strong, the adhesive force of another aspect metal film is strong, flexibility is good, resistance to rubbing;
(4) add NiCr layers of plating on metal film, shield to aluminium film.
Specific embodiment
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention Technical solution be clearly and completely described.The person that is not specified actual conditions in embodiment, according to normal conditions or manufacturer builds The condition of view carries out.Reagents or instruments used without specified manufacturer is the conventional production that can be obtained by commercially available purchase Product.
A kind of MULTILAYER COMPOSITE camouflage cloth of high thermal inertia provided in an embodiment of the present invention is specifically described below.
Embodiment 1
A kind of MULTILAYER COMPOSITE of high thermal inertia pretends cloth, including base fabric, and the two sides of base fabric are equipped with phase-change material coating, and two The high anti-coating of camouflage coating, thermal infrared is respectively provided on the outside of phase-change material coating.
Camouflage coating is made of Camouflage Coatings, and Camouflage Coatings include pigment, adhesive and solvent, and pigment includes Chrome oxide green, oxidation chrome yellow, titanium white, macromolecular is red and high reflection is black, and adhesive is polyurethane resin, and solvent is dimethyl formyl Amine, by weight, chrome oxide green 15% aoxidizes chrome yellow 20% to each component, and titanium white 10%, macromolecular red 0.2%, high reflection is black 1%, polyurethane resin 30%, dimethylformamide 8%.
The preparation method of Camouflage Coatings is, by chrome oxide green 15%, to aoxidize chrome yellow 11%, titanium white 10%, macromolecular Red 0.2%, dimethylformamide 8% is added in the polyurethane resin of high reflection black 1% and 15% after evenly mixing, by above-mentioned mixing Object is placed in three-roll grinder and grinds 2 times, and the mill base after grinding is mixed with 15% polyurethane resin, is placed in high speed disperser 10min is stirred, mixing speed 6000r/min obtains Camouflage Coatings after stirring.
Phase-change material coating includes composite phase-change wax, adhesive and solvent, and composite phase-change wax includes 5 DEG C of phase-change wax, and 10 DEG C Phase-change wax, 15 DEG C of phase-change wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax, 30 DEG C of phase-change wax, adhesive is polyurethane resin, and solvent is Dimethylformamide.Each component by weight, 5 DEG C of phase-change wax 3%, 10 DEG C of phase-change wax 8%, 15 DEG C of phase-change wax 3%, 20 DEG C of phase transformations Wax 8%, 25 DEG C of phase-change wax 10%, 30 DEG C of phase-change wax 3%, adhesive 35%, solvent 1%.Wherein, 5 DEG C of phase-change wax, 10 DEG C of phase transformations Wax, 15 DEG C of phase-change wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax, 30 DEG C of phase-change wax refer to that the phase transition temperature of phase-change wax is respectively 5 DEG C, 10 ℃,15℃,20℃,25℃,30℃.Phase-change material coating with a thickness of 20um.
Base fabric selects high-strength Oxford cloth.
Base fabric two sides are coated with phase-change material coating, one layer of phase-change material coating therein is coated far from the side of base fabric Camouflage paint obtains just making camouflage cloth, and the high anti-coating of thermal infrared is plated on first system camouflage cloth using vacuum evaporatation.With Just system camouflage cloth is substrate, and metallic aluminium is target, and another layer of phase-change material coating plates aluminium film far from the side of base fabric, and aluminium film is thick Degree is 0.012um, and in order to improve the antioxygenic property of aluminium film, plating NiCr protective layer is added in aluminium film.
The operating parameter of vacuum evaporatation is background vacuum: 2.0 × 10-3Pa, Ar flow: 30Sccm sputters function Rate: 500W, sputtering time: metallic aluminium 15min, NiCr 5min.
Embodiment 2
A kind of MULTILAYER COMPOSITE of high thermal inertia pretends cloth, including base fabric, and the two sides of base fabric are equipped with phase-change material coating, and two The high anti-coating of camouflage coating, thermal infrared is respectively provided on the outside of phase-change material coating.
Camouflage coating is made of Camouflage Coatings, and Camouflage Coatings include pigment, adhesive and solvent, and pigment includes Chrome oxide green, oxidation chrome yellow, titanium white, macromolecular is red and high reflection is black, and adhesive is polyurethane resin, and solvent is dimethyl formyl Amine, by weight, chrome oxide green 20% aoxidizes chrome yellow 15% to each component, and titanium white 12%, macromolecular red 0.4%, high reflection is black 2%, polyurethane resin 40%, dimethylformamide 10%.
The preparation method of Camouflage Coatings is, by chrome oxide green 20%, to aoxidize chrome yellow 15%, titanium white 12%, macromolecular Red 0.4%, dimethylformamide 10% is added in the polyurethane resin of high reflection black 2% and 20% after evenly mixing, will be above-mentioned mixed Conjunction object, which is placed in three-roll grinder, to be ground 3 times, and the mill base after grinding is mixed with 20% polyurethane resin, is placed in high speed disperser Middle stirring 15min, mixing speed 6000r/min obtain Camouflage Coatings after stirring.
Phase-change material coating includes composite phase-change wax, adhesive and solvent, and composite phase-change wax includes 5 DEG C of phase-change wax, and 10 DEG C Phase-change wax, 15 DEG C of phase-change wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax, 30 DEG C of phase-change wax, adhesive are acrylate, and solvent is first Benzene.Each component by weight, 5 DEG C of phase-change wax 5%, 10 DEG C of phase-change wax 10%, 15 DEG C of phase-change wax 5%, 20 DEG C of phase-change wax 10%, 25 DEG C phase-change wax 12%, 30 DEG C of phase-change wax 5%, adhesive 45%, solvent 5%.Wherein, 5 DEG C of phase-change wax, 10 DEG C of phase-change wax, 15 DEG C Phase-change wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax, 30 DEG C of phase-change wax refer to the phase transition temperature of phase-change wax be respectively 5 DEG C, 10 DEG C, 15 DEG C, 20℃,25℃,30℃.Phase-change material coating with a thickness of 25um.
Base fabric selects woven dacron.
Base fabric two sides are coated with phase-change material coating, one layer of phase-change material coating therein is coated far from the side of base fabric Camouflage paint obtains just making camouflage cloth, and the high anti-coating of thermal infrared is plated on first system camouflage cloth using vacuum evaporatation.With Just system camouflage cloth is substrate, and metallic aluminium is target, and another layer of phase-change material coating plates aluminium film far from the side of base fabric, and aluminium film is thick Degree is 0.013um, and in order to improve the antioxygenic property of aluminium film, plating NiCr protective layer is added in aluminium film.
The operating parameter of vacuum evaporatation is background vacuum: it is higher than 2.0 × 10-3Pa, Ar flow: 30Sccm, Sputtering power: 500W, sputtering time: metallic aluminium 15min, NiCr 5min.
Embodiment 3
A kind of MULTILAYER COMPOSITE of high thermal inertia pretends cloth, including base fabric, and the two sides of base fabric are equipped with phase-change material coating, and two The high anti-coating of camouflage coating, thermal infrared is respectively provided on the outside of phase-change material coating.
Camouflage coating is made of Camouflage Coatings, and Camouflage Coatings include pigment, adhesive and solvent, and pigment includes Chrome oxide green, oxidation chrome yellow, titanium white, macromolecular is red and high reflection is black, and adhesive is polyurethane resin, and solvent is dimethyl formyl Amine, by weight, chrome oxide green 24% aoxidizes chrome yellow 20% to each component, and titanium white 15%, macromolecular red 0.5%, high reflection is black 5%, polyurethane resin 50%, dimethylformamide 15%.
The preparation method of Camouflage Coatings is, by chrome oxide green 24%, to aoxidize chrome yellow 20%, titanium white 15%, macromolecular Red 0.5%, dimethylformamide 15% is added in the polyurethane resin of high reflection black 5% and 25% after evenly mixing, will be above-mentioned mixed Conjunction object, which is placed in three-roll grinder, to be ground 3 times, and the mill base after grinding is mixed with 25% polyurethane resin, is placed in high speed disperser Middle stirring 15min, mixing speed 6000r/min obtain Camouflage Coatings after stirring.
Phase-change material coating includes composite phase-change wax, adhesive and solvent, and composite phase-change wax includes 5 DEG C of phase-change wax, and 10 DEG C Phase-change wax, 15 DEG C of phase-change wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax, 30 DEG C of phase-change wax, adhesive is polyurethane resin, and solvent is Dimethylbenzene.Each component by weight, 5 DEG C of phase-change wax 8%, 10 DEG C of phase-change wax 12%, 15 DEG C of phase-change wax 8%, 20 DEG C of phase-change wax 12%, 25 DEG C of phase-change wax 15%, 30 DEG C of phase-change wax 8%, adhesive 60%, solvent 10%.Wherein, 5 DEG C of phase-change wax, 10 DEG C of phase transformations Wax, 15 DEG C of phase-change wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax, 30 DEG C of phase-change wax refer to that the phase transition temperature of phase-change wax is respectively 5 DEG C, 10 ℃,15℃,20℃,25℃,30℃.Phase-change material coating with a thickness of 30um.
Base fabric selects polycot blend fabric.
Base fabric two sides are coated with phase-change material coating, one layer of phase-change material coating therein is coated far from the side of base fabric Camouflage paint obtains just making camouflage cloth, and the high anti-coating of thermal infrared is plated on first system camouflage cloth using vacuum evaporatation.With Just system camouflage cloth is substrate, and metallic aluminium is target, and another layer of phase-change material coating plates aluminium film far from the side of base fabric, and aluminium film is thick Degree is 0.015um, and in order to improve the antioxygenic property of aluminium film, plating NiCr protective layer is added in aluminium film.
The operating parameter of vacuum evaporatation is background vacuum: 4.0 × 10-3Pa, Ar flow: 30Sccm sputters function Rate: 500W, sputtering time: metallic aluminium 15min, NiCr 5min.
Embodiment 4
A kind of MULTILAYER COMPOSITE of high thermal inertia pretends cloth, including base fabric, and the two sides of base fabric are equipped with phase-change material coating, and two The high anti-coating of camouflage coating, thermal infrared is respectively provided on the outside of phase-change material coating.
Camouflage coating is made of ashen camouflage paint, and ashen camouflage paint includes pigment, adhesive and solvent, and pigment includes Iron oxide red, iron oxide yellow, titanium white and phthalocyanine blue, adhesive are polyurethane resin, and solvent is dimethylformamide, and each component is pressed Poidometer, iron oxide red 10%, iron oxide yellow 18%, titanium white 15%, phthalocyanine blue 1%, polyurethane resin 38%, dimethyl formyl Amine 12%.
The preparation method of ashen camouflage paint is, by iron oxide red 10%, iron oxide yellow 18%, titanium white 15%, phthalocyanine blue Dimethylformamide 12% is added in 1% and 19% polyurethane resin after evenly mixing, and said mixture is placed in the grinding of three rollers It is ground 2 times in machine, the mill base after grinding is mixed with 19% polyurethane resin, is placed in high speed disperser and is stirred 10min, is stirred Speed 6000r/min obtains ashen camouflage paint after stirring.
Phase-change material coating includes composite phase-change wax, adhesive and solvent, and composite phase-change wax includes 5 DEG C of phase-change wax, and 10 DEG C Phase-change wax, 15 DEG C of phase-change wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax, 30 DEG C of phase-change wax, adhesive is polyurethane resin, and solvent is Dimethylformamide.Each component by weight, 5 DEG C of phase-change wax 3%, 10 DEG C of phase-change wax 8%, 15 DEG C of phase-change wax 3%, 20 DEG C of phase transformations Wax 8%, 25 DEG C of phase-change wax 10%, 30 DEG C of phase-change wax 3%, adhesive 35%, solvent 1%.Wherein, 5 DEG C of phase-change wax, 10 DEG C of phase transformations Wax, 15 DEG C of phase-change wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax, 30 DEG C of phase-change wax refer to that the phase transition temperature of phase-change wax is respectively 5 DEG C, 10 ℃,15℃,20℃,25℃,30℃.Phase-change material coating with a thickness of 20um.
Base fabric selects high-strength Oxford cloth.
Base fabric two sides are coated with phase-change material coating, one layer of phase-change material coating therein is coated far from the side of base fabric Camouflage paint obtains just making camouflage cloth, and the high anti-coating of thermal infrared is plated on first system camouflage cloth using vacuum evaporatation.With Just system camouflage cloth is substrate, and metallic aluminium is target, and another layer of phase-change material coating plates aluminium film far from the side of base fabric, and aluminium film is thick Degree is 0.012um, and in order to improve the antioxygenic property of aluminium film, plating NiCr protective layer is added in aluminium film.
The operating parameter of vacuum evaporatation is background vacuum: it is higher than 2.0 × 10-3Pa, Ar flow: 30Sccm, Sputtering power: 500W, sputtering time: metallic aluminium 15min, NiCr 5min.
Embodiment 5
A kind of MULTILAYER COMPOSITE of high thermal inertia pretends cloth, including base fabric, and the two sides of base fabric are equipped with phase-change material coating, and two The high anti-coating of camouflage coating, thermal infrared is respectively provided on the outside of phase-change material coating.
Camouflage coating is made of ashen camouflage paint, and ashen camouflage paint includes pigment, adhesive and solvent, and pigment includes Iron oxide red, iron oxide yellow, titanium white and phthalocyanine blue, adhesive are polyurethane resin, and solvent is dimethylformamide, and each component is pressed Poidometer, iron oxide red 12%, iron oxide yellow 19%, titanium white 18%, phthalocyanine blue 1%, polyurethane resin 38%, dimethyl formyl Amine 24%.
The preparation method of ashen camouflage paint is, by iron oxide red 12%, iron oxide yellow 19%, titanium white 18%, phthalocyanine blue Dimethylformamide 24% is added in 2% and 19% polyurethane resin after evenly mixing, and said mixture is placed in the grinding of three rollers It is ground 2 times in machine, the mill base after grinding is mixed with 19% polyurethane resin, is placed in high speed disperser and is stirred 10min, is stirred Speed 6000r/min obtains ashen camouflage paint after stirring.
Phase-change material coating includes composite phase-change wax, adhesive and solvent, and composite phase-change wax includes 5 DEG C of phase-change wax, and 10 DEG C Phase-change wax, 15 DEG C of phase-change wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax, 30 DEG C of phase-change wax, adhesive is polyurethane resin, and solvent is 60% dimethylformamide and 40% toluene.Each component by weight, 5 DEG C of phase-change wax 5%, 10 DEG C of phase-change wax 10%, 15 DEG C of phases Become wax 5%, 20 DEG C of phase-change wax 10%, 25 DEG C of phase-change wax 12%, 30 DEG C of phase-change wax 5%, adhesive 45%, solvent 5%.Wherein, 5 DEG C phase-change wax, 10 DEG C of phase-change wax, 15 DEG C of phase-change wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax, 30 DEG C of phase-change wax refer to the phase transformation of phase-change wax Temperature is respectively 5 DEG C, 10 DEG C, 15 DEG C, 20 DEG C, 25 DEG C, 30 DEG C.Phase-change material coating with a thickness of 25um.
Base fabric selects woven dacron.
Base fabric two sides are coated with phase-change material coating, one layer of phase-change material coating therein is coated far from the side of base fabric Camouflage paint obtains just making camouflage cloth, and the high anti-coating of thermal infrared is plated on first system camouflage cloth using vacuum evaporatation.With Just system camouflage cloth is substrate, and metallic aluminium is target, and another layer of phase-change material coating plates aluminium film far from the side of base fabric, and aluminium film is thick Degree is 0.013um, and in order to improve the antioxygenic property of aluminium film, plating NiCr protective layer is added in aluminium film.
The operating parameter of vacuum evaporatation is background vacuum: 7.0 × 10-3Pa, Ar flow: 30Sccm sputters function Rate: 500W, sputtering time: metallic aluminium 15min, NiCr 5min.
Embodiment 6
A kind of MULTILAYER COMPOSITE of high thermal inertia pretends cloth, including base fabric, and the two sides of base fabric are equipped with phase-change material coating, and two The high anti-coating of camouflage coating, thermal infrared is respectively provided on the outside of phase-change material coating.
Camouflage coating is made of ashen camouflage paint, and ashen camouflage paint includes pigment, adhesive and solvent, and pigment includes Iron oxide red, iron oxide yellow, titanium white and phthalocyanine blue, adhesive are polyurethane resin, and solvent is dimethylformamide, and each component is pressed Poidometer, iron oxide red 14%, iron oxide yellow 20%, titanium white 20%, phthalocyanine blue 2%, polyurethane resin 40%, dimethyl formyl Amine 40%.
The preparation method of ashen camouflage paint is, by iron oxide red 14%, iron oxide yellow 20%, titanium white 20%, phthalocyanine blue Dimethylformamide 20% is added in 2% and 20% polyurethane resin after evenly mixing, and said mixture is placed in the grinding of three rollers It is ground 2 times in machine, the mill base after grinding is mixed with 20% polyurethane resin, is placed in high speed disperser and is stirred 10min, is stirred Speed 6000r/min obtains ashen camouflage paint after stirring.
Phase-change material coating includes composite phase-change wax, adhesive and solvent, and composite phase-change wax includes 5 DEG C of phase-change wax, and 10 DEG C Phase-change wax, 15 DEG C of phase-change wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax, 30 DEG C of phase-change wax, adhesive is polyurethane resin, and solvent is 60% dimethylformamide, 25% toluene and 15% dimethylbenzene.Each component by weight, 5 DEG C of phase-change wax 8%, 10 DEG C of phase-change wax 12%, 15 DEG C of phase-change wax 8%, 20 DEG C of phase-change wax 12%, 25 DEG C of phase-change wax 15%, 30 DEG C of phase-change wax 8%, adhesive 60% is molten Agent 10%.Wherein, 5 DEG C of phase-change wax, 10 DEG C of phase-change wax, 15 DEG C of phase-change wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax, 30 DEG C of phase-change wax The phase transition temperature for referring to phase-change wax is respectively 5 DEG C, 10 DEG C, 15 DEG C, 20 DEG C, 25 DEG C, 30 DEG C.Phase-change material coating with a thickness of 30um。
Base fabric selects polycot blend fabric.
Base fabric two sides are coated with phase-change material coating, one layer of phase-change material coating therein is coated far from the side of base fabric Camouflage paint obtains just making camouflage cloth, and the high anti-coating of thermal infrared is plated on first system camouflage cloth using vacuum evaporatation.With Just system camouflage cloth is substrate, and metallic aluminium is target, and another layer of phase-change material coating plates aluminium film far from the side of base fabric, and aluminium film is thick Degree is 0.015um, and in order to improve the antioxygenic property of aluminium film, plating NiCr protective layer is added in aluminium film.
The operating parameter of vacuum evaporatation is background vacuum: it is higher than 2.0 × 10-3Pa, Ar flow: 30Sccm, Sputtering power: 500W, sputtering time: metallic aluminium 15min, NiCr 5min.
Embodiment 7
A kind of MULTILAYER COMPOSITE of high thermal inertia pretends cloth, including base fabric, and the two sides of base fabric are equipped with phase-change material coating, and two The high anti-coating of camouflage coating, thermal infrared is respectively provided on the outside of phase-change material coating.
Camouflage coating is made of ashen camouflage paint, and ashen camouflage paint includes pigment, adhesive and solvent, and pigment includes Iron oxide red, iron oxide yellow, titanium white and phthalocyanine blue, adhesive are polyurethane resin, and solvent is dimethylformamide, and each component is pressed Poidometer, iron oxide red 14%, iron oxide yellow 20%, titanium white 20%, phthalocyanine blue 2%, polyurethane resin 40%, dimethyl formyl Amine 40%.
The preparation method of ashen camouflage paint is, by iron oxide red 14%, iron oxide yellow 20%, titanium white 20%, phthalocyanine blue Dimethylformamide 20% is added in 2% and 20% polyurethane resin after evenly mixing, and said mixture is placed in the grinding of three rollers It is ground 2 times in machine, the mill base after grinding is mixed with 20% polyurethane resin, is placed in high speed disperser and is stirred 10min, is stirred Speed 6000r/min obtains ashen camouflage paint after stirring.
Phase-change material coating includes composite phase-change wax, adhesive and solvent, and composite phase-change wax includes 5 DEG C of phase-change wax, and 10 DEG C Phase-change wax, 15 DEG C of phase-change wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax, 30 DEG C of phase-change wax, adhesive is polyurethane resin, and solvent is 70% toluene and 30% dimethylbenzene.Each component by weight, 5 DEG C of phase-change wax 8%, 10 DEG C of phase-change wax 12%, 15 DEG C of phase-change wax 8%, 20 DEG C of phase-change wax 12%, 25 DEG C of phase-change wax 15%, 30 DEG C of phase-change wax 8%, adhesive 60%, solvent 10%.Wherein, 5 DEG C Phase-change wax, 10 DEG C of phase-change wax, 15 DEG C of phase-change wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax, 30 DEG C of phase-change wax refer to the phase alternating temperature of phase-change wax Degree is respectively 5 DEG C, 10 DEG C, 15 DEG C, 20 DEG C, 25 DEG C, 30 DEG C.Phase-change material coating with a thickness of 30um.
Base fabric selects polycot blend fabric.
Base fabric two sides are coated with phase-change material coating, one layer of phase-change material coating therein is coated far from the side of base fabric Camouflage paint obtains just making camouflage cloth, and the high anti-coating of thermal infrared is plated on first system camouflage cloth using vacuum evaporatation.With Just system camouflage cloth is substrate, and metallic aluminium is target, and another layer of phase-change material coating plates aluminium film far from the side of base fabric, and aluminium film is thick Degree is 0.015um, and in order to improve the antioxygenic property of aluminium film, plating NiCr protective layer is added in aluminium film.
The operating parameter of vacuum evaporatation is background vacuum: 10-4Pa, Ar flow: 30Sccm, sputtering power: 500W, sputtering time: metallic aluminium 15min, NiCr 5min.
Embodiment 8
The present embodiment the difference from embodiment 1 is that, camouflage coating is made of Camouflage Coatings and ashen camouflage paint Camouflage color spot camouflage coating.The composition of camouflage color spot is according to GJB 4004-2000 " army material distortion pattern painting atlas ".
The each component of each component and accounting of Camouflage Coatings, preparation method and the Camouflage Coatings in embodiment 1 And accounting, preparation method are identical.
The each component of each component and accounting of ashen camouflage paint, preparation method and the ashen camouflage paint in embodiment 4 And accounting, preparation method are identical.
Test method
Although also alternatively using ordinary skill people it should be understood that certain methods and apparatus are described below Member determines applicable any method or equipment.
Experimental example 1
It is evaporated in vacuo film experiment
Reflectivity of the first system camouflage cloth of different optics base fabrics in infrared band, the hemisphere measured are tested using AE radiometer The results are shown in Table 1 by emissivity ε h.
The hemispherical emissivity of aluminizer on the first system camouflage cloth of the different optics base fabrics of table 1
Number Just system camouflage cloth Film thickness (um) Emissivity
1 Brown just makes camouflage cloth 0 0.74
2 Brown just makes camouflage cloth plated film 0.013 0.44
3 White just system camouflage cloth 0 0.73
4 White just system camouflage cloth plated film 0.013 0.40
5 Green just system camouflage cloth 0 0.84
6 Green just system camouflage cloth plated film 0.013 0.27
The result shows that on the first system camouflage cloth that same color base fabric is constituted, after filming process, the camouflage cloth of formation Emissivity be below it is uncoated just system camouflage cloth.
Experimental example 2
Camouflage effectiveness analysis
Camouflage cloth camouflage effectiveness can be judged by the degree of closeness of camouflaged target and background at present, Camouflage effectiveness can be passed through This index carries out quantitative analysis.
Infrared camouflage efficiency refers to that within a certain period of time the apparent temperature difference of camouflaged target and background is less than certain temperature Spend time percentage γ shared by difference △ T:
Wherein: △ T is poor for the apparent temperature of target and background;△T0Limiting temperature to realize camouflage is poor.△T0It is artificial The numerical value of setting can set different △ T according to different pseudo- reload requests0Value, for example, according to the regulation in relation to standard, △ T0 It can use 4,7,10 3 different grades, be more than this numerical value, then it is assumed that in this △ T0Requirement under, target is not pretended to imitate Fruit.
Using the resulting MULTILAYER COMPOSITE of embodiment 1 camouflage cloth and common camouflage cloth as experimental subjects.It is with outdoor elements Background, becomes a fine day cloudless, gentle breeze on June 10th, 2019, and 30.5 DEG C of highest environment temperature, 18.7 DEG C of minimum environment temperature.
MULTILAYER COMPOSITE pretends the Camouflage effectiveness of cloth and common camouflage cloth, and the results are shown in Table 2 for experiment.
The Camouflage effectiveness of the different camouflage cloth of table 2
It can be seen that working as △ T0When value is larger, in different time period, Camouflage effectiveness is higher for same sample, be due to The higher reason of limiting temperature difference of artificial settings;As △ T0When being set as 4 DEG C, within daytime and night-time hours, MULTILAYER COMPOSITE The equal Camouflage effectiveness of camouflage cloth is above the Camouflage effectiveness of common camouflage cloth, is since phase-change material layers can pretend MULTILAYER COMPOSITE Cloth carries out temperature regulation in the temperature difference in different time periods, there is preferable thermal adaptability, and MULTILAYER COMPOSITE pretends the apparent temperature of cloth Degree and the apparent temperature of background are close, i.e., Camouflage effectiveness is high, and MULTILAYER COMPOSITE pretends the infrared emittance of cloth and the infrared hair of background The control of rate difference is penetrated to minimum, so that MULTILAYER COMPOSITE camouflage cloth reaches camouflaging purpose, has benefited from different phase transformations in composite phase-change wax The combination matching of the phase-change wax of temperature.
In conclusion the present invention is made of the high anti-coatings combine of base fabric, phase-change material coating, camouflage coating and thermal infrared The MULTILAYER COMPOSITE of high thermal inertia pretends cloth, camouflage coating can according to different component in Camouflage Coatings and ashen camouflage paint into Row matches and suitable for the pseudo- reload request under varying environment;High thermal inertia MULTILAYER COMPOSITE camouflage cloth in the present invention can be achieved at the same time Near-infrared and thermal infrared camouflage performance;MULTILAYER COMPOSITE camouflage cloth and background environment have lower temperature difference, reduce target The probability detected by infrared detector;Phase-change material coating layer thickness is 20-30um, at this time phase transformation coating material phase transformation effect Well, the easy plated film of camouflage cloth that flexibility is good, is formed;If phase-change material coating is too thin, phase transformation effect is poor;If coating is too thick, camouflage Cloth flexibility is poor, and plated film is easy to fall off, and service performance is poor;Pass through phase-change material coating plating of the vacuum evaporatation on camouflage cloth Metal film, operation is easy, film is with high purity, high-quality and rate of film build is high, while thickness of metal film is 0.012um- The infrared external reflection ability of 0.015um, one side metal film are strong, and the adhesive force of another aspect metal film is strong, flexibility is good, resistance to rubs It rubs with the hands;Add NiCr layers of plating on metal film, shields to aluminium film.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, made any to repair Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (9)

1. a kind of MULTILAYER COMPOSITE of high thermal inertia pretends cloth, which is characterized in that including base fabric, the two sides of the base fabric are equipped with phase Become material coating, wherein a phase-change material coating is equipped with camouflage coating, another phase-change material far from the side of base fabric Coating is equipped with thermal infrared highly-reflective coating far from the side of base fabric.
2. the MULTILAYER COMPOSITE of high thermal inertia according to claim 1 pretends cloth, which is characterized in that the phase-change material coating Including composite phase-change wax, adhesive and solvent, the composite phase-change wax includes 5 DEG C of phase-change wax, 10 DEG C of phase-change wax, 15 DEG C of phase transformations Wax, 20 DEG C of phase-change wax, 25 DEG C of phase-change wax and 30 DEG C of phase-change wax, the adhesive be polyurethane resin or acrylate, it is described molten Agent is one or more of in dimethylformamide, toluene and dimethylbenzene.
3. the MULTILAYER COMPOSITE of high thermal inertia according to claim 2 pretends cloth, which is characterized in that the phase-change material coating Each component by weight, 5 DEG C of phase-change wax 3%-8%, 10 DEG C of phase-change wax 8%-12%, 15 DEG C of phase-change wax 3%-8%, 20 DEG C of phases Become wax 8%-12%, 25 DEG C of phase-change wax 10%-15%, 30 DEG C of phase-change wax 3%-8%, adhesive 35%-60%, solvent 1%- 10%.
4. the MULTILAYER COMPOSITE of high thermal inertia according to claim 1 pretends cloth, which is characterized in that the camouflage coating is green Color camouflage coating or ashen camouflage coating, or the camouflage painting coating being made of green camouflage coating and ashen camouflage coating.
5. the MULTILAYER COMPOSITE of high thermal inertia as claimed in any of claims 1 to 4 pretends cloth, which is characterized in that institute Thermal infrared highly-reflective coating is stated to be prepared by vacuum evaporatation.
6. the MULTILAYER COMPOSITE of high thermal inertia according to claim 5 pretends cloth, which is characterized in that be coated with base fabric two sides Phase-change material coating, one layer of phase-change material coating therein coat camouflage coating far from the side of base fabric, obtain just making camouflage cloth, The step of vacuum evaporation coating film preparation thermal infrared highly-reflective coating is that, using first system camouflage cloth as substrate, metallic aluminium is target, another Layer phase-change material coating plates aluminium film far from the side of base fabric, then a protective layer is plated in aluminium film, protective layer NiCr;Vacuum The operating parameter of evaporation coating method is background vacuum: 2.0 × 10-3Pa-1.0×10-4Pa, Ar flow: 30Sccm sputters function Rate: 500W, sputtering time: metallic aluminium 15min, NiCr5min.
7. the MULTILAYER COMPOSITE of high thermal inertia as claimed in any of claims 1 to 6 pretends cloth, which is characterized in that institute The fabric for stating base fabric face selects high-strength Oxford cloth, woven dacron or blend polyester cloth.
8. the MULTILAYER COMPOSITE of high thermal inertia according to claim 7 pretends cloth, which is characterized in that the phase-change material coating With a thickness of 20um-30um.
9. the MULTILAYER COMPOSITE of high thermal inertia according to claim 8 pretends cloth, which is characterized in that the aluminium film with a thickness of 0.012um-0.015um。
CN201910641525.6A 2019-07-16 2019-07-16 Multilayer composite camouflage cloth with high heat inertia Active CN110345816B (en)

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