CN110341280A - A kind of automatically cleaning aphalangia grain decorative plate and its preparation process - Google Patents

A kind of automatically cleaning aphalangia grain decorative plate and its preparation process Download PDF

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Publication number
CN110341280A
CN110341280A CN201910596498.5A CN201910596498A CN110341280A CN 110341280 A CN110341280 A CN 110341280A CN 201910596498 A CN201910596498 A CN 201910596498A CN 110341280 A CN110341280 A CN 110341280A
Authority
CN
China
Prior art keywords
paper
parts
aphalangia
gum dipped
cleaning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910596498.5A
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Chinese (zh)
Inventor
孙晓义
孙学民
高聪民
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHANGZHOU TIANRUN WOOD INDUSTRY Co Ltd
Original Assignee
CHANGZHOU TIANRUN WOOD INDUSTRY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHANGZHOU TIANRUN WOOD INDUSTRY Co Ltd filed Critical CHANGZHOU TIANRUN WOOD INDUSTRY Co Ltd
Priority to CN201910596498.5A priority Critical patent/CN110341280A/en
Publication of CN110341280A publication Critical patent/CN110341280A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/002Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B32B37/1018Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure using only vacuum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/46Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/47Condensation polymers of aldehydes or ketones
    • D21H17/48Condensation polymers of aldehydes or ketones with phenols
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • D21H19/385Oxides, hydroxides or carbonates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • D21H19/40Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/58Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B2038/0052Other operations not otherwise provided for
    • B32B2038/0076Curing, vulcanising, cross-linking

Abstract

The invention discloses a kind of automatically cleaning aphalangia grain decorative plates, including core plate and the facing paper being arranged on two surfaces of core plate;Wherein, core plate is several layers fireproof core board core plate made of heat pressing process;Facing paper is gum dipped paper, and external coating has automatic cleaning coating., the preparation of self-cleaning coating the present invention also provides a kind of preparation processes of automatically cleaning aphalangia grain decorative plate, it is characterised in that: steps are as follows: 1);2), the preparation of gum dipped paper;3), electronic beam curing;4), hot-forming;5) it, is packed in storage.The present invention has rational design, it is brushed using with self-cleaning coating, and processed by the way of electronic beam curing, decorative pattern is formed in coating surface, and there is self-cleaning function, simultaneously, electronic beam curing avoids the occurrence of environmental pollution, Environmental Safety, and panel weight is greatly reduced, it is cheap, it is easy to process.

Description

A kind of automatically cleaning aphalangia grain decorative plate and its preparation process
Technical field
The invention belongs to decorative panel fields, more specifically to a kind of automatically cleaning aphalangia grain decorative plate and its preparation work Skill.
Background technique
Decorative panel is used in decoration industry, has stability height, shock-proof shatter-resistant, resists cold heat-resisting and have fire resisting moisture-proof and resistance to cigarette burning Characteristic, density is mostly in 1.4-1.5g/cm3Between.The application range of decorative panel is extremely wide, the kitchen table in home life Face, bath lavatory compartment, wash platform, reception counters, the article placing cabinet, smallpox for washing one's hands and face table top, dining table, desk, door leaf or even public place Decorative panel production all can be used in plate, desk and office cubicles etc..
Decorative panel after long-term use, can be stained with many fingerprints, and the time, which has been grown, will cause pollution, be in addition exactly it is various not It easily wipes and can be sticked on decorative panel with sticking dirt, will result in the pollution of decorative panel in this way, aesthetic effect drops significantly It is low.
Summary of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of automatically cleaning aphalangia grain decorative plate and Its preparation process, design rationally, are brushed, and carried out by the way of electronic beam curing using with self-cleaning coating Processing forms decorative pattern in coating surface, and has self-cleaning function, meanwhile, electronic beam curing avoids the occurrence of environmental pollution, ring It ensures safety, and panel weight is greatly reduced, it is cheap, it is easy to process.
To achieve the above object, the present invention provides the following technical scheme that
A kind of automatically cleaning aphalangia grain decorative plate, it is characterised in that: including core plate and be arranged on two surfaces of core plate Facing paper;Wherein, core plate is several layers fireproof core board core plate made of heat pressing process;Facing paper is gum dipped paper, table Face is painted with automatic cleaning coating.
The present invention also provides a kind of preparation processes of automatically cleaning aphalangia grain decorative plate, it is characterised in that: steps are as follows:
1), the preparation of self-cleaning coating;
2), the preparation of gum dipped paper;
3), electronic beam curing;
4), hot-forming;
5) it, is packed in storage.
As a kind of technical solution of optimization, the component of the preparation of self-cleaning coating and its mass ratio of component: photocatalyst 60-100 parts of mixed liquor, 30-45 parts of silicone acrylic emulsion, 15-20 parts of fluorine carbon emulsion, auxiliary agent 4-8 parts hydrophobic, nano silica 3-13 Part, 5-10 parts of polysiloxanes, 5-15 parts of nanometer anatase titania, konilite 1-5 parts porous, 1-2 parts of ethylene glycol, thickener 0.5-1 parts, 1-3 parts of coalescing agent, 1-2 parts of dispersing agent, 1-2 parts of light stabilizer, 1-2 parts and water 50-70 parts of ultraviolet absorbing agent; High speed mixer is sufficiently mixed with the speed of 8000r/min to get self-cleaning coating.
As a kind of technical solution of optimization, the step of preparation of gum dipped paper is as follows: phenolic aldehyde glue is poured into steeping vat, dress Paper is adornd by steeping vat, the rubber roller for speckling with phenolic aldehyde glue is uniformly contacted with facing paper surface, forms glue on facing paper surface Layer;Enter in baking oven with the facing paper of rear surface attachment glue layer and dried, oven temperature arrives low, baking oven heat again from low to high Source is provided by pipeline steam or natural gas boiler steam;After facing paper drying, extra body paper leftover pieces, the as leaching of finished product are cut off Gummed paper.
As a kind of technical solution of optimization, the step of electronic beam curing is as follows: gum dipped paper will be from clear by painting device On clean coating application to the surface of gum dipped paper, and dried using baking oven;It is formed certainly on the surface of gum dipped paper after drying Clean coating;Gum dipped paper is solidified by electron beam curing apparatus, and floral designs are made in automatic cleaning coating, and electronics is made Cured gum dipped paper.
As a kind of technical solution of optimization, hot-forming step is as follows: by the impregnation of core paper and electronic curing of preventing fires Paper is arranged in pairs or groups, and is transported to fully-automatic intelligent high temperature and pressure large-scale vacuum press, hot pressing heat source is by pipeline steam and natural steam pot Furnace steam provides, and the temperature of vacuum press controls in 170 DEG C -200 DEG C, and the paper roll prepared is rolled up and down, is made using high temperature The solidification of the gum dipped paper of fire prevention core paper and electronic curing, there is the automatically cleaning aphalangia grain decorative plate of decorative pattern on obtained surface.
Electronic beam curing (EBC) technology --- Curing Beam Electron.Electron beam is by side same in space It is formed to the electron stream of movement, the electron beam for curing process is constantly to be accelerated electronics by the electric field in electron accelerator It is formed to certain speed.
By adopting the above-described technical solution, compared with prior art, the present invention has rational design, using with self-cleaning Coating is brushed, and is processed by the way of electronic beam curing, forms decorative pattern in coating surface, and have from clear Clean function, meanwhile, electronic beam curing avoids the occurrence of environmental pollution, Environmental Safety, and panel weight is greatly reduced, valence Lattice are cheap, easy to process.
Specific embodiment
Embodiment
A kind of automatically cleaning aphalangia grain decorative plate, including core plate and the facing paper being arranged on two surfaces of core plate;Wherein, Core plate is several layers fireproof core board core plate made of heat pressing process;Facing paper is gum dipped paper, and external coating has from clear Clean coating.
The present invention also provides a kind of preparation processes of automatically cleaning aphalangia grain decorative plate, and steps are as follows:
1), the preparation of self-cleaning coating.The component of the preparation of self-cleaning coating and its mass ratio of component: photocatalyst mixing 60-100 parts of liquid, 30-45 parts of silicone acrylic emulsion, 15-20 parts of fluorine carbon emulsion, auxiliary agent 4-8 parts hydrophobic, 3-13 parts of nano silica, 5-10 parts of polysiloxanes, 5-15 parts of nanometer anatase titania, konilite 1-5 parts porous, 1-2 parts of ethylene glycol, thickener 0.5-1 parts, 1-3 parts of coalescing agent, 1-2 parts of dispersing agent, 1-2 parts of light stabilizer, 1-2 parts and water 50-70 parts of ultraviolet absorbing agent; High speed mixer is sufficiently mixed with the speed of 8000r/min to get self-cleaning coating.
2), the preparation of gum dipped paper.The step of preparation of gum dipped paper is as follows: phenolic aldehyde glue pours into steeping vat, facing paper warp It crosses in steeping vat, the rubber roller for speckling with phenolic aldehyde glue is uniformly contacted with facing paper surface, forms glue layer on facing paper surface;Then The facing paper of surface attachment glue layer enters in baking oven and is dried, and oven temperature arrives low again from low to high, and oven is by pipe Road steam or natural gas boiler steam provide;After facing paper drying, extra body paper leftover pieces, the as gum dipped paper of finished product are cut off.
Wherein, the chemical molecular formula of phenolic aldehyde glue is:
3), electronic beam curing.The step of electronic beam curing is as follows: gum dipped paper passes through painting device for self-cleaning coating brushing It is dried onto the surface of gum dipped paper, and using baking oven;Automatic cleaning coating is formed on the surface of gum dipped paper after drying;Leaching Gummed paper is solidified by electron beam curing apparatus, and floral designs are made in automatic cleaning coating, and the impregnation of electronic curing is made Paper.
4), hot-forming.Hot-forming step is as follows: the gum dipped paper of prevent fires core paper and electronic curing arranged in pairs or groups, It is transported to fully-automatic intelligent high temperature and pressure large-scale vacuum press, hot pressing heat source is provided by pipeline steam and natural gas boiler steam, The temperature of vacuum press controls in 170 DEG C -200 DEG C, and the paper roll prepared is rolled up and down, makes prevent fires core paper and electricity using high temperature The cured gum dipped paper solidification of son, there is the automatically cleaning aphalangia grain decorative plate of decorative pattern on obtained surface.
5) it, is packed in storage.
The present invention has rational design, is brushed using with self-cleaning coating, and by the way of electronic beam curing It is processed, forms decorative pattern in coating surface, and there is self-cleaning function, meanwhile, electronic beam curing avoids the occurrence of environment dirt Dye, Environmental Safety, and also panel weight is greatly reduced, and it is cheap, it is easy to process.
Protection scope of the present invention is not limited merely to above-described embodiment, and all technical solutions belonged under thinking of the present invention are equal It belongs to the scope of protection of the present invention.It should be pointed out that for those skilled in the art, not departing from the present invention Several improvements and modifications under the premise of principle, these modifications and embellishments should also be considered as the scope of protection of the present invention.

Claims (6)

1. a kind of automatically cleaning aphalangia grain decorative plate, it is characterised in that: including core plate and the dress being arranged on two surfaces of core plate Adorn paper;Wherein, core plate is several layers fireproof core board core plate made of heat pressing process;Facing paper is gum dipped paper, surface It is painted with automatic cleaning coating.
2. a kind of preparation process of automatically cleaning aphalangia grain decorative plate according to claim 1, it is characterised in that: step is such as Under:
1), the preparation of self-cleaning coating;
2), the preparation of gum dipped paper;
3), electronic beam curing;
4), hot-forming;
5) it, is packed in storage.
3. a kind of preparation process of automatically cleaning aphalangia grain decorative plate according to claim 2, it is characterised in that: automatically cleaning applies The component of the preparation of material and its mass ratio of component: 60-100 parts of photocatalyst mixed liquor, 30-45 parts of silicone acrylic emulsion, fluorine carbon emulsion 15-20 parts, auxiliary agent 4-8 parts hydrophobic, 3-13 parts of nano silica, 5-10 parts of polysiloxanes, nanometer anatase titania 5- 15 parts, konilite 1-5 parts porous, 1-2 parts of ethylene glycol, 0.5-1 parts of thickener, 1-3 parts of coalescing agent, 1-2 parts of dispersing agent, light is steady Determine 1-2 parts of agent, 1-2 parts and water 50-70 parts of ultraviolet absorbing agent;High speed mixer is sufficiently mixed with the speed of 8000r/min, i.e., Obtain self-cleaning coating.
4. a kind of preparation process of automatically cleaning aphalangia grain decorative plate according to claim 3, it is characterised in that: gum dipped paper The step of preparation is as follows: phenolic aldehyde glue pours into steeping vat, and facing paper is by speckling with the rubber roller and dress of phenolic aldehyde glue in steeping vat Decorations paper surface uniformly contacts, and forms glue layer on facing paper surface;Facing paper with rear surface attachment glue layer enters in baking oven It is dried, oven temperature arrives low again from low to high, and oven is provided by pipeline steam or natural gas boiler steam;Facing paper After drying, extra body paper leftover pieces, the as gum dipped paper of finished product are cut off.
5. a kind of preparation process of automatically cleaning aphalangia grain decorative plate according to claim 4, it is characterised in that: electron beam is solid The step of change is as follows: self-cleaning coating is brushed on the surface of gum dipped paper by gum dipped paper by painting device, and utilizes baking oven It is dried;Automatic cleaning coating is formed on the surface of gum dipped paper after drying;Gum dipped paper is consolidated by electron beam curing apparatus Change, and floral designs are made in automatic cleaning coating, the gum dipped paper of electronic curing is made.
6. a kind of preparation process of automatically cleaning aphalangia grain decorative plate according to claim 5, it is characterised in that: hot-forming The step of it is as follows: the gum dipped paper of prevent fires core paper and electronic curing is arranged in pairs or groups, it is large-scale to be transported to fully-automatic intelligent high temperature and pressure Vacuum press, hot pressing heat source are provided by pipeline steam and natural gas boiler steam, and the temperature of vacuum press is controlled at 170 DEG C -200 In DEG C, the paper roll prepared is rolled up and down, solidifies the gum dipped paper of fire prevention core paper and electronic curing using high temperature, obtained surface has The automatically cleaning aphalangia grain decorative plate of decorative pattern.
CN201910596498.5A 2019-07-03 2019-07-03 A kind of automatically cleaning aphalangia grain decorative plate and its preparation process Pending CN110341280A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910596498.5A CN110341280A (en) 2019-07-03 2019-07-03 A kind of automatically cleaning aphalangia grain decorative plate and its preparation process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910596498.5A CN110341280A (en) 2019-07-03 2019-07-03 A kind of automatically cleaning aphalangia grain decorative plate and its preparation process

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113290989A (en) * 2021-04-20 2021-08-24 广西南宁明源木业有限公司 Photocatalyst antibacterial ecological plate and processing method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2868675Y (en) * 2005-04-11 2007-02-14 北京安迪克斯科技有限责任公司 Plate material with air purifying and sterilizing functions
CN101628450A (en) * 2009-08-31 2010-01-20 李运生 Method for pasting melamine dipped paper on blockboard or plywood
CN105731969A (en) * 2016-03-02 2016-07-06 湖北格林森新型建材科技有限公司 Photocatalytic inorganic ecological decoration board and production method thereof
CN105802367A (en) * 2016-03-16 2016-07-27 湖北格林森新型建材科技有限公司 Composite film-coated self-cleaning inorganic ecological decorative plate and preparation method thereof
CN109535884A (en) * 2017-08-14 2019-03-29 江苏中千碧华新材料有限公司 Inorganic nano self-cleaning coating

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2868675Y (en) * 2005-04-11 2007-02-14 北京安迪克斯科技有限责任公司 Plate material with air purifying and sterilizing functions
CN101628450A (en) * 2009-08-31 2010-01-20 李运生 Method for pasting melamine dipped paper on blockboard or plywood
CN105731969A (en) * 2016-03-02 2016-07-06 湖北格林森新型建材科技有限公司 Photocatalytic inorganic ecological decoration board and production method thereof
CN105802367A (en) * 2016-03-16 2016-07-27 湖北格林森新型建材科技有限公司 Composite film-coated self-cleaning inorganic ecological decorative plate and preparation method thereof
CN109535884A (en) * 2017-08-14 2019-03-29 江苏中千碧华新材料有限公司 Inorganic nano self-cleaning coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113290989A (en) * 2021-04-20 2021-08-24 广西南宁明源木业有限公司 Photocatalyst antibacterial ecological plate and processing method thereof

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Application publication date: 20191018