CN109535884A - Inorganic nano self-cleaning coating - Google Patents

Inorganic nano self-cleaning coating Download PDF

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Publication number
CN109535884A
CN109535884A CN201710690567.XA CN201710690567A CN109535884A CN 109535884 A CN109535884 A CN 109535884A CN 201710690567 A CN201710690567 A CN 201710690567A CN 109535884 A CN109535884 A CN 109535884A
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CN
China
Prior art keywords
parts
inorganic nano
cleaning coating
nano self
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710690567.XA
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Chinese (zh)
Inventor
孔军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Zhong Qian Bi Hua Xin Material Co Ltd
Original Assignee
Jiangsu Zhong Qian Bi Hua Xin Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Zhong Qian Bi Hua Xin Material Co Ltd filed Critical Jiangsu Zhong Qian Bi Hua Xin Material Co Ltd
Priority to CN201710690567.XA priority Critical patent/CN109535884A/en
Publication of CN109535884A publication Critical patent/CN109535884A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Catalysts (AREA)

Abstract

The invention discloses a kind of inorganic nano self-cleaning coating, which weighs following components by weight: 60-100 parts of photocatalyst mixed liquor, 30-45 parts of silicone acrylic emulsion, 15-20 parts of fluorine carbon emulsion, auxiliary agent 4-8 parts hydrophobic, 3-13 parts of nano silica, 5-10 parts of polysiloxanes, 5-15 parts of nanometer anatase titania, konilite 1-5 parts porous, 10-15 parts of titanium tetrachloride, 5-10 parts of Titanium Nitrate, 2-5 parts of calcite, 1-2 parts of ethylene glycol, 0.5-1 parts of thickener, 1-3 parts of coalescing agent, 1-2 parts of dispersing agent and 30-40 parts of water.The present invention uses inorganic nano self-cleaning coating, can reach self-cleaning effect well, not vulnerable to rainwater pollution, contamination spot, avoids cleaning repeatedly expending a large amount of human and material resources and financial resources, also avoids field high altitude operation, social benefit is obvious.

Description

Inorganic nano self-cleaning coating
Technical field
The present invention relates to inorganic nano self-cleaning coating technical fields, and in particular to a kind of inorganic nano self-cleaning coating.
Background technique
Currently, building materials, the vehicles, traditional coating used in pipe network bridge are vulnerable to rainwater pollution, contamination spot, repeatedly Cleaning, which expends a large amount of human and material resources and financial resources, field high altitude operation, can also jeopardize personal safety, therefore, need art technology Personnel develop a kind of inorganic nano self-cleaning coating.
Summary of the invention
The problem to be solved in the present invention is to have overcome the deficiencies of the prior art and provide a kind of inorganic nano self-cleaning coating.
Its technical scheme applied to solve the technical problem is: a kind of inorganic nano self-cleaning coating, and the inorganic nano is certainly Cleaning coating weighs following components by weight: 60-100 parts of photocatalyst mixed liquor, 30-45 parts of silicone acrylic emulsion, fluorine carbon emulsion 15- 20 parts, auxiliary agent 4-8 parts hydrophobic, 3-13 parts of nano silica, 5-10 parts of polysiloxanes, nanometer anatase titania 5-15 Part, konilite 1-5 parts porous, 10-15 parts of titanium tetrachloride, 5-10 parts of Titanium Nitrate, 2-5 parts of calcite, 1-2 parts of ethylene glycol, thickening 0.5-1 parts of agent, 1-3 parts of coalescing agent, 1-2 parts of dispersing agent and 30-40 parts of water, preparation method are as follows: in photocatalyst mixed liquor Silicone acrylic emulsion, fluorine carbon emulsion, nano silica, polysiloxanes, nanometer anatase titania, porous konilite, four is added Titanium chloride, Titanium Nitrate, calcite, ethylene glycol, thickener, coalescing agent, dispersing agent and water, with high speed mixer with 100000r/ The speed of min is sufficiently mixed to get inorganic nano self-cleaning coating.
Preferably, the hydrophobic auxiliary agent is modified natural nanoclay.
Preferably, the thickener is methylcellulose thickener.
Preferably, the inorganic nano self-cleaning coating further includes following parts by weight of component: 1-2 parts of mould inhibitor and being disappeared 1-3 parts of infusion.
Preferably, the inorganic nano self-cleaning coating weighs following components by weight: photocatalyst mixed liquor 60 Part, 30 parts of silicone acrylic emulsion, 15 parts of fluorine carbon emulsion, 4 parts of hydrophobic auxiliary agent, 3 parts of nano silica, 5 parts of polysiloxanes, anatase titanium dioxide are received Rice 5 parts of titanium dioxide, 1 part of porous konilite, 10 parts of titanium tetrachloride, 5 parts of Titanium Nitrate, 2 parts of calcite, 1 part of ethylene glycol, thickener 0.5 part, 1 part of coalescing agent, 1 part of dispersing agent and 30 parts of water.
Preferably, the inorganic nano self-cleaning coating further includes following parts by weight of component: 1 part of mould inhibitor and defoaming 1 part of agent.
The invention has the benefit that using inorganic nano self-cleaning coating self-cleaning effect well can be reached, no Vulnerable to rainwater pollution, contamination spot, avoids cleaning repeatedly expending a large amount of human and material resources and financial resources, also avoid field height Idle job, social benefit are obvious.
Specific embodiment
Below with reference to embodiment the present invention will be further explained explanation.
Embodiment
A kind of inorganic nano self-cleaning coating, the inorganic nano self-cleaning coating weigh following components by weight: photocatalyst is mixed Close liquid 60-100 parts, 30-45 parts of silicone acrylic emulsion, 15-20 parts of fluorine carbon emulsion, auxiliary agent 4-8 parts hydrophobic, nano silica 3-13 Part, 5-10 parts of polysiloxanes, 5-15 parts of nanometer anatase titania, konilite 1-5 parts porous, 10-15 parts of titanium tetrachloride, nitre Sour titanium 5-10 parts, 2-5 parts of calcite, 1-2 parts of ethylene glycol, 0.5-1 parts of thickener, 1-3 parts of coalescing agent, 1-2 parts of dispersing agent and 30-40 parts of water, preparation method are as follows: silicone acrylic emulsion is added in photocatalyst mixed liquor, fluorine carbon emulsion, nano silica, gathers Siloxanes, nanometer anatase titania, porous konilite, titanium tetrachloride, Titanium Nitrate, calcite, ethylene glycol, thickener, at Film auxiliary agent, dispersing agent and water are sufficiently mixed with high speed mixer with the speed of 100000r/min to get inorganic nano automatically cleaning Coating.
The hydrophobic auxiliary agent is modified natural nanoclay.The thickener is methylcellulose thickener.It is described inorganic Nano self-cleaning paint weighs following components by weight: 60 parts of photocatalyst mixed liquor, 30 parts of silicone acrylic emulsion, fluorine carbon emulsion 15 Part, 4 parts of hydrophobic auxiliary agent, 3 parts of nano silica, 5 parts of polysiloxanes, 5 parts of nanometer anatase titania, porous konilite 1 Part, 10 parts of titanium tetrachloride, 5 parts of Titanium Nitrate, 2 parts of calcite, 1 part of ethylene glycol, 0.5 part of thickener, 1 part of coalescing agent, dispersing agent 1 Part and 30 parts of water.The inorganic nano self-cleaning coating further includes following parts by weight of component: 1 part and 1 part of defoaming agent of mould inhibitor.
Above content is example and explanation of the invention, but does not mean that the obtainable advantage of the present invention is so limited, all It is wherein one the advantages of may being realized in simple transformation, and/or some embodiments to structure in practice process of the present invention It is a or it is multiple within the scope of protection of this application.

Claims (6)

1. a kind of inorganic nano self-cleaning coating, it is characterised in that: the inorganic nano self-cleaning coating weighs following by weight Component: 60-100 parts of photocatalyst mixed liquor, 30-45 parts of silicone acrylic emulsion, 15-20 parts of fluorine carbon emulsion, auxiliary agent 4-8 parts hydrophobic, nanometer 3-13 parts of silica, 5-10 parts of polysiloxanes, 5-15 parts of nanometer anatase titania, konilite 1-5 parts porous, four chlorinations 10-15 parts of titanium, 2-5 parts of calcite, 1-2 parts of ethylene glycol, 0.5-1 parts of thickener, 1-3 parts of coalescing agent, divides 5-10 parts of Titanium Nitrate 1-2 parts and water 30-40 parts of powder, preparation method are as follows: silicone acrylic emulsion, fluorine carbon emulsion, nanometer are added in photocatalyst mixed liquor Silica, polysiloxanes, nanometer anatase titania, porous konilite, titanium tetrachloride, Titanium Nitrate, calcite, second two Alcohol, thickener, coalescing agent, dispersing agent and water are sufficiently mixed with high speed mixer with the speed of 100000r/min to get nothing Machine nano self-cleaning paint.
2. inorganic nano self-cleaning coating according to claim 1, it is characterised in that: the hydrophobic auxiliary agent is modified natural Nanoclay.
3. inorganic nano self-cleaning coating according to claim 1, it is characterised in that: the thickener is methylcellulose Thickener.
4. inorganic nano self-cleaning coating according to claim 1, it is characterised in that: the inorganic nano self-cleaning coating It further include following parts by weight of component: 1-2 parts and defoaming agent 1-3 parts of mould inhibitor.
5. inorganic nano self-cleaning coating according to claim 1, it is characterised in that: the inorganic nano self-cleaning coating Weigh following components by weight: 60 parts of photocatalyst mixed liquor, 30 parts of silicone acrylic emulsion, 15 parts of fluorine carbon emulsion, 4 parts of hydrophobic auxiliary agent, 3 parts of nano silica, 5 parts of polysiloxanes, 5 parts of nanometer anatase titania, 1 part of porous konilite, 10 parts of titanium tetrachloride, 5 parts of Titanium Nitrate, 2 parts of calcite, 1 part of ethylene glycol, 0.5 part of thickener, 1 part of coalescing agent, 1 part of dispersing agent and 30 parts of water.
6. inorganic nano self-cleaning coating according to claim 4, it is characterised in that: the inorganic nano self-cleaning coating It further include following parts by weight of component: 1 part and 1 part of defoaming agent of mould inhibitor.
CN201710690567.XA 2017-08-14 2017-08-14 Inorganic nano self-cleaning coating Pending CN109535884A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710690567.XA CN109535884A (en) 2017-08-14 2017-08-14 Inorganic nano self-cleaning coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710690567.XA CN109535884A (en) 2017-08-14 2017-08-14 Inorganic nano self-cleaning coating

Publications (1)

Publication Number Publication Date
CN109535884A true CN109535884A (en) 2019-03-29

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110341280A (en) * 2019-07-03 2019-10-18 常州市天润木业有限公司 A kind of automatically cleaning aphalangia grain decorative plate and its preparation process
CN111020807A (en) * 2019-12-13 2020-04-17 武汉纺织大学 Self-cleaning fireproof wall cloth and preparation method thereof
CN111138893A (en) * 2020-01-19 2020-05-12 广州市建桥音响配件有限公司 Self-cleaning horn paint
CN112049459A (en) * 2020-09-24 2020-12-08 韦尔狄(广州)生物工程科技有限公司 Construction method and process for quickly repairing indoor wall surface
CN112210257A (en) * 2019-07-09 2021-01-12 常州市大使涂料有限公司 Non-sticking clean-keeping self-cleaning coating
CN117362864A (en) * 2023-09-26 2024-01-09 江苏华信高新材料有限公司 Antibacterial PVC film with self-cleaning function

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110341280A (en) * 2019-07-03 2019-10-18 常州市天润木业有限公司 A kind of automatically cleaning aphalangia grain decorative plate and its preparation process
CN112210257A (en) * 2019-07-09 2021-01-12 常州市大使涂料有限公司 Non-sticking clean-keeping self-cleaning coating
CN111020807A (en) * 2019-12-13 2020-04-17 武汉纺织大学 Self-cleaning fireproof wall cloth and preparation method thereof
CN111138893A (en) * 2020-01-19 2020-05-12 广州市建桥音响配件有限公司 Self-cleaning horn paint
CN112049459A (en) * 2020-09-24 2020-12-08 韦尔狄(广州)生物工程科技有限公司 Construction method and process for quickly repairing indoor wall surface
CN117362864A (en) * 2023-09-26 2024-01-09 江苏华信高新材料有限公司 Antibacterial PVC film with self-cleaning function

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Application publication date: 20190329