CN110330920A - A kind of low temperature resistant ceramic tile stone material gum and preparation method thereof - Google Patents

A kind of low temperature resistant ceramic tile stone material gum and preparation method thereof Download PDF

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Publication number
CN110330920A
CN110330920A CN201910633783.XA CN201910633783A CN110330920A CN 110330920 A CN110330920 A CN 110330920A CN 201910633783 A CN201910633783 A CN 201910633783A CN 110330920 A CN110330920 A CN 110330920A
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China
Prior art keywords
parts
lotion
ceramic tile
low temperature
temperature resistant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910633783.XA
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Chinese (zh)
Inventor
陈乐舟
陈雯琪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hubei Alkali New Material Co Ltd
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Hubei Alkali New Material Co Ltd
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Priority to CN201910633783.XA priority Critical patent/CN110330920A/en
Publication of CN110330920A publication Critical patent/CN110330920A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J109/00Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09J109/10Latex
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Road Paving Structures (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of low temperature resistant ceramic tile stone material gums, score meter by weight, its raw material composition includes: 15~20 parts of acrylic emulsion, 14.5~16.5 parts of buna lotion, 5~7 parts of isoprene rubber lotion, 25~35 parts of quartz sand, 25~35 parts of miberal powder, 0.2~0.4 part of fungicide, 0.1~0.3 part of mill base.In addition, the invention also discloses the methods for preparing above-mentioned gum, comprising the following steps: 1) acrylic emulsion, buna lotion, isoprene rubber lotion investment dispersion machine are stirred to get mixed emulsion;2) quartz sand, miberal powder, fungicide, mill base are put into above-mentioned mixed emulsion and obtains gum.The problems such as gum prepared by the present invention fully achieves the bonding requirement of vitrified tile, efficiently solves the hollowing occurred when vitrified tile bonds, flakes, falls off;Have the characteristics that waterproof, adhesion are good, cold resistance is preferable, higher tensile strength by the mixed emulsion of acrylic emulsion, buna lotion, the preparation of isoprene rubber lotion.

Description

A kind of low temperature resistant ceramic tile stone material gum and preparation method thereof
Technical field
The invention belongs to building material technical fields, more particularly to a kind of low temperature resistant ceramic tile stone material gum and its preparation side Method.
Background technique
Vitrified tile is fired according to a certain percentage by quartz sand, mud, is then polished bright but does not need to polish, Surface is smooth bright as glass-mirror.Its water absorption rate, straightness of sides, bending strength, in terms of it is better than general Logical glazed tile, polished bricks and general marble.Vitrified tile is a kind of good ornament materials, is used for interior decoration, is had very Good decorative effect.But since the water absorption rate of vitrified tile itself is lower than 5 ‰, so that very tired when it is pasted to cement layer surface It is difficult.Ceramic tile gum can effectively improve the adhesion strength at the vitrified tile back side and cement layer surface, be that current most effective interface is viscous Tie reinforcing material.However, ceramic tile gum is various in style currently on the market, quality is very different, will appear hollowing after use, rises Shell, the problems such as falling off, such as: the vitrified tile after bonding is easy to appear the phenomenon that falling off by after the etch of rainwater;Weather it is cold Thermal change makes cementitious material by the influence deformed, and cementitious material and vitrified tile interface is caused parting occur, and causes vitreous Brick falls off.
Summary of the invention
The present invention is directed to overcome one of the problems of the above-mentioned prior art, a kind of low temperature resistant ceramic tile stone material gum is provided, According to parts by weight, raw material composition includes:
Preferably, according to parts by weight, the buna lotion lotion is by 7.5~8.5 parts of buna, 7~8 parts of first Benzene is made.
Preferably, according to parts by weight, the isoprene rubber lotion is by 3.5~4.5 parts of isoprene rubbers, 1.5~2.5 parts of fourths Alkane is made.
Preferably, the mesh number of the quartz sand is 40~70 mesh.
Further, according to parts by weight, raw material forms further include:
0.2~0.4 part of fungicide,
0.1~0.3 part of mill base.
Preferably, the mill base is middle yellow pulp.
In addition, the present invention also provides a kind of methods for preparing above-mentioned low temperature resistant ceramic tile stone material gum, comprising the following steps:
1) acrylic emulsion, buna lotion, isoprene rubber lotion investment dispersion machine are stirred 25~35 minutes and is obtained Mixed emulsion, the revolving speed of dispersion machine are 800~900 revs/min;
2) quartz sand, miberal powder, fungicide, mill base are put into above-mentioned mixed emulsion, dispersion machine continues 15~25 points of stirring Clock obtains gum, and the revolving speed of dispersion machine is 850~900 revs/min.
Ceramic tile stone material gum prepared by the present invention fully achieves the bonding requirement of vitrified tile, efficiently solves glass The problems such as changing the hollowing occurred when brick bonds, flaking, fall off.By acrylic emulsion, buna lotion, isoprene rubber lotion system Standby mixed emulsion has the characteristics that waterproof, adhesion are good, cold resistance is preferable, higher tensile strength.
Specific embodiment
For a better understanding of the present invention, below with reference to the embodiment content that the present invention is furture elucidated, but it is of the invention Content is not limited solely to the following examples.
Embodiment 1:
A kind of low temperature resistant ceramic tile stone material gum, according to parts by weight, raw material composition includes:
Wherein, according to parts by weight, the buna lotion lotion is made of 7.5 parts of buna, 7 parts of toluene;It states Isoprene rubber lotion is made of 3.5 parts of isoprene rubbers, 1.5 parts of butane.
The mesh number of the quartz sand is 40 mesh;The mill base is middle yellow pulp.
A method of preparing low temperature resistant ceramic tile stone material gum, comprising the following steps:
1) buna lotion will be prepared in buna, toluene investment reaction kettle;
2) isoprene rubber lotion will be prepared in isoprene rubber, butane investment reaction kettle;
3) acrylic emulsion, buna lotion, isoprene rubber lotion investment dispersion machine are stirred 25 minutes and is mixed Lotion, the revolving speed of dispersion machine are 800 revs/min;
4) quartz sand, miberal powder, fungicide, mill base are put into above-mentioned mixed emulsion, dispersion machine continues stirring 15 minutes To gum, the revolving speed of dispersion machine is 850 revs/min.
Embodiment 2:
A kind of low temperature resistant ceramic tile stone material gum, according to parts by weight, raw material composition includes:
Wherein, according to parts by weight, the buna lotion lotion is made of 8 parts of buna, 7.5 parts of toluene;It states Isoprene rubber lotion is made of 4 parts of isoprene rubbers, 2 parts of butane.
The mesh number of the quartz sand is 50 mesh;The mill base is middle yellow pulp.
A method of preparing low temperature resistant ceramic tile stone material gum, comprising the following steps:
1) buna lotion will be prepared in buna, toluene investment reaction kettle;
2) isoprene rubber lotion will be prepared in isoprene rubber, butane investment reaction kettle;
3) acrylic emulsion, buna lotion, isoprene rubber lotion investment dispersion machine are stirred 30 minutes and is mixed Lotion, the revolving speed of dispersion machine are 850 revs/min;
4) quartz sand, miberal powder, fungicide, mill base are put into above-mentioned mixed emulsion, dispersion machine continues stirring 20 minutes To gum, the revolving speed of dispersion machine is 850 revs/min.
Embodiment 3:
A kind of low temperature resistant ceramic tile stone material gum, according to parts by weight, raw material composition includes:
Wherein, according to parts by weight, the buna lotion lotion is made of 8.5 parts of buna, 8 parts of toluene;It states Isoprene rubber lotion is made of 4.5 parts of isoprene rubbers, 2.5 parts of butane.
The mesh number of the quartz sand is 60 mesh;The mill base is middle yellow pulp.
A method of preparing low temperature resistant ceramic tile stone material gum, comprising the following steps:
1) buna lotion will be prepared in buna, toluene investment reaction kettle;
2) isoprene rubber lotion will be prepared in isoprene rubber, butane investment reaction kettle;
3) acrylic emulsion, buna lotion, isoprene rubber lotion investment dispersion machine are stirred 35 minutes and is mixed Lotion, the revolving speed of dispersion machine are 900 revs/min;
4) quartz sand, miberal powder, fungicide, mill base are put into above-mentioned mixed emulsion, dispersion machine continues stirring 25 minutes To gum, the revolving speed of dispersion machine is 900 revs/min.
Embodiment 4:
A kind of low temperature resistant ceramic tile stone material gum, according to parts by weight, raw material composition includes:
Wherein, according to parts by weight, the buna lotion lotion is made of 8 parts of buna, 8 parts of toluene;It states different Penta rubber latex is made of 3.5 parts of isoprene rubbers, 2.5 parts of butane.
The mesh number of the quartz sand is 70 mesh;The mill base is middle yellow pulp.
A method of preparing low temperature resistant ceramic tile stone material gum, comprising the following steps:
1) buna lotion will be prepared in buna, toluene investment reaction kettle;
2) isoprene rubber lotion will be prepared in isoprene rubber, butane investment reaction kettle;
3) acrylic emulsion, buna lotion, isoprene rubber lotion investment dispersion machine are stirred 30 minutes and is mixed Lotion, the revolving speed of dispersion machine are 800 revs/min;
4) quartz sand, miberal powder, fungicide, mill base are put into above-mentioned mixed emulsion, dispersion machine continues stirring 20 minutes To gum, the revolving speed of dispersion machine is 850 revs/min.
Embodiment 5:
Ceramic tile stone material gum made from above-described embodiment 1~4 is tested for the property, referring to JC/T547-2017 " ceramics Brick adhesive " criterion ceramic tile stone material gum is tested for the property, result is as shown in table 1 below:
Table 1
As can be seen from the above table, the present invention mentions prepared ceramic tile stone material gum, fully achieves the bonding of vitrified tile It is required that the problems such as efficiently solving the hollowing occurred when vitrified tile bonds, flaking, fall off, and construction is simple.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that: not A variety of change, modification, replacement and modification can be carried out to these embodiments in the case where being detached from the principle of the present invention and objective, this The range of invention is defined by the claims and their equivalents.

Claims (7)

1. a kind of low temperature resistant ceramic tile stone material gum, which is characterized in that according to parts by weight, raw material composition includes:
2. low temperature resistant ceramic tile stone material gum according to claim 1, which is characterized in that according to parts by weight, the fourth sodium Rubber latex lotion is made of 7.5~8.5 parts of buna, 7~8 parts of toluene.
3. low temperature resistant ceramic tile stone material gum according to claim 2, which is characterized in that according to parts by weight, the isoamyl Rubber latex is made of 3.5~4.5 parts of isoprene rubbers, 1.5~2.5 parts of butane.
4. low temperature resistant ceramic tile stone material gum according to claim 3, which is characterized in that the mesh number of the quartz sand be 40~ 70 mesh.
5. low temperature resistant ceramic tile stone material gum according to claim 1, which is characterized in that according to parts by weight, raw material group At further include:
0.2~0.4 part of fungicide,
0.1~0.3 part of mill base.
6. -5 any low temperature resistant ceramic tile stone material gum according to claim 1, which is characterized in that the mill base is middle yellow Slurry.
7. a kind of method for preparing any low temperature resistant ceramic tile stone material gum of claim 1 to 6, which is characterized in that including Following steps:
1) acrylic emulsion, buna lotion, isoprene rubber lotion investment dispersion machine are stirred 25~35 minutes and is mixed Lotion, the revolving speed of dispersion machine are 800~900 revs/min;
2) quartz sand, miberal powder, fungicide, mill base are put into above-mentioned mixed emulsion, dispersion machine continues stirring 15~25 minutes To gum, the revolving speed of dispersion machine is 850~900 revs/min.
CN201910633783.XA 2019-07-15 2019-07-15 A kind of low temperature resistant ceramic tile stone material gum and preparation method thereof Pending CN110330920A (en)

Priority Applications (1)

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CN201910633783.XA CN110330920A (en) 2019-07-15 2019-07-15 A kind of low temperature resistant ceramic tile stone material gum and preparation method thereof

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Application Number Priority Date Filing Date Title
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102815897A (en) * 2012-07-30 2012-12-12 丁力 Alkali seepage-resistant enhanced back adhesive for stone materials
US20150291858A1 (en) * 2012-11-26 2015-10-15 Nitto Denko Corporation Water-dispersed pressure-sensitive adhesive composition, pressure-sensitive adhesive layer, pressure-sensitive adhesive sheet, and laminate comprising pressure-sensitive adhesive layer or pressure-sensitive adhesive sheet
CN105419198A (en) * 2015-12-28 2016-03-23 广州市优伟家居用品有限公司 Aqueous antiskid rubber, preparation method therefor and applications
CN108485564A (en) * 2018-03-27 2018-09-04 盐城雨辰新型建材有限公司 One pack system ceramic tile gum and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102815897A (en) * 2012-07-30 2012-12-12 丁力 Alkali seepage-resistant enhanced back adhesive for stone materials
US20150291858A1 (en) * 2012-11-26 2015-10-15 Nitto Denko Corporation Water-dispersed pressure-sensitive adhesive composition, pressure-sensitive adhesive layer, pressure-sensitive adhesive sheet, and laminate comprising pressure-sensitive adhesive layer or pressure-sensitive adhesive sheet
CN105419198A (en) * 2015-12-28 2016-03-23 广州市优伟家居用品有限公司 Aqueous antiskid rubber, preparation method therefor and applications
CN108485564A (en) * 2018-03-27 2018-09-04 盐城雨辰新型建材有限公司 One pack system ceramic tile gum and preparation method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
傅高升主编: "《汽车材料》", 31 August 2011, 济南:山东大学出版社 *
刘植榕等主编: "《橡胶工业手册 第8分册 试验方法》", 30 September 1992, 北京:化学工业出版社 *
张东初主编: "《设计材料与加工工艺》", 30 September 2003, 郑州:河南人民出版社 *

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