CN110328904A - Light-sensitive emulsion curing overlay film type air warming compound fabric and preparation method thereof - Google Patents

Light-sensitive emulsion curing overlay film type air warming compound fabric and preparation method thereof Download PDF

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Publication number
CN110328904A
CN110328904A CN201910610559.9A CN201910610559A CN110328904A CN 110328904 A CN110328904 A CN 110328904A CN 201910610559 A CN201910610559 A CN 201910610559A CN 110328904 A CN110328904 A CN 110328904A
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China
Prior art keywords
light
sensitive emulsion
cloth
type air
overlay film
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CN201910610559.9A
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Chinese (zh)
Inventor
纪峰
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Suzhou Xingshichuang Textile Technology Research Co Ltd
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Suzhou Xingshichuang Textile Technology Research Co Ltd
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Priority to CN201910610559.9A priority Critical patent/CN110328904A/en
Publication of CN110328904A publication Critical patent/CN110328904A/en
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    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D3/00Overgarments
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/04Materials specially adapted for outerwear characterised by special function or use
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/04Materials specially adapted for outerwear characterised by special function or use
    • A41D31/06Thermally protective, e.g. insulating
    • A41D31/065Thermally protective, e.g. insulating using layered materials
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/04Materials specially adapted for outerwear characterised by special function or use
    • A41D31/18Elastic
    • A41D31/185Elastic using layered materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/283Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polysiloxanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0008Electrical discharge treatment, e.g. corona, plasma treatment; wave energy or particle radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B2037/1253Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives curable adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B2037/1269Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives multi-component adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/412Transparent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51Elastic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/582Tearability
    • B32B2307/5825Tear resistant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/718Weight, e.g. weight per square meter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • B32B2307/7242Non-permeable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00Clothing

Abstract

The present invention discloses a kind of light-sensitive emulsion curing overlay film type air warming compound fabric and preparation method thereof, its technical characteristic includes that the organosilicone film using thickness range in 0.015mm~0.05mm uses film layer as compound, ultraviolet light solidifies light-sensitive emulsion component as photosensitive binder layer, pass through level pressure to adhesive dispenser between glue to film layer and substrate cloth after ultraviolet light solidification light-sensitive emulsion component is configured to ultraviolet light solidification light-sensitive emulsion colloid in advance, ultraviolet light is set to carry out compressing operation while solidifying the solidification of light-sensitive emulsion colloid by ultraviolet source irradiation to prepare the light-sensitive emulsion curing overlay film type air warming compound fabric, the present invention compared with the prior art the advantages of be by organosilicone film with fabric is compound that composite material is prepared, airtight effect is splendid, organosilicone film it is frivolous, it is transparent, flexible and high-elastic feature, most The relative motion freedom degree of yarn in original fabric structure is maintained to big degree, to keep its stretching, shearing elasticity and bending flexible.

Description

Light-sensitive emulsion curing overlay film type air warming compound fabric and preparation method thereof
Technical field
The present invention relates to a kind of composite materials and preparation method thereof, specifically, are related to a kind of light-sensitive emulsion curing overlay film type Air warming compound fabric and preparation method thereof.
Background technique
The filler material of winter warming clothes (housing) needs to meet low thermal conductivity, light, fluffy requirement, and face/inner Material should reach the requirement to filler material leakproofness, be provided simultaneously with light and soft feature.Top grade thermal cloth is at present with birds Natural feather is filler material, although having the characteristics that lightweight and fluffy, enables that clothes are too fat to move, easy-to-collection is not arranged and is difficult to completely eliminate Peculiar smell.Although early stage is it has been proposed that make the filler of thermal cloth with air, compared with the Conventional fillers material such as natural feather, cotton, silk, chemical fibre Material, bulk density, thermal coefficient and the cost of air will be much smaller, and the loading controllability and designability of air It by force, therefore is the most ideal material for preparing thermal cloth;However how the high-elastic soft of clothes is kept while effectively lockking air Property sense simultaneously keeps excellent against weather, is the main problem researching and developing air thermal cloth and facing.
Solving the problems, such as fabric latching air at present has two class methods.The first is to carry out surface coating to fabric, utilizes painting The hole inside material filling fabric institutional framework is covered to realize latching air effect, right this method persistence is poor, by washing, Solarization aging, repeatedly bend the effects of after, fabric surface coating material, which is easy to fall off, enables hole show again, so that clothes Whole latching air effect failure.Second class method is that it is compound that fabric-film lamination is prepared in fabric surface overlay film Fabric effectively realizes latching air using the air-tightness of film, and this method can obtain effective and lasting gas-tight composite material, Therefore it can be used for developing air thermal cloth functional fabric.
Air thermal cloth fabric, as wearing fabric, need to have light, curved other than having basic latching air function Bent flexibility, tensile property, mechanical are destroyed and the performances such as corrosion-resistant weatherability, therefore, very heavy to the selection of covering material It wants.It is conventionally used to the material of overlay film, such as rubber, latex, although elasticity is preferably, thickness is big to be enabled fabric significantly be hardened, is uncomfortable In taking, and the material is easy aging, reduces the service life;It is currently used in also plastic film etc., but such material of overlay film Tensile property area is small, resisted in the case where thickness is small tear, pierce, hooking, drawing etc. mechanical external forces ability it is low, and against weather It is weak, it is chiefly used in packaging, the package material of object, it is difficult to for taking.
Other than the selection to covering material, fabric-overlay film combination process is also to be solved in fabric research and development asks Topic.Bonding method is traditionally selected, needs to enable bonding gum softening by heating in bonding, but heating process not only needs to consume Relatively large electric power energy, and generate after colloid heating to human body and the harmful escaping gas of environment, do not meet environmental requirement.
By upper, preparing fabric-film lamination composite material is the effective way for developing air thermal cloth fabric, right this method The gas-tight functional and wearing comfort that not yet can effectively solve fabric simultaneously in the selection of covering material and combination process is asked Topic.Current exploitation high quality air thermal cloth fabric needs to solve two key technologies: high-performance covering material in composite material Selection and cloth-overlay film adhesion technique.
Summary of the invention
Goal of the invention: present invention aims in view of the deficiencies of the prior art, providing, a kind of light-sensitive emulsion curing overlay film type is empty Gas warming compound fabric and preparation method thereof.
Technical solution: a kind of light-sensitive emulsion curing overlay film type air warming compound fabric of the present invention, including substrate cloth, Coating layer and adhesive layer, the coating layer are organosilicone film of the thickness range in 0.015mm~0.05mm, and the adhesive layer is Photosensitive binder layer, the photosensitive binder layer are that ultraviolet light solidifies light-sensitive emulsion component composition, and the ultraviolet light solidifies light-sensitive emulsion component Including matrix photosensitive resin, photo polymerization monomer, photoinitiator, light sensitizer, the substrate cloth can be set to single layer or Multilayer, the light-sensitive emulsion curing overlay film type air warming compound fabric successively includes substrate cloth, photosensitive binder layer when single layer is arranged And organosilicone film, substrate cloth and organosilicon are thin in the light-sensitive emulsion curing overlay film type air warming compound fabric when multilayer is arranged Film is alternately laid with and is coated with photosensitive binder layer in each interlayer.
Prepare the preparation method of the light-sensitive emulsion curing overlay film type air warming compound fabric, comprising the following steps:
(1) pre-prepared ultraviolet light solidifies light-sensitive emulsion component, by matrix photosensitive resin, photo polymerization monomer, photoinitiator, light Sensitizer be blended and be stirred into ultraviolet light solidification light-sensitive emulsion colloid it is spare;
(2) lamination equipment complex is set up, lamination equipment complex includes to adhesive dispenser, cloth adhesive dispenser and ultraviolet source;
(3) the ultraviolet light solidification light-sensitive emulsion colloid prepared in step (1) is injected to adhesive dispenser and is communicated to cloth adhesive dispenser On;
(4) level pressure is set to adhesive dispenser to mucilage binding described in step (3), which includes for loading purple to adhesive dispenser The level pressure of outer photocuring light-sensitive emulsion colloid to packing element and setting in level pressure in packing element, for controlling level pressure to ultraviolet in packing element Photocuring light-sensitive emulsion colloid is forced out with fixed pressure and injects the constant DP control block of cloth adhesive dispenser;
(5) ultraviolet light solidification light-sensitive emulsion colloid by cloth adhesive dispenser be uniformly coated to substrate cloth and organosilicone film it Between, and ultraviolet light solidification light-sensitive emulsion colloid solidification bond substrates cloth and organosilicone film is promoted by ultraviolet source irradiation, and Pressing device is arranged in the exit of cloth adhesive dispenser, and the warming composite surface of complete light-sensitive emulsion curing overlay film type air is made after compression Material.
Preferably, the light-sensitive emulsion curing overlay film type air warming compound fabric of required preparation includes single-layer fabric and more Layer composite material.
Preferably, the cloth mucilage binding is set to piece glue paddle when preparing single-layer fabric, the ultraviolet source is setting Line style ultraviolet lamp above piece glue paddle.
Preferably, described glue paddle include be connected to level pressure to be provided on packing element into glue chamber and uniformly into Cloth glue hole on glue chamber.
Preferably, the cloth mucilage binding is set to dispensing paddle when preparing Multilayer plus material, the dispensing paddle includes The a plurality of painting adhesive tape being stitched together, the painting adhesive tape include being connected to level pressure to injected rubber hose on packing element and being arranged in the case where applying adhesive tape Surface and the upper rubber head for being connected to injected rubber hose, the ultraviolet source are that fixed point is equipped with the LED ultraviolet lamp in upper rubber head.
The present invention has the advantages that (1) passes through organosilicone film and the compound preparation of fabric compared to the prior art Composite material is obtained, realizes airtight effect in a manner of filling fabric hole, consolidated yarn structure compared to application type material, this Invention solves the problems, such as the air-tightness of fabric first, enables composite material that can still keep airtight function in the case where bearing compared with atmospheric pressure Energy;Silicon thin film has excellent chemical stability and high temperature resistant, low temperature properties, and overlay film forms fabric and protects, and composite material is enabled to exist Functional effect is still kept in high temperature, low temperature even aggressive atmosphere;
(2) organosilicone film has the characteristics that frivolous, transparent, flexible and high-elastic, overlay film deformation synchronous with fabric, to former face The thickness and weight of material increase minimum.The relative motion freedom degree for farthest maintaining yarn in original fabric structure, from And keep its stretching, shearing elasticity and bending flexible, it enables composite material that light, thin, soft, bullet feature is presented, has ensured that touching skin relaxes The freedom degree of appropriateness and human motion;
(3) effective compound, the order adherency that light-sensitive emulsion replaces traditional hot melt adhesive to implement overlay film and fabric is solidified with ultraviolet light Effect is secured, and peel strength is high, meanwhile, compared with common adhesives, ultraviolet light solidifies light-sensitive emulsion capacity usage ratio height, quick solidifying Speed, room temperature or low-temperature setting do not have to organic solvent, therefore no pollution to the environment;
(4) electric heating is replaced using ultraviolet leds radiation modality, whole process controllability improves, and improves energy utilization Rate;Region-wide illumination is replaced to save energy while accurate, effective implementation light-sensitive emulsion solidification with fixed point, local illumination methods Source consumption, reduces cost.
Specific embodiment
Technical solution of the present invention is described in detail below, but protection scope of the present invention is not limited to the implementation Example.
Embodiment 1: for the embodiment of woven.
A kind of light-sensitive emulsion curing overlay film type air warming compound fabric, including substrate cloth, coating layer and adhesive layer, overlay film Layer is organosilicone film of the thickness range in 0.015mm~0.05mm, and adhesive layer is photosensitive binder layer, and photosensitive binder layer is ultraviolet Photocuring light-sensitive emulsion component is constituted, and it includes matrix photosensitive resin, photo polymerization monomer, photosensitive initiation that ultraviolet light, which solidifies light-sensitive emulsion component, Agent, light sensitizer, substrate cloth can be set to single-layer or multi-layer, and the light-sensitive emulsion curing overlay film type air is warming when single layer is arranged Composite material successively includes substrate cloth, photosensitive binder layer and organosilicone film, light-sensitive emulsion curing overlay film type when multilayer is arranged Substrate cloth and organosilicone film are alternately laid with and are coated with photosensitive binder layer in each interlayer in air warming compound fabric.
Prepare the preparation method of the light-sensitive emulsion curing overlay film type air warming compound fabric of woven, including following step It is rapid:
(1) pre-prepared ultraviolet light solidifies light-sensitive emulsion component, by matrix photosensitive resin, photo polymerization monomer, photoinitiator, light Sensitizer be blended and be stirred into ultraviolet light solidification light-sensitive emulsion colloid it is spare;
(2) lamination equipment complex is set up, lamination equipment complex includes to adhesive dispenser, cloth adhesive dispenser and ultraviolet source;
(3) the ultraviolet light solidification light-sensitive emulsion colloid prepared in step (1) is injected to adhesive dispenser and is communicated to cloth adhesive dispenser On;
(4) level pressure is set to adhesive dispenser to mucilage binding described in step (3), which includes for loading purple to adhesive dispenser The level pressure of outer photocuring light-sensitive emulsion colloid to packing element and setting in level pressure in packing element, for controlling level pressure to ultraviolet in packing element Photocuring light-sensitive emulsion colloid is forced out with fixed pressure and injects the constant DP control block of cloth adhesive dispenser;
(5) ultraviolet light solidification light-sensitive emulsion colloid by cloth adhesive dispenser be uniformly coated to substrate cloth and organosilicone film it Between, and ultraviolet light solidification light-sensitive emulsion colloid solidification bond substrates cloth and organosilicone film is promoted by ultraviolet source irradiation, and Pressing device is arranged in the exit of cloth adhesive dispenser, and the warming composite surface of complete light-sensitive emulsion curing overlay film type air is made after compression Material.
Wherein, cloth mucilage binding is set to piece glue paddle, and ultraviolet source is the line style ultraviolet lamp being arranged in above piece glue paddle, Ultraviolet light solidification light-sensitive emulsion colloid by glue injection cavities be passed through piece glue paddle and by cloth glue hole uniformly squeeze into organosilicone film with Between substrate cloth, ultraviolet light solidification light-sensitive emulsion colloid is cured after the ultraviolet light irradiation of meridional type, then will be had by pressing device Machine silicon thin film and substrate cloth compress the light-sensitive emulsion curing overlay film type air warming compound fabric that realization prepares woven.
Two groups of wovens are prepared with the processing method of embodiment 1, it is as follows to test its mechanical performance:
First set product: seam slippage: 68-2mm, ultimate strength 740N, Tear strength > 20N, ultimate strength > 45N are protected Warm clo value=1.1-1.6.
First set product: seam slippage: 69-2mm, ultimate strength 753N, Tear strength > 22N, ultimate strength > 46N are protected Warm clo value=1.1-1.6.
Embodiment 2: for the embodiment of multilayer fabric.
A kind of light-sensitive emulsion curing overlay film type air warming compound fabric, including substrate cloth, coating layer and adhesive layer, overlay film Layer is organosilicone film of the thickness range in 0.015mm~0.05mm, and adhesive layer is photosensitive binder layer, and photosensitive binder layer is ultraviolet Photocuring light-sensitive emulsion component is constituted, and it includes matrix photosensitive resin, photo polymerization monomer, photosensitive initiation that ultraviolet light, which solidifies light-sensitive emulsion component, Agent, light sensitizer, substrate cloth can be set to single-layer or multi-layer, and the light-sensitive emulsion curing overlay film type air is warming when single layer is arranged Composite material successively includes substrate cloth, photosensitive binder layer and organosilicone film, light-sensitive emulsion curing overlay film type when multilayer is arranged Substrate cloth and organosilicone film are alternately laid with and are coated with photosensitive binder layer in each interlayer in air warming compound fabric.
Prepare the preparation method of the light-sensitive emulsion curing overlay film type air warming compound fabric of woven, including following step It is rapid:
(1) pre-prepared ultraviolet light solidifies light-sensitive emulsion component, by matrix photosensitive resin, photo polymerization monomer, photoinitiator, light Sensitizer be blended and be stirred into ultraviolet light solidification light-sensitive emulsion colloid it is spare;
(2) lamination equipment complex is set up, lamination equipment complex includes to adhesive dispenser, cloth adhesive dispenser and ultraviolet source;
(3) the ultraviolet light solidification light-sensitive emulsion colloid prepared in step (1) is injected to adhesive dispenser and is communicated to cloth adhesive dispenser On;
(4) level pressure is set to adhesive dispenser to mucilage binding described in step (3), which includes for loading purple to adhesive dispenser The level pressure of outer photocuring light-sensitive emulsion colloid to packing element and setting in level pressure in packing element, for controlling level pressure to ultraviolet in packing element Photocuring light-sensitive emulsion colloid is forced out with fixed pressure and injects the constant DP control block of cloth adhesive dispenser;
(5) ultraviolet light solidification light-sensitive emulsion colloid by cloth adhesive dispenser be uniformly coated to substrate cloth and organosilicone film it Between, and ultraviolet light solidification light-sensitive emulsion colloid solidification bond substrates cloth and organosilicone film is promoted by ultraviolet source irradiation, and Pressing device is arranged in the exit of cloth adhesive dispenser, and the warming composite surface of complete light-sensitive emulsion curing overlay film type air is made after compression Material.
Wherein, cloth mucilage binding is set to dispensing paddle, including including a plurality of painting adhesive tape being stitched together, applies adhesive tape and is equipped with Multiple upper rubber heads, ultraviolet source are the LED ultraviolet lamp being arranged in a one-to-one correspondence with gluing head, and ultraviolet light solidification light-sensitive emulsion colloid passes through Injected rubber hose is pressed into upper rubber head and uniformly squeezes between organosilicone film and substrate cloth, while LED ultraviolet lamp solidifies light to ultraviolet light Quick glue colloid, which is irradiated, to be allowed to be cured, then is compressed organosilicone film and substrate cloth by pressing device, repeatedly reciprocal Realization prepares the light-sensitive emulsion curing overlay film type air warming compound fabric of woven after operation.
Two groups of multilayer fabrics are prepared with the processing method of embodiment 2, it is as follows to test its mechanical performance:
First set product: seam slippage: 71-2mm, ultimate strength 800N, Tear strength > 26N, ultimate strength > 53N are protected Warm clo value=1.1-1.6.
First set product: seam slippage: 76-2mm, ultimate strength 835N, Tear strength > 33N, ultimate strength > 61N are protected Warm clo value=1.1-1.6.
According to the test parameter of above-described embodiment it is found that compared to traditional handicraft, the light-sensitive emulsion as made from this method is solid Diaphragm type air warming compound fabric thermal insulation property is covered in change and mechanical performance is more preferable, and the product control stability of woven is better than multilayer Fabric.
As described above, must not be explained although the present invention has been indicated and described referring to specific preferred embodiment For the limitation to invention itself.It without prejudice to the spirit and scope of the invention as defined in the appended claims, can be right Various changes can be made in the form and details for it.

Claims (6)

1. a kind of light-sensitive emulsion curing overlay film type air warming compound fabric, including substrate cloth, coating layer and adhesive layer, feature Be: the coating layer is organosilicone film of the thickness range in 0.015mm~0.05mm, and the adhesive layer is photosensitive binder Layer, the photosensitive binder layer are that ultraviolet light solidifies light-sensitive emulsion component composition, and the ultraviolet light solidification light-sensitive emulsion component includes matrix Photosensitive resin, photo polymerization monomer, photoinitiator, light sensitizer, the substrate cloth can be set to single-layer or multi-layer, single layer The light-sensitive emulsion curing overlay film type air warming compound fabric successively includes that substrate cloth, photosensitive binder layer and organosilicon are thin when setting Film, substrate cloth and organosilicone film are alternately laid in the light-sensitive emulsion curing overlay film type air warming compound fabric when multilayer is arranged And photosensitive binder layer is coated in each interlayer.
2. preparing the preparation method of light-sensitive emulsion curing overlay film type air warming compound fabric as described in claim 1, feature exists In: the following steps are included:
(1) pre-prepared ultraviolet light solidifies light-sensitive emulsion component, and matrix photosensitive resin, photo polymerization monomer, photoinitiator, light are increased sense Agent be blended and be stirred into ultraviolet light solidification light-sensitive emulsion colloid it is spare;
(2) lamination equipment complex is set up, lamination equipment complex includes to adhesive dispenser, cloth adhesive dispenser and ultraviolet source;
(3) the ultraviolet light solidification light-sensitive emulsion colloid prepared in step (1) is injected to adhesive dispenser and is communicated on cloth adhesive dispenser;
(4) level pressure is set to adhesive dispenser to mucilage binding described in step (3), which includes for loading ultraviolet light to adhesive dispenser Solidify the level pressure of light-sensitive emulsion colloid to packing element and setting in level pressure in packing element, for controlling level pressure to the UV light in packing element Change light-sensitive emulsion colloid to be forced out with fixed pressure and inject the constant DP control block of cloth adhesive dispenser;
(5) ultraviolet light solidification light-sensitive emulsion colloid is uniformly coated between substrate cloth and organosilicone film by cloth adhesive dispenser, and Ultraviolet light solidification light-sensitive emulsion colloid solidification bond substrates cloth and organosilicone film are promoted by ultraviolet source irradiation, and in cloth mucilage binding Pressing device is arranged in the exit set, and complete light-sensitive emulsion curing overlay film type air warming compound fabric is made after compression.
3. the preparation method according to claim 2 for preparing light-sensitive emulsion curing overlay film type air warming compound fabric, special Sign is: the light-sensitive emulsion curing overlay film type air warming compound fabric of required preparation includes single-layer fabric and multilayer composite lining.
4. the preparation method according to claim 3 for preparing light-sensitive emulsion curing overlay film type air warming compound fabric, special Sign is: when preparing single-layer fabric, the cloth mucilage binding is set to piece glue paddle, and the ultraviolet source is to be arranged in piece glue paddle The line style ultraviolet lamp of top.
5. the preparation method according to claim 4 for preparing light-sensitive emulsion curing overlay film type air warming compound fabric, special Sign is: described glue paddle includes being connected to be provided with into glue chamber and uniformly into the cloth glue on glue chamber in level pressure on packing element Hole.
6. the preparation method according to claim 3 for preparing light-sensitive emulsion curing overlay film type air warming compound fabric, special Sign is: when preparing Multilayer plus material, the cloth mucilage binding is set to dispensing paddle, and the dispensing paddle includes a plurality of splicing one The painting adhesive tape risen, the painting adhesive tape include being connected to level pressure applying adhesive tape lower surface with setting to injected rubber hose on packing element and be connected to note The upper rubber head of sebific duct, the ultraviolet source are that fixed point is equipped with the LED ultraviolet lamp in upper rubber head.
CN201910610559.9A 2019-07-03 2019-07-03 Light-sensitive emulsion curing overlay film type air warming compound fabric and preparation method thereof Pending CN110328904A (en)

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Citations (4)

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Publication number Priority date Publication date Assignee Title
JPH02114035A (en) * 1988-10-24 1990-04-26 Toray Ind Inc Base cloth for air bag of car
CN1387476A (en) * 1999-11-03 2002-12-25 奥怀欧姆斯奥普托医疗系统有限公司 Elastic composite structure
CN101528459A (en) * 2006-06-02 2009-09-09 霍尼韦尔国际公司 Multi-layer airbag using non-woven fabric and reinforced scrim
CN108138393A (en) * 2015-02-06 2018-06-08 住商安全气囊系统株式会社 Cylinder knits air bag

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02114035A (en) * 1988-10-24 1990-04-26 Toray Ind Inc Base cloth for air bag of car
CN1387476A (en) * 1999-11-03 2002-12-25 奥怀欧姆斯奥普托医疗系统有限公司 Elastic composite structure
CN101528459A (en) * 2006-06-02 2009-09-09 霍尼韦尔国际公司 Multi-layer airbag using non-woven fabric and reinforced scrim
CN108138393A (en) * 2015-02-06 2018-06-08 住商安全气囊系统株式会社 Cylinder knits air bag

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