CN110295496A - A kind of home textile fabric using hooker winghead root extract - Google Patents
A kind of home textile fabric using hooker winghead root extract Download PDFInfo
- Publication number
- CN110295496A CN110295496A CN201810247917.XA CN201810247917A CN110295496A CN 110295496 A CN110295496 A CN 110295496A CN 201810247917 A CN201810247917 A CN 201810247917A CN 110295496 A CN110295496 A CN 110295496A
- Authority
- CN
- China
- Prior art keywords
- hooker winghead
- winghead root
- home textile
- textile fabric
- obtains
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Medicines Containing Plant Substances (AREA)
Abstract
The present invention is a kind of home textile fabric using hooker winghead root extract, it is characterized by: the home textile extracts the manufactured microcapsules of effective component in hooker winghead root with being bonded on fabric by infusion process or padding method, the preparation of the home textile fabric the following steps are included: in (1), hooker winghead root effective component extraction；(2), effective component extracts in hooker winghead root are carried out with the preparation of microcapsules；(3), application of the microcapsules that in hooker winghead root prepared by effective component extracts on home textile fabric.The present invention is bonded on fabric after being prepared into microcapsules by effective component extracts in hooker winghead root, is obtained the home textile fabric for having good antibiotic property, is promoted the usage comfort of user.
Description
Technical field
The present invention relates to a kind of textile fabrics, especially disclose a kind of home textile fabric using hooker winghead root extract, will
Effective component in hooker winghead root is applied to home textile fabric, obtains the home textile fabric for having good antibiotic property, promotes user's
Usage comfort.
Background technique
As the improvement of consumer's living standards, consumer for quality of life improvement there has also been great demand, it is right
Also gradually increasing in the home textile product functional requirements used daily.For example most consumers are in purchase home textile product
When, there is 80% consumer that can select purchase that there is functional product according to investigations, although the price of these products can compare common product
Price be higher by two to three times, but they more value quality of life, the comfortable living environment of health.
Tibetan medicine hooker winghead root derives from Dipsacaceae, has critically important medical value, the diligent poison crow of the entitled list of Tibetan medicine, You Mingbang
Sub- poison crow.Cold in nature, bitter is slightly poisonous, has the effect of relieving superficies by cooling, the cool blood that clears away heart-fire, dispeling wind and dehumidification, anti-inflammatory, antibacterial, analgesic.
Tibetan medicine often treats fever caused by cold, fever and various warm heat diseases with it, in the heart dysphoria with smothery sensation, hemoptysis, haematemesis, hematuria, hematochezia
Equal diseases have apparent curative effect for treatment rheumatoid arthritis.Six kinds of iridoid glycosides in hooker winghead root medicinal ingredient
It is inhibited to six kinds of bacteriums and three kinds of fungies, especially there are good inhibiting effect, effect to staphylococcus aureus
It is suitable with Chinese Drug Rhizomes of Coptis.
At present both at home and abroad relevant enterprise, research institution and university in succession extract in hooker winghead root traditional Chinese medicine ingredients, medicinal ingredient
Many researchs have been made in detection, preparation, purposes etc., and all achieve certain effect.
Chinese patent: a kind of detection method of hooker winghead root (patent No.: 2,014 1 0403099.X of CN), it can be right simultaneously
Loganin in hooker winghead root, ursolic acid and oleanolic acid detection, and changed by simple eluent gradient be both able to achieve difference compared with
The separation and measurement of big loganin, ursolic acid and oleanolic acid, the actually detected demand of further satisfaction.Identification side described in it
Method: taking hooker winghead root powder 0.2g to be added in the conical flask of tool plug, and the close plug of methanol 80ml is added, and reflux or ultrasonic treatment 1.5h are let cool
Filtering, filtrate is concentrated into 10ml, as test solution；Get loganin, oleanolic acid reference substance adds methanol that 1ml is made and contains
The mixed solution of the oleanolic acid of 0.3mg loganin and 0.3mg.As reference substance solution；It is tested according to thin-layered chromatography, in absorption
Sample spot is stated in silica gel thin-layer chromatography version, is unfolded on solvent, taking-up is dried.
Chinese patent: hooker winghead root total saponin extracts and its preparation method and application (patent No.: CN 2,012 1
0061154.2) a kind of method for, disclosing hooker winghead root saponin extract, it is from Dipsacaceae plant spoon leaf hooker winghead root
Drying herb, the extraction species total saponin content be greater than 50%w/w, iridoid content be 0.5%w/w.While the invention is also
Disclose the preparation method and purposes of the extract.
Chinese patent: the detection method (patent No.: CN 2,014 1 0060399.2) of hooker winghead root medicinal material then provides wing head
The detection method of herbal medicine material, it is measured by fast liquid chromatography method UFLC.The invention patent is carried out using UFLC
Measurement can effectively separate chemical component in hooker winghead root, and characteristic peak is more in gained chromatogram, each batch of medicinal materials fingerprint phase
It is good like degree height, separating degree, precision, stability and reproducibility, and chromatography detection time, in 20min, detection efficiency is high.For
The detection of the effective component of hooker winghead root provides quick detection method.
If the effective component in hooker winghead root medicinal material is applied on home textile product, home textile product can be made to have good
Antibiotic property guarantees that product long-term safety is comfortable, has good market prospects, but there is presently no corresponding home textile product quilts
Exploitation.
Summary of the invention
Present invention aim to address the defects of the prior art, for the extracting and developing of hooker winghead root medicinal ingredient, microcapsules
Production program, all kinds of difficulties encountered in the finishing technique applied to home textile product, design a kind of application hooker winghead root and extract
Effective component in hooker winghead root is extracted and the system after microcapsules applied to home textile fabric is made by the home textile fabric of object
Make, obtains the home textile fabric for having good antibiotic property, promote the usage comfort of user.
The present invention is implemented as follows: a kind of home textile fabric using hooker winghead root extract, it is characterised in that: the family
Spinning is bonded with the manufactured microcapsules of effective component in extraction hooker winghead root by infusion process or padding method on fabric, and the wing is first
The effective component extracted in grass includes-sitosterol, oleanolic acid, Triterpenoids sapogenins saponins class compound and bear
Tartaric acid, the preparation of the home textile fabric the following steps are included:
(1), in hooker winghead root effective component extraction；
(2), effective component extracts in hooker winghead root are carried out with the preparation of microcapsules；
(3), application of the microcapsules that in hooker winghead root prepared by effective component extracts on home textile fabric.
In the step (1) in hooker winghead root the extraction of effective component process flow are as follows: take hooker winghead root coarse powder 3kg, use
Medicinal alcohol refluxing extraction obtains medicinal extract, is diluted with water, and centrifugation pours out leafiness, is added on macroporous absorbent resin, the absorption
Resin is D101Type, usage amount 1kg are washed with water to close colourless, then with mass percentage are 85% ethanol elution to nearly nothing
Color recycles ethyl alcohol, is dried in vacuo to obtain 250 ± 1g of yellow powder, gained powder is separated through the silicagel column of 200~300 mesh,
Then chloroform-methanol elution gradient is used, collects eluent, every part of 500ml is checked through TLC, merges different fractions, there are following
Four different components；
Component one is concentrated to dryness, obtains 17g buff powder, then petroleum ether-acetic acid at 60~90 DEG C is used in by silicagel column
Ester gradient elution collects eluent, and every part of 300ml is checked through TLC, merges 4~9 fractions, is concentrated to dryness, obtains yellow powder
End obtains colourless lump shaped crystalline object -1 ± 0.5g of sitosterol with methanol repeated recrystallize；
Component two is concentrated to dryness, obtains 30g buff powder, then petroleum ether-acetic acid at 60~90 DEG C is used in by silicagel column
Ester gradient elution collects eluent, and every part of 300ml is checked through TLC, merges 1~5 part, volatilizes solvent, obtain light jelly,
It is repeatedly washed with methanol, obtains 1.5 ± 0.5g of white powder oleanolic acid；
Component three is concentrated to dryness, obtains 40g buff powder, then by silicagel column, repeatedly with chloroform-methanol with 25 1~
21 gradient elution, obtains white powder, with methanol repeated recrystallize, obtains 30 ± 0.5mg of colourless powder rivularicin
；
Component four is concentrated to dryness, obtains 60g buff powder, then by silicagel column, repeatedly with chloroform-methanol with 10 1~
21 gradient elution, obtains white powder, with methanol repeated recrystallize, obtains 2 ± 0.5g of white powder ursolic acid.
It is gelatin and gum arabic in 11 ratios that the step (2), which selects wall material, will be effective in wall material and hooker winghead root
Component extract is then placed in pre-expansion axe by 1 1~1 5 mixing, is then passed through CO2, when temperature, pressure reaches setting
When value, solute is dissolved in supercritical CO2Saturated solution is formed, the saturated solution eventually formed is quick in precipitating axe by nozzle
It sprays, obtains the microcapsules that in hooker winghead root prepared by effective component extracts.
The step (3) first uses neopelex that will have in hooker winghead root made from step (2) as dispersing agent
The uniform microcapsule dispersion of component extract is imitated, then selecting aqueous polyurethane ADM-F209 is that solvent prepares finishing fluid, it is then right
Cotton fabric carries out microcapsules arrangement, most bonds the microcapsules of effective component extracts in hooker winghead root through aqueous polyurethane bonding afterwards
The home textile fabric finished product using hooker winghead root extract, the proportion of the finishing fluid are made on to cotton fabric are as follows:
Microcapsules: 30 g/l of 10g/l-,
Aqueous polyurethane: 150 g/l of 50g/l-,
Detergent alkylate naphthenic acid sodium: 5 g/l of 1g/l-,
Alkyl polyoxyethylene ether: 2 g/l of 0.5g/l-.
The padding method is an immersing and rolling or second dipping and rolling method.
The process flow of the infusion process are as follows: cotton fabric is impregnated into 30min in finishing fluid, the finishing fluid at 40 DEG C
Dosage be 3% (o.w.f), bath raio 1:15, be then dehydrated to liquid carrying rate be greater than 80%, then sequence at 80 DEG C into
Row preliminary drying 30min, bake, 30min washed at 70 DEG C, the soap flakes at 60 DEG C using 2g/l are soaped 10min and secondary washing process
Process, be made using hooker winghead root extract home textile fabric finished product, the temperature of the baking according to selected adhesive and
It is fixed.
The process flow of one immersing and rolling are as follows: cotton fabric is impregnated at room temperature in the finishing fluid of 30g/l, it is then suitable
Sequence is carried out rolling mill practice, preliminary drying 30min at 80 DEG C, bakes, 30min is washed at 70 DEG C, being soaped at 60 DEG C using the soap flakes of 2g/l
10min and secondary washing, are made the home textile fabric finished product using hooker winghead root extract, and the rolling mill practice pick-up is
70%, depending on the temperature of the baking is according to selected adhesive；
The process flow of the second dipping and rolling are as follows: cotton fabric is impregnated at room temperature in 20g/l finishing fluid, then sequence carries out
Rolling mill practice, double-steeping enter in finishing fluid, secondary rolling mill practice, preliminary drying 30min at 80 DEG C, bakes, washes at 70 DEG C
30min, the soap flakes at 60 DEG C using 2g/l are soaped 10min and secondary washing, and the home textile face using hooker winghead root extract is made
Expect that finished product, the rolling mill practice pick-up are 60%, depending on the temperature of the baking is according to selected adhesive.
There is suppression to six kinds of bacteriums and three kinds of fungies containing six kinds of iridoid glycosides in hooker winghead root Development of Pharmaceutical Microcapsules ingredient
Production is used, and especially has good inhibiting effect to staphylococcus aureus, effect is suitable with Chinese Drug Rhizomes of Coptis.It is used for home textile
On product, there is good antibacterial property, and product safety is comfortable, harmless, no pollution to the environment.
The beneficial effects of the present invention are: extracting difficult, this hair to its effective component because of the complicated component of hooker winghead root
The bright hooker winghead root medicinal ingredient that overcomes extracts difficult difficulty, and is made into micro- glue using the production method of Development of Pharmaceutical Microcapsules
Capsule is applied on home textile fabric, obtains the home textile product with antibiotic property with final, enjoys consumer in use
It is happy to the good life bring of health.The type of rich functionality home textile product increases the selection of consumer.The present invention will
The home textile product that Chinese medicinal health-care function and consumer will contact daily combines, and keeps consumer in use, impression health
Bring is happy, increases the comfortable experience effect of user.The hooker winghead root Chinese medicine microcapsules that the present invention designs are on home textile product
Using, on the one hand increase the type of home textile product, provide more choices for consumer, another aspect pure natural medical at
Point, to human body, environmentally friendly environmental protection, meets the green product that consumer in recent years is pursued, meet the purchase of consumer
Demand is bought, is had a vast market foreground.
Specific embodiment
The present invention is a kind of home textile fabric using hooker winghead root extract, comprising: 1, effective component mentions in hooker winghead root
It takes；2, effective component extracts in hooker winghead root are carried out with the preparation of microcapsules；3, effective component extracts preparation in hooker winghead root
Application of the microcapsules on home textile fabric.
The specific process steps are as follows:
1, in hooker winghead root effective component extraction
(1) hooker winghead root shape
Hooker winghead root root is cylindrical, and long 5~20cm, 1~2cm of diameter, surface sepia to dark brown, crust is easy to fall off, top
Often there is the rhizome of several distorted shapes to grow thickly；Body is light, and matter is crisp, frangibility, and section is uneven, and woody part white, phyllopodium is raw, celadon,
It has been crushed, intact leaf long lanceolar to oblong more.Full edge or pinniform are totally cleaved, and two sides is by coarse wool, flower base coat, head
Inflorescence is subsphaeroidal, 1.5~2.5cm of diameter, grey color to pale red；Sepal is featheriness.Gas is micro-, bitter.
(2) hooker winghead root powder
Hooker winghead root powder is taupe, and calcium oxalate cluster crystal is common, brilliant cusp, 12.14~38.88 μm of diameter.Spiral duct diameter
12.15~48.60 μm, 26.73~60.75 μm of reticulate vessel.Unicellular nonglandular hair is clear to, how cataclasm, and long 381.4~537.90
μm, 24.45~29.34 μm of diameter；Wall thickness, cell are smaller.Glandular hairs are rare, 8, glandular hairs head cell, major diameter 48.60~63.18
μm, 36.45~46.17 μm of minor axis；1 cell of seta, 18.23~31.59 μm of major diameter.17.01~26.73 μm of minor axis.Pollen
Grain is round, yellowish-brown, surface tool verruca, and germinal aperature 3,82.62~94.77 μm of diameter.Phellem layer fragment brown color, carefully
The nearly rectangle of born of the same parents, the accidental irregular block of rufous.
(3) hooker winghead root main chemical compositions
Hooker winghead root mainly contains saponin(e, iridoid and alkaloid and carbohydrate.It is the spy of Dipsacaceae plant rich in saponin component
One of point, by recent years to the Chemical Decomposition of hooker winghead root the study found that hooker winghead root mainly contains the five rings three of oleanane type
The ingredients such as terpene saponins, iridoids.By the methods of macroporous absorbent resin, silica gel column chromatography, divide from spoon leaf hooker winghead root
From having obtained 11 monomeric compounds, respectively four kinds of root of Hooker Winghead glycosides (A, B, C, D), oleanolic acid, the black alcohol of β paddy, palmitin
Acid, ursolic acid, β-gentiobiose, oleanolic acid -3-O- β-D xyloside, iridoid compound etc..Oleanolic acid has drop
Blood glucose, protect liver drop enzyme and apparent anti-inflammatory effect.Ursolic acid is widely present in the plant with anti-inflammatory effect, have it is stable,
Cooling, antibacterial, it is anti-inflammatory, drop enzyme the effects of.Wing head is observed using hot plate method, acetic acid writhing test, caused by dimethylbenzene xylene youngster's exterior feature swelling method
Careless extract part B has apparent anti-inflammatory, analgesic activity.
(4) measurement of content
The measurement of total saponin content extracts it significant.Using the content of spectrophotometry measurement total saposins, total saposins
One of index as medical material quanlity evaluation.Oleanolic acid, ursolic acid are measured using efficient liquid phase form and aspect method.Loganin is as the wing
One ingredient of rheumatoid arthritis, the high low reaction quality of medicinal material of ingredient are treated in first grass.
(5) separation is extracted
Hooker winghead root coarse powder 3kg is taken, medicinal extract is obtained with medicinal alcohol refluxing extraction, is diluted with water, is centrifuged, pours out leafiness, is added on big
On macroporous adsorbent resin, the absorption resin is D101Type, usage amount 1kg are washed with water to close colourless, then contained with quality percentage
Amount is 85% ethanol elution to close colourless, recycles ethyl alcohol, is dried in vacuo to obtain 250 ± 1g of yellow powder, by gained powder through 200~
The silicagel column of 300 mesh is separated, and chloroform-methanol elution gradient is then used, and collects eluent, and every part of 500ml is examined through TLC
It looks into, merges different fractions, there are following four difference component；
Component one is concentrated to dryness, obtains 17g buff powder, then petroleum ether-acetic acid at 60~90 DEG C is used in by silicagel column
Ester gradient elution collects eluent, and every part of 300ml is checked through TLC, merges 4~9 fractions, is concentrated to dryness, obtains yellow powder
End obtains colourless lump shaped crystalline object -1 ± 0.5g of sitosterol with methanol repeated recrystallize；
Component two is concentrated to dryness, obtains 30g buff powder, then petroleum ether-acetic acid at 60~90 DEG C is used in by silicagel column
Ester gradient elution collects eluent, and every part of 300ml is checked through TLC, merges 1~5 part, volatilizes solvent, obtain light jelly,
It is repeatedly washed with methanol, obtains 1.5 ± 0.5g of white powder oleanolic acid；
Component three is concentrated to dryness, obtains 40g buff powder, then by silicagel column, repeatedly with chloroform-methanol with 25 1~
21 gradient elution, obtains white powder, with methanol repeated recrystallize, obtains 30 ± 0.5mg of colourless powder rivularicin
；
Component four is concentrated to dryness, obtains 60g buff powder, then by silicagel column, repeatedly with chloroform-methanol with 10 1~
21 gradient elution, obtains white powder, with methanol repeated recrystallize, obtains 2 ± 0.5g of white powder ursolic acid.
2, effective component extracts in hooker winghead root are carried out with the preparation of microcapsules
Microencapsulation processes are the processes for forming one layer of continuous and thin wrapping layer in core material outer layer with shell material.According to tradition
Microcapsules classification method, chemical method, phase separation method and physical method can be divided into, traditional microcapsule preparation method has solvent evaporation
Method, coacervation, interfacial polymerization and spray drying process etc..These methods all use organic solvent, thus there are organic solvents to exist
Residual and pollution problem in product, and the operation temperature of many methods is relatively high are not suitable for drug and biological products
Microcapsules production.Such problems is not present in supercritical fluid microencapsulation technology at present, therefore uses supercritical fluid technique
Prepare Development of Pharmaceutical Microcapsules.
Supercritical fluid be a kind of temperature and pressure be in critical point or more to have both liquid without gas-liquid interface difference gentle
The substance phase of volume property.It has special solubility, the density of easy modulation, lower viscosity and higher delivery rate etc.
Property.
Development of Pharmaceutical Microcapsules is prepared at present there are mainly two types of technology, both RESS process method and supercritical anti-solvent
Method.RESS process method has many advantages in preparation nano material, but many substances such as high polymer or biochemistry
Solubility very little of the drug in supercritical fluid, has received limitation in this way.On the contrary, Supercritical anti-solvent is exactly sharp
With solute in supercritical CO2In solubility very little, work as supercritical CO2When being dissolved into solution, supercritical CO2When with solution
Between rapid mass transfer make solution dilution expansion, cohesion energy density reduce, to reduce former solvent to the solvability of solute, short
Biggish degree of supersaturation is formed in time and lolute crystallization is precipitated, and forms purity is high, the uniform particle of particle diameter distribution.
Selecting wall material is gelatin and gum arabic in 11 ratios, and effective component extracts in wall material and hooker winghead root are pressed
1 1~1 5 mixing are then placed in pre-expansion axe, are then passed through CO2, when temperature, pressure reaches setting value, solute dissolution
In supercritical CO2Saturated solution is formed, the saturated solution eventually formed is quickly sprayed in precipitating axe by nozzle, obtains wing head
The microcapsules that in grass prepared by effective component extracts.
Supercritical CO2Anti-solvent method has the advantage that by decrease temperature and pressure, organic solvent and CO is may be implemented in (1)2Point
From the purification process of simplified solvent；(2) due to supercritical CO2To the extraction of organic solvent, reduce the residual of organic solvent
Allowance；(3) distribution of partial size can be adjusted by pressure.(4) operation energy consumption is low and can be in relatively low high pressure conditions
The features such as lower operation.
(1) performance characterization of microcapsules
The characterization of properties of microcapsules is related with two factors, and (1) core material must completely be coated by shell material；(2) shell material
The medium factor of local environment, the transmission for being allowed to and being wrapped by core material are adapted.Core material in microcapsules passes through dissolution, infiltration
Thoroughly, the processes such as diffusion, release, rate of release passes through the chemical component of shell material, thickness, hardness and aperture through shell material
Size etc. is controlled.The release of microcapsules core material is divided into 3 stages；Drug dispersal events, poly- from microcapsule shell material
Hydrate hydrolysis makes shell material molecular weight become smaller and the dissolution of low molecule fragment.The property of microcapsules can be tested by high performance liquid chromatography
Energy.
3, application of the microcapsules that in hooker winghead root prepared by effective component extracts on home textile fabric
First use neopelex as dispersing agent by micro- glue of effective component extracts in hooker winghead root made from step (2)
Capsule is evenly dispersed, then selecting aqueous polyurethane ADM-F209 is that solvent prepares finishing fluid, and it is whole then to carry out microcapsules to cotton fabric
Reason is most bonded to the microcapsules of effective component extracts in hooker winghead root on cotton fabric through aqueous polyurethane bonding afterwards and application is made
The home textile of hooker winghead root extract fabric finished product.
The finishing fluid of the arrangement matches are as follows:
Microcapsules: 30 g/l of 10g/l-,
Aqueous polyurethane: 150 g/l of 50g/l-,
Detergent alkylate naphthenic acid sodium: 5 g/l of 1g/l-,
Alkyl polyoxyethylene ether: 2 g/l of 0.5g/l-.
The finishing technique uses infusion process or padding method, and an immersing and rolling or second dipping and rolling can be selected in the padding method
Method.
The infusion process process flow are as follows: cotton fabric is impregnated into 30min in finishing fluid, the finishing fluid at 40 DEG C
Dosage be 3% (o.w.f), bath raio 1:15, be then sequentially dehydrated (liquid carrying rate be greater than 80%), preliminary drying (80 DEG C ×
30min), bake (temperature is formulated according to selected adhesive), washing (70 DEG C × 30min), soap (2g/l soap flakes, 60 DEG C ×
10min) and secondary washing, the home textile fabric finished product using hooker winghead root extract is made.
The one immersing and rolling process flow are as follows:
Cotton fabric is impregnated at room temperature in the finishing fluid of 30g/l, then sequence carries out roll process (pick-up 70%), preliminary drying
(80 DEG C × 30min), bake (temperature is formulated according to selected adhesive), washing (70 DEG C × 30min), soap (2g/l soap flakes,
60 DEG C × 10min) and secondary washing, the home textile fabric finished product using hooker winghead root extract is made.
The second dipping and rolling process flow are as follows:
Cotton fabric is impregnated at room temperature in the finishing fluid of 20g/l, then sequence progress rolling mill practice, a double-steeping enter
In finishing fluid, secondary rolling mill practice (pick-up 60%), preliminary drying (80 DEG C × 30min), bakes, washes (70 DEG C × 30min), soap
(2g/l soap flakes, 60 DEG C × 10min) and secondary washing are washed, the home textile fabric finished product using hooker winghead root extract is made.
4, the microcapsules dosage of the home textile fabric of application hooker winghead root extract is tested
(1) influence of the microcapsules dosage to cotton fabric anti-microbial property
Antibacterial survey is carried out to cotton fabric using the evaluation second part (absorption process) of GB/T20944.2-2007 antibacterial textile
Examination, tests its bacteriostasis property to staphylococcus aureus, gram-positive bacteria and Gram-negative bacteria.
(2) influence of the microcapsules dosage to cotton fabric elastic recovery angle
According to GB/T3819-1997, using the creasy recovery angle of normal beam technique test fabric.
(3) influence of the microcapsules dosage to cotton fabric tensile property
According to GB/T3923-1997, the variation stretched surely for arranging front and back cotton fabric is tested using galley proof method, after arrangement
It is 5cm × 15cmd sample that cotton fabric, which is cut into size,.Rate of extension is 100mm/min, and stretching spacing is 100mm.To stretch
Ultimate strength and elongation size change to indicate.
Home textile produced by the present invention using hooker winghead root extract is as follows with fabric main technical performance index:
(1) weaving finished product washes size changing rate: through to ± 5%.Broadwise ± 5%
(2) weaving finished product color fastness: washable (discoloration, staining) >=3 grades
Perspiration resistance (discoloration, staining) >=3 grades
Resistance to dry friction >=3 grade, resistance to wet friction are 2~3 grades
(3) weaving finished product content of formaldehyde :≤75mg/kg
The present invention combines the home textile product that Chinese medicinal health-care function and consumer will contact daily, is using consumer
In, the healthy bring of impression is happy, increases the comfortable experience effect of user.
Claims (7)
1. a kind of home textile fabric using hooker winghead root extract, it is characterised in that: pass through infusion process on the home textile fabric
Or padding method is bonded with and extracts effective component and manufactured microcapsules in hooker winghead root, the effective component packet extracted in the hooker winghead root
- sitosterol, Triterpenoids sapogenins saponins class compound and ursolic acid are included, the preparation of the home textile fabric includes
Following steps:
(1), in hooker winghead root effective component extraction；
(2), effective component extracts in hooker winghead root are carried out with the preparation of microcapsules；
(3), application of the microcapsules that in hooker winghead root prepared by effective component extracts on home textile fabric.
2. a kind of home textile fabric using hooker winghead root extract according to claim 1, it is characterised in that: described
Step (3) first uses neopelex as dispersing agent by effective component extracts in hooker winghead root made from step (2)
Uniform microcapsule dispersion, then selecting aqueous polyurethane ADM-F209 is that solvent prepares finishing fluid, then carries out micro- glue to cotton fabric
Capsule arranges, and is most bonded to the microcapsules of effective component extracts in hooker winghead root on cotton fabric through aqueous polyurethane bonding afterwards and is made
Using the home textile fabric finished product of hooker winghead root extract, the proportion of the finishing fluid are as follows:
Microcapsules: 30 g/l of 10g/l-,
Aqueous polyurethane: 150 g/l of 50g/l-,
Detergent alkylate naphthenic acid sodium: 5 g/l of 1g/l-,
Alkyl polyoxyethylene ether: 2 g/l of 0.5g/l-.
3. a kind of home textile fabric using hooker winghead root extract according to claim 1, it is characterised in that: described
Padding method is an immersing and rolling or second dipping and rolling method.
4. a kind of home textile fabric using hooker winghead root extract according to claim 1, it is characterised in that: the leaching
The process flow of stain method are as follows: cotton fabric is impregnated into 30min in finishing fluid at 40 DEG C, the dosage of the finishing fluid is 3%
(o.w.f), then bath raio 1:15 is dehydrated to liquid carrying rate and is greater than 80%, then sequence is that preliminary drying is carried out at 80 DEG C
30min, bake, 30min washed at 70 DEG C, the soap flakes at 60 DEG C using 2g/l are soaped 10min and secondary washing process flow, system
The home textile fabric finished product using hooker winghead root extract is obtained, depending on the temperature of the baking is according to selected adhesive.
5. a kind of home textile fabric using hooker winghead root extract according to claim 3, it is characterised in that:
The process flow of one immersing and rolling are as follows: cotton fabric is impregnated at room temperature in the finishing fluid of 30g/l, then sequence into
Row rolling mill practice preliminary drying 30min at 80 DEG C, is baked, 30min is washed at 70 DEG C, soaped 10min using the soap flakes of 2g/l at 60 DEG C
And secondary washing, the home textile fabric finished product using hooker winghead root extract is made, the rolling mill practice pick-up is 70%, institute
Depending on the temperature of baking is stated according to selected adhesive；
The process flow of the second dipping and rolling are as follows: cotton fabric is impregnated at room temperature in 20g/l finishing fluid, then sequence carries out
Rolling mill practice, double-steeping enter in finishing fluid, secondary rolling mill practice, preliminary drying 30min at 80 DEG C, bakes, washes at 70 DEG C
30min, the soap flakes at 60 DEG C using 2g/l are soaped 10min and secondary washing, and the home textile face using hooker winghead root extract is made
Expect that finished product, the rolling mill practice pick-up are 60%, depending on the temperature of the baking is according to selected adhesive.
6. a kind of home textile fabric using hooker winghead root extract according to claim 1, it is characterised in that: described
In step (1) in hooker winghead root the extraction of effective component process flow are as follows: take hooker winghead root coarse powder 3kg, with medicinal alcohol reflux mention
Medicinal extract is obtained, is diluted with water, is centrifuged, is poured out leafiness, be added on macroporous absorbent resin, the absorption resin is D101Type makes
Dosage is 1kg, is washed with water to close colourless, then with mass percentage is 85% ethanol elution to close colourless, recycling ethyl alcohol, vacuum
Dry 250 ± 1g of yellow powder, gained powder is separated through the silicagel column of 200~300 mesh, then uses chloroform-methanol
Gradient elution collects eluent, and every part of 500ml is checked through TLC, merges different fractions, there are following four difference component；
Component one is concentrated to dryness, obtains 17g buff powder, then petroleum ether-acetic acid at 60~90 DEG C is used in by silicagel column
Ester gradient elution collects eluent, and every part of 300ml is checked through TLC, merges 4~9 fractions, is concentrated to dryness, obtains yellow powder
End obtains colourless lump shaped crystalline object -1 ± 0.5g of sitosterol with methanol repeated recrystallize；
Component two is concentrated to dryness, obtains 30g buff powder, then petroleum ether-acetic acid at 60~90 DEG C is used in by silicagel column
Ester gradient elution collects eluent, and every part of 300ml is checked through TLC, merges 1~5 part, volatilizes solvent, obtain light jelly,
It is repeatedly washed with methanol, obtains 1.5 ± 0.5g of white powder oleanolic acid；
Component three is concentrated to dryness, obtains 40g buff powder, then by silicagel column, repeatedly with chloroform-methanol with 25 1~
21 gradient elution, obtains white powder, with methanol repeated recrystallize, obtains 30 ± 0.5mg of colourless powder rivularicin
；
Component four is concentrated to dryness, obtains 60g buff powder, then by silicagel column, repeatedly with chloroform-methanol with 10 1~
21 gradient elution, obtains white powder, with methanol repeated recrystallize, obtains 2 ± 0.5g of white powder ursolic acid.
7. a kind of home textile fabric using hooker winghead root extract according to claim 1, it is characterised in that: described
It is gelatin and gum arabic in 11 ratios that step (2), which selects wall material, and effective component extracts in wall material and hooker winghead root are pressed 1
1~1 5 mixing are then placed in pre-expansion axe, are then passed through CO2, when temperature, pressure reaches setting value, solute is dissolved in
Supercritical CO2Saturated solution is formed, the saturated solution eventually formed is quickly sprayed in precipitating axe by nozzle, obtains hooker winghead root
The microcapsules of middle effective component extracts preparation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810247917.XA CN110295496A (en) | 2018-03-23 | 2018-03-23 | A kind of home textile fabric using hooker winghead root extract |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810247917.XA CN110295496A (en) | 2018-03-23 | 2018-03-23 | A kind of home textile fabric using hooker winghead root extract |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110295496A true CN110295496A (en) | 2019-10-01 |
Family
ID=68026036
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810247917.XA Pending CN110295496A (en) | 2018-03-23 | 2018-03-23 | A kind of home textile fabric using hooker winghead root extract |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110295496A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113136728A (en) * | 2021-04-22 | 2021-07-20 | 无锡万斯家居科技股份有限公司 | Method for applying cannabidiol extract to home textile fabric |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102352553A (en) * | 2011-07-29 | 2012-02-15 | 吴江兰瑞特纺织品有限公司 | Natural antimycotic textile containing tarragon extracts and preparation method thereof |
| CN104480724A (en) * | 2014-12-05 | 2015-04-01 | 南通大学 | Functional natural plant mosquito repelling ecological home textile product |
| CN104805704A (en) * | 2015-05-27 | 2015-07-29 | 天津滨海大田纺织有限公司 | Antimicrobial finishing method of wormwood essential oil microcapsules to cotton fabrics |
| CN104878608A (en) * | 2015-06-08 | 2015-09-02 | 苏州威尔德工贸有限公司 | Degradable antibacterial microcapsule for textile use and preparation method thereof |
| CN107326660A (en) * | 2017-06-26 | 2017-11-07 | 苏州威尔德工贸有限公司 | A kind of preparation method of anti-bacterial textile finishing agent |
-
2018
- 2018-03-23 CN CN201810247917.XA patent/CN110295496A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102352553A (en) * | 2011-07-29 | 2012-02-15 | 吴江兰瑞特纺织品有限公司 | Natural antimycotic textile containing tarragon extracts and preparation method thereof |
| CN104480724A (en) * | 2014-12-05 | 2015-04-01 | 南通大学 | Functional natural plant mosquito repelling ecological home textile product |
| CN104805704A (en) * | 2015-05-27 | 2015-07-29 | 天津滨海大田纺织有限公司 | Antimicrobial finishing method of wormwood essential oil microcapsules to cotton fabrics |
| CN104878608A (en) * | 2015-06-08 | 2015-09-02 | 苏州威尔德工贸有限公司 | Degradable antibacterial microcapsule for textile use and preparation method thereof |
| CN107326660A (en) * | 2017-06-26 | 2017-11-07 | 苏州威尔德工贸有限公司 | A kind of preparation method of anti-bacterial textile finishing agent |
Non-Patent Citations (2)
| Title |
|---|
| 刘圆等: "《中国民族药物学概论》", 30 November 2007 * |
| 张艺等: "藏药翼首草化学成分的研究", 《成都中医药大学学报》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113136728A (en) * | 2021-04-22 | 2021-07-20 | 无锡万斯家居科技股份有限公司 | Method for applying cannabidiol extract to home textile fabric |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101444570B (en) | Niuhuangshangqing soft capsule and preparation method thereof | |
| CN101057926B (en) | Gynaecologic menstruation regulating preparation for treating gynecopathy and its preparation method and detection method | |
| CN102580033B (en) | Medicinal composition for treating skin injury and quality detection method | |
| CN102220648A (en) | Preparation method of traditional Chinese medicine velvet viscose fiber | |
| CN1961929A (en) | 'Yi Kang Bu Yuan' formulation for benefiting qi, moving blood, invigorating spleen and tonifying kidney, its preparation method and quality control method | |
| CN110295496A (en) | A kind of home textile fabric using hooker winghead root extract | |
| CN107315061A (en) | A kind of method of quality control for the alizarin root of Dahurian angelica Chinese medicine preparation for treating uterus bleeding | |
| CN105367581B (en) | A kind of preparation method of phillygenol | |
| CN101015646B (en) | Preparation for treating hyperlipoidemia and its preparing process | |
| CN1895552A (en) | Preparation of compound mixture and its inspection | |
| CN109528901A (en) | Red gold disappears the preparation process of sheeting | |
| CN101439152B (en) | Chinese medicinal composition for treating cataract as well as preparation method | |
| CN102048991B (en) | Sugar-reducing comfort pill and preparation method thereof | |
| CN104147091A (en) | Method for preparing fermented soybean formula granules and quality control method of fermented soybean formula granules | |
| Chaturvedi et al. | Pharmacognostical, phytochemical and cardioprotective activity of Tamarinds indica Linn. Bark | |
| CN1951417A (en) | Quality control method of a pharmaceutical composition | |
| CN105288173B (en) | A kind of the traditional Chinese medicine pellet preparation and preparation method of menstruation-regulating and speckle-dispelling | |
| CN101285814A (en) | Xinkeshu tablet inspection method | |
| CN102552623B (en) | Chinese medicine for nourishing yin, tonifying kidney, producing sperm and filling marrow and preparation method thereof | |
| CN100490868C (en) | Preparing method of coated Tongshu tablet | |
| CN102944641A (en) | Method for detecting medicinal material of Ranunculaceae plant radix paeoniae alba | |
| CN102631395A (en) | Rape pollen dispersible tablet for treating prostatitis and preparation method of rape pollen dispersible tablet | |
| Huang et al. | Film-Controlled Synchronized Release Multicomponent Preparations of Chinese Materia Medica for Oral Administration | |
| CN107468590A (en) | A kind of anti-inflammatory Whelk-eliminating paste and preparation method thereof | |
| CN107737146A (en) | Panax japonicus piece and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191001 |
|
| RJ01 | Rejection of invention patent application after publication |