CN110272784A - A kind of bathroom detergent and preparation method thereof containing citrus reticulata"Chachi" blueness mandarin orange juice - Google Patents
A kind of bathroom detergent and preparation method thereof containing citrus reticulata"Chachi" blueness mandarin orange juice Download PDFInfo
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- CN110272784A CN110272784A CN201910608266.7A CN201910608266A CN110272784A CN 110272784 A CN110272784 A CN 110272784A CN 201910608266 A CN201910608266 A CN 201910608266A CN 110272784 A CN110272784 A CN 110272784A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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Abstract
The present invention relates to daily-use chemical industries and resource environment waste utilization technical field, specifically disclose a kind of bathroom detergent and preparation method thereof containing citrus reticulata"Chachi" blueness mandarin orange juice.The bathroom detergent includes: 30-80 parts of citrus reticulata"Chachi" blueness mandarin orange juice, 3-6.5 parts of surfactant, 0.5-5 parts of auxiliary agent, 8.5-66.5 parts of deionized water in terms of mass fraction.Immature citrus reticulata"Chachi" mandarin orange meat is produced the bathroom detergent of cleaning dirt in daily life by the present invention by remanufacturing processing technology, is turned waste into wealth, is comprehensively utilized, realize the recycling of citrus reticulata"Chachi" mandarin orange meat resource.Simple production process, preparation method are practical, it can be achieved that large-scale industrial production.Product is quality-high and inexpensive, and cleaning effect is good, wide market, and economic value is significant with the value of environmental protection.
Description
Technical field
The invention belongs to daily-use chemical industries and resource environment waste utilization technical field, and in particular to one kind is green containing citrus reticulata"Chachi"
The bathroom detergent and preparation method thereof of mandarin orange juice.
Background technique
Bathroom detergent contains organic acid compound, has the function of removing rust stain, scale, urine stain, grease stain, soap spot, will not
Material surface and its attachment are injured, and has disinfection, wards off smelly effect, and using leaving fresh scent after this product.Bathroom detergent can
It is widely used in the spots such as cleaning bathtub, hand basin, urine slot, toilet bowl, porcelain dish, ceramic tile, mosaic, terrazzo, mosaic tile.
The phenomenon that orange peel of citrus reticulata"Chachi" is the primary raw material for making " citrus chachiensis hortorum ", causes " the expensive meat of skin is low-priced ", in recent years
The phenomenon that random row of mandarin orange meat leaves about obtains the control of government department, but is still one important for the recycling of citrus reticulata"Chachi" mandarin orange meat
Subject under discussion, have the utilization in " biologic ferment " direction in the development and utilization of mandarin orange meat, but ask based on technology and to what mandarin orange meat required
Topic can not accomplish large area covering production, be the raw material for being not suitable as ferment, therefore particularly with immature mandarin orange meat
For immature mandarin orange meat or even most mandarin orange meat newly can area be still to be buried using after the processing of environmental sanitation department
Mode is handled.Therefore for citrus reticulata"Chachi" processing industry, the processing for mandarin orange meat is also many expense.
Its main sour agent of bathroom detergent in the prior art is mainly sodium hypochlorite, hydrochloric acid, citric acid etc., but with tea
Organic mixed acid in branch mandarin orange mandarin orange meat be the bathroom detergent of sour agent not yet, therefore be badly in need of a kind of easy, reliable, it can be achieved that greatly
The immature citrus reticulata"Chachi" mandarin orange meat method of personal batch harmless treatment that area is promoted.
Summary of the invention
The technical problems to be solved by the present invention are: for the limitation of sour agent main in bathroom detergent in the prior art
The deficiency underused with the immature mandarin orange meat of citrus reticulata"Chachi" provides a kind of bathroom detergent containing green mandarin orange juice and its preparation side
Method.It is a primary object of the present invention to produce immature citrus reticulata"Chachi" mandarin orange meat in daily life by remanufacturing processing technology
The bathroom detergent that dirt is cleaned in work, turns waste into wealth, and comprehensively utilizes, realizes the recycling of citrus reticulata"Chachi" mandarin orange meat resource.
Simple production process, preparation method is practical, it can be achieved that large-scale industrial production, economic value are significant with the value of environmental protection.
The present invention adopts the following technical scheme that, Lai Shixian goal of the invention.
Firstly, the invention discloses a kind of bathroom detergents containing citrus reticulata"Chachi" blueness mandarin orange juice.
The bathroom detergent is in terms of mass fraction, including following raw material: 30-80 parts of citrus reticulata"Chachi" blueness mandarin orange juice, surfactant
3-6.5 parts, 0.5-5 parts of auxiliary agent, 8.5-66.5 parts of deionized water.
Further, the citrus reticulata"Chachi" blueness mandarin orange juice preparation method the following steps are included:
(1) immature citrus reticulata"Chachi" mandarin orange meat is carried out meat mincing processing by masticator by；
(2) carries out first time coarse filtration to meat mincing, and settle and separate goes out fruit stone, pulp and green mandarin orange mixture；
(3) carries out smart filtering to green mandarin orange mixture, stands, isolates green mandarin orange juice and pulp；
(4) green mandarin orange juice PH meter measurement of the to separating, and PH to 2.0-2.2 is adjusted with sodium citrate.
Further, the masticator is industrial masticator or household masticator.
Further, the coarse filtration, device are made of three layers of stainless steel filter screen, wherein second layer crude separation
Pulp out, third layer essence isolate pulp；Three layers of stainless steel filter screen, screen size are respectively as follows:
One layer of 16-20 mesh (1.18-0.85mm), second layer 50-70 mesh (0.3-0.212mm), third layer are 230-260 mesh.
Further, the essence filtering, pore size filter are 50-80 microns, and filter device is pumping and filtering device or filters pressing
Equipment or centrifuge.
Further, the surfactant includes: 1-2.5 parts of anionic surfactant in terms of mass fraction, non-
1-2 parts of ionic surface active agent, 1-2 parts of zwitterionic surfactant.
Further, methyl sodiosul foaliphatate (MES, content that the anionic surfactant is 0.3-1 parts
>=35%), 0.7-1.5 parts of α sodium olefin sulfonates (AOS, content >=92%).
Further, the zwitterionic surfactant is that (CHSB contains cocamidopropyl propyl amide hydroxy sulfo lycine
Amount >=35%).
Further, the nonionic surfactant be fatty alcohol polyoxyethylene ether (AEO-9, content >=
99%).
Further, the auxiliary agent, in terms of mass fraction include: 0.1-1 parts bacteriostatic preservative, 0.4-0.8 parts of chlorine
Change sodium (NaC l, content >=99%), suitable acidity regulator.
Further, the preservative is potassium sorbate；The acidity regulator is sodium citrate；
Further, the auxiliary agent further includes suitable essence and/or pigment.
Secondly, the invention discloses a kind of preparation methods of bathroom detergent containing citrus reticulata"Chachi" blueness mandarin orange juice.
The preparation method of the bathroom detergent the following steps are included:
S1. immature citrus reticulata"Chachi" mandarin orange meat the preparation of citrus reticulata"Chachi" blueness mandarin orange juice: is subjected to meat mincing processing by masticator；To broken
Meat carries out first time coarse filtration, and settle and separate goes out fruit stone, pulp and green mandarin orange mixture；Smart mistake is carried out to green mandarin orange mixture
Filter stands, isolates green mandarin orange juice and pulp；Green mandarin orange juice PH meter measurement to separating, and adjusted with sodium citrate
PH to 2.0-2.2；
S2. the preparation of bathroom detergent: according to the quality proportioning of bathroom detergent, fatty acid methyl ester sulfonic acid is weighed respectively
The solutes such as sodium, α sodium olefin sulfonate, secondary alcohol AEO-9, cocamidopropyl propyl amide hydroxy sulfo lycine, sodium chloride, potassium sorbate, and add
Enter in citrus reticulata"Chachi" blueness mandarin orange juice, supply volume with deionized water, under normal pressure, stirring, heating condition, makes in citrus reticulata"Chachi" blueness mandarin orange juice
Each solute sufficiently dissolves, and adjusts PH to 2.0-2.2 with suitable sodium citrate；The heating are as follows: 60-65 DEG C of heating temperature,
Heating time 5-10 minute.
S3. it examines and packs.
Finally, the present invention discloses a kind of application of bathroom detergent containing citrus reticulata"Chachi" blueness mandarin orange juice.It should be green containing citrus reticulata"Chachi"
The bathroom detergent of mandarin orange juice is for bathroom, the clean environment of toilet.
The utility model has the advantages that
(1) present invention turns waste into wealth, and comprehensive utilization adequately achieves the recycling of citrus reticulata"Chachi" mandarin orange meat resource.The present invention
Immature citrus reticulata"Chachi" mandarin orange meat is produced to the bathroom cleaner of cleaning dirt in daily life by remanufacturing processing technology
Agent is turned waste into wealth, and comprehensive utilization realizes the recycling of citrus reticulata"Chachi" mandarin orange meat resource.Simple production process, preparation method are real
With, it can be achieved that large-scale industrial production, economic value are significant with the value of environmental protection.
(2) bathroom detergent of the invention, environmentally protective, biological degradability is good, bio-toxicity is low.Citrus reticulata"Chachi" blueness mandarin orange juice was both
It is organic mixed acid agent of natural green, and is the Normal juice solvent of plant of having drawn from, the present invention is made organic with citrus reticulata"Chachi" blueness mandarin orange juice
Sour agent and primary solvent, greatly reduce the addition of other sour agent of chemistry, at the same compare a variety of solutes to reference to a large amount of related
On the basis of document, other satisfactory auxiliary agents and solute are filtered out, so that the preparation-obtained bathroom detergent of the present invention,
Biological degradability is good, bio-toxicity is low, environmentally protective.
(3) bathroom detergent of the invention, cleaning effect is good, and production cost is low, wide market.The present invention is sufficiently sharp
Mandarin orange meat waste after making " citrus chachiensis hortorum " of local citrus reticulata"Chachi", purchasing price is cheap, and production cost is low；In citrus reticulata"Chachi" blueness mandarin orange
In juice in addition to containing a large amount of organic mixed acid agent, also contain a large amount of natural pectin and natural solute, natural pectin and day
Containing complicated surfactant a variety of, cleaning capacity is strong in right solute, while during preparing bathroom detergent, people is researched and developed
Member filters out other satisfactory auxiliary agents and solute on the basis of comparing a variety of solutes and with reference to relative literature,
Natural pectin, natural solute are compounded with other solutes screened, and generate synergistic effect, and cleaning effect is substantially increased
Fruit reduces dosage so that the preparation-obtained bathroom detergent of the present invention, foaming properties, detergency, stability,
Wall built-up is all substantially better than bathroom detergent commodity in the prior art, and cleaning effect is good, wide market.
Specific embodiment
The present invention is further illustrated combined with specific embodiments below, but the present invention is not limited to following embodiments.
The method is conventional method unless otherwise instructed.The raw material can obtain unless otherwise instructed from public commercial source
?.
Embodiment 1: the preparation of citrus reticulata"Chachi" blueness mandarin orange juice
(1) collects the mandarin orange meat waste after immature citrus reticulata"Chachi" production " citrus chachiensis hortorum ", passes through industrial masticator or household
Immature citrus reticulata"Chachi" mandarin orange meat is carried out meat mincing processing by masticator；
(2) carries out coarse filtration to meat mincing, wherein the second layer by the coarse filter device equipped with three layers of stainless steel filter screen
Rough segmentation separates out pulp, and third layer essence isolates pulp, and settle and separate goes out fruit stone, pulp and green mandarin orange mixture；
The screen size of three layers of stainless steel filter screen is respectively as follows: first layer 16-20 mesh (1.18-0.85mm), second layer 50-70 mesh
(0.3-0.212mm), third layer are 230-260 mesh；
(3) carries out smart filtering to green mandarin orange mixture by the fine filtering apparatus equipped with aperture for 50-80 micron screen,
It stands, isolates green mandarin orange juice and pulp；Its filter device can be pumping and filtering device or filtering equipment or centrifuge；
(4) green mandarin orange juice PH meter measurement of the to separating, and PH to 2.0-2.2 is adjusted with sodium citrate, obtain tea branch
Mandarin orange blueness mandarin orange juice.
Embodiment 2: the orthogonal of four kinds of activating agent proportion dosages in bathroom detergent
(1) orthogonal gauge outfit design (uses 34Four factors, three level design):
Foaming properties by GB/T 13173-2008 " surfactant detergent test method " " detergent foaming power
Measurement (Ross-Mi les method) " method be measured；
" development of toilet cleaner and analysis test method are visited for detergency, stability, the reference of wall built-up test method
Beg for --- Gao Zhihong " method tested in a text is measured.
(2) foaming properties Orthogonal Experiment and Design and test result are as follows
Orthogonal is carried out with initial foam height (and foam height after 5min), obtains 1%MES, 1%AOS, 1.5%
The activating agent proportioning effect of AEO-9,1.5%CHSB are best.
(3) detergency, stability Orthogonal Experiment and Design and test result are as follows
Orthogonal is carried out with detergency, obtains 0.5%MES, 1%AOS, 0.75-2.25%AEO-9,1.5%CHSB
It is best that activating agent matches cleaning effect effect.
(4) wall built-up is tested
It is with activating agent proportion 0.5%MES, 1%AOS, 1.5%AEO-9,1.5%CHSB of above-mentioned orthogonal proportioning test 4
Basis adds sodium chloride 0.3%, 0.4%, 0.5%, 0.6% respectively and carries out wall built-up test, as a result as follows:
| Sodium chloride content | 0.3% | 0.4% | 0.5% | 0.6% |
| The wall built-up time (S) | 25 | 45 | 65 | 75 |
Adding sodium chloride is preferably 0.6%.
Comprehensively consider for above-mentioned foaming properties, detergency, stability orthogonal experiments, bathroom cleaner of the invention
Agent, it is 0.5%MES, 1%AOS, 1.5%AEO-9,1.5%CHSB that activating agent, which matches optimum combination, and with this optimum combination
The appropriate protection scope that expands is to 0.3-1.0%MES, 0.7-1.5%AOS, 1-2%AEO-9,1-2%CHSB, 0.4-0.8% chlorine
Change sodium preferably.
Embodiment 3: the preparation of the bathroom detergent A containing citrus reticulata"Chachi" blueness mandarin orange juice
(1) quality proportioning of bathroom detergent A are as follows: embodiment 1 prepares resulting citrus reticulata"Chachi" blueness mandarin orange juice 60%, fatty acid methyl
Ester sodium sulfonate (MES, content 35%) 0.5%, α sodium olefin sulfonate (AOS, content 92%) 1.0%, fatty alcohol polyoxyethylene ether
(secondary alcohol AEO-9, content 99%) 1.5%, cocamidopropyl propyl amide hydroxy sulfo lycine (CHSB, content 35%) 1.5%, sodium chloride
(content 99%) 0.6%, potassium sorbate 0.2%, surplus are deionized water；
(2) methyl sodiosul foaliphatate, α sodium olefin sulfonate, secondary alcohol AEO-9, cocamidopropyl propyl amide hydroxyl sulfo group are weighed respectively
Solutes such as glycine betaine, sodium chloride, potassium sorbate, and being added in citrus reticulata"Chachi" blueness mandarin orange juice, supply volume with deionized water, normal pressure,
Under stirring, heating condition, dissolve each solute in citrus reticulata"Chachi" blueness mandarin orange juice sufficiently；The heating are as follows: 60 DEG C of heating temperature, add
10 minutes hot time adjusted PH to 2.0-2.2 with suitable sodium citrate.
(3) it examines and packs.Obtain bathroom detergent A.
Embodiment 4: the preparation of the bathroom detergent B containing citrus reticulata"Chachi" blueness mandarin orange juice
(1) quality proportioning of bathroom detergent B are as follows: embodiment 1 prepares resulting citrus reticulata"Chachi" blueness mandarin orange juice 30%, fatty acid methyl
Ester sodium sulfonate (MES, content 35%) 0.5%, α sodium olefin sulfonate (AOS, content 92%) 1.0%, fatty alcohol polyoxyethylene ether
(secondary alcohol AEO-9, content 99%) 1.5%, cocamidopropyl propyl amide hydroxy sulfo lycine (CHSB, content 35%) 1.5%, sodium chloride
(content 99%) 0.6%, potassium sorbate 0.2%, surplus are deionized water；
(2) methyl sodiosul foaliphatate, α sodium olefin sulfonate, secondary alcohol AEO-9, cocamidopropyl propyl amide hydroxyl sulfo group are weighed respectively
Solutes such as glycine betaine, sodium chloride, potassium sorbate, and being added in citrus reticulata"Chachi" blueness mandarin orange juice, supply volume with deionized water, normal pressure,
Under stirring, heating condition, dissolve each solute in citrus reticulata"Chachi" blueness mandarin orange juice sufficiently；The heating are as follows: 60 DEG C of heating temperature, add
10 minutes hot time adjusted PH to 2.0-2.2 with suitable sodium citrate.
(3) it examines and packs.Obtain bathroom detergent B.
Embodiment 5: the preparation of the bathroom detergent C containing citrus reticulata"Chachi" blueness mandarin orange juice
(1) quality proportioning of bathroom detergent C are as follows: embodiment 1 prepares resulting citrus reticulata"Chachi" blueness mandarin orange juice 80%, fatty acid methyl
Ester sodium sulfonate (MES, content 35%) 0.5%, α sodium olefin sulfonate (AOS, content 92%) 1.0%, fatty alcohol polyoxyethylene ether
(secondary alcohol AEO-9, content 99%) 1.5%, cocamidopropyl propyl amide hydroxy sulfo lycine (CHSB, content 35%) 1.5%, sodium chloride
(content 99%) 0.6%, potassium sorbate 0.2%, surplus are deionized water；
(2) methyl sodiosul foaliphatate, α sodium olefin sulfonate, secondary alcohol AEO-9, cocamidopropyl propyl amide hydroxyl sulfo group are weighed respectively
Solutes such as glycine betaine, sodium chloride, potassium sorbate, and being added in citrus reticulata"Chachi" blueness mandarin orange juice, supply volume with deionized water, normal pressure,
Under stirring, heating condition, dissolve each solute in citrus reticulata"Chachi" blueness mandarin orange juice sufficiently；The heating are as follows: 60 DEG C of heating temperature, add
10 minutes hot time adjusted PH to 2.0-2.2 with suitable sodium citrate.
(3) it examines and packs.Obtain bathroom detergent C.
Embodiment 6: the preparation of the bathroom detergent D containing citrus reticulata"Chachi" blueness mandarin orange juice
(1) quality proportioning of bathroom detergent D are as follows: embodiment 1 prepares resulting citrus reticulata"Chachi" blueness mandarin orange juice 60%, fatty acid methyl
Ester sodium sulfonate (MES, content 35%) 0.3%, α sodium olefin sulfonate (AOS, content 92%) 0.7%, fatty alcohol polyoxyethylene ether
(secondary alcohol AEO-9, content 99%) 1.0%, cocamidopropyl propyl amide hydroxy sulfo lycine (CHSB, content 35%) 1.0%, sodium chloride
(content 99%) 0.4%, potassium sorbate 0.1%, surplus are deionized water；
(2) methyl sodiosul foaliphatate, α sodium olefin sulfonate, secondary alcohol AEO-9, cocamidopropyl propyl amide hydroxyl sulfo group are weighed respectively
Solutes such as glycine betaine, sodium chloride, potassium sorbate, and being added in citrus reticulata"Chachi" blueness mandarin orange juice, supply volume with deionized water, normal pressure,
Under stirring, heating condition, dissolve each solute in citrus reticulata"Chachi" blueness mandarin orange juice sufficiently；The heating are as follows: 60 DEG C of heating temperature, add
10 minutes hot time adjusted PH to 2.0-2.2 with suitable sodium citrate.
(3) it examines and packs.Obtain bathroom detergent D.
Embodiment 7: the preparation of the bathroom detergent E containing citrus reticulata"Chachi" blueness mandarin orange juice
(1) quality proportioning of bathroom detergent E are as follows: embodiment 1 prepares resulting citrus reticulata"Chachi" blueness mandarin orange juice 60%, fatty acid methyl
Ester sodium sulfonate (MES, content 35%) 1.0%, α sodium olefin sulfonate (AOS, content 92%) 1.5%, fatty alcohol polyoxyethylene ether
(secondary alcohol AEO-9, content 99%) 2.0%, cocamidopropyl propyl amide hydroxy sulfo lycine (CHSB, content 35%) 2.0%, sodium chloride
(content 99%) 0.8%, potassium sorbate 0.5%, surplus are deionized water；
(2) methyl sodiosul foaliphatate, α sodium olefin sulfonate, secondary alcohol AEO-9, cocamidopropyl propyl amide hydroxyl sulfo group are weighed respectively
Solutes such as glycine betaine, sodium chloride, potassium sorbate, and being added in citrus reticulata"Chachi" blueness mandarin orange juice, supply volume with deionized water, normal pressure,
Under stirring, heating condition, dissolve each solute in citrus reticulata"Chachi" blueness mandarin orange juice sufficiently；The heating are as follows: 65 DEG C of heating temperature, add
5 minutes hot time adjusted PH to 2.0-2.2 with suitable sodium citrate.
(3) it examines and packs.Obtain bathroom detergent E.
Embodiment 8: the preparation (comparative example) of the bathroom detergent F without citrus reticulata"Chachi" blueness mandarin orange juice
Embodiment 3 formula in remove citrus reticulata"Chachi" blueness mandarin orange juice addition, make solvent with deionized water entirely, with citric acid and/
Or sodium citrate makees sour agent.That is:
(1) quality proportioning of bathroom detergent F are as follows: methyl sodiosul foaliphatate (MES, content 35%) 0.5%, α alkenyl
Sodium sulfonate (AOS, content 92%) 1.0%, fatty alcohol polyoxyethylene ether (secondary alcohol AEO-9, content 99%) 1.5%, coconut oleoyl amine
Hydroxysultaine (CHSB, content 35%) 1.5%, sodium chloride (content 99%) 0.6%, potassium sorbate 0.2%, surplus
For deionized water；
(2) methyl sodiosul foaliphatate, α sodium olefin sulfonate, secondary alcohol AEO-9, cocamidopropyl propyl amide hydroxyl sulfo group are weighed respectively
Solutes such as glycine betaine, sodium chloride, potassium sorbate, and being added in citrus reticulata"Chachi" blueness mandarin orange juice, supply volume with deionized water, normal pressure,
Under stirring, heating condition, dissolve each solute sufficiently；The heating are as follows: 60 DEG C of heating temperature, heating time 10 minutes, use
Suitable citric acid and/or sodium citrate adjust PH to 2.0-2.2.
(3) it examines and packs.Obtain bathroom detergent F.
The clean-up performance of bathroom detergent A-F is tested
Foaming properties by GB/T 13173-2008 " surfactant detergent test method " " detergent foaming power
Measurement (Ross-Miles method) " method be measured；Detergency, stability, wall built-up test method quote " toilet cleaner
Development and analysis test method inquire into --- Gao Zhihong " method tested in a text is measured.
Bathroom detergent A-F prepared by embodiment 3-8 is subjected to clean-up performance test, the results list is compared as follows:
It was found from the test of above-mentioned clean-up performance:
The stability of bathroom detergent A-F is under hot/cold environment without emulsification deposited phenomenon.
To foam height, detergency after bathroom detergent A-F progress initial foam height, 5min, it is compared simultaneously
Descending sequence are as follows: C > E > A > D > B > > F.Illustrating that contained blueness mandarin orange juice is bigger in bathroom detergent, clean-up performance is better, without
Bathroom detergent F containing green mandarin orange juice, clean-up performance are relatively minimum；Under contained green mandarin orange juice same case, added four kinds of tables
Face active agent content is higher, and clean-up performance is better.
Specific embodiments of the present invention are described in detail above, but it is merely an example, the present invention is simultaneously unlimited
It is formed on above description specific embodiment.To those skilled in the art, the equivalent modifications and replace that any couple of present invention carries out
In generation, is also all among scope of the invention.Therefore, without departing from the spirit and scope of the invention made by equal transformation and repair
Change, all covers within the scope of the present invention.
Claims (10)
1. a kind of bathroom detergent containing citrus reticulata"Chachi" blueness mandarin orange juice, which is characterized in that in terms of mass fraction, including following raw material:
30-80 parts of citrus reticulata"Chachi" blueness mandarin orange juice, 3-6.5 parts of surfactant, 0.5-5 parts of auxiliary agent, 8.5-66.5 parts of deionized water.
2. a kind of bathroom detergent containing citrus reticulata"Chachi" blueness mandarin orange juice according to claim 1, it is characterised in that: the tea branch
The preparation method of mandarin orange blueness mandarin orange juice the following steps are included:
(1) immature citrus reticulata"Chachi" mandarin orange meat is carried out meat mincing processing by；
(2) carries out first time coarse filtration to meat mincing, and settle and separate goes out fruit stone, pulp and green mandarin orange mixture；
(3) carries out smart filtering to green mandarin orange mixture, stands, isolates green mandarin orange juice and pulp；
(4) adjusts PH to 2.0-2.2 to the green mandarin orange juice sodium citrate separated.
3. a kind of bathroom detergent containing citrus reticulata"Chachi" blueness mandarin orange juice according to claim 1, which is characterized in that the surface
Activating agent, include: in terms of mass fraction 1-2.5 parts of anionic surfactant, 1-2 parts of nonionic surfactant, both sexes from
Sub- surfactant 1-2 parts.
4. a kind of bathroom detergent containing citrus reticulata"Chachi" blueness mandarin orange juice according to claim 3, it is characterised in that: the yin
Ionic surface active agent is 0.3-1 parts of methyl sodiosul foaliphatate, 0.7-1.5 parts of α sodium olefin sulfonate.
5. a kind of bathroom detergent containing citrus reticulata"Chachi" blueness mandarin orange juice according to claim 3, it is characterised in that: described two
Property ionic surface active agent be cocamidopropyl propyl amide hydroxy sulfo lycine；The nonionic surfactant is fatty alcohol polyoxy
Vinethene.
6. a kind of bathroom detergent containing citrus reticulata"Chachi" blueness mandarin orange juice according to claim 1, which is characterized in that described helps
Agent includes: 0.1-1 parts of bacteriostatic preservative, 0.4-0.8 parts of sodium chloride, suitable acidity regulator in terms of mass fraction.
7. a kind of bathroom detergent containing citrus reticulata"Chachi" blueness mandarin orange juice according to claim 6, it is characterised in that: the suppression
Bacterium preservative is potassium sorbate；The acidity regulator is sodium citrate.
8. a kind of bathroom detergent containing citrus reticulata"Chachi" blueness mandarin orange juice according to claim 6, it is characterised in that: described helps
Agent further includes suitable essence and/or pigment.
9. a kind of preparation method of the bathroom detergent a method as claimed in any one of claims 1-8 containing citrus reticulata"Chachi" blueness mandarin orange juice, special
Sign is, comprising the following steps:
S1. immature citrus reticulata"Chachi" mandarin orange meat the preparation of citrus reticulata"Chachi" blueness mandarin orange juice: is subjected to meat mincing processing；Meat mincing are carried out thick for the first time
Filtering, settle and separate go out fruit stone, pulp and green mandarin orange mixture；Smart filtering is carried out to green mandarin orange mixture, stands, isolates blueness
Mandarin orange juice and pulp；PH to 2.0-2.2 is adjusted to the green mandarin orange juice sodium citrate separated；
S2. the preparation of bathroom detergent: according to the quality proportioning of bathroom detergent, methyl sodiosul foaliphatate, α alkene are weighed respectively
The solutes such as base sodium sulfonate, secondary alcohol AEO-9, cocamidopropyl propyl amide hydroxy sulfo lycine, sodium chloride, potassium sorbate, and tea branch is added
In mandarin orange blueness mandarin orange juice, volume is supplied with deionized water, under normal pressure, stirring, heating condition, makes each solute in citrus reticulata"Chachi" blueness mandarin orange juice
Sufficiently dissolution adjusts PH to 2.0-2.2 with suitable sodium citrate；
S3. it examines and packs.
10. a kind of application of bathroom detergent as claimed in any one of claims 1 to 8, it is characterised in that: for bathroom, defend
Clean environment between life.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910608266.7A CN110272784B (en) | 2019-07-08 | 2019-07-08 | Bathroom cleaner containing camellia branch, citrus reticulata blanco and citrus reticulata juice and preparation method thereof |
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| CN201910608266.7A CN110272784B (en) | 2019-07-08 | 2019-07-08 | Bathroom cleaner containing camellia branch, citrus reticulata blanco and citrus reticulata juice and preparation method thereof |
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| CN110272784A true CN110272784A (en) | 2019-09-24 |
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| CN110272784B (en) | 2021-05-04 |
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