CN1102648C

CN1102648C - 包含表面活性剂和缓释过氧酸漂白剂源的洗涤剂

包含表面活性剂和缓释过氧酸漂白剂源的洗涤剂 Download PDF

Info

Publication number: CN1102648C
Authority: CN; China
Prior art keywords: bleach; alkyl; acid; detergent composition; present
Prior art date: 1994-04-13
Legal status : Expired - Fee Related

Application number

CN95193581A

Other languages

English (en)

Chinese (zh)

Other versions

CN1150818A (zh

Inventor

J·杰弗里

J·S·帕克

G·M·贝莱利

Current Assignee

Procter and Gamble Co

Original Assignee

Procter and Gamble Co

Priority date

1994-04-13

Filing date

1995-04-03

Publication date

2003-03-05

1995-04-03 Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co

1997-05-28 Publication of CN1150818A publication Critical patent/CN1150818A/zh

2003-03-05 Application granted granted Critical

2003-03-05 Publication of CN1102648C publication Critical patent/CN1102648C/zh

2015-04-03 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000007844 bleaching agent Substances 0.000 title claims abstract description 115
239000003599 detergent Substances 0.000 title claims abstract description 95
239000004094 surface-active agent Substances 0.000 title claims abstract description 81
150000004965 peroxy acids Chemical class 0.000 title claims abstract description 50
230000003111 delayed effect Effects 0.000 title abstract description 18
239000000203 mixture Substances 0.000 claims abstract description 193
238000000034 method Methods 0.000 claims abstract description 45
239000002253 acid Substances 0.000 claims abstract description 38
238000005406 washing Methods 0.000 claims abstract description 33
-1 toluyl oxygen Chemical compound 0.000 claims description 117
150000001875 compounds Chemical class 0.000 claims description 86
125000000217 alkyl group Chemical group 0.000 claims description 57
125000004432 carbon atom Chemical group C* 0.000 claims description 56
239000011572 manganese Substances 0.000 claims description 40
239000002243 precursor Substances 0.000 claims description 39
239000003054 catalyst Substances 0.000 claims description 35
125000003118 aryl group Chemical group 0.000 claims description 28
239000003446 ligand Substances 0.000 claims description 21
229910052757 nitrogen Inorganic materials 0.000 claims description 18
125000002877 alkyl aryl group Chemical group 0.000 claims description 15
229910052748 manganese Inorganic materials 0.000 claims description 15
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 14
239000003795 chemical substances by application Substances 0.000 claims description 12
238000004061 bleaching Methods 0.000 claims description 11
229910020366 ClO 4 Inorganic materials 0.000 claims description 10
238000010998 test method Methods 0.000 claims description 10
150000001408 amides Chemical group 0.000 claims description 8
230000003287 optical effect Effects 0.000 claims description 8
125000003342 alkenyl group Chemical group 0.000 claims description 7
125000002091 cationic group Chemical group 0.000 claims description 6
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 6
125000003545 alkoxy group Chemical group 0.000 claims description 5
229910052736 halogen Inorganic materials 0.000 claims description 5
150000002367 halogens Chemical class 0.000 claims description 5
239000001257 hydrogen Substances 0.000 claims description 5
229910052739 hydrogen Inorganic materials 0.000 claims description 5
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
HMMPCBAWTWYFLR-UHFFFAOYSA-N n-pyridin-2-ylpyridin-2-amine Chemical compound C=1C=CC=NC=1NC1=CC=CC=N1 HMMPCBAWTWYFLR-UHFFFAOYSA-N 0.000 claims description 5
229910052760 oxygen Inorganic materials 0.000 claims description 5
150000003951 lactams Chemical class 0.000 claims description 4
239000001301 oxygen Substances 0.000 claims description 4
ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical compound N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 claims description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 2
125000003282 alkyl amino group Chemical group 0.000 claims description 2
125000003710 aryl alkyl group Chemical group 0.000 claims description 2
229910052799 carbon Inorganic materials 0.000 claims description 2
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 2
239000013543 active substance Substances 0.000 claims 6
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims 4
150000001451 organic peroxides Chemical class 0.000 claims 3
XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 claims 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 claims 1
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
125000001118 alkylidene group Chemical group 0.000 claims 1
150000004646 arylidenes Chemical group 0.000 claims 1
UVCBVNDFDCGFKI-UHFFFAOYSA-N benzene;carbonic acid Chemical compound OC(O)=O.C1=CC=CC=C1 UVCBVNDFDCGFKI-UHFFFAOYSA-N 0.000 claims 1
SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 claims 1
229940077388 benzenesulfonate Drugs 0.000 claims 1
150000001721 carbon Chemical group 0.000 claims 1
229940050410 gluconate Drugs 0.000 claims 1
238000005984 hydrogenation reaction Methods 0.000 claims 1
XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 claims 1
GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims 1
150000004967 organic peroxy acids Chemical class 0.000 abstract description 18
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 45
150000003839 salts Chemical class 0.000 description 45
239000000243 solution Substances 0.000 description 36
JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 35
238000000576 coating method Methods 0.000 description 33
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 32
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 30
239000000047 product Substances 0.000 description 30
239000000344 soap Substances 0.000 description 27
239000002518 antifoaming agent Substances 0.000 description 26
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 25
239000011248 coating agent Substances 0.000 description 25
239000011734 sodium Substances 0.000 description 25
239000002245 particle Substances 0.000 description 24
239000000463 material Substances 0.000 description 23
229920000768 polyamine Polymers 0.000 description 23
229920000642 polymer Polymers 0.000 description 23
229920001296 polysiloxane Polymers 0.000 description 23
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 21
239000000377 silicon dioxide Substances 0.000 description 20
102000004190 Enzymes Human genes 0.000 description 19
108090000790 Enzymes Proteins 0.000 description 19
229940088598 enzyme Drugs 0.000 description 19
229920005646 polycarboxylate Polymers 0.000 description 18
239000004744 fabric Substances 0.000 description 17
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 16
150000001204 N-oxides Chemical class 0.000 description 16
229920001577 copolymer Polymers 0.000 description 16
229910052708 sodium Inorganic materials 0.000 description 16
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 14
229910001385 heavy metal Inorganic materials 0.000 description 14
229920000036 polyvinylpyrrolidone Polymers 0.000 description 14
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 14
239000002689 soil Substances 0.000 description 14
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 13
150000007513 acids Chemical class 0.000 description 13
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 13
150000001768 cations Chemical class 0.000 description 13
235000014113 dietary fatty acids Nutrition 0.000 description 13
239000000975 dye Substances 0.000 description 13
239000000194 fatty acid Substances 0.000 description 13
229930195729 fatty acid Natural products 0.000 description 13
150000002500 ions Chemical class 0.000 description 13
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 12
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
229910052783 alkali metal Inorganic materials 0.000 description 12
150000001412 amines Chemical class 0.000 description 12
239000011575 calcium Substances 0.000 description 12
239000002270 dispersing agent Substances 0.000 description 12
KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 12
238000012546 transfer Methods 0.000 description 12
108090001060 Lipase Proteins 0.000 description 11
239000004367 Lipase Substances 0.000 description 11
102000004882 Lipase Human genes 0.000 description 11
239000011230 binding agent Substances 0.000 description 11
239000002738 chelating agent Substances 0.000 description 11
150000004665 fatty acids Chemical class 0.000 description 11
230000002401 inhibitory effect Effects 0.000 description 11
235000019421 lipase Nutrition 0.000 description 11
239000000758 substrate Substances 0.000 description 11
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 10
229910052791 calcium Inorganic materials 0.000 description 10
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 10
238000004851 dishwashing Methods 0.000 description 10
239000004615 ingredient Substances 0.000 description 10
229920000620 organic polymer Polymers 0.000 description 10
239000003352 sequestering agent Substances 0.000 description 10
239000007787 solid Substances 0.000 description 10
239000000126 substance Substances 0.000 description 10
VKZRWSNIWNFCIQ-UHFFFAOYSA-N 2-[2-(1,2-dicarboxyethylamino)ethylamino]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NCCNC(C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-UHFFFAOYSA-N 0.000 description 9
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 9
125000000129 anionic group Chemical group 0.000 description 9
238000007046 ethoxylation reaction Methods 0.000 description 9
239000008187 granular material Substances 0.000 description 9
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 9
239000007788 liquid Substances 0.000 description 9
229920001223 polyethylene glycol Polymers 0.000 description 9
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 9
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 9
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
239000002202 Polyethylene glycol Substances 0.000 description 8
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 8
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 8
239000012190 activator Substances 0.000 description 8
150000001298 alcohols Chemical class 0.000 description 8
125000001931 aliphatic group Chemical group 0.000 description 8
229910000323 aluminium silicate Inorganic materials 0.000 description 8
229960003237 betaine Drugs 0.000 description 8
125000000623 heterocyclic group Chemical group 0.000 description 8
230000002209 hydrophobic effect Effects 0.000 description 8
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
229910052700 potassium Inorganic materials 0.000 description 8
239000011591 potassium Substances 0.000 description 8
125000001424 substituent group Chemical group 0.000 description 8
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 7
239000004115 Sodium Silicate Substances 0.000 description 7
125000002947 alkylene group Chemical group 0.000 description 7
230000000694 effects Effects 0.000 description 7
125000001183 hydrocarbyl group Chemical group 0.000 description 7
230000008569 process Effects 0.000 description 7
108010065511 Amylases Proteins 0.000 description 6
102000013142 Amylases Human genes 0.000 description 6
239000002280 amphoteric surfactant Substances 0.000 description 6
235000019418 amylase Nutrition 0.000 description 6
239000003945 anionic surfactant Substances 0.000 description 6
230000003197 catalytic effect Effects 0.000 description 6
239000000460 chlorine Substances 0.000 description 6
150000002191 fatty alcohols Chemical class 0.000 description 6
239000002736 nonionic surfactant Substances 0.000 description 6
239000001267 polyvinylpyrrolidone Substances 0.000 description 6
239000000843 powder Substances 0.000 description 6
159000000000 sodium salts Chemical group 0.000 description 6
241000894007 species Species 0.000 description 6
230000000087 stabilizing effect Effects 0.000 description 6
239000010457 zeolite Substances 0.000 description 6
239000002888 zwitterionic surfactant Substances 0.000 description 6
YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
235000008733 Citrus aurantifolia Nutrition 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 5
AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 5
229910019142 PO4 Inorganic materials 0.000 description 5
108091005804 Peptidases Proteins 0.000 description 5
239000004365 Protease Substances 0.000 description 5
229910004298 SiO 2 Inorganic materials 0.000 description 5
235000011941 Tilia x europaea Nutrition 0.000 description 5
229910021536 Zeolite Inorganic materials 0.000 description 5
150000001340 alkali metals Chemical class 0.000 description 5
229910052784 alkaline earth metal Inorganic materials 0.000 description 5
150000008051 alkyl sulfates Chemical class 0.000 description 5
150000001720 carbohydrates Chemical group 0.000 description 5
150000007942 carboxylates Chemical class 0.000 description 5
239000003093 cationic surfactant Substances 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
229910052801 chlorine Inorganic materials 0.000 description 5
239000007859 condensation product Substances 0.000 description 5
235000011187 glycerol Nutrition 0.000 description 5
238000011065 in-situ storage Methods 0.000 description 5
229910052742 iron Inorganic materials 0.000 description 5
238000004900 laundering Methods 0.000 description 5
239000004571 lime Substances 0.000 description 5
150000002696 manganese Chemical class 0.000 description 5
UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical compound [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 description 5
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
235000021317 phosphate Nutrition 0.000 description 5
229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 5
229920001282 polysaccharide Polymers 0.000 description 5
239000005017 polysaccharide Substances 0.000 description 5
150000004760 silicates Chemical class 0.000 description 5
235000012239 silicon dioxide Nutrition 0.000 description 5
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 5
229910052911 sodium silicate Inorganic materials 0.000 description 5
WLDGDTPNAKWAIR-UHFFFAOYSA-N 1,4,7-trimethyl-1,4,7-triazonane Chemical compound CN1CCN(C)CCN(C)CC1 WLDGDTPNAKWAIR-UHFFFAOYSA-N 0.000 description 4
OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 4
FAGGUIDTQQXDSJ-UHFFFAOYSA-N 3-benzoylazepan-2-one Chemical compound C=1C=CC=CC=1C(=O)C1CCCCNC1=O FAGGUIDTQQXDSJ-UHFFFAOYSA-N 0.000 description 4
229910017090 AlO 2 Inorganic materials 0.000 description 4
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 4
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 4
229910000503 Na-aluminosilicate Inorganic materials 0.000 description 4
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 4
229940025131 amylases Drugs 0.000 description 4
238000004458 analytical method Methods 0.000 description 4
125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 4
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical group OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 4
150000001860 citric acid derivatives Chemical class 0.000 description 4
229910052802 copper Inorganic materials 0.000 description 4
239000010949 copper Substances 0.000 description 4
238000004090 dissolution Methods 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
239000000945 filler Substances 0.000 description 4
239000006260 foam Substances 0.000 description 4
239000000499 gel Substances 0.000 description 4
239000008103 glucose Substances 0.000 description 4
125000004435 hydrogen atom Chemical class [H]* 0.000 description 4
125000002768 hydroxyalkyl group Chemical group 0.000 description 4
HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 4
150000003013 phosphoric acid derivatives Chemical class 0.000 description 4
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 4
229920005989 resin Polymers 0.000 description 4
239000011347 resin Substances 0.000 description 4
235000012217 sodium aluminium silicate Nutrition 0.000 description 4
229910000029 sodium carbonate Inorganic materials 0.000 description 4
235000017550 sodium carbonate Nutrition 0.000 description 4
229910052938 sodium sulfate Inorganic materials 0.000 description 4
235000011152 sodium sulphate Nutrition 0.000 description 4
230000006641 stabilisation Effects 0.000 description 4
238000011105 stabilization Methods 0.000 description 4
229910052717 sulfur Inorganic materials 0.000 description 4
239000003760 tallow Substances 0.000 description 4
150000003512 tertiary amines Chemical class 0.000 description 4
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
QAEDZJGFFMLHHQ-UHFFFAOYSA-N trifluoroacetic anhydride Chemical compound FC(F)(F)C(=O)OC(=O)C(F)(F)F QAEDZJGFFMLHHQ-UHFFFAOYSA-N 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
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238000002203 pretreatment Methods 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
239000011164 primary particle Substances 0.000 description 1
NJKRDXUWFBJCDI-UHFFFAOYSA-N propane-1,1,2,3-tetracarboxylic acid Chemical compound OC(=O)CC(C(O)=O)C(C(O)=O)C(O)=O NJKRDXUWFBJCDI-UHFFFAOYSA-N 0.000 description 1
NJEVMKZODGWUQT-UHFFFAOYSA-N propane-1,1,3,3-tetracarboxylic acid Chemical class OC(=O)C(C(O)=O)CC(C(O)=O)C(O)=O NJEVMKZODGWUQT-UHFFFAOYSA-N 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
238000000746 purification Methods 0.000 description 1
PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 description 1
150000004023 quaternary phosphonium compounds Chemical class 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
229920005604 random copolymer Polymers 0.000 description 1
238000006268 reductive amination reaction Methods 0.000 description 1
238000012552 review Methods 0.000 description 1
HEBKCHPVOIAQTA-ZXFHETKHSA-N ribitol Chemical compound OC[C@H](O)[C@H](O)[C@H](O)CO HEBKCHPVOIAQTA-ZXFHETKHSA-N 0.000 description 1
150000003873 salicylate salts Chemical class 0.000 description 1
VXGABWCSZZWXPC-UHFFFAOYSA-N sarcosine methyl ester hydrochloride Natural products CNCC(=O)OC VXGABWCSZZWXPC-UHFFFAOYSA-N 0.000 description 1
CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
229940071207 sesquicarbonate Drugs 0.000 description 1
229910052814 silicon oxide Inorganic materials 0.000 description 1
229920002050 silicone resin Polymers 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 description 1
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
BUFQZEHPOKLSTP-UHFFFAOYSA-M sodium;oxido hydrogen sulfate Chemical compound [Na+].OS(=O)(=O)O[O-] BUFQZEHPOKLSTP-UHFFFAOYSA-M 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000008247 solid mixture Substances 0.000 description 1
239000012265 solid product Substances 0.000 description 1
239000002195 soluble material Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
235000014347 soups Nutrition 0.000 description 1
235000012424 soybean oil Nutrition 0.000 description 1
239000003549 soybean oil Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
239000012086 standard solution Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
125000000547 substituted alkyl group Chemical group 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
150000003890 succinate salts Chemical class 0.000 description 1
235000000346 sugar Nutrition 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000000375 suspending agent Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
239000003826 tablet Substances 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
150000003892 tartrate salts Chemical class 0.000 description 1
229940104261 taurate Drugs 0.000 description 1
229960003080 taurine Drugs 0.000 description 1
150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
DCQJDRNKCUQEMA-UHFFFAOYSA-N tetradecanediperoxoic acid Chemical compound OOC(=O)CCCCCCCCCCCCC(=O)OO DCQJDRNKCUQEMA-UHFFFAOYSA-N 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
238000004448 titration Methods 0.000 description 1
230000000699 topical effect Effects 0.000 description 1
230000001052 transient effect Effects 0.000 description 1
150000003626 triacylglycerols Chemical class 0.000 description 1
125000004665 trialkylsilyl group Chemical group 0.000 description 1
QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
150000003852 triazoles Chemical group 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical class [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
150000003672 ureas Chemical class 0.000 description 1