CN110252114A - Air cleaning agent solution and preparation method thereof - Google Patents
Air cleaning agent solution and preparation method thereof Download PDFInfo
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- CN110252114A CN110252114A CN201910540376.4A CN201910540376A CN110252114A CN 110252114 A CN110252114 A CN 110252114A CN 201910540376 A CN201910540376 A CN 201910540376A CN 110252114 A CN110252114 A CN 110252114A
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- cleaning agent
- agent solution
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- air cleaning
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/30—Alkali metal compounds
- B01D2251/306—Alkali metal compounds of potassium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/604—Hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
- Y02A50/2351—Atmospheric particulate matter [PM], e.g. carbon smoke microparticles, smog, aerosol particles, dust
Abstract
The invention discloses a kind of air cleaning agent solutions, the component of the air cleaning agent solution includes the air purifying preparation and water that weight ratio is A:B, wherein A is 1, B is 1000~5000, the raw material for preparing of the air purifying preparation includes Titanium, potassium hydroxide and the iron chloride that molar ratio is C:D:E, wherein C 1, D is that 3~6, E is 4~8.The invention also discloses a kind of preparation methods of air cleaning agent solution.When carrying out air cleaning using the air cleaning agent solution that the present invention is prepared, it is not necessary that the function of the pernicious gas in purification air can be realized under ultraviolet light irradiation, therefore it can be used under no light condition.
Description
Technical field
The present invention relates to air purification fields more particularly to air cleaning agent solution and preparation method thereof.
Background technique
Room air pollution has become focus concerned by people, for example, the first at various ornament materials or furniture release
The organic gas such as aldehyde, toluene pollute room air, seriously affect human health.
Currently, photocatalyst cleanser is the most commonly used air purifying preparation, however, photocatalyst cleanser is only in ultraviolet light
Catalytic effect can be just played under irradiation, purify the pollutant in air, therefore current photocatalyst cleanser there can only be light
Under the conditions of use.
Above content is only used to facilitate the understanding of the technical scheme, and is not represented and is recognized that above content is existing skill
Art.
Summary of the invention
The main purpose of the present invention is to provide a kind of air cleaning agent solutions and preparation method thereof, it is intended to solve current
Photocatalyst cleanser needs the technical issues of could purifying air under ultraviolet light irradiation, can only use in the presence of light.
To achieve the above object, the present invention provides a kind of air cleaning agent solution, the component of the air cleaning agent solution
The air purifying preparation and water for being A:B including weight ratio, it is 1000~5000 that wherein A, which is 1, B, and the preparation of the air purifying preparation is former
Material includes Titanium, potassium hydroxide and the iron chloride that molar ratio is C:D:E, wherein C 1, D are that 3~6, E is 4~8.
Preferably, the raw material for preparing of the air purifying preparation includes Titanium, potassium hydroxide and the chlorine that molar ratio is C:D:E
Change iron, wherein C 1, D are that 3~4, E is 4~6.
In addition, to achieve the above object, the present invention also provides a kind of preparation method of air cleaning agent solution, the air
The preparation methods of decontaminant solutions the following steps are included:
Titanium, potassium hydroxide and iron chloride are weighed with molar ratio C:D:E, wherein C 1, D are 3~6, E 4
~8；
The weighed Titanium is melted under vacuum conditions and obtains Titanium fusant；
The weighed potassium hydroxide is added in the Titanium fusant, after keeping the temperature 20min~60min, will be obtained
Product be cooled to room temperature to obtain the first firing object；
It is cold after firing 45min~90min in air after the first firing object and the weighed iron chloride are mixed
But the second firing object is obtained to room temperature, wherein the temperature of the firing is 1450 DEG C~1550 DEG C；
The second firing object is ground at low temperature and obtains air purifying preparation；
The air purifying preparation and water are weighed with weight ratio A:B, it is 1000~5000 that wherein A, which is 1, B,；
The weighed air purifying preparation and water are uniformly mixed and obtain air cleaning agent solution.
Preferably, the Titanium is metallic titanium powder, and the metallic titanium powder is made by the steps to obtain:
Titanium is ground at low temperature；
The powder that grinding obtains is crossed into 2500 meshes, obtains the metallic titanium powder.
Preferably in described that the second firing object is ground the step of obtaining air purifying preparation packet under liquid nitrogen atmosphere
It includes:
The second firing object is ground under liquid nitrogen atmosphere and obtains powder；
The powder is crossed into 2500 meshes, obtains the air purifying preparation.
Preferably, the temperature that the Titanium melts under vacuum conditions is 1650 DEG C~1710 DEG C.
Preferably, obtained product is cooled to room temperature in drier.
Preferably, described that the weighed air purifying preparation and water are uniformly mixed the step of obtaining the decontaminant solutions
Include:
The weighed air purifying preparation and water are put into blender；
10min~40min is stirred with the revolving speed of 1000RPM~5000RPM, so that the air purifying preparation and water mixing are equal
It is even, obtain the air cleaning agent solution.
A kind of air cleaning agent solution and preparation method thereof that the embodiment of the present invention proposes, the air cleaning agent solution
Component includes the air purifying preparation and water that weight ratio is A:B, and it is 1000~5000 that wherein A, which is 1, B, the system of the air purifying preparation
Standby raw material includes Titanium, potassium hydroxide and the iron chloride that molar ratio is C:D:E, wherein C 1, D are that 3~6, E is 4~8.Benefit
Formaldehyde removal rate reaches after the air cleaning agent solution being prepared with the embodiment of the present invention purifies polluted gas 24 hours
96.2%, for total volatile organism (TVOC) removal rate up to 88.8%, purification efficiency is high；And it can be real under being irradiated without ultraviolet light
The function of the pernicious gas in air is now purified, therefore can be used under no light condition.
Specific embodiment
It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not intended to limit the present invention.
Firstly, the preparation method to air cleaning agent solution provided in an embodiment of the present invention and air cleaning agent solution carries out
Brief overview.
The preparation method of air cleaning agent solution provided in an embodiment of the present invention the following steps are included:
(1), raw material weighs:
Titanium, potassium hydroxide and iron chloride are weighed with molar ratio C:D:E, wherein C 1, D are that 3~6, E is 4~8；It is excellent
Selection of land, C 1, D are that 3~4, E is 4~6.In the embodiment of the present invention, the purity of Titanium used, potassium hydroxide and iron chloride
It is all larger than 99.99%.
Preferably, in order to enable next step Titanium can be melted preferably, it is used to prepare the metal of Titanium fusant
Titanium is ultrafine titanium powder, the ultrafine titanium powder by the way that Titanium is ground at low temperature (such as under liquid nitrogen atmosphere),
Then the powder that grinding obtains is crossed 2500 meshes to obtain, the ultrafine titanium powder particle being prepared is less than 5 μm, it is preferable that
Milling time is 20min~60min.
(2), Titanium fusant is prepared:
The weighed Titanium is melted under vacuum conditions (such as in vacuum Muffle furnace) and obtains Titanium melting
Object, wherein melting is metallic titanium oxidation in order to prevent under vacuum conditions；Preferably, melting temperature is 1650 DEG C~1710
℃。
(3), object is fired in preparation first:
The weighed potassium hydroxide is added in the Titanium fusant, after keeping the temperature 20min~60min, will be obtained
Product be cooled to room temperature to obtain the first firing object.Preferably, the product obtained in order to prevent absorbs water in cooling, in drier
The middle product that will be obtained is cooled to room temperature.
(4), prepared by air purifying preparation:
Cooling first obtained is fired into object and weighed iron chloride mixes, is fired in air (such as in Muffle furnace)
It after 45min~90min, is cooled to room temperature to obtain the second firing object, wherein firing temperature is 1450 DEG C~1550 DEG C.
The second firing object is ground at low temperature (such as under liquid nitrogen atmosphere) and obtains air purifying preparation, it is preferable that
A length of 45min~90min when grinding.Preferably, it in order to improve the purification efficiency of the air purifying preparation being prepared, will grind
2500 meshes are crossed to powder, obtain air purifying preparation of the particle less than 5 μm.
(5), prepared by air cleaning agent solution:
The air purifying preparation and water being prepared are weighed with weight ratio A:B, it is 1000~5000 that wherein A, which is 1, B,；
The weighed air purifying preparation and water are uniformly mixed and obtain air cleaning agent solution, it is to be understood that is mixed
The mode of conjunction can be selected voluntarily according to the actual situation, be not particularly limited herein.It optionally, can be net by the weighed air
Agent and water, which are put into blender, to be stirred, so that the air purifying preparation and water are uniformly mixed, obtains the air cleaning
Agent solution.The revolving speed and duration of stirring can self-settinies according to the actual situation, it is preferable that speed of agitator be 1000RPM~
5000RPM, when stirring a length of 10min~40min.
The component for the air cleaning agent solution being prepared according to above scheme includes the air purifying preparation that weight ratio is A:B
And water, it is 1000~5000 that wherein A, which is 1, B, and the raw material for preparing of the air purifying preparation includes the metal that molar ratio is C:D:E
Titanium, potassium hydroxide and iron chloride, wherein C 1, D are that 3~6, E is 4~8.Preferably, the air purifying preparation prepares raw material
Titanium, potassium hydroxide and the iron chloride for being C:D:E including molar ratio, wherein C 1, D are that 3~4, E is 4~6.
The prepared by the method air cleaning agent solution arrived is carried out in air cleaning, takes a small amount of air cleaning
Agent solution is sprayed at the space for needing to carry out air cleaning.
The air cleaning agent solution that the embodiment of the present invention is prepared is a kind of novel air catalyst solution, and purification is former
Reason are as follows: since potassium element includes potassium -39 and kalium-40, contain micro kalium-40 in the air purifying preparation being prepared, kalium-40 is
Natural radioactive element, when decay, give off energy, and hydrone and hydrogen-oxygen free radical is pushed to generate hydrogen peroxide, the peroxide of generation
Redox reaction occurs for titanium, iron in change hydrogen and the air purifying preparation, generates negative oxygen ion, the negative oxygen ion and sky of generation
Redox reaction occurs for formaldehyde, benzene homologues (such as benzene,toluene,xylene) pernicious gas in gas, so that pernicious gas point
Solution, to realize the function of the pernicious gas in purification air；Therefore, the air cleaning agent solution that the present invention is prepared is to dirt
When the air of dye is purified, the purification of pollutant can be realized without ultraviolet irradiation, can be used under no light condition.
Clean-up effect test method:
1. pollutant purification measure of merit
Referring to national standard QB/T2761-2006 " indoor air purification product clean-up effect measuring method ", with two individuals
Product is 1m3Climate compartment (the blank cabin and experimental cabin) air purifying preparation that is prepared of the test embodiment of the present invention to dirty in air
Contaminate the clean-up effect of object.It is filled with the pollution sources of equivalent in two climate compartments, and uniformly sprays into 5 milliliters of present invention in Laboratory Module
The air cleaning agent solution that embodiment is prepared.After 24 hours, pollutant concentration C0 in blank cabin is detected, is detected in experimental cabin
Pollutant concentration C1, and pollutants removal rate y is calculated as follows:
2. peculiar smell clean-up effect is tested
It is filled with the pollution sources of equivalent in two climate compartments (blank cabin and experimental cabin), is filled with equivalent in two climate compartments
Pollution sources, and uniformly spray into Laboratory Module the air cleaning agent solution that 5 milliliters of embodiment of the present invention are prepared.24 hours
Afterwards, the exhaust outlet in blank cabin and experimental cabin is opened respectively, and nose close to exhaust outlet, is evaluated blank cabin by odor gradings personnel respectively
With the oder levels of experimental cabin, the average value of the evaluation result for taking 6 smell evaluating members to make (oder levels) is as peculiar smell
Evaluation result, wherein oder levels indicate that smell judgment criteria is as follows with integer or half:
1 grade: odorlessness；
2 grades: smell is slight, but can feel；
3 grades: it is odorous, but without strong discomfort；
4 grades: strong foreign odor；
5 grades: irritant foreign odor.
Embodiment 1
Titanium is ground into 20min~60min under liquid nitrogen atmosphere, 2500 meshes is crossed, it is ultra-fine less than 5 μm to obtain particle
Metallic titanium powder.
Weigh 100g ultrafine titanium powder, 350g potassium hydroxide and 1355g iron chloride (ultrafine titanium powder, potassium hydroxide
Molar ratio with iron chloride is 1:3:4).
The weighed metallic titanium powder is put into vacuum Muffle furnace, set temperature is 1680 DEG C, and metallic titanium powder is melted
Obtain Titanium fusant.
The weighed potassium hydroxide is added in the Titanium fusant, continues to keep the temperature with 1680 DEG C of set temperature
After 20min, obtained product is put into drier and is cooled to room temperature to obtain the first firing object.
Cooling the first obtained firing object and weighed iron chloride are mixed to get mixture, mixture is put into Muffle furnace
In, after 1500 DEG C of firing 60min, it is cooled to room temperature to obtain the second firing object.
The second firing object is ground into 60min under liquid nitrogen atmosphere, grinding is obtained into powder and crosses 2500 meshes, obtains sky
Gas cleanser 1.
1.000g air purifying preparation 1 is weighed, 2000g water is added, 20min, system are stirred with 2000RPM revolving speed in blender
It is standby to obtain air cleaning agent solution 1.
Clean-up effect test:
According to above-mentioned Assessment of cleaning efficiency method, the air cleaning agent solution 1 being prepared using the present embodiment is to containing dirt
The air of dye object is purified, and test result is as follows.
1, pollutant purification test result is as follows table:
2, peculiar smell clean-up effect test result are as follows: blank cabin oder levels are 4.5, and Laboratory Module oder levels are 2.0.
Test result shows that the air cleaning agent solution 1 being prepared using the present embodiment is small to polluted gas purification 24
When after formaldehyde removal rate up to 96.2%, total volatile organism (TVOC) removal rate is up to 88.8%；And purified air odor
Grade is 2.0, far below non-purified air odor class 4 .5；Illustrate the air cleaning agent solution 1 that the present embodiment is prepared
With good clean-up effect.
Embodiment 2
Titanium is ground into 20min~60min under liquid nitrogen atmosphere, 2500 meshes is crossed, it is ultra-fine less than 5 μm to obtain particle
Metallic titanium powder.
Weigh 100g ultrafine titanium powder, 350g potassium hydroxide and 1693g iron chloride (ultrafine titanium powder, potassium hydroxide
Molar ratio with iron chloride is 1:3:5).
The weighed metallic titanium powder is put into vacuum Muffle furnace, set temperature is 1650 DEG C, and metallic titanium powder is melted
Obtain Titanium fusant.
The weighed potassium hydroxide is added in the Titanium fusant, continues to keep the temperature with 1650 DEG C of set temperature
After 60min, obtained product is put into drier and is cooled to room temperature to obtain the first firing object mixture.
Cooling the first obtained firing object and weighed iron chloride are mixed to get mixture, mixture is put into Muffle furnace
In, after 1550 DEG C of firing 45min, it is cooled to room temperature to obtain the second firing object.
The second firing object is ground into 90min under liquid nitrogen atmosphere, grinding is obtained into powder and crosses 2500 meshes, obtains sky
Gas cleanser 2.
1.000g air purifying preparation 2 is weighed, 1000g water is added, 10min, system are stirred with 5000RPM revolving speed in blender
It is standby to obtain air cleaning agent solution 2.
According to above-mentioned Assessment of cleaning efficiency method, the air cleaning agent solution 2 being prepared using the present embodiment is to containing dirt
The air of dye object is purified, and pollutant purification test result and peculiar smell clean-up effect test result are approximate with embodiment 1, say
The air cleaning agent solution 2 that bright the present embodiment is prepared has good clean-up effect.
Embodiment 3
Titanium is ground into 20min~60min under liquid nitrogen atmosphere, 2500 meshes is crossed, it is ultra-fine less than 5 μm to obtain particle
Metallic titanium powder.
Weigh 100g ultrafine titanium powder, 465g potassium hydroxide and 2030g iron chloride (ultrafine titanium powder, potassium hydroxide
Molar ratio with iron chloride is 1:4:6).
The weighed metallic titanium powder is put into vacuum Muffle furnace, set temperature is 1670 DEG C, and metallic titanium powder is melted
Obtain Titanium fusant.
The weighed potassium hydroxide is added in the Titanium fusant, continues to keep the temperature with 1670 DEG C of set temperature
After 50min, obtained product is put into drier and is cooled to room temperature to obtain the first firing object.
Cooling the first obtained firing object and weighed iron chloride are mixed to get mixture, mixture is put into Muffle furnace
In, after 1520 DEG C of firing 50min, it is cooled to room temperature to obtain the second firing object.
The second firing object is ground into 70min under liquid nitrogen atmosphere, grinding is obtained into powder and crosses 2500 meshes, obtains sky
Gas cleanser 3.
1.000g air purifying preparation 3 is weighed, 3000g water is added, 30min, system are stirred with 4000RPM revolving speed in blender
It is standby to obtain air cleaning agent solution 3.
According to above-mentioned Assessment of cleaning efficiency method, the air cleaning agent solution 3 being prepared using the present embodiment is to containing dirt
The air of dye object is purified, and pollutant purification test result and peculiar smell clean-up effect test result are approximate with embodiment 1, say
The air cleaning agent solution 3 that bright the present embodiment is prepared has good clean-up effect.
Embodiment 4
Titanium is ground into 20min~60min under liquid nitrogen atmosphere, 2500 meshes is crossed, it is ultra-fine less than 5 μm to obtain particle
Metallic titanium powder.
Weigh 100g ultrafine titanium powder, 585g potassium hydroxide and 2372g iron chloride (ultrafine titanium powder, potassium hydroxide
Molar ratio with iron chloride is 1:5:7).
The weighed metallic titanium powder is put into vacuum Muffle furnace, set temperature is 1700 DEG C, and metallic titanium powder is melted
Obtain Titanium fusant.
The weighed potassium hydroxide is added in the Titanium fusant, continues to keep the temperature with 1700 DEG C of set temperature
After 40min, obtained product is put into drier and is cooled to room temperature to obtain the first firing object.
Cooling the first obtained firing object and weighed iron chloride are mixed to get mixture, mixture is put into Muffle furnace
In, after 1470 DEG C of firing 80min, it is cooled to room temperature to obtain the second firing object.
The second firing object is ground into 55min under liquid nitrogen atmosphere, grinding is obtained into powder and crosses 2500 meshes, obtains sky
Gas cleanser 4.
1.000g air purifying preparation 4 is weighed, 4000g water is added, 35min, system are stirred with 3000RPM revolving speed in blender
It is standby to obtain air cleaning agent solution 4.
According to above-mentioned Assessment of cleaning efficiency method, the air cleaning agent solution 4 being prepared using the present embodiment is to containing dirt
The air of dye object is purified, and pollutant purification test result and peculiar smell clean-up effect test result are approximate with embodiment 1, say
The air cleaning agent solution 4 that bright the present embodiment is prepared has good clean-up effect.
Embodiment 5
Titanium is ground into 20min~60min under liquid nitrogen atmosphere, 2500 meshes is crossed, it is ultra-fine less than 5 μm to obtain particle
Metallic titanium powder.
Weigh 100g ultrafine titanium powder, 700g potassium hydroxide and 2710g iron chloride (ultrafine titanium powder, potassium hydroxide
Molar ratio with iron chloride is 1:6:8).
The weighed metallic titanium powder is put into vacuum Muffle furnace, set temperature is 1710 DEG C, and metallic titanium powder is melted
Obtain Titanium fusant.
The weighed potassium hydroxide is added in the Titanium fusant, continues to keep the temperature with 1710 DEG C of set temperature
After 30min, obtained product is put into drier and is cooled to room temperature to obtain the first firing object.
Cooling the first obtained firing object and weighed iron chloride are mixed to get mixture, mixture is put into Muffle furnace
In, after 1450 DEG C of firing 90min, it is cooled to room temperature to obtain the second firing object.
The second firing object is ground into 45min under liquid nitrogen atmosphere, grinding is obtained into powder and crosses 2500 meshes, obtains sky
Gas cleanser 5.
1.000g air purifying preparation 5 is weighed, 5000g water is added, 40min, system are stirred with 1000RPM revolving speed in blender
It is standby to obtain air cleaning agent solution 1.
According to above-mentioned Assessment of cleaning efficiency method, the air cleaning agent solution 5 being prepared using the present embodiment is to containing dirt
The air of dye object is purified, and pollutant purification test result and peculiar smell clean-up effect test result are approximate with embodiment 1, say
The air cleaning agent solution 5 that bright the present embodiment is prepared has good clean-up effect.
As can be seen from the above-described embodiment, the air purifying preparation being prepared using any embodiment in embodiment 1-5 is molten
When liquid purifies the air containing pollutant, pollutants removal rate and peculiar smell clean-up effect are preferable, illustrate implementation of the present invention
The air cleaning agent solution that example is prepared has very high air purification efficiency.In addition, net using air prepared by the present invention
It, only need to be by a small amount of air purifying preparation spray solution in the air for needing to purify, without ultraviolet when agent solution is to air cleaning
Line irradiates the purification that pollutant can be realized, therefore the air cleaning agent solution of preparation of the embodiment of the present invention can be under no light condition
It uses.
It should be noted that, in this document, the terms "include", "comprise" or its any other variant are intended to non-row
His property includes, so that the process, method, article or the system that include a series of elements not only include those elements, and
And further include other elements that are not explicitly listed, or further include for this process, method, article or system institute it is intrinsic
Element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that including being somebody's turn to do
There is also other identical elements in the process, method of element, article or system.
The serial number of the above embodiments of the invention is only for description, does not represent the advantages or disadvantages of the embodiments.
Through the above description of the embodiments, those skilled in the art can be understood that above-described embodiment side
Method can be realized by means of software and necessary general hardware platform, naturally it is also possible to by hardware, but in many cases
The former is more preferably embodiment.Based on this understanding, technical solution of the present invention substantially in other words does the prior art
The part contributed out can be embodied in the form of software products, which is stored in one as described above
In storage medium (such as ROM/RAM, magnetic disk, CD), including some instructions are used so that terminal device (it can be mobile phone,
Computer, server, air conditioner or network equipment etc.) execute method described in each embodiment of the present invention.
The above is only a preferred embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair
Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (8)
1. a kind of air cleaning agent solution, which is characterized in that the component of the air cleaning agent solution includes that weight ratio is A:B
Air purifying preparation and water, it is 1000~5000 that wherein A, which is 1, B, the air purifying preparation prepare raw material include molar ratio be C:
Titanium, potassium hydroxide and the iron chloride of D:E, wherein C 1, D are that 3~6, E is 4~8.
2. air cleaning agent solution as described in claim 1, which is characterized in that the raw material for preparing of the air purifying preparation includes
Molar ratio is Titanium, potassium hydroxide and the iron chloride of C:D:E, wherein C 1, D are that 3~4, E is 4~6.
3. a kind of preparation method of air cleaning agent solution, which is characterized in that the preparation method packet of the air cleaning agent solution
Include following steps:
Titanium, potassium hydroxide and iron chloride are weighed with molar ratio C:D:E, wherein C 1, D are that 3~6, E is 4~8；
The weighed Titanium is melted under vacuum conditions and obtains Titanium fusant；
The weighed potassium hydroxide is added in the Titanium fusant, after keeping the temperature 20min~60min, the production that will obtain
Object is cooled to room temperature to obtain the first firing object；
After firing 45min~90min in air after the first firing object and the weighed iron chloride are mixed, it is cooled to
Room temperature obtains the second firing object, wherein the temperature of the firing is 1450 DEG C~1550 DEG C；
The second firing object is ground at low temperature and obtains air purifying preparation；
The air purifying preparation and water are weighed with weight ratio A:B, it is 1000~5000 that wherein A, which is 1, B,；
The weighed air purifying preparation and water are uniformly mixed and obtain air cleaning agent solution.
4. the preparation method of air cleaning agent solution as claimed in claim 3, which is characterized in that the Titanium is Titanium
Powder, the metallic titanium powder are made by the steps to obtain:
Titanium is ground at low temperature；
The powder that grinding obtains is crossed into 2500 meshes, obtains the metallic titanium powder.
5. the preparation method of air cleaning agent solution as claimed in claim 3, which is characterized in that described to be fired described second
Object grinds the step of obtaining air purifying preparation under liquid nitrogen atmosphere
The second firing object is ground under liquid nitrogen atmosphere and obtains powder；
The powder is crossed into 2500 meshes, obtains the air purifying preparation.
6. the preparation method of air cleaning agent solution as claimed in claim 3, which is characterized in that the Titanium is in vacuum item
The temperature melted under part is 1650 DEG C~1710 DEG C.
7. the preparation method of air cleaning agent solution as claimed in claim 3, which is characterized in that will be obtained in drier
Product is cooled to room temperature.
8. the preparation method of the air cleaning agent solution as described in any one of claim 3~7, which is characterized in that described to incite somebody to action
The weighed air purifying preparation and water are uniformly mixed the step of obtaining the decontaminant solutions
The weighed air purifying preparation and water are put into blender；
10min~40min is stirred with the revolving speed of the RPM of 1000RPM~5000, so that the air purifying preparation and water are uniformly mixed,
Obtain the air cleaning agent solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910540376.4A CN110252114B (en) | 2019-06-20 | 2019-06-20 | Air purifying agent solution and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910540376.4A CN110252114B (en) | 2019-06-20 | 2019-06-20 | Air purifying agent solution and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN110681260A (en) * | 2019-10-24 | 2020-01-14 | 深圳市国测检测技术有限公司 | Air purifying agent and preparation method thereof |
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