CN110250567A - A kind of environment-friendly cigarette filter tip filler and preparation method - Google Patents
A kind of environment-friendly cigarette filter tip filler and preparation method Download PDFInfo
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- CN110250567A CN110250567A CN201910383354.1A CN201910383354A CN110250567A CN 110250567 A CN110250567 A CN 110250567A CN 201910383354 A CN201910383354 A CN 201910383354A CN 110250567 A CN110250567 A CN 110250567A
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- environment
- filter tip
- cigarette filter
- friendly cigarette
- tip filler
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
This application discloses a kind of environment-friendly cigarette filter tip filler and preparation methods, its key points of the technical solution are that being prepared by the raw material of following weight percent: aerosil 17~22%, vinyltrimethoxysilane 0.05~0.25%, Activated Sepiolite powder 5~7%, order mesoporous carbon adsorbent 3~5%, acetate fiber 10~15%, chitosan 0.5~1.5%, Calcium Pectate 1~2%, sodium carboxymethylcellulose 0.5~2.5%, konjaku powder 2~4%, tasty and refreshing dose 0.05~0.25%, remaining water.A kind of environment-friendly cigarette filter tip filler of the application, nontoxic, tasteless, impact resistance, oil resistant, static electrification, resistance to suction be not small, strong adsorption force, and is added with tasty and refreshing ingredient, can promote mouthfeel.
Description
[technical field]
The present invention relates to cigarette filter filler fields, and in particular to a kind of environment-friendly cigarette filter tip filler and preparation method.
[background technique]
Pipe tobacco is rolled into the tobacco product of strip with cigarette paper by cigarette (cigarette).Also known as cigarette, cigarette, cigarette.Have
Filter tip cigarette and without mouth cigarette, and it is divided into flat taste and dense taste.
Currently, China has more than 300,000,000 smoker, number occupies first place in the world.Huge scale and stable demand, support
The height of domestic tobacco business is prosperous, and as economic development and expenditure increase, inhabitant's consumption level is continuously improved, and cigarette is as day
Also when the river rises the boat goes up therewith for normal necessity, whole society's tobacco consumption demand sustainable growth.Cigarette enterprise also actively pushes forward cigarette sales network
Construction, effectively increases Tobacco System to the control force and occupation rate of domestic market, product sales volume is steadily increasing.
But smoking is not only detrimental to health, and can also have a adverse impact to society.Any organized organism
As long as there are also having to breathe as long as sign of life, intracorporal carbon dioxide is breathed out, the oxygen in air is sucked, carries out new old generation
It thanks, to maintain normal vital movement.The people of non-smoking can suck a large amount of fresh air daily；And the people often to smoke,
But it is without access to the grace of the Nature, the not instead of fresh air of sucking is contained in tobacco leaf by the toxic gas of smog pollution
Toxin nicotine, is also nicotine.The nicotine of 1 grammes per square metre can poison 300 rabbits or 500 mouse with poison.If injecting 50 milligrams of cigarettes to people
Alkali, will be lethal.
And smoking endangers maximum to respiratory tract, it is easy to cause laryngitis, tracheitis, the coughs such as pulmonary emphysema.Smoking
When cigarette enter from mouth, by throat, trachea-bronchial epithelial cell, into blood.
The suspended particles generated when the smog of entrance, tar and burning when cigarette filter can be used for reducing smoking, can also subtract
The harmfulness of few cigarette and the tobacco of entrance, currently, the raw material of most of manufacture cigarette filters is taken from the cellulose of timber, fiber
After plain acetylation (making the material of cellulose acetate or abbreviation " acetic acid "), dissolution, it is separated into continuous bunchy arrangement
Synthetic fibers, referred to as tow, on the one hand it reduces the tobacco component content in cigarette, on the other hand but also sucking volume
Smog caused by cigarette reduces.Filter tip is longer, and the effect for reducing smog is better, and also some cigarettes enterprise adds in cigarette filter at present
Enter other fillers, in the hope of obtaining the filter tip of more preferable strainability.
[summary of the invention]
In view of the deficiencies of the prior art, the present invention provides a kind of environment-friendly cigarette filter tip fillers
The present invention also provides a kind of preparation methods of environment-friendly cigarette filter tip filler.
The present invention is achieved by the following technical programs:
A kind of environment-friendly cigarette filter tip filler, it is characterised in that be prepared by the raw material of following weight percent:
A kind of environment-friendly cigarette filter tip filler, is prepared by the raw material of following weight percent:
Aerosil 17.5~19.3%, vinyltrimethoxysilane 0.23~0.25%, Activated Sepiolite
Powder 5.7~7%, order mesoporous carbon adsorbent 3~5%, acetate fiber 12.3~15%, chitosan 0.8~1.5%, pectin
Sour calcium 1~2%, sodium carboxymethylcellulose 1.9~2.5%, konjaku powder 2.64~4%, tasty and refreshing dose 0.13~0.25%, water 45
~53%.
Preferably, the aerosil is made of nano silica, and average grain diameter is 4 microns, and volume is close
Degree is 230Kg/m3.
Preferably, sepiolite powder freeze-day with constant temperature at 105 DEG C and is mechanically pulverized to less than 500 mesh to constant weight.Calcium
Based sepiolite has potent suction-operated to organic matter, but as humidity increases, dirt-removing power can decline, dry sepiolite powder
Cooperate low aqueous aerosil that can keep its adsorption effect for a long time.
Preferably, the partial size of order mesoporous carbon ball is 150~450nm in the order mesoporous carbon adsorbent.
Preferably, it is mixed for Peppermint essential oil and lemon 1:1 in mass ratio for described tasty and refreshing dose.
A kind of preparation method of environment-friendly cigarette filter tip filler, includes the following steps:
Uniform solution is made in the vinyltrimethoxysilane stirring that is added to the water, by aerosil, activation
Sepiolite powder, order mesoporous carbon adsorbent gather acetate fiber, shell after 400-800W ultrasonic vibration processing 10-30min is added
Sugar, Calcium Pectate, konjaku powder, tasty and refreshing dose of addition are obtained after being uniformly mixed with sodium carboxymethylcellulose regulation system viscosity
Thick paste is added in round bottom sesame seed cake and is placed in 50-60 DEG C of decompression steaming water on Rotary Evaporators, finally fills obtained material by thick paste
Finished product can be obtained in bulb separation mill.
Compared with prior art, the present invention has the following advantages:
The present invention provides a kind of environment-friendly cigarette filter tip fillers, and wherein aerosil has elasticity well and heat
Stability, surface void are gathered, and can capture the tar in flue gas, moreover it is possible to adsorb aldehyde compound such as acetaldehyde in flue gas,
Methacrylaldehyde, benzene and toluene etc., the free radical in acetate fiber energy effectively catching flue gas, price is relatively inexpensive, can reduce after addition
The cost of filter tip filler, function of the order mesoporous carbon adsorbent in filler mainly adsorb volatility gas phase hazardous component, drop
The low harmful substance accounted in smoke of tobacco gas phase mitigates the toxicity of flue gas, changes flue gas stream distribution, increases flue gas mechanical retention
Rate, Activated Sepiolite powder have biggish specific surface area, and the polar gas compound of insalubrity is by splendid absorption
Ability, but the non-polar gas compound that cigarette smoke can be made denseer is adsorbed seldom, the experience of smoking is not interfered with, this
Invention environment-friendly cigarette filter tip filler is nontoxic, tasteless, impact resistance, oil resistant, static electrification, resistance to suction be not small, strong adsorption force, and added with refreshing
Mouth ingredient, can promote mouthfeel.
[embodiment]
1~6 illustrates a kind of environment-friendly cigarette filter tip filler of the invention in conjunction with specific embodiments.
Table 1: each embodiment filler component percentage proportion
Embodiment 1:
A kind of environment-friendly cigarette filter tip filler, is prepared by following raw material in parts by weight:
Uniform solution is made in the vinyltrimethoxysilane stirring that is added to the water, by aerosil, activation
Sepiolite powder, order mesoporous carbon adsorbent gather acetate fiber, shell after 400-800W ultrasonic vibration processing 10-30min is added
Sugar, Calcium Pectate, konjaku powder, tasty and refreshing dose of addition are obtained after being uniformly mixed with sodium carboxymethylcellulose regulation system viscosity
Thick paste is added in round bottom sesame seed cake and is placed in 50-60 DEG C of decompression steaming water on Rotary Evaporators, finally fills obtained material by thick paste
Finished product can be obtained in bulb separation mill.
Using 1-6 environment-friendly cigarette filter tip filler of the embodiment of the present invention, cigarette smoke, which is filtered and is detected in flue gas, to be had
The removal rate of evil substance, as a result as shown in table 2 below.
Table 2: embodiment 1-6 environment-friendly cigarette filter tip filler filter effect detection
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | |
| Nicotine | 90.5 | 91.3 | 90.8 | 88.3 | 89.7 | 91.5 |
| Tar | 87.6 | 88.2 | 85.4 | 86.3 | 88.5 | 87.5 |
| Carbon monoxide | 79.5 | 80.6 | 80.1 | 79.8 | 78.9 | 81.4 |
| BaP | 99.5 | 99.5 | 99.6 | 99.3 | 99.6 | 99.8 |
| Nitrogen oxides | 70.8 | 71.2 | 71.6 | 71.3 | 71.5 | 70.6 |
| TSNAs | 98.7 | 95.4 | 96.6 | 97.9 | 96.5 | 95.6 |
By upper table 2 it is found that environment-friendly cigarette filter tip filler of the present invention has the main poisonous and harmful substance in cigarette smoke
Good removal effect, wherein for nicotine removal rate >=90.5%, tar removal rate >=85.4%, BaP removal rate >=
79.5%, wherein aerosil has elasticity and thermal stability well, and surface void is gathered, and can capture flue gas
In tar, moreover it is possible to adsorb the aldehyde compound such as acetaldehyde, methacrylaldehyde, benzene and toluene etc. in flue gas, acetate fiber can effectively be cut
The free radical in flue gas is stayed, price is relatively inexpensive, and the cost of filter tip filler can be reduced after addition, and order mesoporous carbon adsorbent is being filled out
Function in material mainly adsorbs volatility gas phase hazardous component, reduces the harmful substance accounted in smoke of tobacco gas phase, mitigates cigarette
The toxicity of gas changes flue gas stream distribution, increases flue gas machinery rejection, and Activated Sepiolite powder has biggish specific surface
Product, the polar gas compound of insalubrity is by splendid adsorption capacity, but to the nonpolarity that cigarette smoke can be made denseer
Gaseous compound but adsorbs seldom, does not interfere with the experience of smoking, and environment-friendly cigarette filter tip filler of the present invention is nontoxic, tasteless, resistance to
Impact, oil resistant, static electrification, resistance to suction be not small, strong adsorption force, and is added with tasty and refreshing ingredient, can promote mouthfeel, can be very good to protect
Protect human health.
Claims (7)
1. a kind of environment-friendly cigarette filter tip filler, it is characterised in that be prepared by the raw material of following weight percent:
2. environment-friendly cigarette filter tip filler according to claim 1, it is characterised in that by the raw material system of following weight percent
It is standby to form:
Aerosil 17.5~19.3%, vinyltrimethoxysilane 0.23~0.25%, Activated Sepiolite powder
5.7~7%, order mesoporous carbon adsorbent 3~5%, acetate fiber 12.3~15%, chitosan 0.8~1.5%, Calcium Pectate 1
~2%, sodium carboxymethylcellulose 1.9~2.5%, konjaku powder 2.64~4%, tasty and refreshing dose 0.13~0.25%, water 45~
53%.
3. environment-friendly cigarette filter tip filler according to claim 1, it is characterised in that: the aerosil is by nanometer
Silica is made, and average grain diameter is 4 microns, bulk density 230Kg/m3.
4. environment-friendly cigarette filter tip filler according to claim 1, it is characterised in that: the sepiolite powder is at 105 DEG C
Freeze-day with constant temperature is mechanically pulverized to less than 500 mesh to constant weight.
5. environment-friendly cigarette filter tip filler according to claim 1, it is characterised in that: have in the order mesoporous carbon adsorbent
The partial size of sequence mesoporous carbon spheres is 150~450nm.
6. environment-friendly cigarette filter tip filler according to claim 1, it is characterised in that: described tasty and refreshing dose is Peppermint essential oil and lemon
Lemon essential oil 1:1 in mass ratio is mixed.
7. a kind of preparation method of environment-friendly cigarette filter tip filler, it is characterised in that include the following steps:
Uniform solution is made in the vinyltrimethoxysilane stirring that is added to the water, by aerosil, activation Hai Pao
By acetate fiber, chitosan, fruit after stone powder, order mesoporous carbon adsorbent addition 400-800W ultrasonic vibration processing 10-30min
Glue acid calcium, konjaku powder, tasty and refreshing dose be added be uniformly mixed after with sodium carboxymethylcellulose regulation system viscosity obtain thick paste,
Thick paste is added in round bottom sesame seed cake and is placed in 50-60 DEG C of decompression steaming water on Rotary Evaporators, finally by the abundant ball of obtained material
Finished product can be obtained in mill.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910383354.1A CN110250567A (en) | 2019-05-08 | 2019-05-08 | A kind of environment-friendly cigarette filter tip filler and preparation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910383354.1A CN110250567A (en) | 2019-05-08 | 2019-05-08 | A kind of environment-friendly cigarette filter tip filler and preparation method |
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| CN110250567A true CN110250567A (en) | 2019-09-20 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111533133A (en) * | 2020-04-08 | 2020-08-14 | 云南中烟工业有限责任公司 | Silicon dioxide aerogel microsphere and preparation method and application thereof |
| CN114307953A (en) * | 2020-09-30 | 2022-04-12 | 湖南中烟工业有限责任公司 | Silicon dioxide/carbon composite aerogel for reducing harmful substances in smoke and preparation and application thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114307953A (en) * | 2020-09-30 | 2022-04-12 | 湖南中烟工业有限责任公司 | Silicon dioxide/carbon composite aerogel for reducing harmful substances in smoke and preparation and application thereof |
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Legal Events
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Yu Guiqiang Inventor after: Xiong Xi Inventor after: Chu Shubao Inventor before: Yu Guiqiang Inventor before: Xiong Xi Inventor before: Zhu Shubao |
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190920 |