CN108185518A - A kind of filter core with degradable function - Google Patents

A kind of filter core with degradable function Download PDF

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Publication number
CN108185518A
CN108185518A CN201711403506.7A CN201711403506A CN108185518A CN 108185518 A CN108185518 A CN 108185518A CN 201711403506 A CN201711403506 A CN 201711403506A CN 108185518 A CN108185518 A CN 108185518A
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China
Prior art keywords
filter core
degradable
fragrance
powder
core according
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Pending
Application number
CN201711403506.7A
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Chinese (zh)
Inventor
张建波
段瑞海
刘润昌
马涛
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Yunnan Yangrui Technology Group Co Ltd
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Yunnan Yangrui Technology Group Co Ltd
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Priority to CN201711403506.7A priority Critical patent/CN108185518A/en
Publication of CN108185518A publication Critical patent/CN108185518A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/061Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Abstract

The present invention provides a kind of filter core with degradable function, is the siphunculus made of the raw material of following masses part:1 ~ 20 part of degradable high polymer material, 0 ~ 5 part of dusty material, 0 ~ 4 part of liquid perfume, 0 ~ 2 part of assistant formation material;After being sufficiently mixed after above-mentioned raw materials are stocked up in proportion using modes such as chemical melting, physical agitations, according to material character using techniques such as extrusion drawing and forming, injection molding or 3D printings to get to the filter core with degradable function.Filter core degradation rate provided by the invention is greatly enhanced, and has the advantages of biodegradability is good, and the value of environmental protection is high;Filter stick characteristic chicken flavor can be assigned, increase cigarette flavor and promotes suction mouthfeel, also the aldehydes matter effectively in absorption flue gas.Filter core provided by the invention has different structure and end face pattern, has unique product appearance feature, can reach prominent brand, identification cigarette appearance and anti-fake purpose, can be widely applied to traditional cigarette product and novel tobacco product.

Description

A kind of filter core with degradable function
Technical field
The invention belongs to traditional tobaccos and novel tobacco auxiliary material technical field, and in particular to a kind of with degradable function Filter core.
Background technology
Cigarette smoke filtering technique is one of key technology of cigarette products.At present, applied to the filtering in cigarette product Material is mainly diacetate fiber(Belong to vinegar fibre filter material).Diacetate fiber is obtained because of its good strainability and absorption taste port sense Extensive use.With the development of industry and the innovation of technology, based on vinegar fibre filter material, various forms of novel filter sticks constantly gush It is existing, such as capsule filter stick, core wire filter stick, particle filter stick, gel rubber sustained-release filter stick, concentric filter stick, ternary cavity composite filter, abnormity Hollow out filter stick etc..Influence of the innovation of filter stick technology and product to cigarette product and brand is more and more significant, to cigarette product and The development of brand also has more and more important meaning.The novel filter sticks such as capsule filter stick, core wire filter stick, are outside highlight products See or promoted suction quality or enhancing user experience, cost has different degrees of raising compared with vinegar fibre filter stick.But it is above-mentioned with Filter stick based on vinegar fibre filter material there are degradation property it is poor the problem of, degradation process is slow, and adds and increase in fibre bundle After moulding agent, bonding is more secured between fibre bundle, causes degradation more difficult.
The research of degradable filter material and filter stick has had been reported.For example, patent CN101805937A is handed over using poly- left-handed third Ester and poly- dextrorotation lactide are raw material(Two kinds for polylactic acid)Degradable pipe tobacco is prepared, then boundling rolls into filter stick.This A kind of novel tow, process needs to overcome a series of problems, as technology stability, solvent recovery, product stability and Application quality etc. could realize the part or all of replacement to diacetate fiber.However, in fact, polylactic acid tow is in flue gas Aldehydes matter rejection is fine not as good as vinegar, and tow is not easy to cut, filter stick lower hardness and not easy to control.For another example, patent Bubble that is cylindric, and being caused air flow through in its external peripheral surface longitudinal design is made in polylactic acid foam by CN203801722U Hole, then filter stick is prepared as raw material using polylactic acid foam and tobacco sheets by paper making method respectively, it is compound that the two is combined binary Filter stick.Band abscess cylinder described in the technology is grown up and is determined through polylactic acid/gas homogenous system formation, bubble nucleating, abscess The processes such as type are prepared, and there are serial procedures such as high temperature, high pressure, cooling, releases of pressure, and filter stick is the more precise and tiny device of size Part, therefore, the technique controlling difficulty of preparation process are big, and pure polylactic acid foam cost is higher.For another example, patent Edible cereal, potato, beans or starchy material are ground into the particle of homogeneous grain diameter and add in ring paste by CN103300475A Essence, gelatin and water are sufficiently mixed, then puffing filter core is prepared in extrusion molding, using puffing filter core and conventional diacetate fiber as Material is prepared into binary compound filter candle.When puffing filter core is column, although short texture, do not have a gas channel, during application Gas channel be must be specifically designed so that cigarette smoke passes through, make it possible smoking property of cigarette, the technology and aforementioned patent technology There are it is identical the defects of;When puffing filter core is particle, adds in vinegar fibre and prepare particle filter stick, with Chinese herbal medicine particle filter stick, offal The forms such as particle filter stick are no different, and particulate load performance, degradation property etc. not as good as directly by raw material crush or reproduce into particle into Row addition.
Invention content
To solve the deficiencies in the prior art, a kind of degradation property of present invention offer is good, environmental-protecting performance is high, has flavoring, is anti- The filter core of the functions such as puppet.
The purpose of the present invention is achieved by the following technical programs:A kind of filter core with degradable function, the filter core It is the siphunculus made of the raw material of following masses part:
1 ~ 20 part of degradable high polymer material, 0 ~ 5 part of dusty material, 0 ~ 4 part of liquid perfume, 0 ~ 2 part of assistant formation material.
The siphunculus is the pipe that longitudinal direction has single or multiple gas channels, and the cross section of siphunculus is arbitrary shape, such as circle Shape, polygon, heart.
The wall thickness of the siphunculus is 0.10mm to 1.0mm.
The degradable high polymer material is polylactic acid(PLA), poly butylene succinate(PBS), polyadipate/to benzene Dioctyl phthalate fourth diester(PBAT), polycaprolactone(PCL)And one or more of their modified material.
The dusty material is one or more of Plant Powder, mineral powder, starch, acetate fiber powder, active powdered carbon.Institute The grain size for stating dusty material is 18 ~ 830 μm.
The Plant Powder is through physical crushing or through carrying using medicinal plant, the root of fragrant plant, stem, leaf, flower or fruit Take, concentrate, drying, powder processed and etc. prepared by one or more of powder.Preferably, the raw material of the Plant Powder is cigarette One or more of stalk, offal, tobacco leaf, dried orange peel, pomelo peel, tealeaves/flower, agalloch eaglewood/leaf, pueraria lobata, Siraitia grosvenorii.
The mineral powder is one or more of diatomite, vermiculite, zeolite, attapulgite, sepiolite, montmorillonite through object Reason is crushed and is prepared.
The liquid perfume is ester dissolubility, alcohol-soluble fragrance, fruity class fragrance, fragrance of a flower class fragrance, medicine/Radix Aucklandiae fragrance, cool One or more of savory material;Further, ester dissolubility and alcohol-soluble fragrance are tobacco fragrance offal, offal, tobacco leaf Extract or absolute oil, fruity class fragrance for dried orange peel, sweet orange, lemon, blueberry extract or absolute oil, fragrance of a flower class fragrance for rose, The extract or absolute oil of camellia, medicine/Radix Aucklandiae fragrance is agalloch eaglewood, the extract or absolute oil of Radix Aucklandiae, and cool savory material is menthol, thin One or more of lotus alcohol.
The assistant formation material is linear low density polyethylene(LLDPE), thermoplastic elastomer (TPE)(TPE), thermoplastic poly Urethane(TPU), compatilizer, one or more of coupling agent.
The compatilizer is maleic anhydride grafted polyethylene, and coupling agent is Silane coupling agent KH550.
After being sufficiently mixed after above-mentioned raw materials are stocked up in proportion using modes such as chemical melting, physical agitations, according to material Property is using techniques such as extrusion drawing and forming, injection molding or 3D printings, you can form needed for being prepared into has degradable work( The filter core of energy.
Section pattern of filter core of the gained with degradable function with customization, fragrance, have prominent external appearance characteristic and Improve the function of cigarette products suction quality.
There is gained the filter core of degradable function to be combined alone as unitary filter stick or with vinegar fibre filter stick etc. as one Member, binary or ternary filter stick are applied to cigarette products or cigarette holder product etc..
Advantage of the invention is that:
1)Filter core degradation rate provided by the invention with degradable function is greatly enhanced, except addition needed for assistant formation Material outside, other materials used be can full-degradable biological material, have that biodegradability is good, high excellent of the value of environmental protection Point.The disintegration of high molecular degradable material is effectively accelerated in the addition of the substances such as Plant Powder, starch, further improves filter stick degradation Rate improves the value of environmental protection.
2)Filter core provided by the invention with degradable function, the Plant Powder of addition(It is equivalent to solid spice)And liquid Fragrance can assign filter stick characteristic chicken flavor, increase cigarette flavor and promote suction mouthfeel.
3)Filter core provided by the invention with degradable function, the mineral powder of addition and active powdered carbon are high-ratio surface Product porous material, the inner surface of each channel of filter stick fully and smoke contacts, can effectively adsorb the harmful substance in flue gas;Addition Vinegar fibre powder is process using waste vinegar fibre, and one side efficent use of resources, the opposing party effectively adsorbs the aldehydes matter in flue gas.
4)Filter core provided by the invention with degradable function, the dusty material of addition, can be notable when grain size is larger The external appearance characteristic of product is promoted, irregular blotches structure is presented in filter stick surface, has antifalse effect.
5)Filter core provided by the invention with degradable function, for the filter stick with different structure and end face pattern, tool There is unique product appearance feature, can reach prominent brand, identification cigarette appearance and anti-fake purpose.
6)Filter core with degradable function can be widely applied to traditional cigarette product, such as common specification cigarette, ramuscule cigarette, Short branch cigarette etc., it may also be used for novel tobacco product, such as low temperature do not burn cigarette, do not heat smoking article, can be used alone or It is used in combination with the novel filter stick of vinegar fibre filter stick or its derivative form.
Description of the drawings
Fig. 1 is the cross-sectional view of 1 gained filter core of embodiment;
Fig. 2 is the cross-sectional view of 2 gained filter core of embodiment;
Fig. 3 is the cross-sectional view of 4 gained filter core of embodiment;
Fig. 4 is the cross-sectional view of 5 gained filter core of embodiment;
Fig. 5 is the cross-sectional view of 7 composite filter of embodiment.
Specific embodiment
Further the present invention is illustrated in conjunction with the embodiments, but embodiment cannot be considered as limitation of the invention.
Embodiment 1
It by mechanical crushing after the removal of impurities of vermiculite physics and sieves, takes 380 ~ 830 μm of powder of grain size(Particle), it is spare.Take 20 parts of PBAT And molten condition is heated to, 5 parts of vermiculite powder prepared is taken to be slowly added in the PBAT of molten condition, are stirred well to powder It is uniformly mixed with melting PBAT.Using stretch forming process is squeezed out, prepared by the processes such as extruded, sizing, cooling, traction, cutting Filter core with degradable function.Gained cartridge surface have irregular sparrow pecked, filter core section be circular ring shape, outer diameter 7.7 Mm, 1.0 mm of wall thickness, 120 mm of length.By gained filter core and vinegar fibre filter stick with 5:25 ratios(Length ratio)It is compound, it obtains binary and answers Close filter stick.
Embodiment 2
Diatomite, zeolite, attapulgite, sepiolite, montmorillonite are subjected to physics removal of impurities, mechanical crushing respectively, Sieving and casing 18 ~ 48 μm of powder respectively takes 1 part of powder, and abundant mixing respectively, spare.Take 10 parts of PLA, 2 parts of LLDPE fully mixed in blender It is even and be heated to molten condition, the powder of mixing is slowly added in PLA, LLDPE mixture of melting, stirred to fully mixed It closes uniform.Using stretch forming process is squeezed out, the processes such as extruded, sizing, cooling, traction, cutting, preparing has degradable work( The filter core of energy.Filter core section is 1. shape, 7.1 mm of outer diameter, 0.2 mm of wall thickness, 120 mm of length.By gained filter core and vinegar fibre filter stick With 5:20 ratios(Length ratio)It is compound, obtain binary compound filter candle.
Embodiment 3
It by mechanical crushing after dried orange peel removal of impurities in 5 years and sieves, takes 150 ~ 250 μm of powder of grain size, it is spare.Take 1 part of PBS, 0.5 part LLDPE is stirred and evenly mixed and is heated to molten condition, and 0.1 part of Dried Tangerine Peel prepared and 0.1 part of maleic anhydride is taken to be grafted poly- second Alkene is slowly added in molten mixture, and stirring is uniform to being sufficiently mixed.Using squeeze out stretch forming process, it is extruded, sizing, it is cold But, the processes such as traction, cutting, prepare the filter core with degradable function.Gained filter core has dried orange peel fragrance, and filter core section is circle Annular, 5.2 mm of outer diameter, 0.4 mm of wall thickness, 100 mm of length.Gained filter core and vinegar fibre filter stick are subjected to tri compound, obtain vinegar fibre Filter stick:Filter core:Vinegar fibre filter stick is 12:6:12 Three-element composite filter core, as the low temperature not smoke filtration of burning tobacco and cooling Section.
Embodiment 4
By offal, offal, tobacco leaf drying, mechanical crushing is carried out after cleaning respectively, Sieving and casing is 120 ~ 180 μm of powder, is taken 1 part of offal powder, 0.5 part of offal, 0.5 part of abundant mixing of tobacco leaf powder.0.1 part of tobacco extract is taken, is dissolved in ethyl alcohol, It is even to be sprayed in mixture of powders, and stir evenly, gained mixture is spare.Take 10 parts of PCL, 1 part of LLDPE, 1 part of TPE stirring It is melted after mixing, preliminary mixture is all slowly added in fusant, using extrusion stretch forming process, extruded, sizing, The processes such as cooling, traction, cutting, prepare the filter core with degradable function.Gained filter core has this perfume of tobacco, gives off a strong fragrance full Full, filter core section isShape, outer diameter 7.7mm, 0.3 mm of wall thickness, 120 mm of length.By gained filter core and vinegar fibre filter stick with 15:15 Ratio(Length ratio)It is compound, obtain binary compound filter candle.
Embodiment 5
Acetate fiber is subjected to mechanical crushing, Sieving and casing is 75 ~ 150 μm of powder.5 parts of vinegar fibre powder are taken, add in 1 part of indigo plant Certain kind of berries extract is sufficiently mixed uniformly, spare.7 parts of PLA, 10 parts of PBAT is taken abundant mixing and to be heated to molten in blender The acetate fiber powder for sneaking out blueberry extract in advance is slowly added in PLA the and PBAT mixtures of melting by state, is stirred to fully mixed It closes uniform.Using stretch forming process is squeezed out, the processes such as extruded, sizing, cooling, traction, cutting, preparing has degradable work( The filter core of energy.Gained filter core with blueberry feature fruit sweet gas cease, filter core section be corrugated, 7.1 mm of outer diameter, 0.4 mm of wall thickness, 100 mm of length.By gained filter core and vinegar fibre filter stick with 6:24 ratios(Length ratio)It is compound, obtain binary compound filter candle.
Embodiment 6
3 parts of orange oils and 1 part of menthol are taken, are dissolved in Glycerin, mixed triester with caprylic acid capric acid, gains are sprayed and add in 20 parts of PBAT pellets In, it is uniformly mixed.Said mixture is molded by squeezing out drawing process, and addition Masterbatch is in mixture in right amount, through molten The processes such as melt, squeeze out, shaping, cooling down, drawing, preparing the orange filter core with degradable function.Gained filter core cross section is Circular ring shape, 3.0 mm of outer diameter, 0.4 mm of wall thickness are wound into disk.By gained continuously filter core(Core item)Pass through special work Skill landfill prepares the composite filter with the orange degradable filter core of circle centered on cross section, visualization effect in diacetate fiber center Fruit is good, composite filter application cigarette, has the function of to improve mouthfeel, sense of promoting the production of body fluid, and have the fragrant and sweet rhythm of fruit.
Meanwhile in the case where being not added with orange oil and menthol, prepare same specification using PBAT as the degradable of material Filter core(Core item), in addition to characteristic fragrance is different with mouthfeel, gained filter core, composite filter and cigarette have identical visual appearance Effect.
Embodiment 7
Sieving and casing is 75 ~ 180 μm of starch, spare.10 parts of PLA, 2 parts of LLDPE is taken abundant mixing and to be heated in blender To molten condition, 1 part of starch sieved is taken to be slowly added in PLA, LLDPE mixture of molten condition, stirring is fully to mixed It closes uniform.With stretch forming process is squeezed out, the processes such as extruded, sizing, cooling, traction prepare the filter with degradable function Core.Gained filter core section is " ☆ " shape, and 2.0 mm of maximum outside diameter, 0.2 mm of wall thickness are wound into disk.Gained is continuously filtered Core(Core item)The band degradable filter core of " ☆ " shape centered on diacetate fiber center, preparation cross section is filled by special technique Composite filter, effect of visualization is good, composite filter application cigarette, has the product appearance of differentiation, has antifalse effect.
Filter stick degradation property is detected using soil buries method, biodegradation takes place in about 60 days in the filter core of embodiment 1,5,6, real Biodegradation takes place in about 150 days in the filter core for applying example 2,3,4,7.

Claims (10)

1. a kind of filter core with degradable function, it is characterised in that:The filter core is led to made of the raw material of following masses part Pipe:
1 ~ 20 part of degradable high polymer material, 0 ~ 5 part of dusty material, 0 ~ 4 part of liquid perfume, 0 ~ 2 part of assistant formation material.
2. the filter core according to claim 1 with degradable function, it is characterised in that:The siphunculus is that longitudinal direction has list The pipe of a or multiple gas channels, the cross section of siphunculus is arbitrary shape.
3. the filter core according to claim 1 with degradable function, it is characterised in that:The wall thickness of the siphunculus is 0.10mm to 1.0mm.
4. the filter core according to claim 1 with degradable function, it is characterised in that:The degradable high polymer material For polylactic acid, poly butylene succinate, polyadipate/butylene terephthalate, polycaprolactone and their modified material One or more of.
5. the filter core according to claim 1 with degradable function, it is characterised in that:The dusty material is plant One or more of powder, mineral powder, starch, acetate fiber powder, active powdered carbon;The grain size of dusty material is 18 ~ 830 μm.
6. the filter core according to claim 5 with degradable function, it is characterised in that:The Plant Powder is using medicinal Plant, the root of fragrant plant, stem, leaf, flower or fruit are through powder prepared by physical crushing or extracted, concentration, dry, powder processed One or more of.
7. the filter core according to claim 5 with degradable function, it is characterised in that:The mineral powder for diatomite, One or more of vermiculite, zeolite, attapulgite, sepiolite, montmorillonite are prepared through physical crushing.
8. the filter core according to claim 1 with degradable function, it is characterised in that:The liquid perfume is molten for ester One or more of property, alcohol-soluble fragrance, fruity class fragrance, fragrance of a flower class fragrance, medicine/Radix Aucklandiae fragrance, cool savory material;Ester dissolubility It is tobacco fragrance offal with alcohol-soluble fragrance, the extract or absolute oil of offal, tobacco leaf, fruity class fragrance is dried orange peel, sweet orange, lemon The extract or absolute oil of lemon, blueberry, fragrance of a flower class fragrance is rose, the extract or absolute oil of camellia, and medicine/Radix Aucklandiae fragrance is heavy Fragrant, Radix Aucklandiae extract or absolute oil, cool savory material are one or more of menthol, menthol.
9. the filter core according to claim 1 with degradable function, it is characterised in that:The assistant formation material is line One or more of property low density polyethylene (LDPE), thermoplastic elastomer (TPE), thermoplastic polyurethane, compatilizer, coupling agent.
10. the filter core according to claim 9 with degradable function, it is characterised in that:The compatilizer is maleic acid Acid anhydride grafted polyethylene, coupling agent are Silane coupling agent KH550.
CN201711403506.7A 2017-12-22 2017-12-22 A kind of filter core with degradable function Pending CN108185518A (en)

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CN109674087A (en) * 2018-12-24 2019-04-26 中国科学技术大学 A kind of polymer-based cigarette filter tip material and preparation method thereof with excellent temperature control effect
CN109770421A (en) * 2019-03-26 2019-05-21 云南氪莱铂科技有限公司 A kind of flavoring sustained-release gel particle, preparation and its application for cigarette filter rod
CN109998164A (en) * 2019-04-03 2019-07-12 红云红河烟草(集团)有限责任公司 Cigarette filter stick flavor enhancing particle and cigarette filter stick
CN110200317A (en) * 2019-05-08 2019-09-06 中山市博海精细化工有限公司 A kind of low viscosity cigarette filter filler and preparation method
CN110250567A (en) * 2019-05-08 2019-09-20 中山市博海精细化工有限公司 A kind of environment-friendly cigarette filter tip filler and preparation method
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CN111349323A (en) * 2020-04-30 2020-06-30 贵州省烟草公司遵义市公司 Mixed resin based on tobacco extract additive and prepared biodegradable film
CN111543672A (en) * 2020-05-21 2020-08-18 中国烟草总公司郑州烟草研究院 Preparation method of novel filter stick capable of reducing release amount of phenol in smoke and filter stick product
CN111844600A (en) * 2020-07-28 2020-10-30 昆山久硕电子有限公司 Preparation process of plastic filter core rod
CN112089093A (en) * 2020-10-13 2020-12-18 云南养瑞科技集团有限公司 Preparation method and application of aroma-enhancing degradable plastic particles
CN113080509A (en) * 2021-04-12 2021-07-09 上海华宝生物科技有限公司 Temperature-reducing member master batch for heating non-combustible cigarettes and preparation method thereof
CN113925201A (en) * 2021-10-26 2022-01-14 湖北中烟工业有限责任公司 High-filtration low-suction-resistance degradable cigarette filter tip and preparation method thereof
WO2022121480A1 (en) * 2020-12-11 2022-06-16 湖北中烟工业有限责任公司 Fully degradable cooling assembly, preparation method therefor and use thereof
CN115606840A (en) * 2022-11-15 2023-01-17 湖北中烟工业有限责任公司 Cigarette with 3D printing fragrance-carrying model and preparation method thereof
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CN109674087A (en) * 2018-12-24 2019-04-26 中国科学技术大学 A kind of polymer-based cigarette filter tip material and preparation method thereof with excellent temperature control effect
CN109770421B (en) * 2019-03-26 2021-08-06 云南氪莱铂科技有限公司 Flavoring slow-release gel particles for cigarette filter stick, preparation and application thereof
CN109770421A (en) * 2019-03-26 2019-05-21 云南氪莱铂科技有限公司 A kind of flavoring sustained-release gel particle, preparation and its application for cigarette filter rod
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Application publication date: 20180622