CN110208328A - A kind of Test of accuracy system and method for the online pH table of power plant water-steam system - Google Patents

A kind of Test of accuracy system and method for the online pH table of power plant water-steam system Download PDF

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Publication number
CN110208328A
CN110208328A CN201910496039.XA CN201910496039A CN110208328A CN 110208328 A CN110208328 A CN 110208328A CN 201910496039 A CN201910496039 A CN 201910496039A CN 110208328 A CN110208328 A CN 110208328A
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online
detected
conductivity
standard
water sample
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Inventor
刘玮
黄茜
田利
曹杰玉
戴鑫
潘珺
刘欣
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Xian Thermal Power Research Institute Co Ltd
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Thermal Power Research Institute
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/02Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
    • G01N27/04Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
    • G01N27/06Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a liquid

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
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  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

Abstract

A kind of Test of accuracy system and method for the online pH table of power plant water-steam system, the system include and are detected the standard conductivity table that online pH table is connected in parallel, the Data collection and precessing system connecting with standard conductivity table output end;The method of inspection are as follows: 1) by standard conductivity table nearby be detected online pH table and be connected in parallel, water sample is the water sample being detected when online pH table normally measures, by the conductivity measurements of Data collection and precessing system acquisition standard conductivity table;2) conductivity measurements of standard conductivity table are converted to pH value by Data collection and precessing system;3) Data collection and precessing system according to the pH value after conversion and is detected the indicating value of online pH table, calculates the error for being detected online pH table, if error is exceeded, then carries out on-line calibration to being detected online pH table;The present invention does not need to generate standard water sample using low conductivity pH standard water sample preparation facilities, does not need disassembly yet and is detected online pH table, entire checkout procedure is simple, convenient, fast.

Description

A kind of Test of accuracy system and method for the online pH table of power plant water-steam system
Technical field
The invention belongs to power plant water-steam system on-line chemical monitoring instruments to examine field, be related to a kind of power plant water-steam system and exist The Test of accuracy method and system of line pH table.
Background technique
Online pH table is the key chemical instrument in power plant monitoring instrument for steam water system in power plant, it is ensured that online pH table measurement is quasi- Really, and its measured value is controlled in acceptability limit, can effectively prevent the etching problem of heat power equipment.The online pH table of water-steam system Measurement accuracy is not only influenced by online factor (streaming potential, earth-return etc.), and also by pure water factor, (liquid junction potential, temperature are mended Repay) it influences, so DL/T 677-2018 " power plant on-line chemical monitoring instrument inspection procedure " regulation is for measurement water-steam system electricity Conductivity value is not more than the online pH table of 100 μ S/cm, should use the online method of inspection.Currently, the online accuracy inspection of online pH table Proved recipe method is to generate standard water sample method using low conductivity pH standard water sample preparation facilities, needs to dismantle and is detected online pH table.
Summary of the invention
The present invention provides a kind of simple and reliable online pH table Test of accuracy system and method for power plant water-steam system, It does not need to generate standard water sample using low conductivity pH standard water sample preparation facilities, does not need disassembly yet and be detected online pH table.
In order to achieve the above objectives, the present invention adopts the following technical scheme:
A kind of Test of accuracy system of the online pH table of power plant water-steam system, including be connected in parallel with online pH table is detected Standard conductivity table 1, the Data collection and precessing system 2 being connect with 1 output end of standard conductivity table.
The method of inspection of the Test of accuracy system of water-steam system online pH table in power plant of the present invention, including it is following Step:
1) by standard conductivity table 1 nearby be detected online pH table and be connected in parallel, water sample is to be detected online pH table normally to survey Water sample when amount, standard conductivity table 1 and is detected online pH table respectively while measuring water sample conductivity and pH value, is acquired by data The conductivity measurements of standard conductivity table 1 are acquired with processing system 2;
2) Data collection and precessing system 2 converts the conductivity measurements of standard conductivity table 1, principle are as follows: hair The water quality purity of Power Plant Water Vapor system is very high, and containing a small amount of ammonia, low concentration pure water containing ammonia can be calculated by thermodynamic data PH value and conductivity between theory of correspondences value, the conductivity measurements of standard conductivity table 1 directly can be converted into pH Value;
3) Data collection and precessing system 2 according to the pH value after conversion and is detected the indicating value of online pH table, calculates tested The complete machine error of indication of online pH table, according to online pH table specification is detected, is carried out if error is exceeded to online pH table is detected Line calibration.
The invention has the following advantages over the prior art:
(1) it does not need to generate standard water sample using low conductivity pH standard water sample preparation facilities, saves waiting standard water sample The time (30min or more) of rinse-system.
(2) it does not need disassembly and is detected online pH table, do not influence tested pH table in the normal water sample function of the measurement of inspection period, Entire checkout procedure is simple, convenient, fast.
Detailed description of the invention
Fig. 1 is checking system of the present invention and method of inspection schematic diagram.
Wherein, 1 is standard conductivity table, and 2 be Data collection and precessing system.
Specific embodiment
The invention will be described in further detail with reference to the accompanying drawing:
With reference to Fig. 1, water-steam system online pH table Test of accuracy system in power plant of the present invention includes: standard conductance Rate table 1 is connected in parallel with online pH table is detected, and the output end of standard conductivity table 1 is connected with Data collection and precessing system 2.
Water-steam system online pH table Test of accuracy method in power plant of the present invention the following steps are included:
1) by standard conductivity table 1 nearby be detected online pH table and be connected in parallel, water sample is to be detected online pH table normally to survey Water sample when amount, standard conductivity table 1 and is detected online pH table respectively while measuring water sample conductivity and pH value.It is acquired by data The conductivity measurements of standard conductivity table 1 are acquired with processing system 2.
2) Data collection and precessing system 2 converts the conductivity measurements of standard conductivity table 1, principle are as follows: hair The water quality purity of Power Plant Water Vapor system is very high, and containing a small amount of ammonia, low concentration pure water containing ammonia can be calculated by thermodynamic data PH value and conductivity between theory of correspondences value, the conductivity measurements of standard conductivity table directly can be converted into pH Value.
3) Data collection and precessing system 2 according to the pH value after conversion and is detected the indicating value of online pH table, calculates tested The complete machine error of indication of online pH table, according to online pH table specification is detected, is carried out if error is exceeded to online pH table is detected Line calibration.
Final purpose of the present invention is that a kind of simple and reliable water-steam system is provided for Chemical Instruments in Electric Power Plants operation maintenance personnel Online pH table Test of accuracy method and system, only use the very short time, can be achieved with the online pH table accuracy of water-steam system In X -ray inspection X, the measurement accuracy of online pH table is improved, for preventing water-steam system metal erosion, guaranteeing that generating set passes through safely Ji operation is of great significance.

Claims (2)

1. a kind of Test of accuracy system of the online pH table of power plant water-steam system, it is characterised in that: including be detected online pH The standard conductivity table (1) that table is connected in parallel, the Data collection and precessing system being connect with standard conductivity table (1) output end (2)。
2. the method for inspection of the Test of accuracy system of water-steam system online pH table in power plant described in claim 1, feature It is: the following steps are included:
1) by standard conductivity table (1) nearby be detected online pH table and be connected in parallel, water sample is to be detected online pH table normally to measure When water sample, standard conductivity table (1) and be detected online pH table respectively while measuring water sample conductivity and pH value, acquired by data With the conductivity measurements of processing system (2) acquisition standard conductivity table (1);
2) Data collection and precessing system (2) converts the conductivity measurements of standard conductivity table (1), by standard conductance The conductivity measurements of rate table (1) are converted to pH value;
3) Data collection and precessing system (2) according to the pH value after conversion and is detected the indicating value of online pH table, calculates and is detected The complete machine error of indication of line pH table, according to online pH table specification is detected, carries out online if error is exceeded to online pH table is detected Calibration.
CN201910496039.XA 2019-06-10 2019-06-10 A kind of Test of accuracy system and method for the online pH table of power plant water-steam system Pending CN110208328A (en)

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CN201910496039.XA CN110208328A (en) 2019-06-10 2019-06-10 A kind of Test of accuracy system and method for the online pH table of power plant water-steam system

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111060561A (en) * 2019-12-31 2020-04-24 陕西中良智能科技有限公司 Device, method and system for monitoring ph value of liquid
CN112798758A (en) * 2021-03-16 2021-05-14 西安热工研究院有限公司 Intelligent checking and maintaining system and method for online chemical instrument
CN115420789A (en) * 2022-08-29 2022-12-02 大唐秦岭发电有限公司 Power plant low-conductivity water pH electrode failure detection system and method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201034966Y (en) * 2007-04-13 2008-03-12 西安热工研究院有限公司 Testing device of mobile on-line pH measuring instrument
CN201035099Y (en) * 2007-04-13 2008-03-12 西安热工研究院有限公司 Mobile on-line electric conductivity measuring instrument testing device
CN206624728U (en) * 2017-03-23 2017-11-10 长安石门发电有限公司 A kind of electric generator inner cooling water treatment system
CN207730753U (en) * 2018-01-31 2018-08-14 华能陕西秦岭发电有限公司 One kind being used for power plant 2 calibration systems of online pH tables
CN210894193U (en) * 2019-06-10 2020-06-30 西安热工研究院有限公司 Accuracy inspection system of online pH table of power plant steam system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201034966Y (en) * 2007-04-13 2008-03-12 西安热工研究院有限公司 Testing device of mobile on-line pH measuring instrument
CN201035099Y (en) * 2007-04-13 2008-03-12 西安热工研究院有限公司 Mobile on-line electric conductivity measuring instrument testing device
CN206624728U (en) * 2017-03-23 2017-11-10 长安石门发电有限公司 A kind of electric generator inner cooling water treatment system
CN207730753U (en) * 2018-01-31 2018-08-14 华能陕西秦岭发电有限公司 One kind being used for power plant 2 calibration systems of online pH tables
CN210894193U (en) * 2019-06-10 2020-06-30 西安热工研究院有限公司 Accuracy inspection system of online pH table of power plant steam system

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111060561A (en) * 2019-12-31 2020-04-24 陕西中良智能科技有限公司 Device, method and system for monitoring ph value of liquid
CN112798758A (en) * 2021-03-16 2021-05-14 西安热工研究院有限公司 Intelligent checking and maintaining system and method for online chemical instrument
WO2022193562A1 (en) * 2021-03-16 2022-09-22 西安热工研究院有限公司 Intelligent verification and maintenance system and method for online chemical instruments
CN115420789A (en) * 2022-08-29 2022-12-02 大唐秦岭发电有限公司 Power plant low-conductivity water pH electrode failure detection system and method

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